CN115141502A - Visible light catalytic bactericidal antiviral coating material and preparation method thereof - Google Patents

Visible light catalytic bactericidal antiviral coating material and preparation method thereof Download PDF

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Publication number
CN115141502A
CN115141502A CN202210935975.8A CN202210935975A CN115141502A CN 115141502 A CN115141502 A CN 115141502A CN 202210935975 A CN202210935975 A CN 202210935975A CN 115141502 A CN115141502 A CN 115141502A
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parts
coating material
visible light
light catalytic
nano
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CN202210935975.8A
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王飞
孙帅先
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Qingdao Wanyuan Biological Science & Technology Co ltd
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Qingdao Wanyuan Biological Science & Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a visible light catalytic bactericidal antiviral coating material, which comprises 5-20 parts of CSNM nano active oxide, 40-60 parts of purified water, 10-30 parts of nano white bamboo charcoal, 30-50 parts of nano shell powder and 15-30 parts of nano titanium dioxide; wet grinding 5-20 parts of CSNM nano active oxide to 5-10nm to obtain transparent liquid; has the functions of antibiosis, antivirus, antibiosis, mildew prevention, aldehyde removal and purification, can efficiently remove toxic and harmful gases in the air, such as formaldehyde, toluene, ammonia, TVOC and the like, and has the functions of antibiosis, antivirus, mildew prevention, insect prevention, pollution prevention, self-cleaning, ultraviolet aging resistance.

