CN115530133A - Fishhook processing technology for improving surface glossiness of fishhook - Google Patents
Fishhook processing technology for improving surface glossiness of fishhook Download PDFInfo
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- CN115530133A CN115530133A CN202210440500.1A CN202210440500A CN115530133A CN 115530133 A CN115530133 A CN 115530133A CN 202210440500 A CN202210440500 A CN 202210440500A CN 115530133 A CN115530133 A CN 115530133A
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- fishhook
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- processing technology
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- 238000005516 engineering process Methods 0.000 title claims abstract description 23
- 238000012545 processing Methods 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 15
- 239000010452 phosphate Substances 0.000 claims abstract description 15
- 239000000853 adhesive Substances 0.000 claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 claims abstract description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 50
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 37
- 238000003756 stirring Methods 0.000 claims description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 239000003973 paint Substances 0.000 claims description 29
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 27
- 239000000395 magnesium oxide Substances 0.000 claims description 25
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 25
- 239000000843 powder Substances 0.000 claims description 25
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 25
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 23
- 238000010992 reflux Methods 0.000 claims description 23
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 22
- -1 lithium aluminum hydride Chemical compound 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 22
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 21
- 239000004094 surface-active agent Substances 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 18
- 239000012153 distilled water Substances 0.000 claims description 18
- 239000003112 inhibitor Substances 0.000 claims description 18
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 238000001914 filtration Methods 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- 239000005543 nano-size silicon particle Substances 0.000 claims description 14
- 235000012239 silicon dioxide Nutrition 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 238000001962 electrophoresis Methods 0.000 claims description 11
- 239000012280 lithium aluminium hydride Substances 0.000 claims description 11
- QUUCYKKMFLJLFS-UHFFFAOYSA-N Dehydroabietan Natural products CC1(C)CCCC2(C)C3=CC=C(C(C)C)C=C3CCC21 QUUCYKKMFLJLFS-UHFFFAOYSA-N 0.000 claims description 10
- NFWKVWVWBFBAOV-UHFFFAOYSA-N Dehydroabietic acid Natural products OC(=O)C1(C)CCCC2(C)C3=CC=C(C(C)C)C=C3CCC21 NFWKVWVWBFBAOV-UHFFFAOYSA-N 0.000 claims description 10
- NFWKVWVWBFBAOV-MISYRCLQSA-N dehydroabietic acid Chemical compound OC(=O)[C@]1(C)CCC[C@]2(C)C3=CC=C(C(C)C)C=C3CC[C@H]21 NFWKVWVWBFBAOV-MISYRCLQSA-N 0.000 claims description 10
- 229940118781 dehydroabietic acid Drugs 0.000 claims description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 9
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 9
- 238000004132 cross linking Methods 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 9
- 239000011259 mixed solution Substances 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 238000005488 sandblasting Methods 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 230000001680 brushing effect Effects 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000003672 processing method Methods 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 27
- 239000011248 coating agent Substances 0.000 abstract description 24
- 239000002105 nanoparticle Substances 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 3
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- 239000002253 acid Substances 0.000 description 6
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- 230000032683 aging Effects 0.000 description 4
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- 239000003208 petroleum Substances 0.000 description 4
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- 238000004519 manufacturing process Methods 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical group C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical group O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
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- 230000001804 emulsifying effect Effects 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical group OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K83/00—Fish-hooks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/448—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications characterised by the additives used
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/04—Electrophoretic coating characterised by the process with organic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a fishhook processing technology for improving the surface glossiness of a fishhook, which relates to the field of fishhook processing technologies, and solves the problems that the existing fishhook is simple in structure, single in color, low in glossiness and generally long in fishing time, so that the eyes and body of a fisher are easily fatigued, and the fishing efficiency is low; the nano particle surface coating technology is innovatively applied to phosphate inorganic anticorrosive coatings, the Mg0 curing agent is subjected to surface modification by adopting the nano particle surface coating technology, and the modified nano particle surface coating technology is mixed with a phosphate adhesive to enable the anticorrosive coatings to be automatically cured at normal temperature, so that the anticorrosive coatings with excellent comprehensive properties such as water resistance, salt fog resistance, high temperature resistance, adhesive force and the like are obtained.
Description
Technical Field
The invention relates to the field of fishhook processing technology, in particular to a fishhook processing technology for improving the surface glossiness of fishhooks.
