CN115558532A - Environment-friendly fuel for engine - Google Patents

Environment-friendly fuel for engine Download PDF

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Publication number
CN115558532A
CN115558532A CN202211198274.7A CN202211198274A CN115558532A CN 115558532 A CN115558532 A CN 115558532A CN 202211198274 A CN202211198274 A CN 202211198274A CN 115558532 A CN115558532 A CN 115558532A
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parts
auxiliary agent
environment
oil
cosolvent
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CN202211198274.7A
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Chinese (zh)
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姚焱
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/04Catalyst added to fuel stream to improve a reaction
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • C10L2270/026Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses an environment-friendly fuel for an engine, which comprises the following components in parts by mass: 55-75 parts of base diesel oil, 15-45 parts of illegal cooking oil and 0.5-10 parts of auxiliary agent, wherein the flash point of the base diesel oil is 50-90 ℃, the density at normal temperature is 0.83-0.86g/ml, and the kinematic viscosity at normal temperature is 1.9-3.4mm 2 The illegal cooking oil has a flash point of 135-165 deg.C, a density of 0.83-0.886g/ml at room temperature, and a kinematic viscosity of 4.2-5.7mm at room temperature 2 S, the auxiliary agent comprises a cosolvent0.5-5 parts. The environment-friendly fuel provided by the invention has the advantages of reducing incomplete combustion of the fuel and reducing emission of hydrocarbon, oxynitride and the like.

