CN115260932A - Shielding adhesive tape with fingerprint prevention function - Google Patents

Shielding adhesive tape with fingerprint prevention function Download PDF

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Publication number
CN115260932A
CN115260932A CN202210279589.8A CN202210279589A CN115260932A CN 115260932 A CN115260932 A CN 115260932A CN 202210279589 A CN202210279589 A CN 202210279589A CN 115260932 A CN115260932 A CN 115260932A
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parts
layer
black ink
fingerprint
adhesive tape
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CN202210279589.8A
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CN115260932B (en
Inventor
夏厚君
杨晓明
涂大记
向建军
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Zhejiang Ouren New Materials Co ltd
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Zhejiang Ouren New Materials Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a shielding adhesive tape with an anti-fingerprint function, wherein a black ink layer and an adhesive layer are respectively positioned on the upper surface and the lower surface of a substrate layer, the black ink layer is obtained by drying black ink, and the black ink comprises the following components in parts by weight: the light-absorbing material comprises water-based polyurethane, carbon black, 1,1', 1' -methylene tri (4-isocyanic acid) benzene, sodium silicate, carboxymethyl cellulose, sodium tripolyphosphate, polyethyleneimine, octadecyl dimethyl benzyl ammonium chloride, a light absorbing agent, a coupling agent, chitosan and deionized water. The fingerprint-proof adhesive tape has fingerprint-proof performance, and fingerprint traces can not be left after being used for many times in various environments, so that the attachment of stains is reduced.

