CN115322651A - Relief effect spraying liquid for buttons and preparation method of relief effect buttons - Google Patents
Relief effect spraying liquid for buttons and preparation method of relief effect buttons Download PDFInfo
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- CN115322651A CN115322651A CN202211066534.5A CN202211066534A CN115322651A CN 115322651 A CN115322651 A CN 115322651A CN 202211066534 A CN202211066534 A CN 202211066534A CN 115322651 A CN115322651 A CN 115322651A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/002—Pretreatement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2201/00—Polymeric substrate or laminate
- B05D2201/02—Polymeric substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2203/00—Other substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2320/00—Organic additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2502/00—Acrylic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2504/00—Epoxy polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
The invention provides a spray coating liquid with a convex pattern effect for buttons, which comprises a first paint and a second paint; the first paint comprises 100 parts by mass of epoxy resin, 20-40 parts by mass of dipropylene glycol diglycidyl ether, 50-100 parts by mass of butyl acetate and 30 parts by mass of ethylenediamine; the second paint comprises 100 parts of methacrylate, 10-30 parts of hexamethylene diisocyanate, 50-100 parts of butyl acetate and 0.05-0.5 part of zinc naphthenate. The convex pattern effect can be realized on the button by adopting the spraying liquid; the spray coating has excellent machine washing resistance and tetrachloroethylene resistance when being sprayed on the buttons, and can meet the requirements of customers; the comparison efficiency of the single working procedure of the embossed button is 70 times of that of the laser scheme, the dry-water system performance is superior, different colors can be superposed, and more abundant colors can be obtained. Compared with a laser scheme, the button wale provided by the invention is a natural random texture and has uniqueness.
Description
Technical Field
The invention belongs to the technical field of buttons, and particularly relates to a relief effect spraying liquid for buttons and a preparation method of the relief effect buttons.
Background
The button products are widely applied to clothes, shoes and hats and are common clothes accessories. Common button products in the market at present are prepared from materials such as unsaturated polyester resin, urea resin, plastic, metal, wood, oxhorn and the like, and common paint comprises visual effect paint such as bright protective film, semi-bright protective film, magnetic color paint, pearlescent paint and the like. With the change of the consumption concept of people, the pursuit of diversity requires a button with special hand feeling and embossed effect.
In the prior art, laser embossing is used, embossing needs to be carried out one by one, the processing efficiency is low, the laser time of a single button is more than 7s, the energy consumption is high, and the cost is high. Because the laser focal length is fixed, when the height difference of the front modeling of the button is larger, the relief effect deviation can occur.
Disclosure of Invention
In view of the above, the present invention provides a relief effect spray liquid for a button and a method for preparing a relief effect button, wherein the button has a relief effect.
The invention provides a spraying liquid with a convex pattern effect for buttons, which comprises a first paint and a second paint;
the first paint comprises, by mass, 100 parts of epoxy resin, 20-40 parts of dipropylene glycol diglycidyl ether, 50-100 parts of butyl acetate and 30 parts of ethylenediamine;
the second paint comprises 100 parts of methacrylate, 10-30 parts of hexamethylene diisocyanate, 50-100 parts of butyl acetate and 0.05-0.5 part of zinc naphthenate.
In the invention, the first paint in the spraying liquid comprises 100 parts of epoxy resin, 20 parts of dipropylene glycol diglycidyl ether, 50 parts of butyl acetate and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 20 parts of hexamethylene diisocyanate, 50 parts of butyl acetate and 0.5 part of zinc naphthenate.
In the invention, the first paint in the spraying liquid comprises 100 parts of epoxy resin, 25 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 25 parts of hexamethylene diisocyanate, 60 parts of butyl acetate and 0.5 part of zinc naphthenate.
In the invention, the first paint in the spraying liquid comprises 100 parts of epoxy resin, 30 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 35 parts of hexamethylene diisocyanate, 80 parts of butyl acetate and 0.5 part of zinc naphthenate.
