CN115117399A - Gas humidifying device for fuel cell test - Google Patents
Gas humidifying device for fuel cell test Download PDFInfo
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04492—Humidity; Ambient humidity; Water content
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- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
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Abstract
Description
技术领域technical field
本发明涉及燃料电池技术领域,尤其涉及一种用于燃料电池测试的气体加湿装置。The present invention relates to the technical field of fuel cells, in particular to a gas humidification device used for fuel cell testing.
背景技术Background technique
燃料电池是一种电化学发电装置,不受卡诺循环限制,能量转化效率高,无污染,无噪音,成为新一代理想的能源利用方式。随着燃料电池技术的日渐成熟,其商业化应用有着广阔的发展前景。Fuel cell is an electrochemical power generation device, which is not limited by the Carnot cycle, has high energy conversion efficiency, no pollution and no noise, and has become an ideal energy utilization method for a new generation. With the maturity of fuel cell technology, its commercial application has broad prospects for development.
现有技术一般通过燃料电池测试设备来对燃料电池进行结构与材料的优化与验证,具体地,为电堆提供燃料气、空气和冷却水的供应,实施电堆运行参数包括气体流量、温度、湿度、压力等的控制,对电堆的实时运行状态进行进行监测,并完成数据记录。In the prior art, fuel cell testing equipment is generally used to optimize and verify the structure and material of the fuel cell. Specifically, the supply of fuel gas, air and cooling water is provided for the stack. The operating parameters of the stack include gas flow, temperature, Control of humidity, pressure, etc., monitor the real-time operating status of the stack, and complete data recording.
目前,燃料电池测试设备中一般通过气体加湿罐对气体进行加湿,湿度控制则通过气体加湿罐内的水温控制来实现。但耗费时间过长,导致气体湿度无法根据电堆运行需求做出迅速响应。部分测试设备采用干湿气混合来实现气体的快速加湿,但需要增加一路较精确的流量控制(流量计)以保证干气的气量,增加了设备成本,并且,需要较长的管路来保证干湿气的充分混合。管路过长会影响气体的进堆温度和湿度,且流量计的流量控制范围会限制快速加湿的适用区间。At present, the gas humidification tank is generally used to humidify the gas in the fuel cell test equipment, and the humidity control is realized through the water temperature control in the gas humidification tank. However, it takes too long to make the gas humidity unable to respond quickly according to the operation requirements of the stack. Some test equipment uses dry and wet gas mixing to achieve rapid gas humidification, but a more accurate flow control (flow meter) needs to be added to ensure the dry gas volume, which increases the equipment cost, and requires a long pipeline to ensure A good mix of dry and wet air. Excessive length of the pipeline will affect the temperature and humidity of the gas entering the stack, and the flow control range of the flowmeter will limit the applicable range of rapid humidification.
发明内容SUMMARY OF THE INVENTION
鉴于上述的分析,本发明实施例旨在提供一种用于燃料电池测试的气体加湿装置,用以解决现有技术难以根据电堆运行需求迅速调整气体湿度且适用区间有限的问题。In view of the above analysis, the embodiments of the present invention aim to provide a gas humidification device for fuel cell testing, so as to solve the problem that it is difficult to quickly adjust the gas humidity according to the operation requirements of the stack and the applicable range is limited in the prior art.
一方面,本发明实施例提供了一种用于燃料电池测试的气体加湿装置,包括气体加湿罐、装有恒温热水的第一罐体、装有恒温凉水的第二罐体、第一水泵、第二水泵和控制器;其中,On the one hand, an embodiment of the present invention provides a gas humidification device for fuel cell testing, including a gas humidification tank, a first tank with constant temperature hot water, a second tank with constant temperature cold water, and a first water pump , a second water pump and a controller; wherein,
气体加湿罐内设有用于对罐内液体精确调温的加热器、降温板,其入水口一经第一水泵接第一罐体的出水口,构成粗调升温支路,其入水口二经第二水泵接第二罐体的出水口,构成粗调降温支路;The gas humidification tank is provided with a heater and a cooling plate for precise temperature adjustment of the liquid in the tank. The water inlet of the gas humidification tank is connected to the water outlet of the first tank body through the first water pump to form a rough adjustment and heating branch. The second water pump is connected to the water outlet of the second tank to form a coarse adjustment and cooling branch;
控制器,用于启动后确定目标湿度对应的露点温度;以及,获取当前时刻气体加湿罐内实际水温,根据该实际水温与露点温度的比较结果启动粗调升温支路或粗调降温支路对气体加湿罐内注水;以及,注水结束后,启动气体加湿罐内加热器或降温板进一步精调水温,使得气体加湿罐内实际水温达到所述露点温度后,再向气体加湿罐内通气。The controller is used to determine the dew point temperature corresponding to the target humidity after startup; and, obtain the actual water temperature in the gas humidification tank at the current moment, and start the coarse adjustment heating branch or the coarse adjustment cooling branch according to the comparison result of the actual water temperature and the dew point temperature. Water is injected into the gas humidification tank; and, after the water injection is completed, the heater or cooling plate in the gas humidification tank is started to further finely adjust the water temperature, so that the actual water temperature in the gas humidification tank reaches the dew point temperature, and then the gas humidification tank is ventilated.
上述技术方案的有益效果如下:提出一种新的露点温度快速调节的气体加湿装置,增加了两个罐体,通过冷水、热水混合方式的注入,实现水温的快速初调,进而实现湿度的快速调节。再利用气体加湿罐本身的温度控制功能,进行注水后误差的精调节,粗调+精调方案的实施保证温度控制的精度。该装置适用于所有工况点,任意电流密度、任意温度下均可实现气体湿度的快速调节,相比于增加一路较精确的流量控制方案的成本明显较低,且适用范围更广。并且,对气体加湿罐的气体管路无改动,保证在快速加湿模式下和非快速加湿模式下测试的一致性。The beneficial effects of the above technical solutions are as follows: a new gas humidification device with rapid dew point temperature adjustment is proposed, and two tanks are added. Quick adjustment. Then use the temperature control function of the gas humidification tank itself to perform fine adjustment of the error after water injection, and the implementation of the coarse adjustment + fine adjustment scheme ensures the accuracy of temperature control. The device is suitable for all operating points, and can achieve rapid adjustment of gas humidity at any current density and temperature. Compared with adding a more accurate flow control scheme, the cost is significantly lower, and the scope of application is wider. Moreover, there is no change to the gas pipeline of the gas humidification tank, which ensures the consistency of the test in the fast humidification mode and the non-rapid humidification mode.
基于上述装置的进一步改进,该气体加湿装置还包括第一电磁阀、第二电磁阀;其中,Based on a further improvement of the above device, the gas humidification device further includes a first solenoid valve and a second solenoid valve; wherein,
所述第一电磁阀设于气体加湿罐、第一水泵之间的连接管路上,其控制端与控制器的输出端连接;The first solenoid valve is arranged on the connecting pipeline between the gas humidification tank and the first water pump, and its control end is connected with the output end of the controller;
所述第二电磁阀设于气体加湿罐、第二水泵之间的连接管路上,其控制端也与控制器的输出端连接。The second solenoid valve is arranged on the connecting pipeline between the gas humidification tank and the second water pump, and its control end is also connected to the output end of the controller.
进一步,该气体加湿装置还包括电控三通阀;其中,Further, the gas humidification device also includes an electronically controlled three-way valve; wherein,
所述电控三通阀的输入端与气体加湿罐的排水口连接,输出端一与第一罐体的入水口连接,输出端二与第二罐体的入水口连接,控制端与控制器的输出端连接。The input end of the electric control three-way valve is connected with the water outlet of the gas humidification tank, the output end one is connected with the water inlet of the first tank body, the output end two is connected with the water inlet of the second tank body, and the control end is connected with the controller output connection.
进一步,所述控制器,还用于在注水过程中,实时监测气体加湿罐内液位高度是否超过限制,如果否,继续监测,如果是,驱动气体加湿罐排水,并识别气体加湿罐的排水温度接近第一罐体内水温T A还是第二罐体内水温T B,进而调整电控三通阀的开度将气体加湿罐排水回收至匹配的第一罐体或第二罐体;以及,启动第一罐体、第二罐体的调温设备,使得第一罐体、第二罐体内水温保持恒温。Further, the controller is also used to monitor in real time whether the liquid level in the gas humidification tank exceeds the limit during the water injection process, if not, continue monitoring, and if so, drive the gas humidification tank to drain water, and identify the drainage of the gas humidification tank Whether the temperature is close to the water temperature T A in the first tank or the water temperature T B in the second tank, and then adjust the opening of the electronically controlled three-way valve to recover the water from the gas humidification tank to the matching first tank or second tank; and, start The temperature adjustment equipment of the first tank body and the second tank body keeps the water temperature in the first tank body and the second tank body at a constant temperature.
进一步,该气体加湿装置还包括第一换热器、第一电加热器,作为第一罐体的调温设备;其中,Further, the gas humidification device further includes a first heat exchanger and a first electric heater as temperature adjustment equipment for the first tank; wherein,
所述第一换热器与第一罐体内液体、燃料电池电堆的阴极尾排气体分别连通,其控制端与控制器的输出端连接,用于启动后对第一罐体内液体与阴极尾排气体进行热交换;The first heat exchanger is in communication with the liquid in the first tank and the cathode tail gas of the fuel cell stack, respectively, and its control end is connected with the output end of the controller, and is used for the liquid in the first tank and the cathode after startup. Exhaust gas for heat exchange;
所述第一罐体内还设有可对罐内液体进行加热的第一电加热器,其控制端与控制器的输出端连接。The first tank body is also provided with a first electric heater capable of heating the liquid in the tank, the control end of which is connected to the output end of the controller.
进一步,该气体加湿装置还包括第二换热器,作为第二罐体的调温设备;其中,Further, the gas humidification device also includes a second heat exchanger, which is used as a temperature adjustment device for the second tank; wherein,
所述第二换热器与第二罐体内液体、设备冷却水分别连通,其控制端与控制器的输出端连接,用于启动后对第二罐体内液体与设备冷却水进行热交换。The second heat exchanger is respectively connected with the liquid in the second tank and the cooling water of the equipment, and its control end is connected with the output end of the controller, and is used for heat exchange between the liquid in the second tank and the cooling water of the equipment after startup.
进一步,该气体加湿装置还包括第三换热器;所述第三换热器与气体加湿罐内的加热器、降温板一起作为气体加湿罐的调温设备;其中,Further, the gas humidification device also includes a third heat exchanger; the third heat exchanger, together with the heater and the cooling plate in the gas humidification tank, serve as the temperature adjustment equipment of the gas humidification tank; wherein,
所述第三换热器与气体加湿罐内液体、设备冷却水分别连通,其控制端与控制器的输出端连接,用于启动后对气体加湿罐内液体与设备冷却水进行热交换。The third heat exchanger is respectively connected with the liquid in the gas humidification tank and the equipment cooling water, and its control end is connected with the output end of the controller for heat exchange between the liquid in the gas humidification tank and the equipment cooling water after startup.
进一步,所述第一罐体、第二罐体、气体加湿罐的壳体均设有隔热层,并具有保温结构。Further, the shells of the first tank body, the second tank body and the gas humidification tank are all provided with a heat insulating layer and have a heat insulating structure.
进一步,所述控制器进一步包括依次连接的数据采集单元、数据处理与控制单元;其中,Further, the controller further includes a data acquisition unit, a data processing and a control unit connected in sequence; wherein,
所述数据采集单元进一步包括:The data collection unit further includes:
目标湿度获取子单元,用于接收测试气体的目标湿度;The target humidity acquisition subunit is used to receive the target humidity of the test gas;
液位高度传感器,设于气体加湿罐内壁上,用于获取气体加湿罐内液位高度;The liquid level height sensor is installed on the inner wall of the gas humidification tank to obtain the liquid level height in the gas humidification tank;
液体温度传感器,分别设于气体加湿罐、第一罐体、第二罐体内壁上,用于获取气体加湿罐内实际水温、第一罐体内水温、第二罐体内水温;The liquid temperature sensor is respectively arranged on the inner wall of the gas humidification tank, the first tank body and the second tank, and is used to obtain the actual water temperature in the gas humidification tank, the water temperature in the first tank and the water temperature in the second tank;
流量传感器,设于水泵的输出端管道内壁上,用于获取水泵当前转速对应的入水流量。The flow sensor is arranged on the inner wall of the output pipe of the water pump, and is used to obtain the water inlet flow corresponding to the current speed of the water pump.
进一步,所述数据处理与控制单元执行如下程序:Further, the data processing and control unit executes the following procedures:
S1.确定目标湿度对应的露点温度T 1;S1. Determine the dew point temperature T 1 corresponding to the target humidity;
S2.通过气体加湿罐内的液体温度传感器,获取当前时刻气体加湿罐内实际水温T 0;S2. Obtain the actual water temperature T 0 in the gas humidification tank at the current moment through the liquid temperature sensor in the gas humidification tank;
S3.将上述实际水温T 0与露点温度T 1比较,若实际温度T 0低于露点温度T 1,执行步骤S4,若实际温度T 0高于露点温度T 1,执行步骤S5;S3. Compare the above-mentioned actual water temperature T 0 with the dew point temperature T 1 , if the actual temperature T 0 is lower than the dew point temperature T 1 , execute step S4 , and if the actual temperature T 0 is higher than the dew point temperature T 1 , execute step S5 ;
S4.启动第一水泵并开启第一电磁阀,以启动粗调升温支路对气体加湿罐内注水,直到粗调完成,关闭第一水泵、第一电磁阀,并执行步骤S6;其中,粗调过程中第一电磁阀的开启时间t 1满足S4. Start the first water pump and turn on the first solenoid valve to start the coarse adjustment and temperature rise branch to inject water into the gas humidification tank, until the coarse adjustment is completed, close the first water pump and the first solenoid valve, and perform step S6; During the adjustment process, the opening time t1 of the first solenoid valve satisfies
t 1=[(T 1-T 0)L 2/(T A-T 0)]/L 0 t 1 =[( T 1 - T 0 ) L 2 /( T A - T 0 )]/ L 0
式中,L 2为根据液位高度传感器采集数据得出的气体加湿罐内水量,单位为L;L 0为流量传感器采集的水泵转速对应的入水流量,单位为L·s-1;T A为第一罐体内水温,单位为℃;In the formula, L 2 is the water volume in the gas humidification tank obtained according to the data collected by the liquid level sensor, and the unit is L; L 0 is the water inlet flow corresponding to the rotation speed of the pump collected by the flow sensor, and the unit is L s -1 ; T A is the water temperature in the first tank, in °C;
S5.启动第二水泵并开启第二电磁阀,以启动粗调降温支路对气体加湿罐内注水,直到粗调完成,关闭第二水泵、第二电磁阀,并执行步骤S6;其中,第二电磁阀的开启时间t 2满足S5. Start the second water pump and turn on the second solenoid valve to start the coarse adjustment and cooling branch to inject water into the gas humidification tank, until the coarse adjustment is completed, close the second water pump and the second solenoid valve, and perform step S6; The opening time t2 of the second solenoid valve satisfies
t 2=[(T 0-T 1)L 2/(T 0-T B)]/L 0 t 2 =[( T 0 - T 1 ) L 2 /( T 0 - T B )]/ L 0
式中,T B为第一罐体内水温,单位为℃;In the formula, T B is the water temperature in the first tank, the unit is °C;
S6.再次获取气体加湿罐内实际水温,将该实际水温与露点温度再次比较,如果实际水温仍低于露点温度,启动气体加湿罐内加热器进一步精调水温,如果实际水温高于露点温度,启动气体加湿罐内降温板进一步精调水温,使得气体加湿罐内实际水温达到目标湿度对应的露点温度;S6. Obtain the actual water temperature in the gas humidification tank again, and compare the actual water temperature with the dew point temperature again. If the actual water temperature is still lower than the dew point temperature, start the heater in the gas humidification tank to further fine-tune the water temperature. If the actual water temperature is higher than the dew point temperature, Start the cooling plate in the gas humidification tank to further fine-tune the water temperature, so that the actual water temperature in the gas humidification tank reaches the dew point temperature corresponding to the target humidity;
S7.向气体加湿罐内通入待测气体。S7. Pass the gas to be measured into the gas humidification tank.
与现有技术相比,本发明至少可实现如下有益效果之一:Compared with the prior art, the present invention can achieve at least one of the following beneficial effects:
1、通过回收尾排的废热,维持第一罐体的温度,降低了对水加热的能耗。1. By recovering the waste heat of the tail exhaust, the temperature of the first tank is maintained, and the energy consumption for heating water is reduced.
2、在气体加湿罐底部的排水口增加一个温度传感器,排水管路增加一个三通阀,分别与第一罐体和第二罐体相连接,对气体加湿罐的用水进行回收,节约了试验成本。2. A temperature sensor is added to the drainage port at the bottom of the gas humidification tank, and a three-way valve is added to the drainage pipeline, which is connected to the first tank body and the second tank body respectively, and the water used in the gas humidification tank is recovered, saving the test. cost.
3、无流量范围限制,可实现燃料电池电堆全功率段参数下的快速加湿。3. There is no flow range limitation, which can realize rapid humidification under the parameters of the full power section of the fuel cell stack.
提供发明内容部分是为了以简化的形式来介绍对概念的选择,它们在下文的具体实施方式中将被进一步描述。发明内容部分无意标识本公开的重要特征或必要特征,也无意限制本公开的范围。This Summary is provided to introduce a selection of concepts in a simplified form that are further described below in the Detailed Description. This Summary is not intended to identify key features or essential features of the disclosure, nor is it intended to limit the scope of the disclosure.
附图说明Description of drawings
通过结合附图对本公开示例性实施例进行更详细的描述,本公开的上述以及其它目的、特征和优势将变得更加明显,其中,在本公开示例性实施例中,相同的参考标号通常代表相同部件。The above and other objects, features and advantages of the present disclosure will become more apparent from the more detailed description of the exemplary embodiments of the present disclosure, taken in conjunction with the accompanying drawings, wherein the same reference numerals generally refer to the exemplary embodiments of the present disclosure. same parts.
图1示出了实施例1气体加湿装置组成示意图;Figure 1 shows a schematic diagram of the composition of the gas humidification device in Example 1;
图2示出了实施例2气体加湿装置的一种连接示意图。FIG. 2 shows a schematic diagram of a connection of the gas humidifying device in Example 2. FIG.
附图标记:Reference number:
1- 气体加湿罐;2- 第一罐体;3- 第二罐体;4- 第一水泵;5- 第一电池阀;6- 第二水泵;7- 第二电磁阀;8-电控三通阀;9- 燃料电池电堆。1- Gas humidification tank; 2- The first tank; 3- The second tank; 4- The first water pump; 5- The first battery valve; 6- The second water pump; 7- The second solenoid valve; 8- Electric control Three-way valve; 9- fuel cell stack.
具体实施方式Detailed ways
下面将参照附图更详细地描述本公开的实施例。虽然附图中显示了本公开的实施例,然而应该理解,可以以各种形式实现本公开而不应被这里阐述的实施例所限制。相反,提供这些实施例是为了使本公开更加透彻和完整,并且能够将本公开的范围完整地传达给本领域的技术人员。Embodiments of the present disclosure will be described in more detail below with reference to the accompanying drawings. Although embodiments of the present disclosure are shown in the drawings, it should be understood that the present disclosure may be embodied in various forms and should not be limited by the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art.
在本文中使用的术语“包括”及其变形表示开放性包括,即“包括但不限于”。除非特别申明,术语“或”表示“和/或”。术语“基于”表示“至少部分地基于”。术语“一个示例实施例”和“一个实施例”表示“至少一个示例实施例”。术语“另一实施例”表示“至少一个另外的实施例”。术语“第一”、“第二”等等可以指代不同的或相同的对象。下文还可能包括其他明确的和隐含的定义。As used herein, the term "including" and variations thereof mean open-ended inclusion, ie, "including but not limited to". The term "or" means "and/or" unless specifically stated otherwise. The term "based on" means "based at least in part on". The terms "one example embodiment" and "one embodiment" mean "at least one example embodiment." The term "another embodiment" means "at least one additional embodiment." The terms "first", "second", etc. may refer to different or the same objects. Other explicit and implicit definitions may also be included below.