Description

Shielding adhesive tape with fingerprint prevention function
Technical Field
The invention belongs to the technical field of adhesive tapes, and particularly relates to a shielding adhesive tape with a fingerprint prevention function.
Background
The electromagnetic shielding film is a transparent shielding material capable of blocking electromagnetic wave penetration, preventing electromagnetic radiation, protecting electronic components and resisting electromagnetic interference, and the requirements on the electromagnetic shielding film are continuously improved along with the continuous development of electronic products in recent years. The wireless charging technology mainly comprises three main categories of magnetic induction wireless charging, magnetic resonance wireless charging and radio frequency wireless charging, and along with popularization of the wireless charging technology, a plurality of products applying the magnetic induction wireless charging technology emerge in the market. In order to obtain higher charging efficiency and reduce or eliminate the influence of an electromagnetic field on the mobile phone during charging, an electromagnetic shielding film is required for shielding. The electromagnetic shielding film is used for isolating the influence of an electromagnetic field on the mobile phone, preventing materials such as metal and the like from absorbing the electromagnetic wave emitted by the transmitting terminal equipment and generating a magnetic field in the opposite direction. In the wireless charging receiving end of the mobile phone, if the electromagnetic shielding film is not arranged, the wireless charging equipment cannot complete short-distance charging work. The electromagnetic shielding film needs to be fixed on the interference source through an adhesive tape. At present, the film does not have anti-fingerprint performance, and the residual fingerprint traces after multiple uses not only affect the appearance, but also have certain influence on the performance of the film material.
Disclosure of Invention
The invention aims to provide a shielding adhesive tape with an anti-fingerprint function, which has the anti-fingerprint performance, can not leave fingerprint traces after being used for many times in various environments, and can avoid the corrosion of fingerprint sweat stains on the adhesive tape.
In order to achieve the purpose, the invention adopts the technical scheme that: a shielding adhesive tape with an anti-fingerprint function comprises a black ink layer, a base material layer and an adhesive layer, wherein the black ink layer and the adhesive layer are respectively positioned on the upper surface and the lower surface of the base material layer, and a release layer is arranged on one side, opposite to the base material layer, of the adhesive layer;
the black ink layer is obtained by drying black ink, and the black ink comprises the following components in parts by weight: 65 parts of waterborne polyurethane, 2 parts of carbon black, 1,1', 1' -methylene tri (4-isocyanic acid) benzene, 1.3 parts of sodium silicate, 1 part of carboxymethyl cellulose, 0.25 part of sodium tripolyphosphate, 2 parts of polyethyleneimine, 1.5 parts of octadecyl dimethyl benzyl ammonium chloride, 4 parts of a light absorbent, 1.5 parts of a coupling agent, 1 part of chitosan and 16 parts of deionized water.
The technical scheme of further improvement in the technical scheme is as follows:
1. in the above embodiment, the light absorber is selected from nickel powder/carbon nanotube composite.
2. In the scheme, the coupling agent is selected from a coupling agent KH-561.
3. In the above scheme, the substrate layer is a PET polyester film.
4. In the scheme, the thickness of the PET polyester film is 2~4 μm.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
according to the shielding adhesive tape with the fingerprint prevention function, polyethyleneimine and octadecyl dimethyl benzyl ammonium chloride are added into waterborne polyurethane, carbon black and 1,1', 1' -methylene tri (4-isocyanic acid) benzene, so that the fingerprint prevention adhesive tape has the fingerprint prevention performance, fingerprint traces cannot be remained after repeated use in various environments, and the adhesive tape can be prevented from being corroded by fingerprint sweat stains; meanwhile, the anti-stain performance of the anti-fingerprint adhesive tape is enhanced, namely stain on the adhesive tape can be easily wiped off without residue after being left for a period of time in a high-temperature and high-humidity environment, so that the attachment of stains is reduced, and the cleaning difficulty is greatly reduced.
Drawings
FIG. 1 is a schematic structural view of a shielding tape with anti-fingerprint function according to the present invention;
fig. 2 is a partial schematic view of fig. 1.
In the above drawings: 1. a black ink layer; 2. a substrate layer; 3. an adhesive layer; 4. and a release layer.
Detailed Description
In the description of this patent, it is noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, merely for convenience in describing the present invention and for simplicity in description, and do not indicate or imply that the device or element referred to must have a particular orientation, be constructed in a particular orientation, and be operated, and thus, should not be construed as limiting the present invention; the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance; furthermore, unless expressly stated or limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, as they may be fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The meaning of the above terms in this patent may be specifically understood by those of ordinary skill in the art.
The invention is further described below with reference to the following examples:
example (b): a shielding tape with an anti-fingerprint function comprises a black ink layer 1, a base material layer 2 and an adhesive layer 3, wherein the black ink layer 1 and the adhesive layer 3 are respectively positioned on the upper surface and the lower surface of the base material layer 2, and a release layer 4 is arranged on one side, opposite to the base material layer 2, of the adhesive layer 3;
the black ink layer 1 is obtained by drying black ink, and the black ink comprises the following components in parts by weight: 65 parts of waterborne polyurethane, 2 parts of carbon black, 1,1', 1' -methylene tri (4-isocyanic acid) benzene, 1.3 parts of sodium silicate, 1 part of carboxymethyl cellulose, 0.25 part of sodium tripolyphosphate, 2 parts of polyethyleneimine, 1.5 parts of octadecyl dimethyl benzyl ammonium chloride, 4 parts of a light absorbent, 1.5 parts of a coupling agent, 1 part of chitosan and 16 parts of deionized water.
The light absorbing agent is selected from nickel powder/carbon nano tube compound, and the coupling agent is selected from coupling agent KH-580.
The base layer 2 was a 3.5 μm thick PET layer, and the black ink layer 1 was 1.5 μm thick.
The preparation method of the shielding adhesive tape with the fingerprint prevention function comprises the following steps: adding waterborne polyurethane, deionized water, 1,1', 1' -methylene tri (4-isocyanic acid) benzene, sodium tripolyphosphate, carbon black, sodium silicate, polyethyleneimine, octadecyl dimethyl benzyl ammonium chloride, a coupling agent, carboxymethyl cellulose, a light absorbing agent and chitosan into a high-speed stirring dispersing agent for stirring, and uniformly mixing to obtain black ink;
and coating the black ink on the substrate layer 2, and drying to obtain the shielding adhesive tape with the fingerprint prevention function.
Comparative example 1~2: an electromagnetic shielding film comprises a black ink layer 1, a base material layer 2 and an adhesive layer 3, wherein the black ink layer 1 and the adhesive layer 3 are respectively positioned on the upper surface and the lower surface of the base material layer 2, and a release layer 4 is arranged on one side, opposite to the base material layer 2, of the adhesive layer 3;
the black ink layer 1 is obtained by drying black ink, and the black ink comprises the following components in parts by weight as shown in table 1:
TABLE 1
Components Comparative example 1 Comparative example 2
Aqueous polyurethane 60 portions of 80 portions
Carbon black 1 part of 5 portions of
1,1', 1' -Methyltris (4-isocyanato) benzene 1.8 parts of 2 portions of
Sodium silicate 1.5 parts of 1.2 parts of
Carboxymethyl cellulose 1.2 parts of 1.5 parts of
Sodium tripolyphosphate 0.1 part 0.2 part
Polyethylene imine - 5 portions of
Octadecyl dimethyl benzyl ammonium chloride 2 portions of -
Light absorber 2.5 parts of 3 portions of
Coupling agent 0.8 portion of 0.5 portion
Chitosan 0.8 part of 0.6 part
Deionized water 18 portions of 20 portions of
Comparative example the procedure was as in example.
Comparative example 1 light absorber selected from nano Al/Al2O3The core-shell material is characterized in that the coupling agent is selected from a coupling agent KH-580, the base material layer 2 is a PET layer with the thickness of 2 mu m, and the thickness of the black ink layer 1 is 1 mu m.
In comparative example 2, the light absorbing agent is selected from nano nickel powder, the coupling agent is selected from coupling agent KBM403, the base material layer 2 is a PET layer with the thickness of 2.5 μm, and the thickness of the black ink layer 1 is 1.3 μm.
The properties of the electro-magnetic shielding films prepared in the above examples and comparative examples 1~2 are shown in table 2:
TABLE 2
Figure RE-RE-DEST_PATH_IMAGE002
The test method is as follows:
fingerprint prevention test: the appearance of the black ink layer was observed by pressing 10 times with a finger on the black ink layer, and the meanings indicated by the relevant symbols in table 2 were as follows:
o: without fingerprint
X: a fingerprint exists;
and (3) dirt resistance test: and (3) using a ZEBRA oil pen, wherein the angle between the oil pen and the surface of the film layer is about 90 degrees, applying a force of about 1N to draw 5 10mm handwriting on the surface of the film layer at a constant speed, then placing the sample in an environment with the temperature of 60 ℃ and the humidity of 95 percent for 2 hours, taking out the sample, and wiping the surface with alcohol, wherein no trace residue is left on the surface of the sample, and the sample is qualified.
As shown in the evaluation results of table 2, the masking tape with the anti-fingerprint function of the example was excellent in anti-fingerprint property, no trace was left in the case of multiple finger presses, and the stain on the tape could be easily wiped off without residue even if left in a high temperature and high humidity environment for a certain period of time, whereas the anti-fingerprint property of comparative example 1 was relatively poor and the stain resistance of comparative example 2 was much worse; therefore, the anti-fingerprint performance is improved, and the anti-dirt resistance of the shielding adhesive tape with the anti-fingerprint function is enhanced, namely dirt on the adhesive tape can be easily wiped off without residue after being left for a period of time in a high-temperature and high-humidity environment, so that the attachment of the dirt is reduced, and the cleaning difficulty is greatly reduced.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.

