CN114923945B - Simulation method and application of pore water pressure in tailings filling body in high temperature stope - Google Patents

Simulation method and application of pore water pressure in tailings filling body in high temperature stope Download PDF

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CN114923945B
CN114923945B CN202210492193.1A CN202210492193A CN114923945B CN 114923945 B CN114923945 B CN 114923945B CN 202210492193 A CN202210492193 A CN 202210492193A CN 114923945 B CN114923945 B CN 114923945B
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周洋
鲁功达
曾理
安之阳
刘朝晖
丁培培
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Abstract

本发明公开了一种高温采场中的尾矿充填体孔隙水压模拟方法及其应用,包括:基于孔隙热弹性理论框架建立充填体非等温孔隙水压演化模型,分析不同初始温度的充填体单元在温度荷载作用下的孔隙水压演化规律,进而厘清复杂地热环境条件下的充填体行为响应机理,为提出针对性的充填优化方案并实现深部资源的安全清洁开采提供理论支持。

Figure 202210492193

The invention discloses a method for simulating pore water pressure of a tailings filling body in a high-temperature stope and its application, including: establishing a non-isothermal pore water pressure evolution model of a filling body based on a theoretical framework of pore thermoelasticity, and analyzing filling bodies with different initial temperatures The evolution law of pore water pressure of the unit under the action of temperature load, and then clarify the response mechanism of filling body behavior under complex geothermal environment conditions, and provide theoretical support for proposing targeted filling optimization schemes and realizing safe and clean mining of deep resources.

Figure 202210492193

Description

高温采场中的尾矿充填体孔隙水压模拟方法及其应用Simulation method and application of pore water pressure of tailings filling in high temperature mining area

技术领域Technical Field

本发明涉及矿产资源开发技术领域,特别涉及一种高温采场中的尾矿充填体孔隙水压模拟方法及其应用。The invention relates to the technical field of mineral resource development, and in particular to a method for simulating pore water pressure of a tailings filling body in a high-temperature stope and application thereof.

背景技术Background Art

矿产资源开发是为社会提供物质资源的重要途径,然而常规的采矿工艺将产生大量的地下采空区和尾矿地表堆积,进而对矿山安全生产和自然生态环境造成严重危害(Benzaazoua et al.,2004;Kesimal et al.,2005;Bussière,200 7;徐文彬等,2015;吴爱祥等,2016)。在不断提高的安全生产标准和环境保护压力推动下,尾矿的地下处置逐渐成为了实现矿产资源绿色清洁开采的重要途径(N asir and Fall,2009;Ghirian and Fall,2013a;吴爱祥等,2018)。通过将尾矿、胶结剂和水按一定比例混合并回填至地下采空区,该尾矿充填技术不仅避免了尾矿在地表的大量曝露堆积,而且能够显著改善地下采场围岩稳定性,同时可以允许不留矿柱进而提高矿石回采率(Kesimal et al.,2005;Klein andSimon,2006;Wi tteman and Simms,2017;Lu et al.,2020a)。Mineral resource development is an important way to provide material resources for society. However, conventional mining processes will produce a large number of underground goafs and surface accumulation of tailings, which will cause serious harm to mine safety production and natural ecological environment (Benzaazoua et al., 2004; Kesimal et al., 2005; Bussière, 2007; Xu Wenbin et al., 2015; Wu Aixiang et al., 2016). Driven by the continuous improvement of safety production standards and environmental protection pressure, underground disposal of tailings has gradually become an important way to achieve green and clean mining of mineral resources (N asir and Fall, 2009; Ghirian and Fall, 2013a; Wu Aixiang et al., 2018). By mixing tailings, binders and water in a certain proportion and backfilling them into underground goafs, this tailings filling technology not only avoids the large-scale exposure and accumulation of tailings on the surface, but also significantly improves the stability of the surrounding rock of underground mines. At the same time, it allows no pillars to be left, thereby increasing the ore recovery rate (Kesimal et al., 2005; Klein and Simon, 2006; Witteman and Simms, 2017; Lu et al., 2020a).

虽然尾矿充填技术持续为地下资源开采带来了巨大的环境和经济效益,但近年来的现场监测工作则多次发现了充填体在深部矿井中的异常行为,主要表现为孔隙水压力和土压力在充填中止的情况下仍可产生急剧的增长(Thompson et al., 2011,2012,2014;Hasan et al.,2014)。由于底部挡墙在充填过程中所受的作用力决定了充填系统的稳定性,因此现场监测发现的压力异常现象将可能造成充填挡墙破坏进而严重威胁井下人员安全和矿山生产效率。然而,目前的研究工作仍未针对深部复杂温度环境条件下的充填体行为响应规律建立完善的认识。由于采场围岩温度将在地温梯度作用下随不断增加的资源开采深度而持续上升(Fall et al., 2010;Belle et al.,2018;Wang et al,2019;何满潮等,2005;谢和平等,2015;古德生等,2003),因此开展复杂温度环境条件下的充填体多场耦合响应研究,进而揭示高温采场中的充填体行为机理,对于实现深部资源的安全清洁开发利用具有重要的理论和工程意义。Although tailings filling technology continues to bring huge environmental and economic benefits to underground resource mining, field monitoring work in recent years has repeatedly discovered abnormal behavior of filling bodies in deep mines, mainly manifested in the fact that pore water pressure and earth pressure can still increase sharply when filling is stopped (Thompson et al., 2011, 2012, 2014; Hasan et al., 2014). Since the force exerted on the bottom retaining wall during the filling process determines the stability of the filling system, the pressure anomaly found in field monitoring may cause the filling retaining wall to be damaged, thus seriously threatening the safety of underground personnel and mine production efficiency. However, current research work has not yet established a complete understanding of the response law of filling body behavior under complex temperature environment conditions at depth. Since the temperature of the surrounding rock in the mining area will continue to rise with the increasing depth of resource mining under the influence of geothermal gradient (Fall et al., 2010; Belle et al., 2018; Wang et al., 2019; He Manchao et al., 2005; Xie Heping et al., 2015; Gu Desheng et al., 2003), it is of great theoretical and engineering significance to carry out research on the multi-field coupling response of filling bodies under complex temperature environment conditions and then reveal the behavior mechanism of filling bodies in high-temperature mining areas for the safe and clean development and utilization of deep resources.

现有技术一通过考虑能量的产生和运移过程建立了充填体温度-渗流-力学-化学场耦合模型,可用于预测充填体温度、水压和土压等的演化规律(Cui and Fall, 2015,2016,2017,2018)。Prior art 1 established a backfill temperature-seepage-mechanical-chemical field coupling model by considering the energy generation and migration process, which can be used to predict the evolution law of backfill temperature, water pressure, and earth pressure (Cui and Fall, 2015, 2016, 2017, 2018).

现有技术一未考虑水的热膨胀效应:水泥水化放热过程将消耗自由水,进而造成水压耗散。但由于水的热膨胀系数一般比固体颗粒的大,因此水泥水化放热导致的温升作用将造成充填体孔隙水压的上升。同时水热增压现象已由Thompso n et al(2012)的原位测试所证实。该研究发现,即使充填过程终止,充填体仍可能因水泥水化放热造成温度升高而产生异常的水压上升。而现有技术方案一忽略了水的热膨胀效应,因此无法描述由热膨胀变形造成的水压异常现象。Prior art 1 does not take into account the thermal expansion effect of water: the exothermic process of cement hydration will consume free water, thereby causing water pressure dissipation. However, since the thermal expansion coefficient of water is generally larger than that of solid particles, the temperature rise caused by the heat release of cement hydration will cause the pore water pressure of the filling body to rise. At the same time, the hydrothermal pressurization phenomenon has been confirmed by the in-situ test of Thompson et al (2012). The study found that even if the filling process is terminated, the filling body may still produce abnormal water pressure rise due to the temperature rise caused by the heat release of cement hydration. However, the prior art solution 1 ignores the thermal expansion effect of water, and therefore cannot describe the abnormal water pressure phenomenon caused by thermal expansion deformation.

现有技术二通过考虑水化反应造成的自由水消耗以及物理力学性质演化建立了充填体渗流-力学-化学场耦合模型,可用于预测充填体水压和土压等的演化规律(Helinski et al.,2007,2011;Muir Wood et al.,2016;Lu,2017)。The second existing technology establishes a seepage-mechanical-chemical field coupling model of the filling body by considering the free water consumption caused by hydration reaction and the evolution of physical and mechanical properties, which can be used to predict the evolution law of water pressure and soil pressure of the filling body (Helinski et al., 2007, 2011; Muir Wood et al., 2016; Lu, 2017).

现有技术二未考虑温度的影响:水泥水化放热过程不仅会加快化学反应速率以及充填体强度增长,还会造成水分蒸发,从而降低孔隙水压。同时,温度变化也将造成流体粘滞系数的改变,进而影响渗流场的演化规律。此外,随着采矿活动深度不断增加,采场环境温度将在地温梯度的作用下不断上升,因此温度对深部充填体行为特征的影响也将更加凸显。而现有技术方案二忽略了温度对充填体的作用,因此无法准确描述复杂赋存环境中的充填体行为特征。The second prior art does not take into account the influence of temperature: the exothermic process of cement hydration will not only accelerate the chemical reaction rate and the strength of the filling body, but also cause water evaporation, thereby reducing the pore water pressure. At the same time, temperature changes will also cause changes in the viscosity of the fluid, thereby affecting the evolution of the seepage field. In addition, as the depth of mining activities continues to increase, the ambient temperature of the mining area will continue to rise under the influence of the geothermal gradient, so the influence of temperature on the behavior characteristics of deep filling bodies will become more prominent. However, the second prior art solution ignores the effect of temperature on the filling body, and therefore cannot accurately describe the behavior characteristics of the filling body in a complex storage environment.

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发明内容Summary of the invention

本发明针对现有技术的缺陷,提供了一种高温采场中的尾矿充填体孔隙水压模拟方法及其应用。In view of the defects of the prior art, the present invention provides a method for simulating pore water pressure of tailings filling bodies in high-temperature mining areas and its application.

为了实现以上发明目的,本发明采取的技术方案如下:In order to achieve the above invention object, the technical solution adopted by the present invention is as follows:

一种高温采场中的尾矿充填体孔隙水压模拟方法,包括以下步骤:A method for simulating pore water pressure of tailings filling body in a high-temperature stope comprises the following steps:

步骤1,基于Selvadurai和Suvorov的孔隙热弹性理论框架,通过考虑水化反应耗水(即化学收缩作用)造成的水体积变化建立蠕变加载条件下的充填体非等温孔隙水压控制方程:Step 1: Based on the pore thermoelasticity theory framework of Selvadurai and Suvorov, the non-isothermal pore water pressure control equation of the filling body under creep loading conditions is established by considering the water volume change caused by the hydration reaction (i.e., chemical shrinkage):

Figure BDA0003631518850000071
Figure BDA0003631518850000071

其中,α表示Biot系数,α=1–Kd/Ks,式中Kd为充填体骨架的体积模量,n 是孔隙度,Ks和Kw分别为固相和水的体积模量,pw表示孔隙水压力,t为反应进行的时间,βs和βw分别是固相和水的热膨胀系数,T表示当前温度,εv为体积应变,k是渗透系数,η表示水的动态粘度,εshf为化学反应过程中的总耗水,ξ是水化度。Among them, α represents the Biot coefficient, α=1–K d /K s , where K d is the bulk modulus of the filling skeleton, n is the porosity, K s and K w are the bulk moduli of the solid phase and water respectively, p w represents the pore water pressure, t is the reaction time, β s and β w are the thermal expansion coefficients of the solid phase and water respectively, T represents the current temperature, ε v is the volume strain, k is the permeability coefficient, η represents the dynamic viscosity of water, ε shf is the total water consumption in the chemical reaction process, and ξ is the hydration degree.

步骤2,假设Biot系数α近似为1,α≈1,

Figure BDA0003631518850000081
以充填体单元为研究对象,进而排除渗流项并将式(1)简化为:Step 2, assuming that the Biot coefficient α is approximately 1, α≈1,
Figure BDA0003631518850000081
Taking the filling unit as the research object, the seepage term is excluded and equation (1) is simplified as follows:

Figure BDA0003631518850000082
Figure BDA0003631518850000082

式(2)即为三轴水化压力室中的充填体单元孔隙水压控制方程。Formula (2) is the control equation of the pore water pressure of the filling unit in the triaxial hydration pressure chamber.

步骤3,为模拟围岩蠕变造成的压缩效应,利用三轴水化压力室向充填体样品施加速率为j/s的轴向变形,该充填体单元在蠕变加载作用下的热弹性应力-应变关系表示为:Step 3: To simulate the compression effect caused by creep of surrounding rock, a triaxial hydration pressure chamber is used to apply axial deformation at a rate of j/s to the filling body sample. The thermoelastic stress-strain relationship of the filling body unit under creep loading is expressed as:

Figure BDA0003631518850000083
Figure BDA0003631518850000083

其中,ε表示应变,E为杨氏模量,σ’表示有效应力,v是泊松比,T0表示初始温度。Where ε represents strain, E is Young's modulus, σ' represents effective stress, v is Poisson's ratio, and T 0 represents initial temperature.

步骤4,在一维侧限条件下建立充填体的几何模型,因此充填体单元仅存在轴向应变,且x、y方向的有效应力相等,进而有以下关系成立:Step 4: Establish the geometric model of the filling body under one-dimensional confinement conditions. Therefore, the filling body unit only has axial strain, and the effective stresses in the x and y directions are equal, and the following relationship is established:

Figure BDA0003631518850000084
Figure BDA0003631518850000084

因此充填体单元的体积变形通过联立式(3)和式(4)获得:Therefore, the volume deformation of the filling unit is obtained by combining equations (3) and (4):

Figure BDA0003631518850000085
Figure BDA0003631518850000085

式(5)中参数表示为:The parameters in formula (5) are expressed as:

Figure BDA0003631518850000091
Figure BDA0003631518850000091

步骤5,在给定的围压条件下,有效应力的变化等于孔隙水压的变化,即

Figure BDA0003631518850000092
Figure BDA0003631518850000093
假设固相压缩为负,,因此将式(5)记为如下导数形式:Step 5: Under given confining pressure conditions, the change in effective stress is equal to the change in pore water pressure, that is,
Figure BDA0003631518850000092
Figure BDA0003631518850000093
Assuming that the solid phase compression is negative, equation (5) is expressed in the following derivative form:

Figure BDA0003631518850000094
Figure BDA0003631518850000094

步骤6,在小应变假设前提下,将式(7)代入式(2)可最终得到非等温条件下的充填体单元孔隙水压控制方程:Step 6: Substituting equation (7) into equation (2) under the assumption of small strain can finally obtain the pore water pressure control equation of the filling unit under non-isothermal conditions:

Figure BDA0003631518850000095
Figure BDA0003631518850000095

步骤7,假设三轴水化压力室完全绝热,即充填体单元无法与周围环境产生热传导和对流换热,因此绝热不排水条件下的充填体温度变化仅由水化放热和该三轴装置施加的温度荷载产生,进而将充填体温度定义为:Step 7: Assume that the triaxial hydration pressure chamber is completely insulated, that is, the filling unit cannot generate heat conduction and convection heat exchange with the surrounding environment. Therefore, the filling temperature change under adiabatic undrained conditions is only caused by hydration heat release and the temperature load applied by the triaxial device. Then, the filling temperature is defined as:

Figure BDA0003631518850000096
Figure BDA0003631518850000096

其中,k表示三轴装置施加的恒定温度变化速率,Th为水化反应造成的温升, Qf是化学反应过程中放出的热量,(ρC)eff表示有效热容((ρC)eff=(1–n)ρsCs+nρwC w),Cs和Cw分别为固液两相的比热容,ρs和ρw分别是固相和水的密度。Where k represents the constant temperature change rate applied by the triaxial device, Th is the temperature rise caused by the hydration reaction, Qf is the heat released during the chemical reaction, (ρC) eff represents the effective heat capacity ((ρC) eff = (1–n) ρsCs + nρwCw ), Cs and Cw are the specific heat capacities of the solid and liquid phases, respectively, and ρs and ρw are the densities of the solid phase and water, respectively.

步骤8,水化度与参考反应时间te的关系表示为:Step 8, the relationship between the degree of hydration and the reference reaction time te is expressed as:

ξ=1-exp(-κξ·te) (10)ξ=1-exp(-κ ξ ·t e ) (10)

其中,κξ为水化度随参考时间的演化速率。Where κ ξ is the evolution rate of the hydration degree with the reference time.

步骤9,根据阿累尼乌斯公式,实际时间t与参考时间te的关系表示为:Step 9: According to the Arrhenius formula, the relationship between the actual time t and the reference time te is expressed as:

Figure BDA0003631518850000097
Figure BDA0003631518850000097

其中,Ea表示化学反应需要的活化能,Ra是通用气体常数(Ra=8.314J/mol/K), Tr为参考温度。Wherein, Ea represents the activation energy required for the chemical reaction, Ra is the universal gas constant ( Ra = 8.314 J/mol/K), and Tr is the reference temperature.

步骤10,将式(9)–(11)带入式(8),最终得到充填体单元在温度荷载作用下的孔隙水压控制方程:Step 10: Substitute equations (9)–(11) into equation (8) to finally obtain the pore water pressure control equation of the filling unit under temperature load:

Figure BDA0003631518850000101
Figure BDA0003631518850000101

进一步地,本发明使用如下公式描述充填体骨架刚度在水化过程中的增长演化:Furthermore, the present invention uses the following formula to describe the growth evolution of the filling body skeleton stiffness during the hydration process:

Kd=Kdi[λ-(λ-1)exp(-κK·te)] (13)K d =K di [λ-(λ-1)exp(-κ K ·t e )] (13)

式中Kdi为充填体的初始骨架刚度,λ为充填体最终刚度与初始刚度的比值,κK为控制刚度增长速率的模型参数。Where K di is the initial skeleton stiffness of the filling body, λ is the ratio of the final stiffness of the filling body to the initial stiffness, and κ K is the model parameter that controls the stiffness growth rate.

进一步地,使用如下公式描述水的热膨胀系数随温度的演化规律Furthermore, the following formula is used to describe the evolution of the thermal expansion coefficient of water with temperature:

βw=βw0+k0T (14)β ww0 +k 0 T (14)

式中βw0和k0为拟合参数。Where β w0 and k0 are fitting parameters.

本发明还公开了高温采场中的尾矿充填体孔隙水压模拟方法在尾矿充填开采技术领域的应用。The invention also discloses the application of the pore water pressure simulation method of the tailings filling body in the high-temperature mining field in the technical field of tailings filling mining.

与现有技术相比,本发明的优点在于:Compared with the prior art, the advantages of the present invention are:

首次针对复杂温度环境条件下的充填体行为响应规律建立了完整的认识,进而深入揭示了温度荷载作用下的充填体行为机理,可更精准地预测出深部复杂地热环境诱发的压力增长与耗散机制竞争作用下的充填体水压演化规律,进而对提出定制化的充填优化方案并实现深部矿产资源的可持续发展提供更科学的理论指导。For the first time, a complete understanding of the response laws of filling body behavior under complex temperature environment conditions has been established, and the behavior mechanism of filling bodies under temperature load has been deeply revealed. It can more accurately predict the evolution law of filling body water pressure under the competition of pressure growth and dissipation mechanism induced by deep complex geothermal environment, and then provide more scientific theoretical guidance for proposing customized filling optimization schemes and realizing the sustainable development of deep mineral resources.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1是本发明实施例不同时刻的孔隙水压随初始温度的演化规律示意图;FIG1 is a schematic diagram showing the evolution of pore water pressure at different times with initial temperature according to an embodiment of the present invention;

图2是本发明实施例水和固体骨架的热膨胀系数随温度的演化规律示意图;FIG2 is a schematic diagram showing the evolution of thermal expansion coefficients of water and a solid skeleton with temperature according to an embodiment of the present invention;

图3是本发明实施例不同初始温度的充填体单元在不同加热和冷却速率作用下的温度变化示意图;3 is a schematic diagram of temperature changes of filling body units with different initial temperatures under different heating and cooling rates according to an embodiment of the present invention;

图4是本发明实施例不同初始温度的充填体在不同加热和冷却速率作用下的水压变化示意图;(a)加热作用(b)冷却作用。FIG. 4 is a schematic diagram of the change in water pressure of a filling body with different initial temperatures under different heating and cooling rates according to an embodiment of the present invention; (a) heating effect (b) cooling effect.

具体实施方式DETAILED DESCRIPTION

为使本发明的目的、技术方案及优点更加清楚明白,以下根据附图并列举实施例,对本发明做进一步详细说明。In order to make the purpose, technical solutions and advantages of the present invention more clearly understood, the present invention is further described in detail below with reference to the accompanying drawings and examples.

一种高温采场中的尾矿充填体孔隙水压模拟方法,基于Selvadurai和Suvoro v的孔隙热弹性理论框架,通过考虑水化反应耗水(即化学收缩作用)造成的水体积变化建立充填体非等温孔隙水压控制方程:A method for simulating pore water pressure of tailings filling in high-temperature mining sites is based on the pore thermoelasticity theory framework of Selvadurai and Suvorov. The non-isothermal pore water pressure control equation of the filling body is established by considering the water volume change caused by hydration reaction (i.e. chemical shrinkage):

Figure BDA0003631518850000111
Figure BDA0003631518850000111

其中,α表示Biot系数(α=1–Kd/Ks,式中Kd为充填体骨架的体积模量),n 是孔隙度,Ks和Kw分别为固相和水的体积模量,pw表示孔隙水压力,t为反应进行的时间,βs和βw分别是固相和水的热膨胀系数,T表示当前温度,εv为体积应变,k是渗透系数,η表示水的动态粘度,εshf为化学反应过程中的总耗水,ξ是水化度。Wherein, α represents the Biot coefficient (α=1–K d /K s , where K d is the bulk modulus of the filling skeleton), n is the porosity, K s and K w are the bulk moduli of the solid phase and water, respectively, p w represents the pore water pressure, t is the reaction time, β s and β w are the thermal expansion coefficients of the solid phase and water, respectively, T represents the current temperature, ε v is the volume strain, k is the permeability coefficient, η represents the dynamic viscosity of water, ε shf is the total water consumption in the chemical reaction process, and ξ is the hydration degree.

由于固体颗粒的可压缩性与充填体骨架相比可以忽略不计(即Kd<<Ks),因此可假设Biot系数α近似为1(α≈1,

Figure BDA0003631518850000112
)。同时,由于本发明主要关注温度荷载对充填体孔隙水压的影响效应,因此可以充填体单元为研究对象,进而排除渗流项并将式(1)简化为:Since the compressibility of solid particles is negligible compared with that of the filling body skeleton (i.e., K d << K s ), it can be assumed that the Biot coefficient α is approximately 1 (α≈1,
Figure BDA0003631518850000112
). At the same time, since the present invention mainly focuses on the effect of temperature load on the pore water pressure of the filling body, the filling body unit can be taken as the research object, and then the seepage term is excluded and formula (1) is simplified to:

Figure BDA0003631518850000121
Figure BDA0003631518850000121

式(2)即为三轴水化压力室中的充填体单元孔隙水压控制方程。此外,考虑到非等温过程中的热膨胀效应,则该充填体单元的热弹性应力-应变关系可表示为:Formula (2) is the pore water pressure control equation of the filling unit in the triaxial hydration pressure chamber. In addition, considering the thermal expansion effect in the non-isothermal process, the thermoelastic stress-strain relationship of the filling unit can be expressed as:

Figure BDA0003631518850000122
Figure BDA0003631518850000122

其中,ε表示应变,E为杨氏模量,σ’表示有效应力,v是泊松比,T0表示初始温度。Where ε represents strain, E is Young's modulus, σ' represents effective stress, v is Poisson's ratio, and T 0 represents initial temperature.

为简化计算,本实施例进一步在一维侧限条件下建立充填体的几何模型,因此充填体单元仅存在轴向应变,且x、y方向的有效应力相等,进而有以下关系成立:To simplify the calculation, this embodiment further establishes a geometric model of the filling body under one-dimensional confinement conditions, so that the filling body unit only has axial strain, and the effective stresses in the x and y directions are equal, and the following relationship is established:

Figure BDA0003631518850000123
Figure BDA0003631518850000123

因此充填体单元的体积变形可通过联立式(3)和式(4)获得:Therefore, the volume deformation of the filling unit can be obtained by combining equations (3) and (4):

Figure BDA0003631518850000124
Figure BDA0003631518850000124

式(5)中参数可表示为:The parameters in formula (5) can be expressed as:

Figure BDA0003631518850000125
Figure BDA0003631518850000125

在给定的围压条件下,有效应力的变化等于孔隙水压的变化(即

Figure BDA0003631518850000126
假设固相压缩为负),因此可将式(5)记为如下导数形式:Under given confining pressure conditions, the change in effective stress is equal to the change in pore water pressure (i.e.
Figure BDA0003631518850000126
Assuming that the solid phase compression is negative), equation (5) can be expressed as the following derivative form:

Figure BDA0003631518850000131
Figure BDA0003631518850000131

最后,在小应变假设前提下,将式(7)代入式(2)可最终得到非等温条件下的充填体单元孔隙水压控制方程:Finally, under the assumption of small strain, substituting equation (7) into equation (2) can finally obtain the pore water pressure control equation of the filling unit under non-isothermal conditions:

Figure BDA0003631518850000132
Figure BDA0003631518850000132

此外,本实施例假设三轴水化压力室完全绝热,即充填体单元无法与周围环境产生热传导和对流换热,因此绝热不排水条件下的充填体温度变化仅由水化放热和该三轴装置施加的温度荷载产生,进而可将充填体温度定义为:In addition, this embodiment assumes that the triaxial hydration pressure chamber is completely insulated, that is, the filling body unit cannot generate heat conduction and convection heat exchange with the surrounding environment. Therefore, the filling body temperature change under the adiabatic and undrained conditions is only caused by the hydration heat release and the temperature load applied by the triaxial device. The filling body temperature can be defined as:

Figure BDA0003631518850000133
Figure BDA0003631518850000133

其中,k表示三轴装置施加的恒定温度变化速率,Th为水化反应造成的温升, Qf是化学反应过程中放出的热量,(ρC)eff表示有效热容((ρC)eff=(1–n)ρsCs+nρwC w),Cs和Cw分别为固液两相的比热容,ρs和ρw分别是固相和水的密度。Where k represents the constant temperature change rate applied by the triaxial device, Th is the temperature rise caused by the hydration reaction, Qf is the heat released during the chemical reaction, (ρC) eff represents the effective heat capacity ((ρC) eff = (1–n) ρsCs + nρwCw ), Cs and Cw are the specific heat capacities of the solid and liquid phases, respectively, and ρs and ρw are the densities of the solid phase and water, respectively.

根据Doherty和Muir Wood的研究,水化度与参考反应时间te的关系可表示为:According to the research of Doherty and Muir Wood, the relationship between the degree of hydration and the reference reaction time te can be expressed as:

ξ=1-exp(-κξ·te) (24)ξ=1-exp(-κ ξ ·t e ) (24)

其中,κξ为水化度随参考时间的演化速率。Where κ ξ is the evolution rate of the hydration degree with the reference time.

根据阿累尼乌斯公式,实际时间t与参考时间te的关系可表示为:According to the Arrhenius formula, the relationship between the actual time t and the reference time te can be expressed as:

Figure BDA0003631518850000134
Figure BDA0003631518850000134

其中,Ea表示化学反应需要的活化能,Ra是通用气体常数(Ra=8.314J/mol/K), Tr为参考温度。KWhere Ea represents the activation energy required for the chemical reaction, Ra is the universal gas constant ( Ra = 8.314 J/mol/K), and Tr is the reference temperature.

因此,将式(9)–(11)带入式(8),可最终得到充填体单元在温度荷载作用下的孔隙水压控制方程:Therefore, by substituting equations (9)–(11) into equation (8), we can finally obtain the pore water pressure control equation of the filling unit under the action of temperature load:

Figure BDA0003631518850000141
Figure BDA0003631518850000141

本发明使用如下公式描述充填体骨架刚度在水化过程中的增长演化:The present invention uses the following formula to describe the growth evolution of the filling body skeleton stiffness during the hydration process:

Kd=Kdi[λ-(λ-1)exp(-κK·te)] (27)K d =K di [λ-(λ-1)exp(-κ K ·t e )] (27)

式中Kdi为充填体的初始骨架刚度,λ为充填体最终刚度与初始刚度的比值,κK为控制刚度增长速率的模型参数。Where K di is the initial skeleton stiffness of the filling body, λ is the ratio of the final stiffness of the filling body to the initial stiffness, and κ K is the model parameter that controls the stiffness growth rate.

此外,使用如下公式描述水的热膨胀系数随温度的演化规律In addition, the following formula is used to describe the evolution of the thermal expansion coefficient of water with temperature:

βw=βw0+k0T (28)β ww0 +k 0 T (28)

式中βw0和k0为拟合参数。Where β w0 and k0 are fitting parameters.

不同温度环境条件下的充填体孔隙水压演化规律Evolution of pore water pressure in filling bodies under different temperature conditions

1)初始温度的影响1) Effect of initial temperature

以澳大利亚Kanowna Belle金矿使用的尾矿充填体为例,其物理化学参数如表1所示。绝热不排水环境中的充填体单元在不同初始温度条件下的孔隙水压演化规律如图1所示。图1表明,任一时刻的充填体水压均随初始温度的升高而先下降后上升。这是因为升高低温充填体的养护温度将加快化学反应速率,进而促进水化耗水造成的孔压耗散;同时,由于水的热膨胀系数在温度较低时仍然较小 (图2),因此水化放热造成的热膨胀效应并不明显,所以孔隙水压最终将在水化耗水作用的主导下随初始温度的升高而不断降低。然而随着养护温度继续升高,虽然充填体的化学反应速率将进一步加快,但同时水的热膨胀系数也将持续增大(图 2)。因此,当温度达到一定的临界值后,水化放热造成的水热增压效应将超过水化耗水作用,进而使得孔隙水压随初始温度的升高而上升。Taking the tailings backfill used in the Kanowna Belle gold mine in Australia as an example, its physical and chemical parameters are shown in Table 1. The evolution law of pore water pressure of the backfill unit under different initial temperature conditions in an adiabatic undrained environment is shown in Figure 1. Figure 1 shows that the backfill water pressure at any time first decreases and then increases with the increase of initial temperature. This is because increasing the curing temperature of the low-temperature backfill will accelerate the chemical reaction rate, thereby promoting the pore pressure dissipation caused by hydration water consumption; at the same time, since the thermal expansion coefficient of water is still small at low temperatures (Figure 2), the thermal expansion effect caused by hydration heat is not obvious, so the pore water pressure will eventually continue to decrease with the increase of initial temperature under the dominance of hydration water consumption. However, as the curing temperature continues to increase, although the chemical reaction rate of the backfill will further accelerate, the thermal expansion coefficient of water will continue to increase at the same time (Figure 2). Therefore, when the temperature reaches a certain critical value, the hydrothermal pressurization effect caused by hydration heat will exceed the hydration water consumption effect, thereby causing the pore water pressure to increase with the increase of initial temperature.

由图1还可以看出,当经过足够长时间(t=1000h)的化学反应后,孔隙水压几乎随初始温度的升高而单调上升。这是因为该时刻的水化反应已基本完成,即不同初始温度的充填体在水化反应作用下均产生了相同的温度上升和化学收缩,但由于高温时水的热膨胀系数更大,所以充填体将在更强的水热增压效应作用下产生更高的孔隙水压。It can also be seen from Figure 1 that after a sufficiently long time (t = 1000h) of chemical reaction, the pore water pressure increases almost monotonically with the increase of initial temperature. This is because the hydration reaction at this moment has been basically completed, that is, the filling bodies with different initial temperatures have the same temperature rise and chemical shrinkage under the action of hydration reaction, but because the thermal expansion coefficient of water is larger at high temperature, the filling body will produce higher pore water pressure under the stronger hydrothermal pressurization effect.

此外,从图1中还可以注意到,化学反应时间越长,孔隙水压由降转升的临界初始温度越低。这是因为低温会降低水化放热速率,所以需要更长的时间才能产生足够的温升以使得热膨胀效应完全抵消水化耗水的降压作用。In addition, it can be noted from Figure 1 that the longer the chemical reaction time, the lower the critical initial temperature at which the pore water pressure changes from decreasing to increasing. This is because low temperature will reduce the hydration heat release rate, so it takes longer to produce enough temperature rise so that the thermal expansion effect can completely offset the depressurization effect of hydration water consumption.

表1.澳大利亚Kanowna Belle金矿充填体的物理化学参数Table 1. Physical and chemical parameters of the filling body of Kanowna Belle gold mine, Australia

Figure BDA0003631518850000151
Figure BDA0003631518850000151

由以上讨论可知,初始温度条件对充填体孔隙水压演化的影响是水化耗水和水化放热二者相互竞争作用的结果。因为初始温度较低时水的热膨胀系数较小,所以水化耗水造成的水压耗散将起主要作用;然而由于水的热膨胀系数随温度的升高而快速增大,因此水化放热造成的水热增压效应则将最终控制充填体的孔隙水压演化。From the above discussion, it can be seen that the effect of initial temperature conditions on the evolution of pore water pressure in the filling body is the result of the competition between hydration water consumption and hydration heat release. Because the thermal expansion coefficient of water is small when the initial temperature is low, the water pressure dissipation caused by hydration water consumption will play a major role; however, since the thermal expansion coefficient of water increases rapidly with the increase of temperature, the hydrothermal pressurization effect caused by hydration heat release will ultimately control the evolution of pore water pressure in the filling body.

2)温度荷载的影响2) Influence of temperature load

本实施例通过对初始温度为0、15、30℃的充填体单元在不同强制温度变化速率(k=0、±2.5×10-3、±5.0×10-3℃/h)条件下的水压变化过程进行数值分析,进而研究温度荷载对充填体单元孔隙水压的影响机理。This example numerically analyzes the water pressure variation process of filling body units with initial temperatures of 0, 15, and 30°C under different forced temperature change rates (k=0, ±2.5×10 -3 , ±5.0×10 -3 ℃/h) to study the influence mechanism of temperature load on the pore water pressure of filling body units.

不同初始温度的充填体单元在不同加热和冷却速率条件下的温度变化规律如图3所示。图3表明,当k>0℃/h时,初始温度为15℃和30℃的充填体在加热早期均相较于低温(T0=0℃)状态产生了更显著的温升。这是因为初始温度越高,化学反应速率越快,因此充填体温度将在水化放热和强制加热的共同作用下急剧升高。随着水化反应逐渐完成,充填体的温升速率将由于水化放热减缓而不断下降并最终收敛于恒定的外部加热速率。而当k<0℃/h时,由于初始温度越低,化学反应速率越慢,因此冷却作用将强烈抑制低温充填体(T0=0℃)水化放热造成的温度上升。相比之下,初始温度为15℃和30℃的充填体在降温早期仍将由于较快的水化放热速率而产生显著的温升。然而随着水化反应逐渐完成,充填体的温度变化将最终由强制冷却作用控制。The temperature variation of the filling units with different initial temperatures under different heating and cooling rates is shown in Figure 3. Figure 3 shows that when k>0℃/h, the filling units with initial temperatures of 15℃ and 30℃ both produce more significant temperature rises in the early stage of heating compared with the low temperature (T 0 =0℃) state. This is because the higher the initial temperature, the faster the chemical reaction rate, so the filling temperature will rise sharply under the combined effect of hydration heat release and forced heating. As the hydration reaction is gradually completed, the temperature rise rate of the filling will continue to decrease due to the slowdown of hydration heat release and eventually converge to a constant external heating rate. When k<0℃/h, since the lower the initial temperature, the slower the chemical reaction rate, the cooling effect will strongly inhibit the temperature rise caused by the hydration heat release of the low-temperature filling (T 0 =0℃). In contrast, the filling units with initial temperatures of 15℃ and 30℃ will still produce significant temperature rises in the early stage of cooling due to the faster hydration heat release rate. However, as the hydration reaction is gradually completed, the temperature change of the filling body will eventually be controlled by forced cooling.

绝热不排水环境中的充填体单元在温度荷载作用下的水压演化规律如图4(a) 和图4(b)所示。图4(a)表明,初始温度为15℃和30℃的充填体在加热作用下均相较于恒温状态(k=0℃/h)产生了明显的水压增长。这是因为虽然加热造成的温度上升可加速化学收缩进而促进孔压耗散,但由于高温时水的热膨胀系数较大,所以水化耗水造成的降压作用难以抵消升温造成的水热增压效应,进而最终使得孔隙水压在加热过程中逐渐上升。从图4中还可以看出,由于水的热膨胀系数将随温度的升高而增大(图2),所以初始温度更高的充填体在相同的加热速率条件下将产生更早和更快的水压增长。相比之下,由于初始温度为0℃时水的热膨胀系数极小,因此升温对水化耗水的促进作用将超过水热增压效应,所以孔隙水压在加热早期反而略低于恒温状态。然而随着水化反应逐渐完成,持续的加热作用仍将产生显著的水热增压效应,因此充填体的孔隙水压将最终高于恒温状态。以上计算结果表明,由于充填体在持续加热作用下将最终产生显著的水热增压效应,因此高温采空区中的尾矿充填体将可能对挡墙产生更高的长期土压力。The evolution of water pressure of the backfill unit under temperature load in an adiabatic undrained environment is shown in Figure 4(a) and Figure 4(b). Figure 4(a) shows that the backfill with initial temperature of 15℃ and 30℃ has a significant increase in water pressure under heating compared with the constant temperature state (k = 0℃/h). This is because although the temperature rise caused by heating can accelerate chemical shrinkage and promote pore pressure dissipation, the thermal expansion coefficient of water is large at high temperature, so the pressure reduction effect caused by hydration water consumption is difficult to offset the hydrothermal pressurization effect caused by heating, and finally the pore water pressure gradually increases during the heating process. It can also be seen from Figure 4 that since the thermal expansion coefficient of water will increase with the increase of temperature (Figure 2), the backfill with a higher initial temperature will produce an earlier and faster water pressure increase under the same heating rate. In contrast, since the thermal expansion coefficient of water is extremely small when the initial temperature is 0℃, the promotion effect of heating on hydration water consumption will exceed the hydrothermal pressurization effect, so the pore water pressure is slightly lower than the constant temperature state in the early stage of heating. However, as the hydration reaction is gradually completed, the continuous heating will still produce a significant hydrothermal pressurization effect, so the pore water pressure of the filling body will eventually be higher than that of the constant temperature state. The above calculation results show that since the filling body will eventually produce a significant hydrothermal pressurization effect under the action of continuous heating, the tailings filling body in the high-temperature goaf may produce higher long-term earth pressure on the retaining wall.

而在冷却作用下,充填体初始温度为15℃和30℃时的孔隙水压均随温度的下降而快速降低(图4(b))。这是因为虽然降温会抑制水化耗水速率,但由于高温时水的热膨胀系数较大,因此充填体的冷却收缩最终将对孔压耗散产生显著的促进作用。相比之下,由于初始温度为0℃时水的热膨胀系数极小,因此孔隙流体在降温过程中的冷却收缩作用并不明显;同时,由于冷却作用也将强烈抑制水化耗水反应进而减缓孔压耗散速率,因此充填体初始温度为0℃时的孔隙水压在降温早期反而略高于恒温状态。然而随着水化反应逐渐完成,降温造成的冷却收缩将逐渐主导充填体的水压变化,因此孔隙水压最终将由于持续的冷却作用而低于恒温状态。以上计算结果表明,虽然低温环境会抑制水化耗水进而不利于孔压耗散,但由于充填体的冷却过程将导致流体收缩进而产生显著的降压效应,因此低温采空区中的充填作业通常具有更高的安全性。Under the cooling effect, the pore water pressure of the filling body at the initial temperature of 15℃ and 30℃ decreases rapidly with the decrease of temperature (Figure 4(b)). This is because although cooling will inhibit the hydration water consumption rate, the thermal expansion coefficient of water is large at high temperature, so the cooling and shrinkage of the filling body will eventually have a significant promoting effect on the pore pressure dissipation. In contrast, since the thermal expansion coefficient of water is extremely small when the initial temperature is 0℃, the cooling and shrinkage effect of the pore fluid during the cooling process is not obvious; at the same time, since the cooling effect will also strongly inhibit the hydration water consumption reaction and thus slow down the pore pressure dissipation rate, the pore water pressure of the filling body at the initial temperature of 0℃ is slightly higher than the constant temperature state in the early stage of cooling. However, as the hydration reaction is gradually completed, the cooling and shrinkage caused by cooling will gradually dominate the water pressure change of the filling body, so the pore water pressure will eventually be lower than the constant temperature state due to the continuous cooling effect. The above calculation results show that although the low temperature environment will inhibit hydration and water consumption and is not conducive to pore pressure dissipation, the cooling process of the filling body will cause the fluid to shrink and produce a significant pressure reduction effect. Therefore, the filling operation in the low-temperature goaf is usually safer.

由以上讨论可知,充填体与高温围岩的持续热量交换还会诱发热应变进而影响水压演化。当充填体初始温度较高时,由于水的热膨胀系数较大,因此热交换造成的水压变化将对水压演化起控制作用。然而当充填体温度较低时,虽然加热或降温作用造成的热应变也将对孔隙水压造成一定影响,但由于低温时水的热膨胀系数极小,因而热交换造成的水化耗水速率变化则将主导充填体早期的水压演化。然而随着化学反应逐渐完成,低温充填体的孔隙水压最终将由持续热交换产生的热应变控制。From the above discussion, it can be seen that the continuous heat exchange between the filling body and the high-temperature surrounding rock will also induce thermal strain and thus affect the evolution of water pressure. When the initial temperature of the filling body is high, the water pressure change caused by heat exchange will control the evolution of water pressure due to the large thermal expansion coefficient of water. However, when the filling body temperature is low, although the thermal strain caused by heating or cooling will also have a certain impact on the pore water pressure, the thermal expansion coefficient of water at low temperature is extremely small, so the change in hydration water consumption rate caused by heat exchange will dominate the early water pressure evolution of the filling body. However, as the chemical reaction is gradually completed, the pore water pressure of the low-temperature filling body will eventually be controlled by the thermal strain generated by continuous heat exchange.

本领域的普通技术人员将会意识到,这里所述的实施例是为了帮助读者理解本发明的实施方法,应被理解为本发明的保护范围并不局限于这样的特别陈述和实施例。本领域的普通技术人员可以根据本发明公开的这些技术启示做出各种不脱离本发明实质的其它各种具体变形和组合,这些变形和组合仍然在本发明的保护范围内。Those skilled in the art will appreciate that the embodiments described herein are intended to help readers understand the implementation methods of the present invention, and should be understood that the protection scope of the present invention is not limited to such specific statements and embodiments. Those skilled in the art can make various other specific variations and combinations that do not deviate from the essence of the present invention based on the technical revelations disclosed in the present invention, and these variations and combinations are still within the protection scope of the present invention.

Claims (4)

1. The method for simulating the pore water pressure of the tailing filling body in the height Wen Caichang is characterized by comprising the following steps of:
step 1, based on a pore thermoelastic theoretical framework of Selvadurai and Suvorov, establishing a filler non-isothermal pore water pressure control equation under creep loading conditions by considering water volume change caused by hydration reaction water consumption:
Figure QLYQS_1
wherein α represents the Biot coefficient, α=1-K d /K s K in the formula d For bulk modulus of the filler, n is porosity, K s And K w Bulk modulus of solid phase and water, respectively, p w Represents pore water pressure, t is the time of reaction, beta s And beta w The coefficients of thermal expansion of the solid phase and water, respectively, T representing the current temperature, ε v For volumetric strain, k is the permeability coefficient, η represents the dynamic viscosity of water, ε shf Is the total water consumption in the chemical reaction process, and ζ is the hydration degree;
step 2, assuming that the Biot coefficient alpha is approximately 1, alpha 1,
Figure QLYQS_2
taking a filling body unit as a research object, further removing a seepage term and simplifying the formula (1) as follows:
Figure QLYQS_3
the formula (2) is a filler pore water pressure control equation in the triaxial hydration pressure chamber;
step 3, in order to simulate the compression effect caused by the creep of surrounding rock, axial deformation with the rate j/s is applied to a filling body sample by utilizing a triaxial hydration pressure chamber, and the thermoelastic stress-strain relation of the filling body unit under the creep loading effect is expressed as follows:
Figure QLYQS_4
wherein ε represents strain, E represents Young's modulus, σ ' represents effective stress, v is Poisson's ratio, T 0 Indicating an initial temperature;
step 4, establishing a geometric model of the filling body under the one-dimensional lateral limit condition, so that the filling body unit only has axial strain, and the effective stress in the x and y directions is equal, and the following relationship is established:
Figure QLYQS_5
the volumetric deformation of the filler unit is thus obtained by the union (3) and the formula (4):
Figure QLYQS_6
the parameters in formula (5) are expressed as:
Figure QLYQS_7
step 5, under given confining pressure conditions, the change in effective stress is equal to the change in pore water pressure, i.e
Figure QLYQS_8
Figure QLYQS_9
Assuming that the solid phase compression is negative, equation (5) is therefore written as the derivative form: />
Figure QLYQS_10
And 6, substituting the formula (7) into the formula (2) on the premise of small strain assumption to finally obtain a pore water pressure control equation of the filler unit under the non-isothermal condition:
Figure QLYQS_11
step 7, assuming that the triaxial hydration pressure chamber is completely insulated, that is, the filler unit cannot generate heat conduction and convection with the surrounding environment, the temperature change of the filler under the condition of thermal insulation and non-drainage is generated only by hydration heat release and the temperature load applied by the triaxial device, and further define the temperature of the filler as:
Figure QLYQS_12
wherein k represents a constant rate of temperature change, T, applied by the triaxial apparatus h For the temperature rise caused by hydration reaction, Q f Is the heat evolved during the chemical reaction, (ρC) eff Representing effective heat capacity, i.e. ρC eff =(1–n)ρ s C s +nρ w C w ,C s And C w Specific heat capacity, ρ, of solid-liquid two phases respectively s And ρ w Respectively are provided withIs the density of the solid phase and water;
step 8, hydration degree and reference reaction time t e The relationship of (2) is expressed as:
ξ=1-exp(-κ ξ ·t e ) (10)
wherein, kappa ξ Is the evolution rate of hydration degree along with the reference time;
step 9, according to the Arrhenius Wu Sigong formula, the actual time t and the reference time t e The relationship of (2) is expressed as:
Figure QLYQS_13
wherein E is a Represents the activation energy required for chemical reactions, R a Is a general gas constant, R a =8.314J/mol/K,T r Is the reference temperature;
step 10, carrying the formulas (9) - (11) into the formula (8), and finally obtaining a pore water pressure control equation of the filler unit under the action of temperature load:
Figure QLYQS_14
2. a method for simulating pore water pressure of a tailings pond in a height Wen Caichang as claimed in claim 1, wherein: the growth evolution of the filler skeletal stiffness during hydration is described using the following formula:
K d =K di [λ-(λ-1)exp(-κ K ·t e )] (13)
k in the formula di The initial skeleton rigidity of the filler is lambda is the ratio of the final rigidity of the filler to the initial rigidity, kappa K To control the rate of stiffness increase.
3. A method for simulating pore water pressure of a tailings pond in a height Wen Caichang as claimed in claim 1, wherein: describing the evolution law of the thermal expansion coefficient of water along with the temperature by using the following formula
β w =β w0 +k 0 T (14)
Beta in w0 And k 0 Is a fitting parameter.
4. A method for simulating pore water pressure of a tailings pond in a height Wen Caichang as claimed in claim 1, wherein: the method is applied to the technical field of tailing filling and mining.
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