CN115413270B - 超轻质石墨烯-hbn纳米颗粒气凝胶 - Google Patents
超轻质石墨烯-hbn纳米颗粒气凝胶 Download PDFInfo
- Publication number
- CN115413270B CN115413270B CN202180004941.0A CN202180004941A CN115413270B CN 115413270 B CN115413270 B CN 115413270B CN 202180004941 A CN202180004941 A CN 202180004941A CN 115413270 B CN115413270 B CN 115413270B
- Authority
- CN
- China
- Prior art keywords
- aerogel
- hbn
- temperature
- ammonia borane
- hydrocarbon polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004964 aerogel Substances 0.000 title claims abstract description 99
- 239000002105 nanoparticle Substances 0.000 title description 6
- 238000000034 method Methods 0.000 claims abstract description 48
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920000642 polymer Polymers 0.000 claims abstract description 26
- 239000002086 nanomaterial Substances 0.000 claims abstract description 20
- 239000000084 colloidal system Substances 0.000 claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 15
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims description 31
- 238000000137 annealing Methods 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 17
- 229910021389 graphene Inorganic materials 0.000 claims description 17
- 239000013043 chemical agent Substances 0.000 claims description 15
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 15
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 15
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- 150000003624 transition metals Chemical class 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- -1 polydimethylsiloxane Polymers 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 239000012466 permeate Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 6
- 230000008569 process Effects 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000010415 colloidal nanoparticle Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 229910052582 BN Inorganic materials 0.000 description 5
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000001000 micrograph Methods 0.000 description 4
- 239000010955 niobium Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000002064 nanoplatelet Substances 0.000 description 2
