CN115453369A - A fuel cell consistency prediction and fault diagnosis method - Google Patents
A fuel cell consistency prediction and fault diagnosis method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明属于燃料电池技术领域,尤其涉及一种燃料电池一致性预测及故障诊断的方法。The invention belongs to the technical field of fuel cells, in particular to a method for fuel cell consistency prediction and fault diagnosis.
背景技术Background technique
燃料电池是一种将存在于燃料与氧化剂中的化学能直接转化为电能的发电装置,常用于燃料电池发动机系统,燃料和空气分别送进燃料电池,从而快速产生电能,作为发动机的动力驱动装置,并且不会产生污染空气的硫化物等,因此燃料电池具有转化效率高、清洁无污染、室温下快速启动等优点,燃料电池发动机系统在航空航天、交通运输等领域得到了广泛的应用。A fuel cell is a power generation device that directly converts the chemical energy present in fuel and oxidant into electrical energy. It is often used in fuel cell engine systems. Fuel and air are fed into the fuel cell separately to quickly generate electrical energy as a power drive for the engine. , and will not produce sulfides that pollute the air, so fuel cells have the advantages of high conversion efficiency, clean and pollution-free, and quick start at room temperature. Fuel cell engine systems have been widely used in aerospace, transportation and other fields.
在燃料电池发动机系统日益发展的过程中,燃料电池的性能、寿命和成本成为人们日益关注的焦点,燃料电池的性能能够直接影响到燃料电池的寿命和成本,这是因为,燃料电池的运行伴随着一些列复杂的多参数高度耦合的电化学反应,不同操作参数下燃料电池的输出性能均会出现差异,因此,在测试燃料电池的性能时,需要根据燃料电池的特性设定适宜的操作参数,以此来保证燃料电池性能稳定,然而在寻找适宜操作参数的过程非常复杂,需要大量的实验测试,并且极端条件下容易造成不可逆的燃料电池性能衰减,从而影响燃料电池系统的寿命,增加维护和使用的成本。In the process of the increasing development of fuel cell engine systems, the performance, life and cost of fuel cells have become the focus of increasing attention. The performance of fuel cells can directly affect the life and cost of fuel cells. This is because the operation of fuel cells is accompanied by With a series of complex multi-parameter highly coupled electrochemical reactions, the output performance of fuel cells will vary under different operating parameters. Therefore, when testing the performance of fuel cells, it is necessary to set appropriate operating parameters according to the characteristics of fuel cells. , so as to ensure the stable performance of the fuel cell. However, the process of finding suitable operating parameters is very complicated and requires a large number of experimental tests, and it is easy to cause irreversible fuel cell performance degradation under extreme conditions, thereby affecting the life of the fuel cell system and increasing maintenance. and cost of use.
目前的大量研究中选择建立燃料电池模型进行不同操作参数下的燃料电池输出性能预测,并基于建立的燃料电池模型进行燃料电池系统的故障诊断,避免了实验测试造成的资源浪费,但是针对燃料电池模型的研究大多针对单节燃料电池或多节燃料电池电堆的平均电压,而单节燃料电池的输出性能好坏和多节燃料电池之间的一致性都能够影响到燃料电池堆的整个输出性能,并且燃料电池的输出性能影响因素除了一致性之外,还包括稳态特性和动态特性,因此仅仅研究单片电池或者多节电池之间的平均电压或者节电池之间的一致性来进行燃料电池的输出性能的预测,预测结果较为片面,同时对燃料电池系统的故障诊断也不够全面。In a large number of current studies, the fuel cell model is chosen to predict the output performance of the fuel cell under different operating parameters, and the fault diagnosis of the fuel cell system is performed based on the established fuel cell model, which avoids the waste of resources caused by the experimental test, but for the fuel cell Most of the research on the model focuses on the average voltage of a single-cell fuel cell or a multi-cell fuel cell stack, and the output performance of a single-cell fuel cell and the consistency between multiple fuel cells can affect the entire output of a fuel cell stack performance, and the factors affecting the output performance of fuel cells include steady-state characteristics and dynamic characteristics in addition to consistency, so only the average voltage between single-cell or multi-cell batteries or the consistency between cells is studied. The prediction of the output performance of the fuel cell is relatively one-sided, and the fault diagnosis of the fuel cell system is not comprehensive enough.
发明内容Contents of the invention
本发明所解决的技术问题在于提供一种燃料电池一致性预测及故障诊断的方法,以解决现有技术中通过研究单片电池或者多节电池之间的平均电压或者节电池之间的一致性来进行燃料电池的输出性能的预测,使得预测结果较为片面,同时对燃料电池系统的故障诊断也不够全面的问题。The technical problem to be solved by the present invention is to provide a method for fuel cell consistency prediction and fault diagnosis to solve the problems in the prior art by studying the average voltage between a single battery or multiple cells or the consistency between cells. To predict the output performance of the fuel cell, the prediction result is relatively one-sided, and at the same time, the fault diagnosis of the fuel cell system is not comprehensive enough.
本发明提供的基础方案:一种燃料电池一致性预测及故障诊断的方法,包括:The basic solution provided by the present invention: a method for fuel cell consistency prediction and fault diagnosis, including:
S1:预设燃料电池性能预测模型;S1: preset fuel cell performance prediction model;
S2:将设定的不同的燃料电池操作参数输入燃料电池性能预测模型,找到满足燃料电池性能预测模型的期望操作参数,并将该期望操作参数进行燃料电池测试实验,以获取满足燃料电池性能需求的不同工作点下的标准输出特征值;S2: Input the set different fuel cell operating parameters into the fuel cell performance prediction model, find the expected operating parameters that meet the fuel cell performance prediction model, and conduct fuel cell test experiments on the expected operating parameters to obtain fuel cell performance requirements that meet the requirements The standard output eigenvalues at different operating points of ;
S3:在燃料电池发动机系统运行过程中将期望操作参数作为输入,并以标准输出特征值为标准,实时将燃料电池发动机系统不同工作点的实际输出特征值和标准输出特征值根据预设的误差阈值进行比对,生成比对结果;S3: During the operation of the fuel cell engine system, the expected operating parameters are used as input, and the standard output eigenvalue is used as the standard, and the actual output eigenvalues and standard output eigenvalues of the fuel cell engine system at different operating points are calculated in real time according to the preset error The threshold value is compared to generate a comparison result;
S4:若比对结果中燃料电池发动机系统实际输出和节点压特征值的比对结果超出预设的误差阈值,则进行故障诊断。S4: If the comparison result of the actual output of the fuel cell engine system and the characteristic value of the node pressure in the comparison result exceeds a preset error threshold, perform fault diagnosis.
本发明的原理及优点在于:本申请预设的燃料电池性能预测模型,用于根据燃料电池的特性建立的预测模型,通过该燃料电池性能预测模型,将设定的不同的操作参数输入,通过不断地输入验证,以此来找到满足期望的操作参数,并定义为期望操作参数,期望操作参数不止一组,期望操作参数用于表征能够表现出燃料电池输出性能的操作参数,因此还需要将该期望操作参数进行测试实验,通过测试实验能够验证出该期望操作参数在实际应用过程中是否也能达到燃料电池节电压的输出性能需求,从而使得该期望操作参数不仅能够满足理论上的要求,还能满足实际应用的要求,并将确定好的期望操作参数在燃料电池性能预测模型中的不同工作点下的输出结果作为燃料电池的标准输出特征值,。The principle and advantages of the present invention are: the fuel cell performance prediction model preset in this application is used to establish a prediction model based on the characteristics of the fuel cell, and through the fuel cell performance prediction model, different operating parameters set are input, through Continuously input and verify to find the operating parameters that meet the expectations, and define them as expected operating parameters. There are more than one set of expected operating parameters. The expected operating parameters are used to characterize the operating parameters that can show the output performance of the fuel cell. Therefore, it is also necessary to The expected operating parameters are tested and tested to verify whether the expected operating parameters can also meet the output performance requirements of the fuel cell voltage in the actual application process, so that the expected operating parameters can not only meet the theoretical requirements, It can also meet the requirements of practical applications, and the output results of the determined expected operating parameters at different operating points in the fuel cell performance prediction model can be used as the standard output characteristic values of the fuel cell.
随后在燃料电池发动机系统运行过程中,以标准输出特征值为标准,并实时检测燃料电池发动机系统不同工作点下实际的输出特征值,跟标准输出特征值进行比对,若比对的结果中当前工作点下的实际的输出特征值跟标准输出特征值的误差超过了预设的误差阈值,那么表示当前的燃料电池工作点存在故障问题,从而能够在发生故障前提前进行故障检测,避免造成燃料电池发动机系统宕机。Then, during the operation of the fuel cell engine system, the standard output characteristic value is used as the standard, and the actual output characteristic value at different operating points of the fuel cell engine system is detected in real time, and compared with the standard output characteristic value. The error between the actual output eigenvalue at the current operating point and the standard output eigenvalue exceeds the preset error threshold, which means that there is a fault problem at the current fuel cell operating point, so that fault detection can be performed in advance before a fault occurs to avoid causing Fuel cell engine system down.
因此,本申请的优点在于,通过建立燃料电池性能预测模型和实验测试来找出能够满足燃料电池输出性能的标准输出特征值,标准输出特征值能够作为整个燃料电池发动机系统中的输出结果的评定标准,而标准输出特征值用于表征燃料电池的输出性能,因此涵盖的燃料电池特性更多,相较于针对燃料电池节电压一致性进行评定,本申请的输出性能评定范围更全面,评定指标更准确,对于故障诊断也更全面和准确。Therefore, the advantage of the present application is that, by establishing a fuel cell performance prediction model and experimental tests to find out the standard output characteristic value that can satisfy the fuel cell output performance, the standard output characteristic value can be used as the evaluation of the output result in the entire fuel cell engine system standard, and the standard output characteristic value is used to characterize the output performance of the fuel cell, so it covers more characteristics of the fuel cell. More accurate, more comprehensive and accurate for fault diagnosis.
进一步,所述S1包括:Further, the S1 includes:
S1-1:获取燃料电池输出电流在阶跃时的节电压动态特性和稳态特性,建立燃料电池节电池的性能评价指标;S1-1: Obtain the dynamic characteristics and steady-state characteristics of the fuel cell output current in a step, and establish the performance evaluation index of the fuel cell cell;
S1-2:根据燃料电池堆中多节电池的节电压的标准差和极差建立燃料电池节电压一致性评价指标;S1-2: Establish the fuel cell voltage consistency evaluation index according to the standard deviation and range of the cell voltage of multiple cells in the fuel cell stack;
S1-3:根据燃料电池节电池的性能评价指标和燃料电池节电压一致性评价指标建立燃料电池性能预测模型。S1-3: Establish a fuel cell performance prediction model based on the performance evaluation index of the fuel cell cell and the consistency evaluation index of the fuel cell voltage.
有益效果:将燃料电池的特性分为稳态特性、动态特性以及节电压一致性,通过稳态特性和动态特性能够预测评定出燃料电池节电池的性能,通过节电压一致性能够预测评定燃料电池堆的输出性能,将两者结合并进行综合判定,能够更全面的预测和评定燃料电池的输出性能。Beneficial effects: the characteristics of the fuel cell are divided into steady-state characteristics, dynamic characteristics and voltage-saving consistency, the performance of the fuel cell can be predicted and evaluated through the steady-state characteristics and dynamic characteristics, and the fuel cell can be predicted and evaluated through the consistency of the voltage saving The output performance of the fuel cell can be more comprehensively predicted and evaluated by combining the two and making a comprehensive judgment.
进一步,所述S2包括:Further, said S2 includes:
S2-1:设定多组燃料电池的操作参数,将燃料电池的操作参数作为边界条件输入燃料电池性能预测模型;S2-1: Set multiple sets of fuel cell operating parameters, and input the fuel cell operating parameters as boundary conditions into the fuel cell performance prediction model;
S2-2:根据燃料电池性能预测模型中燃料电池节电池的性能评价指标和燃料电池节电压一致性评价指标,得到燃料电池不同工作点下的稳态特性、动态特性以及节点压一致性,生成输出结果;S2-2: According to the performance evaluation index of the fuel cell cell and the consistency evaluation index of the fuel cell voltage in the fuel cell performance prediction model, the steady-state characteristics, dynamic characteristics and node voltage consistency of the fuel cell at different operating points are obtained, and the generated output result;
S2-3:将输出结果与预设的期望值进行对比,若比对结果在预设的期望值误差阈值之内,则执行S2-4,反之则重复执行S2-1至S2-3;S2-3: Comparing the output result with the preset expected value, if the comparison result is within the preset expected value error threshold, execute S2-4, otherwise, repeat S2-1 to S2-3;
S2-4:将满足期望值误差阈值的燃料电池操作参数进行燃料电池测试实验,判断实验结果是否满足燃料电池性能需求,若不满足,则重复S2-1至S2-3,若满足,则输出满足燃料电池性能需求的标准输出特征值。S2-4: Carry out a fuel cell test experiment on the fuel cell operating parameters that meet the expected value error threshold, and judge whether the experimental results meet the performance requirements of the fuel cell. If not, repeat S2-1 to S2-3. If they are satisfied, the output is satisfied. Standard output eigenvalues for fuel cell performance requirements.
有益效果:根据燃料电池性能预测模型能够有效模拟出燃料电池的稳态特性、动态特性和节电压一致性,通过输出结果判定稳态特性、动态特性和节电压一致性是否满足燃料电池的输出性能期望,得到期望操作参数,并将该期望操作参数进行实验验证是否满足燃料电池的输出性能,在满足的条件下的模型输出结果即表示燃料电池的标准输出特征值,因此通过不断地测试和验证能够获得满足燃料电池输出性能需求的操作参数。Beneficial effects: According to the fuel cell performance prediction model, the steady-state characteristics, dynamic characteristics, and voltage-saving consistency of the fuel cell can be effectively simulated, and the output results can be used to determine whether the steady-state characteristics, dynamic characteristics, and voltage-saving consistency meet the output performance of the fuel cell Expectation, get the expected operating parameters, and carry out experiments to verify whether the expected operating parameters meet the output performance of the fuel cell, and the model output results under the satisfied conditions represent the standard output characteristic value of the fuel cell, so through continuous testing and verification Operating parameters that meet fuel cell output performance requirements can be obtained.
进一步,所述燃料电池的操作参数包括燃料电池工作密度、燃料电池工作压力、燃料电池工作温度以及反应气体流量。Further, the operating parameters of the fuel cell include the working density of the fuel cell, the working pressure of the fuel cell, the working temperature of the fuel cell and the flow rate of the reaction gas.
有益效果:将燃料电池工作密度、燃料电池工作压力、燃料电池工作温度以及反应气体流量作为操作参数,能够得到在该参数条件下燃料电池输出性能差异,便于获取到燃料电池的最佳输出性能。Beneficial effects: taking the working density of the fuel cell, the working pressure of the fuel cell, the working temperature of the fuel cell and the flow rate of the reaction gas as operating parameters, the difference in the output performance of the fuel cell under the condition of the parameters can be obtained, and it is convenient to obtain the best output performance of the fuel cell.
进一步,所述S3包括:Further, the S3 includes:
S3-1:通过燃料电池性能预测模型和燃料电池测试实验得到满足燃料电池性能需求的标准输出特征值;S3-1: Through the fuel cell performance prediction model and the fuel cell test experiment, the standard output characteristic value meeting the fuel cell performance requirements is obtained;
S3-2:将期望操作参数作用在燃料电池发动机系统上;S3-2: Apply desired operating parameters to the fuel cell engine system;
S3-3:在燃料电池发动机系统运行时,将实时输出特征值与标准输出特征值进行比对;S3-3: When the fuel cell engine system is running, compare the real-time output characteristic value with the standard output characteristic value;
S3-4:若实时输出特征值与标准输出特征值的比对误差超过预设的误差阈值,则判定燃料电池发动机系统发生故障。S3-4: If the comparison error between the real-time output characteristic value and the standard output characteristic value exceeds the preset error threshold, it is determined that the fuel cell engine system is faulty.
有益效果:通过燃料电池性能预测模型能够得到满足燃料电池输出性能期望的操作参数,该操作参数即为期望操作参数,以该期望操作参数为燃料电池发动机系统的输入,那么输出结果应该与标准输出特征值的误差相差不会超过预设的误差阈值,若超过,则表明该燃料电池发动机系统存在故障,因此可以对燃料电池发动机系统的故障进行提前检测和诊断,避免在实际运行过程中出现故障导致系统宕机。Beneficial effects: the fuel cell performance prediction model can be used to obtain the operating parameters that meet the expected output performance of the fuel cell. The error difference of the characteristic value will not exceed the preset error threshold. If it exceeds, it indicates that there is a fault in the fuel cell engine system. Therefore, the fault of the fuel cell engine system can be detected and diagnosed in advance to avoid faults during actual operation. cause system downtime.
附图说明Description of drawings
图1为本发明实施例一的流程框图;Fig. 1 is a block flow diagram of Embodiment 1 of the present invention;
图2为本发明实施例一的燃料电池输出电流阶跃过程示意图;Fig. 2 is a schematic diagram of the fuel cell output current step process in Embodiment 1 of the present invention;
图3为本发明实施例一的燃料电池电化学模型图;Fig. 3 is the electrochemical model diagram of the fuel cell of Embodiment 1 of the present invention;
图4为本发明实施例一的燃料电池节电压不一致现象示意图;FIG. 4 is a schematic diagram of the phenomenon of inconsistent voltages of the fuel cells in Embodiment 1 of the present invention;
图5为本发明实施例一的燃料电池性能预测和故障诊断流程框图;Fig. 5 is a flowchart of fuel cell performance prediction and fault diagnosis according to Embodiment 1 of the present invention;
图6为本发明实施例二的燃料电池故障解决的流程框图。Fig. 6 is a block diagram of the fuel cell failure solution according to the second embodiment of the present invention.
具体实施方式detailed description
下面通过具体实施方式进一步详细说明:The following is further described in detail through specific implementation methods:
在燃料电池实际工作中,燃料电池的输出性能会由于外部条件的不同出现一定的差异,在不同的操作参数下运行时,燃料电池的输出性能会表现出不同的特性,因此为了更好的比对燃料电池在不同条件下的输出性能,需要一套能够体现燃料电池特性的性能评价指标,用以评定燃料电池输出性能的优劣,而通过对燃料电池特性的性能评价指标结果中,还能够用于对燃料电池系统的故障进行预测和诊断。In the actual work of fuel cells, the output performance of fuel cells will have certain differences due to different external conditions. When operating under different operating parameters, the output performance of fuel cells will show different characteristics. Therefore, in order to better compare For the output performance of the fuel cell under different conditions, a set of performance evaluation indicators that can reflect the characteristics of the fuel cell are needed to evaluate the pros and cons of the output performance of the fuel cell. It is used to predict and diagnose the failure of the fuel cell system.
因此本申请提供了一种燃料电池一致性预测及故障诊断的方法,具体为:Therefore, this application provides a method for fuel cell consistency prediction and fault diagnosis, specifically:
实施例一:Embodiment one:
实施例一基本如附图1和图5所示:一种燃料电池一致性预测及故障诊断的方法,包括:Embodiment 1 is basically shown in Figure 1 and Figure 5: a method for fuel cell consistency prediction and fault diagnosis, including:
S1:预设燃料电池性能预测模型;S1: preset fuel cell performance prediction model;
其中,S1包括:Among them, S1 includes:
S1-1:获取燃料电池输出电流在跃迁时的节电压动态特性和稳态特性,建立燃料电池节电池的性能评价指标;S1-1: Obtain the dynamic characteristics and steady-state characteristics of the fuel cell output current during the transition of the cell voltage, and establish the performance evaluation index of the fuel cell cell;
S1-2:根据燃料电池堆中多节电池的节电压的标准差和极差建立燃料电池节电压一致性评价指标;S1-2: Establish the fuel cell voltage consistency evaluation index according to the standard deviation and range of the cell voltage of multiple cells in the fuel cell stack;
S1-3:根据燃料电池节电池的性能评价指标和燃料电池节电压一致性评价指标建立燃料电池性能预测模型。S1-3: Establish a fuel cell performance prediction model based on the performance evaluation index of the fuel cell cell and the consistency evaluation index of the fuel cell voltage.
