CN115181377B - 一种耐低温抗开裂的高阻燃护套胶料及其制备方法及电缆 - Google Patents
一种耐低温抗开裂的高阻燃护套胶料及其制备方法及电缆 Download PDFInfo
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- CN115181377B CN115181377B CN202210853602.6A CN202210853602A CN115181377B CN 115181377 B CN115181377 B CN 115181377B CN 202210853602 A CN202210853602 A CN 202210853602A CN 115181377 B CN115181377 B CN 115181377B
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 37
- 239000000463 material Substances 0.000 title claims abstract description 37
- 238000005336 cracking Methods 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 50
- 239000011347 resin Substances 0.000 claims abstract description 50
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 44
- 239000004014 plasticizer Substances 0.000 claims abstract description 31
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 31
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 31
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 claims abstract description 22
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000314 lubricant Substances 0.000 claims abstract description 18
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 238000004513 sizing Methods 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000000155 melt Substances 0.000 claims description 14
- 239000011812 mixed powder Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 239000003607 modifier Substances 0.000 claims description 13
- 239000007822 coupling agent Substances 0.000 claims description 12
- 239000000347 magnesium hydroxide Substances 0.000 claims description 12
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 229940009868 aluminum magnesium silicate Drugs 0.000 claims description 6
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- -1 amido silane Chemical compound 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 3
- 238000009817 primary granulation Methods 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 3
- 238000010408 sweeping Methods 0.000 claims description 3
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 3
- 238000004804 winding Methods 0.000 abstract description 18
- 238000002485 combustion reaction Methods 0.000 abstract description 11
- 239000005038 ethylene vinyl acetate Substances 0.000 description 43
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 43
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 11
- 239000002245 particle Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 230000032683 aging Effects 0.000 description 6
- 238000005452 bending Methods 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- NEHDRDVHPTWWFG-UHFFFAOYSA-N Dioctyl hexanedioate Chemical compound CCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC NEHDRDVHPTWWFG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/14—Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
原材料 | 例1 | 例2 | 例3 | 例4 | 例5 | 例6 | 例7 | 例8 | 例9 | 例10 |
SG0型PVC树脂 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
偏苯三酸三辛酯 | 55 | 55 | 55 | 55 | 55 | 55 | 55 | 55 | 55 | 55 |
己二酸二辛酯 | 15 | 20 | 15 | 15 | 15 | 15 | 15 | 15 | 15 | 15 |
EVATANE 33-25 | 20 | 20 | 15 | 15 | 15 | 0 | 0 | 10 | 10 | 0 |
EVATANE 33-45 | 0 | 0 | 0 | 0 | 0 | 20 | 0 | 10 | 0 | 0 |
Evaflex 150 | 0 | 0 | 0 | 0 | 0 | 0 | 20 | 0 | 10 | 0 |
Evaflex 250 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 20 |
三氧化二锑 | 20 | 20 | 15 | 20 | 15 | 20 | 20 | 20 | 20 | 20 |
表面改性氢氧化镁 | 70 | 0 | 70 | 70 | 20 | 70 | 70 | 70 | 70 | 70 |
十溴二苯乙烷 | 20 | 20 | 15 | 20 | 15 | 20 | 20 | 20 | 20 | 20 |
钙锌稳定剂 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 |
润滑剂 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 |
Claims (6)
Priority Applications (1)
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CN202210853602.6A CN115181377B (zh) | 2022-07-11 | 2022-07-11 | 一种耐低温抗开裂的高阻燃护套胶料及其制备方法及电缆 |
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CN202210853602.6A CN115181377B (zh) | 2022-07-11 | 2022-07-11 | 一种耐低温抗开裂的高阻燃护套胶料及其制备方法及电缆 |
Publications (2)
Publication Number | Publication Date |
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CN115181377A CN115181377A (zh) | 2022-10-14 |
CN115181377B true CN115181377B (zh) | 2023-11-03 |
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CN202210853602.6A Active CN115181377B (zh) | 2022-07-11 | 2022-07-11 | 一种耐低温抗开裂的高阻燃护套胶料及其制备方法及电缆 |
Country Status (1)
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CN (1) | CN115181377B (zh) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103450551A (zh) * | 2013-08-30 | 2013-12-18 | 江苏达胜高聚物有限公司 | 一种无卤阻燃聚烯烃电缆料 |
CN109897303A (zh) * | 2019-01-21 | 2019-06-18 | 乐庭电线工业(惠州)有限公司 | 射频线聚氯乙烯电缆料及其制备方法 |
CN114672105A (zh) * | 2021-12-29 | 2022-06-28 | 广东祥利科技有限公司 | 一种耐恶劣环境的机器人拖链电缆用聚氯乙烯材料 |
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2022
- 2022-07-11 CN CN202210853602.6A patent/CN115181377B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103450551A (zh) * | 2013-08-30 | 2013-12-18 | 江苏达胜高聚物有限公司 | 一种无卤阻燃聚烯烃电缆料 |
CN109897303A (zh) * | 2019-01-21 | 2019-06-18 | 乐庭电线工业(惠州)有限公司 | 射频线聚氯乙烯电缆料及其制备方法 |
CN114672105A (zh) * | 2021-12-29 | 2022-06-28 | 广东祥利科技有限公司 | 一种耐恶劣环境的机器人拖链电缆用聚氯乙烯材料 |
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Effective date of registration: 20240109 Address after: No.6, Qingli Second Road, Shuikou Street, Huicheng District, Huizhou, Guangdong Province, 516000 Patentee after: LTK Electric Wire (Huizhou) Ltd. Patentee after: HUIZHOU LTK ELECTRONIC CABLE Co.,Ltd. Patentee after: SHENZHEN WOER SPECIAL CABLE Co.,Ltd. Patentee after: LTK ELECTRIC WIRE (CHANGZHOU) Ltd. Address before: 516229 Desai No.3 Industrial Zone, Zhongkai Avenue, Chenjiang, Huizhou City, Guangdong Province Patentee before: LTK ELECTRIC WIRE (HUIZHOU) Ltd. Patentee before: HUIZHOU LTK ELECTRONIC CABLE Co.,Ltd. Patentee before: LTK ELECTRIC WIRE (CHANGZHOU) Ltd. |
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