CN115302607A - Casting machine and blade coating type casting knife assembly thereof - Google Patents

Casting machine and blade coating type casting knife assembly thereof Download PDF

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Publication number
CN115302607A
CN115302607A CN202210918694.1A CN202210918694A CN115302607A CN 115302607 A CN115302607 A CN 115302607A CN 202210918694 A CN202210918694 A CN 202210918694A CN 115302607 A CN115302607 A CN 115302607A
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CN
China
Prior art keywords
casting
blade
knife
cutter
assembly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210918694.1A
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Chinese (zh)
Inventor
李天航
胡英俊
朱桂强
黄德林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Sunlord Electronics Co Ltd
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Shenzhen Sunlord Electronics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Sunlord Electronics Co Ltd filed Critical Shenzhen Sunlord Electronics Co Ltd
Priority to CN202210918694.1A priority Critical patent/CN115302607A/en
Publication of CN115302607A publication Critical patent/CN115302607A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/29Producing shaped prefabricated articles from the material by profiling or strickling the material in open moulds or on moulding surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B5/00Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping
    • B28B5/02Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type
    • B28B5/026Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type the shaped articles being of indefinite length
    • B28B5/027Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type the shaped articles being of indefinite length the moulding surfaces being of the indefinite length type, e.g. belts, and being continuously fed

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Coating Apparatus (AREA)

Abstract

The invention discloses a casting machine and a knife coating type casting knife assembly thereof, wherein the high-precision knife coating type casting knife assembly comprises a knife body and a knife rest, the knife body is fixedly connected to the knife rest, and the back of the knife rest is provided with a knife rest assembly reference boss; the cutter body vertical adjusting mechanism and the cutter body longitudinal adjusting mechanism can enable the cutter body to generate local micro-deformation in the vertical direction and/or the longitudinal direction. Through the cutter body vertical adjusting mechanism and the cutter body longitudinal adjusting mechanism, the high-precision scraping type casting cutter assembly provided by the embodiment of the invention can enable the integral range of the width of the cutter edge gap to be accurately adjusted to be within 2 mu m, so that the precision requirement of a scraping type casting film with the thickness of 1-10 mu m is met.

