CN115094653A - Colorful basalt fiber fabric and preparation method thereof - Google Patents
Colorful basalt fiber fabric and preparation method thereof Download PDFInfo
- Publication number
- CN115094653A CN115094653A CN202210707510.7A CN202210707510A CN115094653A CN 115094653 A CN115094653 A CN 115094653A CN 202210707510 A CN202210707510 A CN 202210707510A CN 115094653 A CN115094653 A CN 115094653A
- Authority
- CN
- China
- Prior art keywords
- basalt fiber
- fiber fabric
- dye
- color
- colorful
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/80—Inorganic fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention relates to a colorful basalt fiber fabric and a preparation method thereof, wherein the preparation method comprises the following steps: fully stirring and mixing organic environment-friendly dye, adhesive, hardening agent and the like to obtain colored dye liquor; and (3) immersing the basalt fiber fabric into the color dye solution, carrying out dip-dyeing at 75-80 ℃, taking out the basalt fiber fabric, draining, drying, fixing color by using a color fixing agent, and airing to obtain the color basalt fiber fabric. The method has the advantages of simple and easy operation process, low manufacturing cost and reusable dye solution, and can realize the preparation of the basalt fiber fabrics with various colors, and the prepared colorful basalt fiber fabrics have good color fastness, washing resistance and solarization resistance.
Description
Technical Field
The invention discloses a colorful basalt fiber fabric and a preparation method thereof, belonging to the field of preparation of colorful basalt fibers.
Background
Continuous Basalt Fiber (CBF) is a new type of inorganic fiber, which is made of natural basaltThe rock is formed by drawing through a drawing machine at the high temperature of 1400-1500 ℃. Continuous basalt fibers have excellent properties in many respects: in the aspect of physical performance, the continuous basalt fiber has better high and low temperature resistance, the general effective use temperature range is-260 ℃ to 700 ℃, while the special basalt fiber can reach 982 ℃, and the use temperature range thereof is far beyond that of other fiber materials; in terms of chemical properties, the continuous basalt fiber contains K 2 O, MgO and TiO 2 So that the glass fiber has stronger acid resistance, alkali resistance and water resistance than alkali-free glass fiber; the sound absorption coefficient of the continuous basalt fiber is larger than that of other fibers such as glass fiber and the like, so that the continuous basalt fiber is an ideal sound insulation material; the continuous basalt fiber has excellent heat insulation and electric insulation performance, and is an ideal heat insulation material and an electric insulation electronic material; in the aspect of mechanical properties, the tensile strength of the continuous basalt fiber is equivalent to that of the alkali-free glass fiber, the elastic modulus of the continuous basalt fiber is 1.5 times of that of the alkali-free glass fiber and 1.9 times of that of the high-strength S glass fiber, and the continuous basalt fiber far exceeds chemical fibers and wood fibers such as polypropylene and the like, so that the continuous basalt fiber is an ideal composite material reinforcing fiber; the basalt fiber also has excellent high-temperature stability, and various mechanical properties, physical properties and chemical properties of the basalt fiber are reduced less than those of alkali-free glass fiber along with the increase of temperature. In addition, the continuous basalt fiber has less waste during production, has little pollution to the environment, can be directly transferred into the ecological environment after being discarded, has no harm, is called as a novel inorganic green high-performance fiber material, and can be applied to the fields of national defense and military aerospace, high-temperature filter fabrics, fiber reinforced composite materials and the like. And because the production cost is relatively low, the method is widely concerned by the industry.
