CN1151206C - All degraded material and method for making disposable products by utilizing said material - Google Patents
All degraded material and method for making disposable products by utilizing said material Download PDFInfo
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- CN1151206C CN1151206C CNB011136782A CN01113678A CN1151206C CN 1151206 C CN1151206 C CN 1151206C CN B011136782 A CNB011136782 A CN B011136782A CN 01113678 A CN01113678 A CN 01113678A CN 1151206 C CN1151206 C CN 1151206C
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The present invention relates to a fully degradable material and a method for manufacturing disposable products. The material comprises the components of the following proportion (weight percentage): 35 to 55% of amino moulding plastics, 33 to 58% of starch, 4 to 11% of neutral calcium carbonate and 2 to 3% of plant fibre, wherein the plant fibre can be one of rice hulls, crop stalks, bagasse, corncobs and peanut hulls. The manufacturing technique comprises: crushing the raw materials; mixing and preparing the raw materials; moulding and forming by two times with unit pressure being 300 to 450 kg/cm<2>, temperature being 120 to 180DEG C and time for preserving heat and pressure being 25 to 80 seconds; demoulding and carrying out post processing to obtain the product. The present invention which has the characteristics of high degradation speed, low cost, favorable performance, simple manufacturing technique and strong practicability is suitable for manufacturing disposable tableware, food packages, article packages, disposable medical articles, etc.
Description
Technical field
The present invention relates to a kind of Wholly-degradable material and utilize this material to make method disposable, degradable product.Above-mentioned degradable disposable product comprises disposable food and drink tool, food product pack, article packing and disposable medical article etc.
Background technology
As everyone knows, be that main " white pollution " that causes become an outstanding problem in the current governance environmental pollution with the disposable food or beverage container.Countries in the world government and environmentalists have recognized that disaster and the harm that " white pollution " brings to human environment, and are adopting vigorous measures and solving.The many countries in Europe ban use of the disposable food or beverage container and the plastic packing product of non-degraded already.In China, biodegradable plastic is listed in " eight or five " key research projects and " 95 " key popularized project, administers " white pollution " and has been subjected to the great attention of departments at different levels of government, and become the big problem that the whole society pays close attention to.Many cities have begun to ban use of disposable PS food and drink tool, and many enterprises and researchist substitute the research and development of goods in this problem degradation property of throwing oneself into.In recent years, China's patent discloses many technical schemes in succession with regard to the present technique theme, and it is to adopt the method for paper mould to make that conclusion gets up roughly to have following four classes, the first kind; Second class is that the full starch of employing is that raw material is made; The 3rd class is to adopt decomposable plastic material to make; The 4th class is to adopt sponge to make.Although above-mentioned various technical scheme has proposed many measures from different perspectives, and has obtained positively effect, still there are a lot of problems from practical application, such as, paper mould production cost height, the discharging in the production process can bring black pollution.Full starch-type production process is pollution-free, but the cost of material height.The decomposable plastics goods can not be degraded into innoxious substance entirely.Plant fiber products need be by combustion system degraded fast.Above defective from different degree direct influence the substitution effect of existing degraded goods, also be one of problem of really not being resolved of China's " white pollution ".
Summary of the invention
The object of the invention provides a kind of fast, Wholly-degradable material that cost is low, performance good, technology is simple, practical and method of utilizing this material preparation disposable product of degrading.
For achieving the above object, first kind of technical scheme that Wholly-degradable material of the present invention adopts is: a kind of Wholly-degradable material for preparing disposable product, contain the raw material and the weight percent of following component:
Amino film plastics 35～55% weight;
Starch 33～58% weight;
Middle matter lime carbonate 4～11% weight;
Vegetrable fibre material 2～3% weight;
Wherein said Vegetrable fibre material is a kind of in rice hulls, crop straw, bagasse, corn cob, the Pericarppium arachidis hypogaeae.This prescription is suitable for preparing disposable full degraded type food and drink tool, food packaging article and disposable medical article.Amino film plastics in the scheme plays the effect of toning and binding agent in prescription, starch plays degraded, catches aldehyde and filler effect in prescription, middle matter lime carbonate plays degradation agents, modification and filler effect in prescription, Vegetrable fibre material plays filler effect in prescription.
