CN114958121A - Water-based tile paint and preparation method and application method thereof - Google Patents
Water-based tile paint and preparation method and application method thereof Download PDFInfo
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- CN114958121A CN114958121A CN202210833118.7A CN202210833118A CN114958121A CN 114958121 A CN114958121 A CN 114958121A CN 202210833118 A CN202210833118 A CN 202210833118A CN 114958121 A CN114958121 A CN 114958121A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The application discloses waterborne ceramic tile paint, it includes main agent and curing agent, wherein, main agent and curing agent are according to weight ratio 100: (1-5) mixing in proportion; the main agent comprises the following components in parts by weight: 25-65 parts of acrylic emulsion; 0.5-10 parts of a film-forming assistant; 0.05-2 parts of a wetting agent; 0.01-2 parts of a defoaming agent; 0.1-10 parts of polyethylene wax; 0.05-5 parts of rheological additive; 0-40 parts of color paste; 5-25 parts of water; the preparation method comprises the following steps: firstly, preparing color paste, then mixing the color paste with other raw materials to prepare a main agent, and then mixing the main agent and a curing agent to prepare the water-based ceramic tile paint; the use method of the paint can be directly brushed on a ceramic tile substrate without polishing, and the paint has the effects of excellent adhesive force, water resistance and stain resistance.
Description
Technical Field
The application relates to the field of water-based paint, in particular to water-based tile paint and a preparation method and a use method thereof.
Background
Tiles are mostly used in bathroom, toilet, kitchen and other decorations in China, but as the use time increases, the surfaces of the tiles become yellow and dirty after stains such as oil stains, water rust, soap scum and the like are attached, and the tiles are not beautiful. If the method of re-laying the ceramic tiles is adopted, the time and the labor are consumed, and the cost is higher; if the method of tile sticking and paving is adopted, the tile is difficult to be paved and leveled and is not resistant to dirt due to high operation difficulty.
Disclosure of Invention
The inventor finds that the water-based paint on the market is used for renovating tiles at present and can achieve the aim of renovating and color-changing old tiles, but the water-based paint film is easy to drop due to the reasons of poor paint adhesion, poor water resistance and the like, so that the inventor designs the water-based tile paint which is used for renovating the tiles and can solve the problems of poor water-based paint film adhesion, poor water resistance and the like.
In a first aspect, the application provides a water-based tile paint, which adopts the following technical scheme: the adhesive comprises a main agent and a curing agent, wherein the main agent and the curing agent are mixed according to the weight ratio of 100: (1-5) mixing in proportion;
the main agent comprises the following components in parts by weight:
25-65 parts of acrylic emulsion;
0.5-10 parts of a film-forming assistant;
0.05-2 parts of a wetting agent;
0.01-2 parts of a defoaming agent;
0.1-10 parts of polyethylene wax;
0.05-5 parts of rheological additive;
0-40 parts of color paste;
5-25 parts of water.
The acrylic emulsion is subjected to modification pretreatment by an epoxy silane coupling agent.
The pretreatment step specifically comprises the following steps: and adding an epoxy silane coupling agent into the acrylic emulsion, uniformly mixing, and standing for 20-24 h.
The dosage of the epoxy silane coupling agent is 0.1-10 wt% of the acrylic emulsion.
An emulsifier is also added in the pretreatment process.
The dosage of the emulsifier is 0.1-5 wt% of the epoxy silane coupling agent.
The color paste comprises the following components in parts by weight:
15-30 parts of water;
0.5-10 parts of a dispersing agent;
0.1-5 parts of propylene glycol;
0.01-1 part of defoaming agent;
65-85 parts of toner.
The dispersant is at least one of nonionic wetting dispersant and macromolecular dispersant.
In a second aspect, the present application also provides a method for preparing an aqueous tile paint, comprising the steps of: firstly, preparing color paste; uniformly mixing acrylic emulsion, a film forming aid, a wetting agent, a defoaming agent, polyethylene wax, a rheological aid and water, slowly adding color paste while stirring, and uniformly mixing to obtain a main agent; and uniformly mixing the main agent and the curing agent to obtain the water-based ceramic tile paint.
In a third aspect, the application also provides a using method of the water-based tile paint, wherein the main agent and the curing agent are uniformly mixed and then directly brushed on the surface of a tile substrate.
Because the surface of the ceramic tile is smooth and has low roughness, and besides, the surface of the old ceramic tile has dirt such as dust, oil stain and the like, the adhesive force of the traditional coating on the surface of the ceramic tile base material is much poorer than that of the surface of other base materials; in addition, in order to cover the yellowing phenomenon of old tiles, proper pigments are often required to be added into the paint to provide covering power, but the cohesion of the tile paint is reduced, and the adhesion of a paint film on the surface of the tiles is influenced. In order to solve the problems, the application improves the adhesive force of a paint film when the paint film is used on a tile substrate through special crosslinking reaction among raw materials, so that the water resistance and the stain resistance of the tile are further improved.
In summary, the present application includes at least one of the following beneficial technical effects: through formula design and raw material selection, and the acrylic emulsion is subjected to modification crosslinking pretreatment to form a compact crosslinking network, so that the strength of a paint film is enhanced, the adhesive force of the tile paint is improved, and the water resistance and the stain resistance of a tile painted with the tile paint are improved;
according to the preparation method, the color paste is prepared by firstly preparing the toner, and then the color paste is added into the acrylic emulsion, so that the dispersion effect of the color paste in the acrylic emulsion is good, the uniformity of the acrylic emulsion is good, the cohesion of the ceramic tile paint can be further enhanced, the paint film strength is high, the pollution resistance is good, the adhesive force of the paint film can be improved, and the problems that the paint film is easy to peel off, orange peel and the like can be solved.
Detailed Description
The present application will be described in further detail with reference to examples.
The application provides a water-based tile paint, which comprises a main agent and a curing agent, wherein the main agent and the curing agent are 100 percent by weight: (1-5) mixing in proportion;
the main agent comprises the following components in parts by weight:
25-65 parts of acrylic emulsion;
0.5-10 parts of a film-forming assistant;
0.05-2 parts of a wetting agent;
0.01-2 parts of a defoaming agent;
0.1-10 parts of polyethylene wax;
0.05-5 parts of rheological additive;
0-40 parts of color paste;
5-25 parts of water.
The curing agent is selected from a silane adhesion promoter, the general formula of which is RnSiX (4-n), wherein R is a non-hydrolyzed organic part and can be alkyl, aryl, an organic functional group or any combination of the groups. R provides compatibility with other compounds, silane and acrylic emulsion can form interpenetrating network polymer, alkyl and aryl silane can also improve the glossiness, hiding power and miscibility of paint film and improve the wettability and dispersion performance of pigment, thus forming paint film with uniform color on the surface of the tile; x represents hydrolyzable alkoxy part, such as methoxy or ethoxy, which is easily hydrolyzed by moisture in the air or moisture on the surface of the tile to generate silanol, and further reacts with hydroxyl in different forms to release methanol or ethanol, and alkyl or silanol can be covalently or hydrogen-bonded with the surface of the tile substrate and pigment, so that the adhesion of the paint film is improved, and the alkoxy can also directly generate crosslinking reaction with other hydroxyl polymers in raw materials, so that the overall strength of the paint film is improved, and the water resistance and the stain resistance of the paint film are improved. Specifically, the curing agent may be gamma-methacryloxypropyltriethoxysilane.
In the present invention, the weight ratio of the main agent to the curing agent may be 100:1, 100:2, 100:3, 100:4, 100:5, etc., and preferably, the weight ratio of the main agent to the curing agent is 100: 2.
In the invention, the acrylic emulsion is subjected to modification pretreatment by an epoxy silane coupling agent.
In one embodiment, the preprocessing step specifically includes: and adding an epoxy silane coupling agent into the acrylic emulsion, uniformly mixing, and standing for 20-24 h. In the standing process, the epoxy silane coupling agent and acrylic acid are pre-crosslinked to form an interpenetrating network structure, and alkyl of the epoxy silane coupling agent can be connected with other inorganic raw materials through hydrogen bonds, so that the cohesion of the tile paint is improved, the strength of a paint film after film formation and the adhesive force of the tile paint are improved, and the water resistance and the dirt resistance of the paint film are further improved.
In a preferred embodiment, the epoxy silane coupling agent is used in an amount of (0.1-10) wt% of the acrylic emulsion. Specifically, the epoxy silane coupling agent may be used in an amount of 0.1 wt%, 1 wt%, 2 wt%, 5 wt%, 6 wt%, 8 wt%, 10 wt%, etc. of the acrylic emulsion.
According to the invention, the acrylic emulsion is subjected to crosslinking pretreatment by using the epoxy silane coupling agent, the epoxy silane coupling agent and acrylic acid form an interpenetrating network polymer, so that the critical surface tension of the coating on the surface of the ceramic tile is favorably reduced, and a spontaneous wetting effect is generated.
And the epoxy silane coupling agent can be connected with other components in the raw materials through covalent bonds or hydrogen bonds, so that the compatibility and crosslinking acting force among the raw materials are improved, a uniform paint film with high strength is formed, and the water resistance of the paint film is improved. Meanwhile, the epoxy silane coupling agent also has hydrophobic and oleophobic groups, so that the water resistance and oil stain resistance of a paint film can be improved.
Specifically, the epoxy silane coupling agent may be at least one selected from the group consisting of 3- (2, 3-glycidoxy) propyltrimethoxysilane, 3- (2, 3-glycidoxy) propyltriethoxysilane, 3- (2, 3-glycidoxy) propylmethyldimethoxysilane, 3- (2, 3-glycidoxy) propylmethyldiethoxysilane and 2- (3, 4-epoxycyclohexane) ethyltrimethoxysilane.
In the invention, an emulsifier is also added in the pretreatment process. Specifically, the emulsifier is one of polyoxyethylene ether, ethylene oxide and propylene oxide block copolymers, can form an interface film in an epoxy silane coupling agent and water system to protect the epoxy silane coupling agent, and reduces the probability of pre-crosslinking between the epoxy silane coupling agent and water in acrylic emulsion, so that the epoxy silane coupling agent can fully contact with acrylic acid, and the loss of the epoxy silane coupling agent is reduced.
In a preferred embodiment, the emulsifier is used in an amount of (0.1 to 5) wt% of the epoxy silane coupling agent, and specifically, may be 0.1 wt%, 0.5 wt%, 1 wt%, 2 wt%, 3 wt%, 4 wt%, 5 wt%, etc., preferably 0.5 to 1 wt%.
In the invention, the film-forming assistant is a mixture of DPNB and DPM, and the mass ratio of DPNB to DPM is (0.1-1): (0.1-1), the combination of DPNB and DPM can accelerate the film forming speed and improve the strength of the paint film.
In the invention, the wetting agent is an organic silicon wetting agent which can reduce the surface energy of the liquid, thereby carrying out good substrate wetting action on the surface of the ceramic tile and leading a paint film to have good anti-shrinkage performance; meanwhile, the coating can be compounded with polyethylene wax to improve the scratch resistance of a paint film. The silicone wetting agent may be polyether modified polydimethylsiloxane such as digao 270.
In the invention, the defoaming agent is an organic silicon defoaming agent which has a long-term defoaming function, such as polydimethylsiloxane containing acrylate functional groups and polyether modified polydimethylsiloxane, such as digao 810.
In the invention, the rheological additive is a polyurethane thickener, which has the functions of anti-settling and thickening, such as TEGO Visco plus 3010.
In the invention, the color paste comprises the following components in parts by weight:
15-30 parts of water;
0.5-10 parts of a dispersant;
0.1-5 parts of propylene glycol;
0.01-1 part of defoaming agent;
65-85 parts of toner.
In a specific embodiment, the dispersant is at least one of a nonionic wetting dispersant and a high molecular dispersant, and can wrap the toner powder; wherein, the nonionic wetting dispersant can be alkylphenol polyoxyethylene ether, such as nonylphenol polyoxyethylene ether NP-10, octylphenol polyoxyethylene ether, dodecyl polyoxyethylene ether, etc.; the polymeric dispersant may be a polymethacrylate-polymethacrylic acid block copolymer.
The propylene glycol has a moisturizing effect;
the defoaming agent is selected from emulsion type, such as BYK-025;
the toner is usually titanium dioxide, and has good covering power.
In addition, in the invention, a mildew preventive can be added to prevent the mildew of the paint film; preservatives are added to prevent the film from rotting.
Preparation of color paste
Preparation example 1
2.5kg of water, 0.2kg of propylene glycol, 0.02kg of organic silicon defoamer, 0.4kg of non-ionic wetting dispersant and 6.88kg of titanium dioxide are uniformly mixed to prepare uniform color paste.
Wherein, the organic silicon defoamer selects BYK-025; NP-10 is selected as the non-ionic wetting dispersant.
Preparation example 2
2.5kg of water, 0.2kg of propylene glycol, 0.02kg of organic silicon defoamer, 0.4kg of polymer dispersant and 6.88kg of titanium dioxide are uniformly mixed to prepare uniform color paste.
Wherein, the organic silicon defoamer selects BYK-025; the polymer dispersant is polymethacrylate-polymethacrylate block copolymer.
Example 1
The preparation method of the water-based tile paint comprises the following steps:
1. adding 0.03kgDPNB and 0.035kgDPM into 2.5kg of acrylic emulsion, then adding 0.005kg of organic silicon wetting agent, 0.001kg of organic silicon defoamer, 0.4kg of polyethylene wax, 0.03kg of polyurethane thickener and 0.2kg of water, uniformly mixing, then slowly adding 1.48kg of the color paste prepared in the preparation example 1 while stirring, and uniformly mixing to obtain a main agent;
2. and uniformly mixing the main agent and the silane adhesive force curing agent in a ratio of 100:2 to prepare the water-based tile paint.
Wherein the organic silicon wetting agent is polyether modified polydimethylsiloxane; the organic silicon defoamer is polydimethylsiloxane; the polyurethane thickener is TEGO ViscoPlus 3010; the silane adhesive force curing agent is gamma-methacryloxypropyltriethoxysilane.
Example 2
The preparation method of the water-based tile paint comprises the following steps:
1. adding 0.3kg of DPNB and 0.35kg of DPM into 5kg of acrylic emulsion, then adding 0.03kg of organic silicon wetting agent, 0.05kg of organic silicon defoaming agent, 0.4kg of polyethylene wax, 0.03kg of polyurethane thickener and 0.2kg of water, uniformly mixing, then slowly adding 3.64kg of the color paste prepared in the preparation example 1 while stirring, and uniformly mixing to obtain a main agent;
2. and uniformly mixing the main agent and the silane adhesive force curing agent in a ratio of 100:2 to prepare the water-based tile paint.
Wherein the organic silicon wetting agent is polyether modified polydimethylsiloxane; the organic silicon defoaming agent is polydimethylsiloxane; the polyurethane thickener is TEGO ViscoPlus 3010; the silane adhesive force curing agent is gamma-methacryloxypropyltriethoxysilane.
Example 3
The preparation method of the water-based tile paint comprises the following steps:
1. adding 0.3kg of DPNB and 0.35kg of DPM into 5kg of acrylic emulsion, then adding 0.03kg of organic silicon wetting agent, 0.05kg of organic silicon defoaming agent, 0.4kg of polyethylene wax, 0.03kg of polyurethane thickener and 0.2kg of water, uniformly mixing, then slowly adding 3.64kg of the color paste prepared in the preparation example 1 while stirring, and uniformly mixing to obtain a main agent;
2. and uniformly mixing the main agent and the silane adhesive force curing agent in a ratio of 100:4 to prepare the water-based tile paint.
Wherein the organic silicon wetting agent is polyether modified polydimethylsiloxane; the organic silicon defoaming agent is polydimethylsiloxane; the polyurethane thickener is TEGO ViscoPlus 3010; the silane adhesive force curing agent is gamma-methacryloxypropyltriethoxysilane.
Example 4
The difference from example 2 is that a color paste was obtained according to preparation example 2.
Example 5
The preparation method of the water-based tile paint comprises the following steps:
1. taking 5kg of acrylic emulsion, adding 0.01kg of polydimethylsiloxane, uniformly mixing, standing for 24 hours, sequentially adding 0.3kg of DPNB and 0.35kg of DPM, further adding 0.03kg of organic silicon wetting agent, 0.05kg of organic silicon defoaming agent, 0.4kg of polyethylene wax, 0.03kg of polyurethane thickener and 0.2kg of water, uniformly mixing, slowly adding 3.64kg of the color paste prepared in the preparation example while stirring, and uniformly mixing to obtain a main agent;
2. and uniformly mixing the main agent and the silane adhesive force curing agent in a ratio of 100:2 to prepare the water-based tile paint.
Wherein the organic silicon wetting agent is polyether modified polydimethylsiloxane; the organic silicon defoaming agent is polydimethylsiloxane; the polyurethane thickener is TEGO ViscoPlus 3010; the silane adhesive force curing agent is gamma-methacryloxypropyltriethoxysilane.
Example 6
The difference from example 5 is that the amount of polydimethylsiloxane added was 0.001 kg.
Example 7
The difference from example 5 is that the amount of polydimethylsiloxane added was 1 kg.
Example 8
The difference from example 5 is that the acrylic emulsion in step 1 is directly mixed with other raw materials after the silanization crosslinking treatment.
Example 9
The preparation method of the water-based tile paint comprises the following steps:
1. 0.01kg of polydimethylsiloxane and 0.1g of polyoxyethylene ether are uniformly mixed and then added into 5kg of acrylic emulsion, the mixture is kept stand for 24 hours after being uniformly mixed, then 0.3kg of DPNB and 0.35kg of DPM are sequentially added, 0.03kg of organic silicon wetting agent, 0.05kg of organic silicon defoaming agent, 0.4kg of polyethylene wax, 0.03kg of polyurethane thickener and 0.2kg of water are added and uniformly mixed, then 3.64kg of the color paste prepared in the preparation example is slowly added while stirring, and the main agent is uniformly mixed to obtain the main agent.
2. And uniformly mixing the main agent and the silane adhesive force curing agent in a ratio of 100:2 to prepare the water-based tile paint.
Example 10
The difference from example 9 is that polyoxyethylene ether was added in an amount of 0.005 g.
Example 11
The difference from example 9 is that polyoxyethylene ether was added in an amount of 1 g.
Comparative example 1
The difference from example 1 is that equal quality toner is used instead of color paste.
Comparative example 2
The difference from example 5 is that equal quality toner is used instead of color paste.
Application of water-based ceramic tile paint
The tile paints of the above examples and comparative examples were directly painted on the surfaces of marble, ceramic tile, polished crystal tile and glass substrate, respectively, and the thickness was 0.1 mm.
Test of
1. And (3) testing the adhesive force: after painting with tile paint, the surface of marble, ceramic, polished crystal and glass substrates was tested according to GB/T9286-98 paint and varnish test, and the results are filled in the following table.
2. And (3) dirt resistance test: after drying for 7 days, the stain resistance is tested according to GB/T4893.1-2005 furniture surface cold-resistant liquid testing method, household articles such as coffee, soy sauce, black tea, green tea, red wine, mature vinegar, detergent and the like are selected, the time for slight mark to appear is taken as a test result, and the test results of the coffee in the test are filled in the following table.
TABLE 1
TABLE 2
TABLE 3
According to the above table, the water-based tile paint can be directly brushed on the surface of a tile device without polishing, and has an adhesive force of 0 grade and excellent adhesive force; and slight marks appear only in the stain resistance test of 7H, which is far beyond the national standard test time of 2H, and the water resistance and the stain resistance are excellent.
The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.
Claims (10)
1. The water-based tile paint is characterized by comprising a main agent and a curing agent, wherein the main agent and the curing agent are mixed according to a weight ratio of 100: (1-5) mixing in proportion;
the main agent comprises the following components in parts by weight:
25-65 parts of acrylic emulsion;
0.5-10 parts of a film-forming assistant;
0.05-2 parts of a wetting agent;
0.01-2 parts of a defoaming agent;
0.1-10 parts of polyethylene wax;
0.05-5 parts of rheological additive;
0-40 parts of color paste;
5-25 parts of water.
2. The aqueous tile paint of claim 1, wherein: the acrylic emulsion is subjected to modification pretreatment by an epoxy silane coupling agent.
3. The aqueous tile paint of claim 2, wherein: the pretreatment step specifically comprises the following steps: and adding an epoxy silane coupling agent into the acrylic emulsion, uniformly mixing, and standing for 20-24 h.
4. The aqueous tile paint of claim 2, wherein: the dosage of the epoxy silane coupling agent is 0.1-10 wt% of the acrylic emulsion.
5. The aqueous tile paint of claim 2, wherein: an emulsifier is also added in the pretreatment process.
6. The aqueous tile paint of claim 5, wherein: the dosage of the emulsifier is 0.1-5 wt% of the epoxy silane coupling agent.
7. The aqueous tile paint of claim 1, wherein: the color paste comprises the following components in parts by weight:
15-30 parts of water;
0.5-10 parts of a dispersing agent;
0.1-5 parts of propylene glycol;
0.01-1 part of defoaming agent;
65-85 parts of toner.
8. The water-based tile paint of claim 7, wherein the dispersant is at least one of a non-ionic wetting dispersant and a polymeric dispersant.
9. The preparation method of the water-based tile paint is characterized by comprising the following steps:
firstly, preparing color paste;
uniformly mixing acrylic emulsion, a film forming aid, a wetting agent, a defoaming agent, polyethylene wax, a rheological aid and water, slowly adding color paste while stirring, and uniformly mixing to obtain a main agent;
and uniformly mixing the main agent and the curing agent to obtain the water-based ceramic tile paint.
10. A method of using an aqueous tile paint, wherein the aqueous tile paint prepared according to claim 9 is directly brushed onto the surface of a tile substrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202210833118.7A CN114958121A (en) | 2022-07-15 | 2022-07-15 | Water-based tile paint and preparation method and application method thereof |
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| CN202210833118.7A CN114958121A (en) | 2022-07-15 | 2022-07-15 | Water-based tile paint and preparation method and application method thereof |
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