Claims (5)

1. The utility model provides a shielding sticky tape with prevent fingerprint function which characterized in that: the adhesive comprises a black ink layer (1), a base material layer (2) and an adhesive layer (3), wherein the black ink layer (1) and the adhesive layer (3) are respectively positioned on the upper surface and the lower surface of the base material layer (2), and a release layer (4) is arranged on one side, opposite to the base material layer (2), of the adhesive layer (3);
the black ink layer (1) is obtained by drying black ink, and the black ink comprises the following components in parts by weight: 65 parts of waterborne polyurethane, 2 parts of carbon black, 1,1', 1' -methylene tri (4-isocyanic acid) benzene, 1.3 parts of sodium silicate, 1 part of carboxymethyl cellulose, 0.25 part of sodium tripolyphosphate, 2 parts of polyethyleneimine, 1.5 parts of octadecyl dimethyl benzyl ammonium chloride, 4 parts of a light absorbent, 1.5 parts of a coupling agent, 1 part of chitosan and 16 parts of deionized water.
2. The shielding adhesive tape with anti-fingerprint function according to claim 1, wherein: the light absorbent is selected from nickel powder/carbon nanotube compound.
3. The masking tape with anti-fingerprint function as claimed in claim 1, wherein: the coupling agent is selected from a coupling agent KH-580.
4. The masking tape with anti-fingerprint function as claimed in claim 1, wherein: the substrate layer (1) is a PET polyester film.
5. The masking tape with anti-fingerprint function as claimed in claim 4, wherein: the thickness of the PET polyester film is 2~4 mu m.
CN202210279589.8A 2019-06-28 2019-06-28 Adhesive tape with fingerprint prevention function Active CN115260932B (en)

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CN201910571326.2A CN112143394B (en) 2019-06-28 2019-06-28 Fingerprint-proof adhesive tape for wireless charger
CN202210279589.8A CN115260932B (en) 2019-06-28 2019-06-28 Adhesive tape with fingerprint prevention function

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CN202210271552.0A Pending CN114716929A (en) 2019-06-28 2019-06-28 Easy-to-clean electromagnetic shielding film
CN202210185841.9A Pending CN114828603A (en) 2019-06-28 2019-06-28 Electromagnetic shielding film
CN202210279589.8A Active CN115260932B (en) 2019-06-28 2019-06-28 Adhesive tape with fingerprint prevention function
CN201910571326.2A Active CN112143394B (en) 2019-06-28 2019-06-28 Fingerprint-proof adhesive tape for wireless charger

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CN115181509A (en) * 2022-08-15 2022-10-14 江苏伊诺尔新材料科技有限公司 Manufacturing method of novel ultra-soft PI (polyimide) composite adhesive tape
CN115820139A (en) * 2022-12-14 2023-03-21 江苏伊诺尔新材料科技有限公司 Magnetic conduction double sticky tape suitable for wireless field of charging
CN116075059B (en) * 2023-02-27 2023-07-07 健鼎(湖北)电子有限公司 Coated aluminum sheet for PCB drilling and preparation method thereof

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CN114828603A (en) 2022-07-29
CN115260932B (en) 2024-02-20
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CN112143394B (en) 2022-02-11
CN114716929A (en) 2022-07-08

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