In the technique scheme, according to the degraded time limit the requirement difference can produce following two kinds of prescriptions:
1, for described degradable material can be degraded in 180 days (6 months) fully, its feed composition and weight percent are:
Amino film plastics 36～44% weight;
Starch 47～58% weight;
Middle matter lime carbonate 4～6% weight;
Vegetrable fibre material 2～3% weight;
Account for more than 50% owing to the degradable raw material weight in this prescription, so degradation speed is fast.
2, for described degradable material can be degraded in 6～12 months fully, its feed composition and weight percent are:
Amino film plastics 45～55% weight;
Starch 33～42% weight;
Middle matter lime carbonate 9～11% weight;
Vegetrable fibre material 2～3% weight.
For achieving the above object, second kind of technical scheme that Wholly-degradable material of the present invention adopts is: a kind of Wholly-degradable material for preparing disposable product, contain the raw material and the weight percent of following component:
Amino film plastics 45～55% weight;
Starch 18～22% weight;
Middle matter lime carbonate 4～6% weight;
Vegetrable fibre material 20～25% weight;
Water 2～3% weight;
Wherein said Vegetrable fibre material is a kind of in rice hulls, crop straw, bagasse, corn cob, the Pericarppium arachidis hypogaeae.The described degradable material of this scheme can degraded fully in 6～12 months.This prescription is suitable for preparing the usual articles packing material.Amino film plastics in the scheme plays the effect of toning and binding agent in prescription, starch plays degraded, catches aldehyde and filler effect in prescription, middle matter lime carbonate plays degradation agents, modification and filler effect in prescription, Vegetrable fibre material plays filler effect in prescription.
Wholly-degradable material of the present invention can be used to prepare disposable product, and described disposable product includes but not limited to full degraded type food and drink tool, food product pack, article packing and disposable medical article.
For achieving the above object, the present invention utilizes above-mentioned first kind of Wholly-degradable material to prepare the method for disposable product, comprises the following steps:
(1), Vegetrable fibre material is crushed to 100～200 orders;
(2), matter lime carbonate, the mixing of 2～3% weight Vegetrable fibre materials in 35～55% weight amino film plastics, 33～58% weight starch, 4～11% weight are stirred evenly and obtain compound;
(3), compound is added matched moulds first pressing in the die cavity, open parting line venting once, first pressing unit pressure 300～450kg/cm
2, temperature is 120～180 ℃;
(4), matched moulds hot-press solidifying moulding once more, unit pressure is 300～450kg/cm
2, temperature is 120～180 ℃, 25～80 seconds set times of heat-insulation pressure keeping;
(5), the demoulding and carry out aftertreatment and promptly get goods.
For achieving the above object, the present invention utilizes above-mentioned second kind of Wholly-degradable material to prepare the method for disposable product, comprises the following steps:
(1), Vegetrable fibre material is crushed to 100～200 orders;
(2), earlier with 20～25% weight Vegetrable fibre materials and 2～3% weight water mixings, again with 45～55% weight amino film plastics, 18～22% weight starch and 4～6% weight in matter lime carbonate mix to stir evenly and obtain compound;
(3), compound is added matched moulds first pressing in the die cavity, open parting line venting once, first pressing unit pressure 300～450kg/cm
2, temperature is 120～180 ℃;
(4), matched moulds hot-press solidifying moulding once more, unit pressure is 300～450kg/cm
2, temperature is 120～180 ℃, 25～80 seconds set times of heat-insulation pressure keeping;
(5), the demoulding and carry out aftertreatment and promptly get goods.
In the technique scheme the first step, amino film plastics, starch and middle matter lime carbonate are powdery generally speaking, wherein the granularity of amino film plastics and starch is all more than 140 orders, if the raw material of configuration does not reach granularity requirements, and also should be with its pulverization process to 140 orders.
Technique scheme is in the 3rd step, and described unit pressure is preferably 370～430kg/cm
2, temperature is 140～160 ℃.
Technique scheme is in the 4th step, and described unit pressure is preferably 370～430kg/cm
2, temperature is 140～160 ℃, 40～60 seconds set times of heat-insulation pressure keeping.
Technique scheme the 3rd step first pressing and the 4th one-step forming are pressed, and can utilize same secondary mould to finish continuously, also can use two secondary moulds to suppress respectively.
Technique scheme is in the 5th step, and described aftertreatment mainly comprises finishing and sterilization.Sterilization can adopt the method for ultra-violet sterilization to carry out disinfection, and temperature is controlled at about 300 ℃.Also can adopt other routine disinfection method.
Because the technique scheme utilization, the present invention compared with prior art has following advantage and effect:
1, sample of the present invention " migration test: heavy metal determine " is reported as follows:
(1), measuring unit
The Singapore's productivity and the Bureau of Standards (PSB) have 1000 employees' cura legitima office to implement the migration test in Singapore.PSB is by guaranteeing that technology and product directly adapt to international standard and help local company visit world market.
(2), theme
Determining of the heavy metal of the sample that " the biodegradable material " be made up of agricultural fibre made.This test was finished on October 2nd, 2000, and test report is numbered 29S0002989-EO.
(3), sample description
The sample description that " the biodegradable material " be made up of agricultural fibre made is as follows:
A, the table items that can dispose
B, gardening product
C, wrapping material
D, medical device
(4), testing method
EN71-3 is an European standard, is ratified on December 13rd, 1994 by European Committee for Standardization (CEN).The member of CEN is the State Bureau of Standardization of Austria, Belgium, Denmark, Finland, France, Germany, Greece, Ireland, Iceland, Italy, Luxembourg, Holland, Norway, Portugal, Spain, Sweden, Switzerland and Britain.According to the CEN/CENELEC internal rules, these countries must carry out this European standard.
A, EN71: the 3rd part, in March nineteen ninety-five " security of toy ", the 3rd part " is determined the technical qualification of migration of element ".
B, by atom absorption spectrophotometry instrument-cold vapor method test mercury content.
C, disperse spectrophotometer method by inductive coupled plasma-atom and test other element.
(5), test result
The 3rd part nineteen ninety-five of element biodegradable material EN71
Antimony SB (mg/kg)＜5.0 maximum value 60
Arsenic As (mg/kg)＜5.0 maximum value 25
Barium Bs (mg/kg)＜5.0 maximum value 250
Cadmium Cd (mg/kg)＜0.5 maximum value 50
Chromium Cr (mg/kg)＜0.5 maximum value 25
Plumbous Pb (mg/kg)＜5.0 maximum value 90
Mercury Hg (mg/kg)＜0.5 maximum value 25
Selenium Se (mg/kg)＜5.0 maximum value 500
(6), explain
The requirement of this standard is based on toy and uses the biological availability that causes, and each object should not surpass above-mentioned tabulation (test result the 3rd row) level of every day.Measurement is unit (mg/Kg) with the per kilogram milligram.
Sample test result (the 2nd row of table with test results) is away from its upper limit.
2, degradation speed of the present invention is fast, and is high temperature resistant, anti-freezing, water-fast, and intensity is good.According to GB6344-1996 " mensuration of flexible foam polymer materials tensile strength and extension at break degree " and GB3681-2000 " plastics atmospheric exposure test method ", product of the present invention through test and mensuration physicochemical property is:
Tensile strength 〉=1.5MPa
Extension at break degree≤2%
The heatproof situation does not have obviously distortion for 80～100 ℃
Degradation time is under 25 ℃ of humidity 80% conditions, and degraded start-stop day is 7～60 days
Soak in 80～100 ℃ of water of water resisting property and do not have obviously distortion in 2 hours
3, product of the present invention is white or oyster white, and smell is food using slightly, and appearance looks elegant, health are overall near existing disposable PS food and drink tool, wherein some index even surpass disposable PS food and drink tool.
4, manufacture method of the present invention is that dry method is hot-forming, the pollution-free discharge of production process, and also complete processing is simple.
5, goods of the present invention are hot-forming by twice, and are provided with exhaust, retraction technology between twice hot pressing, further raising quality of item has been played active effect, and obtained effect significantly.
6, after disposable product of the present invention used, recyclable grinding and processing adult fish was held feed, but also natural degradation becomes organic fertilizer.
7, abundant raw material of the present invention, cost is relatively low, produces in enormous quantities to have the market competitiveness from product price, is a kind of desirable substitute products that replace existing plastic foam product.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Embodiment one: a kind of disposable full degrading dining tool (degradative phase is in 180 days or 6 months), make by following prescription and preparation technology.The raw material and the weight percent of prescription are:
Amino film plastics powder 40% weight;
Semen Maydis powder 52.5% weight;
Middle matter Paris white 5% weight;
Corn cob 2.5% weight.
