CN115232679A - 一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法 - Google Patents
一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法 Download PDFInfo
- Publication number
- CN115232679A CN115232679A CN202210653351.7A CN202210653351A CN115232679A CN 115232679 A CN115232679 A CN 115232679A CN 202210653351 A CN202210653351 A CN 202210653351A CN 115232679 A CN115232679 A CN 115232679A
- Authority
- CN
- China
- Prior art keywords
- cleaning
- sulfamic acid
- cleaning agent
- acid
- pipelines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 43
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000004140 cleaning Methods 0.000 title claims abstract description 38
- 239000002131 composite material Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 150000007524 organic acids Chemical class 0.000 claims abstract description 16
- 229920001281 polyalkylene Polymers 0.000 claims abstract description 16
- 229920000768 polyamine Polymers 0.000 claims abstract description 16
- 230000007797 corrosion Effects 0.000 claims abstract description 12
- 238000005260 corrosion Methods 0.000 claims abstract description 12
- 239000003112 inhibitor Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 20
- 125000003545 alkoxy group Chemical group 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- -1 alkyl primary amine Chemical class 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- BJHZMIPASCHBRO-UHFFFAOYSA-N sulfomethaneperoxoic acid Chemical compound OOC(=O)S(O)(=O)=O BJHZMIPASCHBRO-UHFFFAOYSA-N 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 239000001384 succinic acid Substances 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 235000011044 succinic acid Nutrition 0.000 claims description 2
- 238000011086 high cleaning Methods 0.000 abstract description 4
- 230000007794 irritation Effects 0.000 abstract description 4
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000009920 chelation Effects 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 11
- 239000010865 sewage Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000001516 effect on protein Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法，涉及清洗剂技术领域；按质量份计，包括以下组分：氨基磺酸15‑30份，有机酸6‑12份，烷氧基化聚亚烷基多胺3‑8份，烷氧基化脂肪1‑5份，表面活性剂1‑5份，缓蚀剂0.1‑1份，水20‑60份。本发明的一种用于清洗管道的氨基磺酸复合清洗剂，通过氨基磺酸与有机酸的复配，一方面可以降低氨基磺酸对基材的腐蚀性，另一方面有机酸具有良好的氧化性和螯合性，在与表面活性剂、缓蚀剂的配合下，将污垢进行剥离、浸润、分散、螯合作用，从而实现管道的清洗；其能有效去除成分复杂的管道污垢，其具有去污力强，清洗效率高，刺激性低的特点。
Description
技术领域
本发明属于清洗剂技术领域，具体涉及一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法。