实施例1Example 1
本发明的一个实施例,公开了一种用于燃料电池测试的气体加湿装置,如图1所示,包括气体加湿罐、装有恒温热水(具体温度可根据测试需求设置,一般为0~30℃)的第一罐体、装有恒温凉水(具体温度可根据测试需求设置,一般为50~90℃)的第二罐体、第一水泵、第二水泵和控制器。An embodiment of the present invention discloses a gas humidification device for fuel cell testing. As shown in Figure 1, it includes a gas humidification tank and is equipped with constant temperature hot water (the specific temperature can be set according to the test requirements, generally 0~ 30°C), the second tank with constant temperature cold water (the specific temperature can be set according to the test requirements, generally 50~90°C), the first water pump, the second water pump and the controller.
其中,气体加湿罐内设有用于对罐内液体精确调温的加热器、降温板,其入水口一经第一水泵接第一罐体的出水口,构成粗调升温支路,其入水口二经第二水泵接第二罐体的出水口,构成粗调降温支路。气体加湿罐的气体入口用于通入待测气体,例如空气或氢气。Among them, the gas humidification tank is provided with a heater and a cooling plate for precise temperature adjustment of the liquid in the tank. Once the water inlet is connected to the water outlet of the first tank through the first water pump, a coarse adjustment and heating branch is formed, and its water inlet two The second water pump is connected to the water outlet of the second tank to form a coarse adjustment and cooling branch. The gas inlet of the gas humidification tank is used to introduce the gas to be measured, such as air or hydrogen.
控制器,用于启动后确定目标湿度对应的露点温度;以及,获取当前时刻气体加湿罐内实际水温,根据该实际水温与露点温度的比较结果启动粗调升温支路或粗调降温支路对气体加湿罐内注水;以及,注水结束后,启动气体加湿罐内加热器或降温板进一步精调水温,使得气体加湿罐内实际水温达到所述露点温度后,再向气体加湿罐内通气。The controller is used to determine the dew point temperature corresponding to the target humidity after startup; and, obtain the actual water temperature in the gas humidification tank at the current moment, and start the coarse adjustment heating branch or the coarse adjustment cooling branch according to the comparison result of the actual water temperature and the dew point temperature. Water is injected into the gas humidification tank; and, after the water injection is completed, the heater or cooling plate in the gas humidification tank is started to further finely adjust the water temperature, so that the actual water temperature in the gas humidification tank reaches the dew point temperature, and then the gas humidification tank is ventilated.
根据目标湿度确定露点温度的方法为现有技术,例如参见专利CN202010632207.6、CN202111321746.9等。本领域技术人员能够理解。The method of determining the dew point temperature according to the target humidity is the prior art, for example, see patents CN202010632207.6, CN202111321746.9 and the like. Those skilled in the art can understand.
实施时,当实际水温低于露点温度,则需要对水温加热,启动粗调升温支路对气体加湿罐内注热水进行水温的粗调后,再启动气体加湿罐内加热器或降温板进一步精调水温。当实际水温高于露点温度,则需要对水温降热,启动粗调降温支路对气体加湿罐内注凉水进行水温的粗调后,再启动气体加湿罐内加热器或降温板进一步精调水温。During implementation, when the actual water temperature is lower than the dew point temperature, it is necessary to heat the water temperature, start the coarse adjustment heating branch to inject hot water into the gas humidification tank to perform a rough adjustment of the water temperature, and then start the heater in the gas humidification tank or the cooling plate to further. Fine-tune the water temperature. When the actual water temperature is higher than the dew point temperature, it is necessary to cool down the water temperature, start the coarse adjustment and cooling branch to inject cold water into the gas humidification tank to make a rough adjustment of the water temperature, and then start the heater or cooling plate in the gas humidification tank to further adjust the water temperature. .
与现有技术相比,本实施例提出一种新的露点温度快速调节的气体加湿装置,增加了两个罐体,通过冷水、热水混合方式的注入,实现水温的快速初调,进而实现湿度的快速调节。再利用气体加湿罐本身的温度控制功能,进行注水后误差的精调节,粗调+精调方案的实施保证温度控制的精度。该装置适用于所有工况点,任意电流密度、任意温度下均可实现气体湿度的快速调节,相比于增加一路较精确的流量控制方案的成本明显较低,且适用范围更广。并且,对气体加湿罐的气体管路无改动,保证在快速加湿模式下和非快速加湿模式下测试的一致性。Compared with the prior art, the present embodiment proposes a new gas humidification device with rapid dew point temperature adjustment, adding two tanks, and through the injection of cold water and hot water, the rapid initial adjustment of the water temperature is realized, and then the Quick regulation of humidity. Then use the temperature control function of the gas humidification tank itself to perform fine adjustment of the error after water injection, and the implementation of the coarse adjustment + fine adjustment scheme ensures the accuracy of temperature control. The device is suitable for all operating points, and can achieve rapid adjustment of gas humidity at any current density and temperature. Compared with adding a more accurate flow control scheme, the cost is significantly lower, and the scope of application is wider. Moreover, there is no change to the gas pipeline of the gas humidification tank, which ensures the consistency of the test in the fast humidification mode and the non-rapid humidification mode.
实施例2Example 2
在实施例1的基础上进行改进,所有管道接口处均设有密封件,防止气体液体的泄露。Improvements are made on the basis of Example 1, and all pipe joints are provided with seals to prevent leakage of gas and liquid.
优选地,所述第二换热器采用板式换热器。该换热器具有换热效率高、热损失小、结构紧凑轻巧、占地面积小、安装清洗方便、应用广泛、使用寿命长等特点。在相同压力损失情况下,其传热系数比列管式换热器高3~5倍,占地面积为管式换热器的三分之一,热回收率可高达90%以上。Preferably, the second heat exchanger is a plate heat exchanger. The heat exchanger has the characteristics of high heat exchange efficiency, small heat loss, compact and lightweight structure, small footprint, convenient installation and cleaning, wide application and long service life. Under the same pressure loss, the heat transfer coefficient is 3-5 times higher than that of the tubular heat exchanger, the floor area is one third of that of the tubular heat exchanger, and the heat recovery rate can be as high as 90% or more.
优选地,该气体加湿装置还包括第一电磁阀、第二电磁阀。其中,所述第一电磁阀设于气体加湿罐、第一水泵之间的连接管路上,其控制端与控制器的输出端连接;所述第二电磁阀设于气体加湿罐、第二水泵之间的连接管路上,其控制端也与控制器的输出端连接。Preferably, the gas humidification device further includes a first solenoid valve and a second solenoid valve. Wherein, the first solenoid valve is arranged on the connecting pipeline between the gas humidification tank and the first water pump, and its control end is connected with the output end of the controller; the second solenoid valve is arranged on the gas humidification tank and the second water pump The control end is also connected to the output end of the controller on the connecting pipeline between them.
优选地,该气体加湿装置还包括电控三通阀。其中,所述电控三通阀的输入端与气体加湿罐的排水口连接,输出端一与第一罐体的入水口连接,输出端二与第二罐体的入水口连接,控制端与控制器的输出端连接。Preferably, the gas humidification device further includes an electronically controlled three-way valve. Wherein, the input end of the electronically controlled three-way valve is connected with the water outlet of the gas humidification tank, the output end 1 is connected with the water inlet of the first tank body, the
优选地,控制器还用于在注水过程中,实时监测气体加湿罐内液位高度是否超过限制,如果否,继续监测,如果是,驱动气体加湿罐排水,并识别气体加湿罐的排水温度接近第一罐体内水温T A还是第二罐体内水温T B,进而调整电控三通阀的开度将气体加湿罐排水回收至匹配的第一罐体或第二罐体;以及,启动第一罐体、第二罐体的调温设备,使得第一罐体、第二罐体内水温保持恒温。Preferably, the controller is also used to monitor in real time whether the liquid level in the gas humidification tank exceeds the limit during the water injection process, if not, continue to monitor, if so, drive the gas humidification tank to drain, and identify that the temperature of the gas humidification tank is close to The water temperature T A in the first tank is still the water temperature T B in the second tank, and then the opening of the electronically controlled three-way valve is adjusted to recover the water from the gas humidification tank to the matching first tank or second tank; and, start the first tank The temperature adjustment equipment of the tank body and the second tank body keeps the water temperature in the first tank body and the second tank body at a constant temperature.
优选地,该气体加湿装置还包括第一换热器、第一电加热器,作为第一罐体的调温设备。Preferably, the gas humidification device further includes a first heat exchanger and a first electric heater as temperature adjustment equipment for the first tank.
其中,第一换热器与第一罐体内液体、燃料电池电堆的阴极尾排气体分别连通,其控制端与控制器的输出端连接,用于启动后对第一罐体内液体与阴极尾排气体进行热交换。Wherein, the first heat exchanger is connected with the liquid in the first tank and the cathode tail gas of the fuel cell stack, respectively, and its control end is connected with the output end of the controller, which is used for the liquid in the first tank and the cathode after startup. The exhaust gas exchanges heat.
第一罐体内还设有可对罐内液体进行加热的第一电加热器,该加热器的控制端与控制器的输出端连接。The first tank body is also provided with a first electric heater capable of heating the liquid in the tank, and the control end of the heater is connected with the output end of the controller.
优选地,该气体加湿装置还包括第二换热器,作为第二罐体的调温设备。Preferably, the gas humidification device further includes a second heat exchanger, which is used as a temperature adjustment device for the second tank.
其中,第二换热器与第二罐体内液体、设备冷却水分别连通,其控制端与控制器的输出端连接,用于启动后对第二罐体内液体与设备冷却水进行热交换。Wherein, the second heat exchanger is respectively connected with the liquid in the second tank and the cooling water of the equipment, and its control end is connected with the output end of the controller for heat exchange between the liquid in the second tank and the cooling water of the equipment after startup.
优选地,该气体加湿装置还包括第三换热器。第三换热器与气体加湿罐内的加热器、降温板一起作为气体加湿罐的调温设备。Preferably, the gas humidification device further includes a third heat exchanger. The third heat exchanger, together with the heater and the cooling plate in the gas humidification tank, serves as a temperature adjustment device for the gas humidification tank.