Manufacturing process is:
(1), raw materials pretreatment.Corn cob is pulverized 120 orders.
(2), preparation compound.Dispose each raw material powder by the prescription weighing, and with each raw material mix stir compound.
(3), compression molding.Compound is added matched moulds first pressing in the die cavity, open parting line venting once, matched moulds hot-press solidifying moulding once more, unit pressure is 400kg/cm
2, temperature is 150 ℃, 50 seconds set times of heat-insulation pressure keeping.
(4), the demoulding.
(5), finishing.Remove burr, repolish attitude shape, if model is the split mold of a plurality of goods then at first wants cutting.
(6), disinfect.
(7), finished product packing.
Embodiment two: a kind of disposable high-fall medical dish (degradative phase is 6～12 months) of separating, make by following prescription and preparation technology.The raw material and the weight percent of prescription are:
Amino film plastics powder 50% weight;
Flour 37.5% weight;
Middle matter Paris white 10% weight;
Straw 2.5% weight.
Manufacturing process is:
(1), raw materials pretreatment.Straw is crushed to 120 orders.
(2), preparation compound.Dispose each raw material powder by the prescription weighing, and with each raw material mix stir compound.
(3), compression molding.Compound is added matched moulds first pressing in the die cavity, open parting line venting once, matched moulds hot-press solidifying moulding once more, unit pressure is 400kg/cm
2, temperature is 150 ℃, 50 seconds set times of heat-insulation pressure keeping.
(4), the demoulding.
(5), finishing.Remove burr, repolish attitude shape, if model is the split mold of a plurality of goods then at first wants cutting.
(6), disinfect.
(7), finished product packing.
Embodiment three: a kind of disposable article packing (degradative phase is 6～12 months), make by following prescription and preparation technology.The raw material and the weight percent of prescription are:
Amino film plastics powder 50% weight;
Beans powder 20% weight;
Middle matter Paris white 5% weight;
Rice bran 22.5% weight;
Water 2.5% weight.
Manufacturing process is:
(1), raw materials pretreatment.Rice bran is crushed to 120 orders.
(2), preparation compound.Dispose each raw material powder by the prescription weighing, earlier the rice bran powder is added the water mixing and stirring, and then obtain compound with amino film plastics powder, beans powder and middle matter Paris white mixing and stirring.
(3), compression molding.Compound is added matched moulds first pressing in the die cavity, open parting line venting once, matched moulds hot-press solidifying moulding once more, unit pressure is 400kg/cm
2, temperature is 150 ℃, 50 seconds set times of heat-insulation pressure keeping.
(4), the demoulding.
(5), finishing.Remove burr, repolish attitude shape, if model is the split mold of a plurality of goods then at first wants cutting.
(6), disinfect.
(7), finished product packing.
Claims (7)
1, a kind of Wholly-degradable material is characterized in that containing following component:
Amino film plastics 35～55% weight;
Starch 33～58% weight;
Middle matter lime carbonate 4～11% weight;
Vegetrable fibre material 2～3% weight;
Wherein said Vegetrable fibre material is a kind of in rice hulls, crop straw, bagasse, corn cob, the Pericarppium arachidis hypogaeae.
2, Wholly-degradable material according to claim 1 is characterized in that described material contains following component:
Amino film plastics 36～44% weight;
Starch 47～58% weight;
Middle matter lime carbonate 4～6% weight;
Vegetrable fibre material 2～3% weight.
3, Wholly-degradable material according to claim 1 is characterized in that described material contains following component:
Amino film plastics 45～55% weight;
Starch 33～42% weight;
Middle matter lime carbonate 9～11% weight;
Vegetrable fibre material 2～3% weight.
4, a kind of Wholly-degradable material is characterized in that containing following component:
Amino film plastics 45～55% weight;
Starch 18～22% weight;
Middle matter lime carbonate 4～6% weight;
Vegetrable fibre material 20～25% weight;
Water 2～3% weight;
Wherein said Vegetrable fibre material is a kind of in rice hulls, crop straw, bagasse, corn cob, the Pericarppium arachidis hypogaeae.
5, according to the application of any one described Wholly-degradable material in the claim 1～4 in the preparation disposable product.
