CN1150085C - Method for making laminated shell fabric for all-weather clothes - Google Patents

Method for making laminated shell fabric for all-weather clothes Download PDF

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Publication number
CN1150085C
CN1150085C CNB991192141A CN99119214A CN1150085C CN 1150085 C CN1150085 C CN 1150085C CN B991192141 A CNB991192141 A CN B991192141A CN 99119214 A CN99119214 A CN 99119214A CN 1150085 C CN1150085 C CN 1150085C
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China
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fabric
surface layer
microporous membrane
laminated shell
production method
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Expired - Fee Related
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CNB991192141A
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CN1286163A (en
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张旭东
张建春
杨廷欣
郝新敏
王西亭
赵鹏程
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Technique Development Dept Military Supplies And Equipments Inst General
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Technique Development Dept Military Supplies And Equipments Inst General
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Abstract

The present invention relates to a method for making composite laminated surfacing materials for all-weather clothes, which comprises the following steps that firstly, coiled fabrics of a surface layer are installed on a coating machine so that the fabrics of the surface layer continuously pass through the coating machine; the speed of weaving is 5 to 50 meters / second; then, the coiled micropore films are installed on a film withdrawing machine arranged in front of a composition position, and the films are withdrawn at the speed of 5 to 50 meters / second. The fabrics of the surface layer, which are provided with adhesive agents, enter a composite device in a composite position after the fabrics of the surface layer are laminated with the micropore films at the equal speed; the fabrics and the micropore films are compounded into a whole body by laminating and processing of pyretic fumigation.

Description

A kind of production method that is used for the laminated shell fabric of all-weather clothes
Technical field
The present invention relates to a kind of production method that is used for the laminated shell fabric of all-weather clothes, this method be will have the microporous membrane of Waterproof Breathable effect through after the specially treated, carry out the compound garment material of making that has waterproof, uses under multi-functional, all weather conditions such as wet, windproof, warming thoroughly of lamination by adhesive and fabric.
Background technology
Twenty or thirty scribbled polyvinyl chloride, polyurethane, neoprene latex and various elastomeric top-weight fabric and is obtaining general application aspect the clothes of bad weather dress in year in the past.Although the clothes that these fabrics are made have been given superior rain proofness, and a spot of windproof property arranged, but can long-pending there be condensed water on the surface and uncomfortable feeling is arranged within it, this kind fabric moisture that human body can not be distributed constantly exhales in fact, promptly there is not poisture-penetrability, in the vigorous exercises such as outdoor sports such as march, operation, mountain-climbing, when wearing this class waterproof garment, because a large amount of sweat can't be discharged with vapor form, form condensed water at inner, make human body feel to glue discomfort such as wet, stuffy.Under mal-condition, wear air-locked clothes and climb the mountain, perspire to be difficult for discharge, freeze easily and freeze to death.This shows the importance of waterproof moisture permeating fabric.Regrettably, the waterproof fabric majority of China all is airtight not wet thoroughly at present, belong to low grade products, even being known as the coated fabric of energy Waterproof Breathable also is that light rain does not leak big rain drain, this is being subjected to considerable restraint aspect dress and the use, urgently the wait in expectation appearance of real waterproof moisture permeating fabric of people, although the external and domestic waterproof moisture permeating fabric that adopts microporous membrane to make that occurred in recent years, but owing to make the washing resistance performance of this fabric relatively poor in existing problem aspect Compound Machining and the adhesive, flexibility is relatively poor, and is especially more obvious in extremely cold area.
Summary of the invention
The purpose of this invention is to provide a kind of production method that is used for the laminated shell fabric of all-weather clothes, this method is to have the microporous membrane of waterproof, saturating wet, windproof performance, by the adhesive and the different process of different conditions, be compounded to form laminated fabric with different structure level with the variety classes fabric.
The object of the present invention is achieved like this:
A, the surface layer fabric of rolling is installed on the coating machine, makes the surface layer fabric continuously by apparatus for coating, the speed of described fabric is the 5-50 meter per second, and by apparatus for coating coating binder on described fabric, glue-spread is a 5-50 gram/rice 2Described surface layer fabric is cotton, hairs natural fabric, or terylene, nylon-type chemical fibre uni-material fabric, or blended fabric;
B, the microporous membrane of rolling is installed in moving back on the film machine before the compound station, moves back film by the speed of 5-50 meter per second, through sided corona treatment, the voltage of sided corona treatment is the 5-20 kilovolt to described microporous membrane earlier, and the time is 1-20 second; Described microporous membrane is the film of polytetrafluoroethylene (PTFE), polyester, polyurethanes;
C, at compound station, have the surface layer fabric of adhesive and microporous membrane constant speed and enter set composite after overlapping, handle being combined into one through lamination and heat baking, temperature that its heat baking is handled is 100-200 ℃, the best is 130-180 ℃, and the time that its heat baking is handled is 20-90 second.
Described adhesive is the PUR of modified polyvinylalcohol (EVA), low density polyethylene (LDPE) (LDPE), polyamide (PA), polyester (PES), polyurethane (PU) type, two point method by powder point, dusting, slurry point, slurry point and dusting combination is fixed on the fabric, its melting range is 100-170 ℃, the best is 120-160 ℃, and melt index is 15-30 gram/10 minutes.
Compared with the prior art the present invention has following advantage:
1, adopt laminated fabric that microporous membrane produced to have waterproof, multiple function such as saturating wet, windproof and warming, the clothes that utilize this lining to make have one-object-many-purposes.
2, adopt selected dry method or wet method combination process, easy to process, and can carry out the compound of the different numbers of plies according to final requirement, also can carry out compound with dissimilar fabrics.
3, adopt dissimilar PUR or adhesive, easy to use, effective, satisfy different occasion needs.Soft feel can use organic silicon adhesive if desired, can not harden even wear still under subzero 40 ℃ of conditions.
4, adopt physics or mechanical means water repellent fabric to be handled the adhesion strength that can improve fabric and film.
5, adopt the low microporous membranes such as polytetrafluoroethylene (PTFE) of Corona discharge Treatment surface tension can on the basis that does not reduce its proper property, reduce compound difficulty, strengthen the adhesion strength of compound fabric, improve the washing resistance performance of laminated fabric.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1, be schematic flow sheet of the present invention
Fig. 2, for using lining () schematic diagram that the present invention produced
Fig. 3, for using lining (two) schematic diagram that the present invention produced
The specific embodiment
Referring to Fig. 1, a kind of production method that is used for the laminated shell fabric of all-weather clothes the steps include:
A, the surface layer fabric of rolling is installed on the coating machine 1, makes the surface layer fabric pass through apparatus for coating continuously
2, this device is a pair of applicator roll, and the speed of described fabric is the 5-50 meter per second, and by apparatus for coating coating binder on described fabric, glue-spread is a 5-50 gram/rice 2
B, the microporous membrane of rolling is installed in moving back on the film machine 3 before the compound station, moves back film by the speed of 5-50 meter per second, through sided corona treatment, the voltage of sided corona treatment is the 5-20 kilovolt to described microporous membrane earlier, and the time is 1-20 second;
C, at compound station, have the surface layer fabric of adhesive and microporous membrane constant speed and enter set composite after overlapping, in this device, be provided with a baking oven 5, be provided with a pair of laminating roll 4 before this baking oven, also be provided with a pair of laminating roll 6 behind this baking oven, when adopting wet processing, selected adhesive is polyurethane (PU) glue and organic silica gel, and the laminating roll before the baking oven is not worked, heat baking is earlier handled, lamination treatment enters baking oven after surface layer fabric and microporous membrane are overlapping again, and hot pressing is carried out by the laminating roll behind the baking oven in the oven dry back, it is combined into one, the temperature that its heat baking is handled is 100-200 ℃, and the best is 130-180 ℃, and the time that its heat baking is handled is 20-90 second.The adhesive that wet method is selected should have moisture absorption preferably and poisture-penetrability, should have good physicochemical performance and cohesive force simultaneously.Particularly use organic silicon adhesive can make compound fabric have soft hand feeling, low temperature can not harden or chap yet, and can effectively keep the waterproof of compound fabric, wet and wind-proof warming performance thoroughly, is convenient to wear at Han Qu or utmost point Han Qu.The wet method spread is a 5-50 gram/rice 2, be preferably in 8-30 gram/rice 2When adopting dry process, laminating roll behind the baking oven is not worked, elder generation's lamination treatment after heat baking is handled, selected adhesive is the PUR of modified polyvinylalcohol (EVA), low density polyethylene (LDPE) (LDPE), polyamide (PA), polyester (PES), polyurethane (PU) type, two point method by powder point, dusting, slurry point, slurry point and dusting combination is fixed on the fabric, its melting range is 100-170 ℃, and the best is 120-160 ℃, and melt index is 15-30 gram/10 minutes.
Described microporous membrane can be films such as polytetrafluoroethylene (PTFE), polyester, polyurethane, this film has more micropore, they can stop raindrop to pass through, possesses fire resistance characteristic, and the hydrone that perspiration forms to human body does not hinder, possess wet characteristic, simultaneously air is had big resistance again, possess windproof, warming characteristic.By the formed film micropore of different processing technologys both can be symmetrical (being that the two sides pore size is the same), also can be asymmetric (being two sides pore size difference), its micropore both can be straight, also can be crooked, the pore size of micropore, pore-size distribution and percent opening directly influence water proofing property of the present invention, poisture-penetrability and wind-proof warming performance, other same cases, the aperture is big more, and water pressure resistance, wind-proof warming performance descend, and poisture-penetrability improves; Other same cases, pore-size distribution is wide more, water pressure resistance, wind-proof warming performance descend, other same cases, percent opening is big more, water pressure resistance, wind-proof warming performance descend, gas permeability improves, and suitable aperture should be preferably between the 0.1-1.0 micron between the 0.1-3.0 micron, average pore size should be between the 0.1-0.8 micron, be preferably in the 0.2-0.5 micrometer range, percent opening is preferably 45%-90% between 20-95%, such film resistance to hydrostatic pressure 〉=0.1 MPa (Mpa), vapor transfer rate 〉=1.0 * 10 4Grammeter 2Second, Air permenbility≤1.0 * 10 -2Gram/rice 2Second.
Embodiments of the invention two are the dry process that produce on the basis of the above, the adhesive that this technology is selected for use is modified polyvinylalcohol (EVA), low density polyethylene (LDPE) (LDPE), polyamide (PA), polyester (PES), the PUR of polyurethane (PU) type, by the powder point, dusting, the slurry point, the two point method of slurry point and dusting combination is fixed on the described surface layer fabric, earlier by baking oven with oven dry of the PUR on the described fabric or fusion after, make the band adhesive plaster, to carry out hot pressing compound with above-mentioned microporous membrane then, the PUR that is fit to this method should have water-wash resistance and dry cleaning resistance, its melting range is 100-170 ℃, the best is 120-160 ℃, and melt index is 15-30 gram/10 minutes.Can use meal (granularity≤80 orders), middle powder (granularity is the 80-200 order), fine powder (granularity 〉=200 orders) according to arts demand.For dry method, suitable spread is a 5-50 gram/rice 2, be preferably in 8-30 gram/rice 2
The adhesive that embodiments of the invention three are selected for use is the PUR of modified polyvinylalcohol (EVA), low density polyethylene (LDPE) (LDPE), polyamide (PA), polyester (PES), polyurethane (PU) type, this PUR is made the hot melt net through meltblown earlier, or hot melt adhesive film is punched.And then be clipped between surface layer fabric and the microporous membrane through hot pressing with the hot melt net or through the hot melt adhesive film of punching and be composited.
For three layers of laminated fabric, can adopt twice dry method or twice wet method combination process, also can adopt technology dried, the wet method combination.
Be applicable to all-weather clothes with the fabric of laminated shell fabric, can adopt woven fabric or knitted fabric, also can adopt nonwoven or flocculus according to the difference of purposes.Used fabric can be natural fibers such as cotton, hair, or chemical fibres such as terylene, nylon are pure spins or blended fabric, as outer fabric, preferably uses woven fabric.For improving the water proofing property of fabric, the surface layer fabric should pass through water repellent finish.Water repellent finish both can be carried out before compound, also can carry out after compound.The fabric of compound prefinishing is because surface tension is lower, combine uniformity and fastness in order to improve with microporous barrier closes lamination, can carry out physics or mechanical surface treatment earlier, physical method is a fabric process sided corona treatment, and mechanical means is about to the fabric sanding, also can two kinds of methods all adopt, during the fabric sided corona treatment, the voltage of sided corona treatment is the 5-20 kilovolt, and the time is 1-20 second, for the water treatment of refusing of fabric behind the lamination, can adopt the Collator Mode of single face feeding.Water repellent finishing agent can be selected Organic fluoride or organosilicon water repellent as required for use, and arrangement will reach refuses water more than 4 grades.
For the lower microporous membrane of surface tension especially microporous teflon membran, for the ease of laminated, improve simultaneously with fabric compound after washing resistance performance, in the waterproof of not destroying film, thoroughly on the wet and windproof performance basis, can adopt corona discharge technology to improve the surface tension of film.During the microporous barrier sided corona treatment, the voltage of sided corona treatment is the 5-20 kilovolt, and the time is 1-20 second.
Referring to laminated shell fabric shown in Figure 2, be composited by surface layer fabric 101, adhesive phase 201 and microporous membrane 301, laminated shell fabric shown in Figure 3, by surface layer fabric 101, adhesive phase 201 microporous membranes 301, adhesive phase and in material 401 be composited, both can be two-layer compound as all-weather clothes with laminated shell fabric, also can be three layers or more multi-layered compound fabric, can adopt woven fabric and knitted fabric to carry out different collocation and use.In clothes, both can use separately, also can be used as surface layer or nexine and cooperate other fabrics or wadding product to use.
The lamination lining that said method is produced, by the relative national standards test, its resistance to hydrostatic pressure reaches 40-120 kPa (Kpa), gets wet greater than level Four, and Air permenbility is less than 1.0 * 10 -2Gram/rice 2Second, vapor transfer rate is greater than 4.0 * 10 3Gram/rice 2Second, the splitting brute force is greater than 5.0 newton/2.5 centimetre, and the washing machine continuous washing did not have and bubbles and lamination after 500 minutes.
Above-mentioned laminated fabric can also be used for aspects such as shoes and hats, gloves, tent, sleeping bag, knapsack except that as the clothes such as gym suit, raincoat, warm-up, wind coat, special working suit.

Claims (5)

1, a kind of production method that is used for the laminated shell fabric of all-weather clothes is characterized in that:
A, the surface layer fabric of rolling is installed on the coating machine, makes the surface layer fabric continuously by apparatus for coating, the speed of described fabric is the 5-50 meter per second, and by apparatus for coating coating binder on described fabric, glue-spread is a 5-50 gram/rice 2; Described surface layer fabric is cotton, hairs natural fabric, or terylene, nylon-type chemical fibre uni-material fabric, or blended fabric;
B, the micropore book film of rolling is installed in moving back on the film machine before the compound station, moves back film by the speed of 5-50 meter per second, through sided corona treatment, the voltage of sided corona treatment is the 5-20 kilovolt to described microporous membrane earlier, and the time is 1-20 second; Described microporous membrane is the film of polytetrafluoroethylene (PTFE), polyester, polyurethanes;
C, at compound station, have the surface layer fabric of adhesive and microporous membrane constant speed and enter set composite after overlapping, handle being combined into one through lamination and heat baking, temperature that its heat baking is handled is 100-200 ℃, the best is 130-180 ℃, and the time that its heat baking is handled is 20-90 second.
2, the production method that is used for the laminated shell fabric of all-weather clothes according to claim 1, it is characterized in that: described adhesive is the PUR of modified polyvinylalcohol (EVA), low density polyethylene (LDPE) (LDPE) polyamide (PA), polyester (PES), polyurethane (PU) type, two point method by powder point, dusting, slurry point, slurry point and dusting combination is fixed on the fabric, its melting range is 100-170 ℃, the best is 120-160 ℃, and melt index is 15-30 gram/10 minutes.
3, the production method that is used for the laminated shell fabric of all-weather clothes according to claim 1, it is characterized in that: described adhesive is polyurethane (PU) glue and organic silica gel, earlier it is coated the surface layer fabric face, cover microporous membrane then, carry out hot pressing after the oven dry.
4, the production method that is used for the laminated shell fabric of all-weather clothes according to claim 1, it is characterized in that: described adhesive is the PUR of modified polyvinylalcohol (EVA), low density polyethylene (LDPE) (LDPE), polyamide (PA), polyester (PES), polyurethane (PU) type, and this PUR is made the hot melt net through meltblown.
5, the production method that is used for the laminated shell fabric of all-weather clothes according to claim 1 and 2 is characterized in that: through sided corona treatment, the voltage of sided corona treatment is the 5-20 kilovolt to described surface layer fabric earlier, and the time is 1-20 second.
CNB991192141A 1999-08-26 1999-08-26 Method for making laminated shell fabric for all-weather clothes Expired - Fee Related CN1150085C (en)

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