CN114774211A - Cleaning powder and using method thereof - Google Patents
Cleaning powder and using method thereof Download PDFInfo
- Publication number
- CN114774211A CN114774211A CN202111618329.0A CN202111618329A CN114774211A CN 114774211 A CN114774211 A CN 114774211A CN 202111618329 A CN202111618329 A CN 202111618329A CN 114774211 A CN114774211 A CN 114774211A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning
- cleaning powder
- benzene sulfonate
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000004140 cleaning Methods 0.000 title claims abstract description 110
- 239000000843 powder Substances 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 11
- 239000002738 chelating agent Substances 0.000 claims abstract description 9
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 32
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 23
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 18
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims description 18
- -1 fatty alcohol sulfate Chemical class 0.000 claims description 17
- 229940077388 benzenesulfonate Drugs 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 10
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 9
- 150000008051 alkyl sulfates Chemical group 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 235000021317 phosphate Nutrition 0.000 claims description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 4
- 239000001630 malic acid Substances 0.000 claims description 4
- 235000011090 malic acid Nutrition 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 4
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 4
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- LGNQGTFARHLQFB-UHFFFAOYSA-N 1-dodecyl-2-phenoxybenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1OC1=CC=CC=C1 LGNQGTFARHLQFB-UHFFFAOYSA-N 0.000 claims description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 229940102253 isopropanolamine Drugs 0.000 claims description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000007785 strong electrolyte Substances 0.000 claims description 3
- 150000003871 sulfonates Chemical class 0.000 claims description 3
- KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 claims description 3
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 abstract description 25
- 239000005304 optical glass Substances 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000002950 deficient Effects 0.000 abstract description 5
- 239000004568 cement Substances 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 51
- 229910052938 sodium sulfate Inorganic materials 0.000 description 17
- 235000011152 sodium sulphate Nutrition 0.000 description 17
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 description 16
- 239000004115 Sodium Silicate Substances 0.000 description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 15
- 229910052911 sodium silicate Inorganic materials 0.000 description 15
- 239000002245 particle Substances 0.000 description 10
- 239000000428 dust Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000693 micelle Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000003670 easy-to-clean Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011775 sodium fluoride Substances 0.000 description 2
- 235000013024 sodium fluoride Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QPXGLRJFCBZQNF-UHFFFAOYSA-N 1-[3-(hydroxymethyl)phenyl]-2-[(2-phenylmethoxyphenyl)methylamino]ethanol Chemical group OCC1=CC=CC(C(O)CNCC=2C(=CC=CC=2)OCC=2C=CC=CC=2)=C1 QPXGLRJFCBZQNF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000246 remedial effect Effects 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0078—Compositions for cleaning contact lenses, spectacles or lenses
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C11D2111/46—
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of optical lens cleaning, and particularly relates to cleaning powder and a using method thereof, wherein the cleaning powder comprises the following components in parts by weight: 15-20 parts of a chelating agent, 25-30 parts of an anionic surfactant, 25-30 parts of an inorganic salt, 10-15 parts of a pH regulator and 3-8 parts of a nonionic surfactant. According to the invention, the adhered optical lens is cleaned by the cleaning powder, so that the dirt at the adhering part can be cleaned, the optical cement cannot be corroded, the surface of the optical glass cannot be corroded, and after the adhering is finished, the defective product which is dirty can be cleaned, the production loss is reduced, and the production benefit is improved.
Description
Technical Field
The invention belongs to the technical field of optical lens cleaning, and particularly relates to cleaning powder and a using method thereof.
Background
GDF camera lenses belong to medium-high optical lenses, the process is relatively complex, the manufacturing cost is high, and GDF lenses have become the mainstream product of optical lenses.
The GDF lens is composed of two main materials, the GDF lens is formed by processing optical glass and an optical PET explosion-proof film through multiple processes and then is pasted and mounted, the pasting and mounting process belongs to a high-difficulty process, the defects such as dirt, scratch, dust, broken filaments and the like can be generated in the pasting and mounting process, particularly, the dirt dust broken filaments are hidden at the interlayer joint between the glass and the PET explosion-proof film and are not easy to clean, a common cleaning agent can corrode optical cement between the optical glass and the explosion-proof film, no remedial measure is provided, defective products can only be scrapped, the GDF lens has high rejection rate, and serious loss is caused.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: aiming at the problem that dirt generated in the mounting process of the existing optical lens is not easy to clean, the cleaning powder and the use method thereof are provided.
In order to solve the technical problem, an embodiment of the present invention provides a cleaning powder, which includes the following components by weight: 15-20 parts of a chelating agent, 25-30 parts of an anionic surfactant, 25-30 parts of an inorganic salt, 10-15 parts of a pH regulator and 3-8 parts of a nonionic surfactant.
Optionally, the cleaning powder further comprises 3-8 parts of a builder.
Optionally, the builder is selected from one or more of silicates, borates, phosphates, carbonates, carboxylates, polyhydroxy sulfonates.
Optionally, the chelating agent is selected from one or more of ethanolamine, triethanolamine oleate soap, diglycolamine, isopropanolamine, malic acid, trisodium phosphate.
Optionally, the anionic surfactant is an alkyl sulfate or a linear alkyl benzene sulfonate.
Optionally, the alkyl sulfate is selected from one or more of sodium dodecyl sulfate, sodium fatty alcohol sulfate, and sodium ethoxylated alkyl sulfate;
the linear alkyl benzene sulfonate is selected from one or more of dodecyl benzene sulfonate, dodecyl diphenyl ether disulfonate, hexadecyl diphenyl ether disulfonate, hexaalkyl diphenyl ether disulfonate, sodium octyl diphenyl ether disulfonate, dinonyl diphenyl ether disulfonate, deca alkyl benzene sulfonate, undecyl alkyl benzene sulfonate, tridecyl benzene sulfonate and tetradecyl alkyl benzene sulfonate.
Optionally, the inorganic salt is a strong electrolyte salt containing Na, F or K.
Optionally, the nonionic surfactant is an alkylolamide type nonionic surfactant.
In another aspect, embodiments of the invention provide a method of using a cleaning powder, comprising the cleaning powder of any one of claims 1-9; mixing 1-5 parts of cleaning powder and 95-99 parts of deionized water in an ultrasonic cleaning tank, wherein the pH value of the mixed solution is 9-10.
Optionally, the method further comprises: and placing the workpiece to be cleaned in an ultrasonic cleaning tank, wherein the ultrasonic vibration frequency is 1.5-2A, the temperature in the cleaning tank is 55-65 ℃, and the ultrasonic cleaning time is 120-170S.
According to the invention, the adhered optical lens is cleaned by the cleaning powder, so that dirt at the adhered part can be cleaned, optical cement cannot be corroded, the surface of optical glass cannot be corroded, and after adhering is finished, defective products which are dirty can be cleaned, so that production loss is reduced, and production benefits are improved.
Detailed Description
In order to make the technical problems, technical solutions and advantageous effects solved by the present invention more apparent, the present invention is further described in detail below with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and do not limit the invention.
The cleaning powder provided by one embodiment of the invention comprises the following components in parts by weight: 15-20 parts of a chelating agent, 25-30 parts of an anionic surfactant, 25-30 parts of an inorganic salt, 10-15 parts of a pH regulator and 3-8 parts of a nonionic surfactant.
According to the invention, before the optical glass and the optical PET explosion-proof film are mounted, the optical PET explosion-proof film is cut into the perspective through hole by laser, after the mounting is finished, impurities such as dirt, dust, broken filaments and the like can be arranged at the joint of the optical glass and the optical PET explosion-proof film and the perspective through hole, wherein the molecules of the chelating agent have strong adsorbability after being ionized into anions in water, the impurities such as dust and the like can have strong adsorbability when the optical lens is cleaned, the inorganic salt is used for increasing electrolyte, and the anionic surfactant and the nonionic surfactant can act synergistically and have strong decontamination capability and cleaning capability.
On the other hand, the nonionic surfactant and the anionic surfactant are mixed to form a mixed micelle, molecules of the nonionic surfactant are inserted between ion molecules of the anionic surfactant, so that the electric repulsion between the original ionic molecular hydrophilic head groups is weakened, namely the charge density of the micelle is reduced, and the micelle has better adsorption capacity on impurities such as dust, broken filaments and the like after being formed.
