CN115287113A - Synthetic chain oil composition with excellent high-temperature adhesion and preparation method thereof - Google Patents

Synthetic chain oil composition with excellent high-temperature adhesion and preparation method thereof Download PDF

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CN115287113A
CN115287113A CN202210910304.6A CN202210910304A CN115287113A CN 115287113 A CN115287113 A CN 115287113A CN 202210910304 A CN202210910304 A CN 202210910304A CN 115287113 A CN115287113 A CN 115287113A
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temperature
chain oil
oil composition
parts
temperature adhesion
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吴华
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Shandong Lianbo New Material Technology Co ltd
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Shandong Lianbo New Material Technology Co ltd
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/003Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • C10M2207/2835Esters of polyhydroxy compounds used as base material
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • C10M2215/065Phenyl-Naphthyl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066Arylene diamines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/108Phenothiazine
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/38Conveyors or chain belts

Abstract

The invention discloses a synthetic chain oil composition with excellent high-temperature adhesion and a preparation method thereof, wherein the composition comprises the following components in percentage by weight: 50-90 parts of base oil, 5-30 parts of metallocene poly-alpha olefin (mPAO), 2-5 parts of high-temperature antioxidant, 1-4 parts of extreme pressure antiwear agent and 0.2-1 part of anticorrosive agent. The synthetic high-temperature chain oil composition has excellent high-temperature adhesion, so that the synthetic high-temperature chain oil composition has good high-temperature lubricating property, less coking amount, excellent low-temperature fluidity, low volatility, good antirust and anticorrosive protection and good paint compatibility.