在现有技术的研究中,燃料电池的输出性能特性通常通过给定电流输出下燃料电池的输出电压作为表征,因此,本申请建立的燃料电池性能预测模型主要针对燃料电池的输出电压进行模型的建立;如图2所示,在本实施例中,通过研究燃料电池的输出电流在以阶跃的方式从I0增加到I1时,燃料电池的节电压会出现下冲现象,因此可以发现,当输出电流为I0时,节电压的幅值为V0;当输出电流阶跃增加至I1时,节电压出现了下冲现象,首先是节电压瞬间降低至V1,之后逐渐增大恢复至V∞,因此在这整个过程中,节电压从V0到V1的差值定义为ΔV1,表示燃料电池直流源在电流从I0阶跃至I1时电池的活化损耗、欧姆损耗、浓度损耗后剩余的电压,可以用ΔV1来表征当前条件下燃料电池的稳态特性;节电压从V1逐渐恢复至V∞的过程称之为节电压下冲的恢复过程,定义为ΔV2,表示燃料电池在损耗后通过电容、电感和内电阻逐渐恢复至稳态的过程,因此采用ΔV2表征当前条件下燃料电池的动态特性。In the research of the prior art, the output performance characteristics of the fuel cell are usually characterized by the output voltage of the fuel cell under a given current output. Therefore, the fuel cell performance prediction model established in this application is mainly aimed at the output voltage of the fuel cell. Establish; as shown in Figure 2, in the present embodiment, when the output current of fuel cell increases from I 0 to I 1 in a stepwise manner by researching, the node voltage of fuel cell can appear undershoot phenomenon, so can find , when the output current is I 0 , the amplitude of the node voltage is V 0 ; when the output current increases stepwise to I 1 , the node voltage appears an undershoot phenomenon, first the node voltage drops to V 1 instantaneously, and then gradually increases Therefore, in the whole process, the difference of the node voltage from V 0 to V 1 is defined as ΔV 1 , which represents the activation loss of the fuel cell DC source when the current steps from I 0 to I 1 , The remaining voltage after ohmic loss and concentration loss can be characterized by ΔV 1 to characterize the steady-state characteristics of the fuel cell under current conditions; the process of the node voltage gradually recovering from V 1 to V ∞ is called the recovery process of the node voltage undershoot, defined as ΔV 2 represents the process of the fuel cell gradually recovering to a steady state through capacitance, inductance and internal resistance after loss, so ΔV 2 is used to characterize the dynamic characteristics of the fuel cell under current conditions.
其中,燃料电池的稳态特性ΔV1和动态特性ΔV2的电化学模型如图3所示,燃料电池的稳态特性ΔV1计算公式具体为:Among them, the electrochemical model of the steady-state characteristic ΔV 1 and the dynamic characteristic ΔV 2 of the fuel cell is shown in Figure 3, and the calculation formula of the steady-state characteristic ΔV 1 of the fuel cell is specifically:
ΔV1=Ecell-Vact-Vohm-Vcon ΔV 1 =E cell -V act -V ohm -V con
Ecell表示能斯特电压,Vact表示活化损耗电压,Vohm表示欧姆损耗电压,Vcon表示浓度损耗电压;E cell means Nernst voltage, V act means activation loss voltage, V ohm means ohmic loss voltage, V con means concentration loss voltage;
其中:in:
其中,c1为常数,i表示燃料电池输出电流密度;Among them, c1 is a constant, and i represents the output current density of the fuel cell;
其中,Tfc表示燃料电池工作温度,表示阳极氢气分压,表示阴极氧气分压,Pca表示燃料电池阴极压力,Psat表示燃料电池饱和蒸气压;Among them, T fc represents the operating temperature of the fuel cell, is the anode hydrogen partial pressure, Indicates the cathode oxygen partial pressure, P ca indicates the cathode pressure of the fuel cell, and P sat indicates the saturated vapor pressure of the fuel cell;
b2=b11λm-b12 b 2 =b 11 λ m -b 12
其中,tm表示然连电池质子交换膜厚度,λm表示质子交换膜含水量,b1、b11、b12表示常数;Among them, t m represents the thickness of the proton exchange membrane of the battery, λ m represents the water content of the proton exchange membrane, and b 1 , b 11 , b 12 represent constants;
其中,imax表示燃料电池性能急剧下降时的电流密度,c3为常数,电阻Ract表示活化损耗,电阻Rohm表示欧姆损耗,电阻Rcon表示浓度损耗。Among them, i max represents the current density when the performance of the fuel cell drops sharply, c 3 is a constant, the resistance R act represents the activation loss, the resistance R o h m represents the ohmic loss, and the resistance R con represents the concentration loss.
燃料电池的稳态特性ΔV2的计算公式具体为:The calculation formula of the steady-state characteristic ΔV 2 of the fuel cell is specifically:
ΔV2=I×RL_para ΔV 2 =I×R L_para
其中,RL_para表示内电阻,:Among them, RL_para represents the internal resistance,:
其中,k、a2、r、a3均为常数。Among them, k, a 2 , r, and a 3 are all constants.
因此,上述的ΔV1和ΔV2在本实施例中用来表征燃料电池节电池的输出性能特性,作为单节电池的性能评价指标。Therefore, the above-mentioned ΔV 1 and ΔV 2 are used in this embodiment to characterize the output performance characteristics of the fuel cell, as the performance evaluation index of a single cell.
