CN114989715A - Low-VOC high-fullness environment-friendly PU (polyurethane) gloss top-coat paint - Google Patents
Low-VOC high-fullness environment-friendly PU (polyurethane) gloss top-coat paint Download PDFInfo
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- CN114989715A CN114989715A CN202210797759.1A CN202210797759A CN114989715A CN 114989715 A CN114989715 A CN 114989715A CN 202210797759 A CN202210797759 A CN 202210797759A CN 114989715 A CN114989715 A CN 114989715A
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- leveling agent
- hexamethylene diisocyanate
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- 239000004814 polyurethane Substances 0.000 title claims abstract description 28
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 8
- 239000003973 paint Substances 0.000 title abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000007787 solid Substances 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 12
- 229930195729 fatty acid Natural products 0.000 claims abstract description 12
- 239000000194 fatty acid Substances 0.000 claims abstract description 12
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 12
- -1 fluorine modified acrylate Chemical class 0.000 claims abstract description 12
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 11
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 11
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 9
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims abstract description 7
- 238000010276 construction Methods 0.000 claims description 18
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 11
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000013638 trimer Substances 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- 239000013530 defoamer Substances 0.000 claims 2
- 239000002966 varnish Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 21
- 239000003960 organic solvent Substances 0.000 abstract description 8
- 229910052731 fluorine Inorganic materials 0.000 abstract description 7
- 239000011737 fluorine Substances 0.000 abstract description 7
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 6
- 229920000570 polyether Polymers 0.000 abstract description 6
- 229910052710 silicon Inorganic materials 0.000 abstract description 6
- 239000010703 silicon Substances 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 5
- 238000005507 spraying Methods 0.000 abstract description 4
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004132 cross linking Methods 0.000 abstract description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000012855 volatile organic compound Substances 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 206010027627 Miliaria Diseases 0.000 description 8
- 201000004169 miliaria rubra Diseases 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000009965 odorless effect Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to the technical field of coatings, and particularly relates to a low-VOC high-fullness environment-friendly PU (polyurethane) gloss clear finish. The synthetic fatty acid resin with high solid content and low viscosity and the hexamethylene diisocyanate based polyisocyanate selected by the invention can reduce the use of organic solvents and reduce VOC. The high-solid-content low-viscosity synthetic fatty acid resin has high hydroxyl content, the hexamethylene diisocyanate group polyisocyanate has high isocyanate group content, the cross-linking density of the hexamethylene diisocyanate group polyisocyanate is high after the hexamethylene diisocyanate group polyisocyanate and the hexamethylene diisocyanate group polyisocyanate react, and the chemical resistance is improved. Three leveling agents are used in a matched manner, so that the flatness of the surface of the whole paint film is improved. The invention uses cyclohexanone and butyl ester as solvents, reduces the addition of triphenyl, and is more environment-friendly. The invention uses the acrylate flatting agent, the fluorine modified acrylate flatting agent and the polyether modified organic silicon flatting agent in a matching way, and can also solve the problem of the flatting property of high-viscosity spraying.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a low-VOC high-fullness environment-friendly PU (polyurethane) bright clear finish.
Background
The paint is a continuous solid film which is coated on the surface of an object to be protected or decorated and can form firm adhesion with the object to be coated, also called paint film or coating, and is a viscous liquid which is usually prepared by taking resin or oil or emulsion as a main material, selectively adding pigment, filler and corresponding auxiliary agents and using organic solvent or water. The coatings can be classified into different categories according to different classification methods, wherein the coatings can be classified into: solvent-based coatings, water-based coatings, powder-based coatings, high-solids coatings, metallic coatings, pearlescent coatings, and solventless coatings; the coating can be classified into a matt coating, a flat coating, a matte coating and a high gloss coating (also called a bright coating) according to the brightness of the appearance of the coating film.
Nowadays, the requirement for environmental protection is getting higher, and the requirement for environmental protection is becoming more and more trend to realize low VOC of oil paint. Meanwhile, for the full-bright furniture products, the Chinese people still love the products with high fullness.
The existing oil paint still has various problems during construction under low VOC and high solid content, such as construction viscosity problem, construction compatibility, balance of leveling property and defoaming property after construction, and the like. One of the obvious differences in GB18581-2020 over GB18581-2009 is also the reduction in the use of triphenyl.
Therefore, how to provide a coating which has good workability under the conditions of high fullness and low VOC and does not contain benzene solvents is a technical problem to be solved at present.
Disclosure of Invention
The invention aims to provide a low-VOC high-fullness environment-friendly PU (polyurethane) bright clear finish. Especially, the effects of high fullness and good construction performance are realized under the conditions of no benzene solvent and low VOC.
The technical scheme adopted by the invention for solving the problems is as follows:
the low-VOC high-fullness environment-friendly PU (polyurethane) bright clear finish is characterized by comprising a component A and a component B;
the component A comprises the following components in parts by weight: 75-90 parts of high-solid content synthetic fatty acid resin, 5-18 parts of cyclohexanone, 4-6 parts of butyl ester, 0.1-0.9 part of flatting agent and 0.5-1 part of defoaming agent;
the component B comprises the following components in parts by weight: 25-40 parts of butyl ester, 50-56 parts of toluene diisocyanate and 10-20 parts of hexamethylene diisocyanate based polyisocyanate.
Further, the solid content of the high-solid content synthetic fatty acid resin is 85-99%, and the viscosity is lower than 18000MPa s/25 ℃. Compared with the conventional resin, the high-solid-content synthetic fatty acid resin and the hexamethylene diisocyanate based polyisocyanate have high solid content but low viscosity, can reduce the addition of organic solvent during construction, reduce the discharge amount of VOC (volatile organic compounds), realize high-solid-content construction, and finally achieve the effect of high fullness, wherein the film thickness of a paint film can reach more than 40 mu m.
Preferably, the toluene diisocyanate is at least one of a toluene diisocyanate trimer and a toluene diisocyanate adduct. Toluene diisocyanate with a solids content of more than 50% is preferred.
Further, the mass ratio of the component A to the component B is 1 (0.9-1.1), and the component A and the component B are mixed according to the mass ratio during construction.
Further, the defoaming agent is a polysiloxane defoaming agent. The polysiloxane antifoaming agent has strong foam breaking capability, and can well solve the foaming problem during high-viscosity spraying. Thereby generating the paint film effect of no prickly heat and dark bubbles.
Further, the leveling agent is at least one of an acrylate leveling agent, a fluorine modified acrylate leveling agent and a polyether modified organic silicon leveling agent.
Preferably, the leveling agent is 0.1-0.5 part of acrylate leveling agent, 0.1-0.3 part of fluorine modified acrylate leveling agent and 0.05-0.1 part of polyether modified organic silicon leveling agent.
Further, the mass ratio of the component A to the component B is 1 (0.9-1.1). When in construction, the components are mixed and used according to a proportion, other organic solvents are not needed to be used as diluents, and the construction solid content can reach more than 58 percent.
The invention has the beneficial effects that:
the invention provides a low-VOC high-fullness environment-friendly PU (polyurethane) bright clear finish, which is characterized in that the selected high-solid-content low-viscosity synthetic fatty acid resin and hexamethylene diisocyanate based polyisocyanate can reduce the use of organic solvents and reduce the discharge amount of VOC, the high-solid-content low-viscosity synthetic fatty acid resin has high hydroxyl content, the hexamethylene diisocyanate based polyisocyanate has high isocyanate group content, the cross-linking density of the two is high after the two react, and the chemical resistance is improved. Three leveling agents are used in a matched manner, so that the flatness of the surface of the whole paint film is improved.
The invention also uses cyclohexanone and butyl ester as solvents, reduces the addition of triphenyl, and is more environment-friendly.
The invention also uses the acrylate flatting agent, the fluorine modified acrylate flatting agent and the polyether modified organic silicon flatting agent in a matching way, and can solve the problem of the flatting property of high-viscosity spraying. The polyether modified organic silicon leveling agent can lower the surface tension strongly, realize rapid short wave leveling, float to the surface and improve the hand feeling and scratch resistance; the acrylate leveling agent and the fluorine modified acrylate leveling agent are long-wave leveling agents, and the late-stage slow leveling effect of the coating can be realized. In the PU gloss clear finish paint provided by the invention, the dryness is slower than that of the conventional PU gloss clear finish paint, and enough time is provided for the acrylate flatting agent and the fluorine modified acrylate flatting agent to play a role, so that the flat paint film effect of the product is achieved.
The polysiloxane antifoaming agent used in the invention has strong foam breaking capability, and can well solve the foaming problem in high-viscosity spraying. Thereby generating the paint film effect of no prickly heat and dark bubbles.
Detailed Description
The present invention will be described in detail with reference to examples, which are only preferred embodiments of the present invention and are not intended to limit the present invention.
The invention is applied to 2 examples and 1 comparative formula table of the component A of the low-VOC high-fullness environment-friendly PU bright clear finish paint when being applied to construction on wood furniture, and the preparation method is conventional mixing and stirring in the field. (unit: parts by weight)
TABLE 1,
| Component A | Example a1 | Example a2 | Example a3 | Example a4 | Comparative example a1 |
| 90% solids synthetic fatty acid resin | 75 | 80 | / | / | / |
| 85% solid content synthetic fatty acid resin | / | / | 90 | 82 | / |
| 80% solids conventional synthetic fatty acid resin | / | / | / | / | 76 |
| Cyclohexanone | 18 | 13 | 5 | 11.2 | 7.6 |
| Butyl ester | 6 | 5.7 | 4 | 5.5 | 5.5 |
| Xylene | / | / | / | / | 10 |
| Acrylate leveling agent | 0.5 | 0.1 | 0.3 | 0.3 | 0.3 |
| Fluorine modified acrylate leveling agent | 0.1 | 0.3 | 0.15 | 0.3 | / |
| Polyether modified organic silicon flatting agent | 0.1 | 0.1 | 0.05 | 0.05 | 0.1 |
| Polymer defoaming agent | / | / | / | / | 0.5 |
| Polysiloxane antifoaming agent | 0.5 | 0.5 | 0.5 | 0.5 | / |
Table 2 shows B component 1 example and a comparative example, prepared by mixing and stirring as is conventional in the art. (unit: parts by weight)
| B component | Example b1 | Example b2 | Comparative example b1 |
| Xylene | / | / | 5 |
| Butyl ester | 40 | 25 | 31 |
| Hexamethylene diisocyanate based polyisocyanate | 10 | 20 | / |
| 50% solids toluene diisocyanate trimer | 12 | 16 | 8 |
| 75% solids toluene diisocyanate adduct | 46 | 34 | 56 |
Testing various performances of the spray plate after oil adjustment, testing the construction VOC content according to the regulation in GB18581-2020 (GB/T23985-; the low VOC high-fullness environment-friendly PU bright and clear surface of the invention during construction has various performances of 5 examples and 1 comparative example, and the test results are shown in the following table:
| test items | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Comparative example 1 |
| Construction ratio | Example a 1: example b1= 1:1 | Example a 2: example b1= 1:0.9 | Example a 1: example b2= 1:1.1 | Example a 3: example b1= 1:1 | Example a 4: example b1= 1:0.9 | Comparative example a 1: comparative example b 1: organic solvent Agent =1:1:0.6 |
| Dilute seconds/rock field 2# Cup, 30 deg.C | 22 second 75 | 23 seconds 22 | 23 seconds 01 | 22 seconds 45 | 21 second 45 | 10 seconds 60 |
| Construction anchor | 58% | 60% | 60% | 60.3% | 59.2% | 41% |
| Construction VOC content (g/L) | 415 | 396 | 394 | 386 | 398 | 596 |
| Test substrate | Benefit-keeping board | Health care board | Benefit-keeping board | Benefit-keeping board | Health care board | Benefit-keeping board |
| Surface dryness/30 deg.C | 50min | 55min | 60min | 53min | 53min | 36min |
| Pressed dry/30 deg.C | 5h30min | 6h | 6h20min | 5h40min | 5h40min | 3h |
| Leveling property | The surface is flat and the leveling property is good | The surface is flat and the leveling property is good | The surface is flat and the leveling property is good | The surface is flat and the leveling property is good | The surface is flat and the leveling property is good | The surface is flat and the leveling property is good |
| Gloss of | 97.5-98 | 98.5-99 | 97-98 | 98-99 | 98-99 | 100-101 |
| Adhesion (lattice drawing method) | Level 1 | Level 1 | Level 1 | Level 1 | Level 1 | Level 1 |
| Film thickness of paint film | 50μm | 54μm | 54μm | 52μm | 51μm | 30μm |
| Effect of panel | Smooth, high transparency and no prickly heat Zi, Lu bubble | Smooth, high transparency and no prickly heat Seed, dark bubble | Smooth, high transparency and no prickly heat Zi, Lu bubble | Smooth, high transparency and no prickly heat Zi, Lu bubble | Smooth, high transparency and no prickly heat Zi, Lu bubble | Smooth, high transparency, no prickly heat and darkness Bubble |
| Smell of paint film | Substantially odorless | Substantially odorless | Substantially odorless | Substantially odorless | Substantially odorless | Substantially odorless |
| Hardness at night | B | B | B | B | B | HB |
| Hardness after 4 days | H | H | H | H | H | H |
The formulation of the comparative example needs to solve the problems of leveling and defoaming after being diluted by an organic solvent, and can be normally constructed for subsequent tests. As can be seen from the test results of the comparative examples, the PU gloss top-coat prepared according to the formula of the invention in examples 1-5 does not need benzene organic solvents, has high construction solid content and low VOC, and can keep high fullness.
The preferred embodiments of the present invention have been described in detail, however, the present invention is not limited to the specific details of the above embodiments, and various simple modifications may be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are all within the protection scope of the present invention.
It should be noted that the various features described in the foregoing embodiments may be combined in any suitable manner without contradiction. The invention is not described in detail in order to avoid unnecessary repetition.
In addition, any combination of the various embodiments of the present invention is also possible, and the same should be considered as the disclosure of the present invention as long as it does not depart from the spirit of the present invention.
Claims (8)
1. The low-VOC high-fullness environment-friendly PU (polyurethane) bright clear finish is characterized by comprising a component A and a component B;
the component A comprises the following components in parts by weight: 75-90 parts of high-solid content synthetic fatty acid resin, 5-18 parts of cyclohexanone, 4-6 parts of butyl ester, 0.1-0.9 part of flatting agent and 0.5-1 part of defoaming agent;
the component B comprises the following components in parts by weight: 25-40 parts of butyl ester, 50-56 parts of toluene diisocyanate and 10-20 parts of hexamethylene diisocyanate based polyisocyanate.
2. The PU gloss clear finish according to claim 1, wherein the high solid content synthetic fatty acid resin solid content is 85% -99%, and the viscosity is lower than 18000 MPa-s/25 ℃.
3. The PU top-coat according to claim 1, wherein the toluene diisocyanate is at least one of a toluene diisocyanate trimer and a toluene diisocyanate adduct.
4. The PU gloss clear finish according to claim 1, wherein the mass ratio of the component A to the component B is 1 (0.9-1.1).
5. The PU gloss clear finish according to claim 3, wherein the component A and the component B are mixed in the mass ratio during construction.
6. The PU gloss varnish according to claim 1, wherein the defoamer is a polysiloxane defoamer.
7. The PU gloss clear finish according to claim 1, wherein the leveling agent is at least one of an acrylate leveling agent, a fluorine-modified acrylate leveling agent, and a polyether-modified silicone leveling agent.
8. The PU top-coat according to any one of claims 1 to 7, wherein the leveling agent is 0.1 to 0.5 part of acrylate leveling agent, 0.1 to 0.3 part of fluorine-modified acrylate leveling agent, and 0.05 to 0.1 part of polyether-modified silicone leveling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210797759.1A CN114989715A (en) | 2022-07-08 | 2022-07-08 | Low-VOC high-fullness environment-friendly PU (polyurethane) gloss top-coat paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210797759.1A CN114989715A (en) | 2022-07-08 | 2022-07-08 | Low-VOC high-fullness environment-friendly PU (polyurethane) gloss top-coat paint |
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| Publication Number | Publication Date |
|---|---|
| CN114989715A true CN114989715A (en) | 2022-09-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210797759.1A Pending CN114989715A (en) | 2022-07-08 | 2022-07-08 | Low-VOC high-fullness environment-friendly PU (polyurethane) gloss top-coat paint |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418417A (en) * | 2017-08-30 | 2017-12-01 | 展辰新材料集团股份有限公司 | A kind of polyurethane Brilliant white paint |
| CN107502172A (en) * | 2017-08-30 | 2017-12-22 | 展辰新材料集团股份有限公司 | A kind of polyurethane glossy varnish |
| CN109627957A (en) * | 2018-10-31 | 2019-04-16 | 澳达树熊涂料(惠州)有限公司 | A kind of plentiful color inhibition showering glossy varnish coating of PU high and preparation method thereof |
| CN113897127A (en) * | 2021-11-11 | 2022-01-07 | 亚士创能科技(上海)股份有限公司 | Polyurethane bright white finish and preparation method and application thereof |
-
2022
- 2022-07-08 CN CN202210797759.1A patent/CN114989715A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418417A (en) * | 2017-08-30 | 2017-12-01 | 展辰新材料集团股份有限公司 | A kind of polyurethane Brilliant white paint |
| CN107502172A (en) * | 2017-08-30 | 2017-12-22 | 展辰新材料集团股份有限公司 | A kind of polyurethane glossy varnish |
| CN109627957A (en) * | 2018-10-31 | 2019-04-16 | 澳达树熊涂料(惠州)有限公司 | A kind of plentiful color inhibition showering glossy varnish coating of PU high and preparation method thereof |
| CN113897127A (en) * | 2021-11-11 | 2022-01-07 | 亚士创能科技(上海)股份有限公司 | Polyurethane bright white finish and preparation method and application thereof |
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Application publication date: 20220902 |