Description

Casting machine and blade coating type casting knife assembly thereof
Technical Field
The invention relates to the technical field of structural design of casting machines, in particular to a casting machine and a blade coating type casting knife thereof.
Background
At present, in the industries of chip-type laminated inductors, multi-layer Ceramic capacitors (MLCC), low-temperature co-fired ceramics (LTCC), and the like, the tape casting mode of a tape casting machine includes a lip die type, an extrusion type, a scratch coating type, and the like. The principle is that casting slurry is uniformly coated on a carrier film through a precise slit, a thin film with uniform thickness is formed after drying, and the size precision of the slit directly influences the uniformity of the thickness of the casting film. As the thickness of the casting film is continuously reduced (1-10 μm), the casting process has extremely high requirements on the precision of a mechanism for forming the slit.
Different casting methods have advantages and disadvantages, wherein the doctor blade casting has a main problem of unstable casting film thickness, which has become a great obstacle to the wide application of the doctor blade casting, and needs to be solved.
It is to be noted that the information disclosed in the above background section is only for understanding the background of the present application and thus may include information that does not constitute prior art known to a person of ordinary skill in the art.
Disclosure of Invention
In order to overcome the defects of the prior art, the embodiment of the application provides a high-precision doctor-blade casting knife assembly, which comprises a knife body and a knife rest, wherein the knife body is fixedly connected to the knife rest, and the back of the knife rest is provided with a knife rest assembly reference boss;
the cutter body vertical adjusting mechanism and the cutter body longitudinal adjusting mechanism can enable the cutter body to generate local micro-deformation in the vertical direction and/or the longitudinal direction.
The invention may also employ the following alternatives/preferences:
the cutter body is of a vertically symmetrical double-cutter-edge structure, and two cutter edges are respectively arranged at the upper end part and the lower end part of the cutter body.
The cutter comprises a cutter body and is characterized by further comprising a cutter cover, wherein a fluid guide structure capable of stabilizing the material flow state of the casting slurry is arranged at the lower end of the cutter cover, and the cutter cover is arranged in front of the cutter body.
The fluid guide structure is a slope surface structure arranged at the lower end of the knife cover, the distance between the slope surface and the knife body is wide at the top and narrow at the bottom, and the sectional area of the casting slurry flowing through the knife cover is gradually reduced.
The cutter body vertical adjusting mechanism comprises a plurality of vertical adjusting bolt-nut assemblies which are respectively arranged at the top of the cutter frame so as to vertically press the cutter body and enable the cutter body to generate local micro-deformation in the vertical direction; the cutter body longitudinal adjusting mechanism comprises a plurality of longitudinal adjusting bolt-nut assemblies which are respectively arranged in front of the cutter rest so as to press the cutter body in the longitudinal direction and enable the cutter body to generate local micro-deformation in the longitudinal direction.
The tool rest adopts a beam structure with equal section; the number of the tool rest assembly reference bosses is three, and the three tool rest assembly reference bosses are respectively arranged at the left end, the right end and the middle part of the back of the tool rest.
The knife rest is further provided with two handles which are respectively arranged at the left end and the right end in front of the knife rest.
The knife body is made of non-magnetic tungsten steel at least at the knife edge.
The invention also provides a casting machine, which comprises a casting machine body, a casting knife assembly, a casting shaft, a material box for containing casting slurry and a bearing film for forming a slurry film; the casting knife assembly is the high-precision scraping type casting knife assembly as described in any one of the above, and is assembled on the casting machine body through the knife rest assembly reference boss; the length direction of the cutter body is parallel to the axial direction of the casting shaft, and a preset cutter edge gap is formed between the cutter edge of the casting cutter and the carrier film; the carrier film is attached to the surface of the casting shaft and is transmitted along with the rotation of the casting shaft.
Preferably, when the casting machine works, casting slurry forms a stable liquid level height between the material box and the knife cover, and a slurry film with uniform thickness is formed on the carrier film after the casting slurry passes through the knife edge gap; the hot air drying component is used for drying the slurry film on the carrier film.
Compared with the prior art, one or more technical schemes provided in the embodiment of the application have at least the following beneficial effects:
through the cutter body vertical adjusting mechanism and the cutter body longitudinal adjusting mechanism, the high-precision scraping type casting cutter assembly provided by the embodiment of the invention can enable the integral range of the width of the cutter edge gap to be accurately adjusted to be within 2 mu m, so that the precision requirement of a scraping type casting film with the thickness of 1-10 mu m is met.
Drawings
FIG. 1 is a schematic perspective view of a casting blade assembly of an embodiment;
FIG. 2 is an exploded view of FIG. 1;
FIG. 3 is a rear view of FIG. 1;
FIG. 4 is a side view of FIG. 1;
FIG. 5 is a schematic view of a configuration of a casting blade assembly in cooperation with a cartridge and a carrier film according to an embodiment.
Detailed Description
The present invention is further described with reference to the following figures 1-5 and the detailed description, wherein like reference numerals refer to like parts, unless otherwise specified. It should be emphasized that the following description is merely exemplary in nature and is not intended to limit the scope of the invention or its application.
It will be understood that when an element is referred to as being "secured to" or "disposed on" another element, it can be directly secured to or disposed on the other element or be indirectly secured to or disposed on the other element. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or be indirectly connected to the other element. In addition, the connection may be for either a fixed or coupled or communicating function.
It is to be understood that the terms "length," "width," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like are used in the indicated orientations and positional relationships based on the orientation shown in the drawings for ease of describing embodiments of the present invention and to simplify the description, and are not intended to indicate or imply that the referenced devices or elements must have a particular orientation, be constructed and operated in a particular orientation, and are therefore not to be considered limiting of the present invention.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or to implicitly indicate the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the embodiments of the present invention, "a plurality" means two or more unless specifically limited otherwise.
The inventors have found that the precision and stability of the knife-edge gap are factors affecting the precision of the film thickness in the precision range of 1 to 10 μm in the cast film thickness. The adjusting mode in the prior art is difficult to be suitable for the precision interval of the casting film thickness of 1-10 mu m, and has the disadvantages that the debugging difficulty is high after the first assembling debugging and the knife grinding, and the precision is difficult to ensure; on the other hand, the precision is reduced due to the micro deformation of the tool rest in the long-term working process. Therefore, the embodiment of the application provides a high-precision doctor blade casting knife, so that the integral range of the width of a knife edge gap can be accurately adjusted to be within 2 mu m.
Example one
As shown in fig. 1 and 3, the high-precision doctor blade casting knife assembly comprises a knife body 5 and a knife rest 6, wherein the knife body 5 is fixedly connected to the knife rest 6, and knife rest assembly reference bosses (15, 16 and 17) are arranged on the back surface of the knife rest 6.
As shown in fig. 2, the cutter body 5 is fixedly connected to the cutter holder by a set of cutter body fixing bolts 9, and the front and back (front view direction) of the cutter body 5 is referred to as longitudinal direction, the up and down (top view direction) is referred to as vertical direction, and the left and right (side view direction) is referred to as horizontal direction. The high-precision scraping and coating type tape casting cutter assembly further comprises a cutter body vertical adjusting mechanism and a cutter body longitudinal adjusting mechanism, wherein the cutter body vertical adjusting mechanism comprises a plurality of vertical adjusting bolt-nut assemblies (7, 8) which are respectively arranged at the top of the cutter frame 6 so as to vertically press the cutter body 5 and enable the cutter body to generate local micro-deformation in the vertical direction; the cutter body longitudinal adjusting mechanism comprises a plurality of longitudinal adjusting bolt-nut assemblies (10, 11) which are respectively arranged in front of the cutter frame 6 so as to press the cutter body 5 along the longitudinal direction and make the cutter body generate local micro-deformation along the longitudinal direction. In the scraping and coating type tape casting knife in the prior art, the knife body and the knife rest are connected and then lack of adjusting function. The assembly precision adjustment of the casting knife and the casting shaft is pressed and extruded by hands, the adjustment difficulty is high, the adjustable precision is low, and the assembly precision can be further reduced along with the long-term release of the internal stress of the knife body. In this embodiment, on the basis of the dimensional accuracy of the blade body 5, the vertical adjusting mechanism and the longitudinal adjusting mechanism can be pressed against each other to cause a local micro-deformation of the corresponding portion of the blade body 5, so as to improve the assembly accuracy of the blade edge 18 of the blade body 5 and the casting shaft 1, for example, the overall range can be accurately adjusted to within 2 μm. The local micro-deformation can be vertical local adjustment, longitudinal local adjustment, or vertical local adjustment and longitudinal local adjustment which are carried out synchronously. The vertical adjusting bolt-nut assemblies (7, 8) can be arranged in two or more than two according to the requirement of adjusting precision and are generally uniformly arranged along the length direction of the tool rest 6, and the longitudinal adjusting bolt-nut assemblies (10, 11) can be arranged in two or more than two according to the requirement of adjusting precision and are generally uniformly arranged along the length direction of the tool rest 6.
