CN1154651A - Hair cosmetic compositions - Google Patents
Hair cosmetic compositions Download PDFInfo
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- CN1154651A CN1154651A CN 95194394 CN95194394A CN1154651A CN 1154651 A CN1154651 A CN 1154651A CN 95194394 CN95194394 CN 95194394 CN 95194394 A CN95194394 A CN 95194394A CN 1154651 A CN1154651 A CN 1154651A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8194—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
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- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
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- Chemical & Material Sciences (AREA)
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Abstract
A hair care composition comprising: (a) from about 0.01 to about 3% by weight of gelling agent comprising a copolymer of methyl vinyl ether/maleic anhydride, cross-linked with C4-C16 alkadiene of hydrolysis products thereof; (b) from about 0.1% to about 10% by weight of hair fixative copolymer comprising a cationic copolymer of nonionic cellulose and diallyl dimethyl ammonium chloride; and the balance comprising a carrier suitable for application to hair. The liquid hair cosmetic products have an improved non-tacky on-hair and on-hand feel, demonstrate excellent hair styling benefits in addition to ease of brush-out.
Description
The present invention relates to hair cosmetic compositions.More particularly, the hair cosmetic compositions that the present invention relates to keeps also containing gel and hair to fix the benefit/hair conditioning polymer and " in the use " with improvement and " on sending out " sensory features except that having carding property and hair style.
Making hair keep a kind of specific shape is a kind ofly to need widely.For reaching this purpose, a kind of common method is to use hair style design, or imposes fixing composition to hair, normally gets wet or dry hair.These compositionss provide temporary transient hair fixed effect, and available water and/or shampoo are removed.Provide hair fixedly the used material of compositions of benefit generally take mousse, hair jelly, washing liquid or spray form to use.
No matter adopt hair jelly or spray, wish all that usually hair composition can keep hair style high-levelly.The hair style of hair jelly product keeps being obtained by one or more hair fixed polymers of employing usually, and for example polyvinylpyrrolidone (PVP) and PVP combine a kind of gel with the copolymer (PVP/VA) of vinyl acetate.A kind of gel commonly used is crosslinked polyacrylic acid, called after Carbomer in CTFA.When this polymer was sneaked in the hair fixing composition that contains conventional gel, they can provide suitable hair style to keep feature.But, such compositions in use with use after can be at hair and produce sticking sense on hand, also can make to cause hair feel to be hardened and natural.
Some combination that has now found that gel and hair fixed polymer can provide good hair style benefit, the uncommon sensation that be clamminess and harden relevant with conventional hair styling gel having.
Therefore there is demand to hair setting composition, said composition can provide effective hair style retentivity, possesses the hair conditioning effect, at hair and do not have on hand yet the sensation of hardening, easily flush away, can prevent to peel off and have stable product and viscosity characteristics simultaneously, and can under long-term and strict storage temperature, keep complete stability.
According to an aspect of the present invention, provide a kind of hair cosmetic compositions, comprise:
(a) about 0.01% gel to about 3% (weight), this gel contains and C
4-C
16The copolymer of methyl vinyl ether/maleic anhydride that alkadiene is crosslinked or its hydrolyzate;
(b) about 0.1% hair fixed polymer to about 10% (weight), this polymer contains the cation copolymer of non-ionic cellulose and diallyldimethylammonium chloride; With
(c) contain the counterbalance of the carrier that is applicable to hair.
Necessary component of the present invention and optional components are described below.Except as otherwise noted, all content and ratio are all based on weight.Gel
By weight, it is about 0.01% to about 3% that compositions of the present invention contains gel, is preferably about 0.05% to about 2%, and more preferably from about 0.5% to about 1.5%, most preferably from about 0.6% to about 1%.The combination of this just gel and a kind of cationic hair fixed polymer just obtains the beneficial effect of the fixing and hair conditioning of hair, and do not exist usually relevant with the hair fixing cosmetics wet sticking do to send out feel and a feel stick-slip.The gel that the present invention is suitable for comprises and C
4-C
16, preferred C
6-C
12, more preferably C
8-C
10The copolymer of methyl vinyl ether/maleic anhydride that alkadiene is crosslinked, with and hydrolyzate.The range of viscosities that gel has usually is extremely about 150,000 centipoises of about 50,000 centipoises, and preferred about 70,000 centipoises to about 100,000 centipoises (are measured with 0.5% gel in the Non-alchoholic solvents under pH7; BrookfieldRVT Spindle TE, 10rpm).
Say that with wider meaning copolymer of the present invention comprises and C
4-C
16, preferred C
6-C
12, more preferably C
8-C
10The copolymer (representing with A later on) of the crosslinked methyl vinyl ether/maleic anhydride of alkadiene (representing with B later on).Suitable polymers and their preparation are described in detail in " polymer and thickening agent " (" Polymers and Thickners ") the 108th volume, in May, 1993, p61-67, S.L.Kopolow, Y.T.Kwak and M.Helioff.These polymer contain A and B part as defined above.In preferred embodiments, B comprises C
6-C
14Alkadiene, C more preferably
6-C
12Alkadiene, C most preferably
8-C
10Alkadiene.
Preferred gel used herein is and 1, methyl vinyl ether/maleic anhydride (PVM/MA decadiene crosslinked polymer) that the 9-decadinene is crosslinked, and it obtains from ISP with Stabileze 06 (RTM).
Gel used herein preferably is taken to the neutral form of small part, so that total pH of hair jelly structure that can obtain requiring and hair cosmetic compositions.
Gel can be neutralized to content about 30% to about 100% with alkali, is preferably about 40% to about 98%, and more preferably from about 50% to about 95%.Any normally used alkali, no matter organic base or inorganic base can be used for the acid gel that neutralizes.In this hair cosmetic compositions, be suitable as the hydroxide and the amino alcohol for alkali metal and alkaline-earth metal of nertralizer.
The example that can be used for the suitable organic neutralizer in the hair cosmetic compositions of the present invention comprises: amine, particularly amino alcohol such as 2-amino-2-methyl-1, ammediol (AMPD), 2-amino-2-ethyl-1, ammediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), 2-amino-1-butanols (AB), monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), monoisopropanolamine (MIPA), diisopropanolamine (DIPA) (DIPA), triisopropanolamine (TIPA), dimethyl second sulfanilamide (DMS) and amino methyl propanol (AMP) and composition thereof.
The preferred nertralizer that adopts is potassium hydroxide or sodium hydroxide, amino methyl propanol (AMP) and triethanolamine (TEA) and composition thereof in the present composition.
Except that the concrete gel of above-mentioned detailed description, said composition also can be chosen wantonly and contain auxiliary gel, is about 0.01% to about 1%, preferred about 0.1% to about 0.5% by weight.Suitable auxiliary gel can be selected from any conventional gel, for example crosslinked acrylic copolymer, ethylene maleic anhydride copolymers or hydroxyethyl-cellulose and derivant thereof.The auxiliary gel that preferably uses is hydroxyethyl-cellulose herein.Carrier
Hair cosmetic compositions of the present invention also contains carrier, and it can be aqueous or water-free and its mixture.This can comprise those and be generally used for containing in the polymer of hair cosmetic prescription.In hair cosmetic compositions, the content of carrier is generally about 70% to about 99.89%, preferred about 78% to about 99.5% by weight.More preferably, in composition total weight, the content of carrier about 80% to 99%.
The organic solvent that is applicable to thing carrier combined according to the invention comprises C
1-C
6Alkanol, carbitol, acetone and their mixture.The preferred C of the present composition
1-C
6Alkanol is C
2-C
4Single hydroxyl alcohol is ethanol, isopropyl alcohol and their mixture for example.
Preferred hair composition according to the present invention contains the water as carrier, and its content is about 70% to about 99.89% by weight, and preferred about 78% to about 99 5%, and more preferably from about 80% to about 99%.The anion hair fixed polymer
Compositions according to the present invention also contains a kind of hair fixed polymer as second kind of necessary component except that containing gel.This hair fixed polymer is preferably dissolved in the gel copolymer or is scattered in the cosmetic hair carrier with colloid.
The preferred hair fixed polymer component of hair cosmetic compositions of the present invention contains the cation copolymer of hydroxyethyl-cellulose and diallyldimethylammonium chloride, it is called after Polyquatemium 4 in CTFA, and is sold with trade name CelquatL200 (RTM) and Celquat H100 (RTM) by National Starch and Chemical Ltd..
With composition weight meter, the content of hair fixed polymer is about 0.1% to about 10%, preferred about 0.3% to 8%, more preferably from about 0.5% to about 6%, most preferably from about 0.8% to about 3%.In the compositions of the present invention, the weight ratio scope of gel and hair fixed polymer is about 10: 1 to about 1: 10.
Other hair fixed polymer that can use herein with above-mentioned material comprises any polymer that can be dissolved in or be scattered in the hair cosmetic carrier with colloid.(25 ℃ and 101.3kPa (latm)) measures dissolubility and dispersion under ambient temperature and pressure.These polymer can be cationic or non-ionic.The molecular weight ranges of the copolymer of Shi Yonging is about 1,000 to about 5,000,000 herein, and preferred about 50,000 to about 4,000,000, and more preferably from about 100,000 to about 3,000,000, most preferably from about 500,000 to about 2,000,000.
In addition, cation and non-ionic resin can followingly describe in detail and be utilized.The polycation hair conditioning polymer resin of Shi Yonging is as described below herein.Describe for the purpose of the polymer for convenient, the monomeric unit in the polymer can refer to the monomer of polymer-derived herein.Cationic monomer can be derived from the polymerizable cationic initial monomers, or polymerisable non-ionic monomer, and the latter can be at the polymerization post-modification for having cationic feature.
These cation unsaturated monomers are with the cationic form polymerization, and perhaps, they can be with its precursor form polymerization, are modified as cationicly then, for example use quaternizing agent (as single halogenated acetic acids ethyl ester, dimethyl sulfate etc.).The preferred cation monomer comprises dimethyl aminoethyl methacrylate, quaternised dimethyl aminoethyl methacrylate, diallyldimethylammonium chloride, vinyl imidazole quaternary ammonium monomer and composition thereof.
The representative example of non-ionic monomer is C
1-C
24The acrylic or methacrylic acid esters of alcohol, alcohol wherein can be for as methanol, ethanol, the 1-propanol, the 2-propanol, the 1-butanols, 2-methyl isophthalic acid-propanol, the 1-amylalcohol, the 2-amylalcohol, the 3-amylalcohol, 2-methyl-1-butene alcohol, 1-methyl isophthalic acid-butanols, 3-methyl isophthalic acid-butanols, 1-methyl-1-pentene alcohol, 2-methyl-1-pentene alcohol, 3-methyl-1-pentene alcohol, the tert-butyl alcohol, Hexalin, 2-ethyl-1-butanols, the 3-enanthol, benzylalcohol, sec-n-octyl alcohol, 6-methyl isophthalic acid-enanthol, 2-ethyl-1-hexanol, 3,5-dimethyl-1-hexanol, 3,5,5-trimethyl-1-hexanol, 1-decanol, the 1-dodecanol, the 1-hexadecanol, 1-octadecanol or the like has 1-24, preferred about 4-18, the alcohols of 4-12 carbon atom more preferably from about; Styrene; Chlorostyrene; Vinyl acetate such as vinyl acetate; Vinyl chloride; Vinylidene chloride; Acrylonitrile; α-Jia Jibenyixi; T-butyl styrene; Butadiene; Cyclohexadiene; Ethylene; Propylene; Vinyltoluene; Alkoxyalkyl (methyl) acrylate, for example methoxy ethyl (methyl) acrylate and butoxyethyl group (methyl) acrylate; With their mixture.Other non-ionic monomer comprises the derivant of acrylate and methacrylate, as the diacrylate of the diacrylate fat of the acrylate of the acrylate of the acrylate of the acrylate of allylic acrylate and methacrylate, cyclohexyl and methacrylate, oil base and methacrylate, benzyl and methacrylate, tetrahydrofuran base and methacrylate, ethylene glycol and dimethylacrylate, 1,3 butylene glycol and dimethylacrylate, two pyroracemamides, isobornyl (methyl) acrylate or the like.
Preferred non-ionic monomer comprises n-BMA, isobutyl methacrylate, methacrylic acid 2-Octyl Nitrite, methyl methacrylate, tert-butyl acrylate, metering system tert-butyl acrylate and their mixture.
The representative of polarity non-ionic monomer comprises: the alcohol of acrylamide, N,N-DMAA, Methacrylamide, N tert butyl acrylamide, methacrylonitrile, acrylamide, acrylate (C for example
2-C
6The alcohol of acrylate is as 2-(Acryloyloxy)ethanol, Hydroxypropyl acrylate), hydroxyethyl methylacrylate, Hydroxypropyl methacrylate, vinyl pyrrolidone, vinyl Ether such as methyl vinyl ether, acyl group lactone and vinylpyridine, 1-propenol-3, vinyl alcohol and caprolactam.
Preferred polycationic polymer resin used herein comprises: the copolymer of the homopolymer of cationic guar gum, cationic polysaccharide, dimethyl diallyl ammonium chloride, dimethyl diallyl ammonium chloride and acrylamide; The acrylate of the functional homopolymer of cation amino and derived from propylene acid and/or methacrylic acid, the particularly acrylate of alkyl amino alkyl and methacrylate monomer such as dimethyl list ethyl and methacrylate, polyalkylene imine and ethyoxyl polyalkylene imine, vinyl imidazole drone salt/vinyl pyrrolidone quaternary copolymer and their mixture.
Auxiliary hair fixed polymer mixes Polyquaternium 4, and its content about by weight 0.01% is to about 10%, preferred about 0.15% to about 5%.Polyquat 4 has certain value with auxiliary hair fixed polymer to good sense, especially to the problem of peeling off.
The present composition can be mixed with the retained type hair cosmetic compositions, for example hair jelly or hair cream.The preparation method of hair cosmetic compositions of the present invention will describe in detail in an embodiment.
Hair cosmetic compositions of the present invention can contain a kind of chelating agen, and its content about by weight 0.01% is to about 5%, preferred about 0.5% to about 3% and preferred about 0.08% to about 1%.The chelating agen that is fit to the present composition comprises: edetate comprises ethylenediaminetetraacetic acid, disodiumedetate and pentaacetic acid five sodium (pentasodium pentatate).Preferred chelating agen is a tetrasodium ethylenediamine tetraacetate in the present composition.
Hair cosmetic compositions of the present invention also can contain various nonessential optional components, for example antiseptic, surfactant, block polymer, thickening agent and viscosity modifier, electrolyte, aliphatic alcohol, pH regulator agent, perfumery oil; Ultra-violet protecting agent; Hair conditioner, pearling agent, emollient; Lubricant and penetrating agent such as various lanoline component; Protein hydrolyzate and other protein derivatives; Ethylene adduct and polyoxyethylene cholesterol; Volatility and non-volatile siloxane liquid.These conventional optional components are known to those skilled in the art, as the surfactant as the spice stabilizing agent, for example cationic (as alkyl sodium sulfate); Nonionic (as the oxide of amine); Amphoteric (aliphatic secondary amine or tertiary amines derived thing); Amphoteric ion type (aliphatic quaternary amine; Phosphonium or sulfonium derivant) and fluorizated surfactant (as Zonyl FSK) (RTM), herein preferred surfactants be nonionic as cithrol, isooctadecane base polyoxyethylene (20) (isosteareth-20), Polysorbate-20, polypropylene glycol (12) Polyethylene Glycol (65) is lanolin oil (PPG-12-PEG-65), Polyethylene Glycol (40) is castor oil hydrogenated (PEG-40), anhydrous sorbitol polyoxyethylene (20) (Polysorbate 80), oil base polyoxyethylene (20) (Oleth 20) and Nonoxynol-10, the diglycollic amide of thickening agent and viscosity modifier such as long-chain fatty acid, sodium chloride, sodium sulfate and ethanol; The block polymer of oxirane and expoxy propane, Pluronic (RTM) F88 that provides as BASF Wyandotte; Antiseptic such as DMDM hydantom, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and diaxolidinyl urea; Aliphatic alcohol is 16/octadecanol (cetearyl alcohol) for example; The salt of electrolyte such as alkali metal and alkaline-earth metal; Quaternary ammonium ion and cationic amine and halogen ion; PH regulator agent such as citric acid, succinic acid, sodium hydroxide and triethanolamine; Perfumery oil is Florasynth (RTM) spice for example; Hair conditioner is for example ethylene glycol bisthioglycolate stearate and Muscovitum of panthenol/pantyl B, pearling agent for example, and ultraviolet light screener is benzophenone-4 and benzophenone-10 for example.With composition weight meter, the content of every kind of these optional materials is about 0.01% to about 5%, preferred about 0.05% to about 3%, most preferably from about 0.08% to about 1%.
Hair cosmetic compositions of the present invention provides the benefit of hair fixing of the present invention/maintenance with usual manner, and sense and the feel that are not clamminess.These methods relate to before or after the hair fixing, or all use the product drying of effective dose before and after the typing or get a head wet." effective dose " refers to a kind of like this amount, and it is considered the length of hair and quality and is enough to provide the benefit of ideal hair volume and hair style.Hair cosmetic compositions of the present invention can be applied on the hair effectively with hands, comb or brush or with sponge or " smearing ".
Following non-limiting example is used for illustrating the present invention.
Gel-Stablileze 06 (RTM)
Nertralizer-triethanolamine (TEA)
Hair fixed polymer A-Polyquaternium 4 (RTM)
Hair fixed polymer B-PVP/VA
Chelating agen-tetrasodium ethylenediamine tetraacetate
EDTA(Na)
4
Example I II III
Stabileze?06 0.6 0.4 0.3
Carbomer?980/201 - 0.2
TEA 0.6 0.6 0.3
Polyquat?4 1.0 0.5 1.0
PVP/VA - 0.5 0?5
EDTA(Na)
4 0.1 0.1 0.1
Ethanol--10.0
Water to balance to balance to balance
Being prepared as follows of this hair cosmetic compositions: (a) gel is scattered in the water, makes gel carry out hydration with the enough time (30 minutes to 1 hour), use in the suitable alkali part then and gel; (b) in an independent step, that hair fixed polymer and all inessential optional members and chelating agen is soluble in water.With pre-composition (a) and (b) mixed, the gained mixture is adjusted to ideal viscosity and pH value with remaining neutralization bases.
Above-mentioned composition can effectively keep hair style, and the hair conditioning effect is provided, and the lower feel that is clamminess is arranged and send out sense.
Claims (12)
1, a kind of hair cosmetic compositions comprises:
(a) about 0.01% gel to about 3% weight, this gel contains and C
4-C
16The copolymer of methyl vinyl ether/maleic anhydride that alkadiene is crosslinked or its hydrolyzate;
(b) about 0.1% hair fixed polymer to about 10% weight, this polymer contains the cation copolymer of non-ionic cellulose and diallyldimethylammonium chloride; With
(c) contain the counterbalance of the carrier that is applicable to hair.
2, the hair cosmetic compositions of claim 1, the range of viscosities of gel wherein are that about 70,000 centipoises to about 100,000 centipoises (are measured with 0.5% gel in the Non-alchoholic solvents at pH7 at 25 ℃; Brookfield RVT, Spindle TE, 10rpm).
3, claim 1 or 2 hair cosmetic compositions, gel content wherein are about 0.05% to about 2%, preferred about 0.5% to about 1.5%, more preferably from about 0.6% to about 1.0% by weight.
4, each hair cosmetic compositions in the claim 1 to 3, gel wherein can be neutralized to content about 30% to about 95% with alkali, and preferred about 40% to about 80%, and more preferably from about 50% to about 60%.
5, the hair cosmetic compositions of claim 4, alkali wherein are selected from the hydroxide of alkali metal, alkaline-earth metal and ammonium and amino alcohol and composition thereof, are selected from triethanolamine (TEA), sodium hydroxide and composition thereof especially.
6, each hair cosmetic compositions in the claim 1 to 5, the weight average molecular weight range of cation copolymer wherein are about 1,000 to about 5,000,000.
7, each hair cosmetic compositions in the claim 1 to 6, cation copolymer wherein contains the copolymer of hydroxyethyl-cellulose and diallyldimethylammonium chloride.
8, each hair cosmetic compositions in the claim 1 to 7, hair fixed polymer wherein content by weight are about 0.5% to about 8%, preferred about 0.8% to 6%, more preferably from about 1% to about 3%.
9, each hair cosmetic compositions in the claim 1 to 8, the weight ratio scope of gel wherein and hair fixed polymer are about 10: 1 to about 1: 10.
10, each hair cosmetic compositions in the claim 1 to 9, carrier system wherein contain water and are selected from C
1-C
6The optional organic solvent of alkanol, glycol, many alcohol, carbitol, acetone and composition thereof.
11, each hair cosmetic compositions in the claim 1 to 10, gel co-polymer cross-linking agent wherein is for being selected from C
4-C
16Alkadiene, preferred C
6-C
14Alkadiene, more preferably C
6-C
12Alkadiene, most preferably C
8-C
10Alkadiene is as 1,9-certain herbaceous plants with big flowers diene.
12, each hair cosmetic compositions in the claim 1 to 11, gel wherein is methyl vinyl ether/maleic anhydride and 1,9-certain herbaceous plants with big flowers diene crosslinked copolymers.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9415324A GB9415324D0 (en) | 1994-07-29 | 1994-07-29 | Hair cosmetic compositions |
| GB9415324.4 | 1994-07-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1154651A true CN1154651A (en) | 1997-07-16 |
| CN1086936C CN1086936C (en) | 2002-07-03 |
Family
ID=10759083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95194394A Expired - Fee Related CN1086936C (en) | 1994-07-29 | 1995-06-30 | Hair cosmetic compositions |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0768864A4 (en) |
| JP (1) | JPH10503514A (en) |
| CN (1) | CN1086936C (en) |
| CA (1) | CA2192799A1 (en) |
| GB (1) | GB9415324D0 (en) |
| MX (1) | MX9700667A (en) |
| WO (1) | WO1996003967A1 (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714135A (en) * | 1996-03-18 | 1998-02-03 | Chesebrough-Pond' S Usa Co., Division Of Conopco, Inc. | Hair treatment compostion |
| FR2755607B1 (en) * | 1996-11-08 | 1999-01-08 | Oreal | COSMETIC COMPOSITION BASED ON FIXING POLYMER AND GELING AGENT, METHOD AND USE |
| US5945093A (en) * | 1998-04-22 | 1999-08-31 | Amway Corporation | Conditioning shampoo |
| AU771906B2 (en) * | 1999-02-19 | 2004-04-08 | Procter & Gamble Company, The | Cosmetic compositions |
| FR2833487B1 (en) * | 2001-12-18 | 2004-08-27 | Oreal | COSMETIC COMPOSITIONS COMPRISING POLYMERS WITH COMPLEMENTARY CHEMICAL FUNCTIONS |
| FR2833486B1 (en) * | 2001-12-18 | 2004-08-20 | Oreal | COSMETIC COMPOSITION FORMING A TACKANT COVER COMPRISING A NON-SILICONE SKELETON POLYMER WITH REACTIVE FUNCTIONS |
| EP2355785A4 (en) | 2008-12-09 | 2014-08-13 | Oréal Sa L | Transfer-resistant emulsion containing a surfactant |
| EP2355787A4 (en) | 2008-12-09 | 2014-08-27 | Oréal Sa L | Moisturizing and shine-imparting emulsion lip compositions |
| US8778316B2 (en) | 2008-12-11 | 2014-07-15 | L'oreal | Non-sticky, hydrating and moisturizing aqueous lip gloss composition |
| WO2010077940A2 (en) | 2008-12-16 | 2010-07-08 | Hy Si Bui | Water-insoluble reaction product of a polyamine and an oil-soluble high carbon polar modified polymer |
| WO2010074726A2 (en) | 2008-12-16 | 2010-07-01 | L'oreal S.A. | Shine-imparting hydrating and moisturizing emulsion lipstick composition |
| WO2010077887A2 (en) | 2008-12-16 | 2010-07-08 | L'oreal S.A | Transfer-resistant and long wear foundation in emulsion form containing oil absorbing powders |
| WO2010077889A2 (en) | 2008-12-16 | 2010-07-08 | L'oreal S.A. | Emulsion lipstick composition |
| JP2012532109A (en) * | 2009-06-29 | 2012-12-13 | ロレアル | Compositions containing polar modified polymers |
| BRPI1002598A2 (en) | 2009-06-29 | 2012-03-13 | L'oreal S.A. | COMPOSITION AND METHOD FOR MAKING UP EYELASHES |
| BRPI1002597A2 (en) | 2009-06-29 | 2012-03-13 | L'oreal S.A. | COMPOSITION THAT UNDERSTAND AT LEAST ONE MODIFIED POLAR POLYMER SOLUBLE IN OIL |
| BRPI1002588A2 (en) | 2009-06-29 | 2012-03-13 | L'oreal S.A. | COMPOSITION AND MAKE-UP METHOD OF A KERATINIC SUBSTRATE |
| JP2012532110A (en) * | 2009-06-29 | 2012-12-13 | ロレアル | Gel refresh cream foundation |
| BRPI1003281A2 (en) | 2009-06-29 | 2012-02-28 | L'oreal S.A. | COMPOSITION AND METHOD FOR MAKING UP A KERATINIC SUBSTRATE |
| EP2319487A1 (en) * | 2009-06-29 | 2011-05-11 | L'oreal S.A. | Refreshing cream foundation in gel form |
| BRPI1003794A2 (en) | 2009-06-29 | 2012-03-20 | L'oreal S.A. | composition and reaction product |
| US8652451B2 (en) | 2009-06-29 | 2014-02-18 | L'oreal | Composition comprising a sugar silicone surfactant and a oil-soluble polar modified polymer |
| US8647611B2 (en) | 2009-06-29 | 2014-02-11 | L'oréal | Composition containing a polyol and a reaction product |
| US8747868B2 (en) | 2010-12-30 | 2014-06-10 | L'oreal | Reaction product of a polar modified polymer and an alkoxysilane and a composition containing the reaction product |
| US10123957B2 (en) * | 2014-09-03 | 2018-11-13 | Conopco, Inc. | Transparent cosmetic and personal care compositions |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU83349A1 (en) * | 1981-05-08 | 1983-03-24 | Oreal | AEROSOL FOAM COMPOSITION BASED ON CATIONIC POLYMER AND ANIONIC POLYMER |
| US5085856A (en) * | 1990-07-25 | 1992-02-04 | Elizabeth Arden Co., Division Of Conopco, Inc. | Cosmetic water-in-oil emulsion lipstick comprising a phospholipid and glycerol fatty acid esters emulsifying system |
| FR2666014B1 (en) * | 1990-08-23 | 1994-10-28 | Oreal | COSMETIC COMPOSITION FOR HAIR CONTAINING A FILM - FORMING POLYMER AND A SILICONE INCORPORATED IN A WAX MICRODISPERSION, AND COSMETIC TREATMENT METHOD. |
| US5066481A (en) * | 1990-11-05 | 1991-11-19 | Isp Investments Inc. | Mousse hair composition |
| US5118498A (en) * | 1990-11-19 | 1992-06-02 | Isp Investments Inc. | Hair setting shampoo composition |
| US5254636A (en) * | 1992-05-28 | 1993-10-19 | Isp Investments Inc. | Rapid hydrolysis of crosslinked maleic anhydride/lower alkyl vinyl ether copolymers |
| DE4232944A1 (en) * | 1992-10-01 | 1994-04-07 | Wella Ag | Hair treatment products and methods for use |
| FR2702958B1 (en) * | 1993-03-24 | 1995-05-24 | Oreal | Cosmetic composition containing at least one nonionic surfactant of the alkylpolyglycoside and / or polyglycerolated type and at least one crosslinked copolymer of maleic anhydride / alkyl (C1-C5) vinyl ether. |
-
1994
- 1994-07-29 GB GB9415324A patent/GB9415324D0/en active Pending
-
1995
- 1995-06-30 WO PCT/US1995/008336 patent/WO1996003967A1/en not_active Application Discontinuation
- 1995-06-30 JP JP8506495A patent/JPH10503514A/en active Pending
- 1995-06-30 EP EP95925443A patent/EP0768864A4/en not_active Ceased
- 1995-06-30 CA CA002192799A patent/CA2192799A1/en not_active Abandoned
- 1995-06-30 CN CN95194394A patent/CN1086936C/en not_active Expired - Fee Related
- 1995-06-30 MX MX9700667A patent/MX9700667A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2192799A1 (en) | 1996-02-15 |
| EP0768864A1 (en) | 1997-04-23 |
| EP0768864A4 (en) | 1997-08-20 |
| MX9700667A (en) | 1997-04-30 |
| JPH10503514A (en) | 1998-03-31 |
| CN1086936C (en) | 2002-07-03 |
| GB9415324D0 (en) | 1994-09-21 |
| WO1996003967A1 (en) | 1996-02-15 |
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