CN115491783A - High-strength flash-spun textile and manufacturing method thereof - Google Patents
High-strength flash-spun textile and manufacturing method thereof Download PDFInfo
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- CN115491783A CN115491783A CN202110782725.0A CN202110782725A CN115491783A CN 115491783 A CN115491783 A CN 115491783A CN 202110782725 A CN202110782725 A CN 202110782725A CN 115491783 A CN115491783 A CN 115491783A
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- Prior art keywords
- flash
- polyvinyl acetate
- textile
- spun
- multifunctional
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- 239000004753 textile Substances 0.000 title claims abstract description 91
- 239000004751 flashspun nonwoven Substances 0.000 title claims abstract description 78
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 32
- -1 polyethylene Polymers 0.000 claims abstract description 51
- 239000004698 Polyethylene Substances 0.000 claims abstract description 50
- 229920000573 polyethylene Polymers 0.000 claims abstract description 50
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 238000007639 printing Methods 0.000 claims abstract description 10
- 238000009987 spinning Methods 0.000 claims description 137
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 121
- 239000011118 polyvinyl acetate Substances 0.000 claims description 121
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 101
- 239000002245 particle Substances 0.000 claims description 99
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 74
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 72
- 229910021389 graphene Inorganic materials 0.000 claims description 72
- 239000000835 fiber Substances 0.000 claims description 59
- 150000004645 aluminates Chemical class 0.000 claims description 34
- 239000007822 coupling agent Substances 0.000 claims description 34
- 229920001474 Flashspun fabric Polymers 0.000 claims description 33
- 239000002904 solvent Substances 0.000 claims description 29
- 238000007731 hot pressing Methods 0.000 claims description 27
- 230000009172 bursting Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 15
- 239000007787 solid Substances 0.000 description 61
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 36
- 229910001626 barium chloride Inorganic materials 0.000 description 36
- 238000002360 preparation method Methods 0.000 description 27
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 26
- 239000005083 Zinc sulfide Substances 0.000 description 25
- 229910052984 zinc sulfide Inorganic materials 0.000 description 25
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 25
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 19
- 239000000126 substance Substances 0.000 description 19
- 238000012360 testing method Methods 0.000 description 16
- XJSRKJAHJGCPGC-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorohexane Chemical compound FC(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F XJSRKJAHJGCPGC-UHFFFAOYSA-N 0.000 description 14
- RIQRGMUSBYGDBL-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,5-decafluoropentane Chemical compound FC(F)(F)C(F)C(F)C(F)(F)C(F)(F)F RIQRGMUSBYGDBL-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- UKDOTCFNLHHKOF-FGRDZWBJSA-N (z)-1-chloroprop-1-ene;(z)-1,2-dichloroethene Chemical group C\C=C/Cl.Cl\C=C/Cl UKDOTCFNLHHKOF-FGRDZWBJSA-N 0.000 description 13
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical group FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 13
- 238000001035 drying Methods 0.000 description 13
- 238000000227 grinding Methods 0.000 description 13
- 238000001125 extrusion Methods 0.000 description 12
- 238000001914 filtration Methods 0.000 description 12
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- 238000005452 bending Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 230000006872 improvement Effects 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 229920001410 Microfiber Polymers 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 229920006253 high performance fiber Polymers 0.000 description 3
- 239000003658 microfiber Substances 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
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- 150000001875 compounds Chemical class 0.000 description 2
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- 239000003063 flame retardant Substances 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 150000008282 halocarbons Chemical group 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 239000004775 Tyvek Substances 0.000 description 1
- 229920000690 Tyvek Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
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- 239000004599 antimicrobial Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000009455 aseptic packaging Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
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- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
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- 239000002356 single layer Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
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- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/11—Flash-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/544—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/558—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in combination with mechanical or physical treatments other than embossing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
The invention relates to a high-strength flash-spun textile and a manufacturing method thereof, wherein the raw material comprises polyethylene, and the gram weight is 35-45 g/m 2 The front face burst index is 4-12 kPa.m 2 (ii)/g; the back burst index is 3-12 kPa.m 2 (ii)/g; the printing surface strength is less than 0.42m/s; the dynamic friction coefficient is 0.08-0.25; the antibacterial rate is more than 97 percent. The high-strength flash-spun textile prepared by the method has good antibacterial property, printability and better hand feeling.
Description
[ technical field ] A method for producing a semiconductor device
The invention relates to the technical field of flash spinning, in particular to a high-strength flash spun textile and a manufacturing method thereof.
[ background of the invention ]
The chemical fiber industry is an emerging industry that develops after new china is established. The chemical fiber is prepared by using natural high molecular compound or artificially synthesized high molecular compound as raw material and through the processes of preparing spinning solution, spinning, post-treatment and the like. The length, thickness, whiteness and gloss of the fiber can be adjusted in the production process. And respectively has the advantages of light resistance, wear resistance, easy washing, easy drying, no mildew and rot, no worm damage and the like. It is widely used for manufacturing clothing fabrics, filter cloth, conveyer belt, hose, rope, fishing net, electric insulating wire, medical suture, tyre cord fabric, parachute, etc. Chemical fibers are divided into two major classes, man-made fibers and synthetic fibers. In recent years, the chemical fiber yield of China is basically kept about 4000-5000 ten thousand tons, and the fluctuation range is not large. According to data, the chemical fiber yield in China in 2019 is 5952.8 ten thousand tons, which is increased by 534.8 ten thousand tons compared with the last year, and the yield is increased by 9.9 percent on the same scale. Therefore, china is a big country for the production of chemical fibers.
At present, through continuous technological attack for many years, chinese bio-based chemical fibers and raw material core technologies make new progress, the development of bio-based chemical fibers is mainly characterized by breaking through the manufacturing of key equipment for industrialization of bio-based chemical fibers, overcoming the technical bottleneck of industrialization of bio-based chemical fibers and raw materials, realizing the large-scale production of bio-based chemical fibers, and further expanding the application in the fields of clothing, home textiles and industrial textiles. The technical level and the industrialized development of the high-performance fiber in China also make great breakthrough, in the future, the key production and application technology of key varieties of the high-performance fiber is further promoted and broken through, the performance index stability of the fiber is further improved, and meanwhile, the application of the high-performance fiber in the fields of aerospace, ocean engineering, advanced rail transit, new energy automobiles, electric power and the like is expanded. In addition, with the improvement of living standard of people, new requirements are put forward on the characteristics of the clothes. The superfine fiber is an epoch-making product in the chemical fiber industry, and opens up a new era of textile products. Originally invented in the middle of the 60 s by doctor miyosi okamoto, the TORAY industrial textiles research laboratory. The superfine fiber is chemical fiber with extremely small filament number, and the standard of fine denier yarn in various countries in the world has no standard definition, but the fiber with the filament number smaller than 0.3dtex is a novel textile raw material with high quality and high technical content, and the product is light and thin in texture, soft and comfortable in hand feeling, good in drapability, large in specific surface area, strong in adsorption, excellent in warmth retention, waterproof and breathable performance and the like. The superfine fiber is a novel textile raw material with high quality and high technical content, and is widely applied to the aspects of clothing, home furnishing, decorative materials and the like. The preparation method of the superfine fiber comprises the following steps: a composite spin-stripping method, a dissolving method, an ultra-drawing method, a melt-blowing method, a flash evaporation method, and the like. Flash spun microfiber formation technology is one of the dry spinning processes, and the resulting fiber web has very fine fiber denier, typically 0.1 to 0.3dtex, originally discovered by the DuPont investigator White. At present, only two companies of DuPont and Asahi Kasei are known as flash-spun microfiber and nonwoven fabric production technologies, and the company is registered as TYVEK and ルクサ. No chemical fiber enterprises in China are put into the technical field of flash spinning for research, and although the chemical fiber yield is high, the chemical fiber enterprises in China are lack of research and development investment for top products in chemical fibers so as to overcome one of the technical difficulties of high-end chemical fibers. At present, the flash evaporation textile has the technical defects of high strength but poor printing performance due to the fact that polyethylene is used as a main raw material, and the purpose of the application is achieved mainly through improvement of flash evaporation raw materials and a process.
For the DuPont patented layout of flash technology, starting from the first flash technology patent in the last 60 s to the present, there was a cluster of 200 patents. We can also analyze the trend of flash evaporation technology from dupont. Most dupont patents are specific product properties that define the product, rather than the conventional raw materials or processes that define the product.
Chinese patent application No. CN201580044322.9 relates to a thermally or mechanically consolidated sheet comprising a flash spun plexifilamentary fiber strand comprising fibers having a total crystallinity index of less than or equal to 55%, and the flash spun plexifilamentary fiber strand having a total crystallinity index of less than or equal to 12m 2 A BET surface area of 0.9mm/g or more, wherein the fiber strand comprises mainly fibers formed of a homopolymer of ethylene; wherein the fiber strand comprises predominantly the fibers, the fibers are formed from high density polyethylene and have a monoclinic structure and an orthorhombic structure as determined by X-ray characteristics, and the monoclinic structure has a crystallinity index higher than 1%; the sheet is produced by a flash spinning process using a spin agent medium comprising a mixture of the following i) and ii), wherein: i) Is dichloromethane or trans-1,2-dichloroethylene; and ii) is 2,3-dihydrodecafluoropentane, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorohexane, 1,1,1,2,2,2,3,3,4,4,5,5,6,6-dodecafluorohexane, or hydrofluoroether.
Chinese patent application No. CN00814511.3 relates to a flash evaporation method of polyethylene plexifilamentary fiber yarnA spun nonwoven sheet having a thickness of between 1.7m 2 G and 10m 2 A surface area between g, the fiber yarn having a crush value between 1mm/g and 5.7 mm/g.
Chinese patent application No. CN201580074166.0 relates to a nanoweb comprising polymer fibers intimately mixed and entangled in a single layer of a separate network, and wherein: (a) The fiber comprises at least 70% of nano fiber, 5-25% of micro fiber and 0-5% of crude fiber according to the number percentage; (b) The number average diameter of all fibers is less than 1000nm, and the median diameter of all fibers is less than 500nm; and (c) the nanoweb has an apparent density of 0.01 to 0.05g/cm3, an electrostatic charge of at least 12kV as measured at a distance of 25mm, and an effective figure of merit (eQF) of greater than about 2.5 (Pa · g/cm 3) -1.
Chinese patent application No. CN201580057011.6 relates to a flame retardant thermal liner comprising (a) a nonwoven sheet comprising nanofibers of a synthetic polymer, the nonwoven sheet having an limiting oxygen index of at least 21, a mean flow pore of 10 microns or less, a thickness air permeability of 25 to 6000 cubic feet per minute-microns (12 to 2880 cubic meters per square meter per minute-micron), and an average thickness T1; and (b) a thermally stable flame retardant fabric attached to the outer surface of the nonwoven sheet, the fabric having an average thickness T2; a surface of the thermally stable fabric is in contact with a surface of the nonwoven sheet; wherein T1 and T2 are selected such that the ratio of T1 to T2 is less than 0.75.
Chinese patent application No. CN201780063000.8 relates to a fibrous nonwoven sheet structure suitable for use in aseptic packaging, the sheet structure being air permeable and having a first surface and a second surface; the first surface having an embossed embossing pattern bonded thereto and the second surface being capable of receiving printing; the sheet structure has a particle barrier penetration of less than 10%, a gurley hill porosity of 40 seconds or less, and a moisture vapor transmission rate of 3500g/m 2/day or greater.
Chinese patent application No. CN201780030076.0 relates to a composite laminate comprising at least one water vapor permeable nonwoven sheet having first and second surfaces and a fluorinated polymer coating on the first surface of the sheet, wherein (i) the fluorinated polymer coating is present in an amount such that the total fluorine content of the coated nonwoven sheet is from 0.05gsm to no greater than 0.4gsm, and (ii) the composite laminate exhibits a retained hydrohead of at least 60% when tested according to test method a after exposure to wet wood.
Chinese patent application No. CN89107884.3 relates to flash spinning of polymer plexifilaments, an improved process for synthetic forming of fibrous polymer plexifilaments Bao Moyuan spun yarn, wherein said polymer is mixed with a spinning liquid consisting essentially of methylene chloride and a co-solvent to form a spinning mixture containing 5 to 30wt% polymer, and said mixture is then flash spun at a pressure higher than the autogenous pressure of said spinning liquid into a zone of substantially lower temperature and pressure, the improvement comprising: said auxiliary solvent is a halocarbon having 1,2 or 3 carbon atoms and at least one hydrogen atom, has a boiling point within the range of 0 to-50 ℃ and is present in the spinning dope in an amount of 10 to 50% by weight, and said mixing and flash spinning are carried out at a temperature within the range of 130 to 240 ℃ and a pressure within the range of 500 to 5000 lb/in 2.
