CN114836076A - Ink-jet printing ink and preparation method and application thereof - Google Patents
Ink-jet printing ink and preparation method and application thereof Download PDFInfo
- Publication number
- CN114836076A CN114836076A CN202210665739.9A CN202210665739A CN114836076A CN 114836076 A CN114836076 A CN 114836076A CN 202210665739 A CN202210665739 A CN 202210665739A CN 114836076 A CN114836076 A CN 114836076A
- Authority
- CN
- China
- Prior art keywords
- ink
- jet printing
- printing ink
- solvent
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007641 inkjet printing Methods 0.000 title claims abstract description 83
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000919 ceramic Substances 0.000 claims abstract description 55
- 239000000843 powder Substances 0.000 claims abstract description 36
- 239000012528 membrane Substances 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000002002 slurry Substances 0.000 claims description 44
- 238000003756 stirring Methods 0.000 claims description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 21
- 238000000227 grinding Methods 0.000 claims description 21
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 238000010304 firing Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 239000003607 modifier Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 229920003081 Povidone K 30 Polymers 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 229910052604 silicate mineral Inorganic materials 0.000 claims description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 239000003002 pH adjusting agent Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 abstract description 2
- 238000005245 sintering Methods 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 83
- 239000002245 particle Substances 0.000 description 20
- 239000012153 distilled water Substances 0.000 description 14
- 238000005516 engineering process Methods 0.000 description 14
- 238000007639 printing Methods 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 8
- 239000004576 sand Substances 0.000 description 8
- 239000011324 bead Substances 0.000 description 7
- 238000007599 discharging Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000010453 quartz Substances 0.000 description 7
- 238000001132 ultrasonic dispersion Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920001592 potato starch Polymers 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 229920000881 Modified starch Polymers 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000005350 fused silica glass Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012876 topography Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention provides ink-jet printing ink and a preparation method and application thereof. The ink-jet printing ink comprises ceramic membrane material powder, a sintering aid, a pore-forming agent, a dispersing agent, a regulator and a solvent, and is suitable for ceramic membrane materials used by ink-jet printing equipment; the ink for ink-jet printing has a viscosity of 5 to 70mpa.s and a surface tension of 10 to 55mN.m ‑1 The pH value is 4.0-10.0, the precipitate is not generated after standing for 24 hours, and the use temperature is 15-45 ℃.
Description
Technical Field
The invention relates to the technical field of ink-jet printing, in particular to ink-jet printing ink and a preparation method and application thereof.
Background
The ink-jet printing technology is a new printing technology without contact, pressure and printing plate, and can input the information stored in an electronic computer into an ink-jet printer to realize printing. The ink jet printing technology can be classified into solid ink jet and liquid ink jet according to the operation principle. The working mode of solid ink-jet is mainly dye thermal sublimation, but the cost is higher; the main working modes of liquid ink jet printers are divided into thermal foaming type and micro piezoelectric type, and these two technologies are still the mainstream technologies in the current ink jet printing market.
The piezoelectric ink-jet printing technology is characterized by that a lot of small piezoelectric ceramics are placed near the nozzle of printing head, and under the action of voltage change at two ends of the piezoelectric ceramics, the piezoelectric ceramics have the characteristic of bending deformation, and when the image information voltage is applied to the piezoelectric ceramics, the stretching vibration deformation of the piezoelectric ceramics can be changed with the change of image information voltage, and the ink can be uniformly and accurately jetted from ink jet head under the stable state of normal temperature and normal pressure. The piezoelectric ink-jet printing technology has stronger control capability on ink drops, the particle shapes of the ink drops are more regular, the positioning is more accurate, the printing resolution is higher, and the high-precision printing is easy to realize.
Inkjet printing technology is divided into printing apparatus technology and printing ink technology. In the printing apparatus technology, dedicated inkjet printing apparatuses for various industries have been developed. The special ink-jet printing equipment for the ceramic color glaze is successfully put into production lines and research and development of ceramic wall and floor tiles in nearly 20 years, and the ceramic color glaze printing ink matched with the equipment is also successfully developed and put into the market along with the ink-jet printing equipment, so that the ceramic color glaze printing ink brings digital revolutionary progress to the ceramic decoration technology. In order to meet the innovative requirements of ceramic products, research and development are being carried out in the industry aiming at ceramic inks of different printing materials, and several types of products with different material compositions, different functions and different effects are derived, including common pigment inks, functional inks, bleeding inks, water-based inks and the like.
The ceramic color glaze ink for ink-jet printing consists of solid powder material and liquid material, the solid powder is the core matter to be printed, and the liquid is the supplementary material for ink-jet printing. The preparation process of the ceramic color glaze ink can be divided into two parts, namely preparation of ceramic color paste and adjustment of ink performance. The most critical in the whole preparation process of the ceramic ink is the grinding of the ceramic color paste. The preparation route of the ceramic color paste is as follows: selecting proper dispersant, solvent and grinding resin to prepare dispersion liquid, adding ceramic color glaze for premixing to fully wet the ceramic color glaze, and grinding the ceramic color glaze to the required particle size through a sand mill to obtain the ceramic color paste. The grain diameter of the colored glaze material is generally controlled to be about 300nm, and the maximum grain diameter is less than 1 mu m. After preparing the color paste, the color paste needs to be blended into ink in the next step: and adding a wetting leveling agent, a defoaming agent and an anti-settling agent into the dispersed ceramic color paste, adding a solvent to adjust the ink to the required solid content and viscosity, and filtering out trace large particles by using a corresponding filter element to obtain the ceramic ink. And then testing various indexes of viscosity, surface tension, particle size distribution, solid content and stability of the ceramic ink, observing whether various physical indexes meet requirements, further observing the shape of ink jet ink drops on an ink drop observation instrument and the printing test performance on an ink jet machine, and obtaining qualified ceramic ink after the series of tests.
From the material perspective, ceramic membranes belong to the field of special ceramic materials. At present, the traditional film coating process of the ceramic film mainly comprises air pressure spraying, dip coating and pouring coating, the processes have respective defects, the air pressure spraying process can cause a large amount of waste of spraying slurry and environmental pollution, and the dip coating and pouring coating process can cause the problems of uneven thickness, fine cracks and the like of the ceramic film due to uneven structure and difference of porosity of a support body. If the ceramic membrane is coated by adopting the ink-jet printing technology, the thickness of the coated membrane can be finely controlled, the waste of membrane materials and the environmental pollution in the membrane coating process are greatly reduced, the energy consumption of the ceramic membrane production is greatly reduced, the tissue structure of the obtained ceramic membrane is more uniform, the membrane quality is greatly improved, and the method is particularly suitable for preparing ultrafiltration-grade ceramic membranes and nanofiltration-grade ceramic membranes with the membrane aperture of less than 100 nanometers.
The ceramic membrane is prepared by adopting an ink-jet printing technology, conditions are provided on ink-jet printing equipment, existing equipment can be used, the most critical problem at present is to prepare ink-jet ink of the ceramic membrane material suitable for the ink-jet printing equipment, and at present, no research report of the ink-jet ink exists at home and abroad, and no product is sold on the market.
Disclosure of Invention
In view of the above, the present invention provides an ink for inkjet printing, a method for preparing the same and applications thereof, so as to solve or partially solve the problems in the prior art.
The first aspect of the invention provides an ink-jet printing ink which comprises, by mass, 20-40% of ceramic membrane material powder, 0.6-8% of a firing aid, 0-12% of a pore-forming agent, 4-15% of a dispersant, 0.2-6.0% of a regulator, and the balance of a solvent.
Preferably, in the inkjet printing ink, the ceramic film material powder includes at least one of alumina, zirconia, titania, silica, and silicon carbide.
Preferably, in the inkjet printing ink, the firing assistant includes at least one of metal oxide, fluoride, insoluble salt, soluble salt, and silicate mineral.
Preferably, the pore-forming agent comprises at least one of carbonate, nitride, soluble starch, soluble cellulose and polyethylene glycol.
Preferably, the dispersant of the ink-jet printing ink comprises at least one of A10, D15, ADD, sodium dodecyl benzene sulfonate, povidone K30 and glycerol.
Preferably, the solvent of the ink-jet printing ink comprises at least one of water, ethanol, glycol and ammonia water.
Preferably, the inkjet printing ink, the regulator comprises at least one of a defoaming agent, an electrolyte, a pH regulator, a viscosity regulator, and a surface tension regulator;
wherein the defoamer comprises n-butanol;
the electrolyte comprises sodium chloride;
the pH value regulator comprises sodium hydroxide or citric acid;
the viscosity modifier comprises polyvinyl alcohol;
the surface tension modifier comprises an ethylene oxide adduct or surfynol 465.
In a second aspect, the present invention also provides a method for preparing the ink for ink jet printing, comprising the following steps:
uniformly stirring ceramic membrane material powder, a firing aid, a pore-forming agent, a dispersant and a part of solvent to obtain slurry;
grinding the slurry;
and adding the rest solvent and the regulator into the ground slurry, and uniformly mixing to obtain the ink-jet printing ink.
Preferably, the preparation method of the ink-jet printing ink comprises the steps of grinding the slurry until the D50 is less than 0.5 μm;
and in the step of uniformly stirring the ceramic membrane material powder, the firing aid, the pore-forming agent, the dispersant and a part of solvent to obtain the slurry, wherein the mass of the part of solvent is 80-98% of the total mass of the solvent.
In a third aspect, the invention also provides an application of the ink-jet printing ink or the ink-jet printing ink prepared by the preparation method in an ink-jet printing ceramic membrane.
Compared with the prior art, the ink for ink-jet printing has the following beneficial effects:
the ink-jet printing ink comprises ceramic membrane material powder, a sintering aid, a pore-forming agent, a dispersing agent, a regulator and a solvent, and is suitable for ceramic membrane materials used by ink-jet printing equipment; the ink for ink-jet printing has a viscosity of 5 to 70mpa.s and a surface tension of 10 to 55mN.m -1 The pH value is 4.0-10.0, the mixture does not precipitate after standing for 24 hours, and the use temperature is 15-45 ℃.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It is obvious that the drawings in the following description are only some embodiments of the invention, and that for a person skilled in the art, other drawings can be derived from them without inventive effort.
FIGS. 1-2 show the surface topography of the alumina ceramic film prepared by the inkjet printing ink prepared in example 1 by an inkjet printing method under different magnifications.
Detailed Description
In the following, the technical solutions in the embodiments of the present invention will be clearly and completely described in conjunction with the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
The embodiment of the application provides an ink-jet printing ink which comprises, by mass, 20-40% of ceramic membrane material powder, 0.6-8% of a firing aid, 0-12% of a pore-forming agent, 4-15% of a dispersing agent, 0.2-6.0% of a regulator and the balance of a solvent.
In some embodiments, the ceramic membrane material powder includes at least one of alumina, zirconia, titania, silica, and silicon carbide. Preferably, the ceramic membrane material powder is a nano-scale powder material.
In some embodiments, the firing aid comprises at least one of a metal oxide, a carbide, an insoluble salt, a soluble salt, a silicate mineral.
Specifically, titanium oxide, lithium oxide, copper oxide, bismuth oxide, calcium oxide, magnesium oxide, boron oxide, etc. may be used as the metal oxide, calcium fluoride, magnesium fluoride, etc. may be used as the fluoride, calcium carbonate, magnesium carbonate, lithium carbonate, etc. may be used as the insoluble salt, copper acetate, etc. may be used as the soluble salt, bentonite, kaolin, etc. may be used as the silicate mineral.
In some embodiments, the pore former comprises at least one of a carbonate, a nitride, a soluble starch, a soluble cellulose, a polyethylene glycol.
Specifically, the carbonate can be potassium carbonate, sodium carbonate, calcium carbonate, magnesium carbonate, etc., the nitride can be silicon nitride, aluminum nitride, etc., the soluble starch can be soluble pregelatinized corn starch, soluble pregelatinized sweet potato starch, soluble pregelatinized potato starch, etc., and the soluble cellulose can be methyl cellulose, carboxymethyl cellulose, etc.
Specifically, the soluble pregelatinized corn starch can be a commercially available product, such as available from Ningjin county Jia and energy saving materials Co., Ltd; the soluble pregelatinized sweet potato starch can be obtained from commercial products, such as from open-seal Yijia building materials Co; the soluble pregelatinized potato starch can be obtained from commercially available products, for example, from Shandong starch Co.
In some embodiments, the dispersant comprises at least one of a10, D15, ADD, sodium dodecylbenzenesulfonate, povidone K30, glycerol.
Specifically, A10, D15 and ADD are all products sold by Taxing advanced New materials science and technology Co.
Povidone K30 is an organic compound with a molecular formula of (C) 6 H 9 NO) n It is white to milk white powder, odorless or slightly smelly, and tasteless.
In some embodiments, the solvent comprises at least one of water, ethanol, ethylene glycol, and ammonia.
In some embodiments, the modifier comprises at least one of a defoamer, an electrolyte, a pH modifier, a viscosity modifier, a surface tension modifier;
wherein the defoaming agent is n-butyl alcohol;
the electrolyte is sodium chloride;
the pH regulator comprises sodium hydroxide or citric acid;
the viscosity regulator is polyvinyl alcohol;
the surface tension modifier comprises an ethylene oxide adduct or surfynol 465.
surfynol 465 is a U.S. gas chemical industry gemini nonionic surfactant, has excellent performances of hydrophilicity, wetting, low foam and the like, and has excellent performance of reducing the surface tension of a water-based system, particularly reducing the dynamic surface tension.
Based on the same inventive concept, the invention also provides a preparation method of the ink-jet printing ink, which comprises the following steps:
s1, uniformly stirring ceramic membrane material powder, a firing aid, a pore-forming agent, a dispersing agent and a part of solvent to obtain slurry;
s2, grinding the slurry;
and S3, adding the rest solvent and the regulator into the ground slurry, and uniformly mixing to obtain the ink-jet printing ink.
In some embodiments, the slurry is milled to a D50 of less than 0.5 μm; and in the step of uniformly stirring the ceramic membrane material powder, the firing aid, the pore-forming agent, the dispersant and a part of solvent to obtain the slurry, wherein the mass of the part of solvent is 80-98% of the total mass of the solvent.
The ink-jet printing ink prepared by the method has the following properties: the ink has a viscosity of 5 to 70mpa.s and a surface tension of 10 to 55mN.m -1 The pH value is 4.0-10.0, and the stability is as follows: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
The ink-jet printing ink and the method for preparing the same according to the present application are further described below in specific examples. This section further illustrates the present invention with reference to specific examples, which should not be construed as limiting the invention. The technical means employed in the examples are conventional means well known to those skilled in the art, unless otherwise specified. Reagents, methods and apparatus employed in the present invention are conventional in the art unless otherwise indicated.
Example 1
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 10kg of aluminum oxide powder with the particle size D50 of 0.5 mu m, 100g of copper acetate, 220g of nano calcium carbonate powder, 170g of titanium oxide powder, 800g of commercially available soluble pregelatinized starch (purchased from Jiangsu Muwei Biotech Co., Ltd.), 1kg of ADD dispersing agent and 80g of n-butyl alcohol into 13kg of distilled water, and uniformly stirring and mixing to obtain aluminum oxide slurry;
s2, grinding the alumina slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.3mm), and discharging when the particle size D50 of the alumina slurry is 0.35 mu m;
s3, pouring 7kg of the alumina slurry ground in the step S2 into a stirring barrel for stirring, then respectively adding 400g of absolute ethyl alcohol, 600g of polyvinyl alcohol aqueous solution with the mass concentration of 0.5% and 2kg of distilled water, stirring for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes to obtain the ink for ink-jet printing.
The ink jet printing ink prepared in example 1 had the following properties: the ink had a viscosity of 50mpa.s and a surface tension of 23mN.m -1 The pH value is 7.0-8.0, and the stability is as follows: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
Example 2
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 10kg of silicon carbide powder with the particle size D50 of 0.3 mu m, 500g of bentonite, 300g of nano magnesium carbonate powder, 200g of white carbon black powder, 900g of ADD dispersing agent and 80g of n-butyl alcohol into 15kg of distilled water, and uniformly stirring and mixing to obtain silicon carbide slurry;
s2, grinding the silicon carbide slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.2mm), and discharging when the particle diameter D50 of the silicon carbide slurry is 0.25 mu m;
s3, pouring 7kg of the silicon carbide slurry ground in the step S2 into a stirring barrel for stirring, then respectively adding 400g of absolute ethyl alcohol, 100g of glycerol, 1kg of HPMC (hydroxypropyl methyl cellulose) aqueous solution with the mass concentration of 0.5% and 1.5kg of distilled water, stirring for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes to obtain the ink-jet printing ink.
The ink jet printing ink prepared in example 2 had the following properties: viscosity of ink: 33mpa.s, surface tension: 15mN.m -1 The pH value: 7.0-8.0, stability: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
Example 3
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 10kg of zirconia powder with the particle size D50 of 0.2 mu m, 300g of yttria powder, 500g of kaolin powder, 150g of calcium fluoride powder, 550g of commercially available soluble pregelatinized starch (purchased from Jiangsu Muwei Biotech Co., Ltd.), 1.2kg of ADD dispersing agent and 80g of n-butyl alcohol into 12kg of distilled water, and stirring and mixing uniformly to obtain zirconia slurry;
s2, grinding the zirconia slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.2mm), and discharging when the particle diameter D50 of the zirconia slurry is 0.15 mu m;
s3, pouring 7kg of the zirconia slurry ground in the step S2 into a stirring barrel for stirring, then respectively adding 400g of absolute ethyl alcohol, 400g of polyvinyl alcohol aqueous solution with the mass concentration of 0.5%, 200g of silica sol with the mass concentration of 30% and 2kg of distilled water, stirring for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes to obtain the ink-jet printing ink.
The properties of the ink-jet printing ink prepared in example 3 were as follows: viscosity of ink: 55mpa.s, surface tension: 40mN.m -1 The pH value: 8.0-9.0, stability: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
Example 4
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 10kg of fused silica powder with a particle size D50 of 1.0 μm, 1kg of alumina sol with a mass concentration of 10%, 200g of boric acid, 300g of bismuth oxide powder, 1.5kg of cellulose aqueous solution with a mass concentration of 5%, 1kg of ADD dispersant, and 80g of n-butanol into 9kg of distilled water, and uniformly stirring and mixing to obtain a silica slurry;
s2, grinding the quartz slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.2mm), and discharging when the particle size D50 of the quartz slurry is 0.30 μm;
s3, pouring 7kg of the quartz slurry ground in the step S2 into a stirring barrel for stirring, then respectively adding 200g of sodium dodecyl benzene sulfonate, 800g of HPMC aqueous solution with the mass concentration of 0.5% and 2kg of distilled water, stirring for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes to obtain the ink-jet printing ink.
The ink jet printing ink prepared in example 4 had the following properties: viscosity of ink: 20mpa.s, surface tension: 35mN.m -1 The pH value: 5.0-6.0, stability: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
Example 5
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 10kg of aluminum oxide powder with the particle size D50 of 0.5 mu m, 3kg of yttrium-stabilized zirconia powder with the particle size D50 of 0.2 mu m, which is produced by Oriental zirconium industries, 100g of copper acetate, 220g of nano calcium carbonate powder, 170g of titanium oxide powder, 800g of pregelatinized starch, 1kg of ADD dispersing agent and 80g of n-butyl alcohol into 13kg of distilled water, and stirring and mixing uniformly to obtain alumina-zirconia slurry;
s2, grinding the alumina-zirconia slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.2mm), and discharging when the particle diameter D50 of the alumina-zirconia slurry is 0.25 μm;
s3, pouring 7kg of the alumina-zirconia slurry ground in the step S2 into a stirring barrel for stirring, then respectively adding 400g of absolute ethyl alcohol, 600g of polyvinyl alcohol aqueous solution with the mass concentration of 0.5% and 2kg of distilled water, stirring for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes to obtain the ink for ink-jet printing.
The ink jet printing ink prepared in example 5 had the following properties: viscosity of ink: 49mpa.s, surface tension: 55mN.m -1 The pH value: 7.0-8.0, stability: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
Example 6
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 10kg of aluminum oxide powder with the particle size D50 of 0.5 mu m, 1kg of self-made AC composite dispersing agent and 120g A10 into 13kg of distilled water, and uniformly stirring and mixing to obtain aluminum oxide slurry;
s2, grinding the alumina slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.3mm), and discharging when the particle size D50 of the alumina slurry is 0.25 μm;
s3, pouring 7kg of the alumina slurry ground in the step S2 into a stirring barrel for stirring, then respectively adding 400g of absolute ethyl alcohol, 200g of ammonia water, 1kg of HPMC (hydroxy propyl methyl cellulose) aqueous solution with the mass concentration of 0.2%, 700g of sodium silicate aqueous solution with the mass concentration of 10% and 1.7kg of distilled water, stirring for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes to obtain the ink-jet printing ink;
the preparation method of the AC composite dispersant comprises the following steps: adding commercially available low-molecular-weight sodium polyacrylate (with the molecular weight of 1000-;
specifically, the mass ratio of the low-molecular-weight sodium polyacrylate, the ammonium polyacrylate, the sodium citrate, the maleic anhydride, the ADD and the water is 1:0.5:0.8:0.6:2.5: 60.
The ink jet printing ink prepared in example 6 had the following properties: viscosity of ink: 70mpa.s, surface tension: 55mN.m -1 The pH value: 9.0-10.0, stability: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
Example 7
The embodiment of the application provides a preparation method of ink-jet printing ink, which comprises the following steps:
s1, adding 6kg of silicon carbide powder with a particle size D50 of 0.3 μm, 4kg of fused silica powder with a particle size D50 of 0.5 μm and 1kg of ADD dispersant into 11kg of distilled water, and stirring and mixing uniformly to obtain silicon carbide-quartz slurry;
s2, grinding the silicon carbide-quartz slurry obtained in the step S1 in a sand mill (the diameter of grinding beads is 0.1mm), and discharging when the particle size D50 of the silicon carbide-quartz slurry is 0.25 mu m;
s3, taking 6kg of the silicon carbide-quartz slurry ground in the step S2, pouring the slurry into a stirring barrel for stirring, and then respectively adding 60g of surfynol-465, 300g of ethylene glycol and 360g of oxygen with the mass concentration of 10%The ink-jet printing ink is prepared by stirring alumina sol, 500g of 10% sodium silicate aqueous solution by mass, 900g of 0.5% polyvinyl alcohol aqueous solution by mass and 2.8kg of distilled water for 60 minutes, and then performing ultrasonic dispersion treatment for 30 minutes. The properties of the ink jet printing ink prepared in example 7 were as follows: viscosity of ink: 5mpa.s, surface tension: 10mN.m -1 The pH value: 4.0-5.0, stability: standing for 24 hours without precipitation, wherein the use temperature is 15-45 ℃.
The ink-jet printing ink prepared in the embodiment 1 is used for preparing an alumina ceramic membrane by an ink-jet printing method, and the surface topography of the prepared alumina ceramic membrane under different multiplying power is shown in fig. 1-2. Wherein fig. 1 is magnified 2000 times and fig. 2 is magnified 20000 times.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (10)
1. The ink for ink-jet printing is characterized by comprising the following raw materials, by mass, 20-40% of ceramic membrane material powder, 0.6-8% of a firing aid, 0-12% of a pore-forming agent, 4-15% of a dispersing agent, 0.2-6.0% of a regulator, and the balance of a solvent.
2. The ink-jet printing ink of claim 1, wherein the ceramic film material powder comprises at least one of alumina, zirconia, titania, silica, and silicon carbide.
3. The ink-jet printing ink of claim 1 wherein the firing aid comprises at least one of a metal oxide, a fluoride, an insoluble salt, a soluble salt, a silicate mineral.
4. The ink-jet printing ink of claim 1, wherein the pore former comprises at least one of a carbonate, a nitride, a soluble starch, a soluble cellulose, and a polyethylene glycol.
5. The ink-jet printing ink of claim 1, wherein the dispersant comprises at least one of a10, D15, ADD, sodium dodecylbenzenesulfonate, povidone K30, and glycerol.
6. The ink-jet printing ink of claim 1 wherein the solvent comprises at least one of water, ethanol, ethylene glycol, and ammonia.
7. The ink-jet printing ink of claim 1, wherein the modifier comprises at least one of a defoamer, an electrolyte, a pH modifier, a viscosity modifier, a surface tension modifier;
wherein the defoamer comprises n-butanol;
the electrolyte comprises sodium chloride;
the pH value regulator comprises sodium hydroxide or citric acid;
the viscosity modifier comprises polyvinyl alcohol;
the surface tension modifier comprises an ethylene oxide adduct or surfynol 465.
8. A method of preparing an ink jet printing ink as claimed in any one of claims 1 to 7, comprising the steps of:
uniformly stirring ceramic membrane material powder, a firing aid, a pore-forming agent, a dispersant and a part of solvent to obtain slurry;
grinding the slurry;
and adding the rest solvent and the regulator into the ground slurry, and uniformly mixing to obtain the ink-jet printing ink.
9. The method of making an ink jet printing ink as claimed in claim 8 wherein the slurry is milled to a D50 of less than 0.5 μm;
and in the step of uniformly stirring the ceramic membrane material powder, the firing aid, the pore-forming agent, the dispersant and a part of solvent to obtain the slurry, wherein the mass of the part of solvent is 80-98% of the total mass of the solvent.
10. Use of the ink-jet printing ink according to claims 1 to 7 or the ink-jet printing ink prepared by the preparation method according to any one of claims 8 to 9 in ceramic membranes for ink-jet printing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210665739.9A CN114836076A (en) | 2022-06-13 | 2022-06-13 | Ink-jet printing ink and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210665739.9A CN114836076A (en) | 2022-06-13 | 2022-06-13 | Ink-jet printing ink and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114836076A true CN114836076A (en) | 2022-08-02 |
Family
ID=82574233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210665739.9A Pending CN114836076A (en) | 2022-06-13 | 2022-06-13 | Ink-jet printing ink and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114836076A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118085640A (en) * | 2024-04-24 | 2024-05-28 | 汇成新材料(山东)有限公司 | Ceramic ink-jet printing anti-slip ink and preparation method and application method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110232524A1 (en) * | 2009-05-25 | 2011-09-29 | Korea Institute Of Ceramic Engineering And Technology | Ceramic ink for manufacturing ceramic thick film by inkjet printing |
| CN103224726A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Glaze ink with leather pattern effect for ceramic jet printing and preparation method thereof |
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| CN105384449A (en) * | 2015-11-11 | 2016-03-09 | 华中科技大学 | Ceramic ink and preparation method and applications thereof |
| CN107556822A (en) * | 2017-09-26 | 2018-01-09 | 深圳大学 | A kind of inkjet printing ceramic ink and preparation method thereof |
| CN108641483A (en) * | 2018-05-18 | 2018-10-12 | 山东国瓷康立泰新材料科技有限公司 | A kind of ceramic ink jet printing ink and preparation method thereof promoting color development |
-
2022
- 2022-06-13 CN CN202210665739.9A patent/CN114836076A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110232524A1 (en) * | 2009-05-25 | 2011-09-29 | Korea Institute Of Ceramic Engineering And Technology | Ceramic ink for manufacturing ceramic thick film by inkjet printing |
| CN103224726A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Glaze ink with leather pattern effect for ceramic jet printing and preparation method thereof |
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| CN105384449A (en) * | 2015-11-11 | 2016-03-09 | 华中科技大学 | Ceramic ink and preparation method and applications thereof |
| CN107556822A (en) * | 2017-09-26 | 2018-01-09 | 深圳大学 | A kind of inkjet printing ceramic ink and preparation method thereof |
| CN108641483A (en) * | 2018-05-18 | 2018-10-12 | 山东国瓷康立泰新材料科技有限公司 | A kind of ceramic ink jet printing ink and preparation method thereof promoting color development |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118085640A (en) * | 2024-04-24 | 2024-05-28 | 汇成新材料(山东)有限公司 | Ceramic ink-jet printing anti-slip ink and preparation method and application method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Dorey et al. | Electroceramic thick film fabrication for MEMS | |
| EP0857702B1 (en) | Method for producing ceramic substrate | |
| CN114836076A (en) | Ink-jet printing ink and preparation method and application thereof | |
| CN108641483B (en) | Ceramic ink-jet printing ink capable of promoting color development and preparation method thereof | |
| EP0426546A2 (en) | Ceramic filter and process for making it | |
| US20080194733A1 (en) | Pigmented Inks Suitable For Use With Ceramics and Method of Producing Same | |
| CN112521131B (en) | High-solid-phase-content alumina photosensitive ceramic material and preparation method thereof | |
| Zhao et al. | Preparation of TiO2 composite microfiltration membranes by the wet powder spraying method | |
| Pandiyan et al. | Formulation of spinel based inkjet inks for protective layer coatings in SOFC interconnects | |
| CN105126637A (en) | Gas-solid separation ceramic film and preparation method thereof | |
| CN105983349A (en) | Method for producing ceramic membrane through adopting suspension particle sintering technology | |
| CN104364222A (en) | Alumina porous body and method for manufacturing same | |
| CN108300229A (en) | A kind of water nano composite coating material and its preparation method and application | |
| Tian et al. | Effect of polystyrene addition on properties of porous Si3N4 ceramics fabricated by digital light processing | |
| CN112108013A (en) | Alumina ultrafiltration microfiltration membrane and preparation method and application thereof | |
| CN110981453B (en) | Preparation method of light ceramic filtering membrane | |
| ZHOU et al. | Barium titanate ceramic inks for continuous ink-jet printing synthesized by mechanical mixing and sol-gel methods | |
| Małek et al. | Technological properties of SiC-based ceramic slurries for manufacturing investment casting shell moulds | |
| KR101752681B1 (en) | Aqueous ceramic blue ink for ink-jet printing | |
| Carrijo et al. | Ti3SiC2-based inks for direct ink-jet printing technology | |
| Leyland et al. | Lithographic printing of ceramics | |
| Gardini et al. | Chemico-physical properties of nano-sized ceramic inks for ink-jet printing | |
| US20070228622A1 (en) | Production process of sheet-like dense cordierite sintered body | |
| CN113072840A (en) | Thermal sublimation ink based on compound disperse black dye and preparation method thereof | |
| Kwon et al. | Rheological behavior and ink-jet printing characteristics of aqueous ceramic complex ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220802 |