The cutter body 5 is preferably designed into a vertically symmetrical double-edge structure, and the two edges 18 are respectively arranged at the upper end part and the lower end part of the cutter body 5, so that the structure has the advantages that when one edge is influenced by abrasion, damage and the like to produce, the other edge can be quickly replaced, and the great influence on the productivity is avoided. In addition, the cutter body 5 is made of non-magnetic tungsten steel at least at the edge part. The knife edge is made of non-magnetic tungsten steel, so that the cost and the processing difficulty can be reduced, the service life is prolonged, and the magnetic influence is eliminated. In the prior art, the cutter body made of the integral stainless steel material has the advantages of long service life, good processability and the like, but the remanence is difficult to completely eliminate, and the influence on ferrite slurry is difficult to avoid.
As shown in figures 2 and 3, the tool rest 6 adopts a uniform-section beam or a similar uniform-section beam structure, and preferably three tool rest assembly reference bosses (15, 16 and 17) are respectively arranged at the left end, the right end and the middle part of the back surface of the tool rest. In addition, the knife rest 6 is also provided with a handle 12 for holding and dismounting. The number of the handles 12 is preferably two, and the handles are respectively provided at the left and right ends of the front surface of the blade holder 6.
As shown in fig. 1, 2 and 4, the present embodiment further includes a blade cover 14 connected to the blade holder 6 by a blade cover fastening bolt 13, a fluid guide structure capable of stabilizing a flow state of the casting slurry is provided at a lower end of the blade cover 14, and the blade cover 14 is provided in front of the blade body 6. The fluid guide structure is a slope structure 19 arranged at the lower end of the knife cover 14, the slope structure 19 is in an inclined plane shape or an inclined arc surface shape, the cross section area of the casting slurry flowing through the knife cover 14 can be gradually reduced, the lowest end of the casting slurry is aligned with the knife edge 18, and the structure can avoid the phenomena of laminar flow disorder and the like caused by abrupt change of the cross section area of the fluid, so that slurry agglomeration is inhibited. The slope structure 19 is preferably integrated with the knife cover 14, or may be separate and connected to each other. In the scraping type casting knife in the prior art, when the casting slurry flows along with the carrier film and passes through the knife edge gap, the cross section area of the casting slurry suddenly changes at the knife edge, the flow velocity of the casting slurry is reduced in a broken manner at the knife edge, so that the laminar state of the casting slurry at the knife edge is damaged, the agglomeration is easy to occur, and the film thickness uniformity of the casting film is greatly influenced.
Example two
A casting machine, as shown in fig. 5, comprises a casting machine body, a casting knife assembly, a casting shaft 1, a material box 2 for containing casting slurry and a bearing film 4 for forming a slurry film. The carrier film 4 is driven at a constant speed along the casting direction at a certain linear speed along with the rotation of the casting shaft 1.
The casting knife assembly is a high-precision scraping type casting knife assembly as described in the first embodiment, and is assembled on the casting machine body through the knife rest assembling reference bosses (15, 16, 17). The length direction of the cutter body 5 is parallel to the axial direction of the casting shaft 1, and a preset cutter edge gap is formed between the cutter edge 18 of the cutter body 5 and the bearing film 4. The carrier film 4 is attached to the surface of the casting shaft 1 and is transported as the casting shaft 1 rotates.
The embodiment preferably further comprises a hot air drying part for timely and uniformly drying the slurry film on the carrier film 4.
When the casting machine works, stable liquid level height is formed between the material box 2 and the knife cover 14 by casting slurry, and after the casting slurry passes through the knife edge gap, a slurry film with uniform thickness is formed on the bearing film 4. The thickness control of the slurry film is mainly realized by changing the width of the knife edge gap, and specifically comprises the following steps: t = h δ; in the formula, t is the thickness of the slurry film after drying, h is the knife edge gap, and delta is the shrinkage rate of the slurry after drying, and the specific values are selected according to the formula of the casting slurry.
The technical scheme in the embodiment of the application at least has the following technical effects or advantages: the problem that the thickness of a casting film is unstable in the blade coating type casting process can be solved, the whole range of the knife edge gap can be accurately adjusted to be within 2 mu m, so that the current high-precision requirement on a mechanism is met, the implementation mode is simple and reliable, and the cost is low.
The foregoing is a more detailed description of the invention in connection with specific/preferred embodiments and is not intended to limit the practice of the invention to those descriptions. It will be apparent to those skilled in the art that numerous alterations and modifications can be made to the described embodiments without departing from the inventive concepts herein, and such alterations and modifications are to be considered as within the scope of the invention. In the description herein, references to the description of the term "one embodiment," "some embodiments," "preferred embodiments," "an example," "a specific example" or "some examples" or the like are intended to mean that a particular feature, such as a structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Various embodiments or examples and features of various embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction. Although embodiments of the present invention and their advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the scope of the claims.

Claims (10)

1. A high-precision scraping and coating type casting knife assembly is characterized by comprising a knife body and a knife rest, wherein the knife body is fixedly connected to the knife rest, and the back of the knife rest is provided with a knife rest assembly reference boss;
the cutter body vertical adjusting mechanism and the cutter body longitudinal adjusting mechanism can enable the cutter body to generate local micro-deformation in the vertical direction and/or the longitudinal direction.
2. A high precision doctor blade assembly as recited in claim 1, wherein said body is of vertically symmetrical double-edged construction, with two edges being provided at the upper and lower ends of said body, respectively.
3. A high precision doctor blade assembly as recited in claim 1, further including a blade housing, said blade housing having a lower end with a fluid directing structure for stabilizing the flow of the casting slurry, said blade housing being disposed in front of said blade body.
4. A high precision doctor blade assembly according to claim 3, wherein said fluid directing structure is a ramp structure at the lower end of said blade housing, said ramp being spaced from said blade body by a distance that is wider at the top and narrower at the bottom to provide a gradually decreasing cross-sectional area for the flow of casting slurry through said blade housing.
5. The high precision doctor blade assembly as claimed in claim 1, wherein said blade body vertical adjustment mechanism includes a plurality of vertical adjustment bolt-nut assemblies respectively disposed at the top of said blade holder for vertically pressing said blade body and causing said blade body to undergo a local micro-deformation in the vertical direction;
the cutter body longitudinal adjusting mechanism comprises a plurality of longitudinal adjusting bolt-nut assemblies which are respectively arranged in front of the cutter rest so as to press the cutter body in the longitudinal direction and enable the cutter body to generate local micro-deformation in the longitudinal direction.
6. A high precision doctor-blade casting blade assembly as claimed in claim 1, wherein said blade holder is of uniform cross-section beam construction;
the number of the tool rest assembly reference bosses is three, and the three tool rest assembly reference bosses are respectively arranged at the left end, the right end and the middle part of the back of the tool rest.
7. A high precision doctor blade assembly according to any one of claims 1 to 6, wherein said blade holder is further provided with two handles, one at each of the left and right ends of the front face of said blade holder.
8. A high precision doctor blade assembly as claimed in claim 7, wherein said blade body is of non-magnetic tungsten steel at least at the blade edge.
9. A casting machine is characterized by comprising a casting machine body, a casting knife assembly, a casting shaft, a material box for containing casting slurry and a bearing film for forming a slurry film;
the casting blade assembly is the high-precision doctor blade casting blade assembly as claimed in any one of claims 1-8, mounted on the casting machine body by the tool holder mounting datum boss;
the length direction of the cutter body is parallel to the axial direction of the casting shaft, and a preset cutter edge gap is formed between the cutter edge of the casting cutter and the carrier film;
the carrier film is attached to the surface of the casting shaft and is conveyed along with the rotation of the casting shaft.
10. The casting machine of claim 9, wherein when the casting machine is in operation, casting slurry forms a stable liquid level height between the material box and the cutter cover, and a slurry film with uniform thickness is formed on the carrier film after the casting slurry passes through the knife edge gap;
the hot air drying component is used for drying the slurry film on the carrier film.
CN202210918694.1A 2022-08-01 2022-08-01 Casting machine and blade coating type casting knife assembly thereof Pending CN115302607A (en)

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CN202210918694.1A CN115302607A (en) 2022-08-01 2022-08-01 Casting machine and blade coating type casting knife assembly thereof

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Application Number Priority Date Filing Date Title
CN202210918694.1A CN115302607A (en) 2022-08-01 2022-08-01 Casting machine and blade coating type casting knife assembly thereof

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH465476A (en) * 1965-12-02 1968-11-15 Redland Tiles Ltd Facility for the production of roof tiles
CN204749080U (en) * 2015-07-03 2015-11-11 淮安科润膜材料有限公司 Casting knife of perfluor ionic membrane steel band casting machine
CN205614806U (en) * 2016-05-13 2016-10-05 洛阳隔宝隔膜科技有限公司 Novel pulp stream prolongs machine curtain coating bush
CN108000697A (en) * 2018-01-09 2018-05-08 肇庆市佳利电子装备有限公司 A kind of casting apparatus of high-accuracy film
CN208180068U (en) * 2018-05-18 2018-12-04 浙江正天新材料科技有限公司 A kind of curtain coating head of casting machine
CN209868909U (en) * 2018-11-23 2019-12-31 浙江臻泰能源科技有限公司 Casting knife assembly
CN114043658A (en) * 2021-12-17 2022-02-15 江苏科润膜材料有限公司 Casting equipment and casting knife for adjusting and correcting production of perfluorinated ion exchange membrane

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH465476A (en) * 1965-12-02 1968-11-15 Redland Tiles Ltd Facility for the production of roof tiles
CN204749080U (en) * 2015-07-03 2015-11-11 淮安科润膜材料有限公司 Casting knife of perfluor ionic membrane steel band casting machine
CN205614806U (en) * 2016-05-13 2016-10-05 洛阳隔宝隔膜科技有限公司 Novel pulp stream prolongs machine curtain coating bush
CN108000697A (en) * 2018-01-09 2018-05-08 肇庆市佳利电子装备有限公司 A kind of casting apparatus of high-accuracy film
CN208180068U (en) * 2018-05-18 2018-12-04 浙江正天新材料科技有限公司 A kind of curtain coating head of casting machine
CN209868909U (en) * 2018-11-23 2019-12-31 浙江臻泰能源科技有限公司 Casting knife assembly
CN114043658A (en) * 2021-12-17 2022-02-15 江苏科润膜材料有限公司 Casting equipment and casting knife for adjusting and correcting production of perfluorinated ion exchange membrane

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Application publication date: 20221108

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