In the present invention, the first paint is preferably prepared according to the following method:
100 parts of epoxy resin, 20-40 parts of dipropylene glycol diglycidyl ether and 50-100 parts of butyl acetate are mixed, stirred at 40-80 rpm to form a uniform resin mixed solution, then uniformly mixed with 30 parts of ethylenediamine, and kept stand for defoaming to obtain the first paint.
In the present invention, the second paint is preferably prepared according to the following method:
mixing 100 parts of methacrylate, 10-30 parts of hexamethylene diisocyanate, 50-100 parts of butyl acetate and 0.05-0.5 part of zinc naphthenate, stirring at 40-80 rpm to be in a uniform state, standing and defoaming to obtain the second paint.
The invention provides a method for preparing a button with a relief effect by adopting the spray coating liquid, which comprises the following steps:
ultrasonically cleaning a button to be treated, spraying first paint after drying, standing for 8-13 min, spraying second paint, and baking to obtain a convex pattern effect button;
the first paint and the second paint are the first paint and the second paint in the technical scheme.
In a specific embodiment, the preparation process of the relief effect button comprises the following steps: button degreasing → ultrasonic cleaning → paint spraying of the arrangement → baking.
In the invention, the button to be treated is made of unsaturated polyester resin, ox horn, shell, ox bone or plastic, but not limited to the above materials.
In the invention, the button to be treated is ultrasonically cleaned in the liquid to be treated;
the liquid to be treated comprises 100 parts of water, 15-25 parts of isopropanol amide, 5-10 parts of sodium hydroxide, 10-15 parts of trisodium phosphate and 5-6 parts of fatty alcohol-polyoxyethylene ether sodium sulfate.
In the invention, the temperature of the ultrasonic cleaning is 40-50 ℃, and the time of the ultrasonic cleaning is 10-30 min.
The invention adopts a spraying mode to form a layer of coating with a convex pattern effect on the surface of the button, and does not depend on laser, so that the button has no focal length limitation and no modeling limitation; the whole plate is used for spraying, the production efficiency is high, each plate is 30 seconds, each plate is provided with 300 buttons, and the single-process efficiency is 70 times that of a laser mode. In the invention, the thickness of the first paint for spraying is 20-200 mu m;
the thickness of the second paint sprayed is 20-200 mu m.
In the present invention, the baking is carried out in an oven or drying tunnel; the baking temperature is 70-90 ℃, and the baking time is 30-90 min.
The invention provides a spray coating liquid with a convex pattern effect for buttons, which comprises a first paint and a second paint; the first paint comprises, by mass, 100 parts of epoxy resin, 20-40 parts of dipropylene glycol diglycidyl ether, 50-100 parts of butyl acetate and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 10-30 parts of hexamethylene diisocyanate, 50-100 parts of butyl acetate and 0.05-0.5 part of zinc naphthenate. The spraying liquid can realize the convex pattern effect on the button; the spray coating has excellent machine washing resistance and tetrachloroethylene resistance when being sprayed on the buttons, and can meet the requirements of customers; the single-process contrast efficiency of the embossed button is 70 times of that of the laser scheme, the dry-water system performance is superior, different colors can be superposed, and more abundant colors can be obtained. Compared with a laser scheme, the button wale provided by the invention is a natural random texture and has uniqueness.
Drawings
FIG. 1 is a schematic view of the appearance of a relief button prepared in example 1 of the present invention;
FIG. 2 is a schematic view showing the appearance of a button prepared in comparative example 1 of the present invention.
Detailed Description
In order to further illustrate the present invention, the spray liquid for relief effect button and the method for manufacturing the relief effect button provided by the present invention will be described in detail with reference to the following examples, which should not be construed as limiting the scope of the present invention.
