CN115491637B - Method for improving optical transmittance of diamond substrate - Google Patents
Method for improving optical transmittance of diamond substrate Download PDFInfo
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- CN115491637B CN115491637B CN202211212567.6A CN202211212567A CN115491637B CN 115491637 B CN115491637 B CN 115491637B CN 202211212567 A CN202211212567 A CN 202211212567A CN 115491637 B CN115491637 B CN 115491637B
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Abstract
The invention relates to a method for improving optical transmittance of a diamond substrate, belonging to the field of preparation and processing of optical materials. The method comprises the steps of firstly carrying out photoetching on a diamond substrate to form an array shape, then removing a surface residual graphite phase through high-temperature or plasma processing, then carrying out activation and terminal modification on the surface of the diamond substrate by adopting mixed gas of high-concentration oxygen and low-concentration argon, and finally sputtering/evaporating a rare earth metal doped oxide film layer with an anti-reflection effect on the surface of the treated diamond substrate, thereby finally obtaining the diamond material coated with the anti-reflection film. The method has the advantages of energy conservation, environmental protection, convenient operation, good controllability, good repeatability, small error and the like, and the coated diamond material prepared by the preparation method has the advantages of high infrared band transmittance, high quality, good uniformity and the like, and can be used in the fields of military, aerospace, electronic products and the like.
Description
Technical Field
The invention belongs to the field of preparation and processing of optical materials, and particularly relates to a method for improving optical transmittance of diamond, in particular to a method for improving optical transmittance of a diamond substrate.
Background
The diamond has the characteristics of high hardness, high thermal conductivity, good optical transmittance, stable chemical property and the like, has important application prospects in the fields of optical devices such as infrared windows of high-speed aircrafts, high-power laser windows and the like, but the high refractive index (n=2.4) of the diamond can cause reflection loss of up to 29%, so that the actual transmittance is less than 70%. At present, the transmittance of the light is mainly improved by constructing an array structure and plating an antireflection film. However, the single process suffers from the following disadvantages: the physical property difference between the antireflection film and the diamond is large, the binding force of the film layer is poor, and the film layer is easy to break in a severe environment; although the transmittance of the array structure can be improved, the transmittance is drastically reduced due to poor high-temperature oxidation resistance, and the array structure on the diamond surface is difficult to obtain due to the superhard characteristic of the diamond. At present, an array structure is mainly obtained by a chemical etching method, which comprises the steps of depositing a metal or alloy film on the surface of diamond, then carrying out dry etching, preparing a microstructure on a substrate, then depositing array diamond, and repeatedly copying and growing. However, the above methods have the problems of complex preparation process, high cost and the like, and meanwhile, the operation safety and environmental protection are required to be further improved.
Disclosure of Invention
The present invention is directed to a method for improving optical transmittance of a diamond substrate, in order to solve the above-mentioned problems of the prior art. The method belongs to the technical field of application of diamond infrared optical components, the coating film obtained by the method has high binding force with a diamond substrate, good optical permeability in an infrared band, good controllability, high repetition rate and the like, and can meet the application requirements of the optical communication and equipment field on diamond window materials coated with an antireflection film.
The invention is realized by the following technical scheme:
a method for improving optical transmittance of diamond substrate includes photoetching diamond substrate to form array shape, removing residual graphite phase on surface by high-temp or plasma processing, activating and terminal modifying surface of diamond substrate by mixed gas of high-concentration oxygen and low-concentration argon, sputtering/evaporating rare-earth metal doped oxide film layer with anti-reflection effect on surface of treated diamond substrate, and finally obtaining diamond material coated with anti-reflection film.
Specifically, the method comprises the following steps:
s1, forming an arrayed shape: patterning the smooth and clean top surface of the diamond substrate by utilizing a laser lithography technology to obtain a patterned diamond substrate with a columnar array pattern;
s2, removing graphite phase by high temperature or oxygen plasma: placing the patterned diamond substrate in a high-temperature treatment furnace or a heatable vacuum device, and removing graphite phases on the surface of the patterned diamond substrate by controlling heating temperature, heating time and parameters of gas inlet;
s3, high-concentration oxygen activation modified surface: the patterned diamond substrate with the graphite phase removed is placed in a sputtering or vapor deposition device, and is vacuumized to 10 -3 ～10 -4 After Pa, introducing oxygen and argon, activating and modifying the surface of the patterned diamond substrate at the terminal;
s4, depositing a rare earth metal doped oxide anti-reflection film layer: in a sputtering or vapor deposition device, the patterned diamond substrate with the rare earth metal doped oxide anti-reflection film layer coated on the surface is finally obtained by controlling parameters of gas flow, matrix temperature, matrix bias, target power and deposition time.
Further, in step S1, the diamond substrate is a single crystal or polycrystalline diamond substrate, the photolithography pattern is a rectangular array pattern, a polygonal array pattern or a concentric array pattern, the single columns obtained by photolithography are rectangular columns, polygonal columns or cylinders, the side length or diameter thereof is 1-10 μm, the height of the columns is 0.01-5 μm, and the pitch of the adjacent single columns is 1-100 μm.
Further, in step S1, the laser frequency at the time of lithography is 0.01 to 20 kHz and the laser axial velocity is 0.01 to 100 μm/S.
Further, in step S2, the heating temperature is 800-1000 ℃, the time is 0.5-3 h, the gas is oxygen, the heating speed is 1-10 ℃/min, and the flow is 300-600 sccm.
Further, in step S3, the concentration ratio of oxygen to argon is (9 to 3): (1-2), the air pressure is 5-20 Pa, the oxygen flow is 100-200 sccm, the argon flow is 50-100 sccm, the substrate temperature is 400-600 ℃, the substrate bias is-100 to-800V, and the activation modification time is 0.2-1 h.
Further, in step S4, in the sputtering or vapor deposition apparatus, the gas pressure is adjusted to 1 to 10 Pa, the argon flow is 20 to 100 sccm, the oxygen flow is 10 to 100 sccm, the substrate temperature is 200 to 800 ℃, the substrate bias is-100 to-300V, the target sputtering power is 30 to 350W, the deposition time is 0.5 to 3 h, and the deposition thickness is 1.0 to 2.0 μm.
Furthermore, the target material adopts a composite single target material or a mixed double target material, wherein the composite single target material is a rare earth metal small column doped oxide ceramic target material or a rare earth metal small column doped metal target material, and the mixed double target material is a rare earth metal target material and a common metal target material.
Further, rare earth metals include La, nd, er, sm, Y, and common metals include Zr, mg, and Al.
And similarly, if photoetching is respectively carried out on the top surface and the bottom surface of the double-sided polished diamond substrate, and the subsequent operation of the preparation method is repeated, namely the method for improving the optical transmittance of the diamond substrate by double-sided coating.
In the method, laser lithography directly acts on the diamond substrate, and the formed array has the advantages of simple structure, convenient operation, easy control, environmental protection, green and the like; the oxygen and argon etching has the advantages of activating the surface, enabling the oxygen to modify the diamond surface and further improving the binding force between the film and the diamond substrate; further depositing an oxide or rare earth metal doped oxide anti-reflection film layer, wherein the rare earth metal has the functions of refining oxide crystal grains and enhancing the combination force between the oxide crystal grains and a matrix; meanwhile, the oxide or rare earth metal doped oxide film layer has the advantages of high melting point, high hardness, low expansion coefficient and the like as an antireflection film, can maintain the stability of diamond in high-oxygen and high-temperature environments, and can improve the transmittance of the diamond in an infrared band.
Compared with the prior art, the invention has the following beneficial effects:
the method has the advantages of energy conservation, environmental protection, convenient operation, good controllability, good repeatability, small error and the like, and the mode that laser lithography directly acts on the diamond substrate to form an array has the advantages of simple structure, convenient operation, easy control, environmental protection and the like; the array structure has an anti-reflection effect, and the oxygen and argon etching has the advantages of activating the surface and modifying the surface of the diamond substrate by oxygen so as to improve the binding force between the film and the diamond substrate; further depositing an oxide or rare earth metal doped oxide anti-reflection film layer, wherein the rare earth metal has the functions of refining oxide crystal grains and enhancing the combination force between the oxide crystal grains and a matrix; meanwhile, the oxide or rare earth metal doped oxide film layer has the advantages of high melting point, high hardness, low expansion coefficient and the like as an antireflection film, can maintain the stability of the diamond in high-oxygen and high-temperature environments, and can improve the transmittance of the diamond in different wave bands. The coated diamond material prepared by the preparation method has the advantages of high far infrared band transmittance, high quality, good uniformity and the like, and can be used in the fields of military, aerospace, electronic products and the like.
Description of the drawings:
in order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings that are needed in the embodiments of the present application will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present application and should not be considered as limiting the scope, and other related drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a flow chart of a single layer coated diamond process of the method of the present invention.
Fig. 2 is a cross-sectional view of a single-layer coated diamond prepared by the method of the present invention.
Fig. 3 is a flow chart of a double-layer coated diamond process according to the method of the present invention.
Fig. 4 is a cross-sectional view of a double-layered coated diamond prepared by the method of the present invention.
In the figure: 101-diamond substrate, 102-patterned diamond substrate, 201-antireflection film.
The specific embodiment is as follows:
the following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is evident that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to fall within the scope of the invention.
Example 1
A method for improving optical transmittance of a diamond substrate, as shown in fig. 1, comprising the steps of:
s1, forming an array shape on a diamond substrate
The diamond substrate 101 with a single-sided crystal face polished and a surface roughness less than 0.8 and nm is cleaned and dried, and laser lithography parameters and pattern types are set: the laser frequency is 0.01 kHz, the laser axial speed is 0.01 mu m/s, the pattern unit is square with a side length of 1 mu m, the etching depth is 0.01 mu m, the distance between adjacent single columns is 1 mu m, and the patterned diamond substrate 102 with the rectangular array pattern of the columns is obtained by performing pattern array photoetching on the diamond substrate 101.
S2, removing graphite phase at high temperature
Placing the obtained patterned diamond substrate 102 into a high-temperature treatment furnace, and setting parameters: heating speed is 1 ℃/min, heating temperature is 800 ℃, heating time is 0.5 h, gas is oxygen, flow rate is 300 sccm, and defects such as graphite on the surface of the patterned diamond substrate 102 are removed.
S3, high-concentration oxygen activation modified surface
The patterned diamond substrate 102 with the graphite phase removed is placed in a DC sputtering apparatus and is evacuated to 1X 10 -4 After Pa, 450 sccm of oxygen and 50 sccm of argon are introduced, oxygenThe concentration ratio of gas to argon is 9:1, activating the surface of the patterned diamond substrate 102, wherein the set parameters are as follows: cavity air pressure 20 Pa, base bias-100V, base temperature 400 ℃, activation modification time 0.2 h, forming oxygen terminal on the surface of patterned diamond substrate 102 to improve the binding force of the film and patterned diamond substrate 102.
S4, deposition of samarium doped yttrium oxide anti-reflection film 201
After the surface modification is activated, a samarium doped yttrium oxide antireflection film layer 201 is deposited on the surface, and the parameters are set as follows: the chamber air pressure is 1 Pa, the argon flow is 20 sccm, the oxygen flow is 10 sccm, the substrate temperature is 200 ℃, the substrate bias is-100V, the samarium column doped metal yttrium target sputtering power is 30W, the sputtering time is 0.5 h, the deposition thickness is 1 μm, and finally the patterned diamond substrate 102 with the samarium doped yttrium oxide antireflection film layer 201 coated on the surface is obtained, as shown in fig. 2.
Through detection, the transmittance of the patterned diamond substrate 102 coated with the samarium doped yttrium oxide anti-reflection film layer 201 on the surface can reach 85% in the wave band of 8-12 mu m.
Example 2
A method for improving optical transmittance of a diamond substrate, as shown in fig. 1, comprising the steps of:
s1, forming an array shape on a diamond substrate
The diamond substrate 101 with a single-sided crystal face polished and a surface roughness less than 1 nm is cleaned and dried, and laser lithography parameters and pattern types are set: the laser frequency is 6 kHz, the laser axial speed is 20 mu m/s, the pattern unit is round with the diameter of 2 mu m, the etching depth is 2 mu m, the distance between adjacent single columnar bodies is 10 mu m, and the patterned diamond substrate 101 is subjected to pattern array photoetching to obtain the patterned diamond substrate 102 with columnar body concentric circle array patterns.