如图4所示,图4为实验测试时燃料电池的节电压不一致的现象,通过选用多节电池的标准差和极差来表征节电压的一致性,具体为,As shown in Figure 4, Figure 4 shows the phenomenon that the cell voltage of the fuel cell is inconsistent during the experimental test, and the consistency of the cell voltage is characterized by selecting the standard deviation and range of multiple cells, specifically,
其中燃料电池节电压的标准差Stdcell通过下式得到:The standard deviation Std cell of the fuel cell voltage is obtained by the following formula:
其中n为燃料电池电堆中燃料电池的节数,Vcell为通过巡检燃料电池节电压采集得到的每一节燃料电池节电压;Among them, n is the number of fuel cells in the fuel cell stack, and V cell is the voltage of each fuel cell obtained through inspection of the fuel cell voltage collection;
燃料电池节电压极差Rcell通过下式得到:The fuel cell voltage extreme difference R cell is obtained by the following formula:
Rcell=Max(Vcell)-Min(VCell)R cell =Max(V cell )-Min(V cell )
通过对燃料电池节电标准差和极差的综合分析,用于对燃料电池电堆节电压的一致性进行分析。Through the comprehensive analysis of the standard deviation and range of fuel cell power saving, it is used to analyze the consistency of fuel cell stack voltage.
因此,通过上述的计算模型能够得到用于表征燃料电池稳态特性的ΔV1、用于表征燃料电池动态特性的ΔV2以及用于表征燃料电池堆节电压一致性的节电压标准差和极差的燃料电池性能预测模型。Therefore, the ΔV 1 used to characterize the steady-state characteristics of the fuel cell, the ΔV 2 used to characterize the dynamic characteristics of the fuel cell, and the standard deviation and range of the cell voltage used to characterize the consistency of the fuel cell stack voltage can be obtained through the above-mentioned calculation model fuel cell performance prediction model.
S2:将设定的不同的燃料电池操作参数输入燃料电池性能预测模型,找到满足燃料电池性能预测模型的期望操作参数,并将该期望操作参数进行燃料电池测试实验,以获取满足燃料电池性能需求的不同工作点下的标准输出特征值;S2: Input the set different fuel cell operating parameters into the fuel cell performance prediction model, find the expected operating parameters that meet the fuel cell performance prediction model, and conduct fuel cell test experiments on the expected operating parameters to obtain fuel cell performance requirements that meet the requirements The standard output eigenvalues at different operating points of ;
其中,S2包括:Among them, S2 includes:
S2-1:设定多组燃料电池的操作参数,将燃料电池的操作参数作为边界条件输入燃料电池性能预测模型;S2-1: Set multiple sets of fuel cell operating parameters, and input the fuel cell operating parameters as boundary conditions into the fuel cell performance prediction model;
S2-2:根据燃料电池性能预测模型中燃料电池节电池的性能评价指标和燃料电池节电压一致性评价指标,得到燃料电池不同工作点下的稳态特性、动态特性以及节点压一致性,生成输出结果;S2-2: According to the performance evaluation index of the fuel cell cell and the consistency evaluation index of the fuel cell voltage in the fuel cell performance prediction model, the steady-state characteristics, dynamic characteristics and node voltage consistency of the fuel cell at different operating points are obtained, and the generated output result;
S2-3:将输出结果与预设的期望值进行对比,若比对结果在预设的期望值误差阈值之内,则执行S2-4,反之则重复执行S2-1至S2-3;S2-3: Comparing the output result with the preset expected value, if the comparison result is within the preset expected value error threshold, execute S2-4, otherwise, repeat S2-1 to S2-3;
S2-4:将满足期望值误差阈值的燃料电池操作参数进行燃料电池测试实验,判断实验结果是否满足燃料电池性能需求,若不满足,则重复S2-1至S2-3,若满足,则输出满足燃料电池性能需求的标准输出特征值。S2-4: Carry out a fuel cell test experiment on the fuel cell operating parameters that meet the expected value error threshold, and judge whether the experimental results meet the performance requirements of the fuel cell. If not, repeat S2-1 to S2-3. If they are satisfied, the output is satisfied. Standard output eigenvalues for fuel cell performance requirements.
在本实施例中,S2的具体实施方式为,首先选择一组燃料电池操作参数,包括燃料电池工作密度、燃料电池工作压力、燃料电池工作温度、燃料电池反应气体流量等,将操作参数作为边界条件输入燃料电池性能预测模型中,燃料电池性能预测模型跟据操作参数得到燃料电池在当前条件下的输出性能,根据模型的输出结果,结合性能评价指标,在本实施例中性能评价指标根据实验者经验选择,再确定操作参数下的输出特征值,即燃料电池的稳态特性、动态特性以及节点压一致性,与期望值进行比较,如果模型输出结果与期望值的误差在预设的期望值误差阈值内,在本实施例中为±5%,则认为当前操作参数对应的燃料电池输出性能较好,可以用于燃料电池系统,如果模型输出结果与期望值的误差超过5%,则表明当前操作参数下燃料电池的输出性能不能满足需求,需要重新涉及操作参数进行测试,直到输出性能满足条件为止,并通过燃料电池实验进行测试验证,得到满足燃料电池实际输出性能需求的操作参数和标准输出特征值。In this embodiment, the specific implementation of S2 is to first select a set of fuel cell operating parameters, including fuel cell operating density, fuel cell operating pressure, fuel cell operating temperature, fuel cell reaction gas flow rate, etc., and use the operating parameters as the boundary The conditions are input into the fuel cell performance prediction model. The fuel cell performance prediction model obtains the output performance of the fuel cell under the current conditions according to the operating parameters. According to the output results of the model, combined with the performance evaluation index, in this embodiment, the performance evaluation index is based on the experimental Then determine the output characteristic value under the operating parameters, that is, the steady-state characteristics, dynamic characteristics and node pressure consistency of the fuel cell, and compare it with the expected value. If the error between the model output result and the expected value is within the preset expected value error threshold In this embodiment, it is ±5%, then it is considered that the output performance of the fuel cell corresponding to the current operating parameter is better, and it can be used in the fuel cell system. If the error between the model output result and the expected value exceeds 5%, it indicates that the current operating parameter The output performance of the fuel cell cannot meet the requirements, and the operating parameters need to be tested again until the output performance meets the conditions, and the fuel cell experiment is used to test and verify, and the operating parameters and standard output characteristic values that meet the actual output performance requirements of the fuel cell are obtained. .
S3:在燃料电池发动机系统运行过程中将期望操作参数作为输入,并以标准输出特征值为标准,实时将燃料电池发动机系统不同工作点的实际输出特征值和标准输出特征值根据预设的误差阈值进行比对,生成比对结果;S3: During the operation of the fuel cell engine system, the expected operating parameters are used as input, and the standard output eigenvalue is used as the standard, and the actual output eigenvalues and standard output eigenvalues of the fuel cell engine system at different operating points are calculated in real time according to the preset error The threshold value is compared to generate a comparison result;
其中,S3包括:Among them, S3 includes:
S3-1:通过燃料电池性能预测模型和燃料电池测试实验得到满足燃料电池性能需求的标准输出特征值;S3-1: Through the fuel cell performance prediction model and the fuel cell test experiment, the standard output characteristic value meeting the fuel cell performance requirements is obtained;
S3-2:将期望操作参数作用在燃料电池发动机系统上;S3-2: Apply desired operating parameters to the fuel cell engine system;
S3-3:在燃料电池发动机系统运行时,将实时输出特征值与标准输出特征值进行比对;S3-3: When the fuel cell engine system is running, compare the real-time output characteristic value with the standard output characteristic value;
S3-4:若实时输出特征值与标准输出特征值的比对误差超过预设的误差阈值,则判定燃料电池发动机系统发生故障。S3-4: If the comparison error between the real-time output characteristic value and the standard output characteristic value exceeds the preset error threshold, it is determined that the fuel cell engine system is faulty.
在本实施例中,实际运行时,由于工况的复杂,不可避免地会遇到各种各样地故障,因此如何快速地进行故障检测对于燃料电池发动机系统地可靠性具有非常重要的意义。而传统的故障检测大多数都是以最低节电压为故障检测标准,即当检测到最低节电压达到某一设定值时,才认为出现故障,这种故障检测方式固然有用,但是不能够实现预判故障,即使判断故障发生,也只能采取停止系统的方式进行调试,并不能提高系统的可靠性。In this embodiment, various faults will inevitably be encountered due to complex working conditions during actual operation, so how to quickly detect faults is of great significance to the reliability of the fuel cell engine system. Most of the traditional fault detection uses the lowest node voltage as the fault detection standard, that is, when the lowest node voltage is detected to reach a certain set value, it is considered that there is a fault. This fault detection method is useful, but it cannot be realized. Prediction of faults, even if it is judged that a fault occurs, can only be debugged by stopping the system, which cannot improve the reliability of the system.
因此,根据S1中预设的燃料电池性能预测模型,可以得到燃料电池发动机系统中燃料电池的标准输出特征值,即稳态特性、动态特性以及节电压一致性,将标准输出特征值作为燃料电池发动机系统的燃料电池输出性能标准,在燃料电池发动机系统运行时,将期望操作参数作为燃料电池发动机系统中燃料电池的输入操作参数,将实时输出特征值和标准输出特征值进行比对,若比对结果中超出预设的误差阈值,在本实施例中为10%,则判定燃料燃料电池出现故障,随即进行检修和维护,因此通过提前输入能够用于故障诊断的期望操作参数,实现提前检测故障,避免因故障导致燃料电池发动机出现宕机现象提升系统的可靠性。Therefore, according to the fuel cell performance prediction model preset in S1, the standard output eigenvalues of the fuel cell in the fuel cell engine system can be obtained, that is, the steady-state characteristics, dynamic characteristics, and voltage-saving consistency, and the standard output eigenvalues can be used as fuel cell The fuel cell output performance standard of the engine system, when the fuel cell engine system is running, the expected operating parameters are used as the input operating parameters of the fuel cell in the fuel cell engine system, and the real-time output characteristic value is compared with the standard output characteristic value. If the result exceeds the preset error threshold, which is 10% in this embodiment, it is determined that the fuel cell is faulty, and repair and maintenance are carried out immediately. Therefore, early detection is realized by inputting expected operating parameters that can be used for fault diagnosis in advance Faults, avoid fuel cell engine downtime due to faults and improve system reliability.
实施例二:Embodiment two:
如图6所示,实施例二与实施例一的不同之处在于,实施例二中,还包括根据故障诊断结果判定故障等级,并根据故障等级执行相应的解决方案,具体为:As shown in Figure 6, the difference between Embodiment 2 and Embodiment 1 is that in Embodiment 2, it also includes determining the fault level according to the fault diagnosis result, and executing a corresponding solution according to the fault level, specifically:
S4:进行故障诊断时,根据实时输出特征值和标准输出特征值的比对结果,进行故障等级判定,并根据故障等级判定执行故障解决方案;S4: When performing fault diagnosis, judge the fault level according to the comparison result of the real-time output characteristic value and the standard output characteristic value, and execute the fault solution according to the judgment of the fault level;
其中,S4包括:Among them, S4 includes:
S4-1:预设三级故障误差阈值,若比对结果在预设的三级故障误差阈值内,则提高燃料电池的操作参数中的工作压力和气体流量的输入,同时对燃料电池发动机系统作出预警;S4-1: Preset the three-level fault error threshold, if the comparison result is within the preset three-level fault error threshold, increase the input of the operating pressure and gas flow in the fuel cell operating parameters, and at the same time, the fuel cell engine system give an early warning;
具体为,在S4-1中,预设三级故障误差阈值在10%-15%,若比对结果的误差在10%-15%之间,不包括15%时,则判定为三级故障,此时通过将燃料电池的操作参数中的工作压力和气体流量的输入提高至原来的120%,因此,通过提高工作压力和流量能够提升燃料电池的性能,可以预防性能持续恶化;最后向燃料电池发动机系统发出预警即可。Specifically, in S4-1, the preset third-level failure error threshold is 10%-15%, and if the error of the comparison result is between 10%-15%, excluding 15%, it is judged as a third-level failure , at this time, by increasing the input of the operating pressure and gas flow in the operating parameters of the fuel cell to 120% of the original, therefore, the performance of the fuel cell can be improved by increasing the operating pressure and flow, and continuous deterioration of performance can be prevented; The battery engine system can issue an early warning.
S4-2:预设二级故障误差阈值,若比对结果在预设的二级故障误差阈值内,则强制执行降载操作,将燃料电池的输出功率降低,同时向燃料电池发动机系统反馈故障状态;S4-2: Preset the error threshold of the secondary fault. If the comparison result is within the preset error threshold of the secondary fault, the load reduction operation will be forcibly executed, the output power of the fuel cell will be reduced, and the fault will be fed back to the fuel cell engine system state;
具体为,在本实施例中,预设的二级故障误差阈值为15%-20%,若比对结果的误差在15%-20%时,则判定燃料电池出现二级故障,通过强行执行降载操作,将燃料电池的输出功率降低至原输出功率的一半即可,因此,可以预防性能持续恶化;同时向燃料电池发动机系统反馈故障状态。Specifically, in this embodiment, the preset secondary fault error threshold is 15%-20%. If the error of the comparison result is 15%-20%, it is determined that the fuel cell has a secondary fault. The load reduction operation is to reduce the output power of the fuel cell to half of the original output power, so that the performance can be prevented from continuously deteriorating; at the same time, the fault status is fed back to the fuel cell engine system.
S4-3:预设一级故障误差阈值,若比对结果在预设的一级故障误差阈值内,则立即完成降载操作,并使燃料电池保持开路,同时锁定燃料电池发动机系统,等待故障排查完成后重新启动。S4-3: Preset the first-level fault error threshold. If the comparison result is within the preset first-level fault error threshold, the load reduction operation will be completed immediately, and the fuel cell will be kept open. At the same time, the fuel cell engine system will be locked to wait for the fault Restart after the troubleshooting is complete.
具体为,在本实施例中,预设的一级故障误差阈值为20%以上,若比对结果判定燃料电池属于一级故障,此时表明燃料电池内有严重的故障,因此需要立即对燃料电池进行降载,并进行故障排查,避免早场燃料电池发动机系统在运行时出现突然宕机现象。Specifically, in this embodiment, the preset first-level fault error threshold is more than 20%. If the comparison result determines that the fuel cell belongs to the first-level fault, it indicates that there is a serious fault in the fuel cell, so the fuel cell needs to be checked immediately. The battery is deloaded and troubleshooting is carried out to avoid sudden downtime of the fuel cell engine system during operation in the morning.
以上的仅是本发明的实施例,方案中公知的具体结构及特性等常识在此未作过多描述,所属领域普通技术人员知晓申请日或者优先权日之前发明所属技术领域所有的普通技术知识,能够获知该领域中所有的现有技术,并且具有应用该日期之前常规实验手段的能力,所属领域普通技术人员可以在本申请给出的启示下,结合自身能力完善并实施本方案,一些典型的公知结构或者公知方法不应当成为所属领域普通技术人员实施本申请的障碍。应当指出,对于本领域的技术人员来说,在不脱离本发明结构的前提下,还可以作出若干变形和改进,这些也应该视为本发明的保护范围,这些都不会影响本发明实施的效果和专利的实用性。本申请要求的保护范围应当以其权利要求的内容为准,说明书中的具体实施方式等记载可以用于解释权利要求的内容。The above is only an embodiment of the present invention, and the common knowledge such as the specific structure and characteristics known in the scheme is not described here too much. Those of ordinary skill in the art know all the common technical knowledge in the technical field to which the invention belongs before the filing date or the priority date , can know all the existing technologies in this field, and have the ability to apply conventional experimental methods before this date. Those of ordinary skill in the art can improve and implement this scheme based on their own abilities under the inspiration given by this application. Some typical The known structures or known methods should not be an obstacle for those of ordinary skill in the art to implement the present application. It should be pointed out that for those skilled in the art, under the premise of not departing from the structure of the present invention, several modifications and improvements can also be made, and these should also be regarded as the protection scope of the present invention, and these will not affect the implementation of the present invention. Effects and utility of patents. The scope of protection required by this application shall be based on the content of the claims, and the specific implementation methods and other records in the specification may be used to interpret the content of the claims.
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