Example 1
1. Preparing a button pretreatment liquid, wherein the formula is as follows:
100 parts of water, 15 parts of isopropanolamide, 5 parts of sodium hydroxide, 12 parts of trisodium phosphate and 5 parts of fatty alcohol-polyoxyethylene ether sodium sulfate;
2. fully stirring the button pretreatment liquid, pouring the button pretreatment liquid into an ultrasonic generator, heating to 40 ℃, placing the button to be treated in the ultrasonic generator for 30min, and taking out to obtain the button before painting;
3. preparing a first paint, wherein the specific formula is as follows: 100 parts of epoxy resin, 20 parts of dipropylene glycol diglycidyl ether, 50 parts of butyl acetate and 30 parts of ethylenediamine;
4. preparing a second paint, wherein the specific formula is as follows: 100 parts of methacrylate, 20 parts of hexamethylene diisocyanate, 50 parts of butyl acetate and 0.5 part of zinc naphthenate;
5. spraying a first paint on the button (made of shell) before paint spraying, wherein the thickness of the paint film is 100 mu m, standing for 10min, and spraying a second paint, wherein the thickness of the paint film is 100 mu m;
6. and (3) baking the sprayed button in an oven at 90 ℃ for 60min to obtain the button with the convex pattern effect.
Example 2
1. Preparing a button pretreatment liquid, wherein the formula is as follows:
100 parts of water, 25 parts of isopropanolamide, 10 parts of sodium hydroxide, 12 parts of trisodium phosphate and 5 parts of fatty alcohol-polyoxyethylene ether sodium sulfate;
2. fully stirring the button pretreatment liquid, pouring the button pretreatment liquid into an ultrasonic generator, heating to 40 ℃, placing the button to be treated in the ultrasonic generator for 30min, and taking out the button to obtain the button before painting;
3. preparing a first paint, wherein the specific formula is as follows: 100 parts of epoxy resin, 25 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 30 parts of ethylenediamine;
4. preparing a second paint, wherein the specific formula is as follows: 100 parts of methacrylate, 25 parts of hexamethylene diisocyanate, 60 parts of butyl acetate and 0.5 part of zinc naphthenate;
5. spraying a first paint on the button (made of shell) before paint spraying, wherein the thickness of the paint film is 200 mu m, standing for 10min, and spraying a second paint, wherein the thickness of the paint film is 100 mu m;
6. and (3) baking the sprayed button in an oven at 80 ℃ for 60min to obtain the convex pattern effect button.
Example 3
1. Preparing a button pretreatment liquid, wherein the formula is as follows:
100 parts of water, 20 parts of isopropanolamide, 5 parts of sodium hydroxide, 12 parts of trisodium phosphate and 6 parts of fatty alcohol-polyoxyethylene ether sodium sulfate;
2. fully stirring the button pretreatment liquid, pouring the button pretreatment liquid into an ultrasonic generator, heating to 40 ℃, placing the button to be treated in the ultrasonic generator for 30min, and taking out to obtain the button before painting;
3. preparing a first paint, wherein the specific formula is as follows: 100 parts of epoxy resin, 30 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 30 parts of ethylenediamine;
4. preparing a second paint, wherein the specific formula is as follows: 100 parts of methacrylate, 35 parts of hexamethylene diisocyanate, 80 parts of butyl acetate and 0.5 part of zinc naphthenate;
5. spraying a first paint on the button (made of shell) before paint spraying, wherein the thickness of a paint film is 200 mu m, standing for 10min, and spraying a second paint, wherein the thickness of the paint film is 50 mu m;
6. and (3) baking the sprayed button in an oven at the temperature of 80 ℃ for 80min to obtain the convex pattern effect button.
Comparative example 1
1. Preparing a button pretreatment liquid, wherein the formula is as follows: 100 parts of water, 20 parts of isopropanolamide, 5 parts of sodium hydroxide, 12 parts of trisodium phosphate and 6 parts of fatty alcohol-polyoxyethylene ether sodium sulfate;
2. fully stirring the button pretreatment liquid, pouring the button pretreatment liquid into an ultrasonic generator, heating to 40 ℃, placing the button to be treated in the ultrasonic generator for 30min, and taking out the button to obtain the button before painting;
3. preparing a first paint, wherein the specific formula is as follows: 100 parts of epoxy resin, 30 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 50 parts of ethylenediamine;
4. preparing a second paint, wherein the specific formula is as follows: 100 parts of methacrylate, 16 parts of hexamethylene diisocyanate, 80 parts of butyl acetate and 0.5 part of zinc naphthenate;
5. spraying a first paint on the button (made of shell) before paint spraying, wherein the thickness of the paint film is 100 mu m, standing for 10min, and spraying a second paint, wherein the thickness of the paint film is 300 mu m;
6. and (3) baking the sprayed button in an oven at the temperature of 80 ℃ for 80min to obtain the button.
Comparative example 2
1. Preparing a button pretreatment liquid, wherein the formula is as follows: 100 parts of water, 20 parts of isopropanolamide, 5 parts of sodium hydroxide, 12 parts of trisodium phosphate and 6 parts of fatty alcohol-polyoxyethylene ether sodium sulfate;
2. fully stirring the button pretreatment liquid, pouring the button pretreatment liquid into an ultrasonic generator, heating to 40 ℃, placing the button to be treated in the ultrasonic generator for 30min, and taking out the button to obtain the button before painting;
3. preparing a first paint, wherein the specific formula is as follows: 100 parts of epoxy resin, 30 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 15 parts of ethylenediamine;
4. preparing a second paint, wherein the specific formula is as follows: 100 parts of methacrylate, 15 parts of hexamethylene diisocyanate, 80 parts of butyl acetate and 0.01 part of zinc naphthenate;
5. spraying a first paint on the button (made of shell) before paint spraying, wherein the thickness of a paint film is 50 mu m, standing for 10min, and spraying a second paint, wherein the thickness of the paint film is 50 mu m;
6. and (3) baking the sprayed button in an oven at the temperature of 80 ℃ for 80min to obtain the button.
The invention adopts a visual inspection mode to observe the convex pattern effect of the button.
The invention carries out performance tests such as dry cleaning, water washing, machine washing and the like on the buttons prepared in the above examples and comparative examples, and the results are shown in Table 1:
TABLE 1 results of performance test of buttons prepared in examples and comparative examples
According to the above embodiments, the present invention provides a relief effect spray coating liquid for buttons, comprising a first paint and a second paint; the first paint comprises 100 parts by mass of epoxy resin, 20-40 parts by mass of dipropylene glycol diglycidyl ether, 50-100 parts by mass of butyl acetate and 30 parts by mass of ethylenediamine; the second paint comprises 100 parts of methacrylate, 10-30 parts of hexamethylene diisocyanate, 50-100 parts of butyl acetate and 0.05-0.5 part of zinc naphthenate. The convex pattern effect can be realized on the button by adopting the spraying liquid; the spray coating has excellent machine washing resistance and tetrachloroethylene resistance when being sprayed on the buttons, and can meet the requirements of customers; the single-process contrast efficiency of the embossed button is 70 times of that of the laser scheme, the dry-water system performance is superior, different colors can be superposed, and more abundant colors can be obtained. Compared with a laser scheme, the button wale provided by the invention is a natural random texture and has uniqueness.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (10)
1. A spray liquid with convex pattern effect for buttons comprises a first paint and a second paint;
the first paint comprises, by mass, 100 parts of epoxy resin, 20-40 parts of dipropylene glycol diglycidyl ether, 50-100 parts of butyl acetate and 30 parts of ethylenediamine;
the second paint comprises 100 parts of methacrylate, 10-30 parts of hexamethylene diisocyanate, 50-100 parts of butyl acetate and 0.05-0.5 part of zinc naphthenate.
2. The relief effect spray coating liquid for buttons according to claim 1, wherein the first paint in said spray coating liquid comprises 100 parts of epoxy resin, 20 parts of dipropylene glycol diglycidyl ether, 50 parts of butyl acetate and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 20 parts of hexamethylene diisocyanate, 50 parts of butyl acetate and 0.5 part of zinc naphthenate.
3. The relief effect spray coating liquid for buttons according to claim 1, wherein the first paint in said spray coating liquid comprises 100 parts of epoxy resin, 25 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 25 parts of hexamethylene diisocyanate, 60 parts of butyl acetate and 0.5 part of zinc naphthenate.
4. The relief effect spray coating liquid for buttons according to claim 1, wherein said spray coating liquid comprises 100 parts of epoxy resin, 30 parts of dipropylene glycol diglycidyl ether, 60 parts of butyl acetate, and 30 parts of ethylenediamine; the second paint comprises 100 parts of methacrylate, 35 parts of hexamethylene diisocyanate, 80 parts of butyl acetate and 0.5 part of zinc naphthenate.
5. A method for preparing a relief effect button using the spray coating liquid of any one of claims 1 to 4, comprising the steps of:
ultrasonically cleaning a button to be treated, spraying first paint after drying, standing for 8-13 min, spraying second paint, and baking to obtain a convex pattern effect button;
the first and second paints are the first and second paints described in claim 1.
6. The method as claimed in claim 5, wherein the button to be treated is made of unsaturated polyester resin, ox horn, shell, ox bone or plastic.
7. The method according to claim 5, characterized in that the button to be treated is ultrasonically cleaned in a liquid to be treated;
the liquid to be treated comprises 100 parts of water, 15-25 parts of isopropanol amide, 5-10 parts of sodium hydroxide, 10-15 parts of trisodium phosphate and 5-6 parts of fatty alcohol-polyoxyethylene ether sodium sulfate.
8. The method according to claim 5, wherein the temperature of the ultrasonic cleaning is 40 to 50 ℃ and the time of the ultrasonic cleaning is 10 to 30min.
9. The method of claim 5, wherein the sprayed first paint has a thickness of 20 to 200 μm;
the thickness of the second paint sprayed is 20-200 mu m.
10. The method according to claim 5, wherein the baking temperature is 70-90 ℃ and the baking time is 30-90 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211066534.5A CN115322651B (en) | 2022-09-01 | 2022-09-01 | Relief effect spraying liquid for buttons and preparation method of relief effect buttons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211066534.5A CN115322651B (en) | 2022-09-01 | 2022-09-01 | Relief effect spraying liquid for buttons and preparation method of relief effect buttons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115322651A true CN115322651A (en) | 2022-11-11 |
| CN115322651B CN115322651B (en) | 2023-04-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211066534.5A Active CN115322651B (en) | 2022-09-01 | 2022-09-01 | Relief effect spraying liquid for buttons and preparation method of relief effect buttons |
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| CN (1) | CN115322651B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5147689A (en) * | 1990-02-22 | 1992-09-15 | Dai Nippon Toryo Co., Ltd. | Method for forming a coating film with a relief pattern |
| CN103194144A (en) * | 2013-04-18 | 2013-07-10 | 广东溢达纺织有限公司 | Button with hammer effect and preparation method of button |
| CN104327571A (en) * | 2014-10-22 | 2015-02-04 | 佛山市顺德区固得丽涂料有限公司 | Wrinkle paint, and preparation method and application method thereof |
| CN112280442A (en) * | 2020-10-26 | 2021-01-29 | 浙江伟星实业发展股份有限公司 | Wear-resistant acrylic matte paint with particle tiling property and preparation method and application thereof |
-
2022
- 2022-09-01 CN CN202211066534.5A patent/CN115322651B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5147689A (en) * | 1990-02-22 | 1992-09-15 | Dai Nippon Toryo Co., Ltd. | Method for forming a coating film with a relief pattern |
| CN103194144A (en) * | 2013-04-18 | 2013-07-10 | 广东溢达纺织有限公司 | Button with hammer effect and preparation method of button |
| CN104327571A (en) * | 2014-10-22 | 2015-02-04 | 佛山市顺德区固得丽涂料有限公司 | Wrinkle paint, and preparation method and application method thereof |
| CN112280442A (en) * | 2020-10-26 | 2021-01-29 | 浙江伟星实业发展股份有限公司 | Wear-resistant acrylic matte paint with particle tiling property and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郭晓静;: "湿碰湿涂装工艺在车桥上的应用" * |
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| CN115322651B (en) | 2023-04-14 |
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