CN115075931A - Automobile anti-corrosion cooling system - Google Patents

Automobile anti-corrosion cooling system Download PDF

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Publication number
CN115075931A
CN115075931A CN202210642366.3A CN202210642366A CN115075931A CN 115075931 A CN115075931 A CN 115075931A CN 202210642366 A CN202210642366 A CN 202210642366A CN 115075931 A CN115075931 A CN 115075931A
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China
Prior art keywords
liquid
box body
cooling system
liquid outlet
outlet pipe
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CN202210642366.3A
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Chinese (zh)
Inventor
李立琳
秦先锋
于成龙
蒲华凯
李奕澎
李孟周
胡庆新
马涛
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Henan Institute of Engineering
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Henan Institute of Engineering
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Priority to CN202210642366.3A priority Critical patent/CN115075931A/en
Publication of CN115075931A publication Critical patent/CN115075931A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01PCOOLING OF MACHINES OR ENGINES IN GENERAL; COOLING OF INTERNAL-COMBUSTION ENGINES
    • F01P11/00Component parts, details, or accessories not provided for in, or of interest apart from, groups F01P1/00 - F01P9/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01PCOOLING OF MACHINES OR ENGINES IN GENERAL; COOLING OF INTERNAL-COMBUSTION ENGINES
    • F01P11/00Component parts, details, or accessories not provided for in, or of interest apart from, groups F01P1/00 - F01P9/00
    • F01P11/06Cleaning; Combating corrosion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01PCOOLING OF MACHINES OR ENGINES IN GENERAL; COOLING OF INTERNAL-COMBUSTION ENGINES
    • F01P11/00Component parts, details, or accessories not provided for in, or of interest apart from, groups F01P1/00 - F01P9/00
    • F01P11/14Indicating devices; Other safety devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01PCOOLING OF MACHINES OR ENGINES IN GENERAL; COOLING OF INTERNAL-COMBUSTION ENGINES
    • F01P11/00Component parts, details, or accessories not provided for in, or of interest apart from, groups F01P1/00 - F01P9/00
    • F01P11/06Cleaning; Combating corrosion
    • F01P2011/061Cleaning or combating corrosion using filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01PCOOLING OF MACHINES OR ENGINES IN GENERAL; COOLING OF INTERNAL-COMBUSTION ENGINES
    • F01P11/00Component parts, details, or accessories not provided for in, or of interest apart from, groups F01P1/00 - F01P9/00
    • F01P11/06Cleaning; Combating corrosion
    • F01P2011/066Combating corrosion
    • F01P2011/068Combating corrosion chemically

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The invention provides an automobile anti-corrosion cooling system which comprises a radiator, wherein the radiator comprises a first box body and a second box body, the first box body and the second box body are connected through a plurality of capillary tubes, and fins are arranged on the capillary tubes; the first box body is also provided with a liquid inlet pipe; a liquid outlet pipe is arranged on the second box body, and a purification assembly is arranged on the liquid outlet pipe; the liquid outlet pipe is externally provided with a storage box, the storage box is divided into an acid liquid area and an alkali liquid area by a partition plate, the bottom of the acid liquid area is provided with a first outlet, the first outlet is connected with the liquid outlet pipe through a first connecting pipe, the first connecting pipe is provided with an acid liquid metering pump, the bottom of the alkali liquid area is provided with a second outlet, the second outlet is connected with the liquid outlet pipe through a second connecting pipe, and the second connecting pipe is provided with an alkali liquid metering pump. The invention can circularly treat the cooling liquid, ensures that the concentration of chloride ions and the pH value in the cooling liquid meet the requirements, prolongs the corrosion rate of the radiator and related equipment, and has the advantage of environmental protection.

Description

Automobile anti-corrosion cooling system
Technical Field
The invention belongs to the technical field of automobiles, and particularly relates to an automobile anti-corrosion cooling system.
Background
With the vigorous development of the manufacturing industry in China, the motor vehicle keeping quantity is increased sharply, and by the end of 2021, the motor vehicle keeping quantity in China reaches 3.95 hundred million. Therefore, with the increase of the automobile holding capacity, the corrosion prevention problem of the automobile is more and more concerned. The performance of the cooling system in the use process of the automobile is related to the service life of the automobile, and the core part in the cooling system is the radiator, and the performance of the cooling system directly influences the heat dissipation effect of the automobile. After a radiator of a certain company is put into use for a period of time, corrosive leakage often occurs, great influence is generated on the dynamic property, the economy and the reliability of an automobile, and researches show that the main reason for generating corrosion on the radiator has great relation with the concentration of chloride ions in cooling liquid and the pH value, for example, the corrosion speed of the radiator can be accelerated by the excessive concentration of the chloride ions, the excessive pH value or the excessive pH value, so that how to effectively slow down the corrosion of the radiator by processing the cooling liquid is a problem which needs to be solved urgently.
Disclosure of Invention
In order to overcome the technical problem, the invention provides an automobile anti-corrosion cooling system, which comprises the following specific schemes:
an automobile anti-corrosion cooling system comprises a radiator for radiating cooling liquid, wherein the radiator comprises a first box body and a second box body, the first box body and the second box body are connected through a plurality of capillary tubes, and fins are arranged on the capillary tubes; the first box body is also provided with a liquid inlet pipe; the second box body is provided with a liquid outlet pipe, the liquid outlet pipe is provided with a purification assembly, the purification assembly comprises a shell, the shell is internally divided into a filtration channel and a bypass channel by a partition plate, and an activated carbon filtration layer and an ion exchange resin layer for replacing chloride ions in the cooling liquid are sequentially arranged in the filtration channel; a PH detector is further arranged in the liquid outlet pipe, a storage box is arranged outside the liquid outlet pipe, the storage box is divided into an acid liquid area for storing acid liquid and an alkali liquid area for storing alkali liquid by a partition plate, a first outlet is arranged at the bottom of the acid liquid area, the first outlet is connected with the liquid outlet pipe through a first connecting pipe, an acid liquid metering pump is arranged on the first connecting pipe, a second outlet is arranged at the bottom of the alkali liquid area, the second outlet is connected with the liquid outlet pipe through a second connecting pipe, and an alkali liquid metering pump is arranged on the second connecting pipe; the PH detector, the acid liquor metering pump and the alkali liquor metering pump are all electrically connected to the controller.
Based on the above, still be equipped with in the drain pipe with controller electric connection's chloride ion sensor
Based on the above, the two ends of the purification component in the liquid outlet pipe are respectively provided with the first flow sensor and the second flow sensor which are electrically connected with the controller.
Based on the above, the cross-sectional area of the bypass passage occupies one-half of the cross-sectional area of the housing.
In view of the above, the material of the ion exchange resin layer is D201 resin.
On the basis, the first box body is provided with the liquid inlet and the pressure release valve, the second box body is provided with the liquid outlet, and the liquid outlet is provided with the valve.
Based on the above, the acid solution is a dilute sulfuric acid solution with a concentration of 20%, and the alkali solution is a sodium hydroxide solution with a concentration of 40%.
Based on the above, the cooling liquid comprises glycol and water, and the content of the cooling liquid is 30% -70%.
Based on the above, the controller is provided with an alarm.
Compared with the prior art, the invention has outstanding substantive characteristics and remarkable progress, and particularly has the following advantages:
1. the corrosion-resistant cooling system provided by the invention is cooperatively matched in two modes of filtering and adjusting, wherein the filtering is to remove chloride ions and partial impurities in cooling liquid to slow down the corrosion speed; the adjustment means that the PH of the cooling liquid is adjusted to be in a proper range, so that the corrosion rate of the radiator is reduced, the working performance of the cooling system is improved, the service life of the automobile is prolonged, and the cooling system has the characteristics of simple and ingenious structural design and strong practicability.
2. According to the invention, the first flow sensor and the second flow sensor which are electrically connected with the controller are respectively arranged at the two ends of the purification assembly in the liquid outlet pipe, so that whether the filter assembly is blocked or not can be monitored in real time by the structural design, and the normal operation of a cooling system is ensured.
Drawings
Fig. 1 is a schematic view of the overall structure of the present invention.
FIG. 2 is a schematic view of the structure of the purification module of the present invention.
In the figure: 1. a heat sink; 1-1. a first box body; 1-2. a second box body; 1-3, connecting pipe; 1-4, a liquid inlet; 1-5, a pressure relief valve; 1-6. fins; 1-8. a liquid outlet; 1-9. a valve; 2. a liquid inlet pipe; 3. a liquid outlet pipe; 4. a purification assembly; 4-1. a shell; 4-2, a separator; 4-3, an active carbon filter layer; 4-4, ion exchange resin layer; 5. a first flow sensor; 6, a PH detector; 7. a second flow sensor; 8. a chloride ion concentration sensor; 9. a storage box; 9-1, acid liquor zone; 9-2, an alkali liquor area; 9-5, a first connecting pipe; 9-6, acid liquor metering pump; 9-7, a second connecting pipe; 9-8, alkali liquor metering pump; 10. and a controller.
Detailed Description
The technical solution of the present invention will be described in detail by the following embodiments.
Examples
As shown in fig. 1-2, the present invention provides an anti-corrosion cooling system for an automobile, including a heat sink 1 for dissipating heat of a coolant, where the heat sink 1 includes a first box 1-1 and a second box 1-2, the first box 1-1 and the second box 1-2 are connected by a plurality of capillaries 1-3, and the capillaries 1-3 are provided with fins 1-6; the first box body 1-1 is also provided with a liquid inlet pipe 2; a liquid outlet pipe 3 is arranged on the second box body 1-2, a purification component 4 is arranged on the liquid outlet pipe 3, the purification component 4 comprises a shell 4-1, the shell 4-1 is internally divided into a filtration channel and a bypass channel by a partition plate 4-2, and an activated carbon filtration layer 4-3 and an ion exchange resin layer 4-4 for replacing chloride ions in the cooling liquid are sequentially arranged in the filtration channel; a PH detector 6 is further arranged in the liquid outlet pipe 3, a storage box 9 is arranged outside the liquid outlet pipe 3, the storage box 9 is divided into an acid liquid area 9-1 for storing acid liquid and an alkali liquid area 9-2 for storing alkali liquid by a partition plate 4-2, a first outlet is arranged at the bottom of the acid liquid area 9-1 and is connected with the liquid outlet pipe 3 through a first connecting pipe 9-5, an acid liquid metering pump 9-6 is arranged on the first connecting pipe 9-5, a second outlet is arranged at the bottom of the alkali liquid area 9-2 and is connected with the liquid outlet pipe 3 through a second connecting pipe 9-7, and an alkali liquid metering pump 9-8 is arranged on the second connecting pipe 9-7; the PH detector 6, the acid liquor metering pump 9-6 and the alkali liquor metering pump 9-8 are all electrically connected to the controller 10.
In order to facilitate monitoring of the concentration of chloride ions in the cooling liquid, a chloride ion concentration sensor 8 electrically connected with the controller 10 is further arranged in the liquid outlet pipe 3
Considering that the purifying assembly 4 may be blocked, a first flow sensor 5 and a second flow sensor 7 electrically connected to the controller 10 are respectively disposed at two ends of the purifying assembly 4 in the liquid outlet pipe 3.
The bypass channel structure is mainly designed by determining the size of the cross section of the bypass channel, and the size of the cross section of the bypass channel is designed based on comprehensive fluid mechanics analysis, which specifically comprises the following steps:
the turbulence model adopts a standard occupation turbulence model, and a turbulence kinetic energy equation and a diffusion equation are shown as a formula (1) and a formula (2):
Figure BDA0003684651480000041
in formula (1): Δ t w Δ t is the change in temperature of the coolant as it circulates during engine operation w In the range of 6 ℃ to 12 ℃ and at w =10℃;γ w Is the density of water, generally gamma w =1000Kg/m 3 ;C w Is the specific heat of water, in KJ/Kg. ℃, in general C w =4.187
1 actual cooling water circulation volume
The formula is as follows:
V a =1.2 V w =1.2×0.00196=0.002352m 3 s type (2)
Since each phase is considered to be an interpenetrating continuum in the euler model, a volume fraction is required to represent the space occupied by each phase in the control volume.
The volume occupied by phase q is defined as:
Figure BDA0003684651480000042
wherein the sum of all phase volume fractions is 1:
Figure BDA0003684651480000043
therefore, the effective density of the q-th phase in the control body is converted into:
Figure BDA0003684651480000051
similarly, using Newton's second law, the change in momentum of the q-th phase in the control volume is written: the rate of change of momentum with time + the amount of change in momentum caused by the fluid passing over the surface of the control body-the force applied to that phase in the control body.
Figure BDA0003684651480000052
According to the design principle of the bypass channel and the comprehensive analysis of fluid mechanics, when the area of the bypass channel is designed to be one-half of the sectional area of the pipeline, the circulation of a cooling system cannot be influenced when the fluid is ensured to effectively pass through.
The material of the ion exchange resin layer 4-4 is D201 resin. The resin has the advantages of small influence of temperature, stable chemical property, high mechanical strength, high anti-pollution capacity, high repeated utilization rate and the like, and is suitable for being used in severe environment, so that the D201 type resin is selected from the ion exchange resin layers 4-4.
In addition, when the D201 resin is not used for adsorbing chloride ions after the adsorption task is finished, the regeneration of the resin is needed. The regeneration of the ion exchange resin is a complex process, and the regeneration concentration, flow rate, time and the like influence the regeneration effect, so that the ion exchange resin device can be disassembled, and then the regeneration of the resin is completed in an external special device. Therefore, the regeneration process of the resin can be simplified by replacing the ion resin device, and the recycling of the resin is realized. Meanwhile, in order to improve the transformation rate of the D201 resin, the resin can be treated by sulfuric acid in the links of pretreatment, desorption and the like. The reference literature shows that the regeneration rate of the resin can reach about 90%.
The first box body 1-1 is provided with a liquid inlet 1-4 and a pressure release valve 1-5, the second box body 1-2 is provided with a liquid outlet 1-8, and a valve 1-9 is arranged at the liquid outlet 1-8.
The acid solution is a 20% dilute sulfuric acid solution, and the alkali solution is a 40% sodium hydroxide solution.
The cooling liquid mainly comprises glycol and water, wherein the content of the cooling liquid is 30-70%.
It should be noted that when the concentration of the chlorine ions is too high or the flow rates of the first flow sensor 5 and the second flow sensor 7 are not consistent or the PH value deviates from the set threshold range, the alarm on the controller 10 will give an alarm.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention and not to limit it; although the present invention has been described in detail with reference to preferred embodiments, those skilled in the art will understand that: modifications to the specific embodiments of the invention or equivalent substitutions for parts of the technical features may be made; without departing from the spirit of the present invention, it is intended to cover all aspects of the invention as defined by the appended claims.

Claims (9)

1. An automobile anticorrosion cooling system, its characterized in that: the radiator comprises a radiator (1) for radiating cooling liquid, wherein the radiator (1) comprises a first box body (1-1) and a second box body (1-2), the first box body (1-1) and the second box body (1-2) are connected through a plurality of capillary tubes (1-3), and fins (1-6) are arranged on the capillary tubes (1-3); the first box body (1-1) is also provided with a liquid inlet pipe (2); a liquid outlet pipe (3) is arranged on the second box body (1-2), a purification assembly (4) is arranged on the liquid outlet pipe (3), the purification assembly (4) comprises a shell (4-1), the shell (4-1) is internally divided into a filtration channel and a bypass channel by a partition plate (4-2), and an active carbon filtration layer (4-3) and an ion exchange resin layer (4-4) for replacing chloride ions in the cooling liquid are sequentially arranged in the filtration channel; a PH detector (6) is arranged in the liquid outlet pipe (3), a storage box (9) is arranged outside the liquid outlet pipe (3), the storage box (9) is internally divided into an acid liquid area (9-1) for storing acid liquid and an alkali liquid area (9-2) for storing alkali liquid by a partition plate (4-2), the bottom of the acid liquid zone (9-1) is provided with a first outlet which is connected with the liquid outlet pipe (3) through a first connecting pipe (9-5), an acid liquor metering pump (9-6) is arranged on the first connecting pipe (9-5), a second outlet is arranged at the bottom of the alkali liquor area (9-2), the second outlet is connected with the liquid outlet pipe (3) through a second connecting pipe (9-7), and an alkali liquor metering pump (9-8) is arranged on the second connecting pipe (9-7); the PH detector (6), the acid liquor metering pump (9-6) and the alkali liquor metering pump (9-8) are all electrically connected to the controller (10).
2. The automotive anti-corrosion cooling system according to claim 1, characterized in that: and a chloride ion concentration sensor (8) electrically connected with the controller (10) is also arranged in the liquid outlet pipe (3).
3. The automotive anti-corrosion cooling system according to claim 1, characterized in that: the two ends of the purification component (4) in the liquid outlet pipe (3) are respectively provided with a first flow sensor (5) and a second flow sensor (7) which are electrically connected with the controller (10).
4. The automotive anti-corrosion cooling system according to claim 1, characterized in that: the cross-sectional area of the bypass channel is one half of the cross-sectional area of the housing (4-1).
5. The automotive anti-corrosion cooling system according to claim 1, characterized in that: the activated carbon filter layer (4-3) comprises a second interlayer surrounded by a stainless steel net, and activated carbon particles are filled in the second interlayer; the ion exchange resin layer (4-4) comprises a first interlayer surrounded by stainless steel meshes, and the first interlayer is filled with D201 resin.
6. The automotive anti-corrosion cooling system according to claim 1, characterized in that: the liquid inlet (1-4) and the pressure relief valve (1-5) are arranged on the first box body (1-1), the liquid outlet (1-8) is arranged on the second box body (1-2), and the valve (1-9) is arranged at the position of the liquid outlet (1-8).
7. The automotive anti-corrosion cooling system according to claim 1, characterized in that: the acid solution is a 20% dilute sulfuric acid solution, and the alkali solution is a 40% sodium hydroxide solution.
8. The automotive anti-corrosion cooling system according to claim 1, characterized in that: the cooling liquid comprises glycol and water, and the content of the cooling liquid is 30% -70%.
9. The automotive anti-corrosion cooling system according to claim 1, characterized in that: an alarm is arranged on the controller (10).
CN202210642366.3A 2022-06-08 2022-06-08 Automobile anti-corrosion cooling system Pending CN115075931A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116242892A (en) * 2023-05-11 2023-06-09 宁德时代新能源科技股份有限公司 Chloride ion concentration monitoring system and method, storage medium and electric automobile

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Publication number Priority date Publication date Assignee Title
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