CN114799047A - Multilayer module superposed wax mold structure and method for efficiently preparing single crystal blade by using same - Google Patents

Multilayer module superposed wax mold structure and method for efficiently preparing single crystal blade by using same Download PDF

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CN114799047A
CN114799047A CN202210530518.0A CN202210530518A CN114799047A CN 114799047 A CN114799047 A CN 114799047A CN 202210530518 A CN202210530518 A CN 202210530518A CN 114799047 A CN114799047 A CN 114799047A
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wax
blade
wax mold
mold
layer
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杨文超
郝文硕
撒世鹏
郭敏
苏海军
张军
刘林
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Northwestern Polytechnical University
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Northwestern Polytechnical University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C7/00Patterns; Manufacture thereof so far as not provided for in other classes
    • B22C7/02Lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • B22C9/043Removing the consumable pattern
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/22Moulds for peculiarly-shaped castings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • B22D27/045Directionally solidified castings

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

The invention provides a multi-layer module superposed wax mold structure and a method for efficiently preparing a single crystal blade by using the same, and relates to the technical field of precision casting of aero-engine blades. The multilayer module superposed wax pattern structure provided by the invention comprises a casting system wax pattern, a blade wax pattern, a crystal selector wax pattern and a chilling plate wax pattern which are sequentially connected from top to bottom; the blade wax pattern comprises a plurality of layers of blade wax patterns which are sequentially connected from top to bottom. The invention effectively reduces the diameter of the die set and reduces the size requirements on the chilling plate and the die cavity of the directional solidification furnace under the condition of ensuring the same production capacity of the blades; the reduction of the diameter of the module obviously improves the temperature field distribution in the directional solidification process, improves the uniformity of a transverse temperature field, reduces the bending degree of an isotherm and improves the temperature gradient at the front edge of a solid-liquid interface; the defects of the single crystal blade are obviously reduced, including the reduction of the generation tendency of mixed crystals at the transition section and the platform, and the qualification rate of the mass production of the single crystal blade is effectively improved.

Description

一种多层模组叠加蜡模结构及其高效制备单晶叶片的方法A multi-layer module superimposed wax mold structure and a method for efficiently preparing a single crystal blade

技术领域technical field

本发明涉及航空发动机叶片精密铸造技术领域,具体涉及一种多层模组叠加蜡模结构及其高效制备单晶叶片的方法。The invention relates to the technical field of precision casting of aero-engine blades, in particular to a multi-layer module superimposed wax mold structure and a method for efficiently preparing single crystal blades.

背景技术Background technique

单晶叶片是航空发动机的重要零件,航空发动机用单晶叶片一般采用熔模铸造法制备。首先进行模组的结构设计,压制蜡模并组合,蜡模模组经脱油脂处理后再经涂挂、撒砂、脱蜡、焙烧等步骤制备模壳,最后将熔融合金液浇入固定于高真空度定向凝固炉的模壳中,抽拉铸型至冷却区域,凝固完成后破真空取样。Single crystal blade is an important part of aero-engine, and single-crystal blade for aero-engine is generally prepared by investment casting method. First, the structural design of the module is carried out, the wax mold is pressed and assembled, the wax mold module is degreasing, and then the mold shell is prepared by coating, sanding, dewaxing, and roasting. Finally, the molten alloy liquid is poured and fixed on the In the mold shell of the high-vacuum directional solidification furnace, the mold is pulled to the cooling area, and the vacuum is broken after the solidification is completed.

其中,模组的结构设计作为单晶叶片生产的起始步骤,会直接影响单晶叶片的质量。目前,行业内大批量生产单晶叶片的模组结构普遍为单层模组,即叶片单层排布;在保证单晶叶片生产能力不变的条件下,单层模组的直径大,一方面要求激冷板和定向凝固炉型腔尺寸大,另一方面导致定向凝固过程中横向温度场分布不均匀,等温线发生弯曲,固液界面前沿温度梯度小,易出现过渡段及平台杂晶等凝固缺陷,制约了单晶叶片生产合格率。Among them, the structural design of the module, as the initial step of single crystal blade production, will directly affect the quality of the single crystal blade. At present, the module structure for mass production of single crystal blades in the industry is generally a single-layer module, that is, the blade is arranged in a single layer; under the condition that the production capacity of single crystal blades remains unchanged, the diameter of the single-layer module is large, and a On the one hand, the size of the cavity of the chill plate and the directional solidification furnace is required to be large. On the other hand, the lateral temperature field distribution during the directional solidification process is uneven, the isotherm is bent, the temperature gradient at the front of the solid-liquid interface is small, and the transition section and platform miscellaneous crystals are prone to appear. and other solidification defects, which restrict the production qualification rate of single crystal blades.

中国专利CN107931523A和CN210730902U所公开的蜡模组树均为当前工业上普遍应用的单层模组结构,即叶片围绕模组中心单层排布;当面临大批量单晶叶片生产任务时,该种结构为提高生产能力而增加模组中叶片数量时,势必导致模组直径的增加,进而提高了对激冷板和定向凝固炉型腔尺寸的要求。The wax module trees disclosed in Chinese patents CN107931523A and CN210730902U are single-layer module structures commonly used in the current industry, that is, the blades are arranged in a single layer around the center of the module; when faced with the task of producing large quantities of single crystal blades, this kind of When the structure increases the number of blades in the module to improve the production capacity, it will inevitably lead to an increase in the diameter of the module, which in turn increases the requirements for the size of the chill plate and the cavity of the directional solidification furnace.

Xu等2014年在Metallurgical and Materials Transactions B发表的“Multiscale Modeling and Simulation of Directional Solidification Process ofTurbine Blade Casting with MCA Method”中指出,模组中叶片数量较多时,定向凝固过程中叶片内部的温度场将会倾斜并弯曲。Xu et al. pointed out in "Multiscale Modeling and Simulation of Directional Solidification Process of Turbine Blade Casting with MCA Method" published in Metallurgical and Materials Transactions B in 2014 that when the number of blades in the module is large, the temperature field inside the blade during the directional solidification process will Tilt and bend.

李亚峰的博士学位论文“镍基单晶高温合金涡轮叶片平台杂晶缺陷研究”指出,弯曲的等温线会导致平台边角处优先过冷,达到过冷度后杂晶便形核,杂晶形成倾向随着等温线弯曲程度增大而增大。Li Yafeng's doctoral dissertation "Research on Miscellaneous Crystal Defects in the Platform of Nickel-Based Single Crystal Superalloy Turbine Blades" pointed out that the curved isotherm will lead to preferential supercooling at the corners of the platform, and the miscellaneous crystals will nucleate and form The tendency increases with the degree of curvature of the isotherm.

综上,现有技术大批量制备单晶叶片时普遍使用的是单层模组,此种单层模组的直径较大,一方面要求激冷板和定向凝固炉型腔具有大的尺寸;另一方面造成定向凝固过程中的温度场分布的恶化,包括横向温度场不均匀、等温线弯曲与固液界面前沿温度梯度小,从而导致杂晶形成倾向的增加,严重降低了单晶叶片大批量生产的合格率。To sum up, single-layer modules are commonly used in the mass production of single-crystal blades in the prior art. The diameter of such single-layer modules is relatively large. On the one hand, the chill plate and the cavity of the directional solidification furnace are required to have large dimensions; On the other hand, it causes the deterioration of the temperature field distribution during the directional solidification process, including the uneven temperature field in the transverse direction, the bending of the isotherm and the small temperature gradient at the front of the solid-liquid interface, which leads to the increase of the formation tendency of miscellaneous crystals and seriously reduces the size of the single crystal blade. Qualification rate of mass production.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于提供一种多层模组叠加蜡模结构及其高效制备单晶叶片的方法,采用本发明提供的多层模组叠加蜡模结构,可在保证叶片生产能力不变的条件下,有效缩小模组直径,缩小激冷板和定向凝固炉型腔尺寸,改善定向凝固过程温度场分布,减少凝固缺陷的产生,实现单晶叶片的高效制备。The purpose of the present invention is to provide a multi-layer module superimposed wax mold structure and a method for efficiently preparing a single crystal blade. Using the multi-layer module superimposed wax mold structure provided by the present invention can ensure that the production capacity of the blade remains unchanged. It can effectively reduce the diameter of the module, reduce the size of the chill plate and the cavity of the directional solidification furnace, improve the temperature field distribution during the directional solidification process, reduce the generation of solidification defects, and realize the efficient preparation of single crystal blades.

为了实现上述发明目的,本发明提供以下技术方案:In order to achieve the above-mentioned purpose of the invention, the present invention provides the following technical solutions:

本发明提供了一种用于制备单晶叶片的多层模组叠加蜡模结构,包括自上而下依次连接的浇注系统蜡模、叶片蜡模、选晶器蜡模和激冷板蜡模;The invention provides a multi-layer modular superimposed wax mold structure for preparing a single crystal blade, including a pouring system wax mold, a blade wax mold, a crystal selector wax mold and a chill plate wax mold connected in sequence from top to bottom ;

所述叶片蜡模包括自上而下依次连接的多层叶片蜡模。The blade wax mold includes multiple layers of blade wax molds connected sequentially from top to bottom.

优选地,所述浇注系统蜡模由浇口杯蜡模和绕所述浇口杯蜡模一圈分布的若干斜浇道蜡模构成;所述斜浇道蜡模的底端与顶层叶片蜡模的顶端相连,所述顶层叶片蜡模的底端与下一层叶片蜡模的顶端相连,以此类推,多层叶片蜡模在垂直方向上首尾相连。Preferably, the casting system wax mold is composed of a sprue cup wax mold and a number of sprue wax molds distributed around the sprue cup wax mold; the bottom end of the sprue wax mold is connected to the top blade wax mold The tops of the molds are connected, the bottom end of the top-layer blade wax mold is connected with the top of the next-layer blade wax mold, and so on, the multi-layer blade wax molds are connected end to end in the vertical direction.

优选地,还包括中柱蜡模;所述浇口杯蜡模、中柱蜡模和激冷板蜡模由上到下依次同轴心连接。Preferably, it also includes a center pillar wax mold; the sprue cup wax mold, the center pillar wax mold and the chill plate wax mold are concentrically connected sequentially from top to bottom.

优选地,所述选晶器蜡模包括上部的螺旋段蜡模和下部的引晶段蜡模。Preferably, the separator wax mold includes an upper spiral segment wax mold and a lower seeding segment wax mold.

优选地,所述叶片蜡模的层数为两层。Preferably, the number of layers of the blade wax model is two layers.

本发明提供了一种单晶叶片的制备方法,包括以下步骤:The invention provides a preparation method of a single crystal blade, comprising the following steps:

提供上述技术方案所述的多层模组叠加蜡模结构;Provide the multi-layer module superimposed wax mold structure described in the above technical solution;

将所述多层模组叠加蜡模结构依次进行涂挂、撒砂、脱蜡和焙烧,得到模壳;The multi-layer module superimposed wax mold structure is successively coated, sanded, dewaxed and roasted to obtain a mold shell;

将熔融合金液浇注至所述模壳内,使熔融合金液自下而上定向凝固,脱壳后得到单晶叶片。The molten alloy liquid is poured into the mold shell, so that the molten alloy liquid is directional solidified from bottom to top, and the single crystal blade is obtained after shelling.

优选地,所述浇注和凝固均在定向凝固炉中进行;所述使熔融合金液自下而上定向凝固包括:在凝固过程中,将模壳向下抽拉至冷却区域。Preferably, both the casting and the solidification are performed in a directional solidification furnace; the directional solidification of the molten alloy liquid from bottom to top includes: during the solidification process, the mold shell is drawn downward to a cooling area.

优选地,所述抽拉的速率为50~150μm/s。Preferably, the pulling rate is 50-150 μm/s.

优选地,所述脱蜡为蒸汽法脱蜡。Preferably, the dewaxing is steam dewaxing.

优选地,在所述模壳内浇注熔融合金液前,还包括对所述模壳进行预热。Preferably, before the molten alloy liquid is poured into the mold shell, the mold shell is also preheated.

本发明提供了一种用于制备单晶叶片的多层模组叠加蜡模结构,包括自上而下依次连接的浇注系统蜡模、叶片蜡模、选晶器蜡模和激冷板蜡模;所述叶片蜡模包括自上而下依次连接的多层叶片蜡模。本发明提供的多层模组叠加蜡模结构在保证叶片生产能力相同的条件下,以叶片蜡模上下叠加的方式构建多层模组叠加蜡模结构,以两层模组叠加蜡模结构为例,可以将模组直径降低到单层模组的一半,有效缩小了模组直径,降低了对激冷板和定向凝固炉型腔的尺寸要求;模组直径的缩小明显改善了定向凝固过程中温度场分布,改善了横向温度场均匀性,降低了等温线弯曲程度,提高了固液界面前沿温度梯度;显著减少了单晶叶片缺陷的产生,能够降低过渡段及平台处杂晶产生倾向,有效提高单晶叶片大批生产的合格率。The invention provides a multi-layer modular superimposed wax mold structure for preparing a single crystal blade, including a pouring system wax mold, a blade wax mold, a crystal selector wax mold and a chill plate wax mold connected in sequence from top to bottom ; The blade wax pattern includes multiple layers of blade wax patterns connected in sequence from top to bottom. The multi-layer module superimposed wax mold structure provided by the present invention builds the multi-layer module superimposed wax mold structure in the manner of superimposing the blade wax mold up and down under the condition of ensuring the same blade production capacity, and the two-layer module superimposed wax mold structure is For example, the diameter of the module can be reduced to half of that of a single-layer module, effectively reducing the diameter of the module and reducing the size requirements for the chill plate and the cavity of the directional solidification furnace; the reduction in the diameter of the module significantly improves the directional solidification process. The medium temperature field distribution improves the uniformity of the transverse temperature field, reduces the bending degree of the isotherm, and increases the temperature gradient at the front of the solid-liquid interface; significantly reduces the generation of defects in single crystal blades, and can reduce the tendency of stray crystals at the transition section and platform. , effectively improve the qualification rate of mass production of single crystal blades.

附图说明Description of drawings

图1为实施例1的多层模组叠加蜡模结构示意图;图1中,1为浇注系统蜡模;1-1为浇口杯蜡模;1-2为斜浇道蜡模;2为叶片蜡模;3为选晶器蜡模;3-1为螺旋段蜡模;3-2为引晶段蜡模;4为激冷板蜡模;5为中柱蜡模;Fig. 1 is a schematic diagram of the structure of the multi-layer module superimposed wax mold of Example 1; in Fig. 1, 1 is the wax mold of the pouring system; 1-1 is the sprue cup wax mold; 1-2 is the inclined runner wax mold; 3 is the wax model of the crystal selector; 3-1 is the wax model of the spiral section; 3-2 is the wax model of the seeding section; 4 is the wax model of the chill plate; 5 is the wax model of the central column;

图2为图1的俯视图;Fig. 2 is the top view of Fig. 1;

图3为图1多层模组叠加蜡模结构中双层叠加叶片的细节展示图;FIG. 3 is a detailed display diagram of the double-layer superimposed blade in the multi-layer module superimposed wax mold structure of FIG. 1;

图4为熔融高温合金凝固至叶身处时,单层模组叶片(a)与双层模组叠加叶片下层叶片(b)与上层叶片(c)的温度场模拟结果对比图,标尺上、下限温度分别为合金的液、固相线温度;Figure 4 is a comparison chart of the temperature field simulation results of the single-layer module blade (a) and the double-layer module superimposed blade (b) and the upper blade (c) when the molten superalloy solidifies to the blade body. The lower limit temperature is the liquid and solidus temperature of the alloy, respectively;

图5为熔融高温合金凝固至叶片平台处时,单层模组叶片(a)与双层模组叠加叶片下层叶片(b)与上层叶片(c)的温度场模拟结果对比图,标尺上、下限温度分别为合金的液、固相线温度;Figure 5 is a comparison chart of the temperature field simulation results of the single-layer module blade (a) and the double-layer module superimposed blade (b) and the upper blade (c) when the molten superalloy solidifies to the blade platform. The lower limit temperature is the liquid and solidus temperature of the alloy, respectively;

图6为单层模组叶片(a)和双层模组叠加叶片(b)的凝固晶粒模拟结果对比图。Figure 6 is a comparison diagram of the simulation results of solidification grains of a single-layer module blade (a) and a double-layer module superimposed blade (b).

具体实施方式Detailed ways

本发明提供了一种用于制备单晶叶片的多层模组叠加蜡模结构,包括自上而下依次连接的浇注系统蜡模、叶片蜡模、选晶器蜡模和激冷板蜡模;The invention provides a multi-layer modular superimposed wax mold structure for preparing a single crystal blade, including a pouring system wax mold, a blade wax mold, a crystal selector wax mold and a chill plate wax mold connected in sequence from top to bottom ;

所述叶片蜡模包括自上而下依次连接的多层叶片蜡模。The blade wax mold includes multiple layers of blade wax molds connected sequentially from top to bottom.

本发明提供的多层模组叠加蜡模结构包括浇注系统蜡模和与所述浇注系统蜡模底端相连的叶片蜡模。作为本发明的一个实施例,所述浇注系统蜡模由浇口杯蜡模和绕所述浇口杯蜡模一圈分布的若干斜浇道蜡模构成。作为本发明的一个实施例,所述斜浇道蜡模为沿浇口杯蜡模周向均匀分布的辐射状结构。在本发明中,所述斜浇道的倾斜角度优选为20°~70°。在本发明中,所述斜浇道蜡模为多根。The multi-layer module superimposed wax model structure provided by the present invention includes a casting system wax model and a blade wax model connected to the bottom end of the casting system wax model. As an embodiment of the present invention, the casting system wax mold is composed of a sprue cup wax mold and a plurality of ramped runner wax molds distributed around the sprue cup wax mold. As an embodiment of the present invention, the sprue wax mold is a radial structure uniformly distributed along the circumference of the sprue cup wax mold. In the present invention, the inclined angle of the inclined runner is preferably 20° to 70°. In the present invention, there are multiple sprue wax molds.

作为本发明的一个实施例,所述斜浇道蜡模的底端与顶层叶片蜡模的顶端相连,所述顶层叶片蜡模的底端与下一层叶片蜡模的顶端相连,以此类推,多层叶片蜡模在垂直方向上首尾相连。作为本发明的一个实施例,一根斜浇道蜡模的底端与两个垂直方向上相邻的叶片蜡模相连接,如图3所示。As an embodiment of the present invention, the bottom end of the sprue wax mold is connected to the top of the top blade wax mold, the bottom end of the top blade wax mold is connected to the top of the next layer blade wax mold, and so on , the multi-layer blade wax patterns are connected end to end in the vertical direction. As an embodiment of the present invention, the bottom end of a sprue wax mold is connected to two blade wax molds adjacent in the vertical direction, as shown in FIG. 3 .

在本发明中,所述叶片蜡模的层数优选为两层。In the present invention, the number of layers of the blade wax model is preferably two layers.

本发明提供的多层模组叠加蜡模结构包括与所述叶片蜡模底端相连的选晶器蜡模。作为本发明的一个实施例,所述选晶器蜡模包括上部的螺旋段蜡模和下部的引晶段蜡模。在本发明中,所述螺旋段蜡模和最底层叶片蜡模的底端相连接。The multi-layer module superimposed wax mold structure provided by the present invention includes a crystallizer wax mold connected to the bottom end of the blade wax mold. As an embodiment of the present invention, the crystal separator wax mold includes an upper spiral segment wax mold and a lower seeding segment wax mold. In the present invention, the spiral segment wax model and the bottom end of the bottommost blade wax model are connected.

本发明提供的多层模组叠加蜡模结构包括与所述选晶器蜡模底端相连的激冷板蜡模。The multi-layer module superimposed wax mold structure provided by the present invention includes a chill plate wax mold connected to the bottom end of the crystal selector wax mold.

作为本发明的一个实施例,所述多层模组叠加蜡模结构还包括中柱蜡模;所述浇口杯蜡模、中柱蜡模和激冷板蜡模由上到下依次同轴心连接。As an embodiment of the present invention, the multi-layer module superimposed wax mold structure further includes a center pillar wax mold; the sprue cup wax mold, center pillar wax mold and chill plate wax mold are coaxial from top to bottom in sequence Heart connection.

作为本发明的一个实施例,当所述叶片蜡模的层数为两层时,所述多层模组叠加蜡模结构为:浇注系统蜡模由浇口杯蜡模和绕所述浇口杯蜡模一圈分布的若干斜浇道蜡模构成;所述斜浇道蜡模的底端与上层叶片蜡模的顶端连接,所述上层叶片蜡模的底端与下层叶片蜡模的顶端连接;所述下层叶片蜡模的底端与螺旋段蜡模的顶端连接,所述螺旋段蜡模的底端与引晶段蜡模的顶端相连接;所述引晶段蜡模的底端与激冷板蜡模连接;所述浇注系统蜡模的浇口杯蜡模、中柱蜡模和激冷板蜡模由上到下依次同轴心连接。As an embodiment of the present invention, when the number of layers of the blade wax mold is two, the multi-layer module superimposed wax mold structure is: the wax mold of the gating system is composed of the sprue cup wax mold and the sprue around the gate. The cup wax mold is composed of several oblique runner wax molds distributed in a circle; the bottom end of the oblique runner wax mold is connected with the top end of the upper blade wax mold, and the bottom end of the upper blade wax mold is connected with the top of the lower blade wax mold connection; the bottom end of the lower blade wax mold is connected with the top end of the wax mold of the spiral segment, and the bottom end of the wax mold of the spiral segment is connected with the top end of the wax mold of the seeding segment; the bottom end of the wax mold of the seeding segment is connected; It is connected with the chill plate wax mold; the sprue cup wax mold, the center column wax mold and the chill plate wax mold of the wax mold of the pouring system are connected concentrically from top to bottom in sequence.

本发明还提供了一种单晶叶片的制备方法,包括以下步骤:The present invention also provides a method for preparing a single crystal blade, comprising the following steps:

提供上述技术方案所述的多层模组叠加蜡模结构;Provide the multi-layer module superimposed wax mold structure described in the above technical solution;

将所述多层模组叠加蜡模结构依次进行涂挂、撒砂、脱蜡和焙烧,得到模壳;The multi-layer module superimposed wax mold structure is successively coated, sanded, dewaxed and roasted to obtain a mold shell;

将熔融合金液浇注至所述模壳内,使熔融合金液自下而上定向凝固,脱壳后得到单晶叶片。The molten alloy liquid is poured into the mold shell, so that the molten alloy liquid is directional solidified from bottom to top, and the single crystal blade is obtained after shelling.

本发明提供上述技术方案所述的多层模组叠加蜡模结构。本发明优选采用气动压蜡机压制得到上述技术方案所述的多层模组叠加蜡模结构。在本发明中,所述压制时蜡缸的温度优选为70~75℃,射嘴温度优选为60~65℃,注射压力优选为0.1~0.6MPa。The present invention provides the multi-layer module superimposed wax mold structure described in the above technical solution. In the present invention, a pneumatic wax pressing machine is preferably used to obtain the multi-layer module superimposed wax mold structure described in the above technical solution. In the present invention, the temperature of the wax cylinder during the pressing is preferably 70-75° C., the temperature of the nozzle is preferably 60-65° C., and the injection pressure is preferably 0.1-0.6 MPa.

得到多层模组叠加蜡模结构后,本发明将所述多层模组叠加蜡模结构依次进行涂挂、撒砂、脱蜡和焙烧,得到模壳。在本发明中,所述多层模组叠加蜡模结构在进行涂挂撒砂前优选还包括除油和脱脂处理。本发明采用除油和脱脂处理能够去除模组表面的油脂,提高涂料润湿蜡模表面的能力。After the multi-layer module superimposed wax mold structure is obtained, the present invention sequentially performs coating, sanding, dewaxing and roasting on the multi-layer module superimposed wax mold structure to obtain a mold shell. In the present invention, the multi-layer modular superimposed wax mold structure preferably further includes degreasing and degreasing treatment before coating, hanging, and sanding. The invention adopts degreasing and degreasing treatment, which can remove the grease on the surface of the die and improve the ability of the coating to wet the surface of the wax die.

本发明优选采用浸涂法对所述多层模组叠加蜡模结构进行涂挂。在具体的涂挂过程中,保持多层模组叠加蜡模结构表面均匀的挂上涂料,避免空白和局部堆积;棱角、凹槽、连接处使用毛笔或特制工具刷涂均匀以避免产生气泡。本发明优选在涂挂每层涂料前清理前一层上的浮砂:涂挂过程中定时搅拌以掌握和调整涂料的粘度。在本发明中,所述撒砂优选为流态化撒砂或雨淋式撒砂。本发明优选将所述多层模组叠加蜡模结构从涂料槽中取出后,待其上剩余的涂料流动均匀而不再连续下滴时即可撒砂;所述撒砂的粒度按涂料层次选择,并与涂料的粘度相适应,面层砂粒度较细,加固层砂粒度较粗。在本发明中,每涂挂和撒砂一层之后,进行干燥和硬化。在本发明的具体实施例中,将所述多层模组叠加蜡模结构进行7层涂挂撒砂,第1层为面层,将70#EC95粉、硅溶胶和料浆混合后进行涂挂,自干8h以上;第2~4层,将35#EC95粉、硅溶胶和料浆混合后进行2层涂挂,自干6h以上;第5~6层,将22#EC95粉、硅溶胶和料浆混合后进行涂挂,自干6h以上;第7层为封严层,仅料浆涂挂,涂挂完成后自干;1~3层干燥后,下层涂挂前用硅溶胶强化且要求良好通风,保证适宜的温度(21±1.5℃)与湿度(40±10%)。The present invention preferably adopts the dip coating method to coat and hang the multi-layer module superimposed wax mold structure. In the specific painting and hanging process, keep the surface of the multi-layer module superimposed wax mold structure evenly hung with paint to avoid blank and local accumulation; use a brush or special tools to brush the edges, grooves, and joints evenly to avoid bubbles. In the present invention, it is preferable to clean the floating sand on the previous layer before painting each layer of paint: stirring regularly during the painting and hanging process to master and adjust the viscosity of the paint. In the present invention, the sanding is preferably fluidized sanding or rain-type sanding. In the present invention, after the multi-layer module superimposed wax mold structure is taken out from the paint tank, sand can be sprinkled when the remaining paint on it flows uniformly and no longer drips continuously; the particle size of the sand is according to the paint level. Select and adapt to the viscosity of the paint, the surface layer sand has a finer particle size, and the reinforcement layer has a coarser sand particle size. In the present invention, drying and hardening are carried out after each coating and sanding layer. In a specific embodiment of the present invention, the multi-layer module is superimposed on the wax mold structure for 7-layer coating, hanging and sanding. The first layer is a surface layer, and 70# EC95 powder, silica sol and slurry are mixed and then coated. Hanging, self-drying for more than 8 hours; 2nd to 4th layers, mix 35#EC95 powder, silica sol and slurry, and then carry out 2-layer coating and hanging, self-drying for more than 6h; 5th to 6th layers, mix 22#EC95 powder, silicon After the sol and slurry are mixed, coat and hang, and dry for more than 6 hours; the seventh layer is the sealing layer, only the slurry is coated and hanged, and it will dry after the coating is completed; after 1 to 3 layers are dried, the lower layer is coated with silica sol before hanging. Strengthen and require good ventilation, ensure suitable temperature (21 ± 1.5 ℃) and humidity (40 ± 10%).

在本发明中,所述脱蜡优选为蒸汽法脱蜡。在本发明中,所述蒸汽脱蜡时,外胆蒸汽压力优选为0.7~0.75MPa,脱蜡时间优选为12~14min,脱蜡温度优选为160~170min。本发明优选在所述脱蜡后,进行通风干燥。In the present invention, the dewaxing is preferably steam dewaxing. In the present invention, during the steam dewaxing, the steam pressure of the outer bladder is preferably 0.7-0.75MPa, the dewaxing time is preferably 12-14min, and the dewaxing temperature is preferably 160-170min. In the present invention, it is preferable to perform ventilation drying after the dewaxing.

在本发明中,所述焙烧优选在加热炉中进行;所述焙烧的温度优选为850℃;保温时间优选为1.5h。本发明在所述焙烧后,优选随炉冷却至500℃后取出,空冷至室温,得到模壳。In the present invention, the roasting is preferably carried out in a heating furnace; the roasting temperature is preferably 850° C.; the holding time is preferably 1.5 h. In the present invention, after the calcination, it is preferably taken out after being cooled to 500° C. with the furnace, and cooled to room temperature in the air to obtain a mold shell.

得到模壳后,本发明将熔融合金液浇注至所述模壳内,使熔融合金液自下而上定向凝固,脱壳后得到单晶叶片。本发明在所述模壳内浇注熔融合金液前,优选还包括对所述模壳进行预热。在本发明中,所述预热的温度优选为1530~1560℃。在本发明中,所述浇注的时间优选低于5s;所述浇注的温度优选为1520~1540℃。After the mold shell is obtained, the present invention pours the molten alloy liquid into the mold shell, so that the molten alloy liquid is directional solidified from bottom to top, and the single crystal blade is obtained after shelling. The present invention preferably further includes preheating the mold shell before pouring the molten alloy liquid into the mold shell. In the present invention, the temperature of the preheating is preferably 1530-1560°C. In the present invention, the pouring time is preferably less than 5s; the pouring temperature is preferably 1520-1540°C.

在本发明中,所述浇注和凝固优选均在定向凝固炉中进行;所述使熔融合金液自下而上定向凝固优选包括:在凝固过程中,将模壳向下抽拉至冷却区域。在本发明中,所述抽拉的速率优选为50~150μm/s,更优选为100μm/s。In the present invention, the casting and solidification are preferably performed in a directional solidification furnace; the directional solidification of the molten alloy liquid from bottom to top preferably includes: during the solidification process, the mold shell is drawn downward to a cooling area. In the present invention, the pulling rate is preferably 50-150 μm/s, more preferably 100 μm/s.

在本发明中,所述浇注和凝固优选在真空条件下进行。In the present invention, the casting and solidification are preferably performed under vacuum conditions.

下面将结合本发明中的实施例,对本发明中的技术方案进行清楚、完整地描述。显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. Obviously, the described embodiments are only some, but not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

实施例1Example 1

第一步,蜡模的结构设计与制备:The first step, the structural design and preparation of the wax model:

本实施例采用的双层模组叠加蜡模结构如图1~2所示。The structure of the double-layer module superimposed wax mold used in this embodiment is shown in Figures 1-2.

a.双层模组叠加蜡模结构的设计与蜡模压制:所述双层模组叠加蜡模结构由浇注系统蜡模1、叶片蜡模2、选晶器蜡模3、激冷板蜡模4及中柱蜡模5五个部分组成;所述浇注系统蜡模1由浇口杯蜡模1-1和绕其一圈均匀分布的若干斜浇道蜡模1-2构成,所述选晶器蜡模3由上部的螺旋段蜡模3-1和下部的引晶段蜡模3-2构成;使用气动压蜡机将以上结构的蜡模压制出;蜡模压制时蜡缸温度为75℃,射嘴温度65℃,注射压力0.5MPa,对所压制的蜡模进行去除毛刺修型操作;a. The design of the double-layer module superimposed wax mold structure and the wax mold pressing: the double-layer module superimposed wax mold structure consists of the casting system wax mold 1, blade wax mold 2, crystal selector wax mold 3, and chill plate wax The mold 4 and the central pillar wax mold 5 are composed of five parts; the pouring system wax mold 1 is composed of a sprue cup wax mold 1-1 and a number of inclined sprue wax molds 1-2 evenly distributed around it. The separator wax mold 3 is composed of the upper spiral section wax mold 3-1 and the lower seeding section wax mold 3-2; the wax mold of the above structure is pressed out by a pneumatic wax press; the temperature of the wax tank when the wax mold is pressed At 75℃, the nozzle temperature is 65℃, the injection pressure is 0.5MPa, and the pressed wax mold is deburred and trimmed;

b.双层模组叠加蜡模结构的组合:将上述蜡模按照如下顺序进行组合:斜浇道蜡模1-2底端与上层叶片蜡模顶端连接,上层叶片蜡模底端与下层叶片蜡模顶端连接;下层叶片蜡模底端与选晶器蜡模3顶端连接;选晶器蜡模3底端与激冷板蜡模4连接;浇注系统蜡模的浇口杯蜡模1-2、中柱蜡模5、激冷板蜡模4由上到下依次同轴心连接;b. The combination of the double-layer module superimposed wax mold structure: the above wax molds are combined in the following order: the bottom end of the sprue wax mold 1-2 is connected to the top of the upper blade wax mold, and the bottom end of the upper blade wax mold is connected to the lower blade. The top of the wax mold is connected; the bottom end of the lower blade wax mold is connected to the top of the crystal selector wax mold 3; the bottom end of the crystal selector wax mold 3 is connected to the chill plate wax mold 4; the wax mold of the pouring system wax mold 1- 2. The central pillar wax mold 5 and the chill plate wax mold 4 are connected concentrically from top to bottom in sequence;

c.除油和脱脂:去除双层模组叠加蜡模结构表面的油脂。c. Degreasing and degreasing: remove the grease on the surface of the double-layer module superimposed wax mold structure.

第二步,模壳的制备:The second step, the preparation of the mold shell:

a.涂挂和撒砂:采用浸涂法对脱油脂处理后的双层模组叠加蜡模进行涂挂,保持蜡模表面均匀的挂上涂料,避免空白和局部堆积;棱角、凹槽、连接处使用毛笔或特制工具刷涂均匀以避免气泡;涂挂每层涂料前清理前一层上的浮砂:涂挂过程中定时搅拌以掌握和调整涂料的粘度。撒砂采用雨淋式撒砂;将双层模组叠加蜡模从涂料槽中取出后,待其上剩余的涂料流动均匀而不再连续下滴时进行撒砂;撒砂的粒度按涂料层次选择,并与涂料的粘度相适应,面层砂粒度较细,加固层砂粒度较粗;每涂挂和撒砂一层之后,进行充分干燥和硬化;双层模组叠加模壳进行7层涂挂撒砂,(1)面层,70#EC95粉+硅溶胶+料浆按1:2:2的质量比混合后进行涂挂,自干8h以上;(2)2~4层,35#EC95粉+硅溶胶+料浆按1:2:2的质量比混合后进行2层涂挂,自干6h以上;(3)5~6层,22#EC95粉+硅溶胶+料浆按1:2:2的质量比混合后进行涂挂,自干6h以上;(4)封严层,仅料浆涂挂,涂挂完成后自干;1~3层干燥后,下层涂挂前用硅溶胶强化且要求良好通风,保证适宜的温度(21℃±1.5℃)与湿度(40%±10%);a. Coating and sanding: use dip coating method to coat and hang the degreasing double-layer module superimposed wax mold to keep the surface of the wax mold evenly coated with paint to avoid blank and local accumulation; edges, corners, grooves, Use a brush or special tool to brush the joints evenly to avoid air bubbles; clean the floating sand on the previous layer before painting each layer of paint: stir regularly during the painting process to master and adjust the viscosity of the paint. The sand is sprayed by rain; after the double-layer module superimposed wax mold is taken out of the paint tank, the remaining paint on it flows evenly and no longer drips continuously; the particle size of the sand is according to the paint level. Select and adapt to the viscosity of the paint, the surface layer sand has a finer grain size, and the reinforcement layer has a coarser grain size; after each layer of coating and sanding, it is fully dried and hardened; the double-layer module is superimposed on the mold shell for 7 layers Coating, hanging and sanding, (1) Surface layer, 70#EC95 powder + silica sol + slurry mixed in a mass ratio of 1:2:2, then coated and hanged, and self-drying for more than 8 hours; (2) 2 to 4 layers, 35 #EC95 powder + silica sol + slurry are mixed in a mass ratio of 1:2:2, and then coated in 2 layers, and self-drying for more than 6 hours; (3) 5 to 6 layers, 22#EC95 powder + silica sol + slurry press After mixing in a mass ratio of 1:2:2, coat and hang, and dry for more than 6 hours; (4) Sealing layer, only the slurry is coated and hanged, and it will dry after the coating is completed; After 1 to 3 layers are dried, the lower layer is coated before hanging It is strengthened with silica sol and requires good ventilation to ensure suitable temperature (21℃±1.5℃) and humidity (40%±10%);

b.脱蜡:打开浇口杯端面模壳以便于排蜡排气,采用蒸汽法脱蜡,外胆蒸汽压力0.7MPa,脱蜡时间13min,脱蜡温度165min;脱蜡完成后在通风条件下充分干燥12h;b. Dewaxing: Open the end face mold shell of the sprue cup to facilitate wax removal and exhaust, and use the steam method to dewax. The steam pressure of the outer bladder is 0.7MPa, the dewaxing time is 13min, and the dewaxing temperature is 165min; after the dewaxing is completed, under ventilation conditions Fully dry for 12h;

c.焙烧:双层模组叠加模壳降温至300℃后,放入加热炉中以850℃焙烧1.5h,随炉冷却至500℃后取出,空冷至室温;c. Roasting: After the double-layer module superimposed mold shell is cooled to 300 ℃, it is put into a heating furnace for calcination at 850 ℃ for 1.5 hours, cooled to 500 ℃ with the furnace, taken out, and air-cooled to room temperature;

d.检查与补壳:检查模壳是否存在变形、裂纹、破损等缺陷;修补裂纹、破损等缺陷,去除浇口多余的模壳边沿。d. Inspection and shell repair: Check whether the mold shell has defects such as deformation, cracks, and damage; repair defects such as cracks and damage, and remove the excess mold shell edge of the gate.

第三步,在定向凝固炉中进行叶片的制备:The third step is to prepare the blades in the directional solidification furnace:

a.检查设备:检查设备的各个阀门是否可以正常运作,供水、供电、供气装置是否正常,根据合金料的多少合理调整测温装置和坩埚底部的相对位置,清理炉腔内部粉尘并擦拭各观察窗口;a. Check the equipment: Check whether the various valves of the equipment can operate normally, whether the water supply, power supply, and gas supply devices are normal, adjust the relative position of the temperature measuring device and the bottom of the crucible reasonably according to the amount of alloy material, clean the dust inside the furnace cavity and wipe the various observation window;

b.装母合金:将切割好的合金料打掉较大尺寸的缩孔,经砂纸打磨并用酒精清洗后置入坩埚;b. Loading the master alloy: knock out the large shrinkage cavity of the cut alloy material, grind it with sandpaper and clean it with alcohol, and then put it into the crucible;

c.固定模壳:将双层模组叠加模壳的激冷板模壳用特制卡子或铁丝固定于定向凝固炉的激冷板上,并使模壳浇口中心位置与导液漏斗中心位置同轴,确保合金液顺利浇入模壳,关好炉门;c. Fixed mold shell: Fix the chill plate mold shell of the double-layer module superimposed mold shell on the chill plate of the directional solidification furnace with special clips or iron wires, and make the center position of the mold shell gate and the center of the liquid guide funnel. Coaxial to ensure that the alloy liquid is poured into the mold shell smoothly, and the furnace door is closed;

d.抽真空:先打开机械泵粗抽真空至1000Pa以内,打开罗茨泵继续抽真空至20Pa以内,预热扩散泵,待扩散泵油温升至300℃后,打开扩散泵阀门抽高真空,直至6.67×10- 3Pa;d. Vacuuming: first open the mechanical pump to rough vacuum to less than 1000Pa, open the roots pump to continue vacuuming to less than 20Pa, preheat the diffusion pump, and after the oil temperature of the diffusion pump rises to 300 ℃, open the valve of the diffusion pump to pump high Vacuum up to 6.67×10 - 3 Pa;

e.升温与加热:按照设定温度曲线升温加热体,加热双层模组叠加模壳;e. Heating and heating: heating the heating body according to the set temperature curve, heating the double-layer module superimposed mold shell;

f.合金熔炼:对单晶高温合金进行熔化并精炼:缓慢加电至合金熔化后,对合金熔体进行过热,直至合金液自由表面仅有少量浮渣存在于边缘区域;之后进行摇炉操作,对坩埚边缘进行预热,防止浇注过程中出现喷溅;过热至设定温度后恒温2min;f. Alloy smelting: melting and refining of single crystal superalloy: slowly power on until the alloy is melted, and then superheat the alloy melt until only a small amount of scum exists in the edge area on the free surface of the alloy liquid; then perform the shaking furnace operation , preheat the edge of the crucible to prevent splashing during the pouring process; keep the temperature constant for 2 minutes after overheating to the set temperature;

g.浇注与抽拉:将过热后的熔体迅速降温至略高于浇注温度后,升起测温热电偶,将合金液浇入双层模组叠加模壳后,按照100μm/s的抽拉速率将铸型拉入冷却区域;g. Pouring and pulling: After the superheated melt is rapidly cooled to slightly higher than the pouring temperature, the temperature measuring thermocouple is raised, and the alloy liquid is poured into the double-layer module superimposed mold shell, and the pumping temperature is 100 μm/s. The pull rate pulls the mold into the cooling zone;

h.取样:凝固完成后,待整个炉体温度降温至100℃以下破真空取样,脱壳并进行修整工作,得到大批量单晶叶片。h. Sampling: After the solidification is completed, the temperature of the entire furnace body is cooled to below 100 ℃, and the vacuum sampling is broken, shelled and trimmed to obtain a large number of single crystal blades.

以使用相同工艺大批量制备单晶叶片的单层模组为对比例,图4为熔融高温合金凝固至叶身底部时,单层模组叶片与双层模组叠加叶片的温度场模拟结果对比图。由图4可以看出,双层模组叠加叶片内等温线弯曲程度低,叶身底部边角部位过冷程度小,难以达到合金的临界形核过冷度,单晶叶片杂晶缺陷形成倾向小。Taking the single-layer module for mass production of single-crystal blades using the same process as a comparative example, Figure 4 shows the comparison of the temperature field simulation results of the single-layer module blade and the double-layer module superimposed blade when the molten superalloy solidifies to the bottom of the blade body picture. It can be seen from Figure 4 that the bending degree of the isotherm in the double-layer module superimposed blade is low, and the degree of supercooling at the bottom and corner of the blade body is small, so it is difficult to achieve the critical nucleation and supercooling degree of the alloy, and the formation of heterocrystalline defects in the single crystal blade tends to be Small.

图5为熔融高温合金凝固至叶片平台处时,单层模组叶片与双层模组叠加叶片的温度场模拟结果对比图。由图5可以看出,双层模组叠加叶片等温线弯曲程度低,平台边角处过冷程度小,难以达到合金的临界形核过冷度,单晶叶片杂晶缺陷形成倾向小。Figure 5 is a comparison diagram of the temperature field simulation results of the single-layer module blade and the double-layer module superimposed blade when the molten superalloy solidifies to the blade platform. It can be seen from Figure 5 that the bending degree of isotherm of the double-layer module superimposed blade is low, the degree of supercooling at the corners of the platform is small, and it is difficult to achieve the critical nucleation and supercooling degree of the alloy, and the formation tendency of miscellaneous crystal defects in the single crystal blade is small.

图6为单层模组叶片和双层模组叠加叶片的凝固晶粒模拟结果对比图。由图6可以看出,单层模组叶片中有杂晶形成而难以产出合格单晶叶片,双层模组叠加叶片无杂晶形成,成功制备出单晶叶片。Figure 6 is a comparison diagram of the simulation results of solidification grains of a single-layer module blade and a double-layer module superimposed blade. It can be seen from Figure 6 that there are miscellaneous crystals formed in the single-layer module blade, which makes it difficult to produce qualified single-crystal blades. The double-layer module superimposed blade has no miscellaneous crystal formation, and the single-crystal blade is successfully prepared.

以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above are only the preferred embodiments of the present invention. It should be pointed out that for those skilled in the art, without departing from the principles of the present invention, several improvements and modifications can be made. It should be regarded as the protection scope of the present invention.

Claims (10)

1. A multi-layer module superposed wax mould structure for preparing a single crystal blade comprises a casting system wax mould, a blade wax mould, a crystal selector wax mould and a chilling plate wax mould which are sequentially connected from top to bottom;
the blade wax pattern comprises a plurality of layers of blade wax patterns which are sequentially connected from top to bottom.
2. The multi-layer pattern assembly superimposed wax pattern structure according to claim 1, wherein the gating system wax pattern is composed of a sprue cup wax pattern and a plurality of inclined runner wax patterns distributed around the sprue cup wax pattern in a circle; the bottom of the inclined pouring channel wax mould is connected with the top end of the top layer blade wax mould, the bottom of the top layer blade wax mould is connected with the top end of the next layer of blade wax mould, and the like, and the multiple layers of blade wax moulds are connected end to end in the vertical direction.
3. The multi-layer pattern assembly superimposed wax pattern structure of claim 2, further comprising a king post wax pattern; the sprue cup wax mold, the center column wax mold and the chilling plate wax mold are sequentially connected with the same axle center from top to bottom.
4. The multi-layer pattern assembly superimposed wax pattern structure as claimed in claim 1, wherein the crystal selector wax pattern comprises an upper spiral segment wax pattern and a lower seeding segment wax pattern.
5. The multi-layer pattern assembly superimposed wax pattern structure of claim 1, wherein the number of layers of the blade wax pattern is two.
6. A method for preparing a single crystal blade, comprising the steps of:
providing a multi-layer module superimposed wax pattern structure as defined in any one of claims 1 to 5;
sequentially coating, sanding, dewaxing and roasting the multi-layer module superposed wax mold structure to obtain a mold shell;
and pouring the molten alloy liquid into the mold shell, so that the molten alloy liquid is directionally solidified from bottom to top, and removing the shell to obtain the single crystal blade.
7. The method according to claim 6, wherein the casting and the solidification are both performed in a directional solidification furnace; the step of directionally solidifying the molten alloy from bottom to top comprises the following steps: during solidification, the formwork is drawn down to a cooling zone.
8. The method according to claim 7, wherein the drawing rate is 50 to 150 μm/s.
9. The method of claim 6, wherein the dewaxing is steam dewaxing.
10. The method of claim 6, further comprising preheating the mold shell prior to pouring the molten alloy in the mold shell.
CN202210530518.0A 2022-05-16 2022-05-16 Multilayer module superposed wax mold structure and method for efficiently preparing single crystal blade by using same Pending CN114799047A (en)

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Application publication date: 20220729