CN114959331B - Method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing - Google Patents
Method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing Download PDFInfo
- Publication number
- CN114959331B CN114959331B CN202210511045.XA CN202210511045A CN114959331B CN 114959331 B CN114959331 B CN 114959331B CN 202210511045 A CN202210511045 A CN 202210511045A CN 114959331 B CN114959331 B CN 114959331B
- Authority
- CN
- China
- Prior art keywords
- crystal
- single crystal
- additive manufacturing
- coaxial powder
- powder feeding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000013078 crystal Substances 0.000 title claims abstract description 156
- 239000000654 additive Substances 0.000 title claims abstract description 80
- 230000000996 additive effect Effects 0.000 title claims abstract description 80
- 238000000034 method Methods 0.000 title claims abstract description 65
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 56
- 229910000601 superalloy Inorganic materials 0.000 title claims abstract description 44
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 30
- 239000000843 powder Substances 0.000 title claims description 35
- 239000000758 substrate Substances 0.000 claims abstract description 50
- 230000017525 heat dissipation Effects 0.000 claims abstract description 20
- 238000007711 solidification Methods 0.000 claims abstract description 19
- 230000008023 solidification Effects 0.000 claims abstract description 19
- 210000001787 dendrite Anatomy 0.000 claims description 62
- 229910045601 alloy Inorganic materials 0.000 claims description 32
- 239000000956 alloy Substances 0.000 claims description 32
- 238000000151 deposition Methods 0.000 claims description 12
- 238000000137 annealing Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000010410 layer Substances 0.000 claims description 9
- 230000008021 deposition Effects 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 238000005520 cutting process Methods 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 239000002356 single layer Substances 0.000 claims description 2
- 230000002093 peripheral effect Effects 0.000 claims 2
- 238000005266 casting Methods 0.000 claims 1
- 238000005242 forging Methods 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- 238000010187 selection method Methods 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000007704 transition Effects 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 206010014970 Ephelides Diseases 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000739 chaotic effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/0433—Nickel- or cobalt-based alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/60—Treatment of workpieces or articles after build-up
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y40/00—Auxiliary operations or equipment, e.g. for material handling
- B33Y40/20—Post-treatment, e.g. curing, coating or polishing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/60—Treatment of workpieces or articles after build-up
- B22F10/64—Treatment of workpieces or articles after build-up by thermal means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
本发明公开了一种基于同轴送粉激光增材制造制备镍基单晶高温合金的方法,具体包括:在锻态或铸态镍基高温合金基板上进行同轴送粉激光增材制造并且加入辅助红外光源加热,成形具有一定尺寸的试样;以具有定向凝固组织特征的增材部分侧面为基板进行第二次激光增材制造,获得晶体取向基本一致的增材成形试样,重复第二步直至得到单晶组织;将除最后一次增材成形以外部分切除,剩余部分则是晶体取向完全一致的单晶高温合金。本发明的有益效果是:提供的单晶制备方法利用激光增材制造定向散热和定向生长特点实现晶体取向由随机到定向再到单晶的过渡,较选晶法、籽晶法等技术具有效率高的特点。
The invention discloses a method for preparing a nickel-based single crystal superalloy based on coaxial powder-feeding laser additive manufacturing, which specifically includes: performing coaxial powder-feeding laser additive manufacturing on a forged or cast nickel-based superalloy substrate and Add an auxiliary infrared light source to heat and form a sample with a certain size; use the side of the additive part with the characteristics of directional solidification as the substrate for the second laser additive manufacturing to obtain an additively formed sample with basically the same crystal orientation, and repeat the first step. Two steps until the single crystal structure is obtained; the part except the last additive forming is cut off, and the remaining part is a single crystal superalloy with completely consistent crystal orientation. The beneficial effects of the present invention are: the single crystal preparation method provided utilizes the characteristics of directional heat dissipation and directional growth of laser additive manufacturing to realize the transition of crystal orientation from random to directional and then to single crystal, which is more efficient than techniques such as crystal selection method and seed crystal method. high feature.
Description
技术领域technical field
本发明涉及激光增材制造领域,具体涉及一种基于同轴送粉激光增材制造制备镍基单晶高温合金的方法。The invention relates to the field of laser additive manufacturing, in particular to a method for preparing a nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing.
背景技术Background technique
作为单晶制造的方法,选晶法、籽晶法以及籽晶加选晶法等已为公众所知。但目前还没有基于激光增材制造技术利用镍基高温合金外延生长特性进行多次选晶的方法。As a method for producing a single crystal, a crystal selection method, a seed crystal method, a seed crystal plus selection method, and the like are known to the public. However, there is currently no method for multiple crystal selection based on the laser additive manufacturing technology using the epitaxial growth characteristics of nickel-based superalloys.
单晶高温合金主要用于制造航空发动机、燃气轮机热端涡轮叶片,具有良好的高温强度、抗氧化和抗腐蚀性能、抗疲劳和抗蠕变性能、断裂性能和组织稳定性。而其承温能力是提升发动机性能、效率、可靠性的关键技术指标。Single crystal superalloys are mainly used in the manufacture of aero-engines and gas turbine hot-end turbine blades. They have good high-temperature strength, oxidation resistance and corrosion resistance, fatigue resistance and creep resistance, fracture performance and structural stability. And its temperature bearing capacity is a key technical index to improve engine performance, efficiency and reliability.
在欧美一些发达国家,单晶高温合金的研发工作开展早、技术成熟度高,但对单晶高温合金研发及单晶叶片的研制一直非常重视。单晶发动机叶片的性能虽然较为优异,但是单晶叶片的材料和制造成本高达上万美元,并且其使用寿命受热疲劳裂纹、叶尖腐蚀、表面磨损和热腐蚀等缺陷的限制。单晶叶片的更换很大程度上影响了现代航空发动机和燃气轮机的运行成本。In some developed countries in Europe and the United States, the research and development of single crystal superalloys was carried out early and the technology maturity is high, but the research and development of single crystal superalloys and the development of single crystal blades have always been attached great importance. Although the performance of single crystal engine blades is relatively excellent, the material and manufacturing costs of single crystal blades are as high as tens of thousands of dollars, and their service life is limited by defects such as thermal fatigue cracks, blade tip corrosion, surface wear and thermal corrosion. The replacement of single crystal blades greatly affects the operating costs of modern aero-engines and gas turbines.
目前,先进航空发动机叶片材料多选用具有优良高温力学性能的定向凝固铸造镍基单晶高温合金,但由于定向凝固和单晶叶片外形复杂,内部为复杂空心气冷结构,制造过程中频繁出现偏晶、杂晶以及小角度晶界等缺陷,杂晶晶界的出现会影响枝晶晶体的完整性,降低单晶合金的力学性能,导致单晶叶片的合格率降低。镍基单晶高温合金的力学性能具有显著的各向异性,其优势是可以保证在应力方向获得最好的性能,但晶体取向的偏离会严重影响单晶叶片的高温力学性能。At present, the advanced aero-engine blades mostly use directionally solidified cast nickel-based single-crystal superalloys with excellent high-temperature mechanical properties. The appearance of miscellaneous grain boundaries will affect the integrity of dendrite crystals, reduce the mechanical properties of single crystal alloys, and lead to a decrease in the pass rate of single crystal blades. The mechanical properties of nickel-based single crystal superalloys have significant anisotropy, which has the advantage of ensuring the best performance in the stress direction, but the deviation of crystal orientation will seriously affect the high temperature mechanical properties of single crystal blades.
单晶叶片制造的关键是如何避免杂晶缺陷的产生以及保证单晶组织的完整性。选晶过程会对单晶取向以及单晶缺陷的形成产生重要影响,最终作用于合金的力学性能。有学者发现在激光增材制造过程中随着距锻态基板表面距离的增加,等轴晶组织逐渐向定向组织转变,当到达一定高度后,等轴晶组织完全转变为定向组织,这说明利用激光增材制造技术直接制备单晶高温合金是具有可行性的。The key to the manufacture of single crystal blades is how to avoid the generation of miscellaneous crystal defects and ensure the integrity of the single crystal structure. The crystal selection process will have an important impact on the single crystal orientation and the formation of single crystal defects, which will ultimately affect the mechanical properties of the alloy. Some scholars have found that in the process of laser additive manufacturing, as the distance from the surface of the forged substrate increases, the equiaxed crystal structure gradually transforms into an oriented structure, and when it reaches a certain height, the equiaxed crystal structure completely transforms into a oriented structure. It is feasible to directly prepare single crystal superalloys by laser additive manufacturing technology.
发明内容Contents of the invention
针对当前激光增材制造制备镍基单晶高温合金过程中易存在杂晶的问题,本发明公开了一种基于同轴送粉激光增材制造制备镍基单晶高温合金的方法,本发明提出的选晶法操作简单,能够有效提高制备单晶的合格率,降低制造镍基单晶高温合金的生产成本。Aiming at the problem that miscellaneous crystals are likely to exist in the process of preparing nickel-based single crystal superalloys in the current laser additive manufacturing process, the present invention discloses a method for preparing nickel-based single crystal superalloys based on coaxial powder feeding laser additive manufacturing. The crystal selection method is simple to operate, can effectively improve the qualified rate of preparing single crystals, and reduce the production cost of manufacturing nickel-based single crystal superalloys.
本发明采用如下的技术方案:一种基于同轴送粉激光增材制造制备镍基单晶高温合金的方法,其特征在于包括四个步骤:The present invention adopts the following technical scheme: a method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing, which is characterized in that it includes four steps:
第一步,在锻态或铸态合金基板上采用同轴送粉激光增材制造镍基高温合金;定向凝固组织中取向一致的枝晶所占比例为70%;The first step is to use coaxial powder feeding laser additive manufacturing of nickel-based superalloy on the forged or cast alloy substrate; the proportion of uniformly oriented dendrites in the directionally solidified structure is 70%;
第二步,选晶,将第一步的增材件试样进行去应力退火后将增材部分侧面铣削加工至表面平整,以此为基板采用与第一步相同的同轴送粉激光增材制造工艺参数进行第二步激光增材过程;定向凝固组织中取向一致的枝晶所占比例为95%;The second step is crystal selection. After stress-relief annealing the additive part sample in the first step, the side of the additive part is milled until the surface is flat, and the same coaxial powder-feeding laser amplification as in the first step is used as the substrate. The material manufacturing process parameters are used to carry out the second-step laser material addition process; the proportion of dendrites with consistent orientation in the directional solidification structure is 95%;
第三步,重复选晶,以第二步选晶后所获得的增材件试样为基板,重复第二步的选晶过程;经过第三步的选晶后,所获得的增材区组织中取向一致的枝晶所占比例为100%,获得所有晶体取向完全一致的单晶组织;The third step is to repeat the crystal selection, using the sample of the additive part obtained after the second step of crystal selection as the substrate, and repeat the second step of the crystal selection process; after the third step of crystal selection, the obtained additive area The proportion of dendrites with consistent orientation in the structure is 100%, and a single crystal structure with completely consistent crystal orientation is obtained;
第四步,将基板部分线切割切除,再次进行第二步相同的去应力退火处理,剩余部分即是所需要的的单晶高温合金试样。In the fourth step, the wire cutting part of the substrate is removed, and the same stress relief annealing treatment as in the second step is performed again, and the remaining part is the required single crystal superalloy sample.
进一步的,第一步在锻态或铸态合金基板上采用同轴送粉激光增材制造镍基高温合金具体为:Further, the first step is to use coaxial powder feeding laser additive manufacturing of nickel-based superalloy on the forged or cast alloy substrate, specifically:
(1)在锻态或铸态合金基板上采用多层多道单向直线沉积方式激光增材成形一定尺寸的试样;(1) On the forged or cast alloy substrate, a sample of a certain size is formed by laser additive material multi-layer multi-channel unidirectional linear deposition;
(2)激光热输入过程中为高温度梯度、高凝固速度,增材区组织为定向凝固的枝晶组织;(2) During the laser heat input process, there is a high temperature gradient and a high solidification rate, and the structure of the additive area is a dendrite structure of directional solidification;
(3)对同轴送粉过程中的散热条件做限制,利用辅助红外光源对增材件试样四周表面进行加热,减少熔池水平方向的散热,只通过基板向下散热,使得散热方向为竖直方向,枝晶优先沿散热方向生长;(3) Limit the heat dissipation conditions during the coaxial powder feeding process, use the auxiliary infrared light source to heat the surface around the additive part sample, reduce the heat dissipation in the horizontal direction of the molten pool, and only dissipate heat through the substrate downward, so that the heat dissipation direction is In the vertical direction, dendrites grow preferentially along the direction of heat dissipation;
(4)使得取向一致的枝晶所占比例提高,为70%。(4) The proportion of dendrites with uniform orientation is increased to 70%.
进一步的,第一步中的锻态或铸态合金基板,等轴晶平均晶粒尺寸为10~30μm,所述的同轴送粉激光增材制造所获得的柱状晶组织晶粒宽度为200~500μm;第二步和第三步中,柱状晶晶粒宽度逐渐增大,最终获得单晶组织。Further, for the forged or cast alloy substrate in the first step, the average grain size of the equiaxed grains is 10-30 μm, and the grain width of the columnar grain structure obtained by the coaxial powder feeding laser additive manufacturing is 200 μm. ~500μm; in the second and third steps, the columnar grain width gradually increases, and finally a single crystal structure is obtained.
进一步的,第一步和第二步中,在同轴送粉过程中利用辅助红外光源对增材件试样四周表面进行加热,减少熔池水平方向的散热,进而获得生长方向更加一致的枝晶组织,采用光学辐射无接触加热,发挥出增材制造微小熔池冶金特点,所述的辅助红外光源工作温度范围为800~1000℃,加热功率为20~30KW,加热的范围能够达到熔池尺寸的5~10倍,加热深度可以达到0.4~1mm,保证熔池在水平方向上没有温度梯度,热量只通过基板向下扩散。Furthermore, in the first and second steps, during the coaxial powder feeding process, the auxiliary infrared light source is used to heat the surface around the additive part sample, so as to reduce the heat dissipation in the horizontal direction of the molten pool, and obtain branches with a more consistent growth direction. The crystal structure is heated by optical radiation without contact, and the metallurgical characteristics of the small molten pool of additive manufacturing are brought into play. The working temperature range of the auxiliary infrared light source is 800-1000 ° C, the heating power is 20-30KW, and the heating range can reach the molten pool 5 to 10 times the size, the heating depth can reach 0.4 to 1mm, ensuring that there is no temperature gradient in the molten pool in the horizontal direction, and the heat only diffuses downward through the substrate.
进一步的,同轴送粉激光增材制造的工艺,具体的工艺参数包括:激光扫描策略采用多层多道单向直线沉积方式,采用小能量输入、大光斑尺寸和大扫描速度的策略,激光功率800~1200W、扫描速度10~20mm/s、光斑直径3~5mm、搭接率20~30%、单层高度0.05~0.1mm、送粉速率3~8g/min、载粉气体流量5~10L/min,采用氩气进行整体保护。Further, the process of coaxial powder-feeding laser additive manufacturing, the specific process parameters include: the laser scanning strategy adopts the multi-layer multi-channel unidirectional linear deposition method, adopts the strategy of small energy input, large spot size and large scanning speed, laser Power 800~1200W, scanning speed 10~20mm/s, spot diameter 3~5mm, overlap rate 20~30%, single layer height 0.05~0.1mm, powder feeding rate 3~8g/min, powder-carrying gas flow 5~ 10L/min, using argon for overall protection.
进一步的,所述多层多道单向直线沉积方式,在增材制造过程中每一层中的每一道均采用单方向和直线扫描方式,相比于目前已知的其它种激光扫描策略,采用多层多道单向直线沉积方式更容易获得枝晶取向更加一致的定向凝固组织。Further, in the multi-layer multi-channel unidirectional linear deposition method, each layer in each layer adopts a unidirectional and linear scanning method during the additive manufacturing process. Compared with other currently known laser scanning strategies, It is easier to obtain a directional solidification structure with more consistent dendrite orientation by using multi-layer multi-channel unidirectional linear deposition.
进一步的,所述第二步获得的同轴送粉增材制造合金试样进行去应力退火,以此增材部分侧面为基板进行第二步;优选的,所述的去应力退火工艺为升温至300~500℃,更优选为500℃;保温4~8小时,更优选为4小时。Further, the coaxial powder feeding additive manufacturing alloy sample obtained in the second step is subjected to stress relief annealing, and the side of the additive part is used as the substrate to perform the second step; preferably, the stress relief annealing process is heating to 300-500°C, more preferably 500°C; keep warm for 4-8 hours, more preferably 4 hours.
进一步的,去应力退火工艺使用温度控制精确度±1℃、可长时间连续工作的马弗炉或真空热处理炉;在以小于100℃每分钟升温速度升温至500℃,保温4小时,再以炉冷或小于100℃每分钟的降温速度冷却至室温。Further, the stress relief annealing process uses a muffle furnace or a vacuum heat treatment furnace with a temperature control accuracy of ±1°C and can work continuously for a long time; the temperature is raised to 500°C at a heating rate of less than 100°C per minute, kept for 4 hours, and then Furnace cooling or cooling to room temperature at a cooling rate of less than 100°C per minute.
本发明的有益效果是:提供的单晶制备方法利用激光增材制造定向散热和定向生长特点实现晶体取向由随机到定向再到单晶的过渡,较选晶法、籽晶法等技术具有效率高的特点。采用同轴送粉激光增材制造技术,能够实现高性能复杂结构金属零件的无模具、快速、全致密近净成形,并且采用本发明所公布的红外辅助多次垂直选晶的方法能够更快更高效的制备得到具有定向生长均匀枝晶组织的成形件。The beneficial effects of the present invention are: the single crystal preparation method provided utilizes the characteristics of directional heat dissipation and directional growth of laser additive manufacturing to realize the transition of crystal orientation from random to directional and then to single crystal, which is more efficient than techniques such as crystal selection method and seed crystal method. high feature. Using coaxial powder-feeding laser additive manufacturing technology can realize moldless, fast, fully dense and near-net shape of high-performance complex structure metal parts, and adopt the method of infrared-assisted multiple vertical crystal selection announced by the present invention to be faster Formed parts with directional growth and uniform dendrite structure can be obtained more efficiently.
附图说明Description of drawings
下面结合附图对本发明进行进一步的说明:Below in conjunction with accompanying drawing, the present invention is further described:
图1是本发明所采用的选晶方法流程图。Fig. 1 is the flow chart of the crystal selection method adopted in the present invention.
图2是本发明锻态GH4169合金基板等轴晶显微组织图。Fig. 2 is an equiaxed grain microstructure diagram of the forged GH4169 alloy substrate of the present invention.
图3是本发明在锻态GH4169合金基板上第一步枝晶生长方向显微组织图。Fig. 3 is a microstructure diagram of the first step of dendrite growth direction on the forged GH4169 alloy substrate of the present invention.
图4是本发明在垂直于第一步中获得的枝晶生长方向的第二步枝晶生长方向显微组织图。Fig. 4 is a microstructure diagram of the second step dendrite growth direction perpendicular to the dendrite growth direction obtained in the first step according to the present invention.
具体实施方式Detailed ways
本发明的核心思想在于提供一种基于同轴送粉激光增材制造获得镍基单晶高温合金的方法,能够获得杂晶较少的定向凝固组织,提高制备单晶的合格率。The core idea of the present invention is to provide a method for obtaining a nickel-based single crystal superalloy based on coaxial powder-feeding laser additive manufacturing, which can obtain a directional solidified structure with less miscellaneous crystals and improve the pass rate of preparing single crystals.
激光增材后成形件存在较大内应力,本发明优选还包括将所述的镍基单晶高温合金成形件进行去应力退火并冷却至室温。在本发明中,所述冷却优选为炉冷或空冷。The formed part after laser material addition has relatively large internal stress, and the present invention preferably further includes performing stress relief annealing on the nickel-based single crystal superalloy formed part and cooling it to room temperature. In the present invention, the cooling is preferably furnace cooling or air cooling.
本发明采用如下的技术方案:一种基于同轴送粉激光增材制造制备镍基单晶高温合金的方法,其特征在于包括四个步骤:The present invention adopts the following technical scheme: a method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing, which is characterized in that it includes four steps:
第一步,在锻态或铸态合金基板上采用同轴送粉激光增材制造镍基高温合金;定向凝固组织中取向一致的枝晶所占比例为70%;The first step is to use coaxial powder feeding laser additive manufacturing of nickel-based superalloy on the forged or cast alloy substrate; the proportion of uniformly oriented dendrites in the directionally solidified structure is 70%;
第二步,选晶,首先将第一步的增材件试样进行去应力退火后将增材部分侧面铣削加工至表面平整,以此为基板采用与第一步相同的同轴送粉激光增材制造工艺参数进行第二步激光增材过程;定向凝固组织中取向一致的枝晶所占比例为95%;The second step is crystal selection. Firstly, the additive part sample in the first step is stress-relieved and annealed, and then the side of the additive part is milled until the surface is flat. The same coaxial powder-feeding laser as the first step is used as the substrate. Additive manufacturing process parameters for the second step of laser additive process; the proportion of uniformly oriented dendrites in the directional solidification structure is 95%;
第三步,重复选晶,以第二步选晶后所获得的增材件试样为基板,重复第二步的选晶过程;经过第三步的选晶后,所获得的增材区组织中取向一致的枝晶所占比例为100%,获得所有晶体取向完全一致的单晶组织;The third step is to repeat the crystal selection, using the sample of the additive part obtained after the second step of crystal selection as the substrate, and repeat the second step of the crystal selection process; after the third step of crystal selection, the obtained additive area The proportion of dendrites with consistent orientation in the structure is 100%, and a single crystal structure with completely consistent crystal orientation is obtained;
第四步,将基板部分线切割切除,再次进行第二步相同的去应力退火处理,剩余部分即是所需要的的单晶高温合金试样。In the fourth step, the wire cutting part of the substrate is removed, and the same stress relief annealing treatment as in the second step is performed again, and the remaining part is the required single crystal superalloy sample.
第一步中,具体过程为在锻态或铸态合金基板上采用多层多道单向直线沉积方式激光增材成形一定尺寸的试样,由于具有激光热输入过程中高温度梯度、高凝固速度等特点,增材区组织为定向凝固的枝晶组织。同时对同轴送粉过程中的散热条件做限制,利用辅助红外光源对增材件试样四周表面进行加热,减少熔池水平方向的散热,只通过基板向下散热,这样散热也可以保证在竖直方向,枝晶会优先沿散热方向生长。在同轴送粉过程中没有加入辅助红外光源控制散热方向的情况下,取向一致的枝晶所占比例只有50%~60%,加入辅助红外光源控制散热方向后,取向一致的枝晶所占比例提高了10%左右,达到了70%。虽然在第一步已经获得了具有一定定向凝固组织特征的枝晶,但由于锻态或铸态合金基板组织为等轴晶,等轴晶之间的晶体取向不一样,导致增材区的枝晶在以这些等轴晶为基底定向凝固生长时相互之间取向差变大,因此组织中还存在着所占比例较大的杂晶数量,取向一致的枝晶所占比例只有70%,所获得的定向凝固组织还远远达不到单晶组织的标准。In the first step, the specific process is to use multi-layer multi-channel unidirectional linear deposition method laser additive forming of a certain size of the sample on the forged or cast alloy substrate, due to the high temperature gradient and high solidification speed in the process of laser heat input And other characteristics, the structure of the additive zone is a dendrite structure of directional solidification. At the same time, limit the heat dissipation conditions during the coaxial powder feeding process, use the auxiliary infrared light source to heat the surface around the additive part sample, reduce the heat dissipation in the horizontal direction of the molten pool, and only dissipate heat through the substrate downward, so that heat dissipation can also be guaranteed In the vertical direction, dendrites will preferentially grow along the direction of heat dissipation. In the process of coaxial powder feeding without adding auxiliary infrared light source to control the heat dissipation direction, the proportion of dendrites with uniform orientation is only 50% to 60%. After adding auxiliary infrared light source to control the heat dissipation direction, the proportion of dendrites with uniform orientation The ratio increased by around 10% to 70%. Although dendrites with certain directional solidification characteristics have been obtained in the first step, since the forged or cast alloy substrate is equiaxed, the crystal orientations between equiaxed crystals are different, resulting in dendrites in the additive area. The orientation difference between crystals becomes larger when these equiaxed crystals are used as the substrate for directional solidification and growth, so there are still a large number of miscellaneous crystals in the structure, and the proportion of dendrites with uniform orientation is only 70%. The obtained directional solidified structure is far from the standard of single crystal structure.
第一步中,目前,关于同轴送粉激光增材制造制备镍基高温合金的研究只针对于本发明第一步中的成形内容,没有通过利用辅助红外光源对增材件试样四周表面进行加热控制枝晶生长方向的案例,同时没有对所获得的具有定向凝固特征的枝晶组织进行进一步的选晶获得单晶合金的案例。相对于取向一致的枝晶所占比例只有70%的定向凝固组织,单晶组织中取向一致的枝晶所占比例则达到100%。单晶组织消除了横向晶界,晶粒取向的一致性使得合金高温下在特定方向具有更加优良的力学性能。而传统的选晶法、籽晶法等技术效率太低,因此,本发明通过对同轴送粉激光增材制造镍基高温合金进行选晶来获得单晶合金,成本低,效率高,得到的单晶组织与传统方法相比效果一致。In the first step, at present, research on the preparation of nickel-based superalloys by coaxial powder-feeding laser additive manufacturing is only aimed at the forming content in the first step of the present invention. There is a case of heating to control the growth direction of dendrites, and there is no case of further crystal selection of the obtained dendrite structure with directional solidification characteristics to obtain a single crystal alloy. Compared with the directionally solidified structure with uniformly oriented dendrites accounting for only 70%, the proportion of uniformly oriented dendrites in the single crystal structure reaches 100%. The single crystal structure eliminates the transverse grain boundary, and the consistency of grain orientation makes the alloy have better mechanical properties in a specific direction at high temperature. However, the technical efficiency of the traditional crystal selection method and seed crystal method is too low. Therefore, the present invention obtains a single crystal alloy by selecting crystals for the coaxial powder feeding laser additive manufacturing of nickel-based superalloys, which is low in cost and high in efficiency. Compared with the traditional method, the single crystal structure has the same effect.
第一步中,同轴送粉激光增材制造的组织中存在取向不一致的枝晶晶向,由于微观生长条件的复杂性,这种枝晶晶向的偏离行为是随机和不可控制的。靠近基板的距离越近,枝晶生长的方向越杂乱;为了获得取向更加一致的单晶组织,需要对熔池的散热方向进行控制,本发明在同轴送粉过程中通过在增材件试样的四周加入辅助红外光源加热,所获得的组织中取向一致的枝晶所占比例提高了10%,但没有达到生产单晶合金的标准。因此本发明设置第二步和第三步的选晶过程。In the first step, there are dendrite orientations with inconsistent orientation in the structure of coaxial powder-feeding laser additive manufacturing. Due to the complexity of microscopic growth conditions, the deviation behavior of dendrite orientation is random and uncontrollable. The closer the distance to the substrate, the more chaotic the direction of dendrite growth; in order to obtain a single crystal structure with a more consistent orientation, it is necessary to control the heat dissipation direction of the molten pool. Adding an auxiliary infrared light source around the sample to heat, the proportion of uniformly oriented dendrites in the obtained structure increased by 10%, but it did not reach the standard for producing single crystal alloys. Therefore, the present invention sets the crystal selection process of the second step and the third step.
第二步中,由于此时的基板组织中取向一致的枝晶所占比例能够达到70%,相比于在锻态或铸态等轴晶合金基板上直接进行激光增材制造,枝晶在以枝晶为基底进行生长时相互之间取向差很小,即发生竞争生长的枝晶数量较少,同时由于加入了辅助红外光源控制熔池的散热方向,所获得的枝晶组织中取向一致的枝晶所占比例达到95%。In the second step, since the proportion of uniformly oriented dendrites in the substrate structure at this time can reach 70%, compared with direct laser additive manufacturing on forged or cast equiaxed crystal alloy substrates, dendrites in When the dendrites are used as the base to grow, the orientation difference between them is very small, that is, the number of dendrites that compete for growth is small. At the same time, due to the addition of an auxiliary infrared light source to control the heat dissipation direction of the molten pool, the obtained dendrites have consistent orientations. The proportion of dendrites reaches 95%.
第三步中,重复第二步的过程进行重复选晶。最终,本发明通过重复选晶过程获得具有枝晶取向完全一致的单晶组织。传统的通过选晶法、籽晶法等技术获得单晶的合格率为90%,本发明通过第三步的重复选晶获得单晶的合格率为100%,所用时间降低为传统方法的1/10,既提高了效率,也节约了成本。In the third step, repeat the process of the second step to repeat crystal selection. Finally, the present invention obtains a single crystal structure with completely consistent dendrite orientation by repeating the crystal selection process. The qualified rate of single crystals obtained by traditional techniques such as crystal selection method and seed crystal method is 90%, but in the present invention, the qualified rate of single crystals obtained by repeated crystal selection in the third step is 100%, and the time used is reduced to 1 of the traditional method. /10, which not only improves efficiency, but also saves costs.
下面结合实施例对本发明提供的基于同轴送粉激光增材制造获得镍基单晶高温合金的方法进行详细的说明,但是不能把它们理解为对本发明保护范围的限定。The method for obtaining a nickel-based single crystal superalloy based on coaxial powder-feeding laser additive manufacturing provided by the present invention will be described in detail below in conjunction with examples, but they should not be construed as limiting the protection scope of the present invention.
实施例1Example 1
基于同轴送粉激光增材制造获得GH4169单晶高温合金Obtain GH4169 single crystal superalloy based on coaxial powder feeding laser additive manufacturing
对合金牌号为GH4169的锻态镍基高温合金基板需增材部位进行打磨去除氧化皮,并用酒精或丙酮对表面进行清理;将所述的镍基高温合金基板固定装夹在具有冷却功能的工装夹具上。采用同轴送粉激光增材多次选晶获得晶体取向完全一致的单晶组织。Grind and remove scale on the wrought nickel-based superalloy substrate with alloy grade GH4169 to remove the scale, and clean the surface with alcohol or acetone; fix the nickel-based superalloy substrate in a tooling with cooling function on the fixture. The single crystal structure with completely consistent crystal orientation is obtained by coaxial powder feeding laser additive multiple times of crystal selection.
如图1所示,本发明所述的一种基于同轴送粉激光增材制造的单晶制备方法,通过四步选晶的过程,最终获得取向一致的枝晶所占比例为100%的单晶组织。其中,第一步:在经过打磨及清洗的锻态GH4169合金基板上进行同轴送粉激光增材制造GH4169合金,采用多层多道单向直线沉积方式,由于在靠近基板区域等轴晶晶粒取向不一致,沿等轴晶晶界生长的柱状枝晶生长方向也存在差异,存在一定区域范围内的失稳区,在失稳区晶粒间平均取向差更大,在制造过程中频繁出现偏晶、杂晶、雀斑、小角晶界等缺陷,晶界的出现割裂了晶体的完整性,显著降低了单晶合金的力学性能,此时增材部分虽具有定向组织特征,但是枝晶生长方向并不一致,分散性很大,取向一致的枝晶所占比例只有70%。定向凝固过程中,热流控制的晶粒竞争生长是晶粒淘汰选择的主要原因,因此,具有一致取向的枝晶在竞争生长过程中淘汰了去他取向的枝晶。第二步:对第一步成形得到的具有初步定向凝固组织的激光增材制造GH4169合金试样进行去应力退火后将其从锻态高温合金基板上切取下来,将第一步增材成形的试样侧面铣削加工至表面平整,以此增材部分为基板进行第二步激光增材成形。此时,组织中取向一致的枝晶所占比例为95%。第三步:重复选晶,以第二步选晶后所获得的增材件试样为基板,重复第二步的选晶过程;经过第三步的选晶后,所获得的增材区组织中取向一致的枝晶所占比例为100%,获得所有晶体取向完全一致的单晶组织;第四步,将基板部分线切割切除,再次进行第二步相同的去应力退火处理,剩余部分即是所需要的的单晶高温合金试样。As shown in Figure 1, a single crystal preparation method based on coaxial powder-feeding laser additive manufacturing according to the present invention, through a four-step crystal selection process, finally obtains a dendrite with a uniform orientation accounting for 100%. single crystal structure. Among them, the first step: Coaxial powder feeding laser additive manufacturing of GH4169 alloy on the polished and cleaned forged GH4169 alloy substrate, using multi-layer multi-channel unidirectional linear deposition method, due to the equiaxed crystal in the area close to the substrate The grain orientation is inconsistent, and the growth direction of the columnar dendrites growing along the equiaxed grain boundaries is also different. There is an instability zone within a certain area, and the average orientation difference between grains in the instability zone is larger, which frequently occurs Defects such as monotectic crystals, miscellaneous crystals, freckles, and small-angle grain boundaries. The appearance of grain boundaries splits the integrity of the crystal and significantly reduces the mechanical properties of the single crystal alloy. At this time, although the additive part has directional structure characteristics, the dendrites grow The direction is not consistent, the dispersion is very large, and the proportion of dendrites with uniform orientation is only 70%. In the process of directional solidification, the competitive growth of grains controlled by heat flow is the main reason for grain elimination selection, therefore, the dendrites with uniform orientation eliminate the dendrites with other orientation during the competitive growth process. The second step: the laser additively manufactured GH4169 alloy sample with the preliminary directional solidification structure obtained in the first step is subjected to stress relief annealing, and then it is cut from the forged superalloy substrate, and the first step is added. The side of the sample is milled until the surface is flat, and the added part is used as the substrate for the second step of laser additive forming. At this time, the proportion of uniformly oriented dendrites in the structure is 95%. The third step: Repeat the crystal selection, using the additive part sample obtained after the second step of crystal selection as the substrate, repeat the second step of the crystal selection process; after the third step of crystal selection, the obtained additive area The proportion of dendrites with uniform orientation in the structure is 100%, and a single crystal structure with all crystal orientations is obtained; the fourth step is to cut off part of the substrate by wire cutting, and perform the same stress relief annealing treatment as the second step, and the remaining part That is, the required single crystal superalloy sample.
图2为锻态GH4169合金基板的等轴晶显微组织图,所述的锻态合金基板中等轴晶平均晶粒尺寸为10~30μm。Fig. 2 is a microstructure diagram of equiaxed grains of a forged GH4169 alloy substrate. The average grain size of equiaxed grains in the forged alloy substrate is 10-30 μm.
图3为在锻态GH4169合金基板上的第一步选晶过程,下部区域基板为晶粒取向各异的等轴晶组织,上部区域为增材区的第一步枝晶生长方向,虽具有定向组织特征,但是枝晶生长方向并不一致,分散性很大,取向一致的枝晶所占比例只有70%;所述的同轴送粉激光增材制造获得的柱状晶组织晶粒宽度为460μm。第二步和第三步中,柱状晶晶粒宽度逐渐增大,最终获得单晶组织。Figure 3 shows the first step of crystal selection process on the forged GH4169 alloy substrate. The substrate in the lower region is an equiaxed crystal structure with different grain orientations, and the upper region is the first step of dendrite growth direction in the additive area. Although it has Directional structure characteristics, but the dendrite growth direction is not consistent, the dispersion is very large, and the proportion of uniformly oriented dendrites is only 70%; the columnar crystal structure obtained by the coaxial powder feeding laser additive manufacturing has a grain width of 460 μm . In the second and third steps, the width of the columnar grains increases gradually, and finally a single crystal structure is obtained.
图4为第二步枝晶生长方向,是在第一步枝晶生长方向上进行第二步选晶过程,将第一步成形得到的具有初步定向凝固组织的激光增材制造GH4169合金试样从锻态GH4169合金基板上切取下来,将第一步增材成形试样侧面铣削加工至表面平整,以此增材部分为基板进行第二步的激光增材成形。此时,组织中取向一致的枝晶所占比例为95%。经过第三步的重复选晶过程后,组织中取向一致的枝晶所占比例为100%,可以认为获得可以得到枝晶取向完全一致的单晶组织。Figure 4 shows the direction of dendrite growth in the second step, which is the second step of crystal selection process in the direction of dendrite growth in the first step, and the laser additive manufacturing GH4169 alloy sample with a preliminary directional solidification structure obtained in the first step It was cut from the forged GH4169 alloy substrate, and the side of the first-step additive forming sample was milled until the surface was flat, and the second-step laser additive forming was performed on this additive part as the substrate. At this time, the proportion of uniformly oriented dendrites in the structure is 95%. After repeated crystal selection in the third step, the proportion of dendrites with consistent orientation in the structure is 100%, and it can be considered that a single crystal structure with completely consistent dendrite orientation can be obtained.
实施例2Example 2
基于同轴送粉激光增材制造获得GH3625单晶高温合金Obtain GH3625 single crystal superalloy based on coaxial powder feeding laser additive manufacturing
对合金牌号为GH3625的锻态镍基高温合金基板需增材部位进行打磨去除氧化皮,并用酒精或丙酮对表面进行清理;将所述的镍基高温合金基板固定装夹在具有冷却功能的工装夹具上。采用同轴送粉激光增材多次选晶获得晶体取向完全一致的单晶组织。Grind and remove scale on the wrought nickel-based superalloy substrate with an alloy grade of GH3625 that needs to be added, and clean the surface with alcohol or acetone; fix and clamp the nickel-based superalloy substrate on a tooling with cooling function on the fixture. The single crystal structure with completely consistent crystal orientation is obtained by coaxial powder feeding laser additive multiple times of crystal selection.
沉积区底部为宽度约8μm的等轴晶、沿沉积高度方向外延生长排列紧密的定向凝固的柱状晶组织,通常含有多个取向各异的晶粒在不断地竞争生长。The bottom of the deposition area is equiaxed grains with a width of about 8 μm, and the directionally solidified columnar grains are tightly arranged epitaxially along the deposition height direction, usually containing multiple grains with different orientations that are constantly competing for growth.
采用线切割将第一步成形得到的具有初步定向凝固组织的激光增材制造GH3625合金试样从锻态高温合金基板上切取下来进行第二步激光增材成形。经过第二步和第三步的选晶过程,组织中取向一致的枝晶所占比例为100%,可以认为获得晶体取向完全一致的单晶组织。The laser additively manufactured GH3625 alloy sample obtained in the first step of forming with a preliminary directional solidification structure was cut from the forged superalloy substrate by wire cutting for the second step of laser additive forming. After the crystal selection process in the second and third steps, the proportion of dendrites with consistent orientation in the structure is 100%, and it can be considered that a single crystal structure with completely consistent crystal orientation is obtained.
对实施例2所述基于同轴送粉激光增材制造获得GH3625单晶高温合金试样进行金相组织观察和扫描电镜观察,结果与图2~4相似,表明经本发明所述的选晶方法可以得到枝晶取向完全一致的单晶试样。Metallographic structure observation and scanning electron microscope observation were carried out on the GH3625 single crystal superalloy sample obtained based on coaxial powder feeding laser additive manufacturing described in Example 2, and the results were similar to those shown in Figures 2 to 4, indicating that the crystal selection process described in the present invention The method can obtain single crystal samples with completely consistent dendrite orientation.
对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Therefore, the present invention will not be limited to the embodiments shown herein, but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210511045.XA CN114959331B (en) | 2022-05-11 | 2022-05-11 | Method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210511045.XA CN114959331B (en) | 2022-05-11 | 2022-05-11 | Method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114959331A CN114959331A (en) | 2022-08-30 |
CN114959331B true CN114959331B (en) | 2023-05-26 |
Family
ID=82980749
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210511045.XA Active CN114959331B (en) | 2022-05-11 | 2022-05-11 | Method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114959331B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116130040A (en) * | 2023-01-20 | 2023-05-16 | 中北大学 | Artificial intelligence-based laser directional cladding method for nickel-based single crystal |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105108142A (en) * | 2015-06-18 | 2015-12-02 | 航星利华(北京)科技有限公司 | Method for manufacturing monocrystalline and directional solidified part through laser 3D printer |
US11318553B2 (en) * | 2019-01-04 | 2022-05-03 | Raytheon Technologies Corporation | Additive manufacturing of laminated superalloys |
GB202007591D0 (en) * | 2020-05-21 | 2020-07-08 | Renishaw Plc | Additive manufacturing methods and apparatus for forming objects from a nickel-based supperally in a layer-by-layer manner |
CN112122617A (en) * | 2020-08-21 | 2020-12-25 | 苏州华普森激光科技有限公司 | Laser additive repair method for high-performance monocrystalline directional crystal turbine blade |
CN214601945U (en) * | 2021-04-12 | 2021-11-05 | 南昌航空大学 | Nickel-based single crystal superalloy laser composite manufacturing auxiliary device with directional heat dissipation function |
CN113458417B (en) * | 2021-06-29 | 2023-02-14 | 西北工业大学 | A preparation method for the directionally solidified structure of nickel-based superalloy manufactured by laser additive manufacturing |
-
2022
- 2022-05-11 CN CN202210511045.XA patent/CN114959331B/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN114959331A (en) | 2022-08-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN113275600B (en) | Heat treatment method for obtaining tri-state structure in SLM forming titanium alloy | |
CN107790717B (en) | A quasi-continuous laser metal 3D printing method for crystallographic texture control of nickel-based alloys | |
WO2021254480A1 (en) | Nickel-based superalloy and manufacturing method therefor, and component and application | |
CN111364096B (en) | Substrate-triggered single crystal high-temperature alloy directional solidification process | |
CN110315075B (en) | Synchronous laser heat treatment method for manufacturing nickel-based high-temperature alloy through laser additive | |
CN112809007B (en) | Preparation method for manufacturing titanium alloy and nickel-based superalloy functionally graded material | |
CN111761149B (en) | Method for eliminating single crystal high temperature alloy electric spark hole-making hole wall remelted layer | |
CN113814413B (en) | Method for manufacturing crack-free high-temperature alloy with controllable strength and toughness by laser additive | |
CN114150367B (en) | Laser cladding repair method and repair system for high-temperature alloy single crystal defect | |
CN114934211B (en) | Nickel-base superalloy, nickel-base superalloy powder, and nickel-base superalloy component | |
CN109014215A (en) | A kind of heat treatment method of increasing material manufacturing monocrystal nickel-base high-temperature alloy | |
CN114959331B (en) | Method for preparing nickel-based single crystal superalloy based on coaxial powder feeding laser additive manufacturing | |
CN107119325A (en) | A kind of method for eliminating laser 3D printing single crystal super alloy recrystallization tendency | |
CN110079752A (en) | Inhibit the heat treatment method of the single crystal super alloy of 3D printing or welding recrystallization | |
CN109706346A (en) | A kind of nickel base superalloy and the article formed by alloy | |
Li et al. | Microstructures and high-temperature oxidation behavior of laser cladded NiCoCrAlYSi coating on Inconel 625 Ni-based superalloy modified via high current pulsed Electron beam | |
CN110344049B (en) | Repair method and application of single crystal/directional solidification nickel-based superalloy | |
CN111975006A (en) | Repair method of aircraft engine blade | |
CN114875347A (en) | Low-speed temperature-rise recovery heat treatment method for blade tenon | |
CN112570729B (en) | Laser additive manufacturing method for reducing cracking sensitivity | |
CN110835756A (en) | Preparation method for MCrAlY single crystal coating epitaxially grown on single crystal high-temperature alloy substrate | |
CN113927044B (en) | Solution treatment method for manufacturing high-temperature alloy by laser additive | |
CN1061072A (en) | Industrial gas turbine engine bucket and manufacture method thereof | |
TW202212028A (en) | Shaped body manufacturing method, intermediate body, and shaped body | |
Liu et al. | Effects of annealing treatment on microstructure and tensile properties of Ti-48Al-2Cr-2Nb-5Ta alloy by laser additive manufacturing |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |