CN114813537A - Solar cell acid-resistant detection device and detection method thereof - Google Patents

Solar cell acid-resistant detection device and detection method thereof Download PDF

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Publication number
CN114813537A
CN114813537A CN202210469147.XA CN202210469147A CN114813537A CN 114813537 A CN114813537 A CN 114813537A CN 202210469147 A CN202210469147 A CN 202210469147A CN 114813537 A CN114813537 A CN 114813537A
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box
solar cell
acid
acetic acid
battery piece
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杨贵忠
陈佳鑫
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Nantong Tiansheng New Energy Technology Co ltd
Nantong T-Sun New Energy Co ltd
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Nantong Tiansheng New Energy Technology Co ltd
Nantong T-Sun New Energy Co ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N17/00Investigating resistance of materials to the weather, to corrosion, or to light
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S50/00Monitoring or testing of PV systems, e.g. load balancing or fault identification
    • H02S50/10Testing of PV devices, e.g. of PV modules or single PV cells

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  • Photovoltaic Devices (AREA)

Abstract

The invention provides a solar cell acid-resistant detection device and a detection method thereof. The invention provides a solar cell acid-resistant detection device and a detection method thereof, which are used for effectively evaluating the acid-resistant performance of slurry by testing the contact resistivity and EL images before and after the acid resistance of a cell piece, thereby improving the slurry and improving the performance of the slurry.

Description

Solar cell acid-resistant detection device and detection method thereof
Technical Field
The invention belongs to the field of solar cell testing, and particularly relates to a solar cell acid resistance detection device and a detection method thereof.
Background
At present, the solar cell is generally packaged by an EVA (ethylene-vinyl acetate copolymer) adhesive film, in the process of outdoor long-time exposure and use, besides water vapor erosion, the EVA adhesive film can be degraded to generate acetic acid, and the escaped acetic acid can corrode electrode grid lines, welding strips and the like of the solar cell, so that the output power and the safety performance of a photovoltaic module are influenced. Therefore, it is necessary to pay attention to the acetic acid corrosion resistance as an index of the reliability test of the photovoltaic product.
However, the current testing method is generally to use a high temperature and high humidity DH (85 ℃, 85% RH) environment test to evaluate the potential corrosion risk of the photovoltaic product, and the standard testing time is 1000h, and to better evaluate the corrosion resistance of the photovoltaic product, the testing time is also extended to 2000h or 3000 h. Such a long test period is obviously difficult to meet the test requirements in actual production, and is more difficult to deal with the introduction and upgrade of various novel battery and component products. Chinese patent discloses a device and method for detecting acid resistance of slurry [ application No.: 202011072801.0], which discloses an acid-resistant detection device, because the battery pieces are vertically placed, the upper part and the lower part of the same battery piece are unevenly corroded by acetic acid, and a certain area of the battery piece is more serious than other places, thereby influencing data analysis.
Therefore, a new detecting device and a new detecting method are needed to be provided, which can make the battery cell receive acid uniformly and improve the detecting efficiency.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to solve the problems of low detection efficiency and unstable detection result in the prior art, and provides an acid-resistant detection device for a solar cell, which comprises a sealing box, wherein acetic acid placing boxes are arranged at two side corners of the sealing box, a box with one side opened is arranged in the sealing box, a frame is arranged in the box, vent holes are uniformly distributed in the upper side and the lower side of the frame, and a cell fixing clamp is arranged on the upper end surface of the frame.
Further preferably, fans are disposed on the left and right sides and the upper and lower sides of the box.
A detection method adopting a solar cell acid-resistant detection device comprises the following steps:
step 1) testing the electrical property of the battery piece;
step 2) adding an acetic acid solution and a KCI solution into the acetic acid placing box, and clamping the battery piece through a battery piece fixing clamp;
step 3) horizontally stacking a plurality of whole sealing boxes in a damp-heat test box for heating, and turning on a fan to ensure that acetic acid vapor in the sealing boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, performing electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry.
Preferably, the concentration of the acetic acid solution is 0.2-0.8%.
Further preferably, the concentration of the KCI solution is 85-99%.
Further optimized, the heating temperature of the damp-heat test box is 70-90 ℃, and the heating time is 10-20 hours.
Further optimized, the electrical properties of step 4 are compared to contact resistivity and EL images.
Has the advantages that: compared with the prior art, the invention has the following specific advantages:
1. according to the invention, the independent seal boxes are arranged, so that the number of single detection is increased, and the detection efficiency is improved.
2. The detection device provided by the invention has the advantages of simple structure, convenience in use, uniform detection environment and detection accuracy improvement.
3. By adopting the detection device and the detection method, the corrosion resistance of the battery piece is rapidly and accurately evaluated by simulating the corrosion reaction of the battery piece in the acetic acid atmosphere and comparing the detection data with the initial data, so that the performance of the slurry is conveniently improved.
Drawings
Fig. 1 is a perspective view of a detection device of the present invention.
In the figure: seal box 1, acetic acid placing box 2, shelf 3, air vent 4, fan 5, battery piece fixation clamp 6, battery piece 7, box 8.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the present invention will be described in further detail with reference to specific embodiments. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the described embodiments of the invention without inventive step, are within the scope of protection of the invention.
The solar cell acid-resistant detection device comprises a sealing box 1, wherein two side corners of the sealing box 1 are fixedly provided with an acetic acid placing box 2, the acetic acid placing box 2 is filled with acetic acid with a certain concentration, a box 8 with one side open is arranged in the sealing box 1, a frame 3 with vent holes 4 uniformly distributed on the upper surface and the lower surface is arranged in the box 8, a cell fixing clamp 6 is arranged on the upper end surface of the frame 3, a cell 7 is flatly placed in the frame 3, and the two sides of the cell 7 are clamped by the cell fixing clamp 6, so that the cell 7 is stably placed in the center of the frame 3. The left side and the right side of box 8 and upper and lower side are equipped with fan 5, and when acetic acid produced steam in the heating of damp heat test box, whole box 8 was covered with to steam, through fan 5 makes steam in the shelf 3 distributes evenly, and the assurance cell 7's two sides receives the corrosivity of acetic acid the same.
A detection method adopting a solar cell acid-resistant detection device comprises the following steps:
step 1) testing the electrical property of the battery piece;
step 2) adding an acetic acid solution and a KCI solution into the acetic acid placing box 2, and clamping the battery piece through a battery piece fixing clamp 6;
step 3) horizontally stacking a plurality of whole sealing boxes 1 in a damp-heat test box for heating, and turning on a fan to ensure that acetic acid steam in the sealing boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, performing electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry.
Preferably, the concentration of the acetic acid solution is 0.2-0.8%.
Preferably, the concentration of the KCI solution is 85-99%.
Preferably, the heating temperature of the damp-heat test box is 70-90 ℃, and the heating time is 10-20 hours.
Optimally, the electrical property of the step 4 is compared with the contact resistivity and the EL image, the smaller the change of the contact resistivity is, the stronger the acid resistance property of the slurry is, and the more serious the shadow on the EL image after the experiment is, the poorer the acid resistance property of the slurry is.
The invention will be further understood by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions provided herein, the definition of the term provided herein controls.
As used herein, a feature that does not define a singular or plural form is also intended to include a plural form of the feature unless the context clearly indicates otherwise. It will be further understood that the term "prepared from …," as used herein, is synonymous with "comprising," including, "comprising," "having," "including," and/or "containing," when used in this specification means that the recited composition, step, method, article, or device is present, but does not preclude the presence or addition of one or more other compositions, steps, methods, articles, or devices. Furthermore, the use of "preferred," "preferably," "more preferred," etc., when describing embodiments of the present application, is meant to refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. In addition, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
Example 1
A detection method adopting a solar cell acid-resistant detection device comprises the following steps:
step 1) selecting four kinds of slurry, and respectively printing the four kinds of slurry on battery pieces, wherein each kind of slurry selects two battery pieces;
step 2) adding an acetic acid solution with the concentration of 0.2% and a KCI solution with the concentration of 85% into the acetic acid placing box 2, and clamping the battery piece by a battery piece fixing clamp 6 to enable the battery piece to be suspended in the center of the rack 3;
step 3) horizontally stacking 4 whole sealing boxes 1 in a damp-heat test box for heating at 70 ℃ for 20 hours, and turning on a fan to ensure that acetic acid steam in the sealing boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, then carrying out electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry, wherein the electrical properties comprise contact resistivity and EL images.
Figure BDA0003625852690000061
Example 2
A detection method adopting a solar cell acid-resistant detection device comprises the following steps:
step 1) selecting four kinds of slurry, and respectively printing the four kinds of slurry on battery pieces, wherein each kind of slurry selects two battery pieces;
step 2) adding an acetic acid solution with the concentration of 0.4% and a KCI solution with the concentration of 90% into the acetic acid placing box 2, and clamping the battery piece through a battery piece fixing clamp 6;
step 3) horizontally stacking 4 whole sealing boxes 1 in a damp-heat test box for heating at 75 ℃ for 16 hours, and turning on a fan to ensure that acetic acid steam in the sealing boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, then carrying out electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry, wherein the electrical properties comprise contact resistivity and EL images.
Figure BDA0003625852690000071
Example 3
A detection method adopting a solar cell acid-resistant detection device comprises the following steps:
step 1) selecting four kinds of slurry, and respectively printing the four kinds of slurry on battery pieces, wherein each kind of slurry selects two battery pieces;
step 2) adding an acetic acid solution with the concentration of 0.6% and a KCI solution with the concentration of 95% into the acetic acid placing box 2, and clamping the battery piece through a battery piece fixing clamp 6;
step 3) horizontally stacking 4 seal boxes 1 in a damp-heat test box for heating at 85 ℃ for 12 hours, and turning on a fan to ensure that acetic acid vapor in the seal boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, then carrying out an electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry, wherein the electrical properties comprise contact resistivity and an EL image.
Figure BDA0003625852690000081
Example 4
A detection method adopting a solar cell acid-resistant detection device comprises the following steps:
step 1) selecting four kinds of slurry, and respectively printing the four kinds of slurry on battery pieces, wherein each kind of slurry selects two battery pieces;
step 2) adding an acetic acid solution with the concentration of 0.8% and a KCI solution with the concentration of 99% into the acetic acid placing box 2, and clamping the battery piece through a battery piece fixing clamp 6;
step 3) horizontally stacking 4 whole sealing boxes 1 in a damp-heat test box for heating at 90 ℃ for 10 hours, and turning on a fan to ensure that acetic acid steam in the sealing boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, then carrying out electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry, wherein the electrical properties comprise contact resistivity and EL images.
Figure BDA0003625852690000091
In the above four examples, each slurry in each example corresponds to two battery pieces, and the average value of the two battery pieces is taken, and it is understood from the experimental results that the slurry 2 in the four examples has the smallest change in contact resistance and contact resistivity before and after, and thus it is understood that the acid resistance of the slurry 2 is the strongest.
Unless otherwise specifically stated, technical or scientific terms used herein shall have the ordinary meaning as understood by those of ordinary skill in the art to which this invention belongs. The use of "including" or "comprising" and the like in this disclosure does not limit the presence or addition of any number, step, action, operation, component, element, and/or group thereof or does not preclude the presence or addition of one or more other different numbers, steps, actions, operations, components, elements, and/or groups thereof. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number and order of the indicated features.
It will be understood that the above embodiments are merely exemplary embodiments adopted to illustrate the principles of the present invention, and the present invention is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.

Claims (7)

1. A solar cell antacid detection device, characterized in that: including seal box (1), the both sides corner of seal box (1) is equipped with acetic acid and places box (2), be equipped with one side open-ended box (8) in seal box (1), be equipped with shelf (3) in box (8), the last lower surface of shelf (3) evenly is covered with air vent (4), shelf (3) up end is equipped with battery piece fixation clamp (6).
2. The solar cell acid-resistance detection device according to claim 1, wherein: fans (5) are arranged on the left side, the right side, the upper side and the lower side of the box (8).
3. A detection method using the solar cell acid-resistance detection device according to any one of claims 1 to 2, comprising the steps of:
step 1) testing the electrical property of the battery piece;
step 2) adding an acetic acid solution and a KCI solution into the acetic acid placing box (2), and clamping the battery piece through a battery piece fixing clamp (6);
step 3) horizontally stacking a plurality of whole sealing boxes (1) in a damp-heat test box for heating, and opening a fan to ensure that acetic acid steam in the sealing boxes is uniformly distributed;
and 4) taking out the battery piece, cooling, performing electrical property test, and comparing with the electrical property test data in the step 1 to obtain the acid resistance of the slurry.
4. The solar cell acid-fast detection method according to claim 3, characterized in that: the concentration of the acetic acid solution is 0.2-0.8%.
5. The solar cell acid-fast detection method according to claim 3, characterized in that: the concentration of the KCI solution is 85-99%.
6. The solar cell acid-fast detection method according to claim 3, characterized in that: the heating temperature of the damp-heat test box is 70-90 ℃, and the heating time is 10-20 hours.
7. The solar cell acid-fast detection method according to claim 3, characterized in that: the electrical properties of step 4 are compared to contact resistivity and EL image.
CN202210469147.XA 2022-04-30 2022-04-30 Solar cell acid-resistant detection device and detection method thereof Pending CN114813537A (en)

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Application Number Priority Date Filing Date Title
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