Description

Environment-friendly fuel for engine
Technical Field
The invention belongs to the technical field of green fuels, and particularly relates to an environment-friendly fuel suitable for a diesel engine.
Background
The traditional engine obtains kinetic energy by burning petroleum, for example, a gasoline engine, air and gasoline are mixed into good mixed gas in a certain proportion, the mixed gas is sucked into a cylinder in an air suction stroke, the mixed gas is compressed, ignited and burned to generate heat energy, high-temperature and high-pressure gas acts on the top of a piston to push the piston to do reciprocating linear motion, and mechanical energy is output outwards through a connecting rod and a crankshaft flywheel mechanism. For another example, a diesel engine uses high temperature generated by compressed air to ignite diesel fuel for combustion to generate heat energy. However, the traditional petroleum fuel is not renewable, so that the dilemma of resource exhaustion always exists, and in addition, in the combustion process of the traditional fuel, a large amount of pollutants such as carbon dioxide, sulfur dioxide, dust and the like can be generated, so that the environment is influenced. In particular, diesel engines are prone to incomplete combustion and also produce large amounts of carbon monoxide, which not only pollutes the environment but also reduces the performance of the engine and reduces the life of the engine. With the increasing environmental pollution, people's demand for clean energy is more and more urgent, and therefore, it is necessary to find an environmentally friendly fuel capable of being regenerated and reducing environmental pollution in the future energy industry.
The biomass energy is renewable clean energy, carbon dioxide and water are synthesized into biomass through photosynthesis of green plants in the energy conversion process, and the carbon dioxide and the water are circularly discharged into the environment through the use of the biomass energy, so that the carbon emission can be effectively reduced. But biomass energy is widely used in the fields of industrial boilers, industrial heat supply and the like. The use of biomass energy in motor fuels has also been less studied.
Currently, the main forms of biomass energy are fuel ethanol, biodiesel and biological hydrogen production. The fuel ethanol is prepared by using grain plants or plant fibers as raw materials, producing high-purity absolute ethanol through fermentation and dehydration, and mixing the absolute ethanol with gasoline to be used as fuel. The raw materials of the biodiesel are mostly vegetable soybean oil, illegal cooking oil, rapeseed oil, castor oil, cottonseed oil, illegal cooking oil and the like, and are converted into liquid fuels through cracking, biomass pyrolysis or alcoholysis. The hydrogen can be obtained by microbial fermentation.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides an environment-friendly fuel for an engine, which is particularly suitable for a diesel engine, reduces incomplete combustion of the fuel, and reduces the emission of hydrocarbon, oxynitride and the like.
In order to achieve the purpose, the invention adopts the technical scheme that: the environment-friendly fuel for the engine is characterized by comprising the following components in parts by mass:
55-75 parts of basic diesel oil,
15-45 parts of illegal cooking oil,
0.5-10 parts of an auxiliary agent,
wherein the flash point of the base diesel oil is 50-90 ℃, and the density at normal temperature is 0.83-086g/ml, kinematic viscosity at room temperature of 1.9-3.4mm 2 /s,
The swish point of the illegal cooking oil is 135-165 ℃, the density at normal temperature is 0.83-0.886g/ml, and the kinematic viscosity at normal temperature is 4.2-5.7mm 2 /s,
The auxiliary agent comprises 0.5-5 parts of cosolvent.
Further, the feed comprises the following components in parts by mass:
65-75 parts of basic diesel oil,
15-25 parts of illegal cooking oil,
0.5-10 parts of an auxiliary agent,
wherein,
the auxiliary agent comprises 0.5-1 part of cosolvent,
the auxiliary agent also comprises a catalyst, and the catalyst accounts for 0.5-1 part.
Further, the feed comprises the following components in parts by mass:
55-70 parts of basic diesel oil,
20-35 parts of illegal cooking oil,
0.5-10 parts of an auxiliary agent,
wherein,
the auxiliary agent comprises a cosolvent, the cosolvent accounts for 0.5-1 part,
the auxiliary agent also comprises a catalyst, and the catalyst accounts for 0.5-1 part.
Further, the feed comprises the following components in parts by mass:
50-60 parts of basic diesel oil,
35-45 parts of illegal cooking oil,
0.5 to 5 portions of auxiliary agent,
wherein,
the auxiliary agent comprises 0.5-5 parts of cosolvent,
the auxiliary agent also comprises a catalyst, and the catalyst accounts for 0.5-3 parts.
Furthermore, the cosolvent is butyl nitrate, the catalyst is catalase, and the mass ratio of the butyl nitrate to the catalase is 2-1.
By adopting the scheme, the fuel oil for the engine has the advantages of emission reduction, environmental protection, full combustion of the power oil, reduction of harmful gas emission and great contribution to environmental protection; the cleaning and the maintenance are safe, the power oil has excellent performance, and the vehicle is well maintained.
The invention is further described with reference to specific examples.
Detailed Description
The specific embodiments of the present invention are shown below:
1. the ingredients of the concrete examples are prepared according to the mixture ratio in Table 1
TABLE 1 ingredient Table
Basic diesel oil (kg) Illegal cooking oil (kg) Cosolvent (kg) Catalyst (kg)
Example 1 75 15 0.5 0.5
Example 2 60 20 1 0.5
Example 3 70 35 0.5 0.5
Example 4 45 45 5 3
Comparative example 1 75 15 0 0
Comparative example 2 60 20 1 0
Comparative example 3 60 20 0 0.5
Comparative example 4 45 45 0 3
In the above examples 1 to 4, the mass ratios of the base diesel oil and the illegal cooking oil are respectively 3; no auxiliary was added in comparative example 1, no catalyst was added in comparative example 2, and no co-solvent was added in comparative example 3.
The flash point of the base diesel oil is 50.3, the density at 20 ℃ is 0.833g/ml, and the kinematic viscosity at 20 ℃ is 1.92mm 2 S; the swish point of the illegal cooking oil is 160 ℃, the density at 20 ℃ is 0.88g/ml, and the kinematic viscosity at 20 ℃ is 4.53mm 2 And s. Firstly, adding cosolvent butyl nitrate and catalase into the illegal cooking oil, uniformly mixing, and then pouring the mixture into the base diesel oil together to uniformly mix at a high speed.
2. The performance test of the mixed clean fuel of the above embodiment is performed, and the results are shown in table 2,
TABLE 2 Performance of the Mixed cleaning oils
Figure BDA0003871295930000041
As can be seen from the comparison of the examples 1 to 4, when the mass ratio of the base diesel oil to the illegal cooking oil is 2; as can be seen from the comparison of examples 2-3, when the mass ratio of the base diesel oil to the illegal cooking oil is consistent, but the amount of the auxiliary agent cannot be kept up with the mass ratio of the base diesel oil to the illegal cooking oil, the performance of the illegal cooking oil is greatly influenced; from comparative examples 1 to 4, it can be seen that when neither the co-solvent nor the catalyst is present, or only the co-solvent is present and only the catalyst is present, the effect of mixing the base diesel oil and the illegal cooking oil is not significantly improved.
3. The fuel oil prepared in the above examples 1 to 4 was subjected to combustion test
The adopted engine is a 295D type diesel engine which is used for a generating set and is directly sprayed with water and cooled, and the working rotating speed is 1500r/min. Specific properties are shown in Table 3.
TABLE 3 Diesel engine test data
Figure BDA0003871295930000051
From the test data of examples 1-4, it is clear that there is a significant decrease in CO, HC, NOx, PM, sulfur dioxide, smoke levels, etc. The change from the CO carbon of comparative examples 1-4 compared to the base diesel was not significant.
The present invention is not limited to the above embodiments, and those skilled in the art can implement the present invention in other various embodiments according to the disclosure of the present invention, or can make simple changes or modifications according to the design structure and idea of the present invention, and fall into the protection scope of the present invention.

