CN114832928A - Pulsed intelligent breaker of high-purity phosphorus - Google Patents
Pulsed intelligent breaker of high-purity phosphorus Download PDFInfo
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 181
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 172
- 239000011574 phosphorus Substances 0.000 title claims abstract description 172
- 239000002994 raw material Substances 0.000 claims abstract description 102
- 239000007787 solid Substances 0.000 claims abstract description 80
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 230000007246 mechanism Effects 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 28
- 230000035939 shock Effects 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 40
- 239000007788 liquid Substances 0.000 claims description 37
- 238000006073 displacement reaction Methods 0.000 claims description 17
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 206010063659 Aversion Diseases 0.000 claims 6
- 230000008676 import Effects 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 19
- 230000002269 spontaneous effect Effects 0.000 abstract description 19
- 238000000034 method Methods 0.000 abstract description 11
- 239000000243 solution Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 9
- 238000013019 agitation Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 239000003350 kerosene Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- DJFBJKSMACBYBD-UHFFFAOYSA-N phosphane;hydrate Chemical compound O.P DJFBJKSMACBYBD-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C19/00—Other disintegrating devices or methods
- B02C19/18—Use of auxiliary physical effects, e.g. ultrasonics, irradiation, for disintegrating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/36—Adding fluid, other than for crushing or disintegrating by fluid energy the crushing or disintegrating zone being submerged in liquid
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- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Disintegrating Or Milling (AREA)
Abstract
本发明公开了一种高纯度磷的脉冲式智能化破碎装置,具备破碎缸体、脉冲式破碎部件和扰流机构,破碎缸体用于放置固体磷原料,破碎缸体内填充有水,扰流机构设置在破碎缸体内,搅动池水,使破碎后的磷粉从固体磷原料上脱离,脉冲式破碎部件包括电磁脉冲发生器和脉冲反射器,电磁脉冲发生器输出端正对着固体磷原料,用于产生电磁脉冲波,并以冲击波的形式震碎固体磷原料,脉冲反射器与电磁脉冲发生器相对,接收并反射电磁脉冲发生器所发出的电磁脉冲,脉冲反射器所反射的电磁脉冲正对着固体磷原料,使电磁脉冲波以冲击波的形式震碎固体磷原料,固体磷原料的破碎过程无物理接触,从而规避碰撞自燃的风险。
The invention discloses a pulse-type intelligent crushing device for high-purity phosphorus, which is provided with a crushing cylinder, a pulse-type crushing component and a turbulence mechanism. The crushing cylinder is used for placing solid phosphorus raw materials, and the crushing cylinder is filled with water to disturb the flow. The flow mechanism is set in the crushing cylinder to agitate the pool water to separate the crushed phosphorus powder from the solid phosphorus raw material. The pulse crushing components include an electromagnetic pulse generator and a pulse reflector. The output end of the electromagnetic pulse generator is facing the solid phosphorus raw material. It is used to generate electromagnetic pulse waves and shatter solid phosphorus raw materials in the form of shock waves. The pulse reflector is opposite to the electromagnetic pulse generator, and receives and reflects the electromagnetic pulse sent by the electromagnetic pulse generator. The electromagnetic pulse reflected by the pulse reflector Directly facing the solid phosphorus raw material, the electromagnetic pulse wave shatters the solid phosphorus raw material in the form of a shock wave, and the crushing process of the solid phosphorus raw material has no physical contact, thereby avoiding the risk of collision and spontaneous combustion.
Description
技术领域technical field
本发明涉及破碎机械技术领域,具体涉及一种高纯度磷的脉冲式智能化破碎装置。The invention relates to the technical field of crushing machinery, in particular to a pulse-type intelligent crushing device of high-purity phosphorus.
背景技术Background technique
白磷是一种磷的单质,化学式为P4。外观为白色或浅黄色半透明性固体。质软,冷时性脆,见光色变深。暴露空气中在暗处产生绿色磷光和白烟。在湿空气中约40℃着火,在干燥空气中则稍高。白磷能直接与卤素、硫、金属等起作用,与硝酸生成磷酸,与氢氧化钠或氢氧化钾生成磷化氢及次磷酸钠或磷酸钾。应避免与氯酸钾、高锰酸钾、过氧化物及其他氧化物接触。White phosphorus is an elemental substance of phosphorus with the chemical formula P 4 . Appearance is white or light yellow translucent solid. Soft, brittle when cold, and darkens when exposed to light. Exposure to air produces green phosphorescence and white smoke in the dark. Fires at about 40°C in moist air and slightly higher in dry air. White phosphorus can directly act with halogen, sulfur, metal, etc., and generate phosphoric acid with nitric acid, and generate phosphine and sodium hypophosphite or potassium phosphate with sodium hydroxide or potassium hydroxide. Contact with potassium chlorate, potassium permanganate, peroxides and other oxides should be avoided.
现有技术中的破碎机构大多以物理接触的方式,通过碰撞来使原料碎裂,但由于磷的物理特性,在对块状高纯度磷破碎时,首先需要将破碎环境置于水中,避免磷原料接触空气而自燃,但是,破碎机构与块状磷原料接触碰撞的瞬间即会产生热量,在热量积蓄后即会使磷自燃,导致破碎无法进行。Most of the crushing mechanisms in the prior art use physical contact to crush the raw materials through collision. However, due to the physical properties of phosphorus, when crushing massive high-purity phosphorus, the crushing environment must first be placed in water to avoid phosphorus. The raw material ignites spontaneously when it comes into contact with the air. However, heat is generated at the moment when the crushing mechanism contacts and collides with the bulk phosphorus raw material. After the heat is accumulated, the phosphorus will spontaneously ignite, making the crushing impossible.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种高纯度磷的脉冲式智能化破碎装置,以解决现有技术中破碎机构大多以物理接触的方式,通过碰撞来使原料碎裂,在破碎磷原料时会使磷自燃,导致破碎无法进行的问题。The purpose of the present invention is to provide a pulse type intelligent crushing device of high-purity phosphorus, so as to solve the problem that most of the crushing mechanisms in the prior art are in the form of physical contact, and the raw materials are broken by collision, and when the phosphorus raw materials are crushed, the phosphorus Spontaneous combustion, resulting in the problem that the crushing cannot be carried out.
为解决上述技术问题,本发明具体提供下述技术方案:In order to solve the above-mentioned technical problems, the present invention specifically provides the following technical solutions:
一种高纯度磷的脉冲式智能化破碎装置,具备:A pulsed intelligent crushing device for high-purity phosphorus, with:
破碎缸体,所述破碎缸体用于放置固体磷原料,所述破碎缸体内填充有水,固体磷原料位于水中;a crushing cylinder, the crushing cylinder is used for placing the solid phosphorus raw material, the crushing cylinder is filled with water, and the solid phosphorus raw material is located in the water;
脉冲式破碎部件,所述脉冲式破碎部件设置在所述破碎缸体上,用于产生电磁脉冲波,并以冲击波的形式震碎固体磷原料;a pulse-type crushing component, which is arranged on the crushing cylinder and is used for generating electromagnetic pulse waves and crushing solid phosphorus raw materials in the form of shock waves;
扰流机构,所述扰流机构设置在所述破碎缸体内,搅动池水,使破碎后的磷粉从固体磷原料上脱离;a flow turbulence mechanism, which is arranged in the crushing cylinder to agitate the pool water to separate the crushed phosphorus powder from the solid phosphorus raw material;
所述脉冲式破碎部件包括电磁脉冲发生器和脉冲反射器,所述电磁脉冲发生器和所述脉冲反射器均固定在所述破碎缸体上,所述电磁脉冲发生器输出端正对着固体磷原料,用于产生电磁脉冲波,并以冲击波的形式震碎固体磷原料,所述脉冲反射器与所述电磁脉冲发生器相对,接收并反射所述电磁脉冲发生器所发出的电磁脉冲,所述脉冲反射器所反射的电磁脉冲正对着固体磷原料。The pulse crushing component includes an electromagnetic pulse generator and a pulse reflector, both of which are fixed on the crushing cylinder, and the output end of the electromagnetic pulse generator is facing the solid phosphorus. The raw material is used to generate electromagnetic pulse waves and shatter solid phosphorus raw materials in the form of shock waves. The pulse reflector is opposite to the electromagnetic pulse generator and receives and reflects the electromagnetic pulses sent by the electromagnetic pulse generator. The electromagnetic pulse reflected by the pulse reflector is directed to the solid phosphorus raw material.
作为本发明的一种优选方案,所述扰流机构为搅动式扰流结构,采用直接接触的方式搅动水液,使破碎后的磷粉从固体磷原料上脱离,所述扰流机构包括扰流板和驱动所述扰流板在所述破碎缸体内移动的搅动扰流部件。As a preferred solution of the present invention, the turbulence mechanism is a stirring turbulence structure, which uses a direct contact method to agitate the water and liquid to separate the crushed phosphorus powder from the solid phosphorus raw material. The turbulence mechanism includes a turbulence mechanism. A flow plate and an agitation and spoiler component that drives the spoiler to move within the crushing cylinder.
作为本发明的一种优选方案,所述搅动扰流部件的输出端与所述扰流板相连,且所述搅动扰流部件带动所述扰流板横向往复移动;As a preferred solution of the present invention, the output end of the agitation and spoiler component is connected to the spoiler, and the agitation and spoiler component drives the spoiler to reciprocate laterally;
所述搅动扰流部件包括设置在所述破碎缸体外部的搅动滑槽,所述搅动滑槽内设置有搅动滑座和驱动所述搅动滑座往复移动的搅动驱动组件,所述搅动滑座连接有倒U形支架,所述倒U形支架的其中一个端头与所述搅动滑座相连,所述倒U形支架的另一个端头则延伸至所述破碎缸体内且该端头与所述扰流板相连。The stirring and disturbing component includes a stirring chute arranged outside the crushing cylinder, and a stirring sliding seat and a stirring driving component for driving the stirring sliding seat to reciprocate are arranged in the stirring sliding groove. An inverted U-shaped bracket is connected, one end of the inverted U-shaped bracket is connected with the stirring sliding seat, and the other end of the inverted U-shaped bracket extends into the crushing cylinder and the end connected to the spoiler.
作为本发明的一种优选方案,所述扰流机构为喷射式扰流结构,利用水流对固体磷原料冲击,使破碎后的磷粉及磷块从固体磷原料上脱离,所述扰流机构包括扰流喷头和与所述扰流喷头相连的扰流泵,所述扰流喷头输出的水流对着固体磷原料。As a preferred solution of the present invention, the turbulence mechanism is a jet turbulence structure, which utilizes water flow to impact the solid phosphorus raw material, so that the crushed phosphorus powder and phosphorus blocks are separated from the solid phosphorus raw material. It includes a spoiler nozzle and a spoiler pump connected to the spoiler nozzle, and the water flow output by the spoiler nozzle is directed to the solid phosphorus raw material.
作为本发明的一种优选方案,所述扰流泵的进口安装于液面下方,所述扰流喷头设置在液面下且正对着固体磷原料。As a preferred solution of the present invention, the inlet of the turbulent pump is installed below the liquid surface, and the turbulent nozzle is arranged below the liquid surface and faces the solid phosphorus raw material.
作为本发明的一种优选方案,所述扰流喷头位于液面上方,且对着固体磷原料。As a preferred solution of the present invention, the turbulent nozzle is located above the liquid level and faces the solid phosphorus raw material.
作为本发明的一种优选方案,所述扰流机构还包括输出端与所述扰流喷头相连的移位部件,所述移位部件带动所述扰流喷头在液面上方移动,使所述扰流喷头喷出水流落在固体磷原料的不同区域上;As a preferred solution of the present invention, the turbulence mechanism further includes a displacement component whose output end is connected to the turbulent nozzle, and the displacement component drives the turbulent nozzle to move above the liquid surface, so that the The water sprayed by the spoiler nozzle falls on different areas of the solid phosphorus raw material;
所述移位部件包括设置在液面上方的环形安装板,所述环形安装板通过支架与所述破碎缸体相连,所述环形安装板上设置有环形的移位滑槽,所述移位滑槽内滑动设置有移位滑座和驱动所述移位滑座滑动的移位驱动组件,所述移位滑座连接有吊杆,所述吊杆的末端竖直向下且与所述扰流喷头相连。The displacement component includes an annular mounting plate arranged above the liquid surface, the annular mounting plate is connected with the crushing cylinder through a bracket, and an annular displacement chute is arranged on the annular mounting plate, and the displacement A shift slide and a shift drive assembly for driving the shift slide to slide are slidably arranged in the chute, the shift slide is connected with a hanger rod, and the end of the hanger rod is vertically downward and connected to the Spoiler nozzles are connected.
作为本发明的一种优选方案,所述扰流机构为涡流式扰流结构,其生成漩涡并利用漩涡吸引磷粉,使破碎后的磷粉从固体磷原料上脱离。As a preferred solution of the present invention, the turbulence mechanism is a vortex turbulence structure, which generates a vortex and uses the vortex to attract the phosphorus powder, so that the crushed phosphorus powder is separated from the solid phosphorus raw material.
作为本发明的一种优选方案,所述扰流机构包括涡流板和驱动所述涡流板水平转动的涡流扰流组件,所述涡流板设置有多个,且若干所述涡流板转动时形成的漩涡位于固体磷原料的四周。As a preferred solution of the present invention, the turbulence mechanism includes a vortex plate and a vortex spoiler assembly that drives the vortex plate to rotate horizontally. There are a plurality of the vortex plates, and a plurality of the vortex plates are formed when the vortex plates rotate. The vortex is located around the solid phosphorus feedstock.
作为本发明的一种优选方案,所述扰流机构包括涡流喷头和与所述涡流喷头相连的涡流泵,所述涡流泵的进口安装在漩涡的上部,且所述涡流泵的抽液方向沿漩涡的切向设置,所述破碎缸体呈圆柱筒状结构,所述涡流喷头紧贴在所述破碎缸体的内壁上,且所述涡流喷头的喷射方向沿所述破碎缸体的切向设置。As a preferred solution of the present invention, the turbulence mechanism includes a vortex nozzle and a vortex pump connected to the vortex nozzle, the inlet of the vortex pump is installed on the upper part of the vortex, and the pumping direction of the vortex pump is along the The vortex is arranged in the tangential direction, the crushing cylinder has a cylindrical structure, the vortex nozzle is closely attached to the inner wall of the crushing cylinder, and the injection direction of the vortex nozzle is along the tangential direction of the crushing cylinder. set up.
本发明与现有技术相比较具有如下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
(1)本发明通过设置脉冲式破碎部件对固体磷原料破碎,脉冲式破碎部件通过电磁脉冲发生器产生电磁脉冲波,使电磁脉冲波以冲击波的形式震碎固体磷原料,固体磷原料的破碎过程无物理接触,从而规避碰撞自燃的风险;(1) The present invention crushes the solid phosphorus raw material by setting the pulse crushing component, and the pulse crushing component generates an electromagnetic pulse wave through the electromagnetic pulse generator, so that the electromagnetic pulse wave smashes the solid phosphorus raw material in the form of a shock wave, and the crushing of the solid phosphorus raw material There is no physical contact in the process, so as to avoid the risk of collision and spontaneous combustion;
(2)本发明通过设置扰流机构,扰流机构具有良好的磷原料剥离性能,可搅动池水,使破碎后的磷粉从固体磷原料上脱离,且能够使磷原料沉底,避免磷原料上浮至液面而自燃,同时,整个破碎过程磷原料不会与其他部件接触碰撞,规避了由于触碰到磷,使磷受热而自燃的风险,从而增强破碎效率,降低破碎过程中自燃的风险,提升安全性能。(2) In the present invention, by setting the turbulence mechanism, the turbulence mechanism has good phosphorus raw material peeling performance, can agitate the pool water, separate the crushed phosphorus powder from the solid phosphorus raw material, and can make the phosphorus raw material sink to the bottom, avoiding the phosphorus raw material It floats to the liquid surface and spontaneously ignites. At the same time, the phosphorus raw material will not contact and collide with other components during the whole crushing process, avoiding the risk of spontaneous combustion due to the contact of phosphorus and heating the phosphorus, thereby enhancing the crushing efficiency and reducing the risk of spontaneous combustion during the crushing process. , to improve safety performance.
附图说明Description of drawings
为了更清楚地说明本发明的实施方式或现有技术中的技术方案,下面将对实施方式或现有技术描述中所需要使用的附图作简单地介绍。显而易见地,下面描述中的附图仅仅是示例性的,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据提供的附图引伸获得其它的实施附图。In order to illustrate the embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that are required to be used in the description of the embodiments or the prior art. Obviously, the drawings in the following description are only exemplary, and for those of ordinary skill in the art, other implementation drawings can also be obtained according to the extension of the drawings provided without creative efforts.
图1为本发明的整体示意图;Fig. 1 is the overall schematic diagram of the present invention;
图2为本发明实施例提供搅动式扰流结构的示意图;FIG. 2 is a schematic diagram of a stirring-type turbulence structure according to an embodiment of the present invention;
图3为本发明实施例提供喷射式扰流结构的示意图;FIG. 3 is a schematic diagram of a jet spoiler structure provided by an embodiment of the present invention;
图4为本发明实施例提供移位部件的结构示意图;4 is a schematic structural diagram of a displacement component provided in an embodiment of the present invention;
图5为本发明实施例提供移位部件的仰视图;5 is a bottom view of a displacement member provided in an embodiment of the present invention;
图6为本发明实施例提供涡流式扰流结构的示意图;FIG. 6 is a schematic diagram of a vortex flow spoiler structure according to an embodiment of the present invention;
图7为本发明实施例提供涡流喷头的示意图;7 is a schematic diagram of a vortex nozzle according to an embodiment of the present invention;
图8为本发明实施例提供涡流喷头的俯视示意图。FIG. 8 is a schematic top view of a vortex nozzle according to an embodiment of the present invention.
图中的标号分别表示如下:The symbols in the figure are as follows:
1-破碎缸体;2-脉冲式破碎部件;3-扰流机构;1- crushing cylinder; 2- pulse crushing part; 3- spoiler mechanism;
201-电磁脉冲发生器;202-脉冲反射器;201-electromagnetic pulse generator; 202-pulse reflector;
311-扰流板;312-搅动扰流部件;311 - spoiler; 312 - stirring spoiler;
3121-搅动滑槽;3122-搅动滑座;3123-搅动驱动组件;3124-倒U形支架;3121-stirring chute; 3122-stirring sliding seat; 3123-stirring drive assembly; 3124-inverted U-shaped bracket;
321-扰流喷头;322-扰流泵;323-移位部件;321 - spoiler nozzle; 322 - spoiler pump; 323 - displacement part;
3231-环形安装板;3232-移位滑槽;3233-移位滑座;3234-移位驱动组件;3235-吊杆;3231-ring mounting plate; 3232-shift chute; 3233-shift slide; 3234-shift drive assembly; 3235-boom;
331-涡流板;332-涡流扰流组件;333-涡流喷头;334-涡流泵。331-vortex plate; 332-vortex spoiler assembly; 333-vortex nozzle; 334-vortex pump.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
如图1至图8所示,本发明提供了一种高纯度磷的脉冲式智能化破碎装置,具备:As shown in Figures 1 to 8, the present invention provides a pulsed intelligent crushing device for high-purity phosphorus, comprising:
破碎缸体1,破碎缸体1用于放置固体磷原料,破碎缸体1内填充有水,固体磷原料位于水中;Crushing
脉冲式破碎部件2,脉冲式破碎部件2设置在破碎缸体1上,用于产生电磁脉冲波,并以冲击波的形式震碎固体磷原料;
扰流机构3,扰流机构3设置在破碎缸体1内,搅动池水,使破碎后的磷粉从固体磷原料上脱离;The
脉冲式破碎部件2包括电磁脉冲发生器201和脉冲反射器202,电磁脉冲发生器201和脉冲反射器202均固定在破碎缸体1上,电磁脉冲发生器201输出端正对着固体磷原料,用于产生电磁脉冲波,并以冲击波的形式震碎固体磷原料,脉冲反射器202与电磁脉冲发生器201相对,接收并反射电磁脉冲发生器201所发出的电磁脉冲,脉冲反射器202所反射的电磁脉冲正对着固体磷原料。The
磷应当保存在水中,且白磷不能存放在煤油或蜡中,因为白磷着火点很低,只有40℃,(熔点44.1℃,沸点280.5℃)暴露在空气中会自燃,所以必须隔绝空气保存在沸点比较高的物质里。而且白磷不溶于水,微溶于苯、氯仿,易溶于二硫化碳、煤油和石蜡等非极性溶剂中,形成白磷溶液。因为溶液是均匀的,在溶液的上层,溶质白磷仍然是与空气接触的,仍然有自燃的危险。并且溶剂煤油或石蜡匀为易燃物质,白磷的自燃会引燃煤油或石蜡,引发更严重的事故,而白磷密度(密度1.82g/cm^3)比水大,会沉在水下,所以采用水保存。Phosphorus should be stored in water, and white phosphorus cannot be stored in kerosene or wax, because the ignition point of white phosphorus is very low, only 40 ℃, (melting point 44.1 ℃, boiling point 280.5 ℃) will spontaneously ignite when exposed to air, so it must be isolated from the air and stored at the boiling point. in high matter. Moreover, white phosphorus is insoluble in water, slightly soluble in benzene and chloroform, and easily soluble in non-polar solvents such as carbon disulfide, kerosene and paraffin to form a white phosphorus solution. Because the solution is homogeneous, in the upper layer of the solution, the solute white phosphorus is still in contact with the air, and there is still a risk of spontaneous combustion. And solvent kerosene or paraffin are flammable substances, the spontaneous combustion of white phosphorus will ignite kerosene or paraffin, causing more serious accidents, while the density of white phosphorus (density 1.82g/cm^3) is larger than that of water and will sink underwater, so Preserve with water.
因此在本实施方式中,破碎缸体1内填充有水,固体磷原料放置在水中破碎,避免破碎过程中固体磷原料与空气接触,从而避免原料自燃的风险。Therefore, in this embodiment, the crushing
同样的,由于磷的着火点很低,若通过机械碰撞的方式来破碎固体磷原料,在碰撞接触的时候会发热,从而使固体磷原料受热,极有可能导致其自燃。本实施方式通过设置脉冲式破碎部件2对固体磷原料破碎,脉冲式破碎部件2通过电磁脉冲发生器201产生电磁脉冲波,使电磁脉冲波以冲击波的形式震碎固体磷原料,固体磷原料的破碎过程无物理接触,从而规避碰撞自燃的风险。Similarly, since the ignition point of phosphorus is very low, if the solid phosphorus raw material is broken by mechanical collision, it will generate heat when it is in collision and contact, so that the solid phosphorus raw material will be heated, which is very likely to cause its spontaneous combustion. In this embodiment, the solid phosphorus raw material is crushed by setting the
进一步地,本实施方式中脉冲式破碎部件2还包括脉冲反射器202,脉冲反射器202与电磁脉冲发生器201相对,接收并反射电磁脉冲发生器201所发出的电磁脉冲,脉冲反射器202所反射的电磁脉冲正对着固体磷原料,电磁脉冲发生器201和脉冲反射器202分别设置在固体磷原料的两侧,电磁脉冲波在破碎缸体1内来回震荡固体磷原料,从而达到较佳的破碎效果。Further, in the present embodiment, the pulsed crushing
需要说明的是,本实施方式通过设置扰流机构3,其可以搅动池水,使池水波动,从而将破碎后的磷从固体磷原料上脱落,落在缸底,使剩下的未被破碎的固体磷原料继续受到冲击波震荡,提升破碎效果。It should be noted that, in this embodiment, by setting the
其中,如图2所示,扰流机构3为搅动式扰流结构,采用直接接触的方式搅动水液,使破碎后的磷粉从固体磷原料上脱离,扰流机构3包括扰流板311和驱动扰流板311在破碎缸体1内移动的搅动扰流部件312。Among them, as shown in FIG. 2 , the
具体地,搅动扰流部件312的输出端与扰流板311相连,且搅动扰流部件312带动扰流板311横向往复移动,搅动扰流部件312包括设置在破碎缸体1外部的搅动滑槽3121,搅动滑槽3121内设置有搅动滑座3122和驱动搅动滑座3122往复移动的搅动驱动组件3123,搅动驱动组件3123可选用直线电机,搅动滑座3122连接有倒U形支架3124,倒U形支架3124的其中一个端头与搅动滑座3122相连,倒U形支架3124的另一个端头则延伸至破碎缸体1内且该端头与扰流板311相连。Specifically, the output end of the agitation and spoiler member 312 is connected to the
搅动扰流部件312工作时,搅动驱动组件3123带动搅动滑座3122在搅动滑槽3121往复移动,通过倒U形支架3124带动扰流板311在破碎缸体1内往复平移,从而搅动水液。When the stirring and disturbing component 312 works, the stirring
通过上述设置,扰流机构3可搅动水液使池水波动,从而将破碎后的磷从固体磷原料上脱落,提升破碎效果。但是其产生的水液拨动较小,难以使破碎的块状磷原料从固体磷原料上脱落,因此其剥离磷原料的效果较差。Through the above arrangement, the
同时在实施方式中,其采用直接接触的方式搅动水液,而水液中含有磷粉,在其搅动极有可能触碰到磷,在碰撞时会使磷受热,从而增加了磷自燃的风险。At the same time, in the embodiment, the water liquid is stirred by direct contact, and the water liquid contains phosphorus powder. During the stirring, it is very likely to touch the phosphorus, and the phosphorus will be heated during the collision, thereby increasing the risk of phosphorus spontaneous combustion. .
进一步地,该实施方式采用搅动式扰流结构,水液在破碎缸体1内不断波动,磷粉则随着水液的波动在破碎缸体1内游荡,若磷粉移动至液面上时,存在与空气接触而自燃的风险。Further, this embodiment adopts a stirring type turbulence structure, the water liquid fluctuates continuously in the crushing
在另一实施方式中,如图3所示,扰流机构3为喷射式扰流结构,利用水流对固体磷原料冲击,使破碎后的磷粉及磷块从固体磷原料上脱离,扰流机构3包括扰流喷头321和与扰流喷头321相连的扰流泵322,扰流喷头321输出的水流对着固体磷原料,扰流泵322的进口安装于液面下方,接近液面的区域,可避免吸入池底的粉末,扰流喷头321设置在液面下且正对着固体磷原料。In another embodiment, as shown in FIG. 3 , the
通过上述设置,扰流机构3可通过对准固体磷原料位置喷射水液,冲击固体磷原料,使其上破碎后的磷粉及块状磷原料从固体磷原料上脱落,相较于上一实施方式,其剥离磷原料的效果更好。Through the above arrangement, the
但是,该实施方式中采用喷射式扰流结构,水液在喷射液的冲击作用下在破碎缸体1内不断波动,磷粉则随着水液的波动在破碎缸体1内游荡,仍然存在着磷粉移动至液面上与空气接触而自燃的风险。However, in this embodiment, a jet-type turbulence structure is adopted, the water liquid continuously fluctuates in the crushing
为了进一步提升本实施方式中扰流机构3剥离磷原料的效果,扰流机构3还包括输出端与扰流喷头321相连的移位部件323,移位部件323带动扰流喷头321在液面上方移动,使扰流喷头321喷出水流落在固体磷原料的不同区域上,移位部件323包括设置在液面上方的环形安装板3231,环形安装板3231通过支架与破碎缸体1相连,环形安装板3231上设置有环形的移位滑槽3232,移位滑槽3232内滑动设置有移位滑座3233和驱动移位滑座3233滑动的移位驱动组件3234,移位驱动组件3234可为齿轮齿条驱动结构,移位滑座3233连接有吊杆3235,吊杆3235的末端竖直向下且与扰流喷头321相连。In order to further improve the effect of the
通过设置移位部件323,其可带动扰流喷头321移动,改变扰流喷头321喷出水流落在固体磷原料的位置,提升其剥离磷原料的效果,但在由于扰流喷头321移动位于液面下,而水液中含有磷粉,在其移动过程中,极有可能触碰到磷,在碰撞时会使磷受热,从而增加了磷自燃的风险。By disposing the displacement member 323, it can drive the
为了规避该风险,可将扰流喷头321位于液面上方,且对着固体磷原料,避免在搅动时与水液中的粉末接触。In order to avoid this risk, the
但总体来说,该实施方式相较于上一实施方式,其剥离磷原料的效果更好,且规避了触碰磷粉而导致自然的风险,但磷粉自行移动至液面上与存在与空气接触而自燃的风险仍然存在。But in general, compared with the previous embodiment, this embodiment has a better effect of stripping phosphorus raw materials, and avoids the natural risk caused by touching the phosphorus powder, but the phosphorus powder moves to the liquid surface by itself The risk of spontaneous combustion from exposure to air remains.
在又一实施方式中,扰流机构3为涡流式扰流结构,其生成漩涡并利用漩涡吸引磷粉,使破碎后的磷粉从固体磷原料上脱离。In yet another embodiment, the
扰流机构3包括涡流板331和驱动涡流板331水平转动的涡流扰流组件332,移位驱动组件3234为电机,涡流板331设置有多个,且若干涡流板331转动时形成的漩涡位于固体磷原料的四周。移位驱动组件3234带动涡流板331旋转,即可使破碎缸体1中水液形成漩涡,利用漩涡中心对周围物质的吸引力,将漩涡中心在固体磷原料的外侧,吸引固体磷原料已被破碎的粉末状磷原料,相较于第一个实施方式中的搅动式扰流结构,涡流式扰流结构对粉末状磷的吸引力更大,因此其剥离磷原料的效果更好,甚至能够与第二个实施方式中喷射式扰流结构相比。The
而且,由于漩涡的特性,会拉扯周围物质,并使该物质向底部沉积,因此涡流式扰流结构能够吸引破碎的磷原料,并磷原料沉积在缸底,避免其移动至液面上,从而减小磷原料与空气接触而自燃的风险。Moreover, due to the characteristics of the vortex, the surrounding material will be pulled and deposited to the bottom, so the vortex turbulence structure can attract the broken phosphorus raw material, and the phosphorus raw material will be deposited on the bottom of the cylinder to prevent it from moving to the liquid surface, thereby Reduce the risk of spontaneous combustion of phosphorus feedstock in contact with air.
需要说明的是,上述涡流式扰流结构通过直接接触的方式搅动水液以生成漩涡,在其搅动极有可能触碰到磷,在碰撞时会使磷受热,从而增加了磷自燃的风险。It should be noted that the above-mentioned vortex turbulence structure agitates the water by direct contact to generate vortices. During the agitation, it is very likely to touch the phosphorus, and the phosphorus will be heated during the collision, thereby increasing the risk of spontaneous combustion of the phosphorus.
为此,本实施方式提供了又一实施方式,在该实施方式中,扰流机构3仍然为涡流式扰流结构,但该扰流机构3包括涡流喷头333和与涡流喷头333相连的涡流泵334,涡流泵334的进口安装在漩涡的上部,且涡流泵334的抽液方向沿漩涡的切向设置,破碎缸体1呈圆柱筒状结构,涡流喷头333紧贴在破碎缸体1的内壁上,且涡流喷头333的喷射方向沿破碎缸体1的切向设置。To this end, this embodiment provides another embodiment. In this embodiment, the
在上述涡流式扰流结构中,通过涡流喷头333沿破碎缸体1的切向设置喷射水流,水流沿着缸体内壁平移,给破碎缸体1内部水液施加旋转力,使破碎缸体1内水液整体一同转动,在其中心形成漩涡。In the above-mentioned vortex flow turbulence structure, the water jet is set along the tangential direction of the crushing
上述实施方式,即可对破碎后的磷原料施加吸力,使其从固体磷原料上脱落,具有良好的磷原料剥离性能,且磷原料进入漩涡后会顺着漩涡下沉,可以避免磷原料上浮至液面而自燃,同时,整个破碎过程磷原料不会与其他部件接触碰撞,规避了由于触碰到磷,使磷受热而自燃的风险,因此,该实施方式可以很好地增强破碎效率,降低破碎过程中自燃的风险,提升安全性能。The above-mentioned embodiment can apply suction to the crushed phosphorus raw material to make it fall off from the solid phosphorus raw material, which has good phosphorus raw material peeling performance, and the phosphorus raw material will sink along the vortex after entering the vortex, which can prevent the phosphorus raw material from floating. At the same time, the phosphorus raw material will not contact and collide with other components during the whole crushing process, avoiding the risk of spontaneous combustion of phosphorus due to contact with phosphorus. Therefore, this embodiment can well enhance the crushing efficiency. Reduce the risk of spontaneous combustion during the crushing process and improve safety performance.
以上实施例仅为本申请的示例性实施例,不用于限制本申请,本申请的保护范围由权利要求书限定。本领域技术人员可以在本申请的实质和保护范围内,对本申请做出各种修改或等同替换,这种修改或等同替换也应视为落在本申请的保护范围内。The above embodiments are only exemplary embodiments of the present application, and are not intended to limit the present application. The protection scope of the present application is defined by the claims. Those skilled in the art can make various modifications or equivalent replacements to the present application within the spirit and protection scope of the present application, and such modifications or equivalent replacements should also be regarded as falling within the protection scope of the present application.
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