CN115251470A - Non-combustible heating sheet, method for producing same, non-combustible heating product, and method for producing same - Google Patents

Non-combustible heating sheet, method for producing same, non-combustible heating product, and method for producing same Download PDF

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Publication number
CN115251470A
CN115251470A CN202110489692.0A CN202110489692A CN115251470A CN 115251470 A CN115251470 A CN 115251470A CN 202110489692 A CN202110489692 A CN 202110489692A CN 115251470 A CN115251470 A CN 115251470A
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China
Prior art keywords
combustible
sheet
smoking
smoke
substrate
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CN202110489692.0A
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Chinese (zh)
Inventor
鲁京序
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Chengdu Youxiang Information Technology Co ltd
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Chengdu Youxiang Information Technology Co ltd
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Priority to CN202110489692.0A priority Critical patent/CN115251470A/en
Publication of CN115251470A publication Critical patent/CN115251470A/en
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40Constructional details, e.g. connection of cartridges and battery parts
    • A24F40/46Shape or structure of electric heating means
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/10Devices using liquid inhalable precursors
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40Constructional details, e.g. connection of cartridges and battery parts
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/50Control or monitoring
    • A24F40/57Temperature control

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  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The invention provides a heating non-combustible sheet and a preparation method thereof, and a heating non-combustible product and a preparation method thereof, and belongs to the technical field of tobacco products. The heat non-combustible sheet of the invention comprises a base material and a smoke generating layer provided on at least one surface of the base material in a printed manner; wherein the thickness of the substrate is less than or equal to 1mm; the smoking layer contains edible smoking agent and biological functional substance, and can gradually release smokable smoke containing the biological functional substance when being heated to the working temperature range; the heating non-combustible sheet is non-combustible in the operating temperature range. The smoke generating layer is formed by a printing mode, and smoke generating agents, biological functional substances and the like in the smoke generating layer can be flexibly selected according to needs, so that the generated smoke has any required taste or effect, and the requirements of various different conditions are met.

Description

Non-combustible sheet and method for producing same, non-combustible product and method for producing same
Technical Field
The invention belongs to the technical field of tobacco products, and particularly relates to a heating non-combustible sheet and a preparation method thereof, and a heating non-combustible product and a preparation method thereof.
Background
The cigarette is a cigarette product which is made by rolling tobacco shreds into strips by using cigarette paper. The cigarette is burnt when being smoked, the temperature can reach 800 ℃, however, in the high-temperature burning process, the cut tobacco can release a large amount of harmful substances, and the health is harmed.
The electronic cigarette is designed by taking the idea of 'heating without combustion', can emit the fragrance of tobacco in the temperature range of less than 350 ℃, and does not generate harmful substances in cigarettes.
The non-combustible heating sheet is a core component for heating the non-combustible electronic cigarette.
Disclosure of Invention
The invention at least partially solves the problem that the existing biological functional substances and smoke agents cannot be flexibly selected, and provides a heating non-combustible sheet and a preparation method thereof, a heating non-combustible product and a preparation method thereof.
In a first aspect of the present invention, there is provided a heat-incombustible sheet comprising a substrate and a smoke generating layer disposed in a printed manner on at least one surface of the substrate; wherein,
the thickness of the substrate is less than or equal to 1mm;
the smoking layer contains edible smoking agent and biological functional substance, and can gradually release smokable smoke containing the biological functional substance when being heated to the working temperature range;
the heating non-combustible sheet is non-combustible in the operating temperature range.
Optionally, the biofunctional substance comprises at least one of:
powder or extract of natural medicine, powder or extract of plant of Nicotiana, food or extract with human-perceived odor, powder or extract of seasoning with human-perceived odor, powder or extract of beverage, artificial synthetic medicine, and artificial synthetic essence.
Optionally, the extract is an essential oil.
Optionally, neither the substrate nor the smoke layer comprises tobacco or extracts thereof.
Optionally, at least one of the substrate and the biofunctional material comprises:
tobacco, and/or, tobacco extract.
Optionally, the operating temperature range is between 100 ℃ and 350 ℃.
Optionally, the smoking layer comprises a plurality of smoking sublayers arranged in a stacked manner, and each smoking sublayer comprises a smoking agent and a biofunctional substance;
each of the sub-smoking layers is disposed on the base material in a printing manner.
Optionally, the substrate is paper or non-woven fabric.
Optionally, at least one surface of the non-combustible heating sheet has a relief structure.
In a second aspect of the present invention, a heat-incombustible article, comprises:
the heating of the embodiment of the invention does not burn the thin sheet;
and/or the presence of a gas in the gas,
the heating of the embodiments of the present invention does not burn pieces of the flakes.
Optionally, the heat-not-burn article comprises:
the rolled sheet is not burned by heating.
In a third aspect of the present invention, a method for producing a heat nonflammable sheet, comprises:
forming a smoking layer on at least one surface of a substrate by printing;
wherein,
the thickness of the substrate is less than or equal to 1mm;
the smoking layer contains edible smoking agent and biological functional substance, and can gradually release smokable smoke containing the biological functional substance when being heated to the working temperature range;
the heated non-combustible sheet is non-combustible within the operating temperature range.
Optionally, the biofunctional substance comprises at least one of:
powder or extract of natural medicine, powder or extract of plant of Nicotiana, food or extract with human-perceived smell, powder or extract of seasoning with human-perceived smell, powder or extract of beverage, artificial synthetic medicine, and artificial synthetic essence.
Optionally, the extract is an essential oil.
Optionally, neither the substrate nor the smoke layer comprises tobacco and extracts thereof.
Optionally, at least one of the substrate and the biofunctional material comprises:
tobacco, and/or, tobacco extract.
Optionally, the forming a smoking layer on a substrate by printing comprises: forming a smoking layer on the substrate by at least one printing process; each of the printing processes comprises:
printing the oil composition on the substrate in a printing mode to form an oil composition layer; wherein the oil composition comprises a smoke agent and a biologically functional substance;
and drying the substrate printed with the oil composition layer.
Optionally, the smoking layer comprises a plurality of stacked smoking sub-layers;
the forming a smoking layer on a substrate by printing comprises: forming a plurality of the sub-smoking layers on the substrate by a plurality of printing processes.
Optionally, the oil composition further comprises a thickener.
Optionally, the oil composition further comprises a solvent, the solvent comprising: water, and/or alcohol.
Optionally, the operating temperature range is between 100 ℃ and 350 ℃.
Optionally, the substrate comprises paper or nonwoven.
In a fourth aspect of the present invention, a method for producing a heat-incombustible article, comprising:
rolling and heating the non-combustible thin sheets;
and/or the presence of a gas in the atmosphere,
chopping the non-combustible heating sheet to obtain crushed materials of the non-combustible heating sheet;
wherein the non-combustible heating sheet is the non-combustible heating sheet of the embodiment of the invention, or the non-combustible heating sheet is the non-combustible heating sheet prepared by the preparation method of the embodiment of the invention.
The heating non-combustion sheet in the embodiment of the invention does not combust in the working temperature range, and harmful substances cannot be generated due to combustion, so that the generated smoke has no harm to users and cannot influence the health of the users; in addition, the fuming layer is formed by a printing mode, so that the fuming layer is uniform in thickness and uniform in releasing process; meanwhile, the smoke agent, the biological functional substance and the like in the smoke layer can be flexibly selected according to the needs, so that the generated smoke has any required taste or effect, and the needs of various different conditions are met.
Drawings
FIG. 1 is a schematic side view of a heated non-combustible sheet according to an embodiment of the invention;
FIG. 2 is a schematic side view of a heated non-combustible sheet having a textured structure in accordance with an embodiment of the invention;
FIG. 3 is a schematic side view of another heated non-combustible sheet having a textured structure according to an embodiment of the invention;
FIG. 4a is a cross-sectional view of a heated non-combustible article according to an embodiment of the invention;
FIG. 4b is a cross-sectional view of yet another heated non-combustible article according to an embodiment of the invention;
FIG. 4c is a cross-sectional view of still another heat-not-combustible article according to an embodiment of the invention;
FIG. 4d is a cross-sectional view of another heat-not-burn article according to an embodiment of the present invention;
FIG. 5 is a flow chart of a method for preparing a heated non-combustible sheet according to an embodiment of the invention;
FIG. 6 is a flow chart of another method of making a heated non-combustible sheet according to an embodiment of the invention;
FIG. 7 is a flow chart of a method for producing a heated non-combustible article according to an embodiment of the invention;
FIG. 8 is a schematic side view of a non-combustible heat-generating sheet according to still another embodiment of the present invention.
Wherein the reference numerals are: 11. a substrate; 12. a smoke layer; 121. a smoke generating agent base layer; 122. particles of a biologically functional material; 13. the sheet is not burned by heating.
Detailed Description
In order to make the technical solutions of the present invention better understood, the present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
It is to be understood that the specific embodiments and figures described herein are merely illustrative of the invention and are not limiting of the invention.
It is to be understood that the embodiments of the invention and features of the embodiments may be combined with each other without conflict.
It is to be understood that only portions related to embodiments of the present invention are shown in the drawings for convenience of description, and portions not related to embodiments of the present invention are not shown in the drawings.
It is to be understood that the functions and steps noted in the flowcharts and block diagrams of the embodiments of the present invention may occur out of the order noted in the figures without conflict.
In some related art, heated non-burning electronic cigarettes employ a cartridge as the object of actual smoking. The cartridge may be in the form of a Tobacco Sheet (Tobacco Sheet) the main component of which is Tobacco leaf, so that a Paper-process Reconstituted Tobacco (abbreviated as Paper recon) is also weighed.
The tobacco sheet can be prepared by a paper making method, a roll pressing method, or the like.
The paper-making method is to mix tobacco stems, tobacco fragments and the like as main raw materials with other fibers (for example, wood pulp fibers, hemp pulp fibers or bamboo pulp fibers), and then form tobacco sheets by the paper-making method from the mixed materials.
The rolling method is that the tobacco leaves are ground into powder, then adhesive and other fibers are added, and the mixed material is pressed into tobacco sheets through rolling images.
As a first aspect of the present invention, referring to fig. 1, there is provided a heat non-combustible sheet comprising a base material 11 and a smoke generating layer 12 disposed on the base material 11 in a printing manner; wherein,
the smoking layer 12 contains edible smoking agent and biological functional substance; the thickness of the substrate 11 is less than or equal to 1mm;
when the smoke layer 12 is heated to the working temperature range, the smoke which comprises the biological functional substances and can be sucked can be gradually released;
the heated non-combustible sheet is non-combustible within the operating temperature range.
The heating non-combustion sheet (HNB) of the embodiment of the invention can be used in the heating non-combustion electronic cigarette, and is particularly used as an actual smoking object (smoke cartridge) in the heating non-combustion electronic cigarette.
The heating non-combustible sheet of the embodiment of the invention has a substantially sheet-like base material 11, and a smoking layer 12 formed by printing is provided on at least one surface of the base material 11.
Wherein, the printing in the embodiment of the invention refers to: a liquid material (e.g., an oil composition) is applied to a medium (e.g., a screen printing plate) and the medium is brought into contact with a substrate (e.g., substrate 11 above) to form a layer of the liquid material (e.g., a layer of the oil composition) on the substrate, and the layer of the liquid material, after drying, forms a layer on the substrate formed by printing (e.g., smoke layer 12 above).
It should be understood that the structure of the layer formed by printing is different from the structure of the layer formed by spraying or the like due to the difference in processes. For example, a layer formed by printing may be depressed by pressure on a surface of a substrate corresponding to the layer, while a layer formed by spraying may be absorbed and fused into the substrate, so that an independent layer structure cannot be formed; for another example, a layer formed by printing may have a uniform thickness, while a layer formed by spraying may have a structure in which the middle region is thicker than the edge regions.
The base material 11 is a base for supporting the smoke layer 12, and has a sheet shape with a thickness of 1mm or less, more preferably 0.05mm to 1mm, and still more preferably 0.2mm to 0.8mm.
When the thickness of the base material 11 is less than 0.05mm, the base material 1 is too thin and too soft, which is not beneficial to forming the smoking layer 12 on the base material 11 by printing and is also not beneficial to forming a non-combustible product by rolling; when the thickness of the base material 11 is greater than 1mm, the base material 11 is hard and inconvenient to roll, and also causes waste of materials.
The smoking layer 12 is printed on the above substrate 11, and contains edible smoking agent and biological functional substance.
Therefore, when the smoke layer 12 is heated to the working temperature range, the edible smoke can be gradually released, and the smoke contains the edible biological functional substances; for example, the smoke agent, which may be the smoke layer 12, is converted to smoke and carries the above biofunctional material.
The substrate 11 may also release the edible biofunctional material, or may not release any material, when heated to within the operating temperature range, and will not be described in detail herein.
The smoke agent is a substance which is converted into smoke in an operating temperature range, and can comprise glycerol (glycerin), propylene glycol, xylitol and the like, which are edible and have a proper smoke temperature (such as a boiling point); for example, glycerol has a boiling point of 290 deg.C, xylitol has a boiling point of 212 deg.C, and propylene glycol has a boiling point of 184 deg.C.
The amount of smoke agent in the smoking layer 12 may be varied depending on the desired time of smoke release, for example the time of smoke release may be adjusted to 5 to 8 minutes (typically the time of smoking a cigarette).
The biofunctional material may be released together into the smoke to produce the desired effect during smoking. The amount of biofunctional material in the smoke layer 12 may be varied depending on the desired concentration of biofunctional material in the smoke.
Meanwhile, all the structures (including the base material 11 and the smoke generating layer 12) in the heat non-combustible sheet of the embodiment of the invention do not burn in the operating temperature range.
Thus, by heating the material comprising the heated non-combustible sheet of embodiments of the invention to within the operating temperature range, it is possible to produce edible smoke and biofunctional material in a sustained manner, thereby giving the user the sensation of smoking.
The heating non-combustion sheet disclosed by the embodiment of the invention does not combust in the working temperature range, and harmful substances cannot be generated due to combustion, so that the generated smoke has no harm to a user and cannot influence the health of the user; in addition, because the smoking layer 12 is formed by printing, the thickness of the smoking layer 12 is uniform, and the releasing process is also uniform; meanwhile, the smoke agent, the biological functional substance and the like in the smoke layer 12 can be flexibly selected according to the needs, so that the generated smoke has any required taste or effect and meets the needs of various conditions.
As a specific embodiment, neither the substrate 11 nor the smoking layer 12 includes tobacco and extracts thereof.
In this case, the non-combustible heat sheet according to the embodiment of the present invention does not have a tobacco flavor during smoking, and can be smoked with other biofunctional substances added thereto.
As another specific embodiment, at least one of the biofunctional materials of the substrate 11 and the smoking layer 12 comprises: tobacco, and/or, tobacco extract.
In this case, the non-combustible heating sheet according to the embodiment of the present invention has a tobacco flavor during smoking. Of course, other biofunctional substances may be included in the smoking layer 12 in this case.
In some alternative embodiments, the substrate 11 is constructed of a flexible material so as to be bendable.
In some alternative embodiments, the substrate 11 comprises paper or nonwoven.
Specifically, paper, nonwoven fabric, or the like can be selected as the substrate 11.
When the tobacco and its extract are not included in the substrate 11, conventional paper or nonwoven fabric may be directly used as the substrate 11, so that it is not necessary to prepare a specially-made substrate.
In some embodiments, the paper as the substrate 11 may be wood pulp paper.
Because wood-pulp paper has better absorbency than non-wood-pulp paper, the oil composition can be absorbed quickly after printing onto the substrate 11; furthermore, the wood pulp paper has better toughness, and can prevent the base material 11 from cracking during printing or during use of the non-combustible sheet.
It should be understood that the properties of the substrate 11 (e.g., material, thickness, grammage, stiffness, tension, toughness) should all meet the requirements of a particular printing process and printing equipment.
For example, the printing process applicable to the present invention may be classified into screen printing (silk screen printing), flat printing, gravure printing, letterpress printing, and the like, depending on the form of the medium surface. The printing process may be classified into a flat printing, a roll printing, etc. according to the shape of its medium. The requirements of the substrate 11 for different printing processes are also different.
Illustratively, when the substrate 11 is paper, the grammage may be 40 to 120g/m2And further 50 to 110g/m2Further, it is 60 to 100g/m2,80~100g/m2And so on.
For example, when the printing apparatus is a flat-bed printing apparatus (including a flat-bed screen printing apparatus), since the substrate 11 is transferred by using a transfer belt, the transfer belt tends to have a gap in the middle thereof, and if the substrate 11 is too soft and stiff, it tends to leak from the gap in the middle of the transfer belt, and therefore, the substrate 11 should have a high stiffness, for example, 70g/m2~120g/m2The paper of (1); further, the substrate 11 may be 70g/m2~110g/m2To enable printing of continuous paper feed; further, the substrate 11 may be 80g/m2~100g/m2The paper is suitable for continuous industrial production.
For another example, when the printing apparatus is a roll printing apparatus (including a roll screen printing apparatus), the substrate 11 is required to be wound into a roll, and the roll is wound to gradually pull out the substrate 11 during printing, so thatIn this way, the toughness requirement of the substrate 11 is high to ensure that the substrate 11 is not torn during the pulling process, and the requirements on the thickness, gram weight and the like of the substrate 11 are not obvious, and 70g/m can be used2Below, for example 60g/m2Or 50g/m2As the substrate 11.
As another example, when the printing apparatus is a roll printing apparatus (including a roll screen printing apparatus), a nonwoven fabric (such as a dry-process papermaking nonwoven fabric or a wet-process nonwoven fabric) may also be used as the substrate 11.
For example, when the printing apparatus is a sheet printing apparatus and sheets are manually fed one by one, the substrate 11 is required to have low toughness, thickness, grammage, and the like, and thin paper or nonwoven fabric can be used as the substrate 11.
In some alternative embodiments, the operating temperature range is between 100 ℃ and 350 ℃, such as between 150 ℃ and 350 ℃, between 200 ℃ and 300 ℃, between 250 ℃ and 300 ℃, and the like.
If the working temperature is too high, the mouth may be burnt, the user experience is reduced, and if the working temperature is too low, the smoke generation amount is insufficient, and only research finds that the above temperature range is suitable.
It will be appreciated that the nature of the smoke producing agent and the biologically functional substance is such that the smoke bed 12 is capable of gradually releasing (e.g. converting to) smoke at the heating temperature (operating temperature range) during smoking.
For example, the smoke generation temperature (e.g., boiling point) of the smoke generator should be below the lower end of the above operating temperature range. For example, when the lower limit of the working temperature range is 300 ℃, xylitol with a boiling point of 212 ℃ or glycerol with a boiling point of 290 ℃ can be used as the smoke agent.
Meanwhile, the temperature (such as the emission, volatilization or sublimation temperature) of the biological functional substances released along with the smoke is lower than the lower limit of the working temperature range. For example, when the lower limit of the working temperature range is 300 ℃, the emission, volatilization or sublimation temperature of the biofunctional material should be lower than 300 ℃.
In the present invention, the biofunctional substance is a substance which can be carried out by a smoking agent within an operating temperature range and can exert a certain physiological effect on a human body after being taken by the human body. For example, the biofunctional substance may cause a person to feel "smell" or "taste" to affect a person's mental state (e.g., mood), or the biofunctional substance may act to excite or inhibit a person's nerves, or the biofunctional substance may act to dilate or constrict a person's blood vessels, or the biofunctional substance may act to promote or delay a person's interstitial fluid metabolism, etc.
Specifically, the biofunctional substance includes at least one of: powder or extract of natural medicine, powder or extract of plant of Nicotiana, food or extract with human-perceived smell, powder or extract of seasoning with human-perceived smell, powder or extract of beverage, artificial medicine, and artificial essence.
The natural medicine can be specifically: botanical or animal medicine. Animal drugs include, but are not limited to, for example, bear gall, snake venom, deer antler, oviductus ranae, bezoar, musk, and the like. Botanical drugs include, but are not limited to, for example, ginseng, ganoderma lucidum, polygonum multiflorum, lycium barbarum, gastrodia elata, atractylodes, cassia twig, white peony, and the like. Among natural drugs, those having aromatic odor are more preferable, for example, musk, dried orange peel, mugwort leaf, schizonepeta, cassia twig, chrysanthemum, wrinkled gianthyssop herb, fortune eupatorium herb, swordlike atractylodes rhizome, clove, tsaoko cardamom, villous amomum fruit, agilawood, frankincense, myrrh, zedoary, sanling, peppermint, perilla leaf, dahurian angelica root, tree peony bark, slenderstyle acanthopanax bark, thinleaf milkwort root-bark, nutgrass galingale rhizome, benzoin, ephedra (including various ephedra plants), and the like.
The genus nicotiana has about 60 species worldwide, and the effective parts are mainly stems and leaves thereof, particularly tobacco leaves. The tobacco leaf extract is typically a fine brown-yellow powder, which includes tobacco leaf protein, tobacco cellulose, nicotine, and the like. Nicotine itself may also be used as a specific example of a tobacco extract.
Odors that may be perceived include, but are not limited to, for example, spicy, hot, sour, bitter, sweet, and the like, as well as sour, sweet, hot, spicy, and the like. Those having a "scent" that refreshes, and resuscitates, e.g., essential oils, are preferred in some embodiments.
Food includes, but is not limited to, vegetables and fruits. Vegetables include, but are not limited to, for example, onions, caraway, celery, peppers, cucumbers, perilla leaves, cedrela sinensis, mint leaves, and the like; fruits include, but are not limited to, for example, oranges, apples, peaches, strawberries, melons, muskmelons, and the like. Condiments include, but are not limited to, for example, anise, ginger, pepper, prickly ash, dried chili, fennel, bay leaf, and the like. Beverages include, but are not limited to, for example, coffee, tea, plum syrup, powdered fruit juice, powdered coconut, powdered cocoa, and the like.
In some alternative embodiments, the extract is an essential oil.
Essential oil is a generic term for volatile aromatic-containing substances extracted from aromatic plants or secreted animals, and can be used for relieving fatigue, relieving stress, relaxing spirit, etc. Generally, the essential oil is a volatile aromatic substance extracted from flowers, leaves, roots, seeds, fruits, barks, resins, hearts and the like of plants by steam distillation, cold pressing, fat absorption or solvent extraction, and can be divided into single essential oil and compound essential oil. In some alternative embodiments, the essential oil includes, but is not limited to, essential oils extracted from sandalwood, agilawood, lavender, lemon, rosemary, bergamot, geranium, chamomile, jasmine, rose, grape seed, almond, or the like.
As the biologically functional substance, a synthetic drug or a pharmaceutical preparation thereof such as budesonide, triamcinolone acetonide, mometasone furoate, dexamethasone, fluticasone, or the like can also be used.
Wherein the natural medicinal materials (or plants of Nicotiana, food, seasoning, beverage, etc.) can be directly ground into powder as the biofunctional substance, or water or ethanol extract of the natural medicinal materials can be used as the biofunctional substance. Or decocting the above natural materials to obtain decoction, extracting medicinal components from the decoction, and blowing to obtain powder as biological functional substance. Among these, the technical means of milling, extraction, blowing etc. are known in the prior art.
Wherein, the specific form of the biological functional substance can be determined according to the requirement. For example, when higher concentrations of biofunctional material are required, the above powders may be employed.
In some alternative embodiments, the powder of biofunctional material may have a particle size generally in the range of from 0.1 to 250 microns, such as from 10 to 230 microns, such as from 50 to 200 microns.
In some alternative embodiments, the biofunctional material is a micropowder, for example, having a particle size in the range of from 0.1 to 10 microns, further in the range of from 0.5 to 5 microns, further in the range of from 1 to 4 microns.
In some alternative embodiments, referring to fig. 8, the smoke generating layer 12 comprises a smoke generating substrate 121 and a powder 122 of a biofunctional material distributed in the smoke generating substrate 121.
When the biofunctional substance is completely in a powder state, the fuming agent forms a continuous layer structure, namely a fuming agent base layer 121, in the fuming layer 12; the particles of the above biofunctional material (biofunctional material powder 122) are distributed in the smoke agent base layer 121 and fixed by the smoke agent base layer 121.
In the case of preparing the heat nonflammable sheet, a solvent (water and/or ethanol), a biofunctional substance, and a smoke generating agent (propylene glycol and/or glycerin) may be mixed in an appropriate ratio to form an oil composition, and the oil composition may be printed on the base material 11 and dried to form the smoke generating layer 12.
Where the oil composition is "thick" (too viscous), the addition of propylene glycol and/or glycerol, or solvent, may be continued until the oil composition has the appropriate viscosity.
If the oil composition is "thin" (too low in viscosity), a thickener such as starch, alginic acid, carboxymethyl cellulose, or the like may be added thereto until the oil composition has a suitable viscosity.
The proper viscosity means that the oil composition cannot stick to a medium (such as a silk screen printing plate) because of being too thin, and the oil composition cannot be printed on a base material because the oil composition always sticks to the medium (such as the silk screen printing plate) because of being too thick.
It has been found through testing that the viscosity of the oil composition may be between 4000 and 12000 centipoise, such as between 5000 and 10000 centipoise, and such as between 6000 and 8000 centipoise.
In some alternative embodiments, the smoking layer 12 comprises a plurality of stacked smoking sublayers, each comprising a smoke agent and a biofunctional substance; each of the sub-smoking layers is disposed on the base substrate 11 in a printed manner.
The different sub-smoking layers can be the same or different in the content of the bio-functional substances, and the different sub-smoking layers can be the same or different in the content of the bio-functional substances. When the biological functional substances are different substances, the plurality of smoke generating sub-layers emit different aromas in the heating process, so that the layered sense of the aroma can be increased.
Taking screen printing as an example, in the screen printing, the thickness of the layer formed every time of printing is the same, and when the thickness of the single printing layer is thin and the amount of the biofunctional substance contained is low, the content of the biofunctional substance in the non-combustible heating sheet can be increased by arranging a plurality of smoke generating sub-layers.
In some alternative embodiments, at least one surface of the non-burning heating sheet has a concave-convex structure.
To facilitate smoke release and reduce smoke resistance, the heat non-combustible sheet may be "fluffy" rather than "compact".
For this purpose, at least one surface of the non-combustible heating sheet may be given an uneven structure.
Specifically, referring to fig. 2, on an originally flat surface of a non-combustible heated sheet (e.g., substrate 11), depressions and projections are formed on the surface by means of press-forming deformation or the like, so that the surface has the above uneven structure.
Of course, the uneven structure may be formed by pressing and deforming two originally flat sheets of the non-combustible sheet.
In some alternative embodiments, the heat-not-burn sheet is waved.
Referring to fig. 3, the entire shape of the non-combustible heating sheet (particularly, the shape of the base material 11) may be in the form of waves, creases, wrinkles, or the like, and both side surfaces of the non-combustible heating sheet may naturally be in the form of waves, creases, or wrinkles, and may have the above concavo-convex structure.
It should be understood that the "wave-like" in fig. 3 is merely exemplary, and "wave-like" also includes "bent" and the like having sharp corners.
As a second aspect of the present invention, referring to fig. 4a to 4d, there is also provided a heat nonflammable article including the heat nonflammable sheet 13 of the embodiment of the present invention, and/or the crushed pieces of the heat nonflammable sheet 13 of the embodiment of the present invention.
The heat non-combustible product of the embodiment of the invention can be used as a cartridge of a heat non-combustible electronic cigarette pack.
In some alternative embodiments, the heat incombustible article includes a rolled heat incombustible sheet 13.
In some alternative embodiments, the heat incombustible article includes a heat incombustible sheet 13 wound in multiple layers about an axis.
The above "rolling" means that the non-combustible heating sheet 13 is "rolled" into "one turn" or "a plurality of turns" around an axis, and then the non-combustible heating sheet can be fixed by dispensing on the edges to obtain the non-combustible heating product shown in fig. 4 a.
In which a "channel" is generally formed in the center of the heat non-combustible product, and in order to prevent air leakage, the winding start edge of the heat non-combustible sheet 13 may be previously tightly wound as a "thin stick", or the winding start edge of the heat non-combustible sheet 13 may be previously folded.
Alternatively, the heat nonflammable sheet 13 may be folded in half first, and then the folded heat nonflammable sheet 13 may be "wound" to obtain a heat nonflammable product having a "double-layered" heat nonflammable sheet 13 as shown in fig. 4 b.
Alternatively, the surface of the heat non-combustible sheet 13 has an uneven structure such as a crease, a wrinkle, a wave, etc., and the heat non-combustible sheet 13 having an uneven structure on the surface is wound to obtain a heat non-combustible product having an uneven structure as shown in fig. 4c, wherein the uneven structure of the heat non-combustible sheet 13 is indicated by a dotted line.
The final winding compactness can be determined according to the thickness of the base material 11, the required suction resistance and the like, so that the situation that the smoke is diluted by air to reduce the taste is ensured to be not only easy to draw out, but also not easy to draw out excessive air.
In some embodiments, referring to fig. 4d, heating a non-combustible article includes heating non-combustible crushed material formed by heating non-combustible sheet 13. Wherein the crushed aggregates are in the form of fine powder, filaments and the like.
Wherein, the particles which are not burnt when being heated have certain fluffiness, so as to be convenient for releasing the smoke and reducing the suction resistance. Thus, when the heat-incombustible article is a heat-incombustible crushed material, the material of the base material is preferably soft, thin, rather than hard, thick. For example, when the substrate is wood pulp paper, a grammage of 40-70g/m may be used2For example, 50g/m2Or 60g/m2Thinner paper.
In some alternative embodiments, the heat-not-burn article includes an enclosure and particles of heat-not-burn chips 13 located within the enclosure.
In which the pieces of heated non-combustible material (pieces of heated non-combustible sheet 13) may be packed in other structures (envelopes), for example, in a "cigarette" type structure, the paper of which corresponds to the above envelope, and the cut tobacco of which corresponds to the above pieces of heated non-combustible material (pieces of heated non-combustible sheet 13).
For example, referring to fig. 4d, the inclusions may be the above non-combustible sheet 13, i.e. pieces of the heat non-combustible sheet 13 are packed in a "roll" of the heat non-combustible sheet 13.
Fig. 4a, 4b, 4c, and 4d are merely exemplary illustrations of relative relationships between the portions of the non-combustible heating sheet 13, and do not represent specific dimensional ratios, numbers, and the like.
The diameter, length, etc. of the whole of the non-combustible heat-generating article may be determined according to the size range of the heater for heating the non-combustible electronic cigarette, and will not be described in detail herein.
As a third aspect of the present invention, referring to fig. 5, an embodiment of the present invention provides a method of manufacturing a heated non-combustible sheet, including:
s301, a smoking layer is printed on at least one surface of the base material.
Wherein the smoke layer contains edible smoke agent and biological functional material; the thickness of the base material is less than or equal to 1mm;
when the smoke layer is heated to the working temperature range, smokable smoke containing biological functional substances can be gradually released;
the heated non-combustible sheet is non-combustible within an operating temperature range.
A method for producing the above heat nonflammable sheet, comprising forming the above smoke layer on the above substrate by printing.
In the present invention, the bio-functional substance is a substance which can be carried out by the smoking agent within the working temperature range and can exert a certain physiological effect on a human after being inhaled by the human. For example, a biofunctional substance may cause a person to feel "smell" or "taste" and thus affect a person's mental state (e.g., mood), or a biofunctional substance may act as an stimulant or depressant to a person's nerves, or a biofunctional substance may act as a dilator or constrictor to a person's blood vessels, or a biofunctional substance may act as a promoter or retardant to a person's interstitial fluid metabolism.
Specifically, the biofunctional substance includes at least one of: powder or extract of natural medicine, powder or extract of plant of Nicotiana, food or extract with human-perceived odor, powder or extract of seasoning with human-perceived odor, powder or extract of beverage, artificial synthetic medicine, and artificial essence.
The natural medicine can be specifically: plant medicine or animal medicine. Animal drugs include, but are not limited to, for example, bear gall, snake venom, deer antler, oviductus ranae, bezoar, musk, and the like. Botanical drugs include, but are not limited to, for example, ginseng, ganoderma lucidum, polygonum multiflorum, lycium barbarum, gastrodia elata, atractylodes, cassia twig, white peony, and the like. Among natural drugs, those having aromatic odor are more preferable, for example, musk, dried orange peel, mugwort leaf, schizonepeta, cassia twig, chrysanthemum, wrinkled gianthyssop herb, fortune eupatorium herb, swordlike atractylodes rhizome, clove, tsaoko cardamom, villous amomum fruit, agilawood, frankincense, myrrh, zedoary, sanling, peppermint, perilla leaf, dahurian angelica root, tree peony bark, slenderstyle acanthopanax bark, thinleaf milkwort root-bark, nutgrass galingale rhizome, benzoin, ephedra (including various ephedra plants), and the like.
The genus nicotiana plants are about 60 species worldwide, and their effective parts are mainly stems and leaves thereof, particularly tobacco leaves. The tobacco leaf extract is typically a fine brown-yellow powder, which includes tobacco leaf protein, tobacco cellulose, nicotine, and the like. Nicotine itself is also a specific example of a tobacco extract.
Odors that may be perceived include, but are not limited to, for example, spicy, hot, sour, bitter, sweet, and the like, as well as sour, sweet, hot, spicy, and the like. Those having a "scent" that refreshes, and resuscitates, e.g., essential oils, are preferred in some embodiments.
Food includes, but is not limited to, vegetables and fruits. Vegetables include, but are not limited to, for example, onions, caraway, celery, peppers, cucumbers, perilla leaves, cedrela sinensis, mint leaves, and the like; fruits include, but are not limited to, for example, oranges, apples, peaches, strawberries, melons, muskmelons, and the like. Condiments include, but are not limited to, for example, anise, dried ginger, pepper, pricklyash, dried chili, fennel, bay leaf, and the like. Beverages include, but are not limited to, for example, coffee, tea, prune, juice powder, coconut powder, cocoa powder, and the like.
In some alternative embodiments, the extract is an essential oil.
Essential oil is a generic term for volatile aromatic-containing substances extracted from aromatic plants or secreted animals, and can be used for relieving fatigue, relieving stress, relaxing spirit, etc. Generally, the essential oil is a volatile aromatic substance extracted from flowers, leaves, roots, seeds, fruits, barks, resins, hearts and the like of plants by steam distillation, cold pressing, fat absorption or solvent extraction, and can be divided into single essential oil and compound essential oil. In some alternative embodiments, the essential oil includes, but is not limited to, essential oils extracted from sandalwood, agilawood, lavender, lemon, rosemary, bergamot, geranium, chamomile, jasmine, rose, grape seed, almond, or the like.
As the biologically functional substance, a human synthetic drug or a pharmaceutical preparation thereof, such as budesonide, triamcinolone acetonide, mometasone furoate, dexamethasone, fluticasone, or the like, can also be used.
Wherein the natural medicinal materials (or plants of Nicotiana, food, seasoning, beverage, etc.) can be directly ground into powder as the biological functional substance, or water or ethanol extract of the natural medicinal materials can be used as the biological functional substance. Or decocting the above natural materials to obtain decoction, extracting medicinal components from the decoction, and blowing to obtain powder as biological functional substance. Among these, the technical means of milling, extraction, blowing etc. are known in the prior art.
Wherein, the specific type of the above biological functional substance can be determined according to the requirement. For example, when higher concentrations of biofunctional material are required, the above powders may be employed.
In some alternative embodiments, the powder of biofunctional material may have a particle size generally in the range of from 0.1 to 250 microns, such as from 10 to 230 microns, such as from 50 to 200 microns.
In some alternative embodiments, the biofunctional material is a micropowder, for example, having a particle size in the range of from 0.1 to 10 microns, further in the range of from 0.5 to 5 microns, further in the range of from 1 to 4 microns.
Wherein, the base material is the base for bearing the fuming layer, is in a sheet shape, and has the thickness of less than or equal to 1mm, further 0.05 mm-1 mm, and further 0.2 mm-0.8 mm.
In some alternative embodiments, the base material is constructed of a flexible material so as to be bendable.
In some alternative embodiments, the substrate comprises paper or nonwoven.
Illustratively, when the substrate 11 is paper, the grammage may be 40 to 120g/m2And further from 50 to 110g/m2Further, it is 60 to 100g/m2,80~100g/m2And the like.
As a specific embodiment, neither the substrate nor the smoking layer comprises tobacco and extracts thereof.
As another specific embodiment, at least one of the biofunctional material of the substrate and smoking layer comprises: tobacco, and/or tobacco extract.
In some alternative embodiments, the operating temperature range is between 100 ℃ and 350 ℃, such as between 150 ℃ and 350 ℃, between 200 ℃ and 300 ℃, between 250 ℃ and 300 ℃, and the like.
In some alternative embodiments, forming the smoking layer on the substrate in a printed manner (S301) comprises: forming a smoking layer on the substrate by at least one printing process; each printing process comprises the following steps:
printing the oil composition on a substrate in a printing mode to form an oil composition layer; wherein the oil composition comprises a smoke agent and a biologically functional substance;
the substrate on which the oil composition layer is printed is dried.
The printing process to form the above smoke generating layer may comprise printing on the substrate a layer forming a liquid oil composition comprising the above smoke generating agent and the biofunctional material such that it dries to form the above smoke generating layer.
In some embodiments, the oil composition further comprises a solvent that is used with the smoke generator used to render the oil composition as a whole in a printable liquid state.
The smoke agent is liquid at room temperature, and has the capability of fusing with biological functional substances, and a solvent is not required to be added in some cases.
In some alternative embodiments, the solvent comprises: water, and/or alcohol.
The solvent may include water from an inexpensive and convenient standpoint. And the solvent may include volatile alcohol in order to accelerate the drying rate of the oil composition layer.
Water and alcohol may also be used in the solvent to achieve better results. For example, if the alcohol concentration is too high, a large amount of alcohol vapor is released in the drying process, so that explosion and ignition are easy to occur, and potential safety hazards are caused; if the concentration of the essence of the fruit wine is too low, the fruit wine needs to be dried for a longer time.
The content of the solvent, the smoke agent and the biological functional substance in the oil composition can be set according to the requirement.
If the viscosity of the oil composition is relatively high (too "thick"), the amount of solvent and/or smoke agent in the oil composition can be increased.
In some alternative embodiments, the oil composition further comprises a thickener.
Thickeners may also be included if the viscosity of the oil composition is low (too "thin"). The thickening agent may also be an edible substance, for example the thickening agent may comprise at least one of starch, alginic acid, carboxymethyl cellulose.
In particular, when a large amount of essential oil is included in the biofunctional material, a thickener may be used to increase the viscosity of the oil composition.
When the biofunctional material comprises a large amount of micropowder, the thickener may be omitted or used sparingly, because micropowder itself can cause the oil composition to form an emulsion or even a suspension, which itself has a higher viscosity.
As another example, when the biofunctional material comprises pectin (e.g., pectin), no or little thickening agent may be used.
Whether and how much thickener is used in the oil composition depends on the viscosity of the oil composition. It is generally preferred to control the viscosity to be in the range 4000 to 12000 centipoise, such as in the range 5000 to 10000 centipoise, and such as in the range 6000 to 8000 centipoise.
In some alternative embodiments, forming the smoking layer on the substrate by printing comprises: a smoke layer is formed on a substrate through a plurality of printing processes.
When the oil composition has a low viscosity (or is relatively "thin"), it is difficult to form a layer having a sufficient thickness by one-time printing, so that the above smoke layer can be formed by a plurality of printing processes.
Wherein the oil composition should have a suitable viscosity. The proper viscosity means that the oil composition cannot be adhered to a medium (such as a silk screen printing plate) due to over-dilution, and the oil composition cannot be printed on a substrate due to the fact that the oil composition is always adhered to the medium (such as the silk screen printing plate) due to over-thickening.
In some alternative embodiments, referring to fig. 6, the method for preparing a heated non-combustible sheet according to the embodiments of the present invention further includes:
and S302, forming a concave-convex structure on at least one surface of the heating non-combustion sheet.
Alternatively, the manner of forming the concave-convex structure includes pressing, folding, and the like.
S302 may be performed before S301, that is, the concave-convex structure is formed on the substrate, and then the smoke layer is formed on the substrate by printing.
S302 may be performed after S301, that is, the smoke layer is formed on the substrate by printing to obtain a complete heat non-combustible sheet, and then the concavo-convex structure is formed on the complete heat non-combustible sheet.
The heat-nonflammable sheet is made "fluffy" rather than "compact" by step S302, so as to facilitate release of smoke and reduce draw resistance.
The method for producing the non-combustible sheet by heating according to the present invention will be described in detail with reference to specific examples. Percentages in the following specific examples are percentages by mass and materials used are commercially available food grade products, if not otherwise specified.
First, an oil composition is prepared. Mixing 25% of propylene glycol and 25% of glycerol to obtain a smoke agent solution, adding 40% of coffee powder and the balance of water and/or ethanol into the smoke agent solution, wherein the particle size of coffee powder particles is 100-200 meshes, and stirring to uniformly mix the coffee powder and the smoke agent solution to obtain an oil composition;
second, the oil composition is printed onto the substrate using screen printing;
thirdly, the substrate printed with the oil composition is heated and cured at 50 ℃ for 30 minutes to obtain a heat non-combustible sheet.
Rolling the sheet to obtain a cigarette. The cigarette is filled into an electronic smoking set as a cartridge, and has the fragrance of coffee when being smoked by people after being heated to the working temperature.
The smoke layer may also be printed with an oil composition containing tobacco leaf extract. An exemplary formulation of the oil composition comprises: the tobacco leaf extract, the smoke agent and the deionized water comprise the following components in percentage by mass: 18 to 45 percent of tobacco leaf extract, 30 to 45 percent of fuming agent, 10 to 22 percent of deionized water and the balance of thickening agent; the smoke agent consists of the following components: the glycerol xylitol refining agent comprises propylene glycol, glycerol and xylitol liquid, wherein the mass percentage of each component is as follows: 20 to 60 percent of propylene glycol, 30 to 50 percent of glycerin and 10 to 30 percent of xylitol.
Rolling the sheet containing tobacco extract in the smoke layer to obtain a real cigarette. The cigarette is filled into an electronic smoking set as a cigarette cartridge, and has stronger tobacco fragrance when being smoked by people after being heated to the working temperature, so that the requirement of most smokers on smoking can be well met.
It should be understood that in the above embodiments, the components and proportions of the oil composition, the specific printing manner and the parameters of the heat curing are all exemplified, and can be adjusted according to the situation in the practical application.
As a fourth aspect of the present invention, referring to fig. 7, an embodiment of the present invention provides a method of manufacturing a heat incombustible article, including:
s401, rolling the heating non-combustible sheet; and/or, chopping the non-combustible, heated flakes to obtain crushed material of non-combustible, heated flakes;
wherein the non-combustible heating sheet is the non-combustible heating sheet provided by the present invention, or the non-combustible heating sheet produced by the method for producing a non-combustible heating sheet of the present invention.
The above heat-not-burn product can be obtained by rolling the above heat-not-burn sheet or cutting the heat-not-burn sheet.
It will be understood that the above embodiments are merely exemplary embodiments adopted to illustrate the principles of the present invention, and the present invention is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.

Claims (10)

1. A heat-incombustible sheet, comprising a base material and a smoke generating layer disposed on at least one surface of the base material in a printed manner; wherein,
the thickness of the substrate is less than or equal to 1mm;
the smoking layer contains edible smoking agent and biological functional substance, and can gradually release smokable smoke containing the biological functional substance when being heated to the working temperature range;
the heated non-combustible sheet is non-combustible within the operating temperature range.
2. The heated non-combustible sheet of claim 1, wherein the biofunctional material comprises at least one of:
powder or extract of natural medicine, powder or extract of plant of Nicotiana, food or extract with human-perceived odor, powder or extract of seasoning with human-perceived odor, powder or extract of beverage, artificial synthetic medicine, and artificial synthetic essence.
3. The heated non-combustible sheet of claim 1,
neither the substrate nor the smoke layer comprises tobacco or extracts thereof.
4. The heat non-combustible sheet according to claim 1, wherein at least one of the substrate and the biofunctional substance comprises:
tobacco, and/or, tobacco extract.
5. The heated non-combustible sheet according to any one of claims 1 to 4,
the working temperature range is between 100 ℃ and 350 ℃.
6. The heated non-combustible sheet according to any one of claims 1 to 4,
the smoking layer comprises a plurality of smoking sublayers arranged in a stacked mode, and each smoking sublayer comprises a smoking agent and a biological functional substance;
each of the sub-smoking layers is disposed on the base material in a printing manner.
7. The heated non-combustible sheet according to any one of claims 1 to 4,
at least one surface of the non-combustible heating sheet has a concavo-convex structure.
8. A heat incombustible article, characterized by comprising:
a heat-incombustible sheet according to any one of claims 1 to 7;
and/or the presence of a gas in the gas,
heating scraps of non-combustible sheets as claimed in any one of claims 1 to 7.
9. A method of making a heated non-combustible sheet, comprising:
forming a smoking layer on at least one surface of a substrate by printing;
wherein,
the thickness of the substrate is less than or equal to 1mm;
the smoking layer contains edible smoking agent and biological functional substance, and can gradually release smokable smoke containing the biological functional substance when being heated to the working temperature range;
the heated non-combustible sheet is non-combustible within the operating temperature range.
10. A method for producing a heat-incombustible article, characterized by comprising:
rolling and heating the non-combustible thin sheets;
and/or the presence of a gas in the gas,
chopping the non-combustible heating flakes to obtain crushed materials of the non-combustible heating flakes;
wherein the heat nonflammable sheet is the heat nonflammable sheet according to any one of claims 1 to 7, or the heat nonflammable sheet is a heat nonflammable sheet produced by the production method according to claim 9.
CN202110489692.0A 2021-04-30 2021-04-30 Non-combustible heating sheet, method for producing same, non-combustible heating product, and method for producing same Pending CN115251470A (en)

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Citations (6)

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Publication number Priority date Publication date Assignee Title
CN108451001A (en) * 2017-12-18 2018-08-28 云南中烟工业有限责任公司 A kind of dry process reproduction tobacco leaf and preparation method thereof for heating the cigarette that do not burn
CN110754682A (en) * 2019-12-09 2020-02-07 中国农业科学院烟草研究所 Tobacco sheet, preparation method thereof and cigarette not burning by heating
CN111938191A (en) * 2019-05-17 2020-11-17 南京理工大学 Cigarette with heating function and without combustion by using energy-containing base heat source
CN112237297A (en) * 2020-11-09 2021-01-19 云南纯旭生物科技有限公司 High-smoke-concentration heating non-combustible product
CN112369668A (en) * 2020-11-09 2021-02-19 湖北中烟工业有限责任公司 Cooling functional material and application thereof in heating non-combustible cigarettes
CN215189454U (en) * 2021-04-30 2021-12-17 成都优翔信息技术有限公司 Sheet and product not combustible by heating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108451001A (en) * 2017-12-18 2018-08-28 云南中烟工业有限责任公司 A kind of dry process reproduction tobacco leaf and preparation method thereof for heating the cigarette that do not burn
CN111938191A (en) * 2019-05-17 2020-11-17 南京理工大学 Cigarette with heating function and without combustion by using energy-containing base heat source
CN110754682A (en) * 2019-12-09 2020-02-07 中国农业科学院烟草研究所 Tobacco sheet, preparation method thereof and cigarette not burning by heating
CN112237297A (en) * 2020-11-09 2021-01-19 云南纯旭生物科技有限公司 High-smoke-concentration heating non-combustible product
CN112369668A (en) * 2020-11-09 2021-02-19 湖北中烟工业有限责任公司 Cooling functional material and application thereof in heating non-combustible cigarettes
CN215189454U (en) * 2021-04-30 2021-12-17 成都优翔信息技术有限公司 Sheet and product not combustible by heating

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