CN114940794A - Solid waste based PVC flame-retardant wood grain film and preparation method thereof - Google Patents
Solid waste based PVC flame-retardant wood grain film and preparation method thereof Download PDFInfo
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- CN114940794A CN114940794A CN202210566844.7A CN202210566844A CN114940794A CN 114940794 A CN114940794 A CN 114940794A CN 202210566844 A CN202210566844 A CN 202210566844A CN 114940794 A CN114940794 A CN 114940794A
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- 239000002023 wood Substances 0.000 title claims abstract description 58
- 239000002910 solid waste Substances 0.000 title claims abstract description 57
- 239000003063 flame retardant Substances 0.000 title claims abstract description 55
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 167
- 239000002893 slag Substances 0.000 claims abstract description 160
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 120
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 106
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 106
- 239000000428 dust Substances 0.000 claims abstract description 80
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 74
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 66
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 66
- 239000011574 phosphorus Substances 0.000 claims abstract description 66
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 60
- 239000004014 plasticizer Substances 0.000 claims abstract description 28
- 239000003381 stabilizer Substances 0.000 claims abstract description 28
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000227 grinding Methods 0.000 claims description 43
- 239000000126 substance Substances 0.000 claims description 35
- 239000002243 precursor Substances 0.000 claims description 25
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 12
- 239000012760 heat stabilizer Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 12
- 150000002910 rare earth metals Chemical class 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 22
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 11
- 239000010456 wollastonite Substances 0.000 abstract description 11
- 229910052882 wollastonite Inorganic materials 0.000 abstract description 11
- 238000000498 ball milling Methods 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 238000003490 calendering Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 33
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 30
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 24
- 229910010413 TiO 2 Inorganic materials 0.000 description 21
- 239000000463 material Substances 0.000 description 13
- 238000003801 milling Methods 0.000 description 13
- 239000011787 zinc oxide Substances 0.000 description 12
- 238000007731 hot pressing Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 229920001875 Ebonite Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K2003/2272—Ferric oxide (Fe2O3)
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C08K3/36—Silica
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
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Abstract
The invention provides a solid waste based PVC flame-retardant wood grain film and a preparation method thereof, belonging to the field of PVC calendering film matrix materials. The wood grain film comprises polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorous slag superfine powder. The invention utilizes a superfine tire vertical mill to form 2500-mesh diatomite superfine powder, 2500-mesh dust mud kiln slag superfine powder and 2500-mesh phosphorus slag superfine powder, and then the superfine powder, polyvinyl chloride, plasticizer, stabilizer and titanium dioxide are mixed to prepare the wood grain film. The invention solves the industrial bottlenecks of high price and large primary resource consumption in the production of PVC wood grain films by adopting titanium dioxide, active nano calcium carbonate and wollastonite; the flame retardance of the PVC wood grain film needs to be improved; the ball-milling method has the advantages that ball-milling is carried out by utilizing the ultra-fine powder which is high in energy consumption and processed, the ball-milling shape is not enough in fiber characteristics, solid wastes are fully utilized, and the current industrial development requirements of energy conservation, environmental protection and circular economy are met.
Description
Technical Field
The invention belongs to the field of PVC calendered film matrix materials, and particularly relates to a solid waste based PVC flame-retardant wood grain film and a preparation method thereof.
Background
The PVC wood grain film is a typical rolled film, can be compounded with materials such as wood, plastics, aluminum plates, steel plates and the like to prepare multifunctional decorative materials, and is widely applied to occasions such as household appliances, interior decoration, airplanes, ships, trains, billboards and the like. In the production formula of the PVC wood grain film, titanium dioxide, nanometer light calcium carbonate, wollastonite and the like are the most commonly used fillers. However, the prices of titanium dioxide, nano light calcium carbonate and wollastonite are continuously increased, so that the production cost of the PVC wood grain film is greatly increased.
The dust mud kiln slag is metallurgical solid waste generated after zinc oxide rotary kiln treatment of zinc-containing intermediate material, and the main chemical component of the dust mud kiln slag is Fe 2 O 3 、CaO、SiO 2 It is alkaline. The phosphorus slag is alkaline, and the main components of the phosphorus slag are CaO and SiO 2 、P 2 O 5 . Diatomite is a siliceous rock with SiO as the main chemical component 2 Since the impurity content is high, it cannot be directly utilized, and deep processing is required. If the ultrafine tire vertical mill (also called ultrafine roller milling) can be used for forming the diatomite ultrafine powder, the mud kiln slag ultrafine powder and the phosphorus slag ultrafine powder to replace nanometer light calcium carbonate and wollastonite, and the using amount of titanium dioxide is reduced, the using additional value of the diatomite, the mud kiln slag and the phosphorus slag can be improved, and the production cost of the PVC wood grain film is reduced.
Disclosure of Invention
Aiming at solving the industrial bottlenecks of high price and large consumption of primary resources in the production of PVC wood grain films by adopting titanium dioxide, active nano calcium carbonate and wollastonite; the flame retardance of the PVC wood grain film needs to be improved; the diatomite is spherical in shape and does not have the problem of fiber reinforcement performance; the material can be processed to the fineness of 450 meshes and the specific surface area of 500m by utilizing the conical vertical mill and the common tire vertical mill 2 The technical limitation of/kg; the ball-milling energy consumption is high, and the processed superfine powder forms a spherical shape without the defects of fiber characteristics. The invention utilizes a superfine tire vertical mill (also called superfine roller mill) to form 2500-mesh diatomite superfine powder, 2500-mesh dust mud kiln slag superfine powder and 2500-mesh phosphorus slag superfine powder, and then the superfine powder, polyvinyl chloride, plasticizer, stabilizer and titanium dioxide are mixed to prepare the solid waste base PVC flame retardant wood grain film, so as to solve the problems.
In order to solve the above technical problems, the present invention is realized by the following technical solutions.
The invention provides a solid waste based PVC flame-retardant wood grain film, which comprises the following raw materials in percentage by weight:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is 30-35%.
The invention also provides a preparation method of the solid waste base PVC flame-retardant wood grain film, which comprises the following steps:
premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 10-15 min; and (3) mixing for 15-20 min in a two-roll open mill with the front and rear roll temperature of 150-170 ℃ and the roll distance of 1mm to obtain the solid waste base PVC flame-retardant wood grain film precursor. And then the solid waste base PVC flame-retardant wood grain film precursor is hot-pressed for 15-20 min on a hydraulic flat press at 180-200 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
The innovation points of the invention are as follows:
(1) the superfine tyre vertical mill (also called superfine roller mill) uses motor to drive speed reducer to drive grinding disc to rotate, the material to be ground is fed into the centre of rotary grinding disc by means of air-locking feeding equipment, and under the action of centrifugal force the material can be moved toward the periphery of grinding disc, and fed into grinding roller table. Under the action of the roller pressure, the material is crushed by the extrusion, grinding and shearing actions. Meanwhile, air is uniformly sprayed upwards at a high speed from an air ring surrounding a grinding disc, the ground materials are blown up by a high-speed air flow at the air ring, the materials with coarser granularity are blown back to the grinding disc to be ground again, fine powder is brought into a grading machine by the air to be graded, qualified fine powder flows out of the grinding machine along with the same air, the fine powder is collected by a grading system (patent No. ZL201030143470.6) of secondary air separation to be a product, unqualified coarse powder falls on the grinding disc again under the action of blades of the grading machine and is ground again together with a newly fed material (patent No. ZL200820113450.1), and the circulation is carried out to obtain the superfine materials with the particle size of 3-10 mu m.
(2) 2500-mesh diatomite superfine powder, 2500-mesh dust mud kiln slag superfine powder and 2500-mesh phosphorus slag superfine powder which are formed by grinding by using a superfine tire vertical mill (also called superfine roller milling) are in gravel shapes (such as arris, sub-arris and sub-circle shapes) and have the fiber characteristics of rod-shaped materials. Not only breaks through the technical barrier that the powder ground by a common tire vertical mill (also called common roller milling) can only reach the fineness of 400, but also solves the technical problem that the ball-milled powder only forms a spherical appearance and does not have fiber characteristics. Wherein the common diatomite is spherical, and is ground into gravel (such as prismatic, sub-prismatic and sub-circular) by an ultrafine tire vertical mill (also called ultrafine roller grinding), and can replace ultrafine powder of needle-shaped wollastonite, so that the mechanical property is further improved.
(3) Fe in dust mud kiln slag 2 O 3 (32.25%) highest content of SiO in diatomaceous earth 2 (92.54%) and CaO (45.72%) and SiO in the phosphorus slag 2 (40.85%) and a certain amount of P 2 O 5 (3.91%). Fe when PVC wood grain film is burnt 2 O 3 、SiO 2 And P 2 O 5 Forming Si-P-Fe smoke abatement-flame retardant bodyIs to be prepared; the phosphorus slag with gravel-shaped appearance and high CaO content can replace nano light calcium carbonate and has gravel-shaped appearance and high SiO content 2 The diatomite can reduce the dosage of titanium dioxide. Meanwhile, the total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorus slag superfine powder meets 30-35 percent, so that the fluidity of the wood grain film precursor is ensured, and the film is conveniently formed.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention solves the industrial bottlenecks of high price and large primary resource consumption in the production of PVC wood grain films by adopting titanium dioxide, active nano calcium carbonate and wollastonite; the flame retardance of the PVC wood grain film needs to be improved; the diatomite is spherical in shape and does not have the problem of fiber reinforcement performance; the material can be processed to the fineness of 450 meshes and the specific surface area of 500m by utilizing the conical vertical mill and the common tire vertical mill 2 The technical limitation of/kg; the ball-milling energy consumption is high, and the processed superfine powder forms a spherical shape without the defects of fiber characteristics.
2. The invention fully utilizes solid wastes, utilizes an ultrafine tire vertical mill (also called ultrafine roller milling) to form 2500-mesh diatomite ultrafine powder, 2500-mesh dust mud kiln slag ultrafine powder and 2500-mesh phosphorus slag ultrafine powder, and then prepares the solid waste based PVC flame-retardant wood grain film with polyvinyl chloride, plasticizer, stabilizer and titanium dioxide, so as to solve the problems and meet the current industrial development requirements of energy conservation, environmental protection and recycling economy.
Drawings
FIG. 1 is an SEM image of dust mud and kiln slag ultrafine powder formed by ultrafine tire vertical mill grinding.
FIG. 2 is an SEM image of the phosphorous slag ultra-fine powder formed by grinding the ultra-fine tire in a vertical mill.
Detailed Description
The present invention will be described in detail with reference to specific examples, but the present invention is not limited to the examples.
Example 1
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is up to 32.5%.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 14 min; and (3) mixing for 20min in a two-roll open mill with the front and rear roll temperature of 150 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste PVC flame-retardant wood-grain film precursor for 19min on a hydraulic flat press at 185 ℃ to obtain the solid waste PVC flame-retardant wood-grain film.
Example 2
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder through a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is 33.5 percent.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 10 min; and (3) mixing for 16min in a two-roll open mill with the front and rear roll temperature of 165 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 15min on a hydraulic flat press at the temperature of 200 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
Example 3
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is up to 31%.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 15 min; and mixing for 18min in a two-roll open mill with the front and rear roll temperature of 155 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste PVC flame-retardant wood-grain film precursor on a hydraulic flat press at 195 ℃ for 17min to obtain the solid waste PVC flame-retardant wood-grain film.
Example 4
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is dust mud kiln slag superfine powder which is ground into 2500 meshes by a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is up to 30%.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 12 min; and (3) mixing for 15min in a two-roll open mill with the front and rear roll temperature of 170 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 16min on a hydraulic flat press at 190 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
Example 5
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is up to 31%.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 11 min; and mixing for 19min in a two-roll open mill with the front and rear roll temperature of 160 ℃ and the roll distance of 1mm to obtain the solid waste base PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste PVC flame-retardant wood-grain film precursor for 20min on a hydraulic flat press at 180 ℃ to obtain the solid waste PVC flame-retardant wood-grain film.
Example 6
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is dust mud kiln slag superfine powder which is ground into 2500 meshes by a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is up to 31%.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 13 min; and (3) mixing for 17min in a two-roll open mill with the front and rear roll temperature of 165 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 18min on a hydraulic flat press at 190 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
Comparative example 1
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by ball-milling diatomite into 2500-mesh diatomite superfine powder, wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is obtained by ball-milling and grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder, and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder through ball milling, wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is up to 31%.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 13 min; and (3) mixing for 17min in a two-roll open mill with the front and rear roll temperature of 165 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 18min on a hydraulic flat press at 190 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
Comparative example 2
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The wollastonite is GY-4000 wollastonite
The dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill (also called superfine roller mill), and the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller mill)The chemical composition of (1) is CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the wollastonite, the dust mud kiln slag superfine powder and the phosphorous slag superfine powder is 31 percent.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, wollastonite, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 13 min; and (3) mixing for 17min in a two-roll open mill with the front and rear roll temperature of 165 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 18min on a hydraulic flat press at 190 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
Comparative example 3
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder by a superfine tire vertical mill (also called superfine roller mill), wherein the chemical component of the diatomite is SiO 2 (92.54％)、Fe 2 O 3 (1.54％)、Al 2 O 3 (3.38%) and others (2.54%).
The dust mud kiln slag superfine powder is dust mudGrinding the kiln slag into 2500-mesh dust mud kiln slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The calcium carbonate is nano light calcium carbonate
The total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the calcium carbonate is 31 percent.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and calcium carbonate in a high-speed mixer for 13 min; and (3) mixing for 17min in a two-roll open mill with the front and rear roll temperature of 165 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 18min on a hydraulic flat press at 190 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
Comparative example 4
The components used for preparing 100g of the product of the invention and the mass ratio thereof are as follows:
the polyvinyl chloride is SG5 polyvinyl chloride resin.
The plasticizer is dibutyl phthalate.
The stabilizer is a BS-105 rare earth composite heat stabilizer.
The titanium dioxide is R6628 titanium dioxide.
The dust mud kiln slag superfine powder is obtained by grinding dust mud kiln slag with a superfine tire vertical mill (also called superfine roller milling)Grinding into 2500 mesh dust mud kiln slag superfine powder, wherein the chemical component of the dust mud kiln slag is Fe 2 O 3 (32.25％)、SiO 2 (19.83％)、CaO(16.41％)、Al 2 O 3 (11.28％)、MgO(3.82％)、Na 2 O(2.81％)、ZnO(2.70％)、MnO(2.42％)、TiO 2 (1.34％)、K 2 O (0.67%) and others (6.47%).
The phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder by a superfine tire vertical mill (also called superfine roller milling), wherein the chemical components of the phosphorus slag comprise CaO (45.72 percent) and Al 2 O 3 (2.57％)、SiO 2 (40.85％)、K 2 O(1.01％)、P 2 O 5 (3.91％)、MgO(3.32％)、TiO 2 (0.22%) and others (2.40%).
The total weight percentage of the titanium dioxide, the dust mud kiln slag superfine powder and the phosphorus slag superfine powder is up to 31 percent.
Premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 13 min; and (3) mixing for 17min in a two-roll open mill with the front and rear roll temperature of 165 ℃ and the roll spacing of 1mm to obtain the solid waste-based PVC flame-retardant wood grain film precursor. And then carrying out hot pressing on the solid waste base PVC flame-retardant wood grain film precursor for 18min on a hydraulic flat press at 190 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
The performance detection process of the solid waste base PVC flame-retardant wood grain film prepared in the embodiments 1-6 and the comparative examples 1-4 is as follows:
determination of tensile Properties of plastics according to section 1: general guidelines (GB/T1040.1-2018), determination of indentation hardness (Shore hardness) by using a hardness tester for plastics and hard rubber (GB/T2411-2008), and oxygen index method for testing plastic combustion performance (GB/T2406-1993).
TABLE 1 solid waste based PVC flame retardant wood grain film
Claims (8)
1. The solid waste based PVC flame-retardant wood grain film is characterized by comprising the following raw materials in percentage by weight:
the plasticizer is dibutyl phthalate;
the stabilizer is a BS-105 rare earth composite heat stabilizer;
the diatomite superfine powder is prepared by grinding diatomite into 2500-mesh diatomite superfine powder through a superfine tire vertical mill;
the dust mud kiln slag superfine powder is prepared by grinding dust mud kiln slag into 2500-mesh dust mud kiln slag superfine powder through a superfine tire vertical mill;
the phosphorus slag superfine powder is prepared by grinding phosphorus slag into 2500-mesh phosphorus slag superfine powder through a superfine tire vertical mill.
2. The solid waste based PVC flame retardant wood grain film according to claim 1, wherein the total weight percentage of the titanium dioxide, the diatomite superfine powder, the dust mud kiln slag superfine powder and the phosphorus slag superfine powder is 30-35%.
3. The solid waste based PVC flame retardant wood-grain film according to claim 1, wherein the diatomite comprises the following chemical components in percentage by mass:
4. the solid waste based PVC flame-retardant wood-grain film according to claim 1, wherein the chemical components and mass percentages of the dust and mud kiln slag are respectively as follows:
5. the solid waste based PVC flame-retardant wood-grain film according to claim 1, wherein the phosphorous slag comprises the following chemical components in percentage by mass:
6. the flame-retardant wood-grain film of PVC based on solid wastes according to claim 1, wherein the polyvinyl chloride is SG5 polyvinyl chloride resin.
7. The solid waste based PVC flame retardant wood grain film according to claim 1, wherein the titanium dioxide is R6628 titanium dioxide.
8. The preparation method of the solid waste based PVC flame-retardant wood-grain film according to claim 1, characterized by comprising the following steps:
premixing polyvinyl chloride, a plasticizer, a stabilizer, titanium dioxide, diatomite superfine powder, dust mud kiln slag superfine powder and phosphorus slag superfine powder in a high-speed mixer for 10-15 min; mixing for 15-20 min in a double-roll open mill with the front and rear roll temperature of 150-170 ℃ and the roll distance of 1mm to obtain a solid waste base PVC flame-retardant wood grain film precursor; and then the solid waste base PVC flame-retardant wood grain film precursor is hot-pressed for 15-20 min on a hydraulic flat press at 180-200 ℃ to obtain the solid waste base PVC flame-retardant wood grain film.
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