Chinese patent application No. CN90110343.8 relates to a method of flash spinning polyolefin organic filament film-like fibrillated tape comprising forming a spinning mixture comprising water, carbon dioxide and polyolefin, the flash spinning mixture entering a zone of substantially lower pressure and temperature at a temperature of at least 130 ℃ and a pressure greater than the pressure of the mixture itself.
Chinese patent application No. CN200580043448.0 relates to a nonwoven fibrous structure comprising an interconnected web of polyolefin filaments having filament widths greater than 1 micron which are further interconnected with a web of smaller polyolefin filaments having filament widths less than 1 micron, wherein the smaller polyolefin filaments comprise a majority of all the filaments.
[ summary of the invention ]
The invention aims to overcome the defects of the prior art and provide a high-strength flash-spun textile and a manufacturing method thereof.
The purpose of the invention is realized by the following technical scheme:
a high-strength flash-spun textile is prepared from polyethylene and has a gram weight of 35-45 g/m 2 ;
The front bursting index is 4-12 kPa.m 2 /g;
The back burst index is 3-12 kPa.m 2 /g;
The printing surface strength is less than 0.42m/s;
the dynamic friction coefficient is 0.08-0.25;
the antibacterial rate is more than 97 percent.
The front face burst index of the high-strength flash-spun textile is 6-8 kPa.m 2 (ii)/g or 9 to 11kPa · m 2 /g。
The back burst index of the high-strength flash-spun textile is 5-7 kPa.m 2 (ii)/g or 8 to 10kPa · m 2 /g。
The printing surface strength of the high-strength flash-spun textile is 0.2-0.3 m/s or 0.3-0.4 m/s.
The dynamic friction coefficient of the high-strength flash-spun textile is 0.08-0.12 or 0.12-0.14.
The high strength flash spun textile has an antimicrobial rate of greater than 98% or greater than 99%, which is the data obtained from testing against staphylococcus aureus.
The high-strength flash-spun textile further comprises multifunctional polyvinyl acetate master batches as raw materials.
The multifunctional polyvinyl acetate master batch is prepared from the raw materials of nano silver particle reduction graphene doped with lithopone, an aluminate coupling agent and polyvinyl acetate.
The mass of the polyethylene and the multifunctional polyvinyl acetate master batch is 1.
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps: firstly preparing the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent into a spinning solution, then carrying out flash spinning on the spinning solution at the temperature of 200-230 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the temperature of 106-116 ℃, and finally obtaining the multifunctional textile.
As a preferred technical scheme:
a manufacturing method of a multifunctional flash textile fabric comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the load nano silver particle reduced graphene to the barium chloride solid is 1:1-1:3;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 8-10%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1-2%.
Firstly, generating barium sulfate precipitates on the surface and in gaps of the reduced graphene loaded with the nano silver particles, then adding zinc sulfide solids, mixing and grinding to obtain lithopone adsorbed and wrapped on the reduced graphene loaded with the nano silver particles; has whitening and slow-release functions.
The lithopone is selected to mainly play a whitening function; and adding the loaded nano silver particles to reduce the graphene, wherein the nano silver has an antibacterial function, the flaky structure of the graphene has a function of serving as a carrier, and the loaded nano silver particles reduce the graphene into black powder. There is a contradiction that tests and analysis must select a proper interval between antibacterial property and whiteness, i.e. the whiteness of the textile is maintained under the premise of having better antibacterial effect.
The lithopone-doped nano silver particle-loaded reduced graphene serving as an inorganic material can be filled into fiber gaps of textiles in a flash spinning process, but the higher the addition amount is, the better the printability of the textiles is, but the higher the addition amount is, the flexible hand feeling and the air permeability of the textiles are reduced. A suitable interval between the feel of the textile and the printability needs to be sought.
The selected aluminate coupling agents herein start from: two active groups exist in the molecule of the aluminate coupling agent, and one RO group can react with the surface of the inorganic filler, namely can react with the inorganic powder; another type of COR group can be entangled with resin molecules, i.e., groups that interact with the polymeric binder. The aluminate coupling agent has a bridging function, one end of the aluminate coupling agent is connected with an inorganic substance, and the other end of the aluminate coupling agent is connected with polyvinyl acetate, so that the aluminate coupling agent has a better dispersing effect than the conventional silane coupling agent.
The polyvinyl acetate is selected as the matrix of the second polymer, mainly the structural characteristics of the polyvinyl acetate, and the polyvinyl acetate has good toughness, so that the technical problem of insufficient toughness of polyethylene raw materials can be solved.
The loaded nano silver particles of the present application reduce graphene, which has the basic properties: the sheet diameter is 500 nanometers to 5 micrometers, and the silver particle content is 50wt%.
2. Spinning solution preparation and flash spinning process
Firstly preparing the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent into a spinning solution, then carrying out flash spinning on the spinning solution at the temperature of 200-230 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the temperature of 106-116 ℃, and finally obtaining the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 12.6-14.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1. When the content of the multifunctional polyvinyl acetate master batch is low, the toughening effect cannot be achieved; when the mass ratio is continuously increased, the improvement on the flexibility of the product is not obvious, but the production cost of the product is obviously increased (the price ratio of the polyethylene with the same mass to the multifunctional polyvinyl acetate master batch is 1:5), so the range of the mass ratio is selected by the application.
The spinning solvent is selected from one or more of aromatic hydrocarbons, aliphatic hydrocarbons, alicyclic hydrocarbons, unsaturated hydrocarbons, halogenated hydrocarbons, alcohols, esters, ethers, ketones, nitriles and fluorocarbon compounds.
The spin solvent is preferably 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, in a volume ratio of 4.
Compared with the prior art, the invention has the following positive effects:
the high-strength flash-spun textile prepared by the method has good antibacterial property, printability and better hand feeling.
[ description of the drawings ]
Fig. 1 SEM image one of a flash spun textile of example 2 of the present application;
figure 2 SEM image of flash spun textile of example 2 of the present application.
[ detailed description ] A
The following provides specific embodiments of a high strength flash-spun textile and method of making the same according to the present invention.
The physical property parameter testing method comprises the following steps:
1. burst index
Burst index is the burst divided by the ration, burst is: the maximum pressure is applied by a hydraulic system when the elastic rubber film breaks the circular area of the sample.
And (3) testing the burst index according to international GB/T1539-2007, and respectively testing the front burst resistance and the back burst resistance of the sample.
For the indexes of the burst index, the higher the parameter is, the better the parameter is, and the better the burst performance of the product is indicated; also the strength of the product is higher as indicated from the side.
2. Strength of printed surface
Print surface strength, the speed at which the paper surface is printed at a continuously increasing speed until fluffing begins. The specific test process is determined according to the national standard GB/T22365-2008 paper and paperboard printing surface strength. During the test, the test specimens were found to have been fully fluffed and less suitable for printing at a speed of 0.42m/s, so the print surface strength was chosen to be less than 0.42m/s.
Under equivalent conditions, higher printing surface intensities are more favorable for printing.
3. Coefficient of dynamic friction
The coefficient of kinetic friction refers to the ratio of the kinetic friction forces acting perpendicularly on two surfaces in a friction test.
The dynamic friction coefficient is tested according to the determination of the static and dynamic friction coefficients of the paper and the paperboard of the national standard GB/T22895-2008. Firstly, longitudinal testing (which is the production and processing direction of a sample) is carried out to obtain a longitudinal dynamic friction coefficient; then carrying out transverse test (perpendicular to the production and processing direction of the sample) to obtain a transverse dynamic friction coefficient; and averaging the last 2 to obtain the dynamic friction coefficient of the sample.
Before testing, the sample is treated for 24 hours in an environment with humidity (10-35)% RH and temperature lower than 40 ℃; before the detection of the sample, the sample is balanced for 4 hours in a constant temperature and humidity chamber with the temperature (23 +/-1) DEG C and the humidity (50 +/-2)% RH. The ambient temperature at the time of the test is 22 ℃ to 24 ℃ and the relative humidity at the time of the test is 48% RH to 52% RH.
4. Antibacterial rate
The test of the antibacterial rate refers to the national standard GB/T20944.2-2007, the evaluation of the antibacterial performance of the textile is carried out, part 2: absorption method. The adopted strain is staphylococcus aureus, 3 samples are taken and are respectively tested, and then the average is calculated to obtain the antibacterial rate. The higher the antibacterial rate, the better, and more preferably more than 98%.
5. D65 luminance
The D65 brightness was measured according to the national standard GB/T7974-2013, according to the paper and board test method, wherein the front and back of the sample were measured separately and averaged to obtain the D65 brightness. The luminance of the present application is 0.88 to 0.93.
Six bending length
The bending length is: the rectangular fabric sample with one end held and the other end suspended is bent to the length of the specified angle under the action of the dead weight.
Bending length test the bending length of the samples was determined according to the national standard GB/T18318-2001, wherein the 6 specimen long sides are oriented in the longitudinal direction of the sample (the production process direction of the sample) and the 6 specimen long sides are oriented in the transverse direction of the sample (perpendicular to the process direction of the sample), and then averaged to obtain the bending length of the sample in centimeters.
The greater the bending length, the better the hand of the product. The preferred range of bending length for this application is 5-11 cm.
Example 1
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:1;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 8%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1 percent.
The loaded nano silver particles of the present application reduce graphene, which has the basic properties: the sheet diameter is 500 nanometers to 5 micrometers, and the silver particle content is 50wt%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution, wherein the flash spinning temperature is 210 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller, wherein the hot pressing temperature is 106 ℃, and finally obtaining the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 12.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
Spin for 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, in a volume ratio of 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Example 2
A manufacturing method of a multifunctional flash textile fabric comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:2;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 9%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃, and finally obtaining the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
The SEM images of the high-strength flash-spun textile of the present application are shown in fig. 1 and fig. 2, and it can be seen from fig. 1 that the single fibers adsorb the inorganic material, and fig. 2 is a schematic structural view of the flash-spun textile, which is seen to be intertwined with each other, and has the functions of high strength, printability, and good softness.
Example 3
A manufacturing method of high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:3;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the nano-silver particle-loaded reduced graphene doped with lithopone in the multifunctional polyvinyl acetate master batch is 10%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 2 percent.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 230 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 116 ℃, and finally obtaining the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 14.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 1
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Reducing the loaded nano silver particles into graphene, lithopone, an aluminate coupling agent and polyvinyl acetate, and finally, melting and extruding to obtain the multifunctional polyvinyl acetate master batch.
The mass fraction of the nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 3%.
The mass fraction of lithopone in the multifunctional polyvinyl acetate master batch is 6 percent.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 2
A manufacturing method of a multifunctional flash textile fabric comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:2;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the silver nanoparticle-loaded reduced graphene doped with lithopone in the multifunctional polyvinyl acetate master batch is 6%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5 percent.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 3
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:2;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 7%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spin solvent is preferably 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, in a volume ratio of 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 4
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:2;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 11%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5 percent.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 5
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the silver nanoparticle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:2;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 12%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃, and finally obtaining the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 6
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the loaded nano silver particle reduced graphene to the barium chloride solid is 1;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 9%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5 percent.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 7
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the silver nanoparticle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the loaded nano silver particle reduced graphene to the barium chloride solid is 1;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 9%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 8
A manufacturing method of a high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the reduced graphene loaded with the nano silver particles to the barium chloride solid is 1:4;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 9%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃, and finally obtaining the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%.
The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4.
The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
Comparative example 9
A manufacturing method of high-strength flash-spun textile comprises the following technical steps:
1. preparation of multifunctional polyvinyl acetate master batch
Dispersing the reduced graphene loaded with the nano-silver particles into a dilute sulfuric acid solution, adding a barium chloride solid, and filtering and drying to obtain the reduced graphene loaded with the nano-silver particles, the surface of which adsorbs barium sulfate; then adding zinc sulfide solid, mixing and grinding to obtain the nano silver particle-loaded reduced graphene doped with lithopone; then adding an aluminate coupling agent and polyvinyl acetate, and finally performing melt extrusion to obtain the multifunctional polyvinyl acetate master batch.
The mass ratio of the loaded nano silver particle reduced graphene to the barium chloride solid is 1;
the mass ratio of the barium chloride solid to the zinc sulfide solid is 1:1;
the mass fraction of the lithopone-doped nano-silver particle-loaded reduced graphene in the multifunctional polyvinyl acetate master batch is 9%.
The mass fraction of the aluminate coupling agent in the multifunctional polyvinyl acetate master batch is 1.5%.
2. Spinning solution preparation and flash spinning process
Firstly preparing a spinning solution from the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent, then carrying out flash spinning on the spinning solution at the flash spinning temperature of 220 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the hot pressing temperature of 110 ℃ to finally obtain the multifunctional textile.
The mass fraction of the mixture of the multifunctional polyvinyl acetate master batch and the polyethylene particles in the spinning solution is 13.6%. The mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
The spinning solvent was 1,1-dichloro-2,2,2-trifluoroethane, 1,2-dichloroethylene, 1H-perfluorohexane, 2,3 dihydrodecafluoropentane, the volume ratio of four was 4. The high strength flash-spun textile of the present application was tested for performance parameters as described above and the results are shown in table 1.
TABLE 1
Claims (10)
1. The high-strength flash-spun textile is characterized in that the raw material of the textile comprises polyethylene, and the gram weight of the textile is 35-45 g/m 2 ;
The front bursting index is 4-12 kPa.m 2 /g;
The back burst index is 3-12 kPa.m 2 /g;
The printing surface strength is less than 0.42m/s;
the dynamic friction coefficient is 0.08-0.25;
the antibacterial rate is more than 97 percent.
2. A high strength flash spun textile according to claim 1, wherein the high strength flash spun textile has a face burst index of 6 to 8 kPa-m 2 (ii)/g or 9 to 11kPa · m 2 /g。
3. The high strength flash spun textile of claim 1, wherein the high strength flash spun textile has a backside burst index of 5 to 7 kPa-m 2 (ii)/g or 8 to 10kPa · m 2 /g。
4. A high strength flash spun textile according to claim 1, wherein the printed surface strength of the high strength flash spun textile is 0.2-0.3 m/s or 0.3-0.40 m/s.
5. A high strength flash spun textile according to claim 1, wherein the high strength flash spun textile has a dynamic coefficient of friction of 0.08 to 0.12 or 0.12 to 0.14.
6. A high strength flash spun textile according to claim 1, wherein the high strength flash spun textile has an antibacterial rate of greater than 98% or greater than 99%.
7. The high-strength flash-spun textile according to claim 1, wherein the raw material of the high-strength flash-spun textile further comprises multifunctional polyvinyl acetate masterbatch.
8. The high-strength flash-spun textile according to claim 1, wherein the multifunctional polyvinyl acetate masterbatch is prepared from lithopone-doped nano-silver particle-loaded reduced graphene, an aluminate coupling agent and polyvinyl acetate.
9. The high-strength flash-spun textile according to claim 1, wherein the mass ratio of the polyethylene to the multifunctional polyvinyl acetate master batch is 1.
10. A manufacturing method of a high-strength flash-spun textile is characterized by comprising the following technical steps: firstly preparing the multifunctional polyvinyl acetate master batch, polyethylene particles and a spinning solvent into a spinning solution, then carrying out flash spinning on the spinning solution at the temperature of 200-230 ℃, then lapping flash spun fibers, and then carrying out hot pressing by using a hot roller at the temperature of 106-116 ℃, and finally obtaining the multifunctional textile.
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CN1314930A (en) * | 1999-04-20 | 2001-09-26 | Pca霍奇森化学品股份有限公司 | Water repellent compositions, process and applications therefor |
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CN103074803A (en) * | 2011-10-25 | 2013-05-01 | 王子控股株式会社 | Matt coated paper for printing |
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CN1042741A (en) * | 1988-08-31 | 1990-06-06 | 纳幕尔杜邦公司 | The flash-spinning of polymer brushes silk |
US5192468A (en) * | 1989-11-22 | 1993-03-09 | E. I. Du Pont De Nemours And Company | Process for flash spinning fiber-forming polymers |
CN1314930A (en) * | 1999-04-20 | 2001-09-26 | Pca霍奇森化学品股份有限公司 | Water repellent compositions, process and applications therefor |
US20040248492A1 (en) * | 2003-06-06 | 2004-12-09 | Reemay, Inc. | Nonwoven fabric printing medium and method of production |
CN103074803A (en) * | 2011-10-25 | 2013-05-01 | 王子控股株式会社 | Matt coated paper for printing |
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