CN114806107A - Ultraviolet photochromic cosmetics hose - Google Patents
Ultraviolet photochromic cosmetics hose Download PDFInfo
- Publication number
- CN114806107A CN114806107A CN202210547609.5A CN202210547609A CN114806107A CN 114806107 A CN114806107 A CN 114806107A CN 202210547609 A CN202210547609 A CN 202210547609A CN 114806107 A CN114806107 A CN 114806107A
- Authority
- CN
- China
- Prior art keywords
- photochromic
- ultraviolet
- coupling agent
- cosmetic hose
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 44
- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000007822 coupling agent Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- -1 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- OFFHCUWJGDPERE-UHFFFAOYSA-N butanedioic acid;1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound OC(=O)CCC(O)=O.CC1(C)CC(O)CC(C)(C)N1CCO OFFHCUWJGDPERE-UHFFFAOYSA-N 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- BSWXAWQTMPECAK-UHFFFAOYSA-N 6,6-diethyloctyl dihydrogen phosphate Chemical class CCC(CC)(CC)CCCCCOP(O)(O)=O BSWXAWQTMPECAK-UHFFFAOYSA-N 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical class [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 229920001903 high density polyethylene Polymers 0.000 claims description 4
- 239000004700 high-density polyethylene Substances 0.000 claims description 4
- 229920001684 low density polyethylene Polymers 0.000 claims description 4
- 239000004702 low-density polyethylene Substances 0.000 claims description 4
- QXLPXWSKPNOQLE-UHFFFAOYSA-N methylpentynol Chemical class CCC(C)(O)C#C QXLPXWSKPNOQLE-UHFFFAOYSA-N 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 4
- UGYRJDSEKCYZKI-UHFFFAOYSA-N 3-pyridin-2-ylpropan-1-amine Chemical class NCCCC1=CC=CC=N1 UGYRJDSEKCYZKI-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 239000001913 cellulose Chemical class 0.000 claims description 3
- 229920002678 cellulose Chemical class 0.000 claims description 3
- 150000004893 oxazines Chemical class 0.000 claims description 3
- 229940083575 sodium dodecyl sulfate Drugs 0.000 claims 1
- 238000012795 verification Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical class CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- LYUQWQRTDLVQGA-UHFFFAOYSA-N 3-phenylpropylamine Chemical class NCCCC1=CC=CC=C1 LYUQWQRTDLVQGA-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
- C08K5/357—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Abstract
The invention relates to an ultraviolet photochromic cosmetic hose which comprises the following raw materials in percentage by weight: 0.5-0.8% of photochromic organic powder, 0.01-1% of dispersant, 0.01-2% of coupling agent, 0.1-5% of antioxidant and the balance of high polymer. The ultraviolet photochromic cosmetic hose provided by the invention is colorless and transparent under common lamplight, and is transparent and colored when placed under sunlight or under ultraviolet irradiation, and is recovered to be colorless and transparent after the sunlight and the ultraviolet are shielded, so that the ultraviolet photochromic cosmetic hose can be used as a verification means for identifying the authenticity of the cosmetic hose, the verification method is simple, and meanwhile, the additional pasting of an anti-counterfeiting mark is avoided, the production cost is low, and the economic benefit is good.
Description
Technical Field
The invention belongs to the technical field of cosmetic hoses, and particularly relates to an ultraviolet photochromic cosmetic hose.
Background
The brand effect is an effect brought by a brand to an enterprise, and the value of the brand effect is continued in a commercial society, but for the anti-counterfeiting maintenance of genuine products of brand products in China at present, an anti-counterfeiting label is basically arranged on a packaging box or a packaging bag for packaging the brand products, such as expensive consumer products such as skin care products, drinks and the like, and the anti-counterfeiting label is arranged on the packaging box or the packaging bag, so that a consumer can verify the authenticity or inquire anti-counterfeiting information in time when purchasing the brand products.
However, there are some packages or bags on which counterfeit products are loaded and which are originally provided with anti-counterfeit labels in the market, so that consumers can falsely or falsely take apart the packages or bags, and find that the purchased products are counterfeit products, and the containers on which the products are loaded do not have related anti-counterfeit marks, or the stickup anti-counterfeit marks are easy to counterfeit, which results in that the consumer has a high difficulty in maintaining the rights of the counterfeit products.
For the anti-counterfeiting mark arranged on the container for loading the product, the anti-counterfeiting ink is printed on the anti-counterfeiting label in the market at present, and then the anti-counterfeiting label is pasted on the surface of the container for loading the product, but the anti-counterfeiting label is easy to fall off or the anti-counterfeiting label is pasted on the surface of the container for counterfeiting the product, and the anti-counterfeiting performance of the container for loading the product is still low.
Disclosure of Invention
The invention aims to provide an ultraviolet photochromic cosmetic hose to solve the technical problem of anti-counterfeiting identification of the cosmetic hose.
The purpose of the invention can be realized by the following technical scheme:
the ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.5-0.8% of photochromic organic powder, 0.01-1% of dispersant, 0.01-2% of coupling agent, 0.1-5% of antioxidant and the balance of high polymer.
Further, the high polymer comprises one or more of high density polyethylene, low density polyethylene, polyethylene terephthalate and polycarbonate which are mixed in any proportion.
Further, the photochromic organic powder comprises one or more of spiropyrans, spirooxazines, bipyridines, aminopropyl pyridines and oxazines which are mixed in any proportion.
Further, the particle size of the photochromic organic powder was 150-200 nm.
Further, the dispersing agent comprises one or more of triethyl hexyl phosphoric acid, sodium dodecyl sulfate, methyl amyl alcohol, cellulose derivatives and polyacrylamide which are mixed in any proportion.
Further, the coupling agent comprises one or more of a silane coupling agent, a titanate coupling agent and an aluminate coupling agent which are mixed in any proportion.
Further, the antioxidant comprises one or more of 2- (2 '-hydroxy-5' -tert-octylphenyl) benzotriazole, 2 '- (2' -hydroxy-3 '-tert-butyl-5' -methylphenyl) -5-chlorobenzotriazole and poly (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate which are mixed in any proportion.
The invention has the beneficial effects that:
the invention provides an ultraviolet photochromic cosmetic hose which comprises the following raw materials in percentage by weight: 0.5-0.8% of photochromic organic powder, 0.01-1% of dispersant, 0.01-2% of coupling agent, 0.1-5% of antioxidant and the balance of high polymer. The ultraviolet photochromic cosmetic hose provided by the invention is colorless and transparent under common lamplight, and is transparent and colored when placed under sunlight or under ultraviolet irradiation, and is recovered to be colorless and transparent after the sunlight and the ultraviolet are shielded, so that the ultraviolet photochromic cosmetic hose can be used as a verification means for identifying the authenticity of the cosmetic hose, the verification method is simple, and meanwhile, the additional pasting of an anti-counterfeiting mark is avoided, the production cost is low, and the economic benefit is good.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.5-0.8% of photochromic organic powder, 0.01-1% of dispersant, 0.01-2% of coupling agent, 0.1-5% of antioxidant and the balance of high polymer.
It will be appreciated that the percentage by weight of photochromic organic powder may take any value within the interval 0.5-0.8%. Specifically, the photochromic organic powder may be 0.5, 0.6, 0.7, or 0.8% by weight. Similarly, the dispersant may be present in an amount of 0.01, 0.05, 0.1, 0.5 or 1% by weight. The weight percentage of coupling agent may be 0.01, 0.05, 0.1, 0.5, 1, 1.5 or 2%. The antioxidant may be present in an amount of 0.1, 1, 2, 3, 4 or 5% by weight.
The photochromic organic powder is added into the raw materials of the cosmetic hose, so that the cosmetic hose is changed from transparent and colorless to colored and transparent under the irradiation of sunlight or ultraviolet light, and can be recovered to be transparent and colorless after the irradiation of the sunlight or the ultraviolet light is shielded, the photochromic organic powder can be used as a means for identifying the authenticity of the cosmetic hose, and the service performance of the cosmetic hose is improved.
Further, the high polymer comprises one or more of high density polyethylene, low density polyethylene, polyethylene terephthalate and polycarbonate mixed in any proportion.
The high polymer adopted by the invention has the excellent characteristics of no color, no odor, no taste, no toxicity and good insulating property, and also has the advantages of good impact resistance, high refractive index, good processability and the like.
Further, the photochromic organic powder comprises one or more of spiropyrans, spirooxazines, bipyridines, aminopropyl pyridines and oxazines which are mixed in any proportion.
After the photochromic organic powder is excited by ultraviolet light, the chemical structure is changed from colorless to colored due to the change of charge transfer, the change of the color is obvious, and the photochromic organic powder has the advantages of high fatigue resistance, high response speed, high sensitivity, low price and the like.
Further, the particle size of the photochromic organic powder was 150-200 nm. It is understood that the particle size of the photochromic organic powder can take any value within the range of 150-200 nm. Specifically, the photochromic organic powder may have a particle size of 150, 160, 170, 180, 190, or 200 nm.
According to the invention, the particle size of the added photochromic organic powder is controlled to be 150-200nm, so that the mixing property of the photochromic organic powder and other materials can be improved, and the smooth surface and no granular feeling of the prepared cosmetic hose are ensured.
Further, the dispersing agent comprises one or more of triethyl hexyl phosphoric acid, sodium dodecyl sulfate, methyl amyl alcohol, cellulose derivatives and polyacrylamide mixed in any proportion.
The invention adopts the dispersing agent to improve the dispersibility of the materials and reduce the agglomeration and sedimentation of the photochromic organic powder, so that the prepared cosmetic hose has certain glossiness and smooth surface.
Further, the coupling agent comprises one or more of silane coupling agent, titanate coupling agent and aluminate coupling agent which are mixed in any proportion.
The coupling agent adopted by the invention can improve the wear resistance and aging resistance of the cosmetic hose.
Further, the antioxidant comprises one or more of 2- (2 '-hydroxy-5' -tert-octylphenyl) benzotriazole, 2 '- (2' -hydroxy-3 '-tert-butyl-5' -methylphenyl) -5-chlorobenzotriazole and poly (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate in any proportion.
The antioxidant adopted by the invention has high-efficiency light stabilization effect, prevents the cosmetic hose from yellowing and aging due to ultraviolet radiation, and maintains the performance of the cosmetic hose in aspects of appearance, mechanics and the like.
Furthermore, the ultraviolet photochromic cosmetic hose can be prepared by adopting an extrusion molding process.
The ultraviolet photochromic cosmetic hose is prepared by adopting an extrusion molding process method, the extrusion molding production process is simple to operate, the quality of the prepared product is ensured, and the manufacturing cost of the finished product is lower.
Example 1
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.5% of spiropyrans, 0.01% of triethylhexylphosphoric acid, 0.01% of a silane coupling agent, 0.1% of 2- (2 '-hydroxy-5' -tert-octylphenyl) benzotriazole and 99.38% of high-density polyethylene.
Example 2
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.6% of spirooxazines, 0.05% of sodium lauryl sulfate, 0.05% of titanate coupling agent, 1% of 2 '- (2' -hydroxy-3 '-tert-butyl-5' -methylphenyl) -5-chlorobenzotriazole and 98.3% of low density polyethylene.
Example 3
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.7% of aminopropyl-benzenes, 0.5% of polyacrylamide, 0.5% of titanate coupling agent, 3% of poly (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate and 95.3% of polycarbonate.
Example 4
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.8% bipyridines, 0.1% methylpentanol, 0.1% titanate coupling agent, 2% poly (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate and 97% polyethylene terephthalate.
Example 5
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.3% bipyridines, 0.2% spiropyrans, 0.3% spirooxazines, 0.1% methylpentanol, 0.1% titanate coupling agent, 1% 2- (2 '-hydroxy-5' -tert-octylphenyl) benzotriazole, 1% 2 '- (2' -hydroxy-3 '-tert-butyl-5' -methylphenyl) -5-chlorobenzotriazole, 1% polysuccinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) ester and 96% polyethylene terephthalate.
Example 6
The ultraviolet photochromic cosmetic hose comprises the following raw materials in percentage by weight: 0.3% bipyridines, 0.2% spiropyrans, 0.3% spirooxazines, 0.1% methylpentanol, 0.1% titanate coupling agent, 1% 2- (2 '-hydroxy-5' -tert-octylphenyl) benzotriazole, 1% 2 '- (2' -hydroxy-3 '-tert-butyl-5' -methylphenyl) -5-chlorobenzotriazole, 1% polysuccinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol), 50% polyethylene terephthalate and 46% polycarbonate.
The invention provides an ultraviolet photochromic cosmetic hose which comprises the following raw materials in percentage by weight: 0.5-0.8% of photochromic organic powder, 0.01-1% of dispersant, 0.01-2% of coupling agent, 0.1-5% of antioxidant and the balance of high polymer. The ultraviolet photochromic cosmetic hose is colorless and transparent under common lamplight, is transparent and colored when placed under sunlight or under ultraviolet irradiation, and is recovered to be colorless and transparent after the sunlight and the ultraviolet light are shielded, so that the ultraviolet photochromic cosmetic hose can be used as a verification means for identifying the authenticity of the cosmetic hose, the verification means is simple, and meanwhile, an anti-counterfeiting mark is prevented from being additionally pasted, the production cost is low, and the economic benefit is good.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only and is not intended to be exhaustive or to limit the invention to the precise embodiments described, and various modifications, additions, and substitutions may be made by those skilled in the art without departing from the scope of the invention or exceeding the scope of the claims.
Claims (7)
1. The ultraviolet photochromic cosmetic hose is characterized by comprising the following raw materials in percentage by weight: 0.5-0.8% of photochromic organic powder, 0.01-1% of dispersant, 0.01-2% of coupling agent, 0.1-5% of antioxidant and the balance of high polymer.
2. The ultraviolet photochromic cosmetic hose of claim 1, wherein the high polymer comprises one or more of high density polyethylene, low density polyethylene, polyethylene terephthalate and polycarbonate mixed at any ratio.
3. The ultraviolet photochromic cosmetic hose of claim 1, wherein the photochromic organic powder comprises one or more of spiropyrans, spirooxazines, bipyridines, aminopropyl pyridines and oxazines mixed in any ratio.
4. The ultraviolet photochromic cosmetic hose of claim 1, wherein the photochromic organic powder has a particle size of 150-200 nm.
5. The uv photochromic cosmetic hose of claim 1, wherein the dispersant comprises one or more selected from the group consisting of triethylhexylphosphoric acid, sodium dodecylsulfate, methylpentanol, cellulose derivatives and polyacrylamide, mixed in any ratio.
6. The ultraviolet photochromic cosmetic hose of claim 1, wherein the coupling agent comprises one or more of a silane coupling agent, a titanate coupling agent and an aluminate coupling agent mixed in any proportion.
7. The uv photochromic cosmetic tube of claim 1, wherein the antioxidant comprises one or more of 2- (2 '-hydroxy-5' -tert-octylphenyl) benzotriazole, 2 '- (2' -hydroxy-3 '-tert-butyl-5' -methylphenyl) -5-chlorobenzotriazole and poly (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate in any proportion.
Priority Applications (1)
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CN202210547609.5A CN114806107A (en) | 2022-05-18 | 2022-05-18 | Ultraviolet photochromic cosmetics hose |
Applications Claiming Priority (1)
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CN202210547609.5A CN114806107A (en) | 2022-05-18 | 2022-05-18 | Ultraviolet photochromic cosmetics hose |
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CN114806107A true CN114806107A (en) | 2022-07-29 |
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CN202210547609.5A Pending CN114806107A (en) | 2022-05-18 | 2022-05-18 | Ultraviolet photochromic cosmetics hose |
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---|---|---|---|---|
CN1044860A (en) * | 1990-03-19 | 1990-08-22 | 北京理工大学 | anti-fake material and preparation method thereof |
CN102329469A (en) * | 2011-08-18 | 2012-01-25 | 上海伟星光学有限公司 | Ultraviolet photochromic plastic product and preparation method thereof |
CN102731913A (en) * | 2012-07-23 | 2012-10-17 | 西南科技大学 | Novel fluorescent plastic and preparation method thereof |
CN104231467A (en) * | 2014-01-03 | 2014-12-24 | 江苏金材科技有限公司 | Anti-counterfeit polyvinyl chloride sheet and preparation method thereof |
CN110128730A (en) * | 2019-05-14 | 2019-08-16 | 安徽银泰塑业有限公司 | A kind of light sensation anti-fake bottle lid and its manufacturing method |
CN110628412A (en) * | 2019-08-30 | 2019-12-31 | 上海迪纺纺织科技有限公司 | Preparation method of color-changing powder |
CN113004884A (en) * | 2021-03-01 | 2021-06-22 | 广东美纳防伪科技有限公司 | Invisible anti-counterfeiting material composition, preparation process and application thereof |
-
2022
- 2022-05-18 CN CN202210547609.5A patent/CN114806107A/en active Pending
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CN102329469A (en) * | 2011-08-18 | 2012-01-25 | 上海伟星光学有限公司 | Ultraviolet photochromic plastic product and preparation method thereof |
CN102731913A (en) * | 2012-07-23 | 2012-10-17 | 西南科技大学 | Novel fluorescent plastic and preparation method thereof |
CN104231467A (en) * | 2014-01-03 | 2014-12-24 | 江苏金材科技有限公司 | Anti-counterfeit polyvinyl chloride sheet and preparation method thereof |
CN110128730A (en) * | 2019-05-14 | 2019-08-16 | 安徽银泰塑业有限公司 | A kind of light sensation anti-fake bottle lid and its manufacturing method |
CN110628412A (en) * | 2019-08-30 | 2019-12-31 | 上海迪纺纺织科技有限公司 | Preparation method of color-changing powder |
CN113004884A (en) * | 2021-03-01 | 2021-06-22 | 广东美纳防伪科技有限公司 | Invisible anti-counterfeiting material composition, preparation process and application thereof |
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Title |
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胡吉永等: "纺织敏感材料与传感器", vol. 1, 中国矿业大学出版社有限责任公司, pages: 156 * |
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