The basalt fiber fabric woven by utilizing the continuous basalt fibers has excellent wear resistance, flame retardance and weather resistance and has no signal shielding interference. By utilizing various advantages of the mobile phone shell, the fireproof suit, the backpack and the like, the mobile phone shell can be manufactured, and the market prospect is very wide. However, the basalt fiber has a compact and smooth surface and contains few active groups, which causes the problems of poor dispersion of the dye on the fiber surface, uneven dyeing, poor color adhesion, easy fading and the like when the basalt fiber is dyed. The traditional dyeing methods of cotton, hemp and the like can dye the basalt fiber in a lighter way due to the darker ground color, and the dyeing rate is lower, so that no mature process exists in the dyeing aspect at present. The preparation method comprises the steps that after the surface of the basalt fiber cloth is pretreated by Liuzhong students, the surface of the basalt fiber cloth is plated with a coating, aluminum plating (CN202010425837.6), nickel plating (CN202010427025.5) and copper plating (CN202010425819.8) are adopted respectively to form a coating, then dyeing is carried out, the obtained fabric is high in dyeing rate and uniform in color, the treatment process is complex, the manufacturing cost is high, the basalt fiber cloth is easy to penetrate through, and the operation difficulty is high. The surface of basalt fiber is subjected to plasma modification by yellow fugax, soaked by sugar water or vegetable pigment and then carbonized at high temperature to obtain black or blue purple inorganic fiber (CN 110863377A) and CN110952345A), and the method has less pollution and the friction resistance and the water-resistant color fastness are both above grade 3. However, the method needs to be carried out step by step, the dyeing condition is harsh, only black or bluish purple can be dyed, and the dyeing is too single. Li satisfactorily carries out plasma modification on the basalt fiber fabric and then carries out dyeing, although the dye uptake of the basalt fiber fabric is improved [ Li satisfactorily 2016], the tensile breaking strength of the fabric is reduced, and the fabric is not dyed uniformly and is easy to fade. The Liujinsong (CN 109778389A) adopts gelatinized starch, vegetable oil, emulsifier and the like to dye glass fiber, and the dyed fiber is not easy to decolor and stain, but the method uses inorganic dye, so that most of various color fastness is about 3 grade, and the color fastness is not ideal. The research and development of the color basalt fiber are few in China, the dyeing application technology of the color basalt fiber is yet to be developed, and if the color basalt fiber with different colors and high color fastness can be provided, the color basalt fiber has important practical significance for the expansion and application of the color basalt fiber.
Disclosure of Invention
The technical problem to be solved is as follows:
1. the invention provides a colorful basalt fiber fabric and a preparation method thereof, and aims to further solve the problem of low coloring rate of the basalt fiber fabric.
2. The invention provides a color basalt fiber fabric and a preparation method thereof, and aims to solve the problem of uneven dyeing caused by smooth surface of basalt fiber.
3. The invention provides a colorful basalt fiber fabric and a preparation method thereof, and aims to solve the problems that the basalt fiber fabric dyed by the traditional method is easy to fade and poor in water resistance.
4. The invention provides a color basalt fiber fabric and a preparation method thereof, and aims to solve the problems of complex process, difficult technical operation and poor effect of dyeing the basalt fiber fabric in the existing dyeing process.
The technical scheme is as follows:
in order to realize the technical requirements, the invention provides a colorful basalt fiber fabric and a preparation method thereof, which can solve the problems of low dye uptake, uneven color, large color difference and fading of the basalt fiber fabric after washing, and is realized by the following technical scheme:
a colorful basalt fiber fabric is prepared from acetone and the following components: basalt fiber fabric, organic environment-friendly dye, adhesive, hardener, surface modifier and color fixing agent.
The invention provides a colorful basalt fiber fabric which comprises an organic environment-friendly dye, wherein the organic environment-friendly dye preferably comprises one of a polyurethane environment-friendly dye and an epoxy resin environment-friendly dye, and the mass fraction of the dye is 2-5%. The present invention is not particularly limited with respect to the source of the dye used.
The color basalt fiber fabric provided by the invention comprises an adhesive, wherein the adhesive preferably comprises one of organic silicon epoxy modified resin and aliphatic polyurethane acrylate, and the mass fraction of the adhesive is 4.0-8.0%. The present invention is not particularly limited with respect to the source of the binder used.
The color basalt fiber fabric provided by the invention comprises a hardening agent, wherein the hardening agent preferably comprises one of a polyurethane hardening agent and an epoxy hardening agent, and the mass fraction of the hardening agent is 3.0-5.0%. The present invention is not particularly limited with respect to the source of the hardener used.
The colorful basalt fiber fabric comprises a surface modifier, wherein the surface modifier preferably comprises one of KH550 and KH570, and the mass fraction of the surface modifier is 0.2-0.6%. The present invention is not particularly limited with respect to the source of the surface modifier used.
The color basalt fiber fabric and the preparation method thereof provided by the invention comprise a color fixing agent, wherein the color fixing agent preferably comprises one of an epoxy resin color fixing agent, a water-based polyurethane color fixing agent and sodium sulfate, and the mass fraction of the color fixing agent is 3-6%. The source of the fixing agent used in the present invention is not particularly limited.
The preparation method comprises the following steps:
the invention also provides a colorful basalt fiber fabric and a preparation method thereof, and the colorful basalt fiber fabric comprises the following steps:
(1) soaking the cut basalt fiber fabric in acetone for about 3.0 h; taking out, and washing with water; and then soaking the mixture in alkali liquor (0.5mol/LNaOH) for 1.0-2.0 h, then washing the mixture with water again, taking out the mixture, and drying the mixture for 2.0-3.0 h for later use.
(2) Weighing a certain amount of adhesive, stirring with 2-3 times of acetone for 30.0min by using a magnetic stirrer, and diluting the adhesive for later use. According to the invention, a continuous uniform film can be wrapped on the basalt fiber fabric by adding the adhesive, the dyeability of the basalt fiber fabric can be improved by the film, and meanwhile, the film can also enable the basalt fiber fabric to keep the performances of the basalt fiber fabric, such as weather resistance, corrosion resistance and the like.
(3) And (3) magnetically stirring a certain amount of hardener for 1.0-2.0 hours by using 8-10 times of acetone, and dissolving the hardener for later use. By adding the hardening agent, the color dye liquor can be quickly dried on the surface of the basalt fiber fabric, a layer of color film is formed and firmly attached to the surface of the basalt fiber fabric, and the dye uptake is improved.
(4) And (3) dissolving a certain amount of the surface modifier by using 10 times of acetone through magnetic stirring for 30.0-40.0 min, and standing by after the surface modifier is dissolved. According to the invention, the surface modifier is added, so that the reactivity of the basalt fiber fabric can be improved, the surface polarity of the basalt fiber fabric is improved, the basalt fiber fabric is more easily soaked by the color dye solution, more color dye molecules are favorably combined on the basalt fiber fabric, and the basalt fiber fabric is uniformly dyed.
(5) And magnetically stirring and diluting a certain amount of dye with 10-15 times of acetone for 30.0-40.0 min, and dissolving for later use.
(6) And stirring and dissolving a certain amount of the color fixing agent with deionized water of 20-30 times for 30.0-40.0 min, and diluting for later use. According to the invention, the color fixing agent is added, so that the adhesion fastness of the dye on the basalt fiber fabric is improved, the color fastness of the basalt fiber fabric is improved, and the situations of fading and fading are reduced.
(7) And sequentially adding a diluted and dissolved hardening agent, a surface modifier and a dye into the diluent of the adhesive, and finally adding the balance of acetone, and carrying out magnetic stirring and mixing for 2.0-3.0 hours to obtain a dye solution containing coloring substances for later use. It should be noted that, in the color dye liquor of the present invention, the organic environmental protection dye, the surface modifier, the hardener and the color fixing agent not only play the conventional role of themselves, but also mutually support each other in function, the technical effect of the present invention is the sum of the synergistic effect of each component, and each component has a certain internal correlation, and is not the superposition of single technical effects.
(8) Dip-dyeing the basalt fiber fabric for 2.0-3.0 h at the dye liquor of the step (7) at 75 ℃, taking out and drying at 80 ℃ for 4.0-5.0 h for later use;
(9) fixing the basalt fiber fabric obtained in the step (8) in the color fixing agent obtained in the step (6) for 2.0-3.0 min, taking out, drying at 75-85 ℃ for 3.0-4.0 h, washing off floating color, taking out, and drying at 80 ℃ in a drying oven for 3.0-5.0 h to obtain the color fixing agent for the basalt fiber fabric, wherein the color fixing agent is a mixture of a dye, a pigment and a pigment
The invention has the following positive effects:
compared with the prior art, the invention provides a colorful basalt fiber fabric and a preparation method thereof, and the positive effects are as follows:
1. a colorful basalt fiber fabric and a preparation method thereof are provided, and the color of the prepared colorful basalt fiber fabric is full and uniform.
2. The color basalt fiber fabric has bright color and high dye uptake.
3. The color basalt fiber fabric has raised water washing resistance, friction resistance and color fastness to sunlight.
4. A color basalt fiber fabric and a preparation method thereof are provided, the basalt fiber fabric is fast and easy to color, the color dye solution can be recycled, and the dyeing process is simple.
Drawings
FIG. 1 is a process diagram for dyeing basalt fiber fabric;
FIG. 2 is an SEM image of a basalt fiber fabric after dyeing in example 1;
fig. 3 is an SEM image of undyed basalt fiber fabric.
The specific implementation mode is as follows:
the present invention is further illustrated by the following examples, which do not limit the present invention in any way, and any modifications or changes that can be easily made by a person skilled in the art to the present invention will fall within the scope of the claims of the present invention without departing from the technical solution of the present invention.
Example 1:
soaking the cut basalt fiber fabrics (50 multiplied by 40cm) in 200mL acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, and washing with water; soaking in 500.0mL of alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:5, and the preparation of the dye solution is as follows: stirring and diluting 10.5g of organic silicon epoxy modified resin with 22.0mL of acetone; 8.2g of epoxy hardener is diluted by stirring with 70.0mL of acetone, 7.7g of epoxy resin bright red environment-friendly dye is diluted by stirring with 80.0mL of acetone, and 1.0gkH 570 is diluted by stirring with 10.0mL of acetone; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.2 hours. And dip-dyeing the basalt fiber fabric for 2.1h at the temperature of 75 ℃ in the dye solution, taking out and drying for 4.1h, taking 3mL of epoxy resin color fixing agent, diluting the epoxy resin color fixing agent with 100.0mL of deionized water, fixing the color of the fabric for 2.0min, taking out and drying for 3.0h at the temperature of 75 ℃, washing off the floating color, taking out and drying for 3.0h at the temperature of 80 ℃ in a drying oven to obtain the bright red basalt fiber fabric.
Example 2:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL of alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabrics needing to be dyed and the bath ratio of 1:5, and the preparation of the dye liquor is as follows: stirring and diluting 11.0g of organic silicon epoxy modified resin with 24.0mL of acetone; stirring and diluting 7.6g of epoxy hardener with 65.0mL of acetone, stirring and diluting 5.8g of bright red environment-friendly epoxy resin dye with 70.0mL of acetone, and stirring and diluting 0.8g of kH570 with 10.0mL of acetone; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.0 h. The basalt fiber fabric is dip-dyed for 2.5h at the temperature of the dye solution of 78 ℃, taken out and dried for 4.2h, 3mL of epoxy resin color fixing agent is taken and diluted by 100.0mL of deionized water, the color of the fabric is fixed for 2.0min, the fabric is taken out and dried for 3.1h at the temperature of 75 ℃, the floating color is washed away, and the fabric is taken out and dried for 3.2h at the temperature of 80 ℃ in a drying oven, so that the brilliant red basalt fiber fabric is obtained.
Example 3:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL of alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:6, and the preparation of the dye solution is as follows: stirring and diluting 8.5g of organic silicon epoxy modified resin with 20.0mL of acetone; 6.8g of epoxy hardener was diluted with 68.0mL of acetone under stirring; 5.5g of epoxy resin blue dye is stirred and diluted by 60.0mL of acetone; 0.7g of kH570 is diluted with 10.0mL of acetone with stirring; the curing agent, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.2 hours. And dip-dyeing the basalt fiber fabric for 2.3h at the temperature of 70 ℃ in the dye solution, taking out and drying for 4.5h, taking 3mL of epoxy resin color fixing agent, diluting the epoxy resin color fixing agent with 120.0mL of deionized water, fixing the color of the fabric for 2.0min, taking out and drying for 3.5h at the temperature of 75 ℃, washing off floating color, taking out and drying for 3.6h at the temperature of 70 ℃ in a drying oven to obtain the blue basalt fiber fabric.
Example 4:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL of alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:6, and the preparation of the dye solution is as follows: stirring and diluting 10.2g of organic silicon epoxy modified resin with 23.0mL of ionized water; 7.1g of epoxy hardener was diluted with 70.0mL of ionic water under stirring, 4.9g of epoxy resin yellow dye was diluted with 50.0mL of ionic water under stirring, and 1.1g of KH570 was diluted with 12.0mL of ionic water under stirring; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.3 h. The method comprises the steps of dip-dyeing the basalt fiber fabric for 2.7 hours at the temperature of the dye solution of 60 ℃, taking out and drying for 5.0 hours, diluting 3mL of epoxy resin color fixing agent with 120.0mL of deionized water, fixing the color of the fabric for 2.0 minutes, taking out and drying for 3.0 hours at the temperature of 75 ℃, washing off the floating color, taking out and drying for 4.0 hours at the temperature of 70 ℃ in a drying oven to obtain the yellow basalt fiber fabric.
Example 5:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL of alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:7, and the preparation of the dye solution is as follows: stirring and diluting 12.5g of organic silicon epoxy modified resin with 27.0mL of ionized water; 8.2g of epoxy hardener is diluted by 82.0mL of ionic water, 4.8g of epoxy resin fluorescent red dye is diluted by 50.0mL of ionic water, and 1.1g of KH570 is diluted by 12.0mL of ionic water; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.0 h. The method comprises the steps of dip-dyeing the basalt fiber fabric for 2.5 hours at the temperature of the dye liquor of 66 ℃, taking out and drying for 5.0 hours, diluting 3mL of epoxy resin color fixing agent with 120.0mL of deionized water, fixing the color of the fabric for 2.0 minutes, taking out and drying for 3.4 hours at the temperature of 75 ℃, washing off the floating color, taking out and drying for 4.5 hours at the temperature of 75 ℃ in a drying oven to obtain the fluorescent red basalt fiber fabric.
Example 6:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:7, and the preparation of the dye solution is as follows: 10.9g of aliphatic polyurethane acrylate is stirred and diluted by 22.0mL of acetone; stirring and diluting 6.8g of polyurethane hardening agent with 70.0mL of acetone, stirring and diluting 4.7g of polyurethane resin white dye with 48.0mL of acetone, stirring and diluting 1.0g of kH550 with 10.0mL of acetone; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.5 h. The method comprises the steps of dip-dyeing the basalt fiber fabric for 3.0h at the temperature of the dye solution of 75 ℃, taking out and drying for 5.0h, diluting 3mL of polyurethane resin color fixing agent with 120.0mL of deionized water, fixing the color of the fabric for 2.5min, taking out and drying for 3.5h at the temperature of 75 ℃, washing off the floating color, taking out and drying for 4.5h at the temperature of 70 ℃ in a drying oven to obtain the white basalt fiber fabric.
Example 7:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL of alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:10, and the preparation of the dye solution is as follows: stirring and diluting 5.5g of aliphatic polyurethane acrylate with 12.0mL of acetone; 4.2g of polyurethane hardener is diluted by stirring with 45.0mL of acetone, 3.8g of polyurethane resin cyan dye is diluted by stirring with 40.0mL of acetone, and 0.4g of KH550 is diluted by stirring with 5.0mL of acetone; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 1.5 h. And dip-dyeing the basalt fiber fabric for 3.0h at the temperature of the dye solution of 80 ℃, taking out and drying, fixing the color for 2.0min by using 100.0mL of 0.85mol/L sodium sulfate aqueous solution, taking out and drying for 3.0h at the temperature of 75 ℃, washing off the floating color, taking out and drying for 3.5h at the temperature of a drying oven of 85 ℃ to obtain the cyan basalt fiber fabric.
