CN114854480A - 一种半合成切削液 - Google Patents
一种半合成切削液 Download PDFInfo
- Publication number
- CN114854480A CN114854480A CN202110150755.XA CN202110150755A CN114854480A CN 114854480 A CN114854480 A CN 114854480A CN 202110150755 A CN202110150755 A CN 202110150755A CN 114854480 A CN114854480 A CN 114854480A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- cutting fluid
- complexing agent
- semi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 239000002131 composite material Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 18
- 239000003899 bactericide agent Substances 0.000 claims abstract description 17
- 239000003513 alkali Substances 0.000 claims abstract description 16
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 239000013556 antirust agent Substances 0.000 claims abstract description 15
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- 239000008233 hard water Substances 0.000 claims abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 239000007957 coemulsifier Substances 0.000 claims abstract description 7
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 68
- 239000008139 complexing agent Substances 0.000 claims description 56
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 239000003112 inhibitor Substances 0.000 claims description 12
- 230000007797 corrosion Effects 0.000 claims description 11
- 238000005260 corrosion Methods 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 8
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004135 Bone phosphate Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004327 boric acid Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical group CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 6
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000006378 damage Effects 0.000 abstract description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000460 chlorine Substances 0.000 abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 abstract description 4
- 239000011593 sulfur Substances 0.000 abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 abstract description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 3
- 150000002989 phenols Chemical class 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 231100000331 toxic Toxicity 0.000 abstract description 3
- 230000002588 toxic effect Effects 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 16
- 238000002156 mixing Methods 0.000 description 9
- 239000004408 titanium dioxide Substances 0.000 description 8
- -1 alcohol ether carboxylic acid Chemical class 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 238000005520 cutting process Methods 0.000 description 6
- 230000001050 lubricating effect Effects 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 239000003784 tall oil Substances 0.000 description 5
- 239000012224 working solution Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000032798 delamination Effects 0.000 description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 3
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/04—Well-defined cycloaliphatic compounds
- C10M2203/045—Well-defined cycloaliphatic compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/18—Tall oil acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明属于切削液领域，具体涉及一种半合成切斜液，其质量配比如下：水性防锈剂6‑10份，碱缓冲剂6‑8份、去离子水52‑56份、特种胺1‑3份、乳化剂5‑8份、助乳化剂1‑2份、抗硬水剂1‑2份、缓释剂1‑2份、杀菌剂复合包1‑2份、基础油15‑20份、极压润滑剂3‑5份、耦合剂1‑3份、表面活性剂1‑3份、消泡剂复合包0.1‑0.2份。本发明满足GB/T6144‑2010及SY1374‑77的指标，不含、氯、酚类和亚硝酸盐，也不含硫等有毒有害物质，对人体无伤害，对环境无影响。
Description
技术领域
本发明属于切削液领域，具体涉及一种半合成切斜液。
背景技术
切削是机械制造中最主要的加工方法，在切削加工的过程中需要在刀具和工件之间加入适量的切削液，用来起到冷却、润滑、防锈、清洗等各种功能。尤其是用在金属切削加工上的切削液，其冷却性能和润滑性能决定了刀具的使用寿命和工件表面的切削效果。
专利号为CN104479826B的发明公开了一种超硬材料加工过程中的切削液，所述切削液包括有以下几种组成成分：二硫化钼、酒石酸、氯化石蜡、油酸、石油磺酸钠，以及变压器油和/或豆油。该发明虽然在切削液中加入了二硫化钼，使其具有较好的润滑性，但是研究发现二硫化钼在高温下容易被碳化失效，从而使得在高温下切削液的润滑性丧失，降低了刀具的使用寿命和工件表面的切削效果。
发明内容
针对现有技术中的问题，本发明提供一种半合成切削液，满足GB/T6144-2010及SY1374-77的指标，不含、氯、酚类和亚硝酸盐，也不含硫等有毒有害物质，对人体无伤害，对环境无影响。
为实现以上技术目的，本发明的技术方案是：
一种半合成切削液，其质量配比如下：
水性防锈剂6-10份，碱缓冲剂6-8份、去离子水52-56份、特种胺1-3份、乳化剂5-8份、助乳化剂1-2份、抗硬水剂1-2份、缓释剂1-2份、杀菌剂复合包1-2份、基础油15-20份、极压润滑剂3-5份、耦合剂1-3份、表面活性剂1-3份、消泡剂复合包0.1-0.2份。
所述水性防锈剂由硼酸、730三元酸和新癸酸组成，且硼酸、730三元酸和新葵酸的质量比为1:1:1。
所述碱缓冲剂采用一乙醇胺和三乙醇胺的混合物。
所述特种胺采用美国陶氏AMP95。
所述乳化剂采用沙索RT64。
所述助乳化剂采用M28B妥尔油脂肪酸。
所述抗硬水剂采用沙索4570LF醇醚羧酸。
所述缓释剂采用铝缓蚀剂，具体采用NEUF815铝缓蚀剂和磷酸酯型铝缓释剂混合而成。
所述杀菌剂复合包包括BIT和IPBC-30，且BIT和IPBC-30的值相比为1:0.5。进一步的，所述杀菌剂还包括微米二氧化钛颗粒，所述二氧化钛颗粒占杀菌剂复合包质量的2%。
所述基础油采用26#环烷基矿物油。
所述极压润滑剂采用禾大3955自乳化酯。
所述耦合剂采用丙二醇苯醚。
所述表面活性剂采用司盘80。
所述消泡剂复合包由快速型消泡剂和长寿命型消泡剂组成，且快速型消泡剂和长寿命型消泡剂的质量比为1:1，所述快速型消泡剂采用道康宁3168，所述长寿命型消泡剂采用道康宁1247。
所述半合成切削液的制备方法，包括如下步骤：
步骤1，将水性防锈剂、碱缓冲剂和部分去离子水按照比例加入至搅拌锅内搅拌0.5h，制成复合剂A；
步骤2，将特种铵加入至复合剂A中搅拌均匀，制成复合剂B；
步骤3，依次将乳化剂、助乳化剂和抗硬水剂加入至复合剂B搅拌均匀，制成复合剂C；
步骤4，将缓释剂和杀菌剂复合包加入至复合剂C中搅拌均匀，制成复合剂D；
步骤5，将基础油和极压润滑剂加入至复合剂D中搅拌均匀，然后将剩余的去离子水加入搅拌，制成复合剂E；
步骤6，将耦合剂和表面活性剂加入至复合剂E中搅拌均匀，然后缓慢加入消泡剂复合包并搅拌均匀，得到半合成切削液。
所述磨削液与蒸馏水配置成质量比为5%的工作液来使用。
从以上描述可以看出，本发明具备以下优点：
1.本发明满足GB/T6144-2010及SY1374-77的指标，不含、氯、酚类和亚硝酸盐，也不含硫等有毒有害物质，对人体无伤害，对环境无影响。
2.本发明具有良好地防锈清洗功能，有效折光40±1%，在保持工件表面清洁光亮防锈的同时，具有较好地清洗效果，同时，其低含油特性，使其拥有较好的润滑性，在用于CNC、加工车床、铣床、锯床等多种工艺，可有效减小刀具磨损，提高刀具的使用寿命。
3.本发明可实现长寿命使用，工作液可循再使用，可做到长期不更换新液，工作液可单机，可集中供应使用。
4.本发明有较好的机台防锈性能，不破坏油漆，与通常使用的机床密封件相容，同时，有较强的杀菌、抗菌、防腐能力，可有效杀灭细菌及真菌，使得工作液长时间使用，不宜生菌发臭。
5.本发明可适应铁、铸铁、不锈钢、碳钢等黑色金属以及各种材质的铝等有色金属材料工件加工。
具体实施方式
结合实施例详细说明本发明，但不对本发明的权利要求做任何限定。
实施例1
一种半合成切削液，其制备方法如下：
步骤1，将2g硼酸、2g730三元酸、2g新癸酸组成6g水性防锈剂，将3g美国陶氏的一乙醇胺和3g美国陶氏的三乙醇胺组成6g碱缓冲剂，将6g水性防锈剂和6g碱缓冲剂加入至20g去离子水中，并放入搅拌锅以500r/min的搅拌速度搅拌0.5h，制成复合剂A；
步骤2，将1g的AMP-95特种铵加入至复合剂A中，以500r/min的搅拌速度搅拌均匀，制成复合剂B；
步骤3，依次将6g沙索RT64、1gM28B妥尔油脂肪酸和1g沙索4570LF醇醚羧酸加入至复合剂B中搅拌均匀，制成复合剂C；
步骤4，将0.5gNEUF815铝缓蚀剂和0.5g磷酸酯型铝缓释剂混合形成1g缓蚀剂，将0.66gBIT和0.34gIPBC-30混合搅拌形成1g杀菌剂复合包，然后将缓释剂和杀菌剂复合包加入至复合剂C中搅拌均匀，制成复合剂D；
步骤5，将15g26#环烷基矿物油和3g禾大3955自乳化酯加入至复合剂D中搅拌均匀，然后将32g去离子水搅拌并持续搅拌，制成复合剂E；
步骤6，将1g丙二醇苯醚和1g司盘80加入至复合剂E中搅拌均匀，然后将0.05g道康宁3168和0.05g道康宁1247组成的0.1g消泡剂复合包缓慢加入，并持续搅拌，得到产品-半合成切削液。
实施例2
一种半合成切削液，其制备方法如下：
步骤1，将3g硼酸、3g730三元酸、4g新癸酸组成10g水性防锈剂，4美国陶氏的一乙醇胺和4g美国陶氏的三乙醇胺组成8g碱缓冲剂，将10g水性防锈剂和8g碱缓冲剂加入至20g去离子水中，并放入搅拌锅以1000r/min的搅拌速度搅拌0.5h，制成复合剂A；
步骤2，将3g的AMP-95特种铵加入至复合剂A中，以1000r/min的搅拌速度搅拌均匀，制成复合剂B；
步骤3，依次将8g沙索RT64、2gM28B妥尔油脂肪酸和2g沙索4570LF醇醚羧酸加入至复合剂B中搅拌均匀，制成复合剂C；
步骤4，将1gNEUF815铝缓蚀剂和1g磷酸酯型铝缓释剂混合形成2g缓蚀剂，将1.3gBIT和0.7gIPBC-30混合搅拌形成2g杀菌剂复合包，然后将缓释剂和杀菌剂复合包加入至复合剂C中搅拌均匀，制成复合剂D；
步骤5，将20g26#环烷基矿物油和5g禾大3955自乳化酯加入至复合剂D中搅拌均匀，然后将36g去离子水搅拌并持续搅拌，制成复合剂E；
步骤6，将3g丙二醇苯醚和3g司盘80加入至复合剂E中搅拌均匀，然后将0.1g道康宁3168和0.1g道康宁1247组成的0.2g消泡剂复合包缓慢加入，并持续搅拌，得到产品-半合成切削液。
实施例3
一种半合成切削液，其制备方法如下：
步骤1，将3g硼酸、3g730三元酸、3g新癸酸组成9g水性防锈剂，将3g美国陶氏的一乙醇胺和3g美国陶氏的三乙醇胺组成6g碱缓冲剂，将9g水性防锈剂和6g碱缓冲剂加入至20g去离子水中，并放入搅拌锅以500r/min的搅拌速度搅拌0.5h，制成复合剂A；
步骤2，将2g的AMP-95特种铵加入至复合剂A中，以500r/min的搅拌速度搅拌均匀，制成复合剂B；
步骤3，依次将7g沙索RT64、1gM28B妥尔油脂肪酸和2g沙索4570LF醇醚羧酸加入至复合剂B中搅拌均匀，制成复合剂C；
步骤4，将0.5gNEUF815铝缓蚀剂和0.5g磷酸酯型铝缓释剂混合形成1g缓蚀剂，将1gBIT和0.5gIPBC-30混合搅拌形成1.5g杀菌剂复合包，然后将缓释剂和杀菌剂复合包加入至复合剂C中搅拌均匀，制成复合剂D；
步骤5，将18g26#环烷基矿物油和4g禾大3955自乳化酯加入至复合剂D中搅拌均匀，然后将34g去离子水搅拌并持续搅拌，制成复合剂E；
步骤6，将2g丙二醇苯醚和2g司盘80加入至复合剂E中搅拌均匀，然后将0.05g道康宁3168和0.05g道康宁1247组成的0.1g消泡剂复合包缓慢加入，并持续搅拌，得到产品-半合成切削液。
实施例4
一种半合成切削液，其制备方法如下：
步骤1，将3g硼酸、3g730三元酸、3g新癸酸组成9g水性防锈剂，将3g美国陶氏的一乙醇胺和3g美国陶氏的三乙醇胺组成6g碱缓冲剂，将9g水性防锈剂和6g碱缓冲剂加入至20g去离子水中，并放入搅拌锅以500r/min的搅拌速度搅拌0.5h，制成复合剂A；
步骤2，将2g的AMP-95特种铵加入至复合剂A中，以500r/min的搅拌速度搅拌均匀，制成复合剂B；
步骤3，依次将7g沙索RT64、1gM28B妥尔油脂肪酸和2g沙索4570LF醇醚羧酸加入至复合剂B中搅拌均匀，制成复合剂C；
步骤4，将0.5gNEUF815铝缓蚀剂和0.5g磷酸酯型铝缓释剂混合形成1g缓蚀剂，将0.98gBIT、0.49gIPBC-30和0.03g微米二氧化钛混合搅拌形成1.5g杀菌剂复合包，然后将缓释剂和杀菌剂复合包加入至复合剂C中搅拌均匀，制成复合剂D；
步骤5，将18g26#环烷基矿物油和4g禾大3955自乳化酯加入至复合剂D中搅拌均匀，然后将34g去离子水搅拌并持续搅拌，制成复合剂E；
步骤6，将2g丙二醇苯醚和2g司盘80加入至复合剂E中搅拌均匀，然后将0.05g道康宁3168和0.05g道康宁1247组成的0.1g消泡剂复合包缓慢加入，并持续搅拌，得到产品-半合成切削液。
其中，微米二氧化钛的制备方法包括：步骤a，将10g钛酸正丁酯加入至30g无水乙醚中搅拌均匀，然后加入20g氯化钠和2g碳酸铵2℃低温搅拌形成悬浊液，40℃的温度，2MPa的压力下恒温造粒形成3mm颗粒，步骤b，将颗粒在100℃下静置0.5h，取出后依次采用甘油和无水乙醚洗涤后得到1-3微米的二氧化钛。微米二氧化钛本身具有抗菌性，能够在抗菌剂复合包中起到物理抗菌效果，同时二氧化钛结构稳定性，不易形成破坏，同时微米级二氧化钛能够形成一定的滚珠效应，大大降低了摩擦力，防止碎屑的二次划伤。
对比试验
以实施例3和实施例4制备的磨削液利用蒸馏水配制质量比为5%的工作液，对比例以某品牌磨削液为例，采用相同的配比配制对比工作液。铝合金加工工件表面粗糙度：实施例3的磨削液Ra0.27μm，实施例4的磨削液Ra0.24μm，对比例的Ra0.40μm。
工作8小时后取循环液进行静置比较：实施例3的磨屑完全分层时间为约1.5小时，实施例3的磨屑完全分层时间为约1.3小时，某品牌磨削液磨屑完全分层时间约为4小时。
本发明以水性防锈剂、碱缓冲剂、去离子水、特种胺、乳化剂、助乳化剂、抗硬水剂、缓释剂、杀菌剂、基础油、极压润滑剂、耦合剂，以及表面活性剂反应而成，具备一定的乳化能力，其稀释液具有良好的防锈性、抗菌性、润滑性，并具有低泡性；适合于多种加工方式，如车削、铣削、磨削等，可广泛用于单机和中央冷却系统。本发明的切削液有良好的清洗性、防锈性、润滑性等性能，同时还具有较强抗硬水性，不含亚硝酸纳，不含氯，不含硫，无气味，无毒无害，对车间员工皮肤不过敏。对铝筒等有色金属加工容易引起的变色，有较好的抑制作用。
可以理解的是，以上关于本发明的具体描述，仅用于说明本发明而并非受限于本发明实施例所描述的技术方案。本领域的普通技术人员应当理解，仍然可以对本发明进行修改或等同替换，以达到相同的技术效果；只要满足使用需要，都在本发明的保护范围之内。
Claims (9)
1.一种半合成切削液，其特征在于：其质量配比如下：
水性防锈剂6-10份，碱缓冲剂6-8份、去离子水52-56份、特种胺1-3份、乳化剂5-8份、助乳化剂1-2份、抗硬水剂1-2份、缓释剂1-2份、杀菌剂复合包1-2份、基础油15-20份、极压润滑剂3-5份、耦合剂1-3份、表面活性剂1-3份、消泡剂复合包0.1-0.2份。
2.根据权利要求1所述的半合成切削液,其特征在于:所述水性防锈剂由硼酸、730三元酸和新癸酸组成。
3.根据权利要求1所述的半合成切削液,其特征在于:所述碱缓冲剂采用一乙醇胺和三乙醇胺的混合物。
4.根据权利要求1所述的半合成切削液,其特征在于:所述缓释剂采用铝缓蚀剂。
5.根据权利要求1所述的半合成切削液,其特征在于:所述基础油采用26#环烷基矿物油。
6.根据权利要求1所述的半合成切削液,其特征在于:所述极压润滑剂采用禾大3955自乳化酯。
7.根据权利要求1所述的半合成切削液,其特征在于:所述耦合剂采用丙二醇苯醚。
8.根据权利要求1所述的半合成切削液,其特征在于:所述半合成切削液的制备方法，包括如下步骤：
步骤1，将水性防锈剂、碱缓冲剂和部分去离子水按照比例加入至搅拌锅内搅拌0.5h，制成复合剂A；
步骤2，将特种铵加入至复合剂A中搅拌均匀，制成复合剂B；
步骤3，依次将乳化剂、助乳化剂和抗硬水剂加入至复合剂B搅拌均匀，制成复合剂C；
步骤4，将缓释剂和杀菌剂复合包加入至复合剂C中搅拌均匀，制成复合剂D；
步骤5，将基础油和极压润滑剂加入至复合剂D中搅拌均匀，然后将剩余的去离子水加入搅拌，制成复合剂E；
步骤6，将耦合剂和表面活性剂加入至复合剂E中搅拌均匀，然后缓慢加入消泡剂复合包并搅拌均匀，得到半合成切削液。
9.根据权利要求1所述的半合成切削液,其特征在于:所述磨削液与蒸馏水配置成质量比为5%的工作液来使用。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110150755.XA CN114854480A (zh) | 2021-02-04 | 2021-02-04 | 一种半合成切削液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110150755.XA CN114854480A (zh) | 2021-02-04 | 2021-02-04 | 一种半合成切削液 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114854480A true CN114854480A (zh) | 2022-08-05 |
Family
ID=82623348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110150755.XA Pending CN114854480A (zh) | 2021-02-04 | 2021-02-04 | 一种半合成切削液 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114854480A (zh) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040248744A1 (en) * | 2001-08-14 | 2004-12-09 | King James P. | Soy-based methyl ester high performance metal working fluids |
| US20050037933A1 (en) * | 2003-04-24 | 2005-02-17 | Bingeman Ronald E. | Low foaming, lubricating, water based emulsions |
| CN104087408A (zh) * | 2014-07-29 | 2014-10-08 | 马思特（上海）化学有限公司 | 一种高润滑、低泡沫、使用寿命长的微乳型切削液 |
| CN106318586A (zh) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | 一种多用途半合成金属加工液及其制备方法 |
| CN109652180A (zh) * | 2019-01-11 | 2019-04-19 | 佛山市铂索润滑材料有限公司 | 一种高性能镁铝合金切削液及其制备方法 |
| CN109797033A (zh) * | 2019-01-11 | 2019-05-24 | 佛山市铂索润滑材料有限公司 | 一种长寿命镁铝合金切削液及其制备方法 |
| CN109797034A (zh) * | 2019-01-11 | 2019-05-24 | 佛山市铂索润滑材料有限公司 | 一种环保型纯镁加工液及其制备方法 |
| CN110452766A (zh) * | 2019-08-23 | 2019-11-15 | 广州市联诺化工科技有限公司 | 一种铝合金加工用全合成环保切削液及其制备方法 |
| CN110804485A (zh) * | 2019-11-25 | 2020-02-18 | 上海森帝润滑技术有限公司 | 一种全合成切削液及其制备方法 |
| CN110951533A (zh) * | 2019-12-05 | 2020-04-03 | 金雪驰科技（马鞍山）有限公司 | 一种金属加工用长效微乳化切削液及其制备方法 |
-
2021
- 2021-02-04 CN CN202110150755.XA patent/CN114854480A/zh active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040248744A1 (en) * | 2001-08-14 | 2004-12-09 | King James P. | Soy-based methyl ester high performance metal working fluids |
| US20050037933A1 (en) * | 2003-04-24 | 2005-02-17 | Bingeman Ronald E. | Low foaming, lubricating, water based emulsions |
| CN104087408A (zh) * | 2014-07-29 | 2014-10-08 | 马思特（上海）化学有限公司 | 一种高润滑、低泡沫、使用寿命长的微乳型切削液 |
| CN106318586A (zh) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | 一种多用途半合成金属加工液及其制备方法 |
| CN109652180A (zh) * | 2019-01-11 | 2019-04-19 | 佛山市铂索润滑材料有限公司 | 一种高性能镁铝合金切削液及其制备方法 |
| CN109797033A (zh) * | 2019-01-11 | 2019-05-24 | 佛山市铂索润滑材料有限公司 | 一种长寿命镁铝合金切削液及其制备方法 |
| CN109797034A (zh) * | 2019-01-11 | 2019-05-24 | 佛山市铂索润滑材料有限公司 | 一种环保型纯镁加工液及其制备方法 |
| CN110452766A (zh) * | 2019-08-23 | 2019-11-15 | 广州市联诺化工科技有限公司 | 一种铝合金加工用全合成环保切削液及其制备方法 |
| CN110804485A (zh) * | 2019-11-25 | 2020-02-18 | 上海森帝润滑技术有限公司 | 一种全合成切削液及其制备方法 |
| CN110951533A (zh) * | 2019-12-05 | 2020-04-03 | 金雪驰科技（马鞍山）有限公司 | 一种金属加工用长效微乳化切削液及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101104831B (zh) | 微乳化型不锈钢切削液 | |
| CN105176656A (zh) | 一种环境友好钛合金半合成切削液及其制备方法与应用 | |
| CN104277902A (zh) | 一种重负荷金属加工全合成切削液及其制备方法与应用 | |
| CN106281616A (zh) | 一种铝合金切削加工用长寿命低泡乳化液 | |
| KR100451979B1 (ko) | 물-혼화성 냉각 윤활 농축액 | |
| CN105670738A (zh) | 一种防锈乳化型金属切削液 | |
| CN109054973B (zh) | 一种微乳化切削液、制备方法及用途 | |
| CN104450087A (zh) | 一种环保型防锈切削剂 | |
| CN103555396A (zh) | 一种水基切削液 | |
| EP1013751A1 (en) | Water-soluble cutting fluid | |
| CN112646654A (zh) | 一种应用于铝合金材质的超高润滑环保切削液及其制备方法 | |
| US3177144A (en) | Lubricating composition | |
| US5417869A (en) | Surfactants and cutting oil formulations using these surfactants which resist microbial degradation | |
| CN109797033A (zh) | 一种长寿命镁铝合金切削液及其制备方法 | |
| US6448207B1 (en) | Metal working fluid | |
| US4218329A (en) | Cooling and lubricating fluid for metal working | |
| CN104004578A (zh) | 一种铝合金专用切削液 | |
| CN114854480A (zh) | 一种半合成切削液 | |
| CN111234909A (zh) | 用于机械加工的水基无油型节能环保高效的合成切削液 | |
| CN108441310B (zh) | 一种金属加工用半合成切削液及其制备方法 | |
| CN108774568B (zh) | 一种半合成铝合金加工液及其制备方法 | |
| CN104277898A (zh) | 一种全合成切削液 | |
| CN103351914A (zh) | 一种水溶性切削液 | |
| CN114317088A (zh) | 一种不含有机胺的生物稳定型水基乳化切削液及其制备方法 | |
| CN102911769A (zh) | 一种水溶性切削液 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220805 |