- 229910052758 niobium Chemical group 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- AGLSQWBSHDEAHB-UHFFFAOYSA-N azane;boric acid Chemical compound N.OB(O)O AGLSQWBSHDEAHB-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000584 environmental toxicity Toxicity 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000013017 mechanical damping Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Chemical group 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical group [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Chemical group 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/583—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/06—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
- C01B21/064—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with boron
- C01B21/0646—Preparation by pyrolysis of boron and nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/022—Carbon
- C04B14/026—Carbon of particular shape, e.g. nanotubes
- C04B14/028—Carbon aerogels
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
- C04B14/301—Oxides other than silica porous or hollow
- C04B14/302—Aerogels
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
- C04B35/528—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from carbonaceous particles with or without other non-organic components
- C04B35/532—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from carbonaceous particles with or without other non-organic components containing a carbonisable binder
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62222—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic coatings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/624—Sol-gel processing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/84—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
- C04B2235/386—Boron nitrides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5292—Flakes, platelets or plates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5454—Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/76—Crystal structural characteristics, e.g. symmetry
- C04B2235/767—Hexagonal symmetry, e.g. beta-Si3N4, beta-Sialon, alpha-SiC or hexa-ferrites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Civil Engineering (AREA)
- Nanotechnology (AREA)
- Carbon And Carbon Compounds (AREA)
- Silicon Compounds (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
超轻质气凝胶以及用于由氨硼烷和载体结构制造此类气凝胶的方法,其中所述载体结构是二维纳米结构或烃聚合物胶体。将组分混合,然后退火。所公开的气凝胶的性质可以通过控制所述载体结构与所述氨硼烷之间的比率或通过用添加剂渗透所述气凝胶来调节。
Description
相关申请的交叉引用
本申请要求2020年1月21日提交的美国专利申请第62/963,815号和2020年6月16日提交的美国专利申请第63/039,792号的权益,这两个申请据此通过引用以其整体并入。
背景技术
大多数聚合物、塑料、纺织品和木材由于其有机性质而本质上是易燃的,这使得它们容易被外部热源或火源点燃。在燃烧时,它们可以在燃烧期间释放大量的热量、烟雾和有毒气体。因此,它们对人类的安全和财产构成了巨大的威胁。因此,工业上已经开发了各种添加剂,如卤素基材料和磷基材料,将其并入聚合物中以用于解决这些问题。然而,由于在燃烧期间对环境的毒性后果和健康问题,这些常规的阻燃剂正逐步被淘汰。此外,一些环氧树脂和无机盐(例如氧化铝和硼酸盐)可以提供优异的阻燃性能,但它们具有非常差的洗涤耐久性。气凝胶可能提供了替代的前进道路。
大多数气凝胶由陶瓷材料(如二氧化硅、氧化铝和碳化物)制成,因此它们非常致密、易碎并且在极端环境应用中不灵活。二维(2D)层状纳米结构,如石墨烯、氧化石墨烯(GO)和h-BN在包括极端环境应用在内的未来技术中具有广阔的潜力,这是因为它们可以承受高温、恶劣的化学环境和腐蚀。尽管自从具有聚合物复合材料的2D层状材料基气凝胶被研究已经过去了十多年,但如差的负载传递、良好的界面工程和分散性的基本挑战仍然是这些材料的商业化需要克服的一大瓶颈。
因此,可以用于高温或恶劣的化学环境的气凝胶和用于形成气凝胶的技术是期望的。
发明内容
本文公开了来自二维层状材料和聚合物胶体的组装体的超轻质、环境友好的耐热和防火气凝胶和复合材料,以及用于合成基于2D纳米结构的超轻质的耐火气凝胶及其复合材料的方法。
用于产生气凝胶的方法通常包含至少三个步骤:(i)混合固体氨硼烷和载体结构,其中所述载体结构是(a)二维纳米结构材料或(b)烃聚合物胶体;(ii)允许所述混合物自组装以形成多个杂化颗粒;和(iii)在第一温度下退火所述多个杂化颗粒以形成所述气凝胶。
任选地,所述方法还可以包括基于所述气凝胶的目标密度(如不超过约11mg/cm3)来确定用于制备所述气凝胶的载体结构的量与所述氨硼烷的量的比率。
任选地,所述方法还可以包括通过允许至少一种化学试剂如聚二甲基硅氧烷(PDMS)渗透所述气凝胶来改变所述气凝胶的至少一种性质。
在各种实施例中,所述二维纳米结构材料是石墨烯、过渡金属二硫属化物或MXene。在各种实施例中,所述烃聚合物是聚苯乙烯。
在一些实施例中,所述载体结构是球形的。在一些实施例中,所述载体结构是非球形的。
在各种实施例中,退火包括在介于1000与1500℃之间的第一温度下提供氮。在一些实施例中,退火还包括在介于500与700℃之间提供空气。
在各种实施例中,所述杂化颗粒的平均粒径小于30μm。
第二方面涉及一种气凝胶。所述气凝胶包含多个含有二维纳米结构材料和六方氮化硼(hBN)的胶体纳米颗粒。
在各种实施例中,所述二维纳米结构材料是石墨烯、过渡金属二硫属化物或MXene。在各种实施例中,气凝胶包含至少一种另外的添加剂(如PDMS)。
在各种实施例中,二维纳米结构材料由B和N原子掺杂。
任选地,所述气凝胶可以被配置为用作涂层或用作结构部件。
附图说明
下面参照附图进一步描述本发明的实施例,其中:
图1是所公开的用于形成气凝胶的方法的简化说明。
图2是说明氧化石墨烯的百分比对所得气凝胶的密度的影响的图。
图3是氧化石墨烯和硼酸氨的杂化颗粒的扫描电子显微镜图像。
图4是hBN气凝胶的扫描电子显微镜图像。
图5是聚焦于石墨烯-hBN颗粒的扫描电子显微镜图像。
图6是说明气凝胶中的PDMS对气凝胶的密度的影响的图。
具体实施方式
可以使用至少三步法来制造有用的气凝胶。参考图1可以最好地理解这一点。
方法100的第一步是固体氨硼烷111和载体结构112的混合110。
氨硼烷在本领域中是熟知的。氨硼烷(AB)(也被称为硼氮烷(borazane))已被研究作为高能量密度的氢源。氨硼烷的合成方法是熟知的。例如,一种工艺涉及使金属硼氢化物(例如硼氢化钠)与氨盐(例如碳酸铵)在合适的溶剂(例如醚溶剂,如四氢呋喃或二噁烷)中反应,然后过滤并置于真空下以产生固体氨硼烷。在商业上可获得高纯度的氨硼烷。
载体结构将属于两种类别的材料之一:(a)二维纳米结构材料或(b)烃聚合物胶体。此类载体结构可以用于控制孔的几何形状和尺寸。
在一些实施例中,所述载体结构是球形的。在一些实施例中,载体结构是非球形的,包括但不限于立方体、杆状和星形。
通常,二维化合物的形式为单层或几层厚,即厚达10个分子层。层状材料(例如无机化合物或石墨烯)的二维晶体是该材料的单个或几个层状颗粒。
合适的二维材料的非限制性实例包括(i)石墨烯或氧化石墨烯;(ii)过渡金属二硫属化物,包括具有式MX2的那些,其中M是钼、钨或铌,并且X是硫、硒或碲,如NbSe2、MoS2、WS2、WSe2、MoTe2和(iii)很少分层的MXene(即具有少于5层的MXene),包括2-1MXene如Ti2C、(Ti0.5,Nb0.5)2C、V2C、Nb2C、Mo2C、Mo2N、Ti2N、W1.33C、Nb1.33C、Mo1.33C、Mo1.33Y0.67C;3-2MXene如Ti3C2、Ti3CN、Zr3C2、Hf3C2;4-3MXene如Ti4N3、Nb4C3、Ta4C3、V4C3、(Mo,V)4C3;5-4MXene如Mo4VC4;和双过渡金属MXene,包括2-1-2MXene,如Mo2TiC2、Cr2TiC2、Mo2ScC2;和2-2-3MXene如Mo2Ti2C3。