背景技术
管道是用管子、管子联接件和阀门等联接成的用于输送气体、液体或带固体颗粒的流体的装置，常见的输送液体的管道包括自来水管、生活污水管等，由于水中含有大量的矿物质和有机物，使管道内壁积累污垢，且积累的污垢越厚，污水管内径越变越小，从而降低液体的流速，增加堵塞的可能，而且污垢与管壁的长时间接触容易腐蚀管壁，而且容易滋生细菌，因此有必要对管道进行定期的清洗。
管道污垢的清理方法一般包括物理清洗和化学清洗，物理清洗可将体积较大的污垢成块剥离，但是在狭小的空间中进行物理清洗的难度较大，需要进行管道的拆除等繁琐的工作；采用化学清洗能大幅降低劳动强度，提高工作效率，但是目前市面上的强力清洗剂为盐酸与磷酸的混酸，或含有氢氟酸的清洗剂，其去污能力强，但是稳定性差，且对管道腐蚀性强，对人体有较强的刺激性；环境友好型的清洗剂普遍成本较高，但是对输送液体的管道去污性能弱，尤其是生活污水管的顽固污垢中富集有无机盐、蛋白质和微生物代谢物等复杂成分，常规清洗剂的清洗性能无法达到人们的预期。
发明内容
为了克服现有技术的不足，本发明的目的之一在于提供一种用于清洗管道的氨基磺酸复合清洗剂，其去污力强，清洗效率高，稳定性高，刺激性低，能有效去除管道污垢，不易腐蚀管壁。
本发明的目的之二在于提供一种用于清洗管道的氨基磺酸复合清洗剂的制备方法，制备工艺简单，可操作性强。
本发明的目的之一采用如下技术方案实现：
一种用于清洗管道的氨基磺酸复合清洗剂，按质量份计，包括以下组分：
进一步地，所述有机酸为柠檬酸、酒石酸、苹果酸和琥珀酸中的一种或两种以上。
进一步地，所述氨基磺酸和有机酸的质量比为1.5-3:1。
进一步地，所述烷氧基化聚亚烷基多胺的通式为式Ⅰ所示；
其中，A1、A2、A3、A4均为烷氧基基团，B为氢、烷氧基、甲基和乙基的任一种基团，R1、R2为支链或支链的C2-C10的亚烷基基团，x为10-50。
进一步地，所述烷氧基化脂肪醇为含1-4个烷氧基基团的C12-C20高级脂肪醇。
进一步地，烷氧基化聚亚烷基多胺和烷氧基化脂肪醇的质量比为0.8-3:1。
进一步地，所述表面活性剂为脂肪醇聚氧乙烯醚、多羟基脂肪酸酰胺、C10-20烷基苯磺酸中的一种或两种以上。
进一步地，所述缓蚀剂为苯并三氮唑和/或烷基伯胺。
进一步地，还包括磺基过氧羧酸1-3份；磺基过氧羧酸克服了常规过氧羧酸的难闻气味的问题，并提高了稳定性，本发明加入磺基过氧羧酸提高抗菌效果，长效抑制微生物，减少污垢的再生。
本发明的目的之二采用如下技术方案实现：
一种用于清洗管道的氨基磺酸复合清洗剂的制备方法，包括以下步骤：
将配方量的水、氨基磺酸和有机酸搅拌均匀后，依次加入烷氧基化聚亚烷基多胺、烷氧基化脂肪醇、表面活性剂和缓蚀剂并搅拌均匀，即得。
相比现有技术，本发明的有益效果在于：
本发明的一种用于清洗管道的氨基磺酸复合清洗剂，氨基磺酸的溶解力强，速度快，对难溶性无机盐的去除效果显著，通过氨基磺酸与有机酸的复配，一方面可以降低氨基磺酸对基材的腐蚀性，另一方面有机酸具有良好的氧化性和螯合性，在与表面活性剂、缓蚀剂的配合下，将污垢进行剥离、浸润、分散、螯合作用，从而实现管道的清洗；烷氧基化脂肪醇具有良好的渗透性和去污力，烷氧基化聚亚烷基多胺能增强烷氧基化脂肪醇与污垢的结合性，尤其是对含蛋白质的污垢具有显著的去除效果；通过各组分之间的协同作用，能有效去除成分复杂的管道污垢，其具有去污力强，清洗效率高，刺激性低的特点。
本发明的一种用于清洗管道的氨基磺酸复合清洗剂的制备方法，其制备工艺简单，可操作性强，可大规模生产。
具体实施方式
下面，结合具体实施方式，对本发明做进一步描述，需要说明的是，在不相冲突的前提下，以下描述的各实施例之间或各技术特征之间可以任意组合形成新的实施例。
实施例1
一种用于清洗管道的氨基磺酸复合清洗剂，按质量份计，包括以下组分：
进一步地，所述有机酸为柠檬酸。
进一步地，所述烷氧基化聚亚烷基多胺的通式为式Ⅰ所示；
其中，A1、A2、A3、A4均为烷氧基基团，B为烷氧基基团，R1、R2为支链或支链的C5的亚烷基基团，x为30；其由聚亚烷基多胺与环氧乙烷在110-130℃下反应而成。
进一步地，所述烷氧基化脂肪醇为含3个烷氧基基团的C15高级脂肪醇。
进一步地，所述表面活性剂为C12烷基苯磺酸。
进一步地，所述缓蚀剂为烷基伯胺。
一种用于清洗管道的氨基磺酸复合清洗剂的制备方法，包括以下步骤：
将配方量的水、氨基磺酸和有机酸搅拌均匀后，依次加入烷氧基化聚亚烷基多胺、烷氧基化脂肪醇、表面活性剂和缓蚀剂并搅拌均匀，即得。
实施例2
一种用于清洗管道的氨基磺酸复合清洗剂，按质量份计，包括以下组分：
进一步地，所述有机酸为质量比为1:1的苹果酸和琥珀酸。
进一步地，所述烷氧基化聚亚烷基多胺的通式为式Ⅰ所示；
其中，A1、A2、A3、A4均为烷氧基基团，B为烷氧基基团，R1、R2为支链或支链的C3的亚烷基基团，x为20。
进一步地，所述烷氧基化脂肪醇为含2个烷氧基基团的C12高级脂肪醇。
进一步地，所述表面活性剂为C10脂肪醇聚氧乙烯醚。
进一步地，所述缓蚀剂为苯并三氮唑。
一种用于清洗管道的氨基磺酸复合清洗剂的制备方法，包括以下步骤：
将配方量的水、氨基磺酸和有机酸搅拌均匀后，依次加入烷氧基化聚亚烷基多胺、烷氧基化脂肪醇、表面活性剂和缓蚀剂并搅拌均匀，即得。
实施例3
一种用于清洗管道的氨基磺酸复合清洗剂，按质量份计，包括以下组分：
进一步地，所述有机酸为质量比为1:1柠檬酸和酒石酸。
进一步地，所述烷氧基化聚亚烷基多胺的通式为式Ⅰ所示；
其中，A1、A2、A3、A4均为烷氧基基团，B为烷氧基基团，R1、R2为支链或支链的C10的亚烷基基团，x为50。
进一步地，所述烷氧基化脂肪醇为含4个烷氧基基团的C20高级脂肪醇。
进一步地，所述表面活性剂为多羟基脂肪酸酰胺。
进一步地，所述缓蚀剂为烷基伯胺。