Background
Along with the development of the fishing motion industry, more and more people begin to like the fishing motion, and a fishhook is used as an indispensable tool of the fishing motion, a good fishhook is convenient for improving the happiness degree in the whole fishing process, the fishhook not only has good quality, is light and hard to break, but also has ingenious design and is comfortable to use, so the fishhook can be one of the most intense market segments of fishing gear market competition, and various comprehensive manufacturers use the fishhook as a main fishing product for production, but the existing fishhook has simple structure, single color and low glossiness, the fishing time is generally longer, the eyes and the body of a fisher are very easy to be fatigued, the fishing efficiency is low, and the fishhook is easily corroded and damaged due to the influence of the environment after being soaked in pool water for a long time;
how to improve the low glossiness of the existing fishhook is the key of the invention, so a fishhook for improving the surface glossiness of the fishhook is needed to solve the problems.
Disclosure of Invention
In order to overcome the technical problems, the invention aims to provide a fishhook processing technology for improving the surface glossiness of the fishhook, which comprises the following steps:
(1) The fishhook processing method comprises the steps of pretreating a fishhook to be processed, polishing and sand blasting the fishhook, painting anticorrosive paint on the polished fishhook, and plating color paint on the fishhook in an electrophoresis mode to obtain the fishhook, and solves the problems that the existing fishhook is simple in structure, single in color, low in glossiness, long in fishing time, easy to cause fatigue of eyes and bodies of a fisher, and low in fishing efficiency;
(2) Uniformly mixing a phosphate adhesive, titanium dioxide, a crosslinking accelerator, an acidic inhibitor and distilled water to obtain a film-forming base material, ultrasonically dispersing magnesium oxide powder into a mixed solution of ethanol, deionized water and ammonia water, simultaneously dropwise adding tetraethoxysilane to the mixed solution to obtain magnesium oxide powder coated by nano silicon dioxide particles, uniformly mixing the magnesium oxide powder coated by the nano silicon dioxide particles, barium sulfate, a polymerization inhibitor, a surfactant and the distilled water to obtain a curing component, mixing and stirring the film-forming base material and the curing component to obtain the anticorrosive coating, and solving the problems that a fishhook is easily corroded and damaged due to the influence of the environment after being soaked in pool water for a long time;
(3) Adding dehydroabietic acid into a three-neck flask, adding dichloromethane for dissolution, dropwise adding thionyl chloride at room temperature to obtain an intermediate A, dissolving the intermediate A in tetrahydrofuran, dropwise adding a tetrahydrofuran solution of the intermediate A into a dimethylamine aqueous solution, dissolving in tetrahydrofuran, adding lithium aluminum hydride, dropwise adding water and a sodium hydroxide solution, adding excessive anhydrous magnesium sulfate, stirring, filtering to obtain an intermediate C, adding octyl dimethyl tertiary amine, alpha, omega-dibromoalkane and anhydrous ethanol into the three-neck flask, obtaining an intermediate D, and adding the intermediate C, the intermediate D and acetone into the three-neck flask to obtain the surfactant.
The purpose of the invention can be realized by the following technical scheme:
a fishhook processing technology for improving the surface glossiness of fishhooks comprises the following steps:
s1: pretreating the fishhook to be treated;
s2: polishing and sand blasting are carried out on the fishhook;
s3: brushing anticorrosive paint on the polished fishhook, placing the fishhook under the ventilation condition of room temperature for 1 to 2 hours, and then placing the fishhook in an oven at the temperature of between 80 and 90 ℃ for baking for 6 to 8 hours;
s4: the colored paint is plated on the fishhook in an electrophoresis mode, and the colored paint can be uniformly deposited on the fishhook in the electrophoresis mode, so that the color of the fishhook is more gorgeous, and the fishhook is obtained;
the anticorrosive paint is prepared by the following preparation steps:
s11: uniformly mixing a phosphate adhesive, titanium dioxide, a crosslinking accelerator, an acidic inhibitor and distilled water to obtain a film-forming base material;
s12: ultrasonically dispersing magnesium oxide powder into a mixed solution of ethanol, deionized water and ammonia water, placing the mixture on a magnetic stirrer for rapid stirring after dispersion is finished, simultaneously dropwise adding tetraethoxysilane into the mixture, controlling the dropwise adding speed to be about 2-3 s/drop, continuously stirring for 2-3h after dropwise adding is finished, aging for 1-2h, filtering, washing and drying to obtain magnesium oxide powder coated by nano silicon dioxide particles;
s13: uniformly mixing magnesium oxide powder coated by nano silicon dioxide particles, barium sulfate, a polymerization inhibitor, a surfactant and distilled water to obtain a curing component;
s14: and mixing the film-forming base material and the curing component, and stirring for 10-30min to obtain the anticorrosive coating.
As a further scheme of the invention: in the step S11, the dosage ratio of the phosphate adhesive to the titanium dioxide to the crosslinking accelerator to the acidic inhibitor to the distilled water is 60-80g:20-40g:0.8-1g:1.2-1.5g:20-25g.
As a further scheme of the invention: in the step S12, the dosage ratio of the magnesium oxide powder, the ethanol, the deionized water, the ammonia water and the ethyl orthosilicate is 3g:81g:51g:9g:36g.
As a further scheme of the invention: in the step S13, the dosage ratio of the magnesium oxide powder coated by the nano silicon dioxide particles, barium sulfate, polymerization inhibitor, surfactant and distilled water is 8-12g:12-14g:0.2-0.5g:0.2-0.5g:20-30g, wherein the dosage ratio of the film-forming base material to the curing component in the step S14 is 20-30g:1g.
As a further scheme of the invention: the preparation process of the surfactant in step S13 is as follows:
s51: adding dehydroabietic acid into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, adding dichloromethane for dissolution, dropwise adding thionyl chloride at room temperature, controlling the dropwise adding speed to be about 1-2 s/drop, reacting at the reflux temperature for 4-5h, and then decompressing and evaporating the solvent to obtain an intermediate A;
the chemical reaction formula is as follows:
s52: dissolving the intermediate A in tetrahydrofuran, dropwise adding the tetrahydrofuran solution of the intermediate A into a dimethylamine aqueous solution at 0-5 ℃, controlling the dropwise adding speed to be about 1-2 s/drop, reacting for 3-5h, and filtering after the reaction is finished to obtain an intermediate B;
the chemical reaction formula is as follows:
s53: dissolving the intermediate B in tetrahydrofuran, stirring and adding lithium aluminum hydride at 0-2 ℃, heating to 70-75 ℃, reacting for 6-8h, after the reaction is finished, continuously dropwise adding water and sodium hydroxide solution at 0-5 ℃, controlling the dropwise adding speed to be about 1-2 s/drop, reacting for 0.5-1h, adding excessive anhydrous magnesium sulfate, stirring for 0.5-1h, and filtering to obtain an intermediate C;
the chemical reaction formula is as follows:
s54: adding octyl dimethyl tertiary amine, alpha, omega-dibromoalkane and absolute ethyl alcohol into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the mixture is completely dissolved, reacting for 72-80h at 50-60 ℃, then reacting for 48-50h at 80-90 ℃, decompressing and evaporating the solvent after the reaction is finished, washing for 4-5 times by using petroleum acid, and drying to obtain an intermediate D;
the chemical reaction formula is as follows:
s55: adding the intermediate C, the intermediate D and acetone into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the intermediates are completely dissolved, reacting for 72-80h at the reflux temperature, and after the reaction is finished, decompressing and distilling out the solvent to obtain the surfactant.
The chemical reaction formula is as follows:
as a further scheme of the invention: in step S51, the molar ratio of dehydroabietic acid to thionyl chloride is 1:1, the dosage ratio of the intermediate A to the tetrahydrofuran in the step S52 is 5.6g:50mL, the mass fraction of the dimethylamine aqueous solution is 40%, and the dosage ratio of the intermediate A to the dimethylamine aqueous solution is 5.6g:7.4g.
As a further scheme of the invention: the dosage ratio of the intermediate B to the tetrahydrofuran in the step S53 is 10.5g:100mL, wherein the molar ratio of the intermediate B to the lithium aluminum hydride is 1:2, the dosage ratio of the lithium aluminum hydride to the water to the sodium hydroxide solution is 1g:1g:1g, wherein the mass fraction of the sodium hydroxide solution is 15%.
As a further scheme of the invention: in the step S54, the dosage ratio of the octyl dimethyl tertiary amine, the alpha, omega-dibromoalkane to the absolute ethyl alcohol is 5.4g:6.0g:100mL.
As a further scheme of the invention: in the step S55, the dosage ratio of the intermediate C to the intermediate D to the acetone is 10.4g:9.6g:100mL.
The invention has the following beneficial effects:
(1) The fishhook is obtained by pretreating the fishhook to be treated, polishing and sandblasting the fishhook, painting anticorrosive paint on the polished fishhook and plating colored paint on the fishhook in an electrophoresis mode, and the phosphate inorganic anticorrosive paint has the advantages of good adhesive force, high temperature resistance, no toxicity, no pollution, low price, safety and the like;
(2) Uniformly mixing a phosphate adhesive, titanium dioxide, a crosslinking accelerator, an acidic inhibitor and distilled water to obtain a film-forming base material, ultrasonically dispersing magnesium oxide powder into a mixed solution of ethanol, deionized water and ammonia water, simultaneously dropwise adding tetraethoxysilane into the mixed solution, uniformly mixing magnesium oxide powder coated by nano silicon dioxide particles, barium sulfate, a polymerization inhibitor, a surfactant and distilled water to obtain a curing component, mixing the film-forming base material and the curing component, and stirring to obtain the anticorrosive coating, wherein 90% of the anticorrosive coating belongs to an organic coating, most of toxic raw materials contained in the organic coating can be dissipated into the surrounding environment in the production and application processes, certain harm can be caused to a human body and the environment, the phosphate inorganic anticorrosive coating has the advantages of good adhesive force, high-temperature resistance, no toxicity, no pollution, low price, safety and the like, the nano particle surface coating technology is innovatively applied to the phosphate inorganic anticorrosive coating, and the Mg0 curing agent is subjected to surface modification by adopting the nano particle surface coating technology, so that the delayed release of Mg0 in the coating curing process is realized, and the anticorrosive coating is mixed with the phosphate adhesive to obtain the anticorrosive coating, so that the anticorrosive coating can be cured at normal temperature, and the comprehensive high-temperature resistance, water, the high-temperature-resistant and the anticorrosive coating can be independently cured;
(3) Adding dehydroabietic acid into a three-neck flask, adding dichloromethane for dissolution, dropwise adding thionyl chloride at room temperature to obtain an intermediate A, dissolving the intermediate A in tetrahydrofuran, dropwise adding a tetrahydrofuran solution of the intermediate A into a dimethylamine aqueous solution, dissolving in tetrahydrofuran, adding lithium aluminum hydride, dropwise adding water and a sodium hydroxide solution, adding excessive anhydrous magnesium sulfate, stirring, filtering to obtain an intermediate C, adding octyl dimethyl tertiary amine, alpha, omega-dibromoalkane and anhydrous ethanol into the three-neck flask to obtain an intermediate D, adding the intermediate C, the intermediate D and acetone into the three-neck flask to obtain the surfactant, wherein dehydroabietic acid belongs to terpene compounds, and rosin groups serve as hydrophobic groups to enhance the emulsifying capacity of the compounds in a system according to the principle of 'similar intermiscibility', so that an anticorrosive coating is attached to the surface of a fishhook through the interaction of the hydrophobic groups and hydrophilic groups, and the permeability of bacteria can be changed by the adsorption of nitrogen positive ions on the surface of the bacteria, and the hydrophobic groups enter into a cell lipid layer of bacteria cell walls to inactivate enzymes and proteins in cells, thereby having bacteriostatic action.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the embodiment relates to a fishhook processing technology for improving the surface glossiness of a fishhook, which comprises the following steps:
s1: pretreating the fishhook to be treated;
s2: polishing and sand blasting are carried out on the fishhook;
s3: brushing anticorrosive paint on the polished fishhook, placing the fishhook in a ventilation condition at room temperature for 1h, and then placing the fishhook in an oven at 90 ℃ for baking for 6h;
s4: the colored paint is plated on the fishhook in an electrophoresis mode, and the colored paint can be uniformly deposited on the fishhook in the electrophoresis mode, so that the color of the fishhook is more gorgeous, and the fishhook is obtained;
the anticorrosive paint is prepared by the following preparation steps:
s11: uniformly mixing 60g of phosphate adhesive, 20g of titanium dioxide, 0.8g of crosslinking accelerator, 1.2g of acid inhibitor and 20g of distilled water to obtain a film-forming base material;
s12: ultrasonically dispersing 3g of magnesium oxide powder in a mixed solution of 81g of ethanol, 51g of deionized water and 9g of ammonia water, placing the mixture on a magnetic stirrer for rapid stirring after the dispersion is finished, simultaneously dropwise adding 36g of tetraethoxysilane to the mixture, controlling the dropwise adding speed to be about 2 s/drop, continuously stirring the mixture for 2 hours after the dropwise adding is finished, aging the mixture for 1 hour, filtering, washing and drying the mixture to obtain magnesium oxide powder coated by nano silicon dioxide particles;
s13: uniformly mixing 8g of magnesium oxide powder coated by nano silicon dioxide particles, 12g of barium sulfate, 0.2g of polymerization inhibitor, 0.2g of surfactant and 20g of distilled water to obtain a curing component;
s14: mixing 20g of film-forming base material and 1g of curing component, and stirring for 10min to obtain the anticorrosive coating;
the preparation process of the surfactant is as follows:
s51: adding dehydroabietic acid into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, adding dichloromethane for dissolution, dropwise adding thionyl chloride at room temperature, controlling the dropwise adding speed to be about 1 s/drop, reacting at the reflux temperature for 4 hours, and then decompressing and evaporating the solvent to obtain an intermediate A;
s52: dissolving 5.6g of the intermediate A in 50mL of tetrahydrofuran, dropwise adding the tetrahydrofuran solution of the intermediate A into 7.4g of dimethylamine aqueous solution at 0 ℃, controlling the dropwise adding speed to be about 1 s/drop, reacting for 3 hours, and filtering after the reaction is finished to obtain an intermediate B;
s53: dissolving the intermediate B in 100mL tetrahydrofuran, adding lithium aluminum hydride under stirring at 0 ℃, heating to 70 ℃, reacting for 6 hours, after the reaction is finished, continuously dropwise adding water and a sodium hydroxide solution at 0 ℃, controlling the dropwise adding speed to be about 1 s/drop, reacting for 0.5 hours, adding excessive anhydrous magnesium sulfate, stirring for 0.5 hours, and filtering to obtain an intermediate C;
s54: adding 5.4g of octyl dimethyl tertiary amine, 6.0g of alpha, omega-dibromoalkane and 100mL of absolute ethyl alcohol into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the octyl dimethyl tertiary amine, the alpha, omega-dibromoalkane and the absolute ethyl alcohol are completely dissolved, reacting for 72 hours at 50 ℃, then reacting for 48 hours at 80 ℃, decompressing and evaporating the solvent after the reaction is finished, washing for 4 times by using petroleum, and drying to obtain an intermediate D;
s55: and (3) adding 10.4g of the intermediate C, 9.6g of the intermediate D and 100mL of acetone into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the intermediate C, the intermediate D and the acetone are completely dissolved, reacting for 72 hours at a reflux temperature, and after the reaction is finished, evaporating the solvent under reduced pressure to obtain the surfactant.
Example 2:
the embodiment is a fishhook processing technology for improving the surface glossiness of a fishhook, and the fishhook processing technology comprises the following steps:
s1: pretreating the fishhook to be treated;
s2: polishing and sand blasting are carried out on the fishhook;
s3: brushing anticorrosive paint on the polished fishhook, placing the fishhook under the ventilation condition of room temperature for 1 hour, and then placing the fishhook in a 90 ℃ oven for baking for 8 hours;
s4: the colored paint is plated on the fishhook in an electrophoresis mode, and the colored paint can be uniformly deposited on the fishhook in the electrophoresis mode, so that the color of the fishhook is more gorgeous, and the fishhook is obtained;
the anticorrosive paint is prepared by the following preparation steps:
s11: uniformly mixing 60g of phosphate adhesive, 20g of titanium dioxide, 0.8g of crosslinking accelerator, 1.5g of acid inhibitor and 25g of distilled water to obtain a film-forming base material;
s12: taking 3g of magnesium oxide powder, ultrasonically dispersing the magnesium oxide powder in a mixed solution of 81g of ethanol, 51g of deionized water and 9g of ammonia water, placing the mixture on a magnetic stirrer for rapid stirring after the dispersion is finished, simultaneously dropwise adding 36g of tetraethoxysilane into the mixture, controlling the dropwise adding speed to be about 3 s/drop, continuously stirring the mixture for 3 hours after the dropwise adding is finished, aging the mixture for 2 hours, filtering, washing and drying the mixture to obtain magnesium oxide powder coated with nano silicon dioxide particles;
s13: uniformly mixing 12g of magnesium oxide powder coated by nano silicon dioxide particles, 14g of barium sulfate, 0.5g of polymerization inhibitor, 0.5g of surfactant and 30g of distilled water to obtain a curing component;
s14: mixing 30g of film-forming base material and 1g of curing component, and stirring for 10min to obtain the anticorrosive coating;
the preparation process of the surfactant is as follows:
s51: adding dehydroabietic acid into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, adding dichloromethane for dissolution, dropwise adding thionyl chloride at room temperature, controlling the dropwise adding speed to be about 1 s/drop, reacting at the reflux temperature for 4 hours, and then decompressing and evaporating the solvent to obtain an intermediate A;
s52: dissolving 5.6g of the intermediate A in 50mL of tetrahydrofuran, dropwise adding the tetrahydrofuran solution of the intermediate A into 7.4g of dimethylamine aqueous solution at 0 ℃, controlling the dropwise adding speed to be about 1 s/drop, reacting for 3 hours, and filtering after the reaction is finished to obtain an intermediate B;
s53: dissolving the intermediate B in 100mL tetrahydrofuran, adding lithium aluminum hydride with stirring at 0 ℃, heating to 70 ℃, reacting for 6 hours, after the reaction is finished, continuously dropwise adding water and sodium hydroxide solution at 0 ℃, controlling the dropwise adding speed to be about 1 s/drop, reacting for 0.5 hour, adding excessive anhydrous magnesium sulfate, stirring for 0.5 hour, and filtering to obtain an intermediate C;
s54: adding 5.4g of octyl dimethyl tertiary amine, 6.0g of alpha, omega-dibromoalkane and 100mL of absolute ethyl alcohol into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the mixture is completely dissolved, reacting for 80h at 60 ℃, then reacting for 50h at 90 ℃, decompressing and evaporating out the solvent after the reaction is finished, washing for 5 times by using petroleum acid, and drying to obtain an intermediate D;
s55: and (3) adding 10.4g of the intermediate C, 9.6g of the intermediate D and 100mL of acetone into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the intermediate C, the intermediate D and the acetone are completely dissolved, reacting for 80 hours at a reflux temperature, and after the reaction is finished, evaporating the solvent under reduced pressure to obtain the surfactant.
Example 3:
the embodiment relates to a fishhook processing technology for improving the surface glossiness of a fishhook, which comprises the following steps:
s1: pretreating the fishhook to be treated;
s2: polishing and sand blasting are carried out on the fishhook;
s3: brushing anticorrosive paint on the polished fishhook, placing the fishhook under the ventilation condition of room temperature for 2 hours, and then placing the fishhook in an oven at 90 ℃ for baking for 8 hours;
s4: the colored paint is plated on the fishhook in an electrophoresis mode, and the colored paint can be uniformly deposited on the fishhook in the electrophoresis mode, so that the color of the fishhook is more gorgeous, and the fishhook is obtained;
the anticorrosive paint is prepared by the following preparation steps:
s11: uniformly mixing 80g of phosphate adhesive, 40g of titanium dioxide, 1g of crosslinking accelerator, 1.5g of acid inhibitor and 25g of distilled water to obtain a film-forming base material;
s12: ultrasonically dispersing 3g of magnesium oxide powder in a mixed solution of 81g of ethanol, 51g of deionized water and 9g of ammonia water, placing the mixture on a magnetic stirrer for rapid stirring after the dispersion is finished, simultaneously dropwise adding 36g of tetraethoxysilane to the mixture, controlling the dropwise adding speed to be about 3 s/drop, continuously stirring the mixture for 3 hours after the dropwise adding is finished, aging the mixture for 2 hours, filtering, washing and drying the mixture to obtain magnesium oxide powder coated by nano silicon dioxide particles;
s13: uniformly mixing 12g of magnesium oxide powder coated by nano silicon dioxide particles, 14g of barium sulfate, 0.5g of polymerization inhibitor, 0.5g of surfactant and 30g of distilled water to obtain a curing component;
s14: mixing 30g of film-forming base material and 1g of curing component, and stirring for 30min to obtain the anticorrosive coating;
the preparation process of the surfactant is as follows:
s51: adding dehydroabietic acid into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, adding dichloromethane for dissolution, dropwise adding thionyl chloride at room temperature, controlling the dropwise adding speed to be about 2 s/drop, reacting at the reflux temperature for 5 hours, and then decompressing and evaporating the solvent to obtain an intermediate A;
s52: dissolving 5.6g of the intermediate A in 50mL of tetrahydrofuran, dropwise adding the tetrahydrofuran solution of the intermediate A into 7.4g of dimethylamine aqueous solution at 5 ℃, controlling the dropwise adding speed to be about 2 s/drop, reacting for 5 hours, and filtering after the reaction is finished to obtain an intermediate B;
s53: dissolving the intermediate B in 100mL tetrahydrofuran, stirring at 2 ℃ and adding lithium aluminum hydride, heating to 75 ℃, reacting for 8 hours, after the reaction is finished, continuously dropwise adding water and sodium hydroxide solution at 5 ℃, controlling the dropwise adding speed to be about 2 s/drop, reacting for 1 hour, adding excessive anhydrous magnesium sulfate, stirring for 1 hour, and filtering to obtain an intermediate C;
s54: adding 5.4g of octyl dimethyl tertiary amine, 6.0g of alpha, omega-dibromoalkane and 100mL of absolute ethyl alcohol into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the mixture is completely dissolved, reacting for 80h at 60 ℃, then reacting for 50h at 90 ℃, decompressing and evaporating out the solvent after the reaction is finished, washing for 5 times by using petroleum acid, and drying to obtain an intermediate D;
s55: and (3) adding 10.4g of the intermediate C, 9.6g of the intermediate D and 100mL of acetone into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube, stirring until the intermediate C, the intermediate D and the acetone are completely dissolved, reacting for 80 hours at a reflux temperature, and after the reaction is finished, evaporating the solvent under reduced pressure to obtain the surfactant.
Comparative example 1:
comparative example 1 differs from example 1 in that no anticorrosive coating is added.
Comparative example 2:
comparative example 2 a commercially available anticorrosive coating was used.
Performance test
The fishhooks of examples 1-3 and comparative examples 1-2 were tested;
the results are shown in the following table:
as can be seen from the above table, the corrosion resistance of the embodiment is better, while the roughness of the surface of the comparative example 1 without adding the anticorrosive paint is larger, which indicates that the surface of the fishhook is corroded, while the corrosion resistance of the commercially available anticorrosive paint is low due to the fact that the part of the paint protrudes or falls off after the acid-base corrosion test, the anticorrosive paint used in the invention has excellent corrosion resistance, can meet the use requirements of fishermen, and the surface color of the fishhook cannot be reduced after the fishhook is soaked for a long time.
In the description herein, references to the description of "one embodiment," "an example," "a specific example," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only and is not intended to be exhaustive or to limit the invention to the precise embodiments described, and various modifications, additions, and substitutions may be made by those skilled in the art without departing from the scope of the invention or exceeding the scope of the claims.
Claims (9)
1. A fishhook processing technology for improving the surface glossiness of fishhooks is characterized by comprising the following steps:
s1: pretreating the fishhook to be treated;
s2: polishing and sand blasting are carried out on the fishhook;
s3: brushing anticorrosive paint on the polished fishhook;
s4: plating the color paint on the fishhook in an electrophoresis mode to obtain the fishhook;
the anticorrosive paint is prepared by the following preparation steps:
s11: uniformly mixing a phosphate adhesive, titanium dioxide, a crosslinking accelerator, an acidic inhibitor and distilled water to obtain a film-forming base material;
s12: ultrasonically dispersing magnesium oxide powder in a mixed solution of ethanol, deionized water and ammonia water, placing the mixture on a magnetic stirrer for rapid stirring after the dispersion is finished, and simultaneously dropwise adding tetraethoxysilane to the mixture to obtain magnesium oxide powder coated by nano silicon dioxide particles;
s13: uniformly mixing magnesium oxide powder coated by nano silicon dioxide particles, barium sulfate, a polymerization inhibitor, a surfactant and distilled water to obtain a curing component;
s14: and mixing and stirring the film-forming base material and the curing component to obtain the anticorrosive paint.
2. The fishhook processing technology for improving the surface gloss of fishhooks according to claim 1, wherein the amount ratio of the phosphate adhesive, the titanium dioxide, the crosslinking accelerator, the acidity inhibitor and the distilled water in step S11 is 60-80g:20-40g:0.8-1g:1.2-1.5g:20-25g.
3. The fishhook processing technology for improving the glossiness of the surface of the fishhook as claimed in claim 1, wherein the ratio of the magnesium oxide powder, the ethanol, the deionized water, the ammonia water and the tetraethoxysilane used in the step S12 is 3g:81g:51g:9g:36g.
4. The fishhook processing technology for improving the surface glossiness of fishhooks according to claim 1, wherein in the step S13, the usage ratio of the nano-silica particle-coated magnesium oxide powder, barium sulfate, polymerization inhibitor, surfactant to distilled water is 8-12g:12-14g:0.2-0.5g:0.2-0.5g:20-30g, wherein the dosage ratio of the film-forming binder to the curing component in the step S14 is 20-30g:1g.
5. The fishhook processing method for improving the glossiness of the surface of the fishhook according to claim 1, wherein the surfactant in step S13 is prepared by the following steps:
s51: adding dehydroabietic acid into a three-neck flask provided with a thermometer, a drying pipe and a condensing reflux pipe, adding dichloromethane for dissolving, and dropwise adding thionyl chloride at room temperature to obtain an intermediate A;
s52: dissolving the intermediate A in tetrahydrofuran, and dropwise adding the tetrahydrofuran solution of the intermediate A into a dimethylamine aqueous solution to obtain an intermediate B;
s53: dissolving the intermediate B in tetrahydrofuran, adding lithium aluminum hydride, dropwise adding water and sodium hydroxide solution, adding excessive anhydrous magnesium sulfate, stirring, and filtering to obtain an intermediate C;
s54: adding octyl dimethyl tertiary amine, alpha, omega-dibromoalkane and absolute ethyl alcohol into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube to obtain an intermediate D;
s55: and adding the intermediate C, the intermediate D and acetone into a three-neck flask provided with a thermometer, a drying tube and a condensing reflux tube to obtain the surfactant.
6. The fishhook processing method for improving the surface gloss of fishhooks of claim 5, wherein the mole ratio of dehydroabietic acid to thionyl chloride in step S51 is 1:1, the dosage ratio of the intermediate A to the tetrahydrofuran in the step S52 is 5.6g:50mL, wherein the mass fraction of the dimethylamine aqueous solution is 40%, and the dosage ratio of the intermediate A to the dimethylamine aqueous solution is 5.6g:7.4g.
7. The fishhook processing technology of claim 5, wherein the ratio of the intermediate B to tetrahydrofuran in step S53 is 10.5g:100mL, and the molar ratio of the intermediate B to the lithium aluminum hydride is 1:2, the dosage ratio of the lithium aluminum hydride to the water to the sodium hydroxide solution is 1g:1g:1g, wherein the mass fraction of the sodium hydroxide solution is 15%.
8. The fishhook processing technology of claim 5, wherein the ratio of the amount of the octyl dimethyl tertiary amine, the α, ω -dibromoalkane to the absolute ethyl alcohol in step S54 is 5.4g:6.0g:100mL.
9. The fishhook processing method for improving the surface gloss of fishhooks of claim 5, wherein the ratio of the intermediate C to the intermediate D to the acetone in step S55 is 10.4g:9.6g:100mL.
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| CN104341808A (en) * | 2014-11-05 | 2015-02-11 | 海南大学 | Room-temperature self-curing inorganic phosphate anti-corrosion paint as well as preparing method and use method of paint |
| CN104645876A (en) * | 2014-10-28 | 2015-05-27 | 齐齐哈尔大学 | Ternary surface active agent adopting 1,1,1-tri(hydroxymethyl) ethane as link group, and preparation method of ternary surface active agent |
| CN112962124A (en) * | 2021-02-07 | 2021-06-15 | 赵亚飞 | Fishhook production process for improving surface brightness of fishhook |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104645876A (en) * | 2014-10-28 | 2015-05-27 | 齐齐哈尔大学 | Ternary surface active agent adopting 1,1,1-tri(hydroxymethyl) ethane as link group, and preparation method of ternary surface active agent |
| CN104341808A (en) * | 2014-11-05 | 2015-02-11 | 海南大学 | Room-temperature self-curing inorganic phosphate anti-corrosion paint as well as preparing method and use method of paint |
| CN112962124A (en) * | 2021-02-07 | 2021-06-15 | 赵亚飞 | Fishhook production process for improving surface brightness of fishhook |
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