6, a kind of method for preparing disposable product according to the Wholly-degradable material of claim 1 of utilizing is characterized in that comprising the following steps:
(1), Vegetrable fibre material is crushed to 100～200 orders;
(2), matter lime carbonate, the mixing of 2～3% weight Vegetrable fibre materials in 35～55% weight amino film plastics, 33～58% weight starch, 4～11% weight are stirred evenly and obtain compound;
(3), compound is added matched moulds first pressing in the die cavity, open parting line venting once, first pressing unit pressure 300～450kg/cm
2, temperature is 120～180 ℃;
(4), matched moulds hot-press solidifying moulding once more, unit pressure is 300～450kg/cm
2, temperature is 120～180 ℃, 25～80 seconds set times of heat-insulation pressure keeping;
(5), the demoulding and carry out aftertreatment and promptly get goods.
7, a kind of method for preparing disposable product according to the Wholly-degradable material of claim 4 of utilizing is characterized in that comprising the following steps:
(1), Vegetrable fibre material is crushed to 100～200 orders;
(2), earlier with 20～25% weight Vegetrable fibre materials and 2～3% weight water mixings, again with 45～55% weight amino film plastics, 18～22% weight starch and 4～6% weight in matter lime carbonate mix to stir evenly and obtain compound;
(3), compound is added matched moulds first pressing in the die cavity, open parting line venting once, first pressing unit pressure 300～450kg/cm
2, temperature is 120～180 ℃;
(4), matched moulds hot-press solidifying moulding once more, unit pressure is 300～450kg/cm
2, temperature is 120～180 ℃, 25～80 seconds set times of heat-insulation pressure keeping;
(5), the demoulding and carry out aftertreatment and promptly get goods.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011136782A CN1151206C (en) | 2001-06-06 | 2001-06-06 | All degraded material and method for making disposable products by utilizing said material |
| PCT/CN2002/000388 WO2003002638A1 (en) | 2001-06-06 | 2002-06-04 | A kind of biodegradable composite material as well as the process for making disposal products using the said material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011136782A CN1151206C (en) | 2001-06-06 | 2001-06-06 | All degraded material and method for making disposable products by utilizing said material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1371944A CN1371944A (en) | 2002-10-02 |
| CN1151206C true CN1151206C (en) | 2004-05-26 |
Family
ID=4660388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011136782A Expired - Fee Related CN1151206C (en) | 2001-06-06 | 2001-06-06 | All degraded material and method for making disposable products by utilizing said material |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1151206C (en) |
| WO (1) | WO2003002638A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101449910B (en) * | 2007-12-08 | 2010-11-24 | 侯玉栋 | Plant straw degradable disposable sanitary chopsticks and production method thereof |
| CN101230201B (en) * | 2008-01-14 | 2010-10-06 | 罗家宏 | Biodegradable plant fibre material and production technique thereof |
| CN102019637A (en) * | 2010-10-21 | 2011-04-20 | 张娅儿 | Method for manufacturing integrated circuit tray with degraded plant fibers |
| CN102504559B (en) * | 2011-11-04 | 2013-09-11 | 山东省塑料研究开发中心 | Method for processing full-degradable and recyclable plastic by using natural straw |
| CN105949802A (en) * | 2016-03-18 | 2016-09-21 | 武志学 | Biodegradable plant fiber material and processing technology thereof |
| CN108004843A (en) * | 2017-11-03 | 2018-05-08 | 苏州梅香雅筑工艺品有限公司 | A kind of false proof covering of the fan |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995015894A2 (en) * | 1993-12-06 | 1995-06-15 | Franz Haas Waffelmaschinen Industriegesellschaft Mbh | Process for producing a decomposable thin-walled molded article based on starch |
| CN1230385A (en) * | 1998-03-31 | 1999-10-06 | 盛丽君 | Degradable tableware and utensils and their production |
| CN1081157C (en) * | 1999-06-08 | 2002-03-20 | 李运吉 | Disposable chopsticks and food containers made of plant fibres and its manufacture method |
| CN1342728A (en) * | 2000-09-12 | 2002-04-03 | 薛叶安 | Formula and process for preparing degradable disposable chopsticks from plant fibres |
-
2001
- 2001-06-06 CN CNB011136782A patent/CN1151206C/en not_active Expired - Fee Related
-
2002
- 2002-06-04 WO PCT/CN2002/000388 patent/WO2003002638A1/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003002638A1 (en) | 2003-01-09 |
| CN1371944A (en) | 2002-10-02 |
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