Description

Synthetic chain oil composition with excellent high-temperature adhesion and preparation method thereof
Technical Field
The invention relates to the technical field of high-temperature chain oil, in particular to a synthetic chain oil composition with excellent high-temperature adhesion and a preparation method thereof.
Background
Textile post-processing equipment such as heat-setting machines, dryers, printing machines and the like are widely used for chain transmission and are generally lubricated by oil. The chain operation temperature of the textile post-treatment equipment is generally higher, the highest temperature is more than 250 ℃, and the highest speed of the chain is more than 120 m/min. The chain used by the post-treatment equipment, particularly the heat setting machine, is as long as 100m, the drying room has more speed saving, and the chain works in the drying room for a long time. On the other hand, the chain runs in the working environment of water-rich, water-vapor-rich and polyacid-base medium. Further, the development of post-processing equipment is advancing toward higher speed, more energy saving, longer life, no or little maintenance. In sum, the textile post-treatment equipment puts a strict requirement on the performance of the high-temperature chain oil. (1) little coking. The chain oil is attached to the chain and the guide rail after coking, so that the phenomena of retardation, dragging and the like occur when the chain runs, the friction, impact load and motor current are increased, the chain abrasion, fatigue and energy waste are aggravated, and the chain is seriously and even causes tooth jumping, chain dragging, fracture or motor burnout. Coking is a product of high-temperature oxidation of chain oil, and the presence of water, steam, acid and alkali substances and floccules can aggravate oxidation and increase the coking amount. Coking is inevitable, good chain oil has stable chemical structure, less oil coke is generated and can be taken away, and the maintenance and decoking period of the chain oil can be prolonged. (2) excellent high-temperature adhesion. High temperature adhesion refers to the oil film retention capability of the chain oil at high temperatures. The high-temperature adhesion is excellent, the oil film holding capacity is strong, the high-temperature lubrication of the chain oil is good, the coking quantity can be reduced, and the energy consumption and the abrasion can be reduced. The high-temperature adhesion is closely related to the viscosity index, the viscosity of the chain oil decreases less with the increase of the temperature, and the chain oil can be better adhered to the surface of a friction point at high temperature. And (3) the permeability is strong. There is a little clearance between the inner and outer chain plates of the chain and between the roller and the inner chain plate, and the chain oil permeates into the friction surfaces between the sleeve and the pin shaft and between the roller and the sleeve through the clearance respectively. The chain oil with poor permeability is difficult to enter a friction point, so that the chain abrasion is aggravated and even the occlusion is generated, and the service life of the chain is shortened. And (4) the low-temperature performance is good. In winter, the equipment is stopped for a long time, and when the equipment is restarted, the viscosity of chain oil is too high or the chain oil is solidified, so that the equipment is difficult to start, the preheating time is prolonged, and even a frequency converter or a motor can be burnt.
The technical development of the high-temperature chain oil goes through three stages of mineral oil type high-temperature chain oil, polyether type high-temperature chain oil and synthetic ester type high-temperature chain oil, and the development process is resisted to a high level. At the temperature of 140-160 ℃, the mineral oil type chain oil is quickly oxidized to form carbon deposit with high volatility. The polyether type high-temperature chain oil has the highest use temperature of about 220 ℃, high viscosity index and less residue, but has poor compatibility with paint, fast high-temperature decomposition and influence on the environment of a factory. The synthetic ester type high-temperature chain oil comprises meta-phenyl ester type high-temperature chain oil and polyol ester type high-temperature chain oil. The highest use temperature of the meta-phenyl ester type high-temperature chain oil is generally 250 ℃, the evaporation loss is small, but the high temperature is easy to coke, and the cleaning work of workers on the surface of the chain is increased. Polyol ester type high-temperature chain oil, particularly pentaerythritol ester, has the advantages of high oxidation resistance, less coking and high viscosity index, but has low viscosity, and can not form an oil film with enough thickness and lubrication at high temperature, so that a part of a degreasing agent is required to be added to improve the viscosity. The common adhesives used in polyol ester type high temperature chain oils currently on the market are Polyisobutylene (PIB) and Polymethacrylate (PMA). The properties of the traditional sticking agent, such as high-temperature oxidation stability, shear stability, low-temperature performance and the like, have great influence on the performance of the polyol ester type high-temperature chain oil, so that the poor high-temperature adhesion and the increased coking amount of the polyol ester type high-temperature chain oil are caused.
Disclosure of Invention
The invention aims to provide a synthetic chain oil composition with excellent high-temperature adhesion and a preparation method thereof.
The technical scheme adopted by the invention for solving the technical problem is as follows: a synthetic chain oil composition with excellent high-temperature adhesion comprises the following components in percentage by weight: 50-90 parts of base oil, 5-30 parts of metallocene poly-alpha olefin (mPAO), 2-5 parts of high-temperature antioxidant, 1-4 parts of extreme pressure antiwear agent and 0.2-1 part of anticorrosive agent.
Further, the base oil is pentaerythritol ester.
Further, the pentaerythritol ester is one or more of pentaerythritol ester, dipentaerythritol ester and tripentaerythritol ester.
Further, the mPAO is one or more of SpectraSyn Elite 65, spectraSyn Elite 150, spectraSyn Elite 300, dowSyn V600 and DowSyn V1000.
Further, the high-temperature antioxidant is a composition of different amine antioxidants, preferably, the amine antioxidant is a composition of more than two of N, N' -di-sec-butyl-p-phenylenediamine, dioctyl diphenylamine, 3, 7-di-tert-octyl phenothiazine, alpha-naphthylamine and N-phenyl-alpha-naphthylamine.
Further, the extreme pressure antiwear agent is a composition of more than two of phosphate, phosphite and molybdenum dialkyl dithiocarbamate.
Further, the corrosion inhibitor is at least one of benzotriazole or zinc dialkyl dithiophosphate.
A method for preparing a synthetic chain oil composition having excellent high-temperature adhesion, comprising the steps of:
s1: adding base oil into a kettle, heating and stirring, controlling the temperature to be between 80 and 100 ℃, sequentially adding a high-temperature antioxidant, an extreme pressure antiwear agent and an anticorrosive agent, and keeping for 0.5 to 1 hour to completely dissolve solid materials;
s2: adding mPAO, and continuously stirring for 0.5-1h;
s3: cooling to below 60 deg.C, and filtering with 500 mesh filter cloth to obtain the final product.
The invention has the following beneficial effects: in the preparation process, the specific pentaerythritol ester is used as the base oil, and the prepared synthetic high-temperature chain oil is suitable for lubricating chains at the ambient temperature of 280 ℃ or below and has small volatilization.
In the preparation process, the traditional finger-sticking agent is replaced by the ultrahigh-viscosity mPAO, and the prepared synthetic high-temperature chain oil has excellent high-temperature adhesion, excellent high-temperature extreme-pressure wear resistance and very low coking amount.
In the preparation process, the compound of different amine antioxidants is used as the high-temperature antioxidant, and the prepared synthetic high-temperature chain oil has excellent high-temperature oxidation resistance, so that the amount of oil sludge and coking is very low.
Drawings
FIG. 1 is a schematic view of a process for preparing a synthetic chain oil composition excellent in high-temperature adhesion according to the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
A synthetic chain oil composition with excellent high-temperature adhesion comprises the following components in percentage by weight: 50-90 parts of base oil, 5-30 parts of metallocene poly-alpha olefin (mPAO), 2-5 parts of high-temperature antioxidant, 1-4 parts of extreme pressure antiwear agent and 0.2-1 part of anticorrosive agent.
The base oil is pentaerythritol ester.
The pentaerythritol ester is one or more of pentaerythritol ester, dipentaerythritol ester and tripentaerythritol ester.
The mPAO is one or more of SpectraSyn Elite 65, spectraSyn Elite 150, spectraSyn Elite 300, dowSyn V600 and DowSyn V1000.
The high-temperature antioxidant is a composition of different amine antioxidants, preferably, the amine antioxidant is a composition of more than two of N, N' -di-sec-butyl-p-phenylenediamine, dioctyl diphenylamine, 3, 7-di-tert-octyl phenothiazine, alpha-naphthylamine and N-phenyl-alpha-naphthylamine.
The extreme pressure antiwear agent is a composition of more than two of phosphate, phosphite and molybdenum dialkyl dithiocarbamate.
The corrosion inhibitor is at least one of benzotriazole or zinc dialkyl dithiophosphate.
A method for preparing a synthetic chain oil composition having excellent high-temperature adhesion, comprising the steps of:
s1: adding base oil into a kettle, heating and stirring, controlling the temperature to be between 80 and 100 ℃, sequentially adding a high-temperature antioxidant, an extreme pressure antiwear agent and an anticorrosive agent, and keeping for 0.5 to 1 hour to completely dissolve solid materials;
s2: then adding mPAO, and continuing stirring for 0.5-1h;
s3: cooling to below 60 deg.C, and filtering with 500 mesh filter cloth to obtain the final product.
Example 1
A synthetic chain oil composition with excellent high-temperature adhesion comprises the following components in percentage by weight: 80 parts of pentaerythritol ester, 14 parts of metallocene poly-alpha olefin (mPAO), 4 parts of high-temperature antioxidant, 3 parts of extreme pressure antiwear agent and 0.3 part of anticorrosive agent.
The pentaerythritol ester is a pentaerythritol ester.
The mPAO is a composition of SpectraSyn Elite 65 and SpectraSyn Elite 150.
The high-temperature antioxidant is a composition of different amine antioxidants, preferably, the amine antioxidants are dioctyl diphenylamine and N-phenyl-alpha-naphthylamine.
The extreme pressure antiwear agent is a composition of more than two of phosphate, phosphite and molybdenum dialkyl dithiocarbamate.
The anticorrosive is benzotriazole.
The preparation method of the synthetic chain oil with excellent high-temperature adhesion comprises the following steps:
s1: adding base oil into a kettle, heating and stirring, controlling the temperature to be 80 ℃, sequentially adding a high-temperature antioxidant, an extreme pressure antiwear agent and an antirust agent, and keeping for 1 hour to completely dissolve solid materials;
s2: then adding mPAO, and continuing stirring for 0.5h;
s3: cooling to 60 deg.C, and filtering with 500 mesh filter cloth to obtain the final product.
Example 2
A synthetic chain oil composition with excellent high-temperature adhesion comprises the following components in percentage by weight: 75 parts of pentaerythritol ester, 20 parts of metallocene poly-alpha olefin (mPAO), 4 parts of high-temperature antioxidant, 3 parts of extreme pressure antiwear agent and 0.3 part of anticorrosive agent.
The pentaerythritol ester is a composition of pentaerythritol ester and dipentaerythritol ester.
The mPAO is DowSyn V600.
The high-temperature antioxidant is a composition of different amine antioxidants, preferably, the amine antioxidants are dioctyl diphenylamine, alkylated phenothiazine and N-phenyl-alpha-naphthylamine.
The extreme pressure antiwear agent is a composition of phosphate and molybdenum dialkyl dithiocarbamate.
The corrosion inhibitor is benzotriazole.
The preparation method of the synthetic chain oil with excellent high-temperature adhesion comprises the following steps:
s1: adding pentaerythritol ester base oil into a kettle, heating and stirring, controlling the temperature to be 100 ℃, sequentially adding a high-temperature antioxidant, an extreme pressure antiwear agent and an antirust agent, and keeping for 0.5h to completely dissolve solid materials;
s2: then adding mPAO, and continuing stirring for 1h;
s3: cooling to 40 deg.C, and filtering with 500 mesh filter cloth to obtain the final product.
Example 3
A synthetic chain oil composition with excellent high-temperature adhesion comprises the following components in percentage by weight: 78 parts of pentaerythritol ester, 18 parts of metallocene poly-alpha olefin (mPAO), 4 parts of high-temperature antioxidant, 3 parts of extreme pressure antiwear agent and 0.3 part of anticorrosive agent.
The pentaerythritol ester is a combination of pentaerythritol ester, dipentaerythritol ester and tripentaerythritol ester.
The mPAO is a composition of SpectraSyn Elite 65 and DowSyn V1000.
The high-temperature antioxidant is a composition of different amine antioxidants, preferably, the amine antioxidants are alkylated phenylenediamine, alkylated phenothiazine and N-phenyl-alpha-naphthylamine.
The extreme pressure antiwear agent is a composition of phosphite ester and molybdenum dialkyl dithiocarbamate.
The corrosion inhibitor is benzotriazole.
The preparation method of the synthetic chain oil with excellent high-temperature adhesion comprises the following steps:
s1: adding base oil into a kettle, heating and stirring, controlling the temperature to be 100 ℃, sequentially adding a high-temperature antioxidant, an extreme pressure antiwear agent and an antirust agent, and keeping for 1h to completely dissolve solid materials;
s2: then adding mPAO, and continuing stirring for 1h;
s3: cooling to 40 deg.C, and filtering with 500 mesh filter cloth to obtain the final product.
The properties of the synthetic chain oil compositions excellent in high-temperature adhesion provided in examples 1 to 3 of the present invention were tested, and the results are shown in table 1.
Test items Test standard Example 1 Example 2 Example 3
Viscosity (40 ℃ C.) GB/T 265 345 330 350
Viscosity (100 ℃ C.) GB/T 265 58 50 55
Viscosity index GB/T 2541 1555 150 152
Flash point GB/T 3536 315 312 315
Pour point GB/T 3535 -25 -25 -25
The copper sheet is corroded for 3 hours at 100 DEG C GB/T 5096 1a 1a 1a
Oven volatilizing at 260 deg.C for 8hrs 1.9% 2.5% 2.4%
Antiwear performance (four-ball method), (392N, 60min,100 deg.C), mm SH/T 0204 0.46 0.48 0.46
Extreme pressure performance (four-ball method) ofSeizure load Pb,100 ℃ N GB/T 12583 981 883 883
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (8)

1. A synthetic chain oil composition with excellent high-temperature adhesion is characterized by comprising the following components in percentage by weight: 50-90 parts of base oil, 5-30 parts of metallocene poly-alpha olefin (mPAO), 2-5 parts of high-temperature antioxidant, 1-4 parts of extreme pressure antiwear agent and 0.2-1 part of anticorrosive agent.
2. The synthetic chain oil composition excellent in high-temperature adhesion according to claim 1, characterized in that: the base oil is pentaerythritol ester.
3. The synthetic chain oil composition excellent in high-temperature adhesion according to claim 2, characterized in that: the pentaerythritol ester is one or more of pentaerythritol ester, dipentaerythritol ester and tripentaerythritol ester.
4. The synthetic chain oil composition excellent in high-temperature adhesion according to claim 1, characterized in that: the mPAO is one or more of SpectraSyn Elite 65, spectraSyn Elite 150, spectraSyn Elite 300, dowSyn V600 and DowSyn V1000.
5. The synthetic chain oil composition excellent in high-temperature adhesion according to claim 1, characterized in that: the high-temperature antioxidant is a composition of different amine antioxidants, preferably, the amine antioxidant is a composition of more than two of N, N' -di-sec-butyl-p-phenylenediamine, dioctyl diphenylamine, 3, 7-di-tert-octyl phenothiazine, alpha-naphthylamine and N-phenyl-alpha-naphthylamine.
6. The synthetic chain oil composition excellent in high-temperature adhesion according to claim 1, characterized in that: the extreme pressure antiwear agent is a composition of more than two of phosphate, phosphite and molybdenum dialkyl dithiocarbamate.
7. The synthetic chain oil composition excellent in high-temperature adhesion according to claim 1, characterized in that: the corrosion inhibitor is at least one of benzotriazole or zinc dialkyl dithiophosphate.
8. The method of claim 1, comprising the steps of:
s1: adding base oil into a kettle, heating and stirring, controlling the temperature to be between 80 and 100 ℃, sequentially adding a high-temperature antioxidant, an extreme pressure antiwear agent and an anticorrosive agent, and keeping for 0.5 to 1 hour to completely dissolve solid materials;
s2: then adding mPAO, and continuing stirring for 0.5-1h;
s3: cooling to below 60 deg.C, and filtering with 500 mesh filter cloth to obtain the final product.
CN202210910304.6A 2022-07-29 2022-07-29 Synthetic chain oil composition with excellent high-temperature adhesion and preparation method thereof Pending CN115287113A (en)

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