一种用于清洗管道的氨基磺酸复合清洗剂的制备方法，包括以下步骤：
将配方量的水、氨基磺酸和有机酸搅拌均匀后，依次加入烷氧基化聚亚烷基多胺、烷氧基化脂肪醇、表面活性剂和缓蚀剂并搅拌均匀，即得。
对比例1
本对比例的一种氨基磺酸复合清洗剂，与实施例1的区别仅在于：按质量份计，本对比例包括以下组分：
对比例2
本对比例的一种氨基磺酸复合清洗剂，与实施例1的区别仅在于：按质量份计，本对比例包括以下组分：
性能测试
1、清洗率测试
机械刮除污水管的污垢，然后用去离子水冲洗后，干燥得到实验样品，称重并记为m1；取实施例1-3和对比例1-2的清洗剂分别稀释至体积浓度为1％后，加入实验样品，25℃下浸泡30min，过滤，洗涤，烘干后，对滤渣物料进行称重并记为m2，按照公式：清洗率P＝(m1-m2)×100％，计算得到清洗率，结果如表1所示。
2、稳定性测试
取100mL实施例1-3和对比例1-2的清洗剂产品分别在50℃±2℃下存放14天，然后在-10℃±2℃下再存放14天，试验完毕，剧烈摇晃，观察产品的变化，结果如表1所示。
表1
| 清洗率/％ | 稳定性 | |
| 实施例1 | 96.3 | 分散均匀，不分层，无析出沉淀物 |
| 实施例2 | 95.8 | 分散均匀，不分层，无析出沉淀物 |
| 实施例3 | 95.6 | 分散均匀，不分层，无析出沉淀物 |
| 对比例1 | 81.2 | 分散均匀，不分层，无析出沉淀物 |
| 对比例2 | 83.6 | 分散均匀，不分层，无析出沉淀物 |
从表1可以看出，本发明的清洗剂稳定性高，清洗效率高，去污力强；对比例1、2的清洗剂中缺少有机酸或烷氧基化聚亚烷基多胺和烷氧基化脂肪醇的组合，其清洗效率明显下降，说明本发明的组分间具有良好的协同作用，提高去污力。
上述实施方式仅为本发明的优选实施方式，不能以此来限定本发明保护的范围，本领域的技术人员在本发明的基础上所做的任何非实质性的变化及替换均属于本发明所要求保护的范围。
Claims (10)
1.一种用于清洗管道的氨基磺酸复合清洗剂，其特征在于，按质量份计，包括以下组分：
2.如权利要求1所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：所述有机酸为柠檬酸、酒石酸、苹果酸和琥珀酸中的一种或两种以上。
3.如权利要求1或2所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：所述氨基磺酸和有机酸的质量比为1.5-3:1。
4.如权利要求1所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：所述烷氧基化聚亚烷基多胺的通式为式Ⅰ所示；
其中，A1、A2、A3、A4均为烷氧基基团，B为氢、烷氧基、甲基和乙基的任一种基团，R1、R2为支链或支链的C2-C10的亚烷基基团，x为10-50。
5.如权利要求1所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：所述烷氧基化脂肪醇为含1-4个烷氧基基团的C12-C20高级脂肪醇。
6.如权利要求4或5所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：烷氧基化聚亚烷基多胺和烷氧基化脂肪醇的质量比为0.8-3:1。
7.如权利要求1所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：所述表面活性剂为脂肪醇聚氧乙烯醚、多羟基脂肪酸酰胺、C10-20烷基苯磺酸中的一种或两种以上。
8.如权利要求1所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：所述缓蚀剂为苯并三氮唑和/或烷基伯胺。
9.如权利要求1所述的用于清洗管道的氨基磺酸复合清洗剂，其特征在于：还包括磺基过氧羧酸1-3份。
10.一种权利要求1-9任一项所述的用于清洗管道的氨基磺酸复合清洗剂的制备方法，其特征在于，包括以下步骤：
将配方量的水、氨基磺酸和有机酸搅拌均匀后，依次加入烷氧基化聚亚烷基多胺、烷氧基化脂肪醇、表面活性剂和缓蚀剂并搅拌均匀，即得。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210653351.7A CN115232679A (zh) | 2022-06-09 | 2022-06-09 | 一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210653351.7A CN115232679A (zh) | 2022-06-09 | 2022-06-09 | 一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115232679A true CN115232679A (zh) | 2022-10-25 |
Family
ID=83669811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210653351.7A Pending CN115232679A (zh) | 2022-06-09 | 2022-06-09 | 一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115232679A (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4548744A (en) * | 1983-07-22 | 1985-10-22 | Connor Daniel S | Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions |
| CN1154137A (zh) * | 1994-05-25 | 1997-07-09 | 普罗格特-甘布尔公司 | 包含用作污垢分散剂的乙氧基化/丙氧基化聚亚烷基胺聚合物的组合物 |
| US20120225943A1 (en) * | 2008-03-28 | 2012-09-06 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
| CN103642612A (zh) * | 2013-12-09 | 2014-03-19 | 成都民航六维航化有限责任公司 | 一种飞机管道用清洗剂及制备方法 |
| US20160312153A1 (en) * | 2013-12-16 | 2016-10-27 | Basf Se | Modified polysaccharide for use in laundry detergent and for use as anti-greying agent |
-
2022
- 2022-06-09 CN CN202210653351.7A patent/CN115232679A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4548744A (en) * | 1983-07-22 | 1985-10-22 | Connor Daniel S | Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions |
| CN1154137A (zh) * | 1994-05-25 | 1997-07-09 | 普罗格特-甘布尔公司 | 包含用作污垢分散剂的乙氧基化/丙氧基化聚亚烷基胺聚合物的组合物 |
| US20120225943A1 (en) * | 2008-03-28 | 2012-09-06 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
| CN103642612A (zh) * | 2013-12-09 | 2014-03-19 | 成都民航六维航化有限责任公司 | 一种飞机管道用清洗剂及制备方法 |
| US20160312153A1 (en) * | 2013-12-16 | 2016-10-27 | Basf Se | Modified polysaccharide for use in laundry detergent and for use as anti-greying agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2366010B1 (de) | Maschinelles geschirrspülmittel | |
| EP2129763B1 (de) | Mittel zur behandlung harter oberflächen | |
| EP2366007B1 (de) | Maschinelles geschirrspülmittel | |
| US9103038B2 (en) | Acidic compositions including reducing agents for scale and decolorization of metal stains | |
| CN102002451A (zh) | 空调专用除垢灭菌清洗剂及其制备方法 | |
| JPS62225597A (ja) | 生存微生物を含む液体洗浄剤 | |
| CN107057878A (zh) | 一种环保型光学玻璃清洗剂及其制备方法 | |
| CN101463296B (zh) | 微电子设备清洗剂 | |
| CN111979054A (zh) | 一种中性环保浴室清洁剂及其制作方法 | |
| CN106281761A (zh) | 一种医疗器械多酶清洗剂及其制备方法 | |
| CN112779543A (zh) | 一种有机酸清洗剂及其制备方法 | |
| CN107057897A (zh) | 一种新型原位清洗剂及其制备方法 | |
| JP2007525549A (ja) | 容易なクリーニング効果を提供するための硬質表面クリーナー中のスルホネート化ポリスチレンポリマーの使用 | |
| CN101265439A (zh) | 单晶硅片水基清洗剂 | |
| KR101140217B1 (ko) | 상수도 정수장 및 배수지 세척용 친환경 세척제 조성물 | |
| CN115232679A (zh) | 一种用于清洗管道的氨基磺酸复合清洗剂及其制备方法 | |
| JPH04323298A (ja) | 金属加工品用アルカリ洗浄剤用添加剤およびこれを含有する金属加工品用アルカリ洗浄剤組成物 | |
| WO2010139107A1 (en) | Cleaning compositions and methods | |
| CN113881515A (zh) | 一种纳滤膜或反渗透膜的清洗剂及清洗方法 | |
| KR101582215B1 (ko) | 락트산을 포함한 친환경 세척제 조성물 | |
| JP2012111846A (ja) | 酸性抗菌洗浄剤組成物 | |
| KR101582221B1 (ko) | 락트산 및 과초산을 포함한 친환경 세정제 조성물 | |
| JP2015021030A (ja) | 台所用洗浄剤 | |
| CN116875388A (zh) | 一种管道疏通剂及其制备方法 | |
| CN1796521A (zh) | 洗衣机桶专用洗涤剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |