CN115231899A - Imitative stone material heat preservation decorative board of light - Google Patents
Imitative stone material heat preservation decorative board of light Download PDFInfo
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- CN115231899A CN115231899A CN202210928598.5A CN202210928598A CN115231899A CN 115231899 A CN115231899 A CN 115231899A CN 202210928598 A CN202210928598 A CN 202210928598A CN 115231899 A CN115231899 A CN 115231899A
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- 239000000463 material Substances 0.000 title claims abstract description 34
- 238000004321 preservation Methods 0.000 title claims abstract description 23
- 239000004575 stone Substances 0.000 title claims description 9
- 239000000919 ceramic Substances 0.000 claims abstract description 33
- 238000009413 insulation Methods 0.000 claims abstract description 33
- 230000032683 aging Effects 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 14
- 239000002440 industrial waste Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 239000004744 fabric Substances 0.000 claims abstract description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 15
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
- 239000010438 granite Substances 0.000 claims description 12
- 239000010451 perlite Substances 0.000 claims description 12
- 235000019362 perlite Nutrition 0.000 claims description 12
- 239000010457 zeolite Substances 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 10
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 10
- 239000010436 fluorite Substances 0.000 claims description 10
- 239000011863 silicon-based powder Substances 0.000 claims description 10
- 229910052656 albite Inorganic materials 0.000 claims description 8
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 239000011148 porous material Substances 0.000 claims description 8
- 238000010304 firing Methods 0.000 claims description 7
- 239000011810 insulating material Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000001694 spray drying Methods 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 230000002265 prevention Effects 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 239000012774 insulation material Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 238000010276 construction Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 6
- 238000007641 inkjet printing Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000009430 construction management Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920006335 epoxy glue Polymers 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 phenolic aldehyde Chemical class 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0871—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
- E04F13/0873—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface the visible surface imitating natural stone, brick work, tiled surface or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/244—Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Architecture (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Civil Engineering (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to a light stone-like heat-preservation veneer, which is prepared by the following steps: step one, preparing powder from the bottom material; secondly, making the fabric into powder; step three, glaze preparation; fourthly, using a press secondary material distribution system to form a ceramic heat-preservation decorative plate blank body in a one-step mode, and then drying the ceramic heat-preservation decorative plate blank body in a drying kiln; and step five, glazing. According to the technical scheme, on the premise of not influencing the quality of the ceramic insulation board, the environmental pollution caused by industrial waste residues of the insulation board is solved, the factory cost is reduced, and the produced light stone-like insulation veneer has the technical effects of light weight, heat insulation, fire prevention, water prevention, high strength and aging resistance and is provided with the decorative surface.
Description
Technical Field
The invention relates to a light stone-like heat-insulation veneer.
Background
The building outer wall heat insulation system is an important part in energy-saving buildings and is widely applied to domestic and foreign building engineering, and the existing heat insulation plates mainly comprise EPS plates, XPS plates, PU plates, phenolic aldehyde plates, foam concrete plates, rock wool plates and the like. The facing layer is inorganic plate, metal plate, stone plate, ceramic plate, etc. with various kinds of coating. The facing is directly bonded on the heat-insulating layer material by adopting polyurethane glue or epoxy glue. Such materials suffer from the following major disadvantages:
1. the veneer is not a light material, has large volume weight and cannot achieve light weight.
2. The heat-insulating layer is made of organic materials, so that the problems of poor durability and poor fireproof performance exist. The adopted inorganic heat-insulating material has the problems of high water absorption rate, large shrinkage rate, low strength, short service life and the like.
3. The volume weight difference between the veneer and the heat-insulating layer material is dozens of times, and the strength difference is dozens of times, so that the external wall heat-insulating system with heavy external weight, light internal weight, strong external force and weak internal force is formed. Although adhesive anchor bonding is generally used, the anchor must be anchored to the facing plate, so the supporting structure system and the construction process are very complicated.
In addition, the currently and generally adopted heat insulation mortar external wall heat insulation system has 4 problems:
1. the system has short durability, the design service life of the external thermal insulation engineering of the external wall is 25 years, whether the common organic thermal insulation material can be used for 25 years is still examined, and the inorganic thermal insulation has high water absorption rate and large shrinkage rate, which affects the actual service life.
2. Safety performance is worried about, the most common external wall thermal insulation material is still an organic material at present, the fireproof performance is poor, and fireproof potential safety hazards exist in the construction and use processes.
3. The construction process is complex, the quality hidden danger is many, the external thermal insulation technology of outer wall has very strict requirements on the construction level, if the construction method is not familiar with the technical requirements, or the technical operation level of workers is low, the construction management is not strict enough, and serious quality problems are easy to generate.
4. The system cost is high, and the external thermal insulation system construction process is more outside the outer wall, when adopting the heat preservation mortar as the heat preservation, generally divide into three (even more) plasters, and each plaster need to go on after the hardening of one previous plaster layer, and the heat preservation needs to add outward to put the anticracking layer, still needs to set up net cloth or wire net protective layer, does the decorative finish coat finally.
Disclosure of Invention
Aiming at the problem that the cost of the existing light imitation stone heat-preservation veneer mainly made of perlite is generally higher, the invention aims to provide the light imitation stone heat-preservation veneer with a decorative surface, which is light, heat-preservation, fireproof, waterproof, high-strength and ageing-resistant, by utilizing industrial waste residues of a heat-preservation plate on the premise of ensuring the quality of the imitation stone heat-preservation veneer.
In order to realize the purpose, the invention provides the following technical scheme: a light stone-like thermal insulation veneer is prepared by the following steps:
step one, preparing powder from the backing material: mixing 10 to 20 parts by weight of perlite, 30 to 60 parts by weight of heat-insulating material industrial waste residue, 5 to 10 parts by weight of bentonite, 8 to 15 parts by weight of zeolite, 5363 parts by weight of kaolin 5~8 parts by weight of granite grinding material, 0.2 to 1.0 part by weight of green ceramic silicon powder and 5 to 10 parts by weight of fluorite tailings, crushing, carrying out wet ball milling, carrying out uniform ageing, carrying out spray drying, granulating and pulverizing;
step two, milling the fabric: mixing raw materials of 15 to 30 parts by weight of perlite, 15 to 45 parts by weight of heat-insulating material industrial waste residue, 5 to 10 parts by weight of bentonite, 8 to 15 parts by weight of zeolite, 5363 parts by weight of kaolin 5~8 parts by weight of granite grinding material, 0.2 to 0.5 part by weight of green ceramic silicon powder and 5 to 10 parts by weight of fluorite tailings, crushing, carrying out wet ball milling, carrying out uniform ageing, carrying out spray drying, granulating and preparing powder;
step three, glaze preparation: ball-milling 40-60 parts of blank raw materials, 20-30 parts of albite, 20-30 parts of potassium feldspar and 5-10 parts of kaolin to obtain a glaze;
fourthly, using a press secondary material distribution system to form a ceramic heat-preservation decorative plate blank body in a one-step mode, and then drying the ceramic heat-preservation decorative plate blank body in a drying kiln;
step five, glazing: and glazing the blank by using a glaze material, and firing the glazed blank at the high temperature of 1100-1300 ℃ to form the light stone-like heat-insulating veneer with closed pores uniformly and densely distributed with glaze surfaces.
Further, in the first step, 12 to 20 parts of perlite, 30-60 parts of heat insulation material industrial waste slag, 3236 parts of bentonite, 8 to 12 parts of zeolite, 5262 parts of granite abrasive, 5262 parts of zxft, 0.2 to 0.8 parts of green ceramic silicon powder and 3763 parts of fluorite tailings.
In the second step, 8 to 12 parts of zeolite and 5~8 parts of granite abrasive are further used.
Further, in the third step, the blank raw material comprises 45-55 parts of albite, 22-28 parts of potassium feldspar and 6~8 parts of kaolin.
Furthermore, the light stone-like heat-preservation decorative panel comprises a blank body and a glaze surface, wherein the blank body is provided with closed air holes which are uniformly and densely distributed, and the blank body and the glaze surface are integrally arranged.
Compared with the prior art, the invention has the beneficial effects that: the light stone-like thermal insulation veneer of the invention fully utilizes wastes such as industrial waste residue, tailings and the like to prepare the light stone-like thermal insulation veneer which has the advantages of light weight, low thermal conductivity, fire resistance, water resistance, aging resistance, good compatibility with cement products and weather resistance, and has the advantages of rich decorative surface and the like and can be applied to the fields of building, decoration, environmental protection and the like because the blank and the glaze are directly compounded when the materials are sintered. And the foamed ceramic stone-like thermal insulation veneer is a new-generation environment-friendly and energy-saving green building material product, is prepared by using industrial waste residues as raw materials and firing and foaming at the high temperature of 1200 ℃, has the advantages of light weight, low water absorption, water resistance, fire resistance, quick installation and the like, and is suitable for being used in various building outer wall scenes.
The following list a number of advantages of the invention:
1. the decorative surface and the green body are integrally sintered and formed without bonding by using a binder.
2. The lightweight is mainly embodied in that products are compared with stone curtain walls and large-size ceramic plates, the weight is greatly reduced, the high-rise building panel is suitable for high-rise buildings, a panel and supporting structure system and a construction process are simplified, the engineering cost is greatly reduced, and convenience is provided for later maintenance.
3. The tensile strength is high, and the bonding strength of the ceramic tile is not less than 0.4Mpa in the inspection standard of bonding strength of facing tiles in architectural engineering (JGJ 110-2008). The tensile strength of the light stone-like thermal insulation veneer is more than or equal to 1.0Mpa. The special outer wall ceramic adhesive is adopted, so that the tensile adhesive strength can be completely ensured, and the standard requirement is met.
4. The thermal conductivity coefficient is less than or equal to 0.07 w/(m × k), is equivalent to the inorganic lightweight aggregate thermal insulation mortar, and can be used as a thermal insulation material of an external thermal insulation system of an external wall.
5. The fireproof performance is good, the product is formed by high-temperature calcination at 1200 ℃, and the combustion performance is A1 level.
6. The water absorption rate is low, the water absorption rate of the product volume is less than or equal to 0.8 percent, the water absorption rate of other insulation volumes such as the contrast expanded perlite insulation board is less than or equal to 10 percent, and the heat insulation performance can not be reduced due to the leakage of the outer wall.
7. The ceramic material has the advantages of aging resistance, stable performance, good durability, no aging, and realization of the same service life as a building, and is incomparable with the conventional organic heat-insulating material.
8. The compatibility is good, the coefficient of linear expansion is similar to that of cement mortar, concrete and the like, the compatibility is good, the bonding is reliable, and the ceramic building material does not crack, deform and shrink under the conditions of thermal expansion and cold contraction like the traditional ceramic building material fired at high temperature.
Detailed Description
The embodiments of the invention are shown below:
the first embodiment,
Step one, preparing powder from the bottom materials: 20 parts of perlite, 38 parts of thermal insulation material industrial waste residues, 10 parts of bentonite, 12 parts of zeolite, 6 parts of kaolin, 6 parts of granite grinding materials, 0.4 part of green ceramic silicon powder and 8 parts of fluorite tailings are mixed, and then the raw materials are crushed, ball-milled by a wet method and aged uniformly, and then spray-dried, granulated and powdered; step three, glaze preparation: performing ball milling on 45 parts by weight of blank raw materials, 20 parts by weight of albite, 28 parts by weight of potassium feldspar and 7 parts by weight of kaolin to obtain a glaze material; step four, using a secondary material distribution system of a press to form a ceramic heat-insulation decorative plate blank body in one step, and then drying the ceramic heat-insulation decorative plate blank body in a drying kiln; and fifthly, glazing the blank by using glaze, and throwing points or performing ink-jet printing on the glaze. And firing the glazed green body by a high-temperature continuous roller kiln at 1100-1300 ℃ to form the light stone-like heat-insulating veneer with closed pores uniformly and densely distributed and glazed surfaces on the green body.
Example II,
Step one, preparing powder from the bottom materials: mixing raw materials of 15 parts by weight of perlite, 48 parts by weight of thermal insulation material industrial waste residue, 10 parts by weight of bentonite, 10 parts by weight of zeolite, 6 parts by weight of kaolin, 6 parts by weight of granite grinding material, 0.48 part by weight of green ceramic silicon powder and 5 parts by weight of fluorite tailings, crushing, ball-milling by a wet method, aging uniformly, and then carrying out spray drying, granulation and powder preparation; step three, glaze preparation: performing ball milling on 45 parts by weight of blank raw materials, 20 parts by weight of albite, 28 parts by weight of potassium feldspar and 7 parts by weight of kaolin to obtain a glaze material; fourthly, using a press secondary material distribution system to form a ceramic heat-preservation decorative plate blank body in a one-step mode, and then drying the ceramic heat-preservation decorative plate blank body in a drying kiln; and fifthly, glazing the blank by using glaze, and throwing points or performing ink-jet printing on the glaze. And firing the glazed green body by a high-temperature continuous roller kiln at 1100-1300 ℃ to form the light stone-like heat-insulating veneer with closed pores uniformly and densely distributed and glazed surfaces on the green body.
Example III,
Step one, preparing powder from the backing material: 12 parts of perlite, 55 parts of thermal insulation material industrial waste residues, 8 parts of bentonite, 8 parts of zeolite, 6 parts of kaolin, 6 parts of granite grinding materials, 0.55 part of green ceramic silicon powder and 5 parts of fluorite tailings are mixed, and then the raw materials are crushed, ball-milled by a wet method and aged uniformly, and then spray-dried, granulated and powdered; step three, glaze preparation: performing ball milling on 45 parts by weight of blank raw materials, 15 parts by weight of albite, 35 parts by weight of potassium feldspar and 5 parts by weight of kaolin to obtain a glaze; step four, using a secondary material distribution system of a press to form a ceramic heat-insulation decorative plate blank body in one step, and then drying the ceramic heat-insulation decorative plate blank body in a drying kiln; and fifthly, glazing the blank by using glaze, and throwing points or performing ink-jet printing on the glaze. And firing the glazed green body in a high-temperature continuous roller kiln at 1050-1200 ℃ to form the light stone-like heat-insulating veneer with closed pores uniformly and densely distributed and glazed surfaces on the green body.
Example four,
Step one, preparing powder from the bottom materials: mixing raw materials of 10 parts by weight of perlite, 60 parts by weight of thermal insulation material industrial waste residue, 8 parts by weight of bentonite, 5 parts by weight of zeolite, 5 parts by weight of kaolin, 6 parts by weight of granite grinding material, 0.55 part by weight of green ceramic silicon powder and 6 parts by weight of fluorite tailings, then crushing, ball-milling by a wet method, aging uniformly, and then carrying out spray drying, granulation and powder preparation; step three, glaze preparation: performing ball milling on 45 parts by weight of blank raw materials, 15 parts by weight of albite, 35 parts by weight of potassium feldspar and 5 parts by weight of kaolin to obtain a glaze; fourthly, using a press secondary material distribution system to form a ceramic heat-preservation decorative plate blank body in a one-step mode, and then drying the ceramic heat-preservation decorative plate blank body in a drying kiln; and fifthly, glazing the blank body by using glaze, and throwing points or performing ink-jet printing on the glaze. And firing the glazed green body in a high-temperature continuous roller kiln at 1050-1200 ℃ to form the light stone-like heat-insulating veneer with closed pores uniformly and densely distributed and glazed surfaces on the green body.
The light imitation stone thermal insulation veneer prepared by the preparation method of the embodiment comprises a blank body and a glaze surface, wherein the blank body is provided with closed pores which are uniformly and densely distributed, and the blank body and the glaze surface are integrally arranged.
The performance indexes of the lightweight stone-like thermal insulation veneer prepared in the first to fourth embodiments are shown in the following reference table through detection:
example 1 | Example 2 | Example 3 | Example 4 | |
Volume weight | ≤330kg/m3 | ≤300kg/m3 | ≤280kg/m3 | ≤270kg/m3 |
Tensile strength | ≥2.0MPA | ≥1.5MPA | ≥1.2MPA | ≥1.2MPA |
Coefficient of thermal conductivity | ≤1.0w/(m*k) | ≤0.085w/(m*k) | ≤0.08W/(m*k) | ≤0.07w/(m*k) |
Fire-proof performance | Class A1 | Class A1 | Class A1 | Class A1 |
Water absorption rate | ≤0.7% | ≤0.6% | ≤0.6% | ≤0.6% |
Aging resistance | Aging resistance | Aging resistance | Aging resistance | Aging resistance |
Compatibility | Compatibility of | Compatibility of | Compatibility of | Compatibility of |
Compressive strength | ≥4.3MPa | ≥4.0MPa | ≥3.5MPa | ≥3.0MPa |
The above description is only an example and an experimental example of the present invention, and is not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes performed by the present specification, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (5)
1. The utility model provides a imitative stone material heat preservation decorative board of light which characterized in that: the preparation method comprises the following steps:
step one, preparing powder from the backing material: mixing 10 to 20 parts by weight of perlite, 30 to 60 parts by weight of heat-insulating material industrial waste residue, 5 to 10 parts by weight of bentonite, 8 to 15 parts by weight of zeolite, 5363 parts by weight of kaolin 5~8 parts by weight of granite grinding material, 0.2 to 1.0 part by weight of green ceramic silicon powder and 5 to 10 parts by weight of fluorite tailings, crushing, carrying out wet ball milling, carrying out uniform ageing, carrying out spray drying, granulating and pulverizing;
step two, making the fabric into powder: mixing raw materials of 15 to 30 parts by weight of perlite, 15 to 45 parts by weight of heat-insulating material industrial waste residue, 5 to 10 parts by weight of bentonite, 8 to 15 parts by weight of zeolite, 4736 parts by weight of kaolin 5~8 parts by weight of granite grinding material, 0.2 to 0.5 part by weight of green ceramic silicon powder and 5 to 10 parts by weight of fluorite tailings, crushing, carrying out wet ball milling, carrying out uniform ageing, carrying out spray drying, granulating and preparing powder;
step three, glaze preparation: ball-milling 40-60 parts of blank raw materials, 20-30 parts of albite, 20-30 parts of potassium feldspar and 5-10 parts of kaolin to obtain a glaze;
fourthly, using a press secondary material distribution system to form a ceramic heat-preservation decorative plate blank body in a one-step mode, and then drying the ceramic heat-preservation decorative plate blank body in a drying kiln;
step five, glazing: and glazing the blank by using a glaze material, and firing the glazed blank at the high temperature of 1100-1300 ℃ to form the light stone-like heat-insulating veneer with closed pores uniformly and densely distributed with glaze surfaces.
2. The light stone-like thermal insulation veneer according to claim 1, characterized in that: in the first step, 12 to 20 parts of perlite, 30-60 parts of heat-insulating material industrial waste slag, 3236 parts of bentonite, 8 to 12 parts of zeolite, 5262 parts of granite abrasive, 0.2 to 0.8 parts of green ceramic silicon powder and 3763 parts of fluorite tailings.
3. The light stone-like thermal insulation veneer according to claim 1, characterized in that: in the second step, 8 to 12 parts of zeolite and 5~8 parts of granite abrasive are used.
4. The light stone-like thermal insulation veneer according to claim 1, characterized in that: in the third step, the raw materials of the blank are 45 to 55 parts, the albite is 22 to 28 parts, the potassium feldspar is 22 to 28 parts, and the kaolin is 6~8 parts.
5. The light-weight stone-like thermal insulation veneer according to any one of claims 1 to 4, characterized in that: the ceramic tile comprises a blank body and a glaze surface, wherein the blank body is provided with closed pores which are uniformly and densely distributed, and the blank body and the glaze surface are integrally arranged.
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