烃聚合物可以是任何合适的烃聚合物,包括聚苯乙烯、聚乙烯和/或聚丙烯。在使用烃聚合物的优选实施例中,烃聚合物是聚苯乙烯。
任选地,所述方法还可以包括基于气凝胶的目标密度(如不超过约50mg/cm3、不超过40mg/cm3、不超过30mg/cm3、不超过20mg/cm3或不超过11mg/cm3)来确定用于制备气凝胶的载体结构的量与氨硼烷的量的比率。如所预期的,随着用于载体结构的材料的变化,比率也必然变化。参见例如图2。在一些实施例中,所得的气凝胶的性质可以通过控制组分(例如石墨烯和氨硼烷)之间的比率来调节。
在各种实施例中,载体结构的平均粒径小于30μm。在一些实施例中,载体结构的平均粒径为≤30μm、≤25μm、≤20μm、≤15μm、≤10μm、≤5μm或≤1μm。用于测量粒径(即使是非球形颗粒)的方法是技术人员已知的。例如,一种方法提供具有给定颗粒的相同表面积的球体直径。
返回参考图1,第二步是允许120固体氨硼烷111和载体结构112混合物自组装以形成多个121杂化颗粒122。通常,如在图1中看到的,这将涉及固体氨硼烷111围绕载体结构112的每个颗粒或元件组装,因为载体结构试图将它们自身排列成某种紧凑的形式。
在各种实施例中,所述杂化颗粒的平均粒径小于30μm。在一些实施例中,杂化颗粒的平均粒径≤30μm、≤25μm、≤20μm、≤15μm、≤10μm、≤5μm或≤1μm。
应当注意,氨硼烷和载体结构应当被选择成使得在该两种组分之间存在吸引人的相互作用。例如,考虑使用氧化石墨烯和氨硼烷的系统。氧化石墨烯由于含氧基团而带负电荷,并且氨硼烷是带负电荷和带正电荷的分子。由于静电荷和其他相互作用(例如范德华力、氢键),该两种组分相互作用并形成颗粒,如在扫描电子显微镜图像中示出的(参见图3)。
第三步是退火130杂化颗粒以形成hBN气凝胶131。
退火过程可以改变通过自组装形成的孔结构。例如,氧化石墨烯是2D片,并且将其与氨硼烷混合形成球形和不规则的椭圆形结构,该结构在退火后变成球形结构。
退火过程通常涉及在大于900℃,并且优选地在介于1000与1500℃之间,如至少1000℃、1050℃、1100℃、1200℃、1300℃或1400℃,并且不超过1500℃、1400℃、1300℃、1200℃、1150℃或1100℃(包括所有子范围及其组合)的第一温度下的第一退火。
通常,第一退火过程在气体,并且优选地惰性气体如氮气的存在下进行。在一些优选的实施例中,在介于1050与1150℃之间的温度下提供氮气。
第一退火过程通常进行第一时间段,该第一时间段为至少六小时,优选地介于6至24小时,更优选地介于10至16小时,并且最优选地介于11至13小时。所需的时间基于使用的温度;退火过程将氨硼烷转化为hBN。如果时间/温度组合不足,则其将为无定形BN。在更高的温度下退火需要更少的时间来完成所需的转化和结晶。
在一个实例中,在N2气氛下,将氧化石墨烯-氨硼烷杂化组装体在1100℃(其中温度升高速率为5℃/分钟)下退火12小时,得到石墨烯-hBN气凝胶。
退火过程还可以包括在介于500与700℃之间,如至少500℃、550℃或600℃,并且不超过700℃、650℃或600℃(包括所有子范围及其组合)的第二温度下的第二退火。。通常,第二退火过程在气体的存在下进行。在优选的实施例中,使用空气。这种第二次退火通常用于hBN气凝胶合成,并且通常不用于形成具有二维纳米结构材料的气凝胶,如石墨烯-hBN气凝胶纳米颗粒合成。此处的主要目的是去除任何残留的烃聚合物胶体,例如聚苯乙烯纳米颗粒,从而获得多孔hBN。气凝胶结构。
第二退火过程通常进行第二时间段,该第二时间段介于3至12小时,优选地介于5至8小时,并且最优选约6小时。
退火过程将氨硼烷转化为六方氮化硼(hBN)。在一些实施例中,产生了hBN纳米片,并且这些hBN纳米片是多晶的。
在一些实施例中,退火过程还导致用B和/或N原子掺杂载体结构,并且特别是用于载体结构的二维纳米结构材料。
如图1所示,气凝胶131的退火部分132包含已经从氨硼烷111转化的hBN 133。
退火过程可以以不同的方式影响载体结构,这取决于用于形成载体结构的材料和退火过程的温度。在一些实施例中,例如,当使用具有高熔点的二维纳米结构材料时,气凝胶131的退火部分132(有时被称为胶体纳米颗粒)含有二维纳米结构材料134和六方氮化硼(hBN)133。在一些实施例中,例如,当使用烃聚合物胶体时,退火过程可以导致例如胶体从杂化材料解聚和消除。在这些实施例中,气凝胶131的每个退火部分132包括六方氮化硼(hBN)133和空隙134,该空隙的体积基本上等于先前由烃聚合物胶体122占据的体积。
因此,在一些实施例中,所形成的气凝胶包含hBN 133或由其组成(参见例如图4),而在其他实施例中,所形成的气凝胶包含多个胶体纳米颗粒132或由其组成,每个胶体纳米颗粒含有hBN 133和二维纳米结构材料134(参见例如图5)。
载体结构(有时被称为“模板”)可以帮助确定最终气凝胶的结构。例如,如果使用球形的聚合物胶体,则hBN结构通常将具有球形空隙。如果使用非球形的聚合物胶体,则hBN结构将具有通常在非球形形状之后形成图案的空隙。在一些实施例中,仅使用单一胶体形状,而在其他实施例中,使用胶体形状的混合物。
气凝胶通常将是高度多孔的,并且通常将具有带有纳米孔隙度的粗糙表面。
返回参考图1,任选地,方法100还可以包括通过允许140至少一种化学试剂142(如聚二甲基硅氧烷(PDMS))渗透气凝胶141来改变气凝胶的至少一种性质。也就是说,气凝胶的性能可以通过掺入渗透添加剂来调节。