Claims (5)

1. The environment-friendly fuel for the engine is characterized by comprising the following components in parts by mass:
55-75 parts of basic diesel oil,
15-45 parts of illegal cooking oil,
0.5 to 10 portions of auxiliary agent,
wherein the base diesel oil has a flash point of 50-90 deg.C, a density of 0.83-0.86g/ml at room temperature, and a kinematic viscosity of 1.9-3.4mm at room temperature 2 /s,
The swish point of the illegal cooking oil is 135-165 ℃, the density at normal temperature is 0.83-0.886g/ml, and the kinematic viscosity at normal temperature is 4.2-5.7mm 2 /s,
The auxiliary agent comprises a cosolvent, and the cosolvent accounts for 0.5-5 parts.
2. The environment-friendly fuel for the engine according to claim 1, which is characterized by comprising the following components in parts by mass:
65-75 parts of basic diesel oil,
15-25 parts of illegal cooking oil,
0.5 to 10 portions of auxiliary agent,
wherein,
the auxiliary agent comprises 0.5-1 part of cosolvent,
the auxiliary agent also comprises a catalyst, and the catalyst accounts for 0.5-1 part.
3. The environment-friendly fuel for the engine according to claim 1, which is characterized by comprising the following components in parts by mass:
55-70 parts of basic diesel oil,
20-35 parts of illegal cooking oil,
0.5-10 parts of an auxiliary agent,
wherein,
the auxiliary agent comprises 0.5-1 part of cosolvent,
the auxiliary agent also comprises a catalyst, and the catalyst accounts for 0.5-1 part.
4. The environment-friendly fuel for the engine according to claim 1, which is characterized by comprising the following components in parts by mass:
50-60 parts of basic diesel oil,
35-45 parts of illegal cooking oil,
0.5-5 parts of an auxiliary agent,
wherein,
the auxiliary agent comprises a cosolvent, the cosolvent accounts for 0.5-5 parts,
the auxiliary agent also comprises 0.5-3 parts of catalyst.
5. The environment-friendly fuel for engines as claimed in any one of claims 1 to 4, wherein the cosolvent is butyl nitrate, the catalyst is catalase, and the mass ratio of the butyl nitrate to the catalase is 2.
CN202211198274.7A 2022-09-29 2022-09-29 Environment-friendly fuel for engine Pending CN115558532A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1869168A (en) * 2006-06-27 2006-11-29 姜建华 Blended diesel oil and its preparation method
CN102776037A (en) * 2012-08-08 2012-11-14 梅州市骏奇科技有限公司 Biological tempered fuel oil using illegal cooking oil as raw material and preparation method thereof
CN103194282A (en) * 2013-04-08 2013-07-10 黄河三角洲京博化工研究院有限公司 Diesel composite additive
CN103421552A (en) * 2013-07-30 2013-12-04 英杰惠能(北京)能源新技术有限公司 Diesel oil improver component containing biological enzyme and preparation method and application thereof
CN105296024A (en) * 2015-11-19 2016-02-03 深圳市广昌达实业有限公司 Multifunctional diesel oil cetane number improver and preparation method thereof
CN107083263A (en) * 2017-04-28 2017-08-22 马健 Diesel cetane-number improver
CN113322107A (en) * 2020-08-26 2021-08-31 中国石油天然气股份有限公司 Marine residual fuel oil and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1869168A (en) * 2006-06-27 2006-11-29 姜建华 Blended diesel oil and its preparation method
CN102776037A (en) * 2012-08-08 2012-11-14 梅州市骏奇科技有限公司 Biological tempered fuel oil using illegal cooking oil as raw material and preparation method thereof
CN103194282A (en) * 2013-04-08 2013-07-10 黄河三角洲京博化工研究院有限公司 Diesel composite additive
CN103421552A (en) * 2013-07-30 2013-12-04 英杰惠能(北京)能源新技术有限公司 Diesel oil improver component containing biological enzyme and preparation method and application thereof
CN105296024A (en) * 2015-11-19 2016-02-03 深圳市广昌达实业有限公司 Multifunctional diesel oil cetane number improver and preparation method thereof
CN107083263A (en) * 2017-04-28 2017-08-22 马健 Diesel cetane-number improver
CN113322107A (en) * 2020-08-26 2021-08-31 中国石油天然气股份有限公司 Marine residual fuel oil and preparation method thereof

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Application publication date: 20230103