CN102775888A - Sand pattern powder coating for aluminum profiles as well as preparation method and application thereof - Google Patents

Sand pattern powder coating for aluminum profiles as well as preparation method and application thereof Download PDF

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Publication number
CN102775888A
CN102775888A CN2012103030692A CN201210303069A CN102775888A CN 102775888 A CN102775888 A CN 102775888A CN 2012103030692 A CN2012103030692 A CN 2012103030692A CN 201210303069 A CN201210303069 A CN 201210303069A CN 102775888 A CN102775888 A CN 102775888A
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Prior art keywords
powder coating
weight percent
preparation
section bar
aluminium section
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CN2012103030692A
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魏育福
马传安
蔡英进
蔡劲树
李会宁
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Guangdong River Powder Science & Technology Co Ltd
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Guangdong River Powder Science & Technology Co Ltd
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Priority to CN2012103030692A priority Critical patent/CN102775888A/en
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Abstract

The invention belongs to the technical field of new materials and discloses a sand pattern powder coating for aluminum profiles as well as a preparation method and application thereof. The coating is prepared from the following raw materials in percentage by weight: 50-60% of saturated carboxyl polyester resin, 3.7-4.5% of triglycidyl isocyanurate, 17-27% of titanium dioxide, 13-20% of precipitated barium sulfate, 0.2-1.5% of bentonite, 0.2-0.7% of sand pattern agent, 0.3% of carbon black, 0.1-0.2% of pink and 0.1-0.2% of phthalocyanine blue. The preparation method comprises the following steps of: putting the raw materials into a mixing cylinder and premixing the raw materials; carrying out melt extrusion on the premixed raw materials and then pressing the materials into flakes; cooling the flakes to room temperature, crushing the flakes and then carrying out fine crushing; and screening the finely crushed materials to obtain the product.

Description

A kind of aluminium section bar is with the sand streak powder coating
Technical field
The invention belongs to new material technology field, relate to a kind of powder coating and preparation method thereof, particularly a kind of aluminium section bar is with sand streak powder coating and preparation method thereof.
Background technology
Existing powder coating, appearance of film majority are Gao Guang, half light or low light series, in carrying, construction and use, are prone to produce scratch; Under atmospheric condition, because of aging loss of gloss and produce efflorescence, lost original decorative effect very soon.Along with expanding economy, development of technology with constantly bring forth new ideas, developed at present and multiplely can change the outer texture auxiliary agent of form at present of filming, add this analog assistant, film coated surface is produced such as grain effects such as decorative pattern, mallear stria, moire and sand streaks.Thereby make the powder coating ornaments more rich and varied.The sand streak powder coating is filmed, because illumination produces scattering, gives people's impression comfortable; Hardness of film is high; Feel is smooth to be difficult for being scratched and advantage such as ageing-resistant, receives people's favor, is widely used in the application on aluminum products surfaces such as building doors and windows, electric appliance and electronic product, five metals furniture; Application Areas is in the ascendant, makes that just sand streak series powder coating is developed accordingly.
Summary of the invention
In order to solve the weak point that prior art exists, primary and foremost purpose of the present invention is to provide a kind of aluminium section bar to use the sand streak powder coating.The hardness of film of this powder coating is high, damage resistant is anti-aging, can give the more comfortable visual impression of people, and have the different texture effect.
Another object of the present invention is to provide the preparation method of above-mentioned aluminium section bar with powder coating.
A purpose more of the present invention is to provide the application of above-mentioned aluminium section bar with powder coating.
The object of the invention is realized through following technical scheme: a kind of aluminium section bar is used the sand streak powder coating, and this sand streak powder coating is formed by following raw material preparing by heavy per-cent:
Figure BDA00002046657700011
Figure BDA00002046657700021
The weight ratio of said saturated terminal carboxyl polyester resin and triglycidyl isocyanurate is 93.1:7~94.6:7.
Above-mentioned aluminium section bar comprises following operation steps with the preparation method of sand streak powder coating:
(1) with the saturated terminal carboxyl polyester resin of weight percent 50~60%; The triglycidyl isocyanurate of weight percent 3.7~4.5%; The titanium oxide of weight percent 17~27%; The process white of weight percent 13~20%; The wilkinite of weight percent 0.2~1.5%; The sand streak agent of weight percent 0.2~0.7%; The carbon black of weight percent 0.3%; Weight percent 0.1~0.2% pink; Pre-mixing in the blue input of the phthalein of weight percent 0.1~0.2% compounding jar;
(2) starting material after the pre-mixing are melt extruded and be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, carries out fine pulverizing again;
(4) material with fine pulverizing sieves, and obtains aluminium section bar and uses the sand streak powder coating.
The said premixed time of step (1) is 3~4 minutes.
Step (2) is said to melt extrude and is meant with the starting material of twin screw extruder after to pre-mixing and carries out the melting mixing homodisperse and extrude that wherein, the temperature in forcing machine I district is 115~125 ℃, and the temperature in II district is 105~115 ℃.
The said fine pulverizing of step (3) is meant with 10~100 microns of the sheet stock pulverized powder particle diameter of air classifying supper micron mill after with fragmentation.
The said screening of step (4) is meant that using rotating screen that powder coating is sized to median size is 25~35 microns.
Above-mentioned a kind of aluminium section bar is with the application of sand streak powder coating at aluminium section bar.
The present invention possesses following outstanding advantage and effect with respect to prior art:
(1) add the sand streak agent in the present invention prescription, filming after the curing produces the grain effect with sand streak, gives the euphorosia sense since film hard, feel is smooth, is producing, processing, is being difficult for producing in using and scratches, and weather resistance is excellent.Fill up the blank of powder coating kind outward appearance dullness.
(2) added of the auxiliary packing of the big wilkinite of oil number in the prescription as the sand streak agent; Bentonitic adding can be adjusted the thickness and the slickness of film coated surface texture; Greatly improved the hardness of sand streak film coated surface; Strengthen the film coated surface scratch resistant performance, and can practice thrift the usage quantity of expensive sand streak agent again, reduced the cost of powder coating.
(3) on production technique, when producing the sand streak powder coating, the height the when rotating ratio of extruder screw is produced ordinary powder coating has improved production efficiency, reduces production costs.
Embodiment
Below in conjunction with embodiment the present invention is done further detailed description, but embodiment of the present invention is not limited thereto.
Embodiment 1
Wherein, saturated terminal carboxyl polyester resin is bought in the emerging resin of Supreme Being (Kunshan) ltd;
(1) with pre-mixing in the raw material input compounding jar of above-mentioned per-cent 3 minutes;
(2) starting material after the pre-mixing are carried out the melting mixing homodisperse with the starting material of twin screw extruder after to pre-mixing and extrude, wherein, the temperature in forcing machine I district is 115 ℃, and the temperature in II district is 105 ℃; And be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, 10~100 microns of the sheet stock pulverized powder particle diameters after using the ACM pulverizing mill with fragmentation again;
(4) using rotating screen to be sized to median size the material of fine pulverizing is 25 microns, obtains aluminium section bar and use the sand streak powder coating.
Above-mentioned gained aluminium section bar is carried out each item Performance Detection with the sand streak powder coating, and the result is following:
Penetration hardness: 85
Wear factor: 0.82L μ m
Quicken weathering resistance: the II level;
Solvent resistance: 3 grades.
Embodiment 2
Figure BDA00002046657700041
Wherein, saturated terminal carboxyl polyester resin is bought in the emerging resin of Supreme Being (Kunshan) ltd;
(1) above-mentioned raw materials was dropped in the compounding jar pre-mixing 3 minutes;
(2) starting material after the pre-mixing are carried out the melting mixing homodisperse with the starting material of twin screw extruder after to pre-mixing and extrude, wherein, the temperature in forcing machine I district is 120 ℃, and the temperature in II district is 110 ℃; And be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, 10~100 microns of the sheet stock pulverized powder particle diameters after using the ACM pulverizing mill with fragmentation again;
(4) using rotating screen to be sized to median size the material of fine pulverizing is 27 microns, obtains aluminium section bar and use the sand streak powder coating.
Above-mentioned gained aluminium section bar is carried out each item Performance Detection with the sand streak powder coating, and the result is following:
Penetration hardness: 84
Wear factor: 0.83L μ m
Quicken weathering resistance: the II level
Solvent resistance: 3 grades.
Embodiment 3
Figure BDA00002046657700042
Figure BDA00002046657700051
Wherein, saturated terminal carboxyl polyester resin is bought in the emerging resin of Supreme Being (Kunshan) ltd;
(1) above-mentioned raw materials was dropped in the compounding jar pre-mixing 4 minutes;
(2) starting material after the pre-mixing are carried out the melting mixing homodisperse with the starting material of twin screw extruder after to pre-mixing and extrude, wherein, the temperature in forcing machine I district is 125 ℃, and the temperature in II district is 115 ℃; And be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, 10~100 microns of the sheet stock pulverized powder particle diameters after using the ACM pulverizing mill with fragmentation again;
(4) using rotating screen to be sized to median size the material of fine pulverizing is 35 microns, obtains aluminium section bar and use the sand streak powder coating.
Above-mentioned gained aluminium section bar is carried out each item Performance Detection with the sand streak powder coating, and the result is following:
Penetration hardness: 85
Wear factor: 0.84L μ m
Quicken weathering resistance: the II level;
Solvent resistance: 4 grades.
Embodiment 4
Figure BDA00002046657700052
Wherein, saturated terminal carboxyl polyester resin is bought in the emerging resin of Supreme Being (Kunshan) ltd;
(1) above-mentioned raw materials was dropped in the compounding jar pre-mixing 4 minutes;
(2) starting material after the pre-mixing are carried out the melting mixing homodisperse with the starting material of twin screw extruder after to pre-mixing and extrude, wherein, the temperature in forcing machine I district is 123 ℃, and the temperature in II district is 113 ℃; And be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, 10~100 microns of the sheet stock pulverized powder particle diameters after using the ACM pulverizing mill with fragmentation again;
(4) using rotating screen to be sized to median size the material of fine pulverizing is 30 microns, obtains aluminium section bar and use the sand streak powder coating.
Above-mentioned gained aluminium section bar is carried out each item Performance Detection with the sand streak powder coating, and the result is following:
Penetration hardness: 83
Wear factor: 0.82L μ m
Quicken weathering resistance: the I level;
Solvent resistance: 4 grades.
Embodiment 5
Figure BDA00002046657700061
Wherein, saturated terminal carboxyl polyester resin is bought in the emerging resin of Supreme Being (Kunshan) ltd;
(1) above-mentioned raw materials was dropped in the compounding jar pre-mixing 4 minutes;
(2) starting material after the pre-mixing are carried out the melting mixing homodisperse with the starting material of twin screw extruder after to pre-mixing and extrude, wherein, the temperature in forcing machine I district is for 118 ℃, and the temperature in II district is for 107 ℃; And be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, 10~100 microns of the sheet stock pulverized powder particle diameters after using the ACM pulverizing mill with fragmentation again;
(4) using rotating screen to be sized to median size the material of fine pulverizing is 28 microns, obtains aluminium section bar and use the sand streak powder coating.
Above-mentioned gained aluminium section bar is carried out each item Performance Detection with the sand streak powder coating, and the result is following:
Penetration hardness: 83
Wear factor: 0.82L μ m
Quicken weathering resistance: the II level;
Solvent resistance: 3 grades.
The foregoing description is a preferred implementation of the present invention; But embodiment of the present invention is not restricted to the described embodiments; Other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; All should be the substitute mode of equivalence, be included within protection scope of the present invention.

Claims (8)

1. an aluminium section bar is used the sand streak powder coating, it is characterized in that: this sand streak powder coating is formed by following raw material preparing by heavy per-cent:
Figure FDA00002046657600011
2. a kind of aluminium section bar according to claim 1 is used the sand streak powder coating, it is characterized in that: the weight ratio of said saturated terminal carboxyl polyester resin and triglycidyl isocyanurate is 93.1:7~94.6:7.
3. aluminium section bar according to claim 1 and 2 is characterized in that comprising following operation steps with the preparation method of sand streak powder coating:
(1) with the saturated terminal carboxyl polyester resin of weight percent 50~60%; The triglycidyl isocyanurate of weight percent 3.7~4.5%; The titanium oxide of weight percent 17~27%; The process white of weight percent 13~20%; The wilkinite of weight percent 0.2~1.5%; The sand streak agent of weight percent 0.2~0.7%; The carbon black of weight percent 0.3%; Weight percent 0.1~0.2% pink; Pre-mixing in the blue input of the phthalein of weight percent 0.1~0.2% compounding jar;
(2) starting material after the pre-mixing are melt extruded and be pressed into sheet stock;
(3) it is broken sheet stock to be cooled off the laggard row of room temperature, carries out fine pulverizing again;
(4) material with fine pulverizing sieves, and obtains aluminium section bar and uses the sand streak powder coating.
4. preparation method according to claim 3 is characterized in that: the said premixed time of step (1) is 3~4 minutes.
5. preparation method according to claim 3; It is characterized in that: step (2) is said to melt extrude and is meant with the starting material of twin screw extruder after to pre-mixing and carries out the melting mixing homodisperse and extrude; Wherein, The temperature in forcing machine I district is 115~125 ℃, and the temperature in II district is 105~115 ℃.
6. preparation method according to claim 3 is characterized in that: the said fine pulverizing of step (3) is meant with 10~100 microns of the sheet stock pulverized powder particle diameter of air classifying supper micron mill after with fragmentation.
7. preparation method according to claim 3 is characterized in that: the said screening of step (4) is meant that using rotating screen that powder coating is sized to median size is 25~35 microns.
8. a kind of aluminium section bar according to claim 1 is with the application of sand streak powder coating at aluminium section bar.
CN2012103030692A 2012-08-23 2012-08-23 Sand pattern powder coating for aluminum profiles as well as preparation method and application thereof Pending CN102775888A (en)

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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103160193A (en) * 2013-02-22 2013-06-19 安徽华辉塑业科技有限公司 Zero diopter type polyester powder coating and preparation method thereof
CN103319989A (en) * 2013-04-26 2013-09-25 安徽美佳新材料股份有限公司 Powder coating material and production method thereof
CN103483988A (en) * 2013-08-26 2014-01-01 广州擎天材料科技有限公司 Boiling-endurable sand-ripple powder paint for coating corners of aluminum section and preparation method thereof
CN103589304A (en) * 2013-10-24 2014-02-19 安徽柏拉图涂层织物有限公司 High-leveling-property bright paint
CN103965752A (en) * 2014-05-06 2014-08-06 张家港江南粉末涂料有限公司 High-temperature-resistant powder coating with good gloss-retention performance and production method thereof
CN103978661A (en) * 2014-04-30 2014-08-13 张家港江南粉末涂料有限公司 Method for producing orange-textured and sand-textured powder coatings by using double-screw extruder
CN104031548A (en) * 2014-07-02 2014-09-10 江苏海田技术有限公司 Finish paint with pitted surface effect and preparation method thereof
CN104312387A (en) * 2014-07-17 2015-01-28 漳州市万诚粉体涂料有限公司 Starlight pattern powder coating and preparation method thereof
CN105176308A (en) * 2015-09-29 2015-12-23 国网智能电网研究院 Paint and preparation method thereof
CN105585943A (en) * 2015-11-24 2016-05-18 海安南京大学高新技术研究院 Extra-fine sand streak weather-proof powder coating
CN106280633A (en) * 2016-08-31 2017-01-04 玉石塑粉有限公司 A kind of thermosetting powder coating auxiliary agent and use the powdery paints of this auxiliary agent
CN106349892A (en) * 2016-08-31 2017-01-25 苏州翰晨商贸有限公司 Outdoor white sand ripple powder paint
CN106380920A (en) * 2016-08-31 2017-02-08 太仓宏璟辅龙信息科技有限公司 Outdoor blue wrinkle powder coating
CN106398485A (en) * 2016-08-31 2017-02-15 太仓宏璟辅龙信息科技有限公司 Outdoor grey wrinkle powder coating
CN107099223A (en) * 2017-04-06 2017-08-29 佛山市涂亿装饰材料科技有限公司 A kind of formula of aluminium section for buildings hydrophobic and the microstructure powder coating product of waterproof spot
CN107151515A (en) * 2017-05-26 2017-09-12 张家港市五湖新材料技术开发有限公司 A kind of preparation method of sand streak paint
CN108467666A (en) * 2018-05-04 2018-08-31 苏州聚康新材料科技有限公司 A kind of preparation method of anti-corrosive powder paint
CN109233405A (en) * 2018-09-17 2019-01-18 常州市源长新材料科技有限公司 A kind of antistatic powder coating and preparation method thereof
CN109354979A (en) * 2018-10-22 2019-02-19 苏州绮联粉体涂料有限公司 A kind of crack powder paint and preparation method thereof
CN113604136A (en) * 2021-09-01 2021-11-05 安徽神剑新材料股份有限公司 Sand grain powder coating with super-delayed mechanical properties and preparation method thereof

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CN103160193B (en) * 2013-02-22 2016-05-18 安徽华辉塑业科技股份有限公司 Zero diopter type polyester powder coating and preparation method thereof
CN103160193A (en) * 2013-02-22 2013-06-19 安徽华辉塑业科技有限公司 Zero diopter type polyester powder coating and preparation method thereof
CN103319989A (en) * 2013-04-26 2013-09-25 安徽美佳新材料股份有限公司 Powder coating material and production method thereof
CN103483988A (en) * 2013-08-26 2014-01-01 广州擎天材料科技有限公司 Boiling-endurable sand-ripple powder paint for coating corners of aluminum section and preparation method thereof
CN103589304B (en) * 2013-10-24 2015-11-25 安徽柏拉图涂层织物有限公司 A kind of High-leveling-properbright bright paint
CN103589304A (en) * 2013-10-24 2014-02-19 安徽柏拉图涂层织物有限公司 High-leveling-property bright paint
CN103978661A (en) * 2014-04-30 2014-08-13 张家港江南粉末涂料有限公司 Method for producing orange-textured and sand-textured powder coatings by using double-screw extruder
CN103965752A (en) * 2014-05-06 2014-08-06 张家港江南粉末涂料有限公司 High-temperature-resistant powder coating with good gloss-retention performance and production method thereof
CN104031548A (en) * 2014-07-02 2014-09-10 江苏海田技术有限公司 Finish paint with pitted surface effect and preparation method thereof
CN104312387B (en) * 2014-07-17 2017-02-15 漳州市万诚粉体涂料有限公司 Starlight pattern powder coating and preparation method thereof
CN104312387A (en) * 2014-07-17 2015-01-28 漳州市万诚粉体涂料有限公司 Starlight pattern powder coating and preparation method thereof
CN105176308A (en) * 2015-09-29 2015-12-23 国网智能电网研究院 Paint and preparation method thereof
CN105585943A (en) * 2015-11-24 2016-05-18 海安南京大学高新技术研究院 Extra-fine sand streak weather-proof powder coating
CN106349892A (en) * 2016-08-31 2017-01-25 苏州翰晨商贸有限公司 Outdoor white sand ripple powder paint
CN106380920A (en) * 2016-08-31 2017-02-08 太仓宏璟辅龙信息科技有限公司 Outdoor blue wrinkle powder coating
CN106280633A (en) * 2016-08-31 2017-01-04 玉石塑粉有限公司 A kind of thermosetting powder coating auxiliary agent and use the powdery paints of this auxiliary agent
CN106398485A (en) * 2016-08-31 2017-02-15 太仓宏璟辅龙信息科技有限公司 Outdoor grey wrinkle powder coating
CN107099223A (en) * 2017-04-06 2017-08-29 佛山市涂亿装饰材料科技有限公司 A kind of formula of aluminium section for buildings hydrophobic and the microstructure powder coating product of waterproof spot
CN107151515A (en) * 2017-05-26 2017-09-12 张家港市五湖新材料技术开发有限公司 A kind of preparation method of sand streak paint
CN108467666A (en) * 2018-05-04 2018-08-31 苏州聚康新材料科技有限公司 A kind of preparation method of anti-corrosive powder paint
CN109233405A (en) * 2018-09-17 2019-01-18 常州市源长新材料科技有限公司 A kind of antistatic powder coating and preparation method thereof
CN109354979A (en) * 2018-10-22 2019-02-19 苏州绮联粉体涂料有限公司 A kind of crack powder paint and preparation method thereof
CN113604136A (en) * 2021-09-01 2021-11-05 安徽神剑新材料股份有限公司 Sand grain powder coating with super-delayed mechanical properties and preparation method thereof

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Application publication date: 20121114