S2, removing graphite phase at high temperature
Placing the obtained patterned diamond substrate 102 into a high-temperature heating furnace, and setting etching parameters: heating speed is 3 ℃/min, heating temperature is 850 ℃, heat preservation time is 1 h, oxygen flow is 400 sccm, and defects such as graphite on the surface of the patterned diamond substrate 102 are removed.
S3, high-concentration oxygen activation modified surface
The patterned diamond substrate 102 with the graphite phase removed is placed in a magnetron sputtering device and is vacuumized to 1×10 -3 After Pa, 150 sccm of oxygen and 100 sccm of argon were introduced, the concentration ratio of oxygen to argon being 3:2, activating the surface of the patterned diamond substrate 102, wherein the set parameters are as follows: cavity air pressure 5 Pa, base bias-200V, activation temperature 450 ℃ and activation time 0.5 h, and oxygen termination is formed on the surface of the patterned diamond substrate 102 to improve the bonding force of the film and the patterned diamond substrate 102.
S4 deposition of lanthanum doped hafnium oxide anti-reflection film 201
After activating the modified surface, a lanthanum-doped hafnium oxide anti-reflection film 201 is deposited on the surface, and the parameters are set as follows: the chamber air pressure is 3 Pa, the argon flow is 40 sccm, the oxygen flow is 30 sccm, the substrate temperature is 400 ℃, the substrate bias is-200V, the metal hafnium target sputtering power is 200W, the metal lanthanum target sputtering power is 30W, the sputtering time is 1 h, the deposition thickness is 1.2 μm, and finally the patterned diamond substrate 102 with the lanthanum-doped hafnium oxide antireflection film layer 201 coated on the surface is obtained, as shown in fig. 2.
Through detection, the transmittance of the patterned diamond substrate 102 coated with the lanthanum-doped hafnium oxide anti-reflection film 201 reaches 80% in the long-wave infrared band.
Example 3
A method for improving the optical transmittance of a diamond substrate, as shown in fig. 3, comprising the steps of:
s1, forming an array shape on a diamond substrate
The diamond substrate 101 with the top and bottom double-sided crystal faces polished and the surface roughness less than 0.5 nm is cleaned and dried, and laser photoetching parameters and pattern types are set: the laser frequency is 10 kHz, the laser axial speed is 60 mu m/s, the pattern unit is a hexagon with a side length of 6.8 mu m, the etching depth is 3 mu m, the distance between adjacent single columns is 70 mu m, and the patterned diamond substrate 102 with the hexagonal array pattern of the columns is obtained by performing pattern array photoetching on the diamond substrate 101.
S2, removing graphite phase by oxygen plasma
To be obtainedThe patterned diamond substrate 102 is placed in a chemical vapor deposition device and is evacuated to 10 a -3 After Pa, the heating temperature is 7 ℃/min, 500 sccm of oxygen is introduced, and parameters are set: cavity air pressure 3000 Pa, microwave power 1000W, base station temperature 900 ℃ and time 2 h, and the defects of graphite and the like on the surface of the patterned diamond substrate 102 are removed.
S3, high-concentration oxygen activation modified surface
The patterned diamond substrate 102 with the graphite phase removed is placed in a vacuum evaporation device and is vacuumized to 1×10 -4 After Pa, 240 sccm of oxygen and 80 sccm of argon were introduced, the concentration ratio of oxygen to argon being 3:1, activating the surface of the patterned diamond substrate 102, wherein the set parameters are as follows: cavity air pressure 12 Pa, base bias-400V, activation temperature 500 ℃, activation time 0.8 h, forming oxygen termination on the surface of patterned diamond substrate 102 to improve the bonding force of the film and patterned diamond substrate 102.
S4, deposition of erbium-doped alumina anti-reflection film layer 201
After the surface is activated and modified, an erbium-doped alumina anti-reflection film layer 201 is deposited on the surface by an evaporation device, and when the air pressure of the cavity is pumped to 1 multiplied by 10 -4 After Pa, argon and oxygen are introduced, the flow rate of the argon is 70 sccm, the flow rate of the oxygen is 80 sccm, the deposition air pressure is 7 Pa, the plating material is 5 wt% of metal erbium particles and 95 wt% of aluminum oxide particles, the evaporation power is set to be 280W, the deposition time is 2 h, the deposition thickness is 1.5 mu m, and finally the patterned diamond substrate 102 with the erbium-doped aluminum oxide antireflection film layer 201 coated on the surface is obtained, as shown in fig. 4.
Example 4
A method for improving optical transmittance of a diamond substrate, as shown in fig. 1, comprising the steps of:
s1, forming an array shape on a diamond substrate
Cleaning and drying the diamond substrate 101 with the single crystal surface polished and the surface roughness smaller than 0.5 and nm, and setting laser lithography parameters and pattern types: the laser frequency is 20 kHz, the laser axial speed is 100 mu m/s, the pattern unit is octagon with the side length of 10 mu m, the etching depth is 5 mu m, the distance between adjacent single columns is 100 mu m, the patterned array photoetching is carried out on the diamond substrate 101, and the patterned diamond substrate 102 with rectangular array patterns of the columns is obtained.
S2, removing graphite phase at high temperature
Placing the obtained patterned diamond substrate 102 into a high-temperature heating furnace, and setting etching parameters: heating speed is 10 ℃/min, heating temperature is 1000 ℃, heat preservation time is 3 h, oxygen flow is 600 sccm, and defects such as graphite on the surface of the patterned diamond substrate 102 are removed.
S3, high-concentration oxygen activation modified surface
The patterned diamond substrate 102 with the graphite phase removed is placed in a vacuum evaporation device and is vacuumized to 1×10 -4 After Pa, 300 sccm of oxygen and 150 sccm of argon were introduced, the concentration ratio of oxygen to argon being 2:1, activating the surface of the patterned diamond substrate 102, wherein the set parameters are as follows: cavity air pressure 18 Pa, base bias-800V, activation temperature 600 ℃ and activation time 1 h, and oxygen termination is formed on the surface of the patterned diamond substrate 102 to improve the bonding force of the film and the patterned diamond substrate 102.
S4, deposition of neodymium doped zirconia anti-reflection film layer 201
After activating the modified surface, a neodymium-doped zirconia antireflection film layer 201 is deposited on the modified surface, and parameters are set as follows: the deposition air pressure is 10 Pa, the argon flow is 100 sccm, the oxygen flow is 100 sccm, the substrate temperature is 800 ℃, the substrate bias is-300V, the sputtering power of the metal neodymium target is 350W, the sputtering power of the metal zirconium target is 350W, the sputtering time is 3 h, the deposition thickness is 2 μm, and finally the patterned diamond substrate 102 with the neodymium-doped zirconia antireflection film layer 201 coated on the surface is obtained, as shown in fig. 2.
It should be noted that the foregoing description is only specific embodiments of the present invention, and is not intended to limit the present invention, and the embodiments and features of the embodiments may be combined without conflict. Any modification, equivalent replacement, improvement, etc. should be included in the protection scope of the present invention, while remaining within the technical scope and principle of the present invention.
Claims (7)
1. A method for improving optical transmittance of a diamond substrate, comprising the steps of:
s1, forming an arrayed shape: patterning the smooth and clean top surface of the diamond substrate by utilizing a laser lithography technology to obtain a patterned diamond substrate with a columnar array pattern;
s2, removing graphite phase by high temperature or oxygen plasma: placing the patterned diamond substrate in a high-temperature treatment furnace or a heatable vacuum device, and removing graphite phases on the surface of the patterned diamond substrate by controlling heating temperature, heating time and parameters of gas inlet;
s3, high-concentration oxygen activation modified surface: the patterned diamond substrate with the graphite phase removed is placed in a sputtering or vapor deposition device, and is vacuumized to 10 -3 ～10 -4 After Pa, introducing oxygen and argon, activating and modifying the surface of the patterned diamond substrate at the terminal; the concentration ratio of oxygen to argon is (9-3): (1-2), wherein the cavity air pressure is 5-20 Pa, the oxygen flow is 150-450 sccm, the argon flow is 50-150 sccm, the substrate temperature is 400-600 ℃, the substrate bias is-100 to-800V, and the activation modification time is 0.2-1 h;
s4, depositing a rare earth metal doped oxide anti-reflection film layer: in a sputtering or vapor deposition device, the patterned diamond substrate with the rare earth metal doped oxide anti-reflection film layer coated on the surface is finally obtained by controlling parameters of gas flow, matrix temperature, matrix bias, target power and deposition time.
2. A method of increasing the optical transmission of a diamond substrate according to claim 1, wherein: in step S1, the diamond substrate is a monocrystalline or polycrystalline diamond substrate, the lithographic pattern is a rectangular array pattern, a polygonal array pattern or a concentric array pattern, the single columns obtained by lithography are rectangular columns, polygonal columns or cylinders, the side length or diameter of each column is 1-10 μm, the height of each column is 0.01-5 μm, and the distance between adjacent single columns is 1-100 μm.
3. A method of increasing the optical transmission of a diamond substrate according to claim 1, wherein: in step S1, the laser frequency at the time of lithography is 0.01-20 kHz/, and the laser axial velocity is 0.01-100 μm/S.
4. A method of increasing the optical transmission of a diamond substrate according to claim 1, wherein: in the step S2, the heating temperature is 800-1000 ℃, the time is 0.5-3 h, the gas is oxygen, the heating speed is 1-10 ℃/min, and the flow is 300-600 sccm.
5. A method of increasing the optical transmission of a diamond substrate according to claim 1, wherein: in step S4, in the sputtering or vapor deposition device, the air pressure is regulated to be 1-10 Pa, the argon flow is 20-100 sccm, the oxygen flow is 10-100 sccm, the substrate temperature is 200-800 ℃, the substrate bias is-100 to-300V, the target sputtering power is 30-350W, the deposition time is 0.5-3 h, and the deposition thickness is 1-2 μm.
6. A method of increasing the optical transmission of a diamond substrate according to claim 5, wherein: the target material adopts a composite single target material or a mixed double target material, wherein the composite single target material is a rare earth metal small column doped oxide ceramic target material or a rare earth metal small column doped metal target material, and the mixed double target material is a rare earth metal target material and a common metal target material.
7. A method of increasing the optical transmission of a diamond substrate according to claim 6, wherein: rare earth metals include La, nd, er, sm, Y, common metals include Zr, mg, al.
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| CN101118378B (en) * | 2007-08-22 | 2010-08-25 | 武汉工程大学 | Preparation method of diamond surface graphics |
| CN101894797B (en) * | 2009-05-20 | 2013-08-28 | 鸿富锦精密工业（深圳）有限公司 | Manufacture method of backside illumination image sensor |
| US8088685B2 (en) * | 2010-02-09 | 2012-01-03 | Taiwan Semiconductor Manufacturing Company, Ltd. | Integration of bottom-up metal film deposition |
| GB201307321D0 (en) * | 2013-04-23 | 2013-05-29 | Element Six Ltd | Synthetic diamond optical elements |
| CN105861984B (en) * | 2016-04-12 | 2018-05-22 | 太原理工大学 | A kind of preparation method of carbon/carbon composite surface refractory oxide covering |
| CN108359942B (en) * | 2018-03-28 | 2020-07-10 | 北京师范大学 | Preparation method of wear-resistant diamond-like coating |
| CN109280882B (en) * | 2018-11-06 | 2020-06-02 | 太原理工大学 | Preparation method of diamond single crystal radiating fin |
| CN110482482B (en) * | 2019-07-24 | 2022-04-19 | 北京科技大学 | Preparation method of insulated patterned high-thermal-conductivity diamond heat dissipation device |
| CN113430498B (en) * | 2021-06-23 | 2022-11-29 | 太原理工大学 | Preparation method of high-precision diamond polishing sheet |
| CN113832430B (en) * | 2021-09-29 | 2023-09-05 | 太原理工大学 | Preparation method of diamond-based amorphous carbon-yttrium oxide gradient composite antireflection film |
| CN113960133B (en) * | 2021-10-25 | 2022-12-27 | 山东大学 | Boron-doped diamond microarray electrode loaded by metal nanosheet, preparation method thereof and application of boron-doped diamond microarray electrode in glucose sensor |
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| 关于CVD金刚石表面图形化的研究进展;满卫东;谢鹏;吴宇琼;孙蕾;汪建华;;真空与低温(02);全文 * |
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