CN114889260A - Breathable and warm-keeping down jacket fabric and preparation method thereof - Google Patents
Breathable and warm-keeping down jacket fabric and preparation method thereof Download PDFInfo
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- CN114889260A CN114889260A CN202210569011.6A CN202210569011A CN114889260A CN 114889260 A CN114889260 A CN 114889260A CN 202210569011 A CN202210569011 A CN 202210569011A CN 114889260 A CN114889260 A CN 114889260A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/06—Thermally protective, e.g. insulating
- A41D31/065—Thermally protective, e.g. insulating using layered materials
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/14—Air permeable, i.e. capable of being penetrated by gases
- A41D31/145—Air permeable, i.e. capable of being penetrated by gases using layered materials
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/24—Resistant to mechanical stress, e.g. pierce-proof
- A41D31/245—Resistant to mechanical stress, e.g. pierce-proof using layered materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
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- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/107—Ceramic
- B32B2264/108—Carbon, e.g. graphite particles
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- D—TEXTILES; PAPER
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Abstract
The invention belongs to the technical field of garment processing, and particularly relates to a breathable and warm-keeping down jacket fabric and a preparation method thereof, wherein the breathable and warm-keeping down jacket fabric comprises a base fabric layer, a warm-keeping layer and a porous TPU film layer which are sequentially stacked from inside to outside, the warm-keeping layer is combined on the base fabric layer through padding type dyeing and finishing, and the warm-keeping layer is prepared from the following raw materials in parts by weight: 70 parts by weight of polyurethane, 50-70 parts by weight of silicon dioxide aerogel, 20 parts by weight of graphene particles and 0.1-0.5 part by weight of modified pore-foaming agent; the polyurethane in the heat-insulating layer of the fabric has good bonding strength, toughness and wear resistance, after the dyeing and finishing are combined on the base fabric layer, the heat-insulating property of the fabric can be greatly improved, and countless nano-scale air holes exist in the silicon dioxide aerogel through the combination of the silicon dioxide aerogel and the porous graphene particles, so that the heat-insulating and air-permeable properties can be improved.
Description
Technical Field
The invention belongs to the technical field of garment processing, and particularly relates to a breathable and warm-keeping down jacket fabric and a preparation method thereof.
Background
The garment is made of fabric, the fabric is the material for making the garment, and the down jacket is no exception. As one of the three elements of the garment, the fabric not only can explain the style and the characteristics of the garment, but also directly controls the expression effects of the color and the shape of the garment, presents the noble and perfect self and has soft hand feeling. However, in general, the high-quality and high-grade fabric of the down jacket has the characteristics of comfortable wearing, sweat absorption, air permeability, stiff and smooth suspension, noble vision, soft touch and the like. In particular, because the frequency of cleaning is relatively low, more stringent requirements are placed on the performance such as heat retention. Most of the existing down jacket fabrics adopt a surface coating method to coat a plurality of layers of functional coatings, although the down jacket fabrics have certain windproof and warm-keeping properties, the ventilation property is poor due to the extremely uneven surface coating and the unstable coating property, and the down jacket fabrics cannot be suitable for being worn and used in outdoor severe cold environments.
Disclosure of Invention
The invention aims to provide a breathable and warm-keeping down jacket fabric and a preparation method thereof, and solves the problems of poor warm-keeping performance and poor breathable effect of the existing down jacket fabric.
The invention realizes the purpose through the following technical scheme:
the breathable and warm-keeping down jacket fabric comprises a base cloth layer, a warm-keeping layer and a porous TPU film layer which are sequentially stacked from inside to outside, wherein the warm-keeping layer is combined on the base cloth layer through padding type dyeing and finishing, and is prepared from the following raw materials in parts by weight: 70 parts by weight of polyurethane, 50-70 parts by weight of silicon dioxide aerogel, 20 parts by weight of graphene particles and 0.1-0.5 part by weight of modified pore-foaming agent.
As a further optimization scheme of the invention, the modified pore-foaming agent is obtained by modifying a silane coupling agent and oxazoline to the pore-foaming agent.
As a further optimization scheme of the invention, the pore-forming agent is one of sodium chloride, potassium chloride, sodium citrate, sodium bicarbonate, potassium bicarbonate, lecithin and chitin.
As a further optimized scheme of the invention, the base cloth is formed by weaving 70% of terylene and 30% of polyarylate fibers.
As a further optimization scheme of the invention, the thickness of the TPU film layer is 0.08-0.15mm, and each square centimeter of the TPU film layer is provided with at least 500 air holes.
As a further optimization scheme of the invention, the diameter of the graphene particle is 150-300 μm.
A preparation method of the breathable and warm-keeping down jacket fabric comprises the following steps:
the method comprises the following steps: weaving terylene and polyarylester fibers to prepare a base cloth layer;
step two: adding a certain amount of silane coupling agent and oxazoline into the pore-foaming agent, and stirring for 20-60min at 40-60 ℃ to obtain a mixed solution A;
step three: mixing the silica aerogel and the mixed solution A in proportion, and stirring at the rotating speed of 300r/min for 5-10min at 250-;
step four: mixing polyurethane and the mixed solution B in proportion, adding graphene particles in proportion while stirring, continuously stirring for at least 50min, and standing for 2-3h to obtain a warm-keeping layer mixed solution;
step five: soaking the obtained base cloth layer in the mixed solution of the thermal insulation layer for padding treatment, wherein the padding process specifically comprises two-soaking and two-rolling, the soaking time is 3-5min, and the mangle ratio is 75-90%; and after padding, pre-drying and baking at 50-80 ℃ for 4-8min at the baking temperature of 120-140 ℃ for 3-4min, fully washing, drying at 60-80 ℃, bonding a TPU film layer on the outer side of the obtained heat-insulating layer on the base cloth layer through an adhesive, and hot-pressing to obtain the breathable and heat-insulating down jacket fabric.
As a further optimized scheme of the present invention, the graphene particles are specifically graphene porous particles obtained by performing thermal reduction on graphene oxide in an inert gas atmosphere.
The invention has the beneficial effects that:
1) polyurethane in the heat-insulating layer of the fabric has good bonding strength, toughness and wear resistance, after the fabric is combined with a base cloth layer fabric in a dyeing and finishing mode, the heat-insulating property of the fabric can be greatly improved, countless multiple nanoscale air holes exist in the silica aerogel through the combination of the silica aerogel and the porous graphene particles, the heat-insulating property and the air permeability can be improved, the graphene has a far infrared effect, the heat-insulating effect of the silica aerogel can be improved in an auxiliary mode, in addition, the porous graphene particles are adopted, the high heat-insulating property is provided for the fabric, and meanwhile, the air permeability is achieved;
2) according to the fabric, the modified pore-forming agent is added into the warm-keeping layer of the fabric, so that pore-forming substances in the polyurethane can be formed, and the modified pore-forming agent is added in the process of forming micropores in the polyurethane, so that the micropore structure of the polyurethane can be improved, the air permeability of the polyurethane is improved, the mechanical property of the polyurethane is reduced due to the increase of the air permeability, and the touch feeling of the warm-keeping layer is improved.
Detailed Description
The present application is described in further detail below, and it should be noted that the following detailed description is provided for illustrative purposes only, and is not intended to limit the scope of the present application, which is defined by the appended claims.
Example 1
The breathable and warm-keeping down jacket fabric comprises a base fabric layer, a warm-keeping layer and a porous TPU film layer, wherein the base fabric layer is formed by weaving 70% of terylene and 30% of polyarylester fibers which are sequentially stacked from inside to outside, the TPU film layer is 0.08 mm thick, at least 500 air holes are formed in each square centimeter of the TPU film layer, the TPU film layer is bonded to the outer side of the warm-keeping layer through a bonding agent, the warm-keeping layer is combined on the base fabric layer through padding type dyeing and finishing, and the warm-keeping layer is made of the following raw materials in parts by weight: 70 parts by weight of polyurethane, 50 parts by weight of silicon dioxide aerogel, 20 parts by weight of graphene particles with the diameter of 150 mu m and 0.1 part by weight of modified pore-foaming agent.
Wherein the modified pore-foaming agent is obtained by modifying sodium citrate with silane coupling agent and oxazoline.
The preparation method of the breathable warm-keeping down jacket fabric comprises the following steps:
the method comprises the following steps: weaving terylene and polyarylester fibers to prepare a base cloth layer;
step two: adding a certain amount of silane coupling agent and oxazoline into the pore-foaming agent, and stirring for 20min at 40 ℃ to obtain a mixed solution A;
step three: mixing the silica aerogel and the mixed solution A in proportion, and stirring at the rotating speed of 250r/min for 5min to obtain a mixed solution B;
step four: mixing polyurethane and the mixed solution B in proportion, adding graphene particles in proportion while stirring, continuously stirring for at least 50min, and standing for 2h to obtain a heat-insulating layer mixed solution;
step five: soaking the obtained base cloth layer in a warm-keeping layer mixed solution for padding treatment, wherein the padding process is specifically two-soaking and two-rolling, the soaking time is 3min, and the mangle ratio is 75%; and after padding, pre-drying and baking at 50 ℃ for 4min at 120 ℃ for 3min, fully washing, drying at 60 ℃, bonding a TPU film layer on the outer side of the obtained heat-insulating layer on the base cloth layer through an adhesive, and hot-pressing to obtain the breathable and heat-insulating down jacket fabric.
The graphene particles are specifically graphene porous particles obtained by carrying out thermal reduction on graphene oxide in an inert gas atmosphere.
Example 2
The breathable and warm-keeping down jacket fabric comprises a base fabric layer, a warm-keeping layer and a porous TPU film layer, wherein the base fabric layer is formed by weaving 70% of terylene and 30% of polyarylester fibers which are sequentially stacked from inside to outside, the TPU film layer is 0.15mm thick, each square centimeter of the TPU film layer is provided with at least 500 air holes, the TPU film layer is bonded to the outer side of the warm-keeping layer through a bonding agent, the warm-keeping layer is combined on the base fabric layer through padding type dyeing and finishing, and the warm-keeping layer is made of the following raw materials in parts by weight: 70 parts by weight of polyurethane, 70 parts by weight of silicon dioxide aerogel, 20 parts by weight of graphene particles with the diameter of 300 mu m and 0.5 part by weight of modified pore-foaming agent.
Wherein the modified pore-foaming agent is obtained by modifying potassium bicarbonate by using a silane coupling agent and oxazoline.
The preparation method of the breathable warm-keeping down jacket fabric comprises the following steps:
the method comprises the following steps: weaving terylene and polyarylester fibers to prepare a base cloth layer;
step two: adding a certain amount of silane coupling agent and oxazoline into the pore-foaming agent, and stirring for 60min at 60 ℃ to obtain a mixed solution A;
step three: mixing the silica aerogel and the mixed solution A in proportion, and stirring at the rotating speed of 300r/min for 10min to obtain a mixed solution B;
step four: mixing polyurethane and the mixed solution B in proportion, adding graphene particles in proportion while stirring, continuously stirring for at least 50min, and standing for 3h to obtain a heat-insulating layer mixed solution;
step five: soaking the obtained base cloth layer in the mixed solution of the thermal insulation layer for padding treatment, wherein the padding process is specifically two-soaking and two-rolling, the soaking time is 5min, and the mangle ratio is 90%; and after padding, pre-drying and baking at 80 ℃ for 8min at 140 ℃ for 4min, fully washing, drying at 80 ℃, bonding a TPU film layer on the outer side of the obtained heat-insulating layer on the base cloth layer through an adhesive, and hot-pressing to obtain the breathable and heat-insulating down jacket fabric.
The graphene particles are specifically graphene porous particles obtained by carrying out thermal reduction on graphene oxide in an inert gas atmosphere.
Example 3
The breathable and warm-keeping down jacket fabric comprises a base fabric layer, a warm-keeping layer and a porous TPU film layer, wherein the base fabric layer is formed by weaving 70% of terylene and 30% of polyarylester fibers which are sequentially stacked from inside to outside, the TPU film layer is 0.1 mm thick, each square centimeter of the TPU film layer is provided with at least 500 air holes, the TPU film layer is bonded to the outer side of the warm-keeping layer through a bonding agent, the warm-keeping layer is combined on the base fabric layer through padding type dyeing and finishing, and the warm-keeping layer is made of the following raw materials in parts by weight: 70 parts by weight of polyurethane, 60 parts by weight of silicon dioxide aerogel, 20 parts by weight of graphene particles with the diameter of 300 mu m and 0.3 part by weight of modified pore-foaming agent.
Wherein the modified pore-foaming agent is obtained by modifying potassium chloride by using a silane coupling agent and oxazoline.
The preparation method of the breathable warm-keeping down jacket fabric comprises the following steps:
the method comprises the following steps: weaving terylene and polyarylester fibers to prepare a base cloth layer;
step two: adding a certain amount of silane coupling agent and oxazoline into the pore-foaming agent, and stirring for 40min at 50 ℃ to obtain a mixed solution A;
step three: mixing the silica aerogel and the mixed solution A in proportion, and stirring at the rotating speed of 250r/min for 7min to obtain a mixed solution B;
step four: mixing polyurethane and the mixed solution B in proportion, adding graphene particles in proportion while stirring, continuously stirring for at least 50min, and standing for 2.5h to obtain a warm-keeping layer mixed solution;
step five: soaking the obtained base cloth layer in the mixed solution of the thermal insulation layer for padding treatment, wherein the padding process is specifically two-soaking and two-rolling, the soaking time is 4min, and the mangle ratio is 80%; and after padding, pre-drying and baking at 65 ℃ for 6min at 130 ℃ for 4min, fully washing, drying at 70 ℃, bonding a TPU film layer on the outer side of the heat-insulating layer on the obtained base cloth layer through an adhesive, and hot-pressing to obtain the breathable and heat-insulating down jacket fabric.
The graphene particles are specifically graphene porous particles obtained by carrying out thermal reduction on graphene oxide in an inert gas atmosphere.
Comparative example 1
The raw materials and the preparation method of the breathable and warm-keeping down jacket fabric are basically the same as those of the embodiment 1, and the only difference is that: the silica aerogel in the preparation raw materials of the thermal insulation layer is replaced by polyurethane with the same weight part.
Comparative example 2
The raw materials and the preparation method of the breathable and warm-keeping down jacket fabric are basically the same as those of the embodiment 2, and the only difference is that: the silane coupling agent and oxazoline modified potassium bicarbonate in the preparation raw materials of the warm-keeping layer are replaced by unmodified potassium bicarbonate.
Comparative example 3
The raw materials and the preparation method of the breathable and warm-keeping down jacket fabric are basically the same as those of the embodiment 3, and the only difference is that: the modified pore-foaming agent (obtained by modifying potassium chloride with silane coupling agent and oxazoline) in the preparation raw material of the thermal insulation layer is replaced by the silicon dioxide aerogel with equal weight parts.
The down jackets prepared in the above examples 1 to 3 and comparative examples 1 to 3 were taken as test samples, and the following tests were performed:
1. and (3) testing the heat retention property: the heat retention property adopts international standard ASTM D1518-2014 ″ (thermal plate method) in thermal resistance test method of cotton fiber system, (applicable to cotton fiber and multi-layer cotton fiber/fabric aggregate, having thermal conductivity and in the range of 0.1W/m 2 ·K~1.5W/m 2 K, the thickness of the test sample is not more than 50mm), and the warm keeping property of the sample down jacket before cleaning and the warm keeping property of the sample down jacket after cleaning are tested;
2. and (3) testing the air permeability: the test was carried out according to GB/T5453-1997 determination of the air permeability of textile fabrics, the test results being expressed in air permeability (mm/s).
The data in the table show that the down jacket fabric prepared in the embodiments 1-3 of the invention has excellent heat preservation and air permeability, and the fabric prepared by weaving 70% of terylene and 30% of polyarylate fiber into the base fabric layer has good elasticity, high tensile breaking strength and good air permeability; specifically, the thermal insulation layer is prepared from polyurethane, silica aerogel, porous graphene particles and a modified pore-forming agent, and as can be seen from the experimental results of examples 1 to 3, the polyurethane has good bonding strength, toughness and wear resistance, after the polyurethane is dyed and combined with the base fabric layer, an organosilicon chain segment with low surface energy can be enriched on the surface of the fabric, the polyurethane chain segment is close to the fabric and is tightly bonded with the fabric through hydrogen bonds and chemical bonds, the purposes of good water repellency and good fabric bonding property are achieved, the thermal insulation performance of the fabric can be greatly improved, countless nano-scale pores exist in the silica aerogel through the combination of the silica aerogel and the porous graphene particles, the thermal insulation and air permeability can be improved, the graphene has a far infrared effect, and the thermal insulation effect of the silica aerogel can be improved in an auxiliary manner, in addition, the porous graphene particles are adopted, so that the fabric has high heat preservation performance and air permeability; the experimental results of the embodiment 1 and the comparative example 1 show that the thermal insulation performance and the air permeability of the down jacket fabric without adding the silica aerogel are greatly reduced, because countless nanometer-scale air holes exist in the silica aerogel, the extremely high thermal insulation performance and the air permeability can be improved; it can be seen from the experimental data of example 2 and comparative example 2 that the thermal property of the fabric prepared in examples 1 to 3 is not much different from that of the conventional pore-forming agent but the air permeability is greatly reduced by replacing the modified pore-forming agent in the raw material for preparing the thermal layer with the conventional pore-forming agent, because the modified pore-forming agent can make the pore-forming substance in the polyurethane, and in the process of forming the micropores in the polyurethane, the modified pore-forming agent is added to improve the micropore structure of the polyurethane, so that the air permeability of the polyurethane is improved, while the conventional pore-forming agent also has the function of forming the pores in the polyurethane, but: the modifier oxazoline is added to effectively coat the pore-foaming agent in a multi-molecule accumulation mode, and the oxazoline is hydrophilic, and has enhanced moisture permeability and air permeability; the mechanical property of the polyurethane is reduced due to the increase of the air permeability, so that the touch feeling of the warm-keeping layer is improved; finally, it can be obtained from the experimental data of example 3 and comparative example 3 that the thermal insulation performance and the air permeability of the thermal insulation layer without the modified pore-forming agent are the lowest, so that the above conclusion can be demonstrated.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.
Claims (8)
1. A breathable and warm-keeping down jacket fabric is characterized in that: the thermal insulation fabric comprises a base fabric layer, a thermal insulation layer and a TPU film layer with a porous structure, wherein the base fabric layer, the thermal insulation layer and the TPU film layer are sequentially stacked from inside to outside, the thermal insulation layer is combined on the base fabric layer through padding type dyeing and finishing, and the thermal insulation layer is prepared from the following raw materials in parts by weight: 70 parts by weight of polyurethane, 50-70 parts by weight of silicon dioxide aerogel, 20 parts by weight of graphene particles and 0.1-0.5 part by weight of modified pore-foaming agent.
2. The breathable and warm-keeping down jacket fabric according to claim 1, characterized in that: the modified pore-foaming agent is obtained by modifying a silane coupling agent and oxazoline to the pore-foaming agent.
3. The breathable and warm-keeping down jacket fabric according to claim 1, characterized in that: the pore-forming agent is one of sodium chloride, potassium chloride, sodium citrate, sodium bicarbonate, potassium bicarbonate, lecithin and chitin.
4. The breathable and warm-keeping down jacket fabric according to claim 1, characterized in that: the base cloth is formed by weaving 70% of terylene and 30% of polyarylate fiber.
5. The breathable and warm-keeping down jacket fabric according to claim 1, characterized in that: the thickness of the TPU thin film layer is 0.08-0.15mm, and at least 500 air holes are formed in each square centimeter of the TPU thin film layer.
6. The breathable and warm-keeping down jacket fabric according to claim 1, characterized in that: the diameter of the graphene particle is 150-300 mu m.
7. A method for preparing the breathable and warm-keeping down jacket fabric as claimed in any one of claims 1 to 6, wherein the method comprises the following steps: the method comprises the following steps:
the method comprises the following steps: weaving terylene and polyarylester fibers to prepare a base cloth layer;
step two: adding a certain amount of silane coupling agent and oxazoline into the pore-foaming agent, and stirring for 20-60min at 40-60 ℃ to obtain a mixed solution A;
step three: mixing the silica aerogel and the mixed solution A in proportion, and stirring at the rotating speed of 300r/min for 5-10min at 250-;
step four: mixing polyurethane and the mixed solution B in proportion, adding graphene particles in proportion while stirring, continuously stirring for at least 50min, and standing for 2-3h to obtain a warm-keeping layer mixed solution;
step five: soaking the obtained base cloth layer in the mixed solution of the thermal insulation layer for padding treatment, wherein the padding process specifically comprises two-soaking and two-rolling, the soaking time is 3-5min, and the mangle ratio is 75-90%; and after padding, pre-drying and baking at 50-80 ℃ for 4-8min at the baking temperature of 120-140 ℃ for 3-4min, fully washing, drying at 60-80 ℃, bonding a TPU film layer on the outer side of the obtained heat-insulating layer on the base cloth layer through an adhesive, and hot-pressing to obtain the breathable and heat-insulating down jacket fabric.
8. The preparation method of the breathable and warm-keeping down jacket fabric according to claim 7, characterized by comprising the following steps of: the graphene particles are specifically graphene porous particles obtained by carrying out thermal reduction on graphene oxide in an inert gas atmosphere.
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