CN115319031A - Light-transmitting bronze mirror and preparation method thereof - Google Patents

Light-transmitting bronze mirror and preparation method thereof Download PDF

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Publication number
CN115319031A
CN115319031A CN202210990886.3A CN202210990886A CN115319031A CN 115319031 A CN115319031 A CN 115319031A CN 202210990886 A CN202210990886 A CN 202210990886A CN 115319031 A CN115319031 A CN 115319031A
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China
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mirror
mirror body
grinding
bronze
light
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CN115319031B (en
Inventor
李卓
姜峰
王福增
江安娜
黄身桂
谭援强
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Huaqiao University
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Huaqiao University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/22Moulds for peculiarly-shaped castings
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G1/00Mirrors; Picture frames or the like, e.g. provided with heating, lighting or ventilating means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • B22C9/046Use of patterns which are eliminated by the liquid metal in the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B1/00Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B13/00Machines or devices designed for grinding or polishing optical surfaces on lenses or surfaces of similar shape on other work; Accessories therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/02Alloys based on copper with tin as the next major constituent

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Adornments (AREA)

Abstract

The invention provides a light-transmitting bronze mirror and a preparation method thereof, wherein the method comprises the following steps: firstly, designing a mirror body model, and manufacturing a mirror model according to the mirror body model; then putting the mirror body material into a crucible for heating and smelting to obtain liquid alloy, then casting the liquid alloy into the mirror model, and cooling to obtain a cast blank mirror body; and finally, sequentially carrying out mirror plane grinding and mirror surface curved surface fine grinding on the as-cast blank mirror body to obtain the light-transmitting bronze mirror. According to the invention, through reasonable design of the mirror body modeling and casting condensation process and reasonable proportion of mirror body material components, enough casting residual stress is generated in the as-cast blank mirror body, so that an energy basis is provided for the deformation difference of the mirror body in the subsequent mirror surface grinding process. After the plane grinding is finished, the rigidity of the mirror body can be reduced to a certain degree, and then the mirror body is ground into an arc shape which is beneficial to the deformation of the mirror body and the release of casting residual stress, so that the micro texture on the mirror surface is more obvious, and the light transmission effect is achieved.

Description

Light-transmitting bronze mirror and preparation method thereof
Technical Field
The invention relates to the technical field of bronze mirror manufacturing, in particular to a light-transmitting bronze mirror and a preparation method thereof.
Background
Bronze mirrors were originally introduced as sacrificial instruments in commercial generations, and the mirror making process by the time of sihan was very exquisite. The 'light-transmitting' bronze mirror appeared in this period attracts the research interests of students in ancient times and modern times, and the ancient times refer to as sun glasses or light-transmitting mirrors. The appearance of the bronze mirror is almost the same as that of a common bronze mirror, but the mirror surface is slightly convex, and patterns are cast on the back. When a light source illuminates the mirror surface of a "light transmitting" mirror, an image corresponding to the pattern on the back side of the mirror surface appears on the screen opposite the mirror surface as if the light is transmitted. In view of the peculiar phenomenon, the 'light-transmitting mirror' becomes one of the three treasures of the ancient bronze in China, which are parallel to chimes and water-spraying fish washing. A great number of scholars have extensively and deeply researched the light-transmitting bronze mirror for more than one thousand years, and the existing research data preliminarily considers that the 'light-transmitting' phenomenon is related to cooling shrinkage of mirror casting and mirror grinding, but unfortunately, the former people cannot research an accurate mirror casting and mirror grinding processing method.
At present, bronze mirrors with good light transmission effects are difficult to manufacture by the processes of casting, mirror plane grinding, mirror surface engraving, tinkle and the like. If the specific manufacturing mechanism of the light-transmitting mirror can be explored, the millennium mystery formed by the light-transmitting phenomenon is revealed, the light-transmitting mirror has higher scientific significance for the research of the light-transmitting phenomenon of the bronze mirror and a specific mirror manufacturing method, the protection of excellent traditional manufacturing technology of China can be enhanced, and the national culture recognition and culture confidence of Chinese people are improved.
Disclosure of Invention
The invention aims to provide a light-transmitting bronze mirror and a preparation method thereof, wherein the microscopic texture on the mirror surface of the prepared light-transmitting bronze mirror is more obvious through the reasonable design of the mirror body modeling and casting condensation process and the reasonable proportion of the mirror body material components, so that the light-transmitting effect is achieved.
The technical problem to be solved by the invention is realized by adopting the following technical scheme.
The invention provides a preparation method of a light-transmitting bronze mirror, which comprises the following steps:
s1, designing the shape of a mirror body, and manufacturing a mirror model according to the shape of the mirror body to obtain a mirror model;
s2, smelting and casting: putting the mirror body material into a crucible for heating and smelting to obtain liquid alloy, then casting the liquid alloy into the mirror model, and cooling to obtain a cast blank mirror body;
s3, mirror surface grinding: and sequentially carrying out mirror plane grinding and mirror surface curved surface fine grinding on the as-cast blank mirror body to obtain the light-transmitting bronze mirror.
The invention provides a light-transmitting bronze mirror which is prepared according to the preparation method.
The light-transmitting bronze mirror and the preparation method thereof have the beneficial effects that:
the invention generates enough casting residual stress in the as-cast blank mirror body through the reasonable design of the mirror body modeling and casting condensation process and the reasonable proportion of the mirror body material components, thereby providing an energy basis for the deformation difference of the mirror body in the subsequent mirror surface grinding process. The mirror grinding process includes mirror plane grinding and mirror surface curved surface finish grinding. After the plane grinding is finished, the rigidity of the mirror body can be reduced to a certain degree, and then the mirror surface is ground into an arc shape which is beneficial to the deformation of the mirror body and the release of casting residual stress, so that the micro texture on the mirror surface is more obvious, and the light transmission effect is achieved. The invention explains the reason for forming the 'light transmission' effect of the bronze mirror surface in detail theoretically, and gives the concrete manufacturing process of the light transmission bronze mirror from the process, thereby providing theoretical and technical support for researching the 'light transmission' effect formed by the bronze mirror and disclosing the 'light transmission mirror' puzzle for thousands of years.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.
FIG. 1 is a schematic structural diagram of a light-transmitting bronze mirror according to an embodiment of the present invention;
FIG. 2 is a cross-sectional view of an as-cast blank mirror according to an embodiment of the present invention;
FIG. 3 is a graph of cast residual stress in the mirror of an as-cast blank according to an embodiment of the present invention;
FIG. 4 is a schematic view illustrating mirror plane polishing according to an embodiment of the present invention;
FIG. 5 is a schematic diagram illustrating the finish grinding of a mirror surface curved surface according to an embodiment of the present invention;
FIG. 6 is a diagram illustrating the "light-transmitting" effect of the light-transmitting bronze mirror according to the embodiment of the present invention;
fig. 7 is a flow chart of the preparation of the light-transmitting bronze mirror according to the embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
The following describes a transparent bronze mirror and a method for manufacturing the same according to embodiments of the present invention.
Referring to fig. 1 to 7, an embodiment of the present invention provides a method for manufacturing a light-transmitting bronze mirror, including the following steps:
s1, designing the shape of the mirror body 1, and manufacturing a mirror model according to the shape of the mirror body 1 to obtain the mirror model.
Referring to fig. 1, the mirror body 1 is a circular mirror body with a mirror surface in a slightly convex arc shape towards a direction away from the mirror back, and a mirror handle 11 is further arranged in the middle of the mirror back. Specifically, the middle part of the mirror surface is convex toward the side far away from the mirror back. The mirror back is further provided with a pattern area 12, the pattern area 12 is located between the mirror handle 11 and the mirror edge 13, and the thickness of the mirror body at the mirror edge 13 and the thickness of the mirror body at the mirror handle 11 are both larger than the thickness of the mirror body at the pattern area 12. The mirror edge 13 of the invention is thicker and the mirror back is cast with patterns, therefore, the mirror surface can reflect light and shade alternate images with the same shape as the pattern of the mirror back on the opposite screen under the irradiation of a light source.
Further, in the preferred embodiment of the present invention, the patterns of the pattern region 12 are distributed concentrically, the patterns are microscopically convex relative to the mirror surface, and the convex height of the patterns is 1.3 to 1.7 μm. Preferably, the bump height is 1.5 μm.
Further, in the preferred embodiment of the present invention, the mirror is made by a lost wax method. The technological process includes making wax mold for lens body, compounding gypsum slurry, grouting, drying and hardening, dewaxing and burning. Because the mirror body 1 has a pattern structure with a complex shape, the invention adopts a lost wax method to manufacture the mirror model.
S2, smelting and casting: the mirror body material is put into a crucible to be heated and melted to obtain liquid alloy, then the liquid alloy is cast into the mirror mold, and after cooling, a cast blank mirror body is obtained (refer to fig. 2). The thinner pattern areas 12 of the mirror body 1 cool down faster, while the thicker mirror rim 13 portions cool down slower, so that the pattern areas 12 have already cooled down substantially completely after the as-cast condensation, while the mirror rim 13 continues to shrink by cooling. At this point, the rim 13 will produce a hoop effect on the mirror 1, eventually resulting in casting residual stresses in the as-cast blank mirror.
Referring to fig. 3, during the cooling process of the mirror body 1, casting residual stress is generated on the mirror body 1 due to the difference of thickness. Due to the convex shape of the mirror edge 13 towards the mirror back, the mirror edge 13 can tightly clamp the mirror body 1, so that the cast-state blank mirror body has the tendency of upward arching deformation of the mirror surface, a small part of the mirror body 1 close to the mirror surface side is subjected to tensile stress parallel to the mirror surface, and most of the mirror body tissue close to the mirror back side is subjected to compressive stress parallel to the mirror surface.
Further, in a preferred embodiment of the present invention, the mirror material is a high tin bronze, which comprises, in mass percent, 70-75% of Cu, 18-22% of Sn, 4-6% of Pb, 1-2% of Zn, 0.5-1% of P. The mirror body material is tin bronze with the tin content of at least more than 18%, and the high tin bronze is easy to generate casting residual stress due to the difference of the shrinkage rate of the mirror body when the mirror body is cast and cooled, so that the sufficient residual stress in the mirror body can be ensured when the mirror body is cast and condensed.
Further, in the preferred embodiment of the invention, the melting temperature is 1000-1400 ℃, and the melting time is 20-40 min.
Referring to fig. 4 and 5, S3, mirror polishing: and sequentially carrying out mirror plane grinding and mirror surface curved surface fine grinding on the as-cast blank mirror body to obtain the light-transmitting bronze mirror. Wherein, the mirror body 1 should be ground to remove more than half of the thickness in the mirror plane grinding and mirror surface curved surface finish grinding process at least, so that the rigidity of the mirror body 1 is reduced to meet the standard of casting residual stress effective release. The thickness and the rigidity of the mirror body 1 are reduced through plane grinding in the mirror surface grinding process, so that casting residual stress in the mirror body 1 is released to form deformation difference on the mirror surface, then the mirror surface is ground into a certain radian through curved surface grinding, the casting residual stress can be effectively released, and finally the microtexture with a light transmission effect on the mirror surface is more obvious. The bronze mirror with the light transmission effect is manufactured by a casting technology and a mirror grinding processing technology, so that the forming process and the forming mechanism of the light transmission effect are researched.
It should be noted that the "light transmission" phenomenon of the bronze mirror of the present invention specifically means that the mirror surface reflects a light and dark alternate image having a shape identical to the pattern on the mirror back on the screen opposite to the mirror surface under the irradiation of the light source, and the pattern on the mirror back reflected by the mirror surface of the bronze mirror prepared by the present invention has a clear and beautiful shape.
Further, in a preferred embodiment of the present invention, the step of mirror plane polishing comprises: and grinding the mirror surface of the as-cast blank mirror body by adopting a planar mirror surface grinding disc, and reducing the thickness of the mirror surface by at least 1/3. The invention adopts the plane grinding disc to grind the mirror surface. The thickness of the mirror body 1 is gradually reduced in the grinding process, the rigidity is gradually reduced, the casting residual stress gradually overcomes the rigidity of the mirror body 1 to enable the mirror body 1 to generate bending deformation, normal deformation differences can be generated at different thickness positions of the mirror body 1, namely, the thick position with patterns on the mirror surface generates normal tensile deformation, and the thin position without patterns generates normal shrinkage deformation.
Further, in a preferred embodiment of the present invention, the step of mirror surface finish grinding comprises: and grinding the mirror surface of the as-cast blank mirror body after mirror surface plane grinding by using a mirror surface polishing grinding disc in a curved surface form, and removing at least 1/5 of the thickness of the mirror edge 13 part of the mirror surface. The mirror surface after the plane grinding is continuously ground by adopting the mirror surface polishing grinding disc in the curved surface form, and the mirror surface can be gradually ground into an upward slightly convex arc shape. The arc mirror surface is more beneficial to fully releasing residual stress in the mirror body, so that the normal deformation difference on the mirror surface is gradually obvious, and finally, a micro texture corresponding to the pattern on the back of the mirror is formed on the mirror surface, thereby meeting the requirement of light transmission. The mirror surface reflects a mirror back pattern image on the screen opposite to the mirror surface under the irradiation of the light source (see fig. 6).
The bronze mirror of the invention has the characteristics of thicker mirror edge 13, slightly convex mirror surface, back-cast patterns and the like. The mirror surface can reflect alternate light and dark images consistent with the patterns on the back of the mirror on a screen corresponding to the mirror surface under the irradiation of a light source, and the effect that similar light penetrates through the mirror body is achieved. The preparation process is simple and efficient, the intensity degree of the light transmission effect of the mirror surface can be adjusted by controlling the grinding amount in the mirror surface grinding process, and a new technical basis is provided for the mechanism of the light transmission effect of the bronze mirror.
The invention also provides a light-transmitting bronze mirror which is prepared according to the preparation method.
The features and properties of the present invention are described in further detail below with reference to examples.
Example 1
The embodiment provides a light-transmitting bronze mirror which is prepared according to the following method:
(1) The mirror body 1 is shaped as shown in fig. 1. Wherein, the whole shape of the mirror body 1 is round, the mirror edge 13 and the mirror handle 11 are thicker, the pattern area 12 is thinner, and the mirror edge 13 protrudes at one side of the mirror back.
(2) The method for manufacturing the mirror by adopting the lost wax method comprises the following process flows: preparing a lens wax mould, preparing gypsum slurry, grouting, drying and hardening, dewaxing and burning a shell.
(3) Smelting and casting: the mirror body material is firstly put into a crucible to be heated to 1200 ℃ and smelted for 30min, so that all components of the mirror body material are fully mixed to obtain the liquid alloy. The liquid alloy is then cast into the mirror. Wherein the mirror material being smelted is high tin bronze comprising, in mass percent, 70% Cu, 22% Sn, 6% Pb, 1% Zn and 1% P.
(4) After casting, the mirror body 1 is naturally cooled and solidified in the mirror mold to generate casting residual stress. And taking out the as-cast blank mirror body after cooling.
(5) Mirror plane grinding: and (3) grinding the mirror surface of the as-cast blank by using a planar mirror grinding disc, and removing 1/3 of the thickness of the mirror grinding.
(6) And (3) finely grinding the curved surface of the mirror surface: and continuously grinding the mirror surface after plane grinding by using a mirror surface polishing grinding disc in a curved surface form, and grinding and removing 1/5 of the thickness of the edge 13 of the mirror to obtain the light-transmitting bronze mirror.
Example 2
The embodiment provides a light-transmitting bronze mirror which is prepared according to the following method:
(1) The mirror body 1 is designed in accordance with the design shown in fig. 1. Wherein, the whole shape of the mirror body 1 is round, the mirror edge 13 and the mirror handle 11 are thicker, the pattern area 12 is thinner, and the mirror edge 13 protrudes at one side of the mirror back.
(2) The method for manufacturing the mirror by adopting the lost wax method comprises the following process flows: preparing a lens wax mould, preparing gypsum slurry, grouting, drying and hardening, dewaxing and burning a shell.
(3) Smelting and casting: the mirror body material is firstly put into a crucible to be heated to 1200 ℃ and smelted for 30min, so that all components of the mirror body material are fully mixed to obtain the liquid alloy. The liquid alloy is then cast into the mirror. Wherein the mirror material being smelted is high tin bronze comprising, in mass percent, 75% Cu, 18% Sn, 4% Pb, 2% Zn and 1% P.
(4) After casting, the mirror body 1 is naturally cooled and solidified in the mirror mold to generate casting residual stress. And taking out the as-cast blank mirror body after cooling.
(5) Mirror plane grinding: and (3) grinding the mirror surface of the as-cast blank by using a planar mirror grinding disc, and removing 1/3 of the thickness of the mirror grinding.
(6) And (3) finely grinding the curved surface of the mirror surface: and continuously grinding the mirror surface after plane grinding by using a mirror surface polishing grinding disc in a curved surface form, and grinding and removing 1/5 of the thickness of the edge 13 of the mirror to obtain the light-transmitting bronze mirror.
Example 3
The light-transmitting bronze mirror provided by the embodiment is prepared according to the following method:
(1) The mirror body 1 is designed in accordance with the design shown in fig. 1. Wherein, the whole shape of the mirror body 1 is round, the mirror edge 13 and the mirror handle 11 are thicker, the pattern area 12 is thinner, and the mirror edge 13 protrudes at one side of the mirror back.
(2) The method adopts a lost wax method to manufacture a mirror model, and the process flow comprises the following steps: preparing a lens wax mould, preparing gypsum slurry, grouting, drying and hardening, dewaxing and burning a shell.
(3) Smelting and casting: the mirror body material is firstly put into a crucible to be heated to 1200 ℃ and smelted for 30min, so that all components of the mirror body material are fully mixed to obtain the liquid alloy. The liquid alloy is then cast into the mirror. Wherein the mirror material being smelted is high tin bronze comprising, in mass percent, 72% Cu, 22% Sn, 4% Pb, 1.5% Zn and 0.5% P.
(4) After casting, the mirror body 1 is naturally cooled and solidified in the mirror mold to generate casting residual stress. And taking out the as-cast blank mirror body after cooling.
(5) Mirror plane grinding: and (3) grinding the cast blank mirror surface by using a plane mirror grinding disc, and removing 1/3 of the thickness of the mirror grinding.
(6) And (3) finely grinding the curved surface of the mirror surface: and continuously grinding the mirror surface after plane grinding by using a mirror surface polishing grinding disc in a curved surface form, and grinding and removing 1/5 of the thickness of the edge 13 of the mirror to obtain the light-transmitting bronze mirror.
The embodiments described above are some, but not all embodiments of the invention. The detailed description of the embodiments of the present invention is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Claims (10)

1. A method for preparing a light-transmitting bronze mirror is characterized by comprising the following steps:
s1, designing the model of a mirror body, and manufacturing a mirror model according to the model of the mirror body to obtain a mirror model;
s2, smelting and casting: putting the mirror body material into a crucible for heating and smelting to obtain liquid alloy, then casting the liquid alloy into the mirror model, and cooling to obtain a cast blank mirror body;
s3, mirror surface grinding: and sequentially carrying out mirror plane grinding and mirror surface curved surface fine grinding on the as-cast blank mirror body to obtain the light-transmitting bronze mirror.
2. The preparation method of claim 1, wherein the mirror body is a round mirror body with a slightly convex cambered surface facing away from the mirror back, and a mirror handle is further arranged in the middle of the mirror back.
3. The preparation method of claim 2, wherein a pattern area is further arranged on the mirror back, the pattern area is positioned between the mirror handle and the mirror edge, and the mirror body thickness at the mirror edge and the mirror body thickness at the mirror handle are both larger than the mirror body thickness of the pattern area.
4. The production method according to claim 3, wherein the patterns of the pattern region are concentrically arranged, the patterns are microscopically convex with respect to the mirror surface, and the pattern has a convex height of 1.3 to 1.7 μm.
5. The method according to claim 1, wherein in step S1, the mirror pattern is formed by a lost wax method.
6. The method of claim 1, wherein in step S2, the lens body material is a high tin bronze, the high tin bronze comprises, in mass percent, 70-75% by weight of Cu, 18-22% by weight of Sn, 4-6% by weight of Pb, 1-2% by weight of Zn, 0.5-1% by weight of P.
7. The preparation method according to claim 1, wherein in the step S2, the melting temperature is 1000-1400 ℃ and the melting time is 20-40 min.
8. The method according to claim 1, wherein in step S3, the step of mirror-surface plane polishing includes: and grinding the mirror surface of the as-cast blank mirror body by adopting a planar mirror surface grinding disc, and reducing the thickness of the mirror surface by at least 1/3.
9. The production method according to claim 1, wherein in step S3, the step of mirror-surface finish-grinding includes: and grinding the mirror surface of the as-cast blank mirror body after mirror surface plane grinding by adopting a mirror surface polishing grinding disc in a curved surface form, and removing at least 1/5 of the thickness of the edge part of the mirror surface.
10. A light-transmitting bronze mirror, characterized by being produced by the production method according to any one of claims 1 to 9.
CN202210990886.3A 2022-08-18 2022-08-18 Light-transmitting bronze mirror and preparation method thereof Active CN115319031B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100593A (en) * 1987-02-04 1988-08-17 黄克忠 Metallic mirror surface curvature fluctuating technology and speculum
JPH06148411A (en) * 1992-11-02 1994-05-27 Toyama Pref Gov Production of mirror
CN1099074A (en) * 1993-07-30 1995-02-22 董亚巍 bronze mirror and preparation method thereof
CN1134335A (en) * 1996-02-26 1996-10-30 董亚巍 Preparation method of bronze mirror
CN101195196A (en) * 2007-11-14 2008-06-11 施近勇 Process for producing metallic translucent lens
US20210167255A1 (en) * 2019-11-28 2021-06-03 Panasonic Intellectual Property Management Co., Ltd. Light-emitting device and connection method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100593A (en) * 1987-02-04 1988-08-17 黄克忠 Metallic mirror surface curvature fluctuating technology and speculum
JPH06148411A (en) * 1992-11-02 1994-05-27 Toyama Pref Gov Production of mirror
CN1099074A (en) * 1993-07-30 1995-02-22 董亚巍 bronze mirror and preparation method thereof
CN1134335A (en) * 1996-02-26 1996-10-30 董亚巍 Preparation method of bronze mirror
CN101195196A (en) * 2007-11-14 2008-06-11 施近勇 Process for producing metallic translucent lens
US20210167255A1 (en) * 2019-11-28 2021-06-03 Panasonic Intellectual Property Management Co., Ltd. Light-emitting device and connection method

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