其中,第三换热器与气体加湿罐内液体、设备冷却水分别连通,其控制端与控制器的输出端连接,用于启动后对气体加湿罐内液体与设备冷却水进行热交换。Wherein, the third heat exchanger is connected with the liquid in the gas humidification tank and the equipment cooling water respectively, and its control end is connected with the output end of the controller for heat exchange between the liquid in the gas humidification tank and the equipment cooling water after startup.
优选地,所述第一罐体、第二罐体、气体加湿罐的壳体均设有隔热层,并具有保温结构。Preferably, the shells of the first tank body, the second tank body, and the gas humidification tank are all provided with a thermal insulation layer and have a thermal insulation structure.
优选地,所述控制器进一步包括依次连接的数据采集单元、数据处理与控制单元。Preferably, the controller further comprises a data acquisition unit, a data processing and control unit connected in sequence.
其中,所述数据采集单元进一步包括目标湿度获取子单元、液位高度传感器、液体温度传感器、流量传感器。Wherein, the data acquisition unit further includes a target humidity acquisition sub-unit, a liquid level sensor, a liquid temperature sensor, and a flow sensor.
目标湿度获取子单元,用于接收测试气体的目标湿度。The target humidity acquisition subunit is used to receive the target humidity of the test gas.
液位高度传感器,设于气体加湿罐内壁上,用于获取气体加湿罐内液位高度。The liquid level height sensor is arranged on the inner wall of the gas humidification tank and is used to obtain the liquid level height in the gas humidification tank.
液体温度传感器,分别设于气体加湿罐、第一罐体、第二罐体内壁上,用于获取气体加湿罐内实际水温、第一罐体内水温、第二罐体内水温。The liquid temperature sensors are respectively arranged on the inner wall of the gas humidification tank, the first tank body and the second tank, and are used to obtain the actual water temperature in the gas humidification tank, the water temperature in the first tank and the water temperature in the second tank.
流量传感器,设于水泵的输出端管道内壁上,用于获取水泵当前转速对应的入水流量。The flow sensor is arranged on the inner wall of the output pipe of the water pump, and is used to obtain the water inlet flow corresponding to the current speed of the water pump.
优选地,数据处理与控制单元执行如下程序:Preferably, the data processing and control unit executes the following procedures:
S1.确定目标湿度对应的露点温度T 1;S1. Determine the dew point temperature T 1 corresponding to the target humidity;
S2.通过气体加湿罐内的液体温度传感器,获取当前时刻气体加湿罐内实际水温T 0;S2. Obtain the actual water temperature T 0 in the gas humidification tank at the current moment through the liquid temperature sensor in the gas humidification tank;
S3.将上述实际水温T 0与露点温度T 1比较,若实际温度T 0低于露点温度T 1,执行步骤S4,若实际温度T 0高于露点温度T 1,执行步骤S5;S3. Compare the above-mentioned actual water temperature T 0 with the dew point temperature T 1 , if the actual temperature T 0 is lower than the dew point temperature T 1 , execute step S4 , and if the actual temperature T 0 is higher than the dew point temperature T 1 , execute step S5 ;
S4.启动第一水泵并开启第一电磁阀,以启动粗调升温支路对气体加湿罐内注水,直到粗调完成,关闭第一水泵、第一电磁阀,并执行步骤S6;其中,粗调过程中第一电磁阀的开启时间t 1满足S4. Start the first water pump and turn on the first solenoid valve to start the coarse adjustment and temperature rise branch to inject water into the gas humidification tank, until the coarse adjustment is completed, close the first water pump and the first solenoid valve, and perform step S6; During the adjustment process, the opening time t1 of the first solenoid valve satisfies
t 1=[(T 1-T 0)L 2/(T A-T 0)]/L 0 t 1 =[( T 1 - T 0 ) L 2 /( T A - T 0 )]/ L 0
式中,L 2为根据液位高度传感器采集数据得出的气体加湿罐内水量,单位为L;L 0为流量传感器采集的水泵转速对应的入水流量,单位为L·s-1;T A为第一罐体内水温,单位为℃;In the formula, L 2 is the water volume in the gas humidification tank obtained according to the data collected by the liquid level sensor, and the unit is L; L 0 is the water inlet flow corresponding to the rotation speed of the pump collected by the flow sensor, and the unit is L s -1 ; T A is the water temperature in the first tank, in °C;
S5.启动第二水泵并开启第二电磁阀,以启动粗调降温支路对气体加湿罐内注水,直到粗调完成,关闭第二水泵、第二电磁阀,并执行步骤S6;其中,第二电磁阀的开启时间t 2满足S5. Start the second water pump and turn on the second solenoid valve to start the coarse adjustment and cooling branch to inject water into the gas humidification tank, until the coarse adjustment is completed, close the second water pump and the second solenoid valve, and perform step S6; The opening time t2 of the second solenoid valve satisfies
t 2=[(T 0-T 1)L 2/(T 0-T B)]/L 0 t 2 =[( T 0 - T 1 ) L 2 /( T 0 - T B )]/ L 0
式中,T B为第一罐体内水温,单位为℃;In the formula, T B is the water temperature in the first tank, the unit is °C;
S6.再次获取气体加湿罐内实际水温,将该实际水温与露点温度再次比较,如果实际水温仍低于露点温度,启动气体加湿罐内加热器进一步精调水温,如果实际水温高于露点温度,启动气体加湿罐内降温板进一步精调水温,使得气体加湿罐内实际水温达到目标湿度对应的露点温度;S6. Obtain the actual water temperature in the gas humidification tank again, and compare the actual water temperature with the dew point temperature again. If the actual water temperature is still lower than the dew point temperature, start the heater in the gas humidification tank to further fine-tune the water temperature. If the actual water temperature is higher than the dew point temperature, Start the cooling plate in the gas humidification tank to further fine-tune the water temperature, so that the actual water temperature in the gas humidification tank reaches the dew point temperature corresponding to the target humidity;
S7.向气体加湿罐内通入待测气体。S7. Pass the gas to be measured into the gas humidification tank.
实施时,第一罐体内部配有加热器,另通过与阴极尾排进行热交换,维持水温70℃,温度可根据用户需求进行设定、更改,本方案中以70℃为例。第二罐体通过板换与设备冷却水进行热交换,维持水温20℃。During implementation, the first tank is equipped with a heater, and the water temperature is maintained at 70°C through heat exchange with the cathode tail row. The temperature can be set and changed according to user needs. In this scheme, 70°C is taken as an example. The second tank exchanges heat with the cooling water of the equipment through plate exchange, and maintains the water temperature at 20°C.
第一罐体与第二罐体分别与气体加湿罐相连。The first tank body and the second tank body are respectively connected with the gas humidification tank.
气体加湿罐底部的排水口增加一个温度传感器,排水管路增加一个三通阀,分别与第一罐体和第二罐体相连接。A temperature sensor is added to the water outlet at the bottom of the gas humidification tank, and a three-way valve is added to the drain pipeline, which is respectively connected with the first tank body and the second tank body.
控制方法为:启动相应电磁阀以及恒定转速的水泵,对气体加湿罐注水以进行水温的粗调,注水结束后,通过气体加湿罐内的加热器或降温板对气体加湿罐内的水温进行精调,实现水温升高或降低的快速控制。由于注水过程可能会导致气体加湿罐内的液位超限,从而出现气体加湿罐自动排水,造成实际入水量不能将气体加湿罐内的水温调节至目标温度值,所以需要气体加湿罐的调温设备,对注水后的温度进行进一步控制,使得水温可很快达到目标值。气体加湿罐排出的水,根据排水温度,若排水温度更靠近70℃,则通过三通阀控制将排出的水收集至第一罐体,若水温更靠近20℃,则将排出的水收集至第二罐体。收集到排出的水后,第一罐体和第二罐体保持水温,准备进行下一次的温度调节。The control method is as follows: start the corresponding solenoid valve and the water pump with a constant speed, and inject water into the gas humidification tank for rough adjustment of the water temperature. To achieve rapid control of water temperature increase or decrease. Since the water injection process may cause the liquid level in the gas humidification tank to exceed the limit, the gas humidification tank will automatically drain, resulting in the fact that the actual water input cannot adjust the water temperature in the gas humidification tank to the target temperature value, so it is necessary to adjust the temperature of the gas humidification tank. The equipment further controls the temperature after water injection, so that the water temperature can quickly reach the target value. The water discharged from the gas humidification tank, according to the drainage temperature, if the drainage temperature is closer to 70 ℃, the discharged water will be collected to the first tank through the control of the three-way valve; if the water temperature is closer to 20 ℃, the discharged water will be collected to second tank. After collecting the discharged water, the first tank body and the second tank body maintain the water temperature and prepare for the next temperature adjustment.
与实施例1相比,本实施例提供的气体加湿装置具有如下有益效果:Compared with Embodiment 1, the gas humidifying device provided in this embodiment has the following beneficial effects:
1、通过回收尾排的废热,维持第一罐体的温度,降低了对水加热的能耗。1. By recovering the waste heat of the tail exhaust, the temperature of the first tank is maintained, and the energy consumption for heating water is reduced.
2、在气体加湿罐底部的排水口增加一个温度传感器,排水管路增加一个三通阀,分别与第一罐体和第二罐体相连接,对气体加湿罐的用水进行回收,节约了试验成本。2. A temperature sensor is added to the drainage port at the bottom of the gas humidification tank, and a three-way valve is added to the drainage pipeline, which is connected to the first tank body and the second tank body respectively, and the water used in the gas humidification tank is recovered, saving the test. cost.
3、无流量范围限制,可实现燃料电池电堆全功率段参数下的快速加湿。3. There is no flow range limitation, which can realize rapid humidification under the parameters of the full power section of the fuel cell stack.
以上已经描述了本公开的各实施例,上述说明是示例性的,并非穷尽性的,并且也不限于所披露的各实施例。在不偏离所说明的各实施例的范围和精神的情况下,对于本技术领域的普通技术人员来说许多修改和变更都是显而易见的。本文中所用术语的选择,旨在最好地解释各实施例的原理、实际应用或对现有技术的改进,或者使本技术领域的其它普通技术人员能理解本文披露的各实施例。Various embodiments of the present disclosure have been described above, and the foregoing descriptions are exemplary, not exhaustive, and not limiting of the disclosed embodiments. Numerous modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the various embodiments, the practical application or improvement over the prior art, or to enable others of ordinary skill in the art to understand the various embodiments disclosed herein.
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