CN1149612A - Collecting oil agent composition - Google Patents
Collecting oil agent composition Download PDFInfo
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- CN1149612A CN1149612A CN 95112179 CN95112179A CN1149612A CN 1149612 A CN1149612 A CN 1149612A CN 95112179 CN95112179 CN 95112179 CN 95112179 A CN95112179 A CN 95112179A CN 1149612 A CN1149612 A CN 1149612A
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- agent composition
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- carboxylic acid
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Abstract
The collecting oil agent used for overflow of diesel oil is composed of (mass percentage) 1%-10% of natural carboxylic acid and 90-99% of alcoholic or kerosene organic solvent. The collecting oil agent used for overflow of crude oil is composed of (by mass percentage) 1%-10% of natural carboxylic acid and polyoxyethylene oleate and 90-99% of the above mentioned organic solvent. The invented composite features simple for making, convenient for applying, low cost and good result for collecting oil.
Description
The present invention relates to a kind of oil-collecting agent that is used for marine oil overflow, belong to the chemical composition technical field.
The oil spilling that offshore oil exploitation and transportation usually cause because of accident or other technologies reason, this not only causes enormous economic loss to enterprise, but also can cause serious environmental to pollute.Processing to oil spilling generally has physics method, chemical method and the combination of the two.The physics method uses mechanical fence with the oil spilling corral, with sorbent material or pump oil spilling is reclaimed again; Chemical method adopts oil-treatment agent that oil spilling is carried out chemical treatment, and then row reclaims.Oil treatment comprises oil-collecting agent, sinking agent, peptizer, emulsifying dispersant etc.After the marine oil overflow accident took place, normal conditions were to be that very fast diffusion is carried out at the center with the accident spot, will cover areas tens thousand of or thousands of square metres in several hours.Form the oil spilling layer that thickness is about 0.1mm in seawater surface, be difficult to reclaim with general physical or chemical process.So the processing top priority of marine oil overflow is to prevent the oil spilling diffusion, be convenient to further remove and reclaim.Adopt mechanical fence with the method for oil spilling trap in certain zone, its equipment complexity operate cumbersomely, and will finish in the very short time after the accident generation generally is to be difficult to realization for this reason, and the oil-collecting effect is undesirable.Oil-collecting agent based on tensio-active agent, can reduce the surface tension of seawater, form insoluble monolayer in seawater surface, when it is sprawled pressure and presses greater than sprawling of oil, just produce the reactive force of an inhibited oil diffusion, make oil spill area that the trend of dwindling be arranged, and control the diffusion of oil spilling effectively, this effect is referred to as chemical fence.Dwindle and to keep a few hours though pasta is long-pending, won valuable time for using mechanical fence or mechanical treatment.The general consumption of oil-collecting agent seldom, it is very fast to take effect, and become to use other chemical agents, and the physics method is handled the necessary prerequisite of oil spilling.
Nineteen forty-three United States Patent (USP) U.S.Pat.2,447,551 disclose a kind of oil-collecting agent, major ingredient is the oxyhydroxide of liquid aliphatic acid esters and sugar and sugared derivative, requirement does not have clear and definite effect being lower than 40 uses down, and this has limited the practical application of this oil-collecting agent widely.United States Patent (USP) U.S.Pat 3 in 1974,810,835 disclose some oil-collecting agent, are tensio-active agent with alkylamide, alkyl glycol, thiazolinyl ethylene glycol, alkyl propylene glycol ester, alkyl acid polyoxyethylene glycol ester etc., are equipped with ethoxy ethanol, two acetaldehyde, Virahol equal solvent.Its experiment is carried out in fresh water, does not relate to holding time of compression oil film, and raw materials used more expensive, and is unsuitable practical.
Japan's " technological development of public hazards countermeasure " is magazine (1976 (P.P.M), 5,1-30) delivered and obtained former-" marine oil overflow processing " literary composition that Fang showed, chemical processing agent has wherein used two kinds of tensio-active agents of polyvinyl alcohol, glycerol mono-laurate of butter fat, experimental result is that the crude oil oil spill area dwindles about 70%, have only 2.5 hours but hold time, and this treatment agent price is expensive, is unsuitable for practicality.At China's " marine environmental sciences " magazine (1986,5 (4), 58) delivered " the marine oil overflow treatment agent " of works such as Liu Chunhua on, 47 kinds of tensio-active agents estimated in article, think that can be used for the oil-collecting agent has five kinds: span-20 (sorbitan mono-laurate), span-80 (sorbitan monooleate), oleyl alcohol, tallow fatty acid-polyoxyethylene glycol, the glycerol mono laurate.This article does not provide concrete application example, and the oil-collecting effect is also had no way of as can be known.In sum, also do not have a kind of ideal at present, inexpensive makes known publicly with effective oil spilling oil-collecting agent.
The objective of the invention is to remedy the deficiency of prior art, a kind of convenience, cheap, diesel oil or crude oil oil spilling oil-collecting agent efficiently are provided.
Oil-collecting agent constituent prescription of the present invention is as follows:
I. the oil-collecting agent component A that is used for the diesel oil oil spilling: the natural carboxylic acid, (25 ℃) are brown viscous liquid under the room temperature, purity＞95%.Can from
The Vegetable oil lipoprotein tankage extract with ordinary method.Component B: alcohols or kerosene organic solvent, technical grade.
Wherein, A component 1～10% mass percent, B component 90～99% mass percents.With A component 3～5%, B component 95～97% is good.
II. be used for the oil-collecting agent of crude oil
Component A, B are the same, and increase component C: polyoxyethylene oleate, wherein the mole number of oxyethane is 400～800, can be expressed as P (EO)
400～800Oleic acid ester, this component normal temperature and pressure are liquid down, and the purity requirement technical grade gets final product.
Concrete proportioning is:
A: C=(3～5): (3～5) (mass ratio), (A+B) two component mass percents are 1～10%, B component 90～99%.With (A+B)) two components are 3～5%, the B component is 95～97% for good.
Earlier component A and C are mixed in proportion, add a certain proportion of solvent B then.
Consider factors such as cost and pollution, component B is best with ethanol, and C is with P (EO)
400Oleic acid ester is best.
Methods such as conventional stirring, dissolving are adopted in the preparation of the present composition, and finished product is stable homogeneous solution, is light brown.
Present composition I is used for the oil-collecting of marine diesel oil oil spilling, under conditions such as different temperature, salinity, PH, oil reservoir is shunk rapidly in the short period of time, dwindle area and reach more than 70%, and keep interface stability and reach more than 6 hours environmentally safe.Present composition II is used for the oil-collecting of marine crude oil oil spilling, under conditions such as different temperature, salinity, PH, all can dwindle more than 55% making the oil reservoir area in the short time, and keep interface stability more than 6 hours, same environmentally safe.
Below in conjunction with embodiment the present invention is further described.Embodiment 1. collecting oil agent composition I 100 grams
The A natural carboxylic acid, purity 98%, 1 gram
B ethanol, technical grade, 99 grams
Test apparatus, 55 * 5 * 5 (cm)
3The synthetic glass tank is equipped with the seawater of certain specification in the groove.
A, B two components mix at normal temperatures and are finished product.Getting one of this finished product (0.02 gram) joins the surface and has sprawled 10m1, diesel oil (0
#) the seawater groove in, (salinity is 25 ‰, and PH8.3), 25 ℃ of observationss of room temperature are as follows: in the several seconds, the diesel oil layer length of side shortens 45cm, and it is long-pending 81.8% to be equivalent to dwindle the diesel oil aspect, and kept 7 hours at the interface.Change salinity, PH, the temperature of seawater, to the influence such as the table one of diesel oil oil spilling.
The salinity of table one, seawater, PH, temperature are to the influence of diesel oil oil spilling
Embodiment 2. collecting oil agent composition I 100 grams
The A natural carboxylic acid, purity 95% 9 grams
B ethanol, technical grade 91 grams
Other dwindle 83% with embodiment 1. effect areas, keep 7 hours.Embodiment 3. collecting oil agent composition I 100 grams
The A natural carboxylic acid, purity 96% 5 grams
B ethanol, technical grade 95 grams
Other are with embodiment 1, and the effect area dwindles 82%, keep 7 hours.Embodiment 4. collecting oil agent composition II 100 grams
The A natural carboxylic acid, purity 95% 1 grams
B ethanol, technical grade 98 grams
C P (EO)
400Oleic acid ester technical grade 1 gram
Earlier A and C are mixed, dissolve among the B again, stirring gets final product.Get 1 about 0.02 gram of finished product, join the surface and sprawled in the seawater circular groove of 80mol crude oil (circular groove diameter 35cm).Crude oil is provided by No. two oil gathering station of Shengli Oil Field.Under different temperature, salinity and pH value, all reaching and dwindling the crude oil area is more than 55.6%, keeps interface stability more than 6 hours.The results are shown in table two.
The salinity of table two, seawater, PH thermometric degree are to the influence of crude oil
Embodiment 5. collecting oil agent composition II 100 grams
The A natural carboxylic acid, purity 95% 5 grams
B ethanol, technical grade 92 grams
C P (EO)
400Oleic acid ester, technical grade 3 grams
Other are all with embodiment 4, and its effect makes crude oil dwindle area above 55.6%, keeps the interface more than 6 hours.Embodiment 6. collecting oil agent composition II 100 grams
The A natural carboxylic acid, purity 95% 1.5 grams
B ethanol, technical grade 96 grams
C P (EO)
400Oleic acid ester, technical grade 2.5 grams
Other are all with embodiment 4, and the effect that the crude oil area dwindles surpasses 55.6%, keeps the boundary more than 6 hours.
Claims (6)
1. a collecting oil agent composition that is used for the diesel oil oil spilling is characterized in that, is that the alcohols or the kerosene organic solvent of 1%～10% natural carboxylic acid and 90～99% formed by mass percent.
2. the collecting oil agent composition that is used for the diesel oil oil spilling as claimed in claim 1 is characterized in that, is that 3%～5% natural carboxylic acid and 95%～97% organic solvent are formed by mass percent.
3. the collecting oil agent composition that is used for the diesel oil oil spilling as claimed in claim 1 is characterized in that described organic solvent is an ethanol.
4. collecting oil agent composition that is used for the crude oil oil spilling, it is characterized in that, form by natural carboxylic acid, polyoxyethylene oleate and alcohols or kerosene organic solvent, wherein, the mass ratio of natural carboxylic acid and polyoxyethylene oleate is (3～5): (3～5), the shared mass percent of its sum of the two is 1%～10%, and organic solvent is 90～99%.
5. the collecting oil agent composition that is used for the crude oil oil spilling as claimed in claim 4 is characterized in that, the number of moles of ethylene oxide in the described polyoxyethylene oleate is 400～800.
6. the collecting oil agent composition that is used for the crude oil oil spilling as claimed in claim 4 is characterized in that described organic solvent is an ethanol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95112179A CN1055299C (en) | 1995-10-27 | 1995-10-27 | Collecting oil agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95112179A CN1055299C (en) | 1995-10-27 | 1995-10-27 | Collecting oil agent composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99112499 Division CN1073612C (en) | 1999-10-22 | 1999-10-22 | Oil-collecting agent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1149612A true CN1149612A (en) | 1997-05-14 |
| CN1055299C CN1055299C (en) | 2000-08-09 |
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ID=5079379
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95112179A Expired - Fee Related CN1055299C (en) | 1995-10-27 | 1995-10-27 | Collecting oil agent composition |
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| Country | Link |
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| CN (1) | CN1055299C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100376654C (en) * | 2003-04-23 | 2008-03-26 | 广州南沙经济技术开发区高奇环保技术有限公司 | Agglutinant for leaking oil and fabricating method |
| WO2012028031A1 (en) * | 2010-08-31 | 2012-03-08 | 广东标美硅氟新材料有限公司 | A compounded oil outflow round-up agent, a reocess for its production and its use |
| CN102417215A (en) * | 2010-09-28 | 2012-04-18 | 广东标美硅氟新材料有限公司 | Method for recovering spilled oil in water area |
| CN101831276B (en) * | 2009-03-10 | 2012-10-31 | 长江大学 | Water-based oil dispersant for eliminating floating oil on sea surface and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1379222A (en) * | 1972-01-28 | 1975-01-02 | British Petroleum Co | Emulsifying composition |
| GB1419803A (en) * | 1973-11-21 | 1975-12-31 | British Petroleum Co | Detergent composition |
-
1995
- 1995-10-27 CN CN95112179A patent/CN1055299C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100376654C (en) * | 2003-04-23 | 2008-03-26 | 广州南沙经济技术开发区高奇环保技术有限公司 | Agglutinant for leaking oil and fabricating method |
| CN101831276B (en) * | 2009-03-10 | 2012-10-31 | 长江大学 | Water-based oil dispersant for eliminating floating oil on sea surface and preparation method thereof |
| WO2012028031A1 (en) * | 2010-08-31 | 2012-03-08 | 广东标美硅氟新材料有限公司 | A compounded oil outflow round-up agent, a reocess for its production and its use |
| CN102417215A (en) * | 2010-09-28 | 2012-04-18 | 广东标美硅氟新材料有限公司 | Method for recovering spilled oil in water area |
| CN102417215B (en) * | 2010-09-28 | 2014-04-16 | 广东标美硅氟新材料有限公司 | Method for recovering spilled oil in water area |
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| Publication number | Publication date |
|---|---|
| CN1055299C (en) | 2000-08-09 |
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