Example 8:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabrics needing to be dyed and the bath ratio of 1:10, and the preparation of the dye liquor is as follows: stirring and diluting 9.5g of aliphatic polyurethane acrylate with 20.0mL of acetone; 5.2g polyurethane hardening agent with 55.0mL acetone stirring dilution, 3.5g polyurethane resin orange dye with 48.0mL acetone stirring dilution, 0.5g KH570 with 6.0mL acetone stirring dilution; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 1.8 h. And dip-dyeing the basalt fiber fabric for 2.5h at the temperature of the dye solution of 85 ℃, taking out and drying for 4.5h, fixing the color of the basalt fiber fabric for 3.0min by using 100.0mL of 0.85mol/L sodium sulfate aqueous solution, taking out and drying for 3.0h at the temperature of 75 ℃, washing off the floating color, taking out and drying for 4.9h at the temperature of 80 ℃ in a drying oven to obtain the orange basalt fiber fabric.
Example 9:
soaking the cut basalt fiber fabrics (50 multiplied by 40cm) in 200mL acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabrics needing to be dyed and the bath ratio of 1:11, and the preparation of the dye liquor is as follows: 5.7g of aliphatic polyurethane acrylate is stirred and diluted by 15.0mL of ionized water; 3.8g of polyurethane hardening agent is stirred and diluted by 42.0mL of ionized water, 3.6g of polyurethane resin black dye is stirred and diluted by 35.0mL of ionized water, and 0.4g of KH550 is stirred and diluted by 5.0mL of ionized water; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 3.0 h. And dip-dyeing the basalt fiber fabric for 3.0h at the temperature of the dye solution of 80 ℃, taking out and drying for 4.0h, fixing the color of the basalt fiber fabric for 2.8min by using 100.0mL of 0.8mol/L sodium sulfate aqueous solution, taking out and drying for 3.0h at the temperature of 75 ℃, washing off floating color, taking out and drying for 5.0h at the temperature of 80 ℃ in a drying oven to obtain the black basalt fiber fabric.
Example 10:
soaking the cut basalt fiber fabric (50 multiplied by 40cm) in 200mL of acetone for 3.0h (80 multiplied by 80cm sealed box); taking out, washing with water, and drying; soaking in 500.0mL alkali solution (0.5mol/L NaOH) for 1.5h, washing with water again, taking out, and drying; dyeing is carried out according to the mass of the basalt fiber fabric needing to be dyed according to the bath ratio of 1:12, and the preparation of the dye solution is as follows: stirring 8.7g of aliphatic polyurethane acrylate with 19.0mL of ionic water for dilution; 3.7g of polyurethane curing agent is stirred and diluted by 40.0mL of ionized water, 3.4g of polyurethane blue dye is stirred and diluted by 35.0mL of ionized water, and 0.5g of KH550 is stirred and diluted by 6.0mL of ionized water; the hardener, the surface modifier and the dye which are diluted and dissolved are sequentially added into the diluent of the adhesive and stirred and mixed for 2.0 h. And dip-dyeing the basalt fiber fabric for 2.5h at the temperature of the dye solution of 80 ℃, taking out and drying for 4.7h, taking 3mL of polyurethane resin color fixing agent, diluting the polyurethane resin color fixing agent with 120.0mL of deionized water, fixing the color of the fabric for 2.0min, taking out and drying for 4.5h at the temperature of 75 ℃, washing off the floating color, taking out and drying for 4.2h at the temperature of 80 ℃ in a drying oven to obtain the blue basalt fiber fabric.
Performance experiments were performed on the colored basalt fiber fabrics prepared in examples 1 to 10. The method for detecting the color fastness to washing comprises the following steps of determining the color fastness to rubbing according to GB/T5713-: outdoor insolation), dyeing process as shown in figure 1, and experimental results as shown in table 1, figure 2 and figure 3.
TABLE 1 measurement of Properties of examples
Claims (8)
1. A preparation method of a colorful basalt fiber fabric is characterized by comprising the following specific implementation steps:
(1) soaking the cut basalt fiber fabrics in acetone for 3.0 h; taking out, and washing with water; further soaking the mixture in alkali liquor (0.5mol/LNaOH) for 1.0-2.0 h, then washing the mixture with water again, taking out the mixture, and drying the mixture for 2.0-3.0 h for later use;
(2) weighing a certain amount of adhesive, stirring the adhesive with 2-3 times of acetone for about 30.0min by using a magnetic stirrer, and diluting the adhesive for later use;
(3) magnetically stirring a certain amount of hardener for 1.0-2.0 hours by using 8-10 times of acetone, and dissolving the hardener for later use;
(4) dissolving a certain amount of surface modifier by using 10 times of acetone under magnetic stirring for 30.0-40.0 min, and standing for later use after the surface modifier is dissolved;
(5) magnetically stirring and diluting a certain amount of organic environment-friendly dye with 10-15 times of acetone for 30.0-40.0 min for dissolving, and standing by after dissolving;
(6) stirring, dissolving and diluting a certain amount of color fixing agent with deionized water of 20-30 times for 30.0-40.0 min, and diluting for later use;
(7) sequentially adding a diluted and dissolved hardening agent, a surface modifier and an organic environment-friendly dye into a diluent of the adhesive, and finally adding the balance of acetone, and carrying out magnetic stirring and mixing for 2.0-3.0 hours to obtain a dye solution containing coloring substances for later use;
(8) dip-dyeing the basalt fiber fabric for 2.0-3.0 h at the dye liquor of 75 ℃ in the step (7), taking out, and drying for 4.0-5.0 h at the temperature of 80 ℃ for later use;
(9) and (3) fixing the basalt fiber fabric in the step (8) in the color fixing agent in the step (6) for 2.0-3.0 min, taking out, drying at 75-85 ℃ for 3.0-4.0 h, washing off floating color, taking out, and drying at 80 ℃ in a drying oven for 3.0-5.0 h.
2. The method for preparing the colorful basalt fiber fabric according to the claim 1, characterized in that the colorful dye solution consists of the following components: 2-5% of organic environment-friendly dye, 4-8% of adhesive, 3-5% of hardener, 0.2-0.6% of surface modifier and 3-6% of color fixing agent.
3. The method for preparing the colorful basalt fiber fabric according to claim 1, characterized in that: the organic environment-friendly dye can be one of epoxy resin type dye and polyurethane resin type dye.
4. The method for preparing the colorful basalt fiber fabric according to claim 1, characterized in that: the resin adhesive can be one of organic silicon epoxy modified resin and aliphatic polyurethane acrylate.
5. The method for preparing the colorful basalt fiber fabric according to claim 1, characterized in that: the hardener can be one of phenolic hardener, polyurethane hardener and epoxy hardener.
6. The method for preparing the colorful basalt fiber fabric according to claim 1, characterized in that: the surface modifier can be one of KH550 and KH 570.
7. The method for preparing the colorful basalt fiber fabric according to claim 1, characterized in that: the color fixing agent can be one or more of an epoxy resin color fixing agent, sodium sulfate, a water-based polyurethane color fixing agent and a cationic quaternary ammonium salt.
8. A colored basalt fiber fabric, characterized by being manufactured by the method of manufacturing any one of the colored basalt fiber fabrics according to claims 1 to 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210707510.7A CN115094653A (en) | 2022-06-21 | 2022-06-21 | Colorful basalt fiber fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210707510.7A CN115094653A (en) | 2022-06-21 | 2022-06-21 | Colorful basalt fiber fabric and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115094653A true CN115094653A (en) | 2022-09-23 |
Family
ID=83292405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210707510.7A Pending CN115094653A (en) | 2022-06-21 | 2022-06-21 | Colorful basalt fiber fabric and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115094653A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3068546A (en) * | 1959-02-24 | 1962-12-18 | Owens Corning Fiberglass Corp | Method of producing dyed glass fiber yarn |
| CN102532942A (en) * | 2012-01-15 | 2012-07-04 | 山西大学 | Colorant for basalt fiber or glass fiber and preparation method thereof |
| CN103553366A (en) * | 2013-10-29 | 2014-02-05 | 东华大学 | Glass fiber soakage agent for dyeing and preparation method of glass fiber soakage agent |
| CN103833235A (en) * | 2014-01-15 | 2014-06-04 | 东华大学 | Method for preparing color glass fibers by on-line coating |
| CN113480200A (en) * | 2021-07-02 | 2021-10-08 | 深圳市明斯达实业有限公司 | Dyeing process of glass fiber and colored glass fiber |
| CN113501671A (en) * | 2021-07-02 | 2021-10-15 | 深圳市明斯达实业有限公司 | Dyeing process of glass fiber and colored glass fiber |
-
2022
- 2022-06-21 CN CN202210707510.7A patent/CN115094653A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3068546A (en) * | 1959-02-24 | 1962-12-18 | Owens Corning Fiberglass Corp | Method of producing dyed glass fiber yarn |
| CN102532942A (en) * | 2012-01-15 | 2012-07-04 | 山西大学 | Colorant for basalt fiber or glass fiber and preparation method thereof |
| CN103553366A (en) * | 2013-10-29 | 2014-02-05 | 东华大学 | Glass fiber soakage agent for dyeing and preparation method of glass fiber soakage agent |
| CN103833235A (en) * | 2014-01-15 | 2014-06-04 | 东华大学 | Method for preparing color glass fibers by on-line coating |
| CN113480200A (en) * | 2021-07-02 | 2021-10-08 | 深圳市明斯达实业有限公司 | Dyeing process of glass fiber and colored glass fiber |
| CN113501671A (en) * | 2021-07-02 | 2021-10-15 | 深圳市明斯达实业有限公司 | Dyeing process of glass fiber and colored glass fiber |
Non-Patent Citations (2)
| Title |
|---|
| 徐艳 等: "自着色水性聚氨酯制备及其在棉织物涂层中的应用", 《纺织学报》, vol. 40, no. 7, pages 85 - 89 * |
| 赵彤 等编: "《高性能热固性树脂》", vol. 1, 中国原子能出版社, pages: 112 - 115 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101735663B (en) | Composite black disperse dye | |
| CN101705020B (en) | Blue disperse dye mixture | |
| CN103833235A (en) | Method for preparing color glass fibers by on-line coating | |
| CN102561068A (en) | Dyeing process for brocade and cotton fabric by reactive dye | |
| CN1858118A (en) | Active composite dye | |
| CN115094653A (en) | Colorful basalt fiber fabric and preparation method thereof | |
| CN108589326A (en) | A kind of technological process of printing and dyeing | |
| CN104927541A (en) | Reflecting heat-insulation type real stone paint and preparation technology thereof | |
| CN107524018B (en) | A kind of method for repairing color with the dye of positive ion after cotton grey cloth reactive dyeing | |
| CN102585548A (en) | Red active dye composition | |
| CN101880475B (en) | Active scarlet dye composition | |
| CN112574594B (en) | Disperse yellow-orange dye composition and product thereof | |
| CN101880474A (en) | Orange red reactive dyestuff composition | |
| CN108102424A (en) | A kind of composite active black dye mixture, its preparation method and application | |
| CN112876876B (en) | Disperse yellow-orange dye composition and dye product thereof | |
| CN111574845B (en) | Bright red fluorescent dye and application thereof | |
| CN104231668A (en) | Preparation method and application of yellow reactive dye combination and fibers or fiber fabrics dyed with yellow reactive dye combination | |
| CN107987556B (en) | Composite active black dye | |
| CN111607250A (en) | High-fastness reactive orange dye composition | |
| CN102975254A (en) | Dyeing method with low waste water discharge of wood meal for colorful wood-plastic composite material with high fastness | |
| CN102558905A (en) | Composite reactive red dye for low-salt dyeing and dyeing application thereof | |
| CN105040465A (en) | Pigment dyeing liquor for dyeing superfine fibers and method for improving dyeing color depth of superfine fibers | |
| CN110835386A (en) | Polydimethy diallyl amine chloride polymer and preparation method and application thereof | |
| CN111909536A (en) | Black direct dye composition, black direct dye and preparation method and application thereof | |
| CN110983822B (en) | Coating composition for yarn pigment dyeing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |