CN115521082A - Method for promoting light calcium digestion process by improving digestion temperature through photo-thermal technology - Google Patents

Method for promoting light calcium digestion process by improving digestion temperature through photo-thermal technology Download PDF

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Publication number
CN115521082A
CN115521082A CN202211243640.6A CN202211243640A CN115521082A CN 115521082 A CN115521082 A CN 115521082A CN 202211243640 A CN202211243640 A CN 202211243640A CN 115521082 A CN115521082 A CN 115521082A
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China
Prior art keywords
tube
digestion
temperature
vacuum
heat
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CN202211243640.6A
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Chinese (zh)
Inventor
刘佳宇
唐振中
朱启帅
黄海智
林永权
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China Resources Cement Technology R&D Co Ltd
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China Resources Cement Technology R&D Co Ltd
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Priority to CN202211243640.6A priority Critical patent/CN115521082A/en
Publication of CN115521082A publication Critical patent/CN115521082A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00Lime, magnesia or dolomite
    • C04B2/02Lime
    • C04B2/04Slaking
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00Lime, magnesia or dolomite
    • C04B2/02Lime
    • C04B2/04Slaking
    • C04B2/08Devices therefor

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention provides a method for improving digestion temperature and promoting a light calcium digestion process by utilizing a photo-thermal technology, belonging to the technical field of photo-thermal utilization. The slaking water has higher temperature, the physical form tends to gaseous state, the slaking effect is better when contacting with the lime, the internal temperature of the adopted heat preservation device is more stable, and the slaked pulp after slaking can not cause quality change due to temperature change. Meanwhile, the heat loss caused by the temperature difference between the inside and the outside of the digestion kiln is reduced.

Description

Method for promoting light calcium digestion process by improving digestion temperature through photo-thermal technology
Technical Field
The invention relates to the technical field of photo-thermal utilization, in particular to a method for improving digestion temperature and promoting a light calcium digestion process by utilizing a photo-thermal technology.
Background
The calcium carbonate has wide source and large demand, is used in various fields such as coating, papermaking, rubber, plastics and the like, and can be called as industrial monosodium glutamate. It can be divided into two categories of heavy calcium carbonate and light calcium carbonate according to the preparation method. The light calcium carbonate is prepared by chemical processing method, which comprises burning limestone to obtain lime (main component is calcium oxide) and carbon dioxide, adding water to digest lime to obtain lime milk (main component is calcium hydroxide), introducing carbon dioxide to carbonize lime milk to obtain calcium carbonate precipitate, dewatering, drying and pulverizing.
The reaction of the lime obtained after calcination with water is called a slaking process, the lime calcined in the existing vertical kiln enters a vibrating screening conveyor to remove coal slag, small-particle lime and lime dust, the lime is crushed to 10-30mm by a crusher, the crushed lime is conveyed to a lime storage bin by a bucket elevator, lime in the storage bin is conveyed into the slaking kiln from the front end by a feeder at a certain speed, and hot water at 55-65 ℃ and the lime are mixed according to the ratio of 1:4.8, the lime and the water are fed into the slaking kiln from the front end, and move towards the rear part along with the slaking screw and the shoveling plate when slaking reaction is carried out in the slaking kiln, and after the slaked slurry (lime milk) is sieved at the rear part, the slaked slurry flows out of the slaking kiln, and the temperature is about 90 ℃.
In the prior art, the temperature of water for digestion is 55-65 ℃, moreover, the outer skin of the digestion kiln is made of metal, the heat conductivity is good, when the temperature difference between the inside and the outside of the digestion kiln is overlarge, the heat in the digestion kiln is lost, the digestion reaction temperature is reduced, and the digestion reaction speed is reduced.
Disclosure of Invention
The invention aims to provide a method for improving digestion temperature and promoting light calcium digestion process by using photo-thermal technology, and solves the technical problems of low reaction speed and excessive flow loss in the existing calcium digestion process.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a method for promoting the digestion process of light calcium by using photo-thermal technology to increase the digestion temperature includes such steps as setting the digestion kiln as solar vacuum heat-collecting tube, and introducing lime and water for digestion into the solar vacuum heat-collecting tube at 100-400 deg.C.
Furthermore, the solar vacuum heat collecting tube device comprises a heat absorbing tube and a vacuum glass tube, wherein the vacuum glass tube is arranged on the outer side of the heat absorbing tube, a vacuum structure is arranged between the heat absorbing tube and the vacuum glass tube, and the outer side surface of the heat absorbing tube is coated with a selective absorbing coating to inhibit the heat loss of air conduction and convection in the vacuum tube.
Furthermore, the selective absorption coating comprises an infrared reflection bottom layer and a solar spectrum absorption layer, the infrared reflection bottom layer is arranged at the bottom of the solar spectrum absorption layer, the infrared reflection bottom layer is made of infrared reflection metal, and the solar spectrum absorption layer is made of metal compounds or metal composite materials.
Furthermore, the vacuum glass tube is arranged into a double-layer vacuum glass sleeve, and the inner wall of the double-layer vacuum glass sleeve is coated with a reflecting film for condensing light.
Furthermore, the end parts of the heat absorption tube and the vacuum glass tube are provided with sealing devices, and the sealing devices are metal corrugated tubes and are used for compensating expansion and contraction of the heat absorption tube.
Furthermore, an inner sleeve is arranged at the front end of the solar vacuum heat collecting pipe device, lime and digestion water simultaneously enter, digested lime cream flows out from a jacket arranged between the inner sleeve at the front end and a heat absorbing pipe of the solar vacuum heat collecting pipe device, a rotary screen for screening ash and slag rotating along with the heat absorbing pipe is arranged at the rear end of the solar vacuum heat collecting pipe device, the ash and slag move to the rear part of the heat absorbing pipe under the propelling action of the rotation of the heat absorbing pipe, the ash and slag enter the rotary screen and are washed by water, and finally the ash and slag are discharged from the rear end.
The solar vacuum heat collecting tube device is characterized in that a heat collecting tube and a glass tube are manufactured, the heat collecting tube needs to be subjected to high-temperature steam corrosion for a long time, high-temperature resistant steel materials are selected and used, the thickness of the heat collecting tube is more than 16mm, the glass tube is made of borosilicate glass, a selective absorption film is coated on the surface of the steel tube in a co-sputtering mode through a plurality of targets, the sunlight absorptivity is larger than 95%, the black body emissivity is smaller than or equal to 5%, an antireflection film is coated on the surface of the glass tube, the light transmittance is increased to 97% from 89%, a metal corrugated tube is welded with the steel tube, the glass tube is connected with the corrugated tube, gas between the steel tube and the glass tube is pumped away, the vacuum requirement is met, sealing treatment is carried out at an exhaust port, and annealing is carried out on the glass tube.
Due to the adoption of the technical scheme, the invention has the following beneficial effects:
the slaking water has higher temperature, the physical form tends to gaseous state, the slaking effect is better when contacting with the lime, the internal temperature of the adopted heat preservation device is more stable, and the slaked pulp after slaking can not cause quality change due to temperature change. Meanwhile, the heat loss caused by the temperature difference between the inside and the outside of the digestion kiln is reduced.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail below with reference to preferred embodiments. However, it should be noted that the numerous details set forth in the description are merely intended to provide a thorough understanding of one or more aspects of the present invention, even though such aspects of the invention may be practiced without these specific details.
