CN115491045A - Self-healing metalized film capacitor dip-sealing wax - Google Patents

Self-healing metalized film capacitor dip-sealing wax Download PDF

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Publication number
CN115491045A
CN115491045A CN202210926392.9A CN202210926392A CN115491045A CN 115491045 A CN115491045 A CN 115491045A CN 202210926392 A CN202210926392 A CN 202210926392A CN 115491045 A CN115491045 A CN 115491045A
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China
Prior art keywords
wax
healing
self
asphalt
film capacitor
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Pending
Application number
CN202210926392.9A
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Chinese (zh)
Inventor
孙月强
李毅
张炳强
杜伟平
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Jiangsu Taier New Material Co ltd
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Jiangsu Taier New Material Co ltd
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Priority to CN202210926392.9A priority Critical patent/CN115491045A/en
Publication of CN115491045A publication Critical patent/CN115491045A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/224Housing; Encapsulation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Materials Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Civil Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to a self-healing metalized film capacitor dip-sealing wax which comprises the following components in percentage by weight: base oil: 0 to 30 percent; wax: 10 to 30 percent; asphalt: 40-90%; grain refiner: 0 to 10 percent. According to the invention, the viscosity of the asphalt is reduced by adding the wax compound with low viscosity and high melting point and the base oil into the asphalt, and the high-temperature performance of the asphalt is improved, so that the defects of high sealing cost due to the use of epoxy resin and microcrystalline wax, high sealing viscosity due to the use of black glue, difficulty in filling and no high temperature resistance are overcome, and the product has the advantages of lower cost than microcrystalline wax, low shrinkage rate, low viscosity compared with black glue, easiness in filling and good high temperature resistance.

Description

Self-healing metalized film capacitor dip-sealing wax
Technical Field
The invention relates to the technical field of sealing wax, in particular to self-healing metalized film capacitor dip-sealing wax.
Background
At present, epoxy resin, microcrystalline wax or black glue (asphalt) is generally adopted to dip and seal a gap between a capacitor core and a capacitor metal shell in the production process of the self-healing metalized film capacitor, the epoxy resin, the microcrystalline wax or the black glue mainly plays roles in insulation, sealing, supporting and preventing water vapor from entering, but the epoxy resin, the microcrystalline wax or the black glue has certain problems. Firstly, the epoxy resin is used as a sealant, has the advantages of better high-temperature resistance than microcrystalline wax and black glue, but has the defects of higher cost, complex curing process and long time of the epoxy resin, and greatly reduces the production efficiency; secondly, the microcrystalline wax is used as a sealant, the curing time is shorter than that of epoxy, the cost is lower than that of epoxy resin, but the cost is still far higher than that of black glue, the shrinkage rate is higher, and the sealant is easy to crack; thirdly, the sealant made of the black glue has the advantages of low cost and the disadvantages of poor high temperature resistance, high viscosity and difficult filling.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides the self-healing metalized film capacitor dip sealing wax which has the advantages of good high-temperature resistance and corrosion resistance, moderate viscosity and low cost, and solves the defects of high dip sealing cost due to the use of epoxy resin and microcrystalline wax, high dip sealing viscosity due to the use of black glue, difficult filling and no high temperature resistance.
In order to achieve the purpose, the invention adopts the technical scheme that: the self-healing metalized film capacitor dip-sealing wax comprises the following components in percentage by weight:
Figure BDA0003779789680000021
preferably, the base oil is selected from mineral oil, vegetable oil, synthetic oil.
Preferably, the wax is selected from the group consisting of paraffin wax, microcrystalline wax, fischer-tropsch wax, animal wax, vegetable wax, and metallic soap wax.
Preferably, the asphalt is a base asphalt, including natural asphalt and petroleum asphalt.
Preferably, the grain refiner is selected from ethylene vinyl acetate copolymer, microcrystalline wax, polyethylene wax, polypropylene wax.
Preferably, the self-healing metalized film capacitor dip-sealing wax comprises the following components in percentage by weight:
Figure BDA0003779789680000022
preferably, the self-healing metalized film capacitor dip-sealing wax comprises the following components in percentage by weight:
Figure BDA0003779789680000023
Figure BDA0003779789680000031
preferably, the self-healing metalized film capacitor dip-sealing wax comprises the following components in percentage by weight:
Figure BDA0003779789680000032
the preparation process of the invention is as follows: adding the base oil into a reaction kettle, adding a grain refiner, heating until the grain refiner is completely melted, then adding wax and asphalt, cooling and taking out of the kettle after the grain refiner is completely melted, and cooling and forming.
The new material formed by organically combining the wax material and the asphalt material has the advantages of the wax material and the asphalt material and avoids the disadvantages of the wax material and the asphalt material. The application of the coupling agent improves the compatibility of the wax material and the asphalt, and improves the stability and the high-temperature resistance of the material. The introduction of the base oil can adjust the hardness degree and viscosity of the capacitor wax, and meet the use requirements of different customers.
According to the invention, the viscosity of the asphalt is reduced by adding the wax compound with low viscosity and high melting point and the base oil into the asphalt, and the high temperature performance of the asphalt is improved, so that the product has good high temperature resistance and corrosion resistance, low shrinkage rate, moderate viscosity and low cost, overcomes the defects of high immersion sealing cost due to the use of epoxy resin and microcrystalline wax, high immersion sealing viscosity due to the use of black glue, difficulty in filling and no high temperature resistance, and has the advantages of low cost and shrinkage rate compared with microcrystalline wax, easiness in filling and good high temperature resistance compared with the black glue.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes or modifications can be made by those skilled in the art after reading the contents of the present invention, and these equivalents also fall within the scope of the invention defined by the present invention.
Example 1
A self-healing metallized film capacitor sealing wax,
Figure BDA0003779789680000041
adding all base oil into a reaction kettle, adding all grain refiners, heating until the grain refiners are completely melted, then adding all wax and asphalt, cooling and taking out of the kettle after the grain refiners are completely melted, and cooling and forming.
Example 2
A self-healing metallized film capacitor dip-sealing wax:
Figure BDA0003779789680000042
example 3
Figure BDA0003779789680000051
Ethylene vinyl acetate copolymer: 2 percent.
Example 4
Figure BDA0003779789680000052
Example 5
Figure BDA0003779789680000053
Table 1 test table for product performance in examples
Figure BDA0003779789680000054
Figure BDA0003779789680000061
The self-healing metalized film capacitor dip-sealing wax has the advantages of excellent high-temperature resistance and corrosion resistance, low shrinkage, moderate viscosity and excellent comprehensive performance.
According to the invention, the wax compound with low viscosity and high melting point and the base oil are added into the asphalt to reduce the viscosity of the asphalt and improve the high-temperature performance of the asphalt, so that the defects of high cost of sealing by using epoxy resin and microcrystalline wax, high viscosity, difficult filling and no high temperature resistance caused by using black glue are overcome.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention, and is provided in the accompanying drawings. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (6)

1. The self-healing metalized film capacitor dip-sealing wax is characterized by comprising the following components in percentage by weight:
Figure FDA0003779789670000011
2. a self-healing metalized film capacitor dip wax as recited in claim 1, wherein the base oil is selected from the group consisting of mineral oil, vegetable oil, and synthetic oil.
3. A self-healing metalized film capacitor dip-sealing wax as recited in claim 1, wherein the wax is selected from the group consisting of paraffin wax, microcrystalline wax, fischer-tropsch wax, animal wax, vegetable wax, and metallic soap wax.
4. A self-healing metalized film capacitor potting wax as defined in claim 1, wherein the asphalt is a matrix asphalt including natural asphalt and petroleum asphalt.
5. A self-healing metalized film capacitor encapsulation wax as recited in claim 1, wherein the grain refiner is selected from the group consisting of ethylene vinyl acetate copolymer, microcrystalline wax, polyethylene wax, and polypropylene wax.
6. The self-healing metalized film capacitor dip-sealing wax as recited in claim 1, which comprises the following components in percentage by weight:
Figure FDA0003779789670000012
CN202210926392.9A 2022-08-03 2022-08-03 Self-healing metalized film capacitor dip-sealing wax Pending CN115491045A (en)

Priority Applications (1)

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CN202210926392.9A CN115491045A (en) 2022-08-03 2022-08-03 Self-healing metalized film capacitor dip-sealing wax

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210926392.9A CN115491045A (en) 2022-08-03 2022-08-03 Self-healing metalized film capacitor dip-sealing wax

Publications (1)

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CN115491045A true CN115491045A (en) 2022-12-20

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR730716A (en) * 1931-06-25 1932-08-20 Electric capacitor
US4812941A (en) * 1987-08-19 1989-03-14 Magnetec Corporation Capacitor and method of manufacture
CN201352497Y (en) * 2008-07-04 2009-11-25 骆家星 Dry type explosion-proof type capacitor
CN105713706A (en) * 2016-01-21 2016-06-29 泰尔精蜡(上海)有限公司 Asphalt type wire rope surface grease
CN210403513U (en) * 2019-10-09 2020-04-24 苏州工业园区苏容电气有限公司 Capacitor filled with dielectric
CN113881241A (en) * 2021-09-28 2022-01-04 南京天诗新材料科技有限公司 Low-shrinkage blended wax material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR730716A (en) * 1931-06-25 1932-08-20 Electric capacitor
US4812941A (en) * 1987-08-19 1989-03-14 Magnetec Corporation Capacitor and method of manufacture
CN201352497Y (en) * 2008-07-04 2009-11-25 骆家星 Dry type explosion-proof type capacitor
CN105713706A (en) * 2016-01-21 2016-06-29 泰尔精蜡(上海)有限公司 Asphalt type wire rope surface grease
CN210403513U (en) * 2019-10-09 2020-04-24 苏州工业园区苏容电气有限公司 Capacitor filled with dielectric
CN113881241A (en) * 2021-09-28 2022-01-04 南京天诗新材料科技有限公司 Low-shrinkage blended wax material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
佟天夫等编著, 机械工业出版社 *

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