Description

Visible light catalytic bactericidal antiviral coating material and preparation method thereof
Technical Field
The invention relates to a visible light catalytic sterilization antiviral coating material and a preparation method thereof, belonging to the technical field of materials.
Background
The PET bottle cleaning and recycling technology is characterized in that PET bottles collected after consumption are subjected to impurity removal through a specific recovery cleaning mechanism in each process, the impurity removal comprises label separation, bottle surface purification, bottle classification, metal removal and the like, the PET bottles are reduced into fragments from bottles, and then the fragments are subjected to cleaning and purification treatment again to finally serve as recycled PET raw materials.
The PET bottle is cleaned and then needs to be crushed into bottle flakes to be further cleaned and purified, the crusher is important equipment in the process, materials are sheared by the relative movement between the driven knife and the fixed knife after entering the crusher, the bottom of the machine body is provided with a screen plate with a certain size, and the materials with the aperture smaller than that of the screen plate can pass through the screen plate to the next process after being sheared for a plurality of times.
Rubbing crusher among present PET bottle cleaning equipment uses removable blade, and nevertheless blade wearing and tearing are very fast in the course of working, and the blade that needs to be changed every 24 hours under the usual condition, and because processing production needs, the size of rubbing crusher and its cutter is great relatively, and this has brought great work degree of difficulty for tool changing and the work of whetting a knife, needs a large amount of personnel to carry out tool changing, the work of whetting a knife every day to cause the cost of labor to rise.
Meanwhile, the phenomenon of blade breakage exists in the normal production process, the common blade cannot be repaired after the problems occur, only a new blade can be selected to be replaced, and the equipment maintenance expenditure is increased.
In addition, process shutdown is caused during waste bottle crushing and tool changing to influence production efficiency, or a spare crusher is arranged to increase equipment and factory building investment to improve production cost; for the reasons mentioned above, it is necessary to study how to shorten the tool replacement time and prolong the tool service life.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a visible light catalytic sterilization antiviral coating material and a preparation method thereof, and the visible light catalytic sterilization antiviral coating material has the advantages of antibiosis, antivirus, antibiosis, mildew prevention, aldehyde removal and purification, can efficiently remove toxic and harmful gases such as formaldehyde, toluene, ammonia, TVOC and the like in the air, and has the effects of antibiosis, antivirus, mildew prevention, insect prevention, pollution prevention, self-cleaning and ultraviolet aging resistance.
In order to solve the above problems, the present invention provides the following technical solutions:
the visible light catalytic bactericidal antiviral coating material comprises 5-20 parts of CSNM nanometer active oxide, 40-60 parts of purified water, 10-30 parts of nanometer white bamboo charcoal, 30-50 parts of nanometer shell powder and 15-30 parts of nanometer titanium dioxide.
The following is a further improvement of the above technical scheme:
wet grinding 5-20 parts of CSNM nanometer active oxide to 5-10nm to obtain transparent liquid.
The following is a further improvement of the above technical solution:
the purified water is ozone-sterilized purified water.
The following is a further improvement of the above technical solution:
sterilizing purified water 40-60 parts by ozone, adding the transparent liquid, adding nanometer white bamboo charcoal 10-30 parts, nanometer shell powder 30-50 parts and nanometer titanium dioxide 15-30 parts, and stirring.
The following is a further improvement of the above technical solution:
the stirring process is carried out uniformly at a rotating speed of more than 1900 rpm.
The following is a further improvement of the above technical solution:
the temperature in the stirring step is controlled to be more than 90 ℃.
In the stirring step, the stirring was continued under vacuum for 25 minutes.
And after stirring, cooling to less than 30 ℃ and filling.
The visible light catalytic sterilization antiviral coating material has the advantages of antibiosis, antivirus, antibiosis, mildew prevention, aldehyde removal and purification, can efficiently remove toxic and harmful gases in air such as formaldehyde, toluene, ammonia, TVOC and the like, and has the effects of antibiosis, antivirus, mildew prevention, insect prevention, pollution prevention, self-cleaning and ultraviolet aging resistance.
Antibacterial property and antibacterial durability; the antibacterial rate of escherichia coli, staphylococcus aureus, pneumonia bacillus and pseudomonas aeruginosa is more than 99.9%; the mildew resistance and the mildew resistance durability are achieved, and the mildew-proof grade is 0; the algae resistance is rated as 0 grade; the antiviral activity rate of the influenza virus H1N1, the enterovirus 71 and the poliovirus reaches over 90 percent; the purification performance and the purification durability are high, and the purification removal rate of indoor volatile harmful gases such as formaldehyde, toluene, ammonia, TVOC, hydrogen sulfide and the like and peculiar smell is over 85 percent.
Detailed Description
The visible light catalytic bactericidal antiviral coating material comprises 5-20 parts of CSNM nano active oxide, 40-60 parts of purified water, 10-30 parts of nano white bamboo charcoal, 30-50 parts of nano shell powder and 15-30 parts of nano titanium dioxide.
A preparation method of a visible light catalytic sterilization antiviral coating material comprises the step of wet grinding 5-20 parts of CSNM nano active oxide to 5-10nm to obtain transparent liquid.
The preparation method of the visible light catalytic sterilization antiviral coating material comprises the steps of disinfecting 40-60 parts of purified water by ozone, adding 10-30 parts of nano white bamboo charcoal, 30-50 parts of nano shell powder and 15-30 parts of nano titanium dioxide, controlling the temperature to be more than 90 ℃ at a speed of more than 1900 r/min, continuing for 25 minutes in a vacuum state, and beginning cooling to be less than 30 ℃ for filling.
The visible light catalytic bactericidal antiviral coating material is obtained, and has the functions of antibiosis, antivirus, antibiosis, mould prevention, aldehyde removal and purification.
The high-performance manufacturing technology aims at improving the requirements of different performances of the material on the antibacterial and antiviral material, takes the basic chemical design principle of the material as guidance, takes the basic chemical structure of the material as a basis, develops a novel systematic method for controlling the structure of the purifying material, provides a new way for synthesizing the material with the molecular function of a specific structure, and provides a basis for the research and development of the material with different performances and different application fields.
The difficulty of the inorganic nano composite antibacterial material lies in that the antibacterial and antiviral properties of the material are difficult to control, so that the problem is fundamentally solved in order to reduce the purification performance of the whole system, and the selection of raw materials is particularly important.
The obtained visible light catalytic bactericidal antiviral coating material is tested, and the technical indexes are shown in the table I:
Figure DEST_PATH_IMAGE002A
the visible light catalytic sterilization antiviral coating material is suitable for antibacterial, antiviral, antibacterial, mildewproof, aldehyde-removing and purification, can efficiently remove toxic and harmful gases in the air, such as formaldehyde, toluene, ammonia, TVOC and the like, and has the functions of antibacterial, antiviral, mildewproof, insect prevention, pollution prevention, self-cleaning and ultraviolet aging resistance;
the usage and dosage are as follows: according to the functional requirements of the applicable material such as structural performance, use environment, different antiviral and antibacterial effects and the like, the optimal dosage needs to be tested by tests, and the recommended addition dosage is as follows: 1) adding the coating material accounting for 3-5% of the total weight during antivirus and antibiosis, 2) adding the coating material accounting for 2-5% of the total weight during antibiosis and mildew prevention, 3) adding the coating material accounting for 3-5% of the total weight during formaldehyde and toluene removal, and 4) adding the coating material accounting for 1-5% of the total weight during peculiar smell removal.
The raw materials are directly added into the raw material formula according to a certain dosage proportion in the production process, the raw materials are fully and uniformly stirred for use after the raw materials are added, and the original production process and equipment conditions do not need to be changed. Wherein, when the powder is used for manual sample preparation, the powder is uniformly dispersed; can be added with water for mixing evenly and then stirred.
Safety: the product is very safe under the use concentration, the result of one-time complete skin irritation and corrosion test shows no irritation, and the acute oral toxicity test shows no toxicity and no adverse reaction. Sealed and dried for storage at normal temperature in dark place, and the product is not suitable for long-term exposure to air.
The detection method comprises the following steps: content of non-volatile matter: the product is uniformly mixed according to the specification and then is weighed immediately, the sample weight is weighed to be (2 +/-0.2) g, the weighed sample is placed at the temperature of (23 +/-2) DEG C for 24h and then is tested according to the specification of GB/T1725-2007, the baking temperature is (105 +/-2) DEG C, the baking time is 1h, and no volatile matter is detected.
The antibacterial performance tests the durability of the microorganisms and the antibacterial performance, and the microorganism and bacteria are not detected in the invention according to the GB/T21866-2008 standard requirement (grade I) and the average recovery bacterial count of a blank control sample after 24 h.
And (3) testing the virus and the host, wherein the sample is diluted by adding 25% of water and then coated, after the control sample is inoculated with the sample which is not subjected to antiviral treatment for 1 hour, and after the virus titer control sample is inoculated with the sample which is not subjected to antiviral treatment for 24 hours, the virus titer antiviral activity rate is less than 1%.
And (3) testing the mildew resistance, wherein the sample is a coated glass sheet, 50mm x 50mm filter paper is used as a positive control of the test, and a test sample inoculated with sterile water is used as a negative control. The detection basis is as follows: GB/T1741-2007 determination method of the resistance of paint films to fungi.
Safety detection, inspection basis: disinfection Specification 2002 edition 2.3.1 acute oral toxicity test.
A limited test method is adopted, namely 10 female and male test objects are orally administered to a tested mouse at one time according to the administration dosage of 5000mg/kgBW, the test objects are prepared at present, 2.5g of test object solution samples are weighed, a proper amount of deionized water is added to the constant volume of 10mL, a sample solution with the concentration of 0,25g/mL is obtained, and the sample solution is fully and uniformly mixed for later use. The test substance is fasted overnight before being given to the mouse, weighed and marked on the same day of the experiment, and is given to the mouse by single oral gavage according to the stomach volume of 20mIAgBWM, and the servo is given 2 hours after the mouse is given to the test substance.
Animal signs are observed 0.5 hour, 2 hours and 4 hours after the test object is given, the toxic signs, the appearance and disappearance of symptoms and the death time of the animal of the mouse are recorded, and then the observation is carried out for 1 time every day, wherein the observation period is 14 days.

Claims (8)

1. The visible light catalytic bactericidal antiviral coating material is characterized in that: comprises 5-20 parts of CSNM nano active oxide, 40-60 parts of purified water, 10-30 parts of nano white bamboo charcoal, 30-50 parts of nano shell powder and 15-30 parts of nano titanium dioxide.
2. The visible light catalytic bactericidal antiviral coating material as set forth in claim 1, wherein: wet grinding 5-20 parts of CSNM nanometer active oxide to 5-10nm to obtain transparent liquid.
3. The visible light catalytic bactericidal antiviral coating material as set forth in claim 2, wherein: the purified water is ozone-disinfected purified water.
4. The preparation method of the visible light catalytic bactericidal antiviral coating material is characterized by comprising the following steps: sterilizing 40-60 parts of purified water by ozone, adding the transparent liquid, adding 10-30 parts of nano white bamboo charcoal, 30-50 parts of nano shell powder and 15-30 parts of nano titanium dioxide, and uniformly stirring.
5. The method for preparing the visible light catalytic bactericidal antiviral coating material as claimed in claim 4, wherein: the stirring process is carried out uniformly at a rotating speed of more than 1900 rpm.
6. The preparation method of the visible light catalytic bactericidal antiviral coating material as claimed in claim 5, characterized in that: the temperature in the stirring step is controlled to be more than 90 ℃.
7. The preparation method of the visible light catalytic bactericidal antiviral coating material as claimed in claim 6, characterized in that: in the stirring step, the stirring was continued under vacuum for 25 minutes.
8. The preparation method of the visible light catalytic bactericidal antiviral coating material as claimed in claim 7, characterized in that: and after stirring, cooling to less than 30 ℃ and filling.
CN202210935975.8A 2022-08-05 2022-08-05 Visible light catalytic bactericidal antiviral coating material and preparation method thereof Pending CN115141502A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104592841A (en) * 2014-12-30 2015-05-06 三棵树涂料股份有限公司 Inorganic antibacterial formaldehyde-removing paint and preparation method thereof
CN111053089A (en) * 2019-12-23 2020-04-24 中星(广州)纳米材料有限公司 Nano sterilizing and formaldehyde removing composition and preparation method thereof
CN112921666A (en) * 2021-01-26 2021-06-08 广西每好实业股份有限公司 Agilawood emulsion with antiviral and bactericidal effects as well as preparation method and application thereof
CN114250004A (en) * 2021-12-28 2022-03-29 沈阳康亿环保科技有限公司 Environment-friendly antibacterial antiviral mildew-proof integrated interior wall coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104592841A (en) * 2014-12-30 2015-05-06 三棵树涂料股份有限公司 Inorganic antibacterial formaldehyde-removing paint and preparation method thereof
CN111053089A (en) * 2019-12-23 2020-04-24 中星(广州)纳米材料有限公司 Nano sterilizing and formaldehyde removing composition and preparation method thereof
CN112921666A (en) * 2021-01-26 2021-06-08 广西每好实业股份有限公司 Agilawood emulsion with antiviral and bactericidal effects as well as preparation method and application thereof
CN114250004A (en) * 2021-12-28 2022-03-29 沈阳康亿环保科技有限公司 Environment-friendly antibacterial antiviral mildew-proof integrated interior wall coating and preparation method thereof

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Application publication date: 20221004