A method for improving the digestion temperature and promoting the digestion process of light calcium carbonate by utilizing a photo-thermal technology converts solar energy into heat energy to heat water for digestion, and simultaneously carries out heat preservation treatment on the outer wall of a digestion kiln to reduce heat loss, thereby achieving the aims of efficiently utilizing energy and improving the digestion rate of lime and water.
According to the principle of solar vacuum heat collecting tubes, a digestion kiln is designed into a large-scale solar vacuum heat collecting tube which mainly comprises a heat absorbing tube and a vacuum glass tube. The heat absorbing body and the vacuum tube are made of metal materials, and can operate at high temperature and under pressure, the operating temperature is 100-400 ℃, and the temperature required by water vapor digestion can be met. The surface of the heat absorbing pipe is coated with a selective absorbing coating, and the inner wall of the glass tube is coated with a light-gathering material coating.
Firstly, arranging a part of water in a slaking kiln, which is in contact with lime for slaking, as a metal heat absorption pipe, and communicating one end of the metal heat absorption pipe to form a fluid flow channel;
then, coating a selective absorption coating on the surface of the metal heat absorption pipe, wherein the selective absorption coating is basically divided into two parts, namely an infrared reflection bottom layer (high-infrared-reflectance metal such as copper, aluminum and the like) and a solar spectrum absorption layer (metal compound or metal composite material);
then, a double-layer vacuum glass sleeve is sleeved below the metal heat conduction pipe, and a reflecting film is coated on the inner wall of the glass tube below the heat absorption tube for light condensation.
The invention has the characteristic of one-way heat transfer technically, and both ends between the metal heat absorption tube and the glass tube need to be sealed, so that the heat absorption tube needs to be in transition by means of the corrugated tube in order to compensate for the expansion caused by heat and contraction caused by cold. Therefore, the integral heat preservation performance is excellent.
The light calcium slaking kiln is designed into a large-scale metal vacuum heat collecting pipe. In order to meet the working environment of the digestion process, the vacuum heat collecting tube mainly comprises an inner metal heat absorbing body and an outer layer of glass tube. The surface of the heat absorber is deposited with a spectrally selective absorbing coating by various means. Because the interlayer between the heat absorber and the glass tube keeps high vacuum degree, the heat loss of conduction and convection of air in the vacuum tube can be effectively inhibited; since the selective absorption coating has low infrared emissivity, the radiation heat loss of the heat absorbing plate can be obviously reduced. The solar water heater can utilize solar energy to the maximum extent in the digestion kiln, heat the water for digestion and improve the digestion efficiency.
The device production process mainly comprises the following steps:
1. manufacturing steel pipes and glass pipes and performing cleaning pretreatment; the heat collecting tube for the digestion kiln is required to be subjected to high-temperature steam corrosion for a long time, high-temperature resistant steel materials are required to be selected and used, the thickness of the heat collecting tube is more than 16mm, and the glass tube is made of borosilicate glass;
2. the surface of the steel pipe is coated with a selective absorption film by adopting multi-target co-sputtering, so that the sunlight absorption rate is more than 95 percent, and the black body emissivity is less than or equal to 5 percent;
3. coating an antireflection film on the surface of the glass tube to increase the light transmittance from 89% to 97%;
4. welding a metal corrugated pipe and a steel pipe, and then connecting a glass pipe and the corrugated pipe;
5. pumping the gas between the steel tube and the glass tube to meet the vacuum requirement, and sealing at the exhaust port;
6. the glass tube is annealed.
The front end of the slaking kiln is provided with an inner sleeve, lime and slaking water simultaneously enter, and slaked lime milk flows out from a jacket between the inner sleeve at the front end and the cylinder body. The rotary screen for screening ash and slag is installed at the back of the digesting kiln, and under the propelling action of the rotation of the drum, the ash and slag move to the back of the drum, and the ash and slag are washed with water after entering the rotary screen and finally discharged from the back end.
Both the temperature of the lime and the temperature of the water used for slaking affect the rate of slaking of the lime. It is known that the lime digestion reaction is strongly exothermic and that 1kg of pure calcium oxide will digest it with sufficient heat to heat 2.8kg of water from 0 c to 100 c, so that too high a temperature will inhibit the reaction. However, from the viewpoint of dynamics, the higher the temperature, the larger the reaction rate constant and the higher the reaction rate. From the water vapor equilibrium pressure at different temperatures during calcium oxide digestion, it can be known that the digestion reaction temperature is in the range from normal temperature to 300 ℃, and the higher the temperature is, the faster the reaction speed is.
The temperature of the water for digestion is higher, the physical form is more gaseous, and the digestion effect is better when the lime is contacted with the water for digestion compared with the prior art (the hot water for digestion from a kiln gas cooling and purifying section with the temperature of 55-65 ℃). The heat preservation device who adopts, the metal outer wall of contrast prior art makes the inside temperature of digestion kiln more stable, and the ripe thick liquid (calcium hydroxide) after the digestion can not cause the quality change because of the temperature change. Meanwhile, the heat loss caused by the temperature difference between the inside and the outside of the digestion kiln is reduced.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that those skilled in the art can make various improvements and modifications without departing from the principle of the present invention, and these improvements and modifications should also be construed as the protection scope of the present invention.

