CN114957950A - 一种应用于液体中具有释放负离子的环保材料 - Google Patents
一种应用于液体中具有释放负离子的环保材料 Download PDFInfo
- Publication number
- CN114957950A CN114957950A CN202210791851.7A CN202210791851A CN114957950A CN 114957950 A CN114957950 A CN 114957950A CN 202210791851 A CN202210791851 A CN 202210791851A CN 114957950 A CN114957950 A CN 114957950A
- Authority
- CN
- China
- Prior art keywords
- releasing
- environment
- additive
- friendly material
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000002500 ions Chemical class 0.000 title claims abstract description 42
- 239000000463 material Substances 0.000 title claims abstract description 28
- 239000007788 liquid Substances 0.000 title claims abstract description 20
- 239000000654 additive Substances 0.000 claims abstract description 30
- 230000000996 additive effect Effects 0.000 claims abstract description 30
- 239000000835 fiber Substances 0.000 claims abstract description 25
- 150000001450 anions Chemical class 0.000 claims abstract description 11
- 150000001449 anionic compounds Chemical class 0.000 claims abstract description 10
- 229910001412 inorganic anion Inorganic materials 0.000 claims abstract description 10
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 10
- 239000004626 polylactic acid Substances 0.000 claims abstract description 10
- 239000004575 stone Substances 0.000 claims description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- 241000195493 Cryptophyta Species 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 238000009987 spinning Methods 0.000 claims description 3
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 abstract description 9
- 229940072056 alginate Drugs 0.000 abstract description 9
- 235000010443 alginic acid Nutrition 0.000 abstract description 9
- 229920000615 alginic acid Polymers 0.000 abstract description 9
- 230000002265 prevention Effects 0.000 abstract description 4
- 230000005670 electromagnetic radiation Effects 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000047875 Pica hudsonia Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910001953 rubidium(I) oxide Inorganic materials 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2262—Oxides; Hydroxides of metals of manganese
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
Abstract
本发明提供了一种应用于液体中具有释放负离子的环保材料，属于环保材料技术领域。本发明提供的应用于液体中具有释放负离子的环保材料，按重量百分比计，包括如下组分：聚乳酸90‑95％；负离子添加剂5‑10％；负离子添加剂包括无机释放负离子添加剂和海洋纤维。本发明以无机释放负离子添加剂和海藻纤维作为释放负离子的添加剂，充分利用海藻纤维具有释放负离子功能，且具有抑菌防霉、阻燃、防电磁辐射的作用。
Description
技术领域
本发明涉及环保材料技术领域，尤其涉及一种应用于液体中具有释放负离子的环保材料。
背景技术
早在1889年，德国科学家埃尔斯特和格特尔发现了空气负离子的存在，1902年，科学界就已经肯定了空气负离子的生物学意义。上个世纪末，Kubo对电气石电解水释放空气负离子的行为进行了研究，引起了全世界的广泛关注。近年来，国内外对于空气负离子的研究正方兴未艾，并且已经取得了一系列的成果。在健康环保观念已经深入人心的今天，释放负离子液体材料以其健康、环保、节能的优点，正日益吸引人们的眼球。其在室内装修材料、生活用品、卫生洁具、车内装饰液体材料等方面的发展前景不可估量。
然而，在现有技术中，目前尚未有关于利用海洋纤维作为释放负离子液体材料的研究。
发明内容
有鉴于此，为解决上述背景技术中存在的不足，本发明提供了一种应用于液体中具有释放负离子的环保材料，其具有能够显著的释放负离子的技术效果。
为实现上述目的，本发明提供了如下的技术方案：
一种应用于液体中具有释放负离子的环保材料，按重量百分比计，包括如下组分：
聚乳酸90-95％；
负离子添加剂5-10％；
所述负离子添加剂包括无机释放负离子添加剂和海洋纤维。
优选地，按占液体环保材料的重量百分比计，所述无机释放负离子添加剂为1-4％，海洋纤维为4-6％。
优选地，所述无机释放负离子添加剂为矿物类无机释放负离子添加剂。
优选地，所述矿物类无机释放负离子添加剂为六环石。
优选地，所述海洋纤维为从海洋藻类植物中提取得到的海藻酸钠为原料经纺丝制得的生物基纤维。
本发明相对于现有技术，具有如下的有益效果：
1.本发明提供的应用于液体中具有释放负离子的环保材料，以无机释放负离子添加剂和海藻纤维作为释放负离子的添加剂，充分利用海藻纤维具有释放负离子功能，且具有抑菌防霉、阻燃、防电磁辐射的作用。
2.本发明提供的应用于液体中具有释放负离子的环保材料，其中，以六环石作为矿物类无机释放负离子添加剂，充分利用六环石能够释放4000个/cm3，使液体环保材料具有优良的释放负离子的功能。
具体实施方式
本发明提供了一种应用于液体中具有释放负离子的环保材料，按重量百分比计，包括如下组分：
聚乳酸90-95％，优选为90％；
负离子添加剂5-10％，优选为10％；
所述负离子添加剂包括无机释放负离子添加剂和海洋纤维。
在本发明中，按占液体环保材料的重量百分比计，所述无机释放负离子添加剂为1-4％，优选为2％，海洋纤维为4-6％，优选为8％。
在本发明中，所述无机释放负离子添加剂为矿物类无机释放负离子添加剂。
在本发明中，所述矿物类无机释放负离子添加剂为六环石。
本发明中，六环石指的是天然六环石，产于内蒙古包头市属地黄河流域，生成于奥陶系，距今2亿4千万年，属沉积岩。经方解石切割成有规则的块体，在块体中心由褐铁矿经周期性沉淀而形成的环，其具有耐高温、保健功能、释放负离子的功能等。其主要成分如下：
CaO 44.1％，MgO 23.6％,SiO220.6％，Al2O35.6％,K2O2.82％,Fe2O32.59％，TiO20.32％,P2O5 830ppm，CuO 740ppm,MnO 680ppm,SO3 590ppm,SrO 410ppm,Rb2O 99ppm，V2O576ppm，ZrO233ppm。
在本发明中，所述海洋纤维为从海洋藻类植物中提取得到的海藻酸钠为原料经纺丝制得的生物基纤维，海藻纤维具有优良的阻燃性、抑菌防霉性、释放负离子和防电磁辐射的性能，其中，海藻纤维，抗菌性能达到国家3A标准，抗菌率达99％以上；防霉性能达到国家0级标准。
上述应用于液体中具有释放负离子的环保材料的制备方法为：按照一定比例将聚乳酸和负离子添加剂加入到常规的加工设备中(如挤出机)，经捏合、混炼、挤出和造粒而得到具有释放负离子的环保材料。
下面结合具体实施例对本发明的技术方案进行清楚详细的解释。
实施例1
聚乳酸90％，六环石2％，海藻纤维8％。
实施例2
聚乳酸95％，六环石4％，海藻纤维1％。
实施例3
聚乳酸93％，六环石2％，海藻纤维5％。
实施例4
聚乳酸95％，六环石3％，海藻纤维2％。
实施例4
聚乳酸90％，六环石5％，海藻纤维5％。
以上实施例1-5的负离子浓度使用日本ECO-HOLISTIC公司的EB13型离子检测器进行测量，其结果如下表格：
| 实施例 | 负离子浓度个/cm<sup>3</sup> |
| 实施例1 | 6540 |
| 实施例2 | 6483 |
| 实施例3 | 6386 |
| 实施例4 | 6492 |
| 实施例5 | 6502 |
Claims (5)
1.一种应用于液体中具有释放负离子的环保材料，其特征在于，按重量百分比计，包括如下组分：
聚乳酸90-95％；
负离子添加剂5-10％；
所述负离子添加剂包括无机释放负离子添加剂和海洋纤维。
2.根据权利要求1所述的一种应用于液体中具有释放负离子的环保材料，其特征在于，按占液体环保材料的重量百分比计，所述无机释放负离子添加剂为1-4％，海洋纤维为4-6％。
3.根据权利要求1所述的一种应用于液体中具有释放负离子的环保材料，其特征在于，所述无机释放负离子添加剂为矿物类无机释放负离子添加剂。
4.根据权利要求3所述的一种应用于液体中具有释放负离子的环保材料，其特征在于，所述矿物类无机释放负离子添加剂为六环石。
5.根据权利要求1所述的一种应用于液体中具有释放负离子的环保材料，其特征在于，所述海洋纤维为从海洋藻类植物中提取得到的海藻酸钠为原料经纺丝制得的生物基纤维。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210791851.7A CN114957950A (zh) | 2022-07-07 | 2022-07-07 | 一种应用于液体中具有释放负离子的环保材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210791851.7A CN114957950A (zh) | 2022-07-07 | 2022-07-07 | 一种应用于液体中具有释放负离子的环保材料 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114957950A true CN114957950A (zh) | 2022-08-30 |
Family
ID=82966657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210791851.7A Pending CN114957950A (zh) | 2022-07-07 | 2022-07-07 | 一种应用于液体中具有释放负离子的环保材料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114957950A (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004084120A (ja) * | 2002-08-27 | 2004-03-18 | Toray Ind Inc | マイナスイオンを発生する生分解性詰め綿 |
| JP2008045053A (ja) * | 2006-08-18 | 2008-02-28 | Hino Jushi:Kk | 生分解性プラスチック組成物 |
| CN101575190A (zh) * | 2008-05-05 | 2009-11-11 | 张金玲 | 一种释放负离子发射远红外线的多功能六环石母料 |
| CN109438944A (zh) * | 2018-11-30 | 2019-03-08 | 万卓（武汉）新材料有限公司 | 一种海藻纤维复合增强可降解塑料瓶及其制备方法 |
| CN112076352A (zh) * | 2020-08-25 | 2020-12-15 | 云南科威液态金属谷研发有限公司 | 医用液态金属热塑性功能复合材料及其制备方法与应用 |
-
2022
- 2022-07-07 CN CN202210791851.7A patent/CN114957950A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004084120A (ja) * | 2002-08-27 | 2004-03-18 | Toray Ind Inc | マイナスイオンを発生する生分解性詰め綿 |
| JP2008045053A (ja) * | 2006-08-18 | 2008-02-28 | Hino Jushi:Kk | 生分解性プラスチック組成物 |
| CN101575190A (zh) * | 2008-05-05 | 2009-11-11 | 张金玲 | 一种释放负离子发射远红外线的多功能六环石母料 |
| CN109438944A (zh) * | 2018-11-30 | 2019-03-08 | 万卓（武汉）新材料有限公司 | 一种海藻纤维复合增强可降解塑料瓶及其制备方法 |
| CN112076352A (zh) * | 2020-08-25 | 2020-12-15 | 云南科威液态金属谷研发有限公司 | 医用液态金属热塑性功能复合材料及其制备方法与应用 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102584343B (zh) | 具有抗菌、易洁和活化水功能的能量陶瓷及其制备方法 | |
| US11174574B2 (en) | Plant-extract-containing polyester fiber | |
| CN102763678B (zh) | 立方体磷酸锆载银抗菌粉的制备方法 | |
| CN102816493B (zh) | 富含银硒锗多元素多功能健康益寿的纳米内墙环保涂料 | |
| CN105623326A (zh) | 一种纳米贝壳粉生态功能弹涂涂料 | |
| CN112007426B (zh) | 一种高性能介孔二氧化硅-壳聚糖复合的抗菌过滤片的制备方法 | |
| CN104878589A (zh) | 一种纺织品的整理剂的制备方法 | |
| CN102250456A (zh) | 一种抗菌聚乳酸餐具及其制备方法 | |
| CN107325730A (zh) | 一种多功能低碳养生涂料 | |
| CN105648745B (zh) | 织物用聚合物基铈掺杂纳米氧化锌复合抗菌剂及其制备方法 | |
| CN104206418A (zh) | 一种防变色粉状含银抗菌剂的制备方法和应用 | |
| CN101698769A (zh) | 一种预防流感病毒涂料及其制备方法 | |
| CN110204245A (zh) | 一种除醛负离子墙体材料 | |
| CN105174903A (zh) | 谐振生物能量陶瓷及其制备方法 | |
| CN114957950A (zh) | 一种应用于液体中具有释放负离子的环保材料 | |
| CN104628337A (zh) | 保温隔热材料 | |
| CN107266024A (zh) | 一种抗菌耐磨环保瓷砖及其制备方法 | |
| CN104876645B (zh) | 一种含玻璃丝抗菌釉料及其制作方法 | |
| CN105010398A (zh) | 一种负离子、远红外及复合功能性抗菌消毒剂的制备方法 | |
| CN104161044A (zh) | 一种有机/无机复合抗菌剂的制备方法和应用 | |
| CN108300055A (zh) | 基于低辐射高效负离子材料的涂料式应用及其制备工艺 | |
| CN116397440A (zh) | 一种含有益生菌微胶囊的功能性植物纤维 | |
| CN108976836A (zh) | 一种节能环保型耐磨墙纸及其制备方法 | |
| CN108084869A (zh) | 一种新型环保涂料及其制备方法 | |
| CN108455856A (zh) | 一种健康陶瓷釉料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220830 |