气凝胶的性质通常包括物理性质如密度、机械性质如压缩强度、屈服强度、弹性/柔韧性等,以及电阻和电导率,如耐化学性或耐热性、导热性或导电性等。
在允许化学试剂渗透气凝胶之前,气凝胶可以例如在100℃的真空下脱气例如30分钟,以去除水分,以用于气凝胶与化学试剂之间的更好的润湿。渗透可以通过本领域技术人员已知的任何合适的方法完成,包括例如将气凝胶浸入化学试剂中,或者将化学试剂喷涂或以其他方式沉积在气凝胶上,然后允许毛细作用将试剂吸入气凝胶的孔中。在其他实施例中,使用真空抽吸将化学试剂抽吸到气凝胶中。
化学试剂可以包括技术人员已知的任何合适的化学试剂。优选地,化学试剂包含液体。在一些实施例中,化学试剂是硅酮或基于硅酮的聚合物。
在一些实施例中,当化学试剂渗透到气凝胶中时,气凝胶的密度受到影响。例如,如在图6中看到的,气凝胶的密度随着渗透到气凝胶中的PDMS的量的增加而增加。具体地,对于该实例,用甲苯将PDMS稀释至在甲苯中的10重量%、20重量%、40重量%和60重量%的浓度。然后将hBN气凝胶分成单独的气凝胶部分,并将每个气凝胶部分浸入稀释的PDMS溶液之一中过夜(即约12小时),然后在100℃下固化2小时。
在一些实施例中,当化学试剂渗透到气凝胶中时,气凝胶变得更加柔韧。例如,在气凝胶结构没有实质性变化(孔径的变化、结构的断裂等)的情况下,一种气凝胶无法被对折。在引入PDMS之后,气凝胶能够被对折三次,然后展开,而气凝胶结构没有实质性的变化。
在一些实施例中,仅使用单一化学试剂。在其他实施例中,引入两种或更多种化学试剂。
因此,在一些实施例中,形成的气凝胶141包括以下或者由以下组成:hBN 133或多个胶体纳米颗粒132,每个胶体纳米颗粒含有hBN 133和二维纳米结构材料134;和任选地一种或多种化学试剂142。
在各种实施例中,所述二维纳米结构材料是石墨烯、过渡金属二硫属化物或MXene。在各种实施例中,气凝胶包含至少一种另外的添加剂(如PDMS)。
在各种实施例中,胶体纳米颗粒含有聚合物(其含有二维纳米结构材料)、六方氮化硼或其组合。
如本领域中所理解的,可以对气凝胶进行额外的加工步骤。例如,气凝胶一旦形成,就可以被压缩以降低(或消除)其孔隙率。可替代地或另外地,气凝胶可以被粉末化以形成气凝胶粉末。气凝胶粉末可以随后与聚合物混合并浇铸成所需的形式(例如,形状、尺寸或图案)。在一些实施例中,将气凝胶粉末与粘合剂、溶剂或其组合混合。在一些实施例中,可以将催化剂或催化剂前体添加到气凝胶中以形成气凝胶负载的催化剂。催化剂可以包含过渡金属,例如选自钯、铑、钌、铂、镍、铜、锇等的过渡金属。在一些实施例中,这些各种技术被进一步组合(例如,将具有催化剂的气凝胶粉末分散在可以任选地含有聚合物或粘合材料的溶剂中)。
任选地,所述气凝胶可以被配置为用作涂层或用作结构部件。例如,在一些实施例中,将有机硅材料(如PDMS或原硅酸四乙酯(TEOS))引入到气凝胶中以允许气凝胶用作超轻质结构材料。在其他实施例中,将粘合剂层添加到气凝胶的一侧以允许其附着到例如热敏部件。在一些实施例中,氧化石墨烯-hBN纳米颗粒被分散在适当的溶剂中,并且被涂覆在各种表面上以用于期望的应用,如阻燃剂、太阳能吸收器、催化剂、用于能量存储的电极、水净化、热平台等。在一些实施例中,气凝胶用于机械阻尼、汽车或航空航天应用。
所公开的材料可以用于广泛的技术应用,尤其包括燃料电池、太阳能电池和Li离子电池、超级电容器、催化和催化剂载体中的能量存储和转换;吸附应用(例如,CO2、H2)、气体纯化、分离技术、药物递送、环境补救、水脱盐、纯化和分离、传感器、电子、磁性装置和热应用。此外,所公开的材料具有用于包装、汽车工业、建筑隔离、热隔离、航空航天应用(例如,高热发动机部件)和高温应用、隔音、其防火应用的潜力。
实例1
通过以下来形成hBN气凝胶:将聚苯乙烯胶体和固体氨硼烷混合,允许自组装,然后在氮气中在1100℃下退火12小时,随后在空气中在600℃下退火。所得到的hBN气凝胶为超轻质(约11mg/cm3)且多孔的。
为了说明气凝胶的耐火特性,使用了丙烷火焰炬(>1000℃)实验,其中将气凝胶暴露于丙烷火焰10分钟。在火焰暴露10分钟后,结构保持稳定且未改变(对于人眼而言)。
扫描电子显微镜(SEM)表征显示,由于PS胶体模板,hBN气凝胶的微观结构由球形孔组成。
实例2
如下形成各种石墨烯-hBN(g-hBN)气凝胶纳米颗粒。首先,将各种比率的GO和AB的混合物组合,并允许自组装,如下所示:(i)90%GO+10%AB;(ii)70%GO+30%AB;(iii)50%GO+50%AB;(iv)30%GO+70%AB;和(v)10%GO+90%AB。
在混合后,将混合样品在惰性气氛下在1100℃(5℃/分钟)下退火12小时。然后,将聚合物添加剂渗透到气凝胶结构中。特别地对于PDMS渗透到g-hBN中,将184在甲苯中稀释至所需的浓度(此处为10%至60%),然后将每种g-hBN气凝胶浸入到稀释的PDMS溶液中过夜(约12小时),然后在100℃下固化2小时。
本领域技术人员将认识到,或者能够仅使用常规实验来确定,本文描述的本发明的具体实施例的许多等同物。此类等同物旨在被所附的权利要求所涵盖。
Claims (14)
1.一种用于产生气凝胶的方法,所述方法包含:
形成固体氨硼烷和(a)二维纳米结构材料或(b)烃聚合物胶体的混合物;
允许所述混合物自组装以形成多个杂化颗粒;和
在第一温度下退火所述多个杂化颗粒以形成所述气凝胶。
2.根据权利要求1所述的方法,其中所述二维纳米结构材料是石墨烯。
3.根据权利要求1所述的方法,其中所述二维纳米结构材料是过渡金属二硫属化物或MXene。
4.根据权利要求1所述的方法,其中所述烃聚合物是聚苯乙烯。
5.根据权利要求1所述的方法,其中所述烃聚合物胶体是球形的。
6.根据权利要求1所述的方法,其中所述烃聚合物胶体是非球形的。
7.根据权利要求1所述的方法,其进一步包含基于所述气凝胶的目标密度来确定用于制备所述气凝胶的氧化物与氨硼烷的比率。
8.根据权利要求1所述的方法,其中所述第一温度在1000℃与1500℃之间。
9.根据权利要求8所述的方法,其中所述退火进一步包含将所述温度降低至500℃与700℃之间的第二温度,并且在空气中在所述第二温度下退火。
10.根据权利要求1所述的方法,其中所述杂化颗粒的平均粒径小于30μm。
11.根据权利要求1所述的方法,其进一步包含通过允许至少一种化学试剂渗透所述气凝胶来改变所述气凝胶的至少一种性质。
12.根据权利要求11所述的方法,其中所述至少一种化学试剂是聚二甲基硅氧烷。
13.根据权利要求1所述的方法,其中所述气凝胶的密度不超过11mg/cm3。
14.一种通过根据权利要求1所述的方法获得的气凝胶。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202062963815P | 2020-01-21 | 2020-01-21 | |
US62/963,815 | 2020-01-21 | ||
US202063039792P | 2020-06-16 | 2020-06-16 | |
US63/039,792 | 2020-06-16 | ||
PCT/US2021/014128 WO2021150569A2 (en) | 2020-01-21 | 2021-01-20 | Ultra-lightweight graphene-hbn nanoparticle aerogels |
Publications (2)
Publication Number | Publication Date |
---|---|
CN115413270A CN115413270A (zh) | 2022-11-29 |
CN115413270B true CN115413270B (zh) | 2024-02-13 |
Family
ID=76992689
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202180004941.0A Active CN115413270B (zh) | 2020-01-21 | 2021-01-20 | 超轻质石墨烯-hbn纳米颗粒气凝胶 |
Country Status (3)
Country | Link |
---|---|
US (1) | US20220348507A1 (zh) |
CN (1) | CN115413270B (zh) |
WO (1) | WO2021150569A2 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114288953B (zh) * | 2021-12-15 | 2022-10-25 | 同济大学 | 一种超疏水性MXene基/纤维素复合气凝胶的制备方法及应用 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7618608B1 (en) * | 2005-12-13 | 2009-11-17 | Keller Companies, Inc. | Aerogel and method of manufacturing same |
CN103232027A (zh) * | 2013-04-22 | 2013-08-07 | 南京航空航天大学 | 一种三维氮化硼泡沫及其制备方法 |
CN106629636A (zh) * | 2017-01-13 | 2017-05-10 | 河北工业大学 | 一种磺酸盐辅助低温合成多孔氮化硼的方法 |
CN106829929A (zh) * | 2017-02-20 | 2017-06-13 | 上海大学 | 一种三维氮硼共掺杂石墨烯气凝胶的制备方法 |
CN107746052A (zh) * | 2017-10-31 | 2018-03-02 | 电子科技大学 | 一种氮掺杂的石墨烯气凝胶的制备方法 |
CN108516839A (zh) * | 2018-07-03 | 2018-09-11 | 辽宁大学 | 一种氮化硼泡沫的制备方法及应用 |
CN109196139A (zh) * | 2016-01-08 | 2019-01-11 | 南洋理工大学 | 氮化硼材料及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101458846B1 (ko) * | 2004-11-09 | 2014-11-07 | 더 보드 오브 리전츠 오브 더 유니버시티 오브 텍사스 시스템 | 나노섬유 리본과 시트 및 트위스팅 및 논-트위스팅 나노섬유 방적사의 제조 및 애플리케이션 |
US7750056B1 (en) * | 2006-10-03 | 2010-07-06 | Sami Daoud | Low-density, high r-value translucent nanocrystallites |
KR101781552B1 (ko) * | 2010-06-21 | 2017-09-27 | 삼성전자주식회사 | 보론 및 질소로 치환된 그라핀 및 제조방법과, 이를 구비한 트랜지스터 |
US20120301360A1 (en) * | 2011-05-26 | 2012-11-29 | Lockheed Martin Corporation | Nanostructured aerogel-thermoelectric device, making and using the same |
US9040339B2 (en) * | 2013-10-01 | 2015-05-26 | The Pen | Practical method of producing an aerogel composite continuous thin film thermoelectric semiconductor material |
GB201413701D0 (en) * | 2014-08-01 | 2014-09-17 | Isis Innovation | Process |
GB201517795D0 (en) * | 2015-10-08 | 2015-11-25 | Univ Manchester | Aerogels |
US10807059B2 (en) * | 2018-06-13 | 2020-10-20 | City University Of Hong Kong | Method for making aerogel |
-
2021
- 2021-01-20 US US17/621,798 patent/US20220348507A1/en active Pending
- 2021-01-20 CN CN202180004941.0A patent/CN115413270B/zh active Active
- 2021-01-20 WO PCT/US2021/014128 patent/WO2021150569A2/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7618608B1 (en) * | 2005-12-13 | 2009-11-17 | Keller Companies, Inc. | Aerogel and method of manufacturing same |
CN103232027A (zh) * | 2013-04-22 | 2013-08-07 | 南京航空航天大学 | 一种三维氮化硼泡沫及其制备方法 |
CN109196139A (zh) * | 2016-01-08 | 2019-01-11 | 南洋理工大学 | 氮化硼材料及其制备方法 |
CN106629636A (zh) * | 2017-01-13 | 2017-05-10 | 河北工业大学 | 一种磺酸盐辅助低温合成多孔氮化硼的方法 |
CN106829929A (zh) * | 2017-02-20 | 2017-06-13 | 上海大学 | 一种三维氮硼共掺杂石墨烯气凝胶的制备方法 |
CN107746052A (zh) * | 2017-10-31 | 2018-03-02 | 电子科技大学 | 一种氮掺杂的石墨烯气凝胶的制备方法 |
CN108516839A (zh) * | 2018-07-03 | 2018-09-11 | 辽宁大学 | 一种氮化硼泡沫的制备方法及应用 |
Also Published As
Publication number | Publication date |
---|---|
WO2021150569A2 (en) | 2021-07-29 |
US20220348507A1 (en) | 2022-11-03 |
CN115413270A (zh) | 2022-11-29 |
WO2021150569A3 (en) | 2021-09-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Yeo et al. | Structurally controlled cellular architectures for high‐performance ultra‐lightweight materials | |
Gautam et al. | Synthesis of low-density, carbon-doped, porous hexagonal boron nitride solids | |
US10953467B2 (en) | Porous materials comprising two-dimensional nanomaterials | |
Zu et al. | Superelastic multifunctional aminosilane-crosslinked graphene aerogels for high thermal insulation, three-component separation, and strain/pressure-sensing arrays | |
Zhang et al. | Graphene-like two-dimensional nanosheets-based anticorrosive coatings: A review | |
Zhang et al. | Cellular graphene aerogel combines ultralow weight and high mechanical strength: A highly efficient reactor for catalytic hydrogenation | |
Karamikamkar et al. | In situ interface design in graphene-embedded polymeric silica aerogel with organic/inorganic hybridization | |
Zhao et al. | Amphiphilic graphene aerogel with high oil and water adsorption capacity and high contact area for interface reaction | |
Liu et al. | Superhydrophobic coatings prepared by the in situ growth of silicone nanofilaments on alkali-activated geopolymers surface | |
Aljumaily et al. | Embedded high-hydrophobic CNMs prepared by CVD technique with PVDF-co-HFP membrane for application in water desalination by DCMD | |
Uddin et al. | Effects of Pt shell thickness on self-assembly monolayer Pd@ Pt core-shell nanocrystals based hydrogen sensing | |
Habel et al. | Lightweight ultra-high-barrier liners for helium and hydrogen | |
AU2021201413A1 (en) | Graphene electrode | |
Li et al. | Three dimensional nanosuperstructures made of two-dimensional materials by design: Synthesis, properties, and applications | |
CN115413270B (zh) | 超轻质石墨烯-hbn纳米颗粒气凝胶 | |
Beckert et al. | Nitrogenated graphene and carbon nanomaterials by carbonization of polyfurfuryl alcohol in the presence of urea and dicyandiamide | |
He et al. | Molecular‐Based Design of Microporous Carbon Nanosheets | |
Baumann et al. | Atomic layer deposition of uniform metal coatings on highly porous aerogel substrates | |
Mirzaee et al. | A simple, low cost, and template-free method for synthesis of boron nitride using different precursors | |
Pagaduan et al. | Freeze-burn: fabrication of porous carbon networks via polymer-templated rapid thermal annealing | |
CN111874866A (zh) | 一种多孔陶瓷及其制备方法和应用 | |
KR101590683B1 (ko) | 그래핀을 수분산성을 갖도록 개질하는 방법 | |
Li et al. | Synthesis of nanostructured boron nitride aerogels by rapid pyrolysis of melamine diborate aerogels via induction heating: from composition adjustment to property studies | |
Ji et al. | Melt-Quenched Glass Films of Coordination Polymers as Impermeable Barrier Layers and Protective Anticorrosion Coatings | |
Wang et al. | Preparation of phenolic resin derived 3-D ordered macroporous carbon |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |