CN114958221A - Flexible protective film for display screen - Google Patents

Flexible protective film for display screen Download PDF

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Publication number
CN114958221A
CN114958221A CN202110214034.0A CN202110214034A CN114958221A CN 114958221 A CN114958221 A CN 114958221A CN 202110214034 A CN202110214034 A CN 202110214034A CN 114958221 A CN114958221 A CN 114958221A
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CN
China
Prior art keywords
parts
display screen
protective film
flexible protective
tackifying resin
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Granted
Application number
CN202110214034.0A
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Chinese (zh)
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CN114958221B (en
Inventor
金闯
梁豪
丁豪杰
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Taicang Sidike New Material Science and Technology Co Ltd
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Taicang Sidike New Material Science and Technology Co Ltd
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Priority to CN202110214034.0A priority Critical patent/CN114958221B/en
Publication of CN114958221A publication Critical patent/CN114958221A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/318Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)

Abstract

The invention discloses a flexible protective film for a display screen, which is characterized in that: the flexible protective film comprises a release film, a PET substrate layer and an optical adhesive layer positioned between the release film and the PET substrate layer, wherein the optical adhesive layer comprises the following components in parts by weight: 100 parts of acrylic resin, 1-5 parts of tetrahydrofuran acrylate, 5-8 parts of acrylic soft monomer, 6-10 parts of hydroxyethyl acrylate, 3-6 parts of tackifying resin, 1-2 parts of flatting agent, 0.4-1.2 parts of photoinitiator, 0.5-1 part of cellulose acetate butyrate and 2-5 parts of polyoxyethylene polyoxypropylene ether. The flexible protective film for the display screen overcomes the defect that the liquid crystal screen is easy to age and yellow due to continuous radiation and long-term use, and can maintain a transparent state for a long time, thereby improving the reliability of the product.

Description

Flexible protective film for display screen
Technical Field
The invention relates to the field of protective films, in particular to a flexible protective film for a display screen.
Background
China is a large producing and consuming country of displays, the market demand is large, but optical adhesives with excellent performance almost completely depend on import, and the localization process of the display industry in China is seriously hindered. The existing display screen protective film is easy to yellow after being used for a long time.
Disclosure of Invention
The invention aims to provide a flexible protective film for a display screen, which overcomes the defects of easy aging and yellowing caused by continuous radiation from a liquid crystal screen and long-term use, and can maintain a transparent state for a long time, thereby improving the reliability of products.
In order to achieve the purpose, the technical scheme of the brightener is as follows: the utility model provides a flexible protection pad pasting for display screen, flexible protection pad pasting is including leaving type membrane, PET substrate layer and being located from the optics glue film between type membrane and the PET substrate layer, optics glue film comprises the component of following parts by weight:
100 parts of acrylic resin, namely 100 parts of acrylic resin,
1-5 parts of tetrahydrofuran acrylate,
5-8 parts of acrylic acid soft monomer,
6-10 parts of hydroxyethyl acrylate,
3-6 parts of tackifying resin,
1-2 parts of a leveling agent,
0.4 to 1.2 parts of photoinitiator,
0.5 to 1 part of acetic acid-cellulose butyrate,
2-5 parts of polyoxyethylene polyoxypropylene amine ether.
The technical scheme of further improvement in the technical scheme is as follows:
1. in the scheme, the tackifying resin comprises one or more of C5 series tackifying resin, C9 series tackifying resin, terpene tackifying resin and hydrogenated rosin tackifying resin.
2. In the scheme, the flatting agent is at least one of an acrylate flatting agent, an organic silicon flatting agent and a fluorocarbon flatting agent.
3. In the scheme, the acrylic acid soft monomer is isooctyl methacrylate or lauryl acrylate.
4. In the scheme, the acrylic acid soft monomer is isooctyl methacrylate or lauryl acrylate.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
according to the flexible protective film for the display screen, the optical adhesive layer of the flexible protective film is added with 0.5-1 part of cellulose acetate-butyrate and 2-5 parts of polyoxyethylene polyoxypropylene ether based on 1-5 parts of tetrahydrofuran acrylate and 6-10 parts of hydroxyethyl acrylate, so that the defects of easy aging and yellowing caused by continuous radiation from a liquid crystal screen and long-term use are overcome, and the transparent state can be maintained for a long time, so that the reliability of a product is improved.
Drawings
FIG. 1 is a schematic structural diagram of a flexible optical adhesive film according to the present invention.
In the drawings above: 1. a release film; 2. a PET substrate layer; 3. and an optical adhesive layer.
Detailed Description
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. indicate orientations or positional relationships based on the illustrated orientations or positional relationships, and are only used for convenience of description and simplification of the description, but do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention; the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance; furthermore, unless expressly stated or limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, as they may be fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
The invention is further described below with reference to the following examples:
examples 1 to 4: the utility model provides a flexible protection pad pasting for display screen, flexible protection pad pasting is including leaving type membrane, PET substrate layer and being located from the optics glue film between type membrane and the PET substrate layer, optics glue film comprises the component of following parts by weight, as shown in Table 1:
TABLE 1
Components Example 1 Example 2 Example 3 Example 4
Acrylic resin 100 portions of 100 portions of 100 portions of 100 portions of
Tetrahydrofuran acrylic ester 1 part of 2 portions of 4 portions of 3 portions of
Acrylic acid soft monomer 6 portions of 7 portions of 5.5 parts of 8 portions of
Acrylic acid hydroxy ethyl ester 8 portions of 6 portions of 7 portions of 9 portions of
Tackifying resins 4 portions of 6 portions of 4 portions of 5 portions of
Leveling agent 1.5 parts of 1 part of 1.2 parts of 1.8 parts of
Photoinitiator 1 part of 0.6 part of 1 part of 0.8 portion of
Cellulose acetate butyrate 1 part of 0.6 part of 1 part of 0.8 portion of
Polyoxyethylene polyoxypropylene amine ether 5 portions of 3 portions of 4 portions of 3 portions of
In example 1, the tackifying resin was a C5-series tackifying resin, the leveling agent was an organic silicon-based leveling agent, the soft acrylic monomer was isooctyl methacrylate, the soft acrylic monomer was lauryl acrylate, and the photoinitiator was 1-hydroxycyclohexyl phenyl ketone.
In example 2, the tackifying resin was a terpene tackifying resin, the leveling agent was an acrylate leveling agent, the soft acrylic monomer was lauryl acrylate, the soft acrylic monomer was isooctyl methacrylate, and the photoinitiator was 2-isopropyl thioxanthone.
In example 3, the tackifying resin is a hydrogenated rosin tackifying resin, the leveling agent is a fluorocarbon leveling agent, the soft acrylic monomer is isooctyl methacrylate, and the photoinitiator is 1-hydroxycyclohexyl phenyl ketone.
In example 4, the tackifier resin was a C5-series tackifier resin, the leveling agent was a silicone-based leveling agent, the soft acrylic monomer was lauryl acrylate, and the photoinitiator was 2-isopropyl thioxanthone.
The preparation method of the flexible protection film for the display screen comprises the following steps:
step one, mixing 100 parts of acrylic resin and 1-5 parts of tetrahydrofuran acrylate to form a first mixture;
secondly, adding 5-8 parts of acrylic acid soft monomer, 6-10 parts of hydroxyethyl acrylate, 3-6 parts of tackifying resin, 1-2 parts of flatting agent, 0.5-1 part of acetic acid-cellulose butyrate and 2-5 parts of polyoxyethylene polyoxypropylene amine ether into the first mixture in sequence, and mixing to form a second mixture;
adding 0.4-1.2 parts of photoinitiator into the second mixture, uniformly stirring to form adhesive, and coating the adhesive on the surface of the PET base material layer;
and step four, adhering the film obtained in the step three to a release film after ultraviolet irradiation to form the flexible protection adhesive film.
Comparative examples 1 to 2: the utility model provides a protection pad pasting, flexible protection pad pasting is including leaving type membrane, PET substrate layer and being located from the optics glue film between type membrane and the PET substrate layer, optics glue film comprises the component of following parts by weight, as shown in Table 2:
TABLE 2
Components Comparative example 1 Comparative example 2
Acrylic resin 100 portions of 100 portions of
Tetrahydrofuran acrylic ester 1 part of 1 part of
Acrylic acid soft monomer 6 portions of 6 portions of
Acrylic acid hydroxy ethyl ester 8 portions of 8 portions of
Tackifying resins 4 portions of 4 portions of
Leveling agent 1.5 parts of 1.5 parts of
Photoinitiator 1 part of 1 part of
Cellulose acetate butyrate - 1 part of
Polyoxyethylene polyoxypropylene amine ether 5 portions of -
The tackifying resin in comparative examples 1 and 2 was a C5 series tackifying resin, the leveling agent was a silicone-based leveling agent, the soft acrylic monomer was isooctyl methacrylate, the soft acrylic monomer was lauryl acrylate, and the photoinitiator was 1-hydroxycyclohexyl phenyl ketone.
The comparative example was prepared in the same manner as in the example.
The films obtained in example 1 and comparative examples 1 to 3 were put into a UV aging oven at 60 ℃ and 0.9w/cm 2 Standing for 400h, testing the yellow index of the aged sample,as shown in table 3:
TABLE 3
Test items Example 1 Comparative example 1 Comparative example 2
Yellow index 0.16 0.38 0.35
As shown in the evaluation results of Table 3, the yellowness index of example 1 is lower than that of comparative examples 1 and 2, which shows that the adhesive film of the present invention is not easily aged and yellowed due to long-term use, thereby improving the reliability of the product.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.

Claims (6)

1. The utility model provides a flexible protection pad pasting for display screen which characterized in that: the flexible protective film comprises a release film (1), a PET substrate layer (2) and an optical adhesive layer (3) positioned between the release film (1) and the PET substrate layer (2), wherein the optical adhesive layer (3) comprises the following components in parts by weight:
100 parts of acrylic resin, namely 100 parts of acrylic resin,
1-5 parts of tetrahydrofuran acrylate,
5-8 parts of acrylic acid soft monomer,
6-10 parts of hydroxyethyl acrylate,
0 to 6 parts of tackifying resin,
1-2 parts of a leveling agent,
0.4 to 1.2 parts of photoinitiator,
0.5 to 1 part of acetic acid-cellulose butyrate,
2-5 parts of polyoxyethylene polyoxypropylene amine ether.
2. The flexible protective film for a display screen according to claim 1, wherein: the tackifying resin comprises one or more of C5 series tackifying resin, C9 series tackifying resin, terpene tackifying resin and hydrogenated rosin tackifying resin.
3. The flexible protective film for a display screen according to claim 1, wherein: the flatting agent is at least one of an acrylate flatting agent, an organic silicon flatting agent and a fluorocarbon flatting agent.
4. The flexible protective film for a display screen according to claim 1, wherein: the acrylic acid soft monomer is isooctyl methacrylate or lauryl acrylate.
5. The flexible protective film for a display screen according to claim 1, wherein: the photoinitiator is 1-hydroxycyclohexyl phenyl ketone, 2-benzyl-2-dimethylamine-1- (4-morpholine benzyl phenyl) butanone or 2-isopropyl thioxanthone.
6. A method for preparing a flexible protective film for a display screen according to claim 1, wherein the method comprises the following steps: the method comprises the following steps:
step one, mixing 100 parts of acrylic resin and 1-5 parts of tetrahydrofuran acrylate to form a first mixture;
secondly, sequentially adding 5-8 parts of acrylic acid soft monomer, 6-10 parts of hydroxyethyl acrylate, 3-6 parts of tackifying resin, 1-2 parts of flatting agent, 0.5-1 part of cellulose acetate-butyrate and 2-5 parts of polyoxyethylene polyoxypropylene amine ether into the first mixture, and mixing to form a second mixture;
adding 0.4-1.2 parts of photoinitiator into the second mixture, uniformly stirring to form adhesive, and coating the adhesive on the surface of the PET base material layer;
and step four, adhering the film obtained in the step three to a release film after ultraviolet irradiation to form the flexible protection adhesive film.
CN202110214034.0A 2021-02-26 2021-02-26 Flexible protective film for display screen Active CN114958221B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5183831A (en) * 1991-08-22 1993-02-02 Ciba-Geigy Corporation Radiation curable composition with high temperature oil resistance
CN101575173A (en) * 2008-05-05 2009-11-11 王广武 UV light- curable glue film glass and manufacture method thereof
CN101589125A (en) * 2007-01-22 2009-11-25 信越化学工业株式会社 The blooming of binder composition and band tackiness agent
CN103184019A (en) * 2011-12-29 2013-07-03 第一毛织株式会社 Adhesive used for polarizing plate, polarizing plate including an adhesive layer, and optical member
CN103339534A (en) * 2010-12-24 2013-10-02 宇部日东化成株式会社 Anti-reflection material
CN103589382A (en) * 2012-08-14 2014-02-19 广东泰强化工实业有限公司 All-purpose glue
CN109535334A (en) * 2018-10-30 2019-03-29 西安点云生物科技有限公司 One kind is for quickly molding photosensitive resin of continuous liquid level and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5183831A (en) * 1991-08-22 1993-02-02 Ciba-Geigy Corporation Radiation curable composition with high temperature oil resistance
CN101589125A (en) * 2007-01-22 2009-11-25 信越化学工业株式会社 The blooming of binder composition and band tackiness agent
CN101575173A (en) * 2008-05-05 2009-11-11 王广武 UV light- curable glue film glass and manufacture method thereof
CN103339534A (en) * 2010-12-24 2013-10-02 宇部日东化成株式会社 Anti-reflection material
CN103184019A (en) * 2011-12-29 2013-07-03 第一毛织株式会社 Adhesive used for polarizing plate, polarizing plate including an adhesive layer, and optical member
CN103589382A (en) * 2012-08-14 2014-02-19 广东泰强化工实业有限公司 All-purpose glue
CN109535334A (en) * 2018-10-30 2019-03-29 西安点云生物科技有限公司 One kind is for quickly molding photosensitive resin of continuous liquid level and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴健伟等: """UV-固化胶黏剂收缩率的研究"", 《化学与黏合》, vol. 27, no. 2, pages 96 - 100 *

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