CN115368159B - Preparation method of triangular honeycomb porous ceramic material - Google Patents
Preparation method of triangular honeycomb porous ceramic material Download PDFInfo
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- CN115368159B CN115368159B CN202210983981.0A CN202210983981A CN115368159B CN 115368159 B CN115368159 B CN 115368159B CN 202210983981 A CN202210983981 A CN 202210983981A CN 115368159 B CN115368159 B CN 115368159B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0006—Honeycomb structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/063—Preparing or treating the raw materials individually or as batches
- C04B38/0635—Compounding ingredients
- C04B38/0645—Burnable, meltable, sublimable materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/063—Preparing or treating the raw materials individually or as batches
- C04B38/0635—Compounding ingredients
- C04B38/0645—Burnable, meltable, sublimable materials
- C04B38/068—Carbonaceous materials, e.g. coal, carbon, graphite, hydrocarbons
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Abstract
The invention relates to a preparation method of a triangular honeycomb porous ceramic material, which comprises the following process steps: 1) Designing a two-dimensional model of a single-layer triangle honeycomb structure, and constructing a three-dimensional model of the single-layer triangle honeycomb structure according to the two-dimensional model to obtain a single-layer triangle honeycomb structure (primary unit); 2) Stacking the three layers of primary units to obtain a three-layer triangular honeycomb structure (secondary unit); 3) Stacking the secondary units to obtain a three-dimensional model of the tubular geometric body; 4) The designed tubular three-dimensional model data are imported into a 3D printer, and the model is printed by taking ceramic slurry as a printing material; 5) And sintering the ceramic blank in a high-temperature environment to obtain the tubular triangular honeycomb porous ceramic material. The triangular honeycomb porous ceramic material prepared by the invention has improved mechanical properties, can be applied to places with more severe mechanical properties on the material, and fills the application blank of various materials in a plurality of application fields.
Description
[ field of technology ]
The invention relates to a preparation method of a porous material, in particular to a preparation method of a triangular honeycomb porous ceramic material, and belongs to the technical field of porous material manufacturing.
[ background Art ]
The porous material has the characteristics of light weight, high energy absorptivity, large specific surface area and the like due to the existence of pores inside the porous material. On the premise of meeting the structural characteristics, the structure is appropriately changed, and the application requirements can be met on the basis of meeting the mechanical property requirements.
The metal porous material is expensive and is easy to react with other substances. The organic porous material is not high-temperature resistant, and inorganic porous materials such as glass wool and the like are harmful to human bodies. Some brittle materials have the advantages of stable chemical property, high hardness, high melting point, good biocompatibility and the like, can make up the defects of the metal porous materials, and can be better suitable for certain special occasions.
However, brittle materials such as ceramic materials themselves have extremely high brittleness, which limits their use in many applications to some extent. The mechanical property of the material can be improved to a certain extent by introducing the toughening phase, the problem caused by brittleness of the material can be overcome by structural design, and a proper structure is designed, so that the required effect is particularly important on the premise of meeting the requirement of the mechanical property.
Therefore, to solve the above-mentioned problems, it is necessary to provide an innovative preparation method of triangular cellular porous ceramic materials to overcome the drawbacks of the prior art.
[ invention ]
The invention aims to provide a preparation method of a triangular honeycomb porous ceramic material, which can improve the mechanical properties of the material and is applied to places with harsher mechanical properties.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows: a preparation method of a triangular honeycomb porous ceramic material comprises the following process steps:
1) Designing a two-dimensional model of a single-layer triangle honeycomb structure, and constructing a three-dimensional model of the single-layer triangle honeycomb structure in computer model design software according to the two-dimensional model to obtain the single-layer triangle honeycomb structure (primary unit);
2) Stacking the three layers of primary units to obtain a three-layer triangular honeycomb structure (secondary unit);
3) Stacking the secondary units to obtain a three-dimensional model of the tubular geometric body;
4) The designed tubular three-dimensional model data are imported into a 3D printer, and the model is printed by taking ceramic slurry added with pore formers as a printing material;
5) And (3) sintering the ceramic blank obtained in the step (4) in a high-temperature environment to obtain the tubular triangular honeycomb porous ceramic material.
The preparation method of the triangular honeycomb porous ceramic material provided by the invention further comprises the following steps: in the step 2), the three-layer single-layer triangular honeycomb structure is subjected to geometric transformation and then combined to obtain a three-layer triangular honeycomb structure; the geometric transformation includes translation or rotation.
The preparation method of the triangular honeycomb porous ceramic material provided by the invention further comprises the following steps: in the step 2), the primary units of the second layer and the third layer are rotated by 60 degrees and 120 degrees respectively relative to the primary units of the first layer.
The preparation method of the triangular honeycomb porous ceramic material provided by the invention further comprises the following steps: in the step 3), the geometric body is prismatic, cylindrical or cubic.
The preparation method of the triangular honeycomb porous ceramic material provided by the invention further comprises the following steps: in the step 4), the pore-forming agent comprises carbon powder and starch.
The preparation method of the triangular honeycomb porous ceramic material of the invention also comprises the following steps: in the step 4), the porosity and the pore size of the model are adjusted by changing the volume fraction and the size of the pore-forming agent in the ceramic slurry; or, by controlling the volume fraction and the size of the pore-forming agent in the ceramic slurry in different printing time periods, different pore characteristics at different positions in the triangular honeycomb ceramic structure model are realized.
Compared with the prior art, the invention has the following beneficial effects:
1. the ceramic material adopted in the preparation method of the triangular honeycomb porous ceramic material can be used in more severe environments than metal porous materials and organic porous materials: the special advantages of the material are shown in the fields of corrosive fluids, high-temperature fluids, molten metals and the like, and the application blank of various materials in various application fields is filled.
2. The triangular honeycomb porous ceramic material prepared by the invention guides crack propagation through the structure when cracks are generated, realizes crack redirection, improves the mechanical property of the triangular honeycomb porous ceramic material, and makes up the defects caused by the brittleness of the brittle material. And abundant micropores exist on the surface of the material frame, and the material frame has wide application prospect in the fields of heat preservation, heat insulation, filtration and separation, catalyst carrier, biomedical treatment and the like.
[ description of the drawings ]
FIG. 1 is a two-dimensional model of a single layer triangular honeycomb structure in step 1) of the present invention.
Fig. 2 is a three-dimensional model of the single layer triangular honeycomb structure of step 1) of the present invention.
Fig. 3 is a three-dimensional model of a three-layer triangular honeycomb structure (secondary cell) of step 2) of the present invention.
FIG. 4 is a three-dimensional model of the tubular geometry of step 3) of the present invention stacked from two-level cells.
Fig. 5 is an internal structure view taken along the a-plane in fig. 4.
Fig. 6 is an internal structure view taken along the B-plane in fig. 4.
FIG. 7 is a graph showing the "pseudoplastic" mechanical properties of a tubular triangular cellular porous ceramic material made in accordance with the present invention when compressed.
[ detailed description ] of the invention
Referring to fig. 1 to 7 of the specification, the invention relates to a preparation method of a triangular honeycomb porous ceramic material, which comprises the following process steps:
1) As shown in fig. 1, a two-dimensional model of a single-layer triangular honeycomb structure was designed.
As shown in fig. 2, a three-dimensional model is constructed in computer model design software according to a two-dimensional model, so as to obtain a single-layer triangular honeycomb structure (primary unit).
2) The three-layer primary unit is stacked to obtain a three-layer triangular honeycomb structure (secondary unit). Specifically, the three-layer single-layer triangular honeycomb structure (primary unit) is subjected to geometric transformation and then combined to obtain the three-layer triangular honeycomb structure (secondary unit). The geometric transformation includes translation, rotation in either direction, or any combination thereof. In this embodiment, the primary units of the second and third layers are rotated 60 ° and 120 ° with respect to the primary units of the first layer, respectively.
3) And stacking the secondary units to obtain a three-dimensional model of the tubular geometric body. Wherein the geometry includes, but is not limited to, prismatic, cylindrical, and cubic.
4) And (3) importing the designed tubular three-dimensional model data into a 3D printer, and printing the model by taking the ceramic slurry added with the pore-forming agent as a printing material. The 3D printer extrudes the slurry with high ceramic content from the nozzle through the material extrusion process, the viscosity of the ceramic slurry is reduced along with the shearing of the extrusion process in the extrusion process, when the slurry is extruded, the shearing stress on the material is reduced, the viscosity is increased, and the extruded slurry returns to the previous pasty consistency, so that self-support is realized.
Further, the pore-forming agent includes, but is not limited to, carbon powder, starch. Meanwhile, the porosity and the pore size of the model are adjusted by changing the volume fraction and the size of the pore-forming agent in the ceramic slurry; or, by controlling the volume fraction and the size of the pore-forming agent in the ceramic slurry in different printing time periods, different pore characteristics at different positions in the triangular honeycomb ceramic structure model are realized.
5) And (3) sintering the ceramic blank obtained in the step (4) in a high-temperature environment to enable abundant micropores to exist in the interior and the surface, and finally obtaining the tubular triangular honeycomb porous ceramic material.
Referring to fig. 4-6 of the drawings, it is clearly seen that the tubular triangular cellular porous ceramic material has regular triangular "frames" within it and that each layer of frames are inter-lapped to form a triangular honeycomb structure. The triangular honeycomb structure can improve the mechanical properties to a certain extent. When a crack is generated under load, a certain unit surface is broken, and in the crack conduction process, the structure can change the crack propagation direction, prolong the crack propagation path, realize crack redirection, show the mechanical characteristic of pseudo plasticity and solve the problem of high brittleness of the material.
Reference is made to fig. 7 of the accompanying specification, which shows the "pseudo-plastic" mechanical properties exhibited by triangular honeycomb structures. Wherein peaks and valleys in the stress-strain curve represent fractures of certain elementary surfaces, the overall trend of the stress-strain curve is similar to that of plastic materials, since the structure itself can guide crack propagation.
The above embodiments are only preferred embodiments of the present invention, and are not intended to limit the present invention, but any modifications, equivalent substitutions, improvements, etc. within the spirit and principles of the present invention should be included in the scope of the present invention.
Claims (2)
1. A preparation method of a triangular honeycomb porous ceramic material is characterized by comprising the following steps of: the method comprises the following process steps:
1) Designing a two-dimensional model of a single-layer triangle honeycomb structure, and constructing a three-dimensional model of the single-layer triangle honeycomb structure in computer model design software according to the two-dimensional model to obtain a single-layer triangle honeycomb structure, namely a primary unit;
2) Stacking the three layers of primary units to obtain a three-layer triangular honeycomb structure, namely a secondary unit; the primary units of the second layer and the third layer rotate by 60 degrees and 120 degrees respectively relative to the primary units of the first layer;
3) Stacking the secondary units to obtain a three-dimensional model of the tubular geometric body;
4) The designed tubular three-dimensional model data are imported into a 3D printer, and the model is printed by taking ceramic slurry added with pore formers as a printing material;
the pore-forming agent comprises carbon powder and starch; the porosity and the pore size of the model are adjusted by changing the volume fraction and the size of the pore-forming agent in the ceramic slurry; or, by controlling the volume fraction and the size of pore-forming agents in the ceramic slurry in different printing time periods, different pore characteristics at different positions in the triangular honeycomb ceramic structure model are realized;
5) And (3) sintering the ceramic blank obtained in the step (4) in a high-temperature environment to obtain the tubular triangular honeycomb porous ceramic material.
2. The method for preparing the triangular honeycomb porous ceramic material according to claim 1, wherein: in the step 3), the geometric body is prismatic or cylindrical in shape.
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Citations (4)
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CN109095912A (en) * | 2018-09-06 | 2018-12-28 | 深圳大学 | A kind of method that 3D printing is integrated cordierite honeycomb ceramic carrier |
CN112277123A (en) * | 2020-11-02 | 2021-01-29 | 西北工业大学 | Preparation method of low-thermal-expansion high-modulus ceramic thermal metamaterial |
CN113681109A (en) * | 2021-08-30 | 2021-11-23 | 哈尔滨工业大学(威海) | Metal magnetic control electric arc additive manufacturing device and method with bionic interweaving structure |
CN216662904U (en) * | 2021-12-30 | 2022-06-03 | 辽宁省轻工科学研究院有限公司 | Honeycomb ceramic |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4815108B2 (en) * | 2003-12-26 | 2011-11-16 | イビデン株式会社 | Honeycomb structure |
JP2006289237A (en) * | 2005-04-08 | 2006-10-26 | Ibiden Co Ltd | Honeycomb structure |
US11285468B2 (en) * | 2017-11-24 | 2022-03-29 | Ngk Insulators, Ltd. | Honeycomb structure |
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Patent Citations (4)
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CN109095912A (en) * | 2018-09-06 | 2018-12-28 | 深圳大学 | A kind of method that 3D printing is integrated cordierite honeycomb ceramic carrier |
CN112277123A (en) * | 2020-11-02 | 2021-01-29 | 西北工业大学 | Preparation method of low-thermal-expansion high-modulus ceramic thermal metamaterial |
CN113681109A (en) * | 2021-08-30 | 2021-11-23 | 哈尔滨工业大学(威海) | Metal magnetic control electric arc additive manufacturing device and method with bionic interweaving structure |
CN216662904U (en) * | 2021-12-30 | 2022-06-03 | 辽宁省轻工科学研究院有限公司 | Honeycomb ceramic |
Non-Patent Citations (1)
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不同填充物三角孔蜂窝板抗弹性能数值模拟研究;侯策;《科技通报》;第33卷(第4期);第1-5页 * |
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