CN115213418A - Silver powder manufacturing device - Google Patents

Silver powder manufacturing device Download PDF

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Publication number
CN115213418A
CN115213418A CN202210814949.XA CN202210814949A CN115213418A CN 115213418 A CN115213418 A CN 115213418A CN 202210814949 A CN202210814949 A CN 202210814949A CN 115213418 A CN115213418 A CN 115213418A
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CN
China
Prior art keywords
chamber
atomizing
silver powder
heat preservation
gas
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210814949.XA
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Chinese (zh)
Inventor
任华
蔡明祥
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Guizhou Yueda Additive Material Technology Co ltd
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Guizhou Yueda Additive Material Technology Co ltd
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Publication date
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Priority to CN202210814949.XA priority Critical patent/CN115213418A/en
Publication of CN115213418A publication Critical patent/CN115213418A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/06Metallic powder characterised by the shape of the particles
    • B22F1/065Spherical particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • B22F2009/0844Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid in controlled atmosphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • B22F2009/086Cooling after atomisation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

The present invention provides an apparatus for manufacturing silver powder, comprising: the device comprises an atomizing chamber, an atomizing nozzle arranged above the atomizing chamber, a tundish arranged on the atomizing nozzle and a smelting furnace arranged above the tundish; wherein, the atomizer chamber is provided with the heat preservation subassembly, the heat preservation subassembly is used for promoting ambient temperature in the atomizer chamber. In the process of the silver powder manufacturing method, the environmental temperature in the atomizing chamber is increased in advance, so that the cooling time of the liquid drops is prolonged, the spheroidizing time of the liquid drops is further prolonged, the silver powder particles obtained after final cooling have better sphericity (roundness), and the product quality of the silver powder particles is improved.

Description

Silver powder manufacturing device
Technical Field
The invention relates to the technical field of metal powder manufacturing, in particular to a silver powder manufacturing device.
Background
The silver ornament is a popular traditional ornament for people in the southwest of China, and more advanced manufacturing processes are introduced into the process of the silver ornament on the basis of the traditional process along with the development of time, wherein one of the methods is a metal powder forming method.
At present, the metal powder molding method is mainly applied to the field of machine manufacturing, and therefore, an alloy powder material is used as a raw material for metal powder molding in the field of general machine manufacturing. The alloy powder is obtained by atomizing an alloy melt, for example, in the gas atomization method, in the process of dropping the alloy melt from a crucible, impact atomization is carried out on dropped alloy droplets through inert gas, and the atomized small-particle droplets are cooled in the dropping process and are spheroidized to form the alloy powder with round particles.
Because the metal powder molding has the advantage of being capable of rapidly molding complex structures and realizing the advantage of complex structures which cannot be achieved by some traditional processes, the process of the silver ornament also starts to introduce the metal powder molding method. However, after the introduction of the existing metal powder forming method, which may be based on the difference of material properties, the roundness of the particles in the metal powder manufacturing process by pure silver does not always reach the required standard, and the aluminum or other alloys do not have the problem.
Therefore, when the metal powder forming method applied to the field of mechanical manufacturing is applied to the forming of the silver ornaments, certain problems still exist in the silver metal powder manufacturing process, and the raw material standard required by the forming cannot be met.
Disclosure of Invention
The invention aims to provide a silver powder manufacturing device for improving the roundness of silver powder particles.
In order to solve the above technical problem, the present invention provides an apparatus for manufacturing silver powder, comprising: the device comprises an atomizing chamber, an atomizing nozzle arranged above the atomizing chamber, a tundish arranged on the atomizing nozzle and a smelting furnace arranged above the tundish;
wherein, the atomizer chamber is provided with the heat preservation subassembly, the heat preservation subassembly is used for promoting ambient temperature in the atomizer chamber.
Preferably, the heat-insulating assembly includes: with the gaseous pipeline that lets in of heat preservation of atomizer chamber intercommunication, with gaseous heating device and the gaseous storage device that the pipeline is connected are let in to heat preservation gas, it is right when needs the atomizer chamber heaies up, to the atomizer chamber lets in heat preservation gas, heat preservation gas passes through gaseous heating device heats.
Preferably, the heat preservation gas inlet pipeline is arranged on the inner side of the tank body and close to the peripheral wall of the tank body, and the air outlet direction of the heat preservation gas and the spraying direction of the atomizing nozzle are not interfered with each other.
Preferably, the insulating gas is also an inert gas.
Preferably, an interlayer is arranged in the atomizing chamber, the heat-insulating gas introducing pipeline is arranged in the interlayer, and the heat-insulating gas firstly enters the gas slow-flow space of the interlayer and then overflows into the atomizing space of the atomizing chamber.
Preferably, the partition is composed of at least two partitions, and is welded on the wall of the atomization chamber respectively.
Preferably, the heat-insulating assembly includes: and the heating device is arranged on the wall surface of the atomizing chamber and is used for heating the wall surface of the atomizing chamber.
Preferably, the heating device is a heat pipe arranged on the inner wall surface of the atomizing chamber.
Preferably, a heat insulating material layer is arranged outside the atomizing chamber.
Preferably, a temperature measuring device is further arranged in the atomizing chamber.
Compared with the prior art, the silver powder manufacturing device disclosed by the invention has the advantages that the ambient temperature in the atomizing chamber is increased in advance, and meanwhile, the ambient temperature in the atomizing chamber is continuously kept in the preset range, so that the cooling time of atomized liquid drops is prolonged in the atomizing process, the liquid drops have enough spheroidizing time, the silver powder particles obtained after final cooling have better sphericity (roundness), and the product quality of the silver powder particles is improved. The method can simultaneously solve the problem of unstable quality of the silver powder particles caused by climate reasons, particularly can cause that the temperature in the atomizing chamber is lower than the ordinary temperature under the condition of low temperature in a factory building in winter to cause the quality reduction of products, can keep the temperature in the atomizing chamber in a reasonable range, and ensures the stability of the quality of the products.
Drawings
FIG. 1 is a schematic view showing a structure of an apparatus for manufacturing silver powder according to an embodiment of the present invention;
fig. 2 is a schematic cross-sectional view of an atomization chamber provided by the present invention.
Detailed Description
The following examples, which are given in conjunction with the drawings, further illustrate the embodiments of the silver powder production method of the present invention.
The embodiment of the invention provides a silver powder manufacturing device, which is used for manufacturing silver powder. The silver powder with spherical particles is obtained by heating and atomizing pure silver serving as a base material, can be used in a forming process of pure silver commodities such as silver ornaments and artworks, and particularly can be used in a process of forming the silver powder by laser sintering.
Referring to fig. 1 and 2, an apparatus for manufacturing silver powder according to an embodiment of the present invention includes an atomizing assembly 100 and a powder collecting device 200, wherein the atomizing assembly 100 includes: an atomizing chamber 110 surrounded by a tank body 111, an atomizing nozzle 120 arranged above the atomizing chamber, a tundish 130 arranged on the atomizing nozzle 120, and a smelting furnace 140 arranged above the tundish; wherein, the atomizer chamber 110 is provided with the heat preservation subassembly, the heat preservation subassembly is used for promoting the ambient temperature in the atomizer chamber 110.
As an alternative embodiment, the insulation assembly comprises: with the gaseous pipeline 150 that lets in of heat preservation of atomizer chamber intercommunication, with gaseous heating device (not shown in the figure) and the gaseous storage device (not shown in the figure) that the gaseous pipeline 150 is connected of heat preservation let in, when needs right atomizer chamber 110 intensifies, to atomizer chamber 110 lets in heat preservation gas, heat preservation gas passes through gaseous heating device heats.
In one embodiment, the gas heating device may be a steam heat exchanger, a plate heat exchanger, or other heat exchanger.
In this embodiment, referring to fig. 2, the heat preservation gas introducing pipeline 150 is disposed inside the tank 111 and near the peripheral wall of the tank, an air outlet direction of the heat preservation gas and an air outlet direction of the atomizing nozzle do not interfere with each other, specifically, the air outlet direction may be downward or inclined downward, and the heat preservation gas is attached to the peripheral wall of the tank 111 to be discharged, so as to avoid interference with the atomized liquid droplets.
In this embodiment, the insulating gas is also an inert gas, preferably the same gas as the atomizing gas, so that it is convenient to recycle.
In this embodiment, be provided with interlayer 160 in the atomizer chamber, heat preservation gas lets in pipeline 150 and sets up in interlayer 160, forms a gaseous slow flow space 161 between interlayer 160 and the jar body 111, heat preservation gas gets into earlier when letting in the gaseous slow flow space 161 of interlayer 160, and gaseous admission speed in gaseous slow flow space 161 slows down, and after filling gaseous slow flow space 161, overflow into by interlayer 160 again in the atomizer space of atomizer chamber 110, avoid too fast gaseous letting in to produce great influence to the temperature of atomizer chamber 110, also can avoid too fast gaseous letting in the balling process that influences the atomized liquid drop simultaneously.
Further, the partition 160 is composed of at least two segments, and is welded to the wall of the atomization chamber 110 (inside the tank) by a welding structure 162. The interlayer that the piecemeal set up can more conveniently be under construction, and simultaneously, the distance between the piecemeal can be as gas overflow mouth 163, makes the fine overflow of gas.
In another embodiment, the insulation assembly comprises: and a heating device (not shown) provided on the wall surface of the atomizing chamber for heating the wall surface of the atomizing chamber. Specifically, the heating device is a heat pipe arranged on the inner wall surface of the atomization chamber.
Further, an insulating material layer is disposed outside the atomizing chamber 110.
On the basis of the above embodiment, a temperature measuring device is further arranged in the atomizing chamber, wherein the temperature measuring device can be fixed on the interlayer 160, and as the atomizing gas is introduced at a high speed, the temperature difference of the areas with different heights can be caused, so that a plurality of temperature measuring devices can be arranged at different heights, and the temperature of the falling area in the droplet spheroidizing process can be monitored in a proper range in real time.
Based on the above, an embodiment of the present invention provides a method for manufacturing silver powder, including:
s1, putting the pure silver substrate into a smelting furnace for heating and melting to obtain silver melt.
Specifically, in the step, the silver substrate is firstly cut into the size meeting the requirement according to the size requirement, and then is added into a smelting furnace (namely a smelting crucible), and the material is loaded in a mode that the bottom is compact and the upper part is loose, so that the bridging phenomenon can be avoided. After the blowing is accomplished, open the smelting power, make the silver-colored base material in the smelting furnace melt, at the melting in-process, reciprocal tilting smelting furnace makes the material slowly sink in the melting in-process, improves melting efficiency, if the bridging phenomenon appears, then need increase the tilting angle of smelting furnace to avoid the smelting furnace local overheat. And after the silver substrate is completely melted (the molten pool is calm and stops bubbling), continuously heating to ensure that the molten liquid reaches the pouring temperature.
In the process of melting the silver base material, the temperature of the molten liquid in the smelting furnace needs to be continuously detected, and various detection methods can be combined, such as thermocouple temperature measurement, infrared temperature measurement, mechanical temperature measurement and the like. The melt of smelting crucible can adopt infrared temperature measurement and mechanical temperature measurement to combine together to ensure the accuracy of temperature measurement, at first descend the temperature measurement pole to melt upper portion through the mode of machinery, stay a period and preheat, preheat a period after, fall 0 with the mains power of smelting furnace, insert again in the melt and carry out the temperature measurement, meanwhile, aim at the melt with infrared temperature measurement module and carry out the temperature measurement, can obtain two numerical values like this, through the temperature of two numerical values accuracy judgments melt. And after the temperature measurement is finished, the power supply power of the smelting furnace is recovered to keep continuously heating the molten liquid.
S2, preheating the atomization chamber, and detecting the temperature in the atomization chamber in real time to enable the temperature in the atomization chamber to reach a preset temperature.
In the step, the purpose of preheating the atomization chamber is mainly to improve the ambient temperature in the atomization chamber, so that the spheroidization time of the silver liquid drops is increased in the subsequent atomization process, the spheroidization process of the silver liquid drops is realized in enough time, and the silver powder particles with better sphericity (roundness) are obtained.
As a specific embodiment, the process of preheating the atomization chamber comprises:
s21, introducing heat preservation gas with the temperature higher than the preset temperature into the atomizing chamber;
and S22, detecting the temperature in the atomizing chamber in real time until the preset temperature is reached.
Specifically, the heat-insulating gas is also an inert gas, which may be the same as the atomizing gas, or an inert gas with different properties. The amount of the heat-insulating gas is such that the pressure in the atomizing chamber reaches a micro-negative pressure state (e.g., -0.01 MPa).
The temperature in the real-time detection atomizer chamber, accessible set up the sensor in the atomizer chamber and carry out real-time detection, after reaching preset temperature, can stop letting in the gaseous or the gaseous letting in that reduces the heat preservation of letting in of heat preservation.
As another alternative embodiment, the process of preheating the atomization chamber comprises:
s21a, heating the wall surface of the atomizing chamber;
s22a, detecting the temperature in the atomizing chamber in real time until the preset temperature is reached;
and S23a, continuously heating the wall surface of the atomizing chamber and keeping the temperature in the atomizing chamber.
Further, in the step S21a, when the wall surface of the atomizing chamber is heated, the air in the atomizing chamber may be circulated by a circulation fan disposed in the atomizing chamber, so as to accelerate the temperature rise of the environment in the atomizing chamber and equalize the ambient temperature in the atomizing chamber.
The wall surface of the atomizing chamber can be heated by a heating device (such as a heating pipe) arranged on the wall surface of the atomizing chamber, and meanwhile, in order to ensure that the temperature of the atomizing chamber is within a preset range, the wall surface of the atomizing chamber can be subjected to heat preservation treatment, such as adding a heat preservation layer.
And S3, controlling the silver melt to be poured into the tundish and uniformly flow out of the atomizing chamber.
Specifically, the tundish is heated while the heat preservation gas is introduced or after the heat preservation gas is introduced, so that the tundish meets the requirement of the pouring temperature.
Specifically, the molten metal is controlled to be poured into the tundish in a thin liquid column, the molten metal with the height not more than 2cm is remained in the tundish, the uniform control is realized, and when the molten metal smoothly flows in a columnar shape, the gas can be opened for carrying out the atomization process.
And S4, introducing high-pressure inert gas, spraying the inert gas from the atomizing nozzle, and atomizing the dropped silver melt.
Specifically, the silver melt flows into the atomizing nozzle through the liquid guide pipe at the bottom of the tundish under the action of the gravity of the silver melt, the flowing silver melt is impacted and broken by high-pressure controllable inert gas in the atomizing nozzle, so that the silver melt is atomized into fine liquid drops, and the liquid drops fall in the atomizing furnace and are spheroidized, cooled and solidified into spherical metal powder in the falling process.
Because the temperature of the atomizing chamber is increased, the time for spheroidizing the liquid drops is prolonged if the cooling time is longer in the falling process of the liquid drops, and the sphericity of particles formed by the finally cooled liquid drops is better.
Further, the step S4 further includes:
s41, monitoring the temperature in the atomization chamber in real time in the atomization process, and if the real-time temperature is not in a preset range, regulating and controlling the temperature in the atomization chamber to keep the temperature in the preset range.
The atomizing device is influenced by atomizing gas and external environment, and the temperature of the atomizing chamber possibly fluctuates in the atomizing process, so that the temperature in the atomizing chamber can be regulated and controlled by regulating heating power, the temperature of the atomizing chamber is ensured to be always in a reasonable range, and the spheroidizing time of liquid drops is ensured.
And S5, cooling and collecting powder after atomization is finished.
After atomization, the silver powder particles are cooled at the bottom of the atomization chamber, and then the silver powder is collected through the cyclone separation system.
Further, before performing cooling in step S5, the method further includes:
and S50, reducing the pressure of the atomizing gas, and stopping introducing the atomizing gas after continuously purging for a period of time.
Specifically, after atomization is finished, a smelting and tundish heat-insulating power supply is closed, the pressure of atomized gas is reduced, and purging is continued for a period of time (such as 30 seconds). This ensures the completeness of atomization and allows the local region of the atomization chamber to be cleaned.
The cooling process can be through water circulative cooling's mode, and the cooling time goes on according to concrete demand, if the smelting furnace survives the liquation, then need increase the cooling time to avoid producing the damage to the coil.
Compared with the prior art, in the process of the silver powder manufacturing method, the cooling time of the liquid drops is prolonged by pre-increasing the environment temperature in the atomizing chamber, so that the liquid drops are spheroidized for a longer time, the finally cooled silver powder particles have better sphericity (roundness), and the product quality of the silver powder particles is improved.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by using the contents of the present specification and the accompanying drawings, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.

Claims (10)

1. An apparatus for manufacturing silver powder, comprising: the device comprises an atomizing chamber, an atomizing nozzle arranged above the atomizing chamber, a tundish arranged on the atomizing nozzle and a smelting furnace arranged above the tundish;
wherein, the atomizer chamber is provided with the heat preservation subassembly, the heat preservation subassembly is used for promoting ambient temperature in the atomizer chamber.
2. The silver powder manufacturing apparatus according to claim 1, wherein the heat retaining member comprises: with the gaseous pipeline that lets in of heat preservation of atomizer chamber intercommunication, with gaseous heating device and the gaseous storage device that the pipeline is connected are let in to heat preservation gas, it is right when needs the atomizer chamber heaies up, to the atomizer chamber lets in heat preservation gas, heat preservation gas passes through gaseous heating device heats.
3. The silver powder manufacturing apparatus according to claim 2, wherein the insulating gas introduction pipe is provided inside the can body adjacent to a peripheral wall of the can body, and an air outlet direction of the insulating gas does not interfere with an ejection direction of the atomizing nozzle.
4. The silver powder production apparatus according to claim 2, wherein the insulating gas is also an inert gas.
5. The silver powder manufacturing apparatus according to claim 2, wherein a partition is provided in the atomizing chamber, the insulating gas introduction pipe is provided in the partition, and the insulating gas is introduced into the gas flowing space of the partition and then overflows from the partition into the atomizing space of the atomizing chamber.
6. The silver powder manufacturing apparatus according to claim 4, wherein the partition is formed of at least two pieces, each of which is welded to the wall of the atomization chamber.
7. The silver powder manufacturing apparatus according to claim 1, wherein the heat retaining member comprises: and the heating device is arranged on the wall surface of the atomizing chamber and is used for heating the wall surface of the atomizing chamber.
8. The silver powder manufacturing apparatus according to claim 7, wherein the heating means is a heat pipe provided on an inner wall surface of the atomizing chamber.
9. The silver powder manufacturing apparatus according to claim 1, wherein a heat insulating material layer is provided outside the atomization chamber.
10. The silver powder manufacturing apparatus according to claim 1, wherein a temperature measuring device is further provided in the atomizing chamber.
CN202210814949.XA 2022-07-12 2022-07-12 Silver powder manufacturing device Pending CN115213418A (en)

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Application Number Priority Date Filing Date Title
CN202210814949.XA CN115213418A (en) 2022-07-12 2022-07-12 Silver powder manufacturing device

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Application Number Priority Date Filing Date Title
CN202210814949.XA CN115213418A (en) 2022-07-12 2022-07-12 Silver powder manufacturing device

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CN115213418A true CN115213418A (en) 2022-10-21

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001254103A (en) * 2000-03-13 2001-09-18 Sanei Kasei Kk Metallic grain having nanocomposite structure and its producing method by self-organizing
WO2015026224A1 (en) * 2013-08-23 2015-02-26 Universiti Malaysia Perlis A system and a method of producing granulated solder
CN113145854A (en) * 2021-06-10 2021-07-23 江苏智仁景行新材料研究院有限公司 Vacuum electrode induction melting double-flow gas atomization metal powder device
CN113828780A (en) * 2020-06-24 2021-12-24 湖南天际智慧材料科技有限公司 Secondary quenching type amorphous powder production equipment and method thereof
CN114042925A (en) * 2021-11-29 2022-02-15 湖南天际智慧材料科技有限公司 Preheating device for atomization chamber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001254103A (en) * 2000-03-13 2001-09-18 Sanei Kasei Kk Metallic grain having nanocomposite structure and its producing method by self-organizing
WO2015026224A1 (en) * 2013-08-23 2015-02-26 Universiti Malaysia Perlis A system and a method of producing granulated solder
CN113828780A (en) * 2020-06-24 2021-12-24 湖南天际智慧材料科技有限公司 Secondary quenching type amorphous powder production equipment and method thereof
CN113145854A (en) * 2021-06-10 2021-07-23 江苏智仁景行新材料研究院有限公司 Vacuum electrode induction melting double-flow gas atomization metal powder device
CN114042925A (en) * 2021-11-29 2022-02-15 湖南天际智慧材料科技有限公司 Preheating device for atomization chamber

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Application publication date: 20221021