Claims (7)

1. A method for promoting the digestion process of light calcium by improving the digestion temperature by using a photo-thermal technology is characterized in that: the slaking kiln is arranged as a solar vacuum heat collecting tube device, lime and slaking water simultaneously enter the solar vacuum heat collecting tube device, the operation temperature is 100-400 ℃, and the slaking water is in a water vapor state.
2. The method for promoting the digestion process of light calcium by increasing the digestion temperature through the photothermal technology as claimed in claim 1, wherein: the solar vacuum heat collecting tube device comprises a heat absorbing tube and a vacuum glass tube, wherein the vacuum glass tube is arranged on the outer side of the heat absorbing tube, a vacuum structure is arranged between the heat absorbing tube and the vacuum glass tube, and the surface of the outer side of the heat absorbing tube is coated with a selective absorbing coating to inhibit the heat loss of air conduction and convection in the vacuum tube.
3. The method for promoting the digestion process of light calcium by increasing the digestion temperature through the photothermal technology as claimed in claim 2, wherein: the selective absorption coating comprises an infrared reflection bottom layer and a solar spectrum absorption layer, the infrared reflection bottom layer is arranged at the bottom of the solar spectrum absorption layer, the infrared reflection bottom layer is made of infrared reflection metal, and the solar spectrum absorption layer is made of metal compounds or metal composite materials.
4. The method for promoting the digestion process of light calcium by utilizing the photothermal technology to increase the digestion temperature according to the claim 2, wherein: the vacuum glass tube is a double-layer vacuum glass sleeve, and the inner wall of the double-layer vacuum glass sleeve is coated with a reflecting film for condensing light.
5. The method for promoting the digestion process of light calcium by increasing the digestion temperature through the photothermal technology as claimed in claim 2, wherein: the end parts of the heat absorption tube and the vacuum glass tube are provided with sealing devices, and the sealing devices are metal corrugated tubes and are used for compensating expansion and contraction of the heat absorption tube.
6. The method for promoting the digestion process of light calcium by utilizing the photothermal technology to increase the digestion temperature according to the claim 2, wherein: an inner sleeve is arranged at the front end of the solar vacuum heat collecting tube device, lime and digestion water simultaneously enter, digested lime milk flows out from a jacket arranged between the inner sleeve at the front end and a heat absorbing tube of the solar vacuum heat collecting tube device, a rotary screen for screening ash and slag rotating along with the heat absorbing tube is arranged at the rear end of the solar vacuum heat collecting tube device, the ash and slag move to the rear part of the heat absorbing tube under the propelling action of the rotation of the heat absorbing tube, the ash and slag enter the rotary screen and are washed by water, and finally the ash and slag are discharged from the rear end.
7. The method for promoting the digestion process of light calcium by utilizing the photothermal technology to increase the digestion temperature according to the claim 1, wherein: the solar vacuum heat collecting tube device is manufactured by manufacturing a heat collecting tube and a glass tube, wherein the heat collecting tube needs to be subjected to high-temperature steam corrosion for a long time, a high-temperature-resistant steel material with the thickness of more than 16mm is selected as a fixed material, the glass tube is made of borosilicate glass, a selective absorption film is coated on the surface of the steel tube by co-sputtering of a plurality of targets, the sunlight absorption rate is more than 95%, the black body emissivity is less than or equal to 5%, an antireflection film is coated on the surface of the glass tube, the light transmittance is increased from 89% to 97%, a metal corrugated tube is welded with the steel tube, the glass tube is connected with the corrugated tube, gas between the steel tube and the glass tube is pumped away, the vacuum requirement is met, sealing treatment is carried out at an air outlet, and annealing is carried out on the glass tube.
CN202211243640.6A 2022-10-11 2022-10-11 Method for promoting light calcium digestion process by improving digestion temperature through photo-thermal technology Pending CN115521082A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19532807A1 (en) * 1995-08-25 1997-02-27 Knoell Hans Forschung Ev Utilisation of solar radiation for photochemical or photo-biological processes
CN102872785A (en) * 2012-10-20 2013-01-16 南京工业大学 Through type solar heat collection high-temperature reactor
CN103011627A (en) * 2012-11-27 2013-04-03 宜兴天力化工纳米科技有限公司 Lime slaking device
US20130145761A1 (en) * 2011-08-12 2013-06-13 Mcalister Technologies, Llc Systems and methods for providing supplemental aqueous thermal energy
CN106830716A (en) * 2017-02-28 2017-06-13 成都格瑞思文化传播有限公司 A kind of lime slaking chemicals dosing plant
CN109297203A (en) * 2018-11-14 2019-02-01 中国科学技术大学 A kind of high-temperature vacuum heat-collecting tube for slot light collection collecting system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19532807A1 (en) * 1995-08-25 1997-02-27 Knoell Hans Forschung Ev Utilisation of solar radiation for photochemical or photo-biological processes
US20130145761A1 (en) * 2011-08-12 2013-06-13 Mcalister Technologies, Llc Systems and methods for providing supplemental aqueous thermal energy
CN102872785A (en) * 2012-10-20 2013-01-16 南京工业大学 Through type solar heat collection high-temperature reactor
CN103011627A (en) * 2012-11-27 2013-04-03 宜兴天力化工纳米科技有限公司 Lime slaking device
CN106830716A (en) * 2017-02-28 2017-06-13 成都格瑞思文化传播有限公司 A kind of lime slaking chemicals dosing plant
CN109297203A (en) * 2018-11-14 2019-02-01 中国科学技术大学 A kind of high-temperature vacuum heat-collecting tube for slot light collection collecting system

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Title
文建光: "纯碱与烧碱", 31 May 1998, 化学工业出版社, pages: 22 *
王光伟: "太阳能利用技术基础与工程实践", 30 November 2021, 天津大学出版社, pages: 27 *
谢秉正: "绿色智能建筑工程技术", 31 March 2007, 东南大学出版社, pages: 41 *

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