CN115504547A - Automatic scientific research device of experimental integration of waste water electrolysis - Google Patents

Automatic scientific research device of experimental integration of waste water electrolysis Download PDF

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Publication number
CN115504547A
CN115504547A CN202211253702.1A CN202211253702A CN115504547A CN 115504547 A CN115504547 A CN 115504547A CN 202211253702 A CN202211253702 A CN 202211253702A CN 115504547 A CN115504547 A CN 115504547A
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China
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automatic
box body
scientific research
electrolysis
wastewater
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CN202211253702.1A
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Inventor
周莉
杭小帅
朱冬冬
尤晓慧
张澜
王燕
肖静
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Nanjing Institute of Environmental Sciences MEE
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Nanjing Institute of Environmental Sciences MEE
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01DMEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D21/00Measuring or testing not otherwise provided for
    • G01D21/02Measuring two or more variables by means not covered by a single other subclass
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/22O2

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Hydrology & Water Resources (AREA)
  • Food Science & Technology (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an integrated automatic scientific research device for a wastewater electrolysis test, which comprises an electrolysis device box body, a power supply and a data processing terminal, wherein the electrolysis device box body comprises a box body, a reactor and an automatic liquid adding device, and an inlet of the box body is communicated with the automatic liquid adding device. This experimental automatic scientific research device of integration of waste water electrolysis, through adopting the integration, automated design, and is easy and simple to handle, the application scene is abundant, can regard as the experimental scientific research device of indoor electrolysis, it is loaded down with trivial details to solve current indoor scientific experiment, the uncontrollable technological problem of data, but effective control cost, avoid the waste of staff in the indoor test process, practice thrift the manpower, material resources, simultaneously can regulate and control experimental environment in real time, obtain a large amount of process monitoring data, regular exploration can be carried out, make things convenient for scientific research and aassessment, convenient to use is easy, can be used to all kinds of waste water of electrolysis, be favorable to popularizing and applying.

Description

Automatic scientific research device of experimental integration of waste water electrolysis
Technical Field
The invention relates to the technical field of environmental engineering, in particular to an integrated automatic scientific research device for a wastewater electrolysis test.
Background
With the rapid development of social economy, the pollution of surface water bodies and the eutrophication trend are increased, and the water pollution seriously threatens the safety of drinking water. The electrooxidation technology is a safe and stable degradation technology which is generally recognized at present, an indoor test is usually required for discussing the process mechanism of wastewater degradation by the electrooxidation technology, the degradation mechanism of the electrooxidation technology is discussed by changing conditions such as the distance between polar plates, the material of the polar plates, the current, the temperature and the like, the indoor test is real and reliable, regular exploration can be carried out, and the electrooxidation technology is an important means for scientific research.
At present, research data about an automatic electrolysis test device is less, and a patent CN216273622U discloses laboratory wastewater treatment equipment interconnected by micro-electrolysis-MBR coupling technology, wherein the micro-electrolysis device and an MBR membrane biological reaction device are matched to purify laboratory wastewater, and the wastewater is subjected to micro-electrolysis treatment by the micro-electrolysis device and then enters the MBR membrane biological reaction device to be easily further degraded. The device can be used for purifying the wastewater in a laboratory, but the device is complex and is not suitable for scientific research as an indoor experimental electrolysis device, so that the device for providing the indoor automatic electrolysis experimental device with adjustable environmental influence factors is urgent.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an integrated automatic scientific research device for wastewater electrolysis tests, which can change environmental influence factors (polar plate distance, polar plate material, current and temperature) simply, conveniently and quickly, provide convenient operation for scientific research and ensure the scientificity of research data.
(II) technical scheme
In order to realize the purpose, the invention is realized by the following technical scheme: the utility model provides an experimental automatic scientific research device of waste water electrolysis, includes electrolytic device box, power and data processing terminal, the electrolytic device box includes box body, reactor and automatic liquid feeding device, the entry of box body with automatic liquid feeding device intercommunication, the reactor sets up inside the box body.
The box body still includes thermometer, electric agitator, sample connection and automatic appearance of examining soon, the thermometer is located the bottom of box body for the change of monitoring scientific experimentation in-process waste water temperature, electric agitator is located the bottom of box body inner wall, the sample connection layering sets up in one side of box body, automatic examine appearance fixed mounting soon in the top of every layer of sample connection on the box body for monitor this internal data of box, data processing terminal is uploaded to in real time to the monitoring data.
Preferably, the automated rapid test meter includes, but is not limited to, monitoring pH, dissolved oxygen concentration, turbidity, chemical oxygen demand, and ammonia nitrogen level.
Preferably, the outer surface of the box body is marked with scales for controlling the volume.
Preferably, the reactor comprises a reaction electrode plate and an automatic spacing adjusting device.
Preferably, the reaction electrode plate is connected with a power supply, and the power supply, the automatic distance adjusting device, the automatic fast inspection instrument, the automatic liquid adding device, the thermometer and the electric stirrer are all connected with the data processing terminal.
Preferably, the data processing terminal comprises a display and a processor, the data is monitored in real time and then displayed and recorded on the display, and a large amount of scientific research data is formed.
Preferably, the sampling port is used for collecting wastewater samples at different depths, and the sampling port is controlled by a valve.
Preferably, the electric stirrer is used for setting conditions of different disturbance degrees.
(III) advantageous effects
The invention provides an integrated automatic scientific research device for a wastewater electrolysis test. Compared with the prior art, the method has the following beneficial effects:
(1) The integrated automatic scientific research device for the wastewater electrolysis test is communicated with the automatic liquid adding device through an inlet of the box body; the reactor is arranged inside the box body; the thermometer is positioned at the bottom end of the box body; the electric stirrer is positioned at the bottom end of the box body; the sampling ports can be arranged in layers and used for collecting wastewater samples at different depths; the automatic fast detector is positioned near the sampling port and comprises but is not limited to monitoring pH, dissolved oxygen concentration, turbidity, chemical oxygen demand and ammonia nitrogen, and monitoring data are uploaded to the data processing terminal in real time; the reaction electrode plate is connected with a power supply; the power supply, the automatic interval adjusting device, the automatic quick detector, the automatic liquid adding device, the thermometer and the electric stirrer are all connected with the data processing terminal; and the data processing terminal is used for monitoring the test data in real time to form a large amount of scientific research data.
(2) This experimental automatic scientific research device of waste water electrolysis, through adopting the integration, automated design, and is easy and simple to handle, the applied scene is abundant, can regard as the experimental scientific research device of indoor electrolysis, it is loaded down with trivial details to solve current indoor scientific experiment, the uncontrollable technological problem of data, but effective control cost, avoid among the indoor test process staff's waste, practice thrift the manpower, material resources, simultaneously can regulate and control experimental environment in real time, obtain a large amount of process monitoring data, can carry out the regularity and explore, make things convenient for scientific research and aassessment, it is convenient easy to use, can be used to all kinds of waste water of electrolysis, be favorable to popularizing and applying.
Drawings
FIG. 1 is a schematic structural diagram of an integrated automatic scientific research device for wastewater electrolysis tests provided by an embodiment of the invention.
In the figure: 1-automatic liquid adding device, 2-reaction electrode plate, 3-box body, 4-thermometer, 5-electric stirrer, 6-automatic spacing adjusting device, 7-power supply, 8-automatic fast inspection instrument, 9-sampling port and 10-data processing terminal.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, the embodiment of the present invention provides four technical solutions: an integrated automatic scientific research device for a wastewater electrolysis test is mainly applied to the technical field of environmental engineering, can simply, conveniently and quickly change environmental influence factors (polar plate distance, polar plate material, current and temperature), provides convenient operation for scientific research, and ensures the scientificity of research data. The device comprises: an electrolyzer case, a power supply 7 and a data processing terminal 10; the electrolyzer box includes: a box body 3, a reactor and an automatic liquid adding device 1; the reactor comprises a reaction electrode plate 2 and an automatic spacing adjusting device 6; the box body 3 also comprises a thermometer 4, an electric stirrer 5, an automatic quick detector 8 and a sampling port 9.
The inlet of the box body 3 is communicated with the automatic liquid adding device 1; the reactor is arranged inside the box body 3; the thermometer 4 is positioned at the bottom end of the box body 3; the electric stirrer 5 is positioned at the bottom end of the box body 3; the sampling port 9 is arranged on the side surface of the box body 3; the automatic fast detection instrument 8 is positioned near the sampling port 9; the reaction electrode plate 2 is connected with a power supply 7; the power supply 7, the automatic interval adjusting device 6, the automatic fast inspection instrument 8, the automatic liquid adding device 1, the thermometer 4 and the electric stirrer 5 are all connected with the data processing terminal 10; the data processing terminal 10 is used for monitoring the test data in real time to form a large amount of scientific research data.
As an alternative embodiment, the box body 3 is provided with scales, so that the volume control is convenient.
As an alternative embodiment, the electric stirrer 5 is used to set conditions of different degrees of turbulence.
As an alternative embodiment, the sampling port 9 can be arranged in layers, and waste water samples at different depths are collected and controlled by a valve.
As an optional embodiment, the automatic fast detection instrument 8 includes, but is not limited to, monitoring pH, dissolved oxygen concentration, turbidity, chemical oxygen demand, ammonia nitrogen, and monitoring data is uploaded to the data processing terminal in real time.
Example 1:
the embodiment of the invention provides a more specific automatic scientific research device for integrated wastewater electrolysis tests, wherein according to actual test requirements, the diameter of the bottom surface of a box body 3 is designed to be 80cm, the height of the bottom surface of the box body is designed to be 100cm, and the side surface of the box body is provided with scales, so that the volume control is convenient. The inlet of the box body 3 is communicated with the automatic liquid adding device 1. The reactor sets up inside box 3, and 2 sizes of reaction electrode board are 70cm 40cm, and the total length of reaction electrode board interval design size is 50cm, and the adjustable interval scope of automatic interval adjusting device 6 is 50cm promptly. The thermometer 4 is positioned at the bottom end of the box body 3 and 2cm away from the side surface of the box body. The electric stirrer 5 is positioned in the middle of the bottom end of the box body 3 and is divided into 3 grades of disturbance intensity, namely a low grade, a medium grade and a high grade. The sample connection 9 sets up in 3 sides of box, and the design sample connection totally 4, two liang of intervals are 25cm, and the export has valve control. The automatic fast detector 8 is positioned near the sampling port 9 and can monitor pH, dissolved oxygen concentration, turbidity, chemical oxygen demand and ammonia nitrogen. The reaction electrode plate 2 is connected to a power supply 7. The power supply 7, the automatic distance adjusting device 6, the automatic fast inspection instrument 8, the automatic liquid adding device 1, the thermometer 4 and the electric stirrer 5 are all connected with the data processing terminal 10. The data processing terminal 10 can input the current density, the electrode spacing and the disturbance intensity required by the indoor test, discuss the process mechanism of electrolyzing the wastewater by the electrooxidation method under different environmental conditions, discuss the degradation mechanism of the electrooxidation technology and explore regularly.
Example 2:
the distance between the input electrode plates at the data processing terminal 10 is 10cm, the current density is 5mA/cm < 2 >, and the disturbance intensity is low. After the setting is finished, the automatic liquid feeding device 1 is started, and the microcapsule algae liquid wastewater cultured in the early stage is injected into the box body 3, wherein the height of the wastewater is 90cm. The switch of the power supply 7 is turned on, the indoor wastewater electrolysis test is started, in the experimental process, 4 automatic quick detectors 8 transmit monitoring data to the data processing terminal 10 every 1min, the water quality change trend of wastewater of different levels in the test process is measured, the total test time is 2h, the sampling is performed for 1 time at the sampling port 9 every 5min in the first 30min, the sampling is performed for 1 time at the sampling port 9 every 10min in the last 30min, and the sampling is performed for 1 time at the sampling port 9 every 15min in the last 60 min. After the test is finished, the current density is adjusted to be 6mA/cm < 2 >, other test conditions are unchanged, the test is carried out once again according to the test steps, the water quality change trend of the wastewater of different levels in the test process is recorded under the condition that the current density is 6mA/cm < 2 >, and water samples are collected at the same time. According to the steps, the current densities are adjusted to be 7mA/cm < 2 >, 8mA/cm < 2 >, 9mA/cm < 2 > and 10mA/cm < 2 >, the tests are respectively carried out, and the influence of different current densities on the electrolytic test effect under the same external condition is studied by adopting a controlled variable method.
Example 3:
in order to discuss the influence of different electrode spacing on the test effect of the electrolytic microcystin, the spacing between the input electrode plates of the data processing terminal 10 is 10cm, the current density is 10mA/cm < 2 >, and the disturbance intensity is low. After the setting is finished, the automatic liquid feeding device 1 is started, and the microcapsule algae liquid wastewater cultured in the early stage is injected into the box body 3, wherein the height of the wastewater is 90cm. The switch of the power supply 7 is turned on, the indoor wastewater electrolysis test is started, in the experimental process, 4 automatic quick detectors 8 transmit monitoring data to the data processing terminal 10 every 1min, the water quality change trend of wastewater of different levels in the test process is measured, the total test time is 2h, the sampling is performed for 1 time at the sampling port 9 every 5min in the first 30min, the sampling is performed for 1 time at the sampling port 9 every 10min in the last 30min, and the sampling is performed for 1 time at the sampling port 9 every 15min in the last 60 min. After the test is finished, the electrode spacing is adjusted to be 20cm, 30cm, 40cm and 50cm, other test conditions are unchanged, the test is carried out again according to the test steps, and the influence of different electrode spacing on the electrolytic test effect under the same external conditions is discussed by adopting a controlled variable method.
Example 4:
in order to discuss the influence of different disturbance conditions on the test effect of the electrolytic microcystin, the distance between the input electrode plates of the data processing terminal 10 is 10cm, and the current density is 10mA/cm 2 The disturbance intensity is low. After the setting is finished, the automatic liquid feeding device 1 is started, and the microcapsule algae liquid wastewater cultured in the early stage is injected into the box body 3, wherein the height of the wastewater is 90cm. Starting a power supply 7 switch, starting an indoor wastewater electrolysis test, and in the test process, transmitting monitoring data to a data processing terminal 10 by 4 automatic quick detectors 8 every 1min, measuring the water quality change trend of wastewater of different levels in the test process, wherein the total test time is 2h, sampling is carried out for 1 time by a sampling port 9 every 5min in the first 30min, and sampling is carried out for 10min in the last 30minThe port 9 was sampled 1 time, and finally 60min was sampled 1 time every 15min sampling port 9. After the test is finished, the disturbance intensity is adjusted to be in a medium-grade or high-grade state, other test conditions are unchanged, the test is carried out again according to the test steps, and the influence of different disturbance intensities on the electrolysis test effect under the same external conditions is discussed by adopting a controlled variable method.
In conclusion, the automatic liquid adding device is communicated with the automatic liquid adding device through the inlet of the box body; the reactor is arranged in the box body; the thermometer is positioned at the bottom end of the box body; the electric stirrer is positioned at the bottom end of the box body; the sampling ports can be arranged in layers and used for collecting wastewater samples at different depths; the automatic fast detector is positioned near the sampling port and comprises but is not limited to monitoring pH, dissolved oxygen concentration, turbidity, chemical oxygen demand and ammonia nitrogen, and monitoring data are uploaded to the data processing terminal in real time; the reaction electrode plate is connected with a power supply; the power supply, the automatic interval adjusting device, the automatic quick detector, the automatic liquid adding device, the thermometer and the electric stirrer are all connected with the data processing terminal; data processing terminal is used for real-time supervision test data, form a large amount of scientific research data, through adopting the integration, automated design, and is easy and simple to handle, the application scene is abundant, can regard as the experimental scientific research device of indoor electrolysis, it is loaded down with trivial details to solve current indoor scientific experiment, the uncontrollable technological problem of data, but effective control cost, avoid among the indoor test process staff's waste, practice thrift the manpower, material resources, simultaneously can regulate and control experimental environment in real time, obtain a large amount of process monitoring data, can carry out the regularity and explore, make things convenient for scientific research and aassessment, convenient to use is easy, can be used to all kinds of waste water of electrolysis, be favorable to popularizing and applying.
And those not described in detail in this specification are well within the skill of those in the art.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. The utility model provides an experimental automatic scientific research device of integration of waste water electrolysis, includes electrolytic device box, power (7) and data processing terminal (10), its characterized in that: the electrolytic device box comprises a box body (3), a reactor and an automatic liquid adding device (1), wherein an inlet of the box body (3) is communicated with the automatic liquid adding device (1), and the reactor is arranged in the box body;
the utility model discloses a quick-witted box body, including box body (3), thermometer (4), electric stirrer (5), sample connection (9) and automatic quick-witted (8) of examining, thermometer (4) are located the bottom of box body (3) for the change of monitoring scientific experiment in-process waste water temperature, electric stirrer (5) are located the bottom of box body (3) inner wall, sample connection (9) layering sets up in one side of box body (3), automatic quick-check appearance (8) fixed mounting is in the top of every layer of sample connection (9) on box body (3) for data in the monitoring box body (3), and data processing terminal (10) are uploaded to monitoring data in real time.
2. The integrated automatic scientific research device for wastewater electrolysis tests according to claim 1, characterized in that: the automatic rapid detection meter (8) includes, but is not limited to, detection for monitoring pH, dissolved oxygen concentration, turbidity, chemical oxygen demand and ammonia nitrogen amount.
3. The integrated automatic scientific research device for wastewater electrolysis tests according to claim 1, characterized in that: scales are marked on the outer surface of the box body (3) and used for controlling the volume.
4. The integrated automatic scientific research device for wastewater electrolysis tests according to claim 1, characterized in that: the reactor comprises a reaction electrode plate (2) and an automatic spacing adjusting device (6).
5. The integrated automatic scientific research device for wastewater electrolysis tests according to claim 1, characterized in that: the reaction electrode plate (2) is connected with a power supply (7), and the power supply (7), the automatic distance adjusting device (6), the automatic fast inspection instrument (8), the automatic liquid adding device (1), the thermometer (4) and the electric stirrer (5) are all connected with the data processing terminal (10).
6. The integrated automatic scientific research device for wastewater electrolysis tests according to claim 1, characterized in that: the data processing terminal (10) comprises a display and a processor, and the data is monitored in real time and then displayed and recorded on the display to form a large amount of scientific research data.
7. The integrated automatic scientific research device for wastewater electrolysis tests according to claim 1, characterized in that: the sampling port (9) is used for collecting wastewater samples of different depths, and the sampling port (9) is controlled by a valve.
8. The integrated automatic scientific research device for the wastewater electrolysis test according to claim 1, which is characterized in that: the electric stirrer (5) is used for setting conditions of different disturbance degrees.
CN202211253702.1A 2022-10-13 2022-10-13 Automatic scientific research device of experimental integration of waste water electrolysis Pending CN115504547A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101962216A (en) * 2010-09-21 2011-02-02 复旦大学 Method for removing harmful algae in water body by adopting electro-Fenton
CN114212862A (en) * 2021-09-29 2022-03-22 哈尔滨工业大学 Electric flocculation oxidation integrated wastewater treatment device and treatment method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101962216A (en) * 2010-09-21 2011-02-02 复旦大学 Method for removing harmful algae in water body by adopting electro-Fenton
CN114212862A (en) * 2021-09-29 2022-03-22 哈尔滨工业大学 Electric flocculation oxidation integrated wastewater treatment device and treatment method

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Application publication date: 20221223