Through when the cleaning powder agent is cleaned optical lens after being pasted, the dirt of the joint can be cleaned, the optical cement can not be corroded, the surface of the optical glass can not be corroded, after the pasting, the defective products which are dirty can be cleaned, the production loss is reduced, and the production benefit is improved.
In one embodiment, the cleaning powder further comprises 3-8 parts of a builder. The builder is compounded with the nonionic surfactant and the anionic surfactant, so that the detergency of the surfactant can be improved. Moreover, the builder is used as a cleaning assistant, has strong detergency, can form a protective film on the surface of optical glass, and has a good anti-corrosion effect.
In one embodiment, the builder is selected from one or more of silicates, borates, phosphates, carbonates, carboxylates, polyhydroxy sulfonates. Preferably, the builder is silicate, most preferably, the builder is sodium silicate.
In one embodiment, the chelating agent is selected from one or more of ethanolamine, triethanolamine oleate soap, diglycolamine, isopropanolamine, malic acid, trisodium phosphate.
In one embodiment, the anionic surfactant is an alkyl sulphate or linear alkyl benzene sulphonate.
In one embodiment, the alkyl sulfate is selected from one or more of sodium lauryl sulfate, sodium fatty alcohol sulfate, and sodium ethoxylated alkyl sulfate.
The linear alkyl benzene sulfonate is selected from one or more of dodecyl benzene sulfonate, dodecyl diphenyl ether disulfonate, hexadecyl diphenyl ether disulfonate, hexaalkyl diphenyl ether disulfonate, sodium octyl diphenyl ether disulfonate, dinonyl diphenyl ether disulfonate, deca alkyl benzene sulfonate, undecyl alkyl benzene sulfonate, tridecyl benzene sulfonate and tetradecyl alkyl benzene sulfonate.
Preferably, the anionic surfactant is dodecyl benzene sulfonate, and when the anionic surfactant is compounded with the nonionic surfactant, foaming force can be increased, and cleaning capacity is further increased.
In one embodiment, the inorganic salt is a strong electrolyte salt containing Na, F or K. Preferably, the inorganic salt is selected from one or more of sodium sulfate, potassium sulfate, sodium carbonate, potassium carbonate and sodium fluoride, and more preferably, the inorganic salt is sodium sulfate.
In one embodiment, the nonionic surfactant is an alkylolamide nonionic surfactant, and has good foaming, foam stabilizing and dirt removing capabilities, and after the cleaning powder is dissolved in deionized water, the cleaning powder can be well dissolved with alkyl sulfate or linear alkylbenzene sulfonate, so that the surface activity can be improved.
Preferably, the alkylolamide type nonionic surfactant is selected from one or more of alkylolamide polyoxyethylene ether, alkylolamide phosphate, fatty acid alkylolamide, and alkylolamide polyoxyethylene ether.
In another aspect, the present invention provides a method of using a cleaning powder, comprising the use of a cleaning powder as described above; mixing 1-5 parts of cleaning powder and 95-99 parts of deionized water in an ultrasonic cleaning tank, wherein the pH value of a mixed solution is 9-10, the pH regulator of the cleaning powder is used for regulating the pH value of the mixed solution, and the pH regulator is sodium hydroxide or potassium hydroxide.
In one embodiment, a method of using a cleaning powder further comprises: placing a workpiece to be cleaned in an ultrasonic cleaning tank, starting ultrasonic waves, wherein the vibration frequency of the ultrasonic waves is 1.5-2A, the temperature in the cleaning tank is 55-65 ℃, and the ultrasonic cleaning time is 120-170S.
The ultrasonic cleaning principle is as follows:
the ultrasonic wave has high energy, and when the ultrasonic wave is transmitted in the medium liquid, the energy is transmitted to the medium particles, and then the medium particles transmit the energy to the surface of the object to be cleaned, so that dirt is dissociated and dispersed. The acoustic wave is a longitudinal wave, i.e. the vibration direction of the medium particle coincides with the propagation direction of the wave. In the process of longitudinal wave propagation, the movement of medium particles causes uneven particle distribution, areas with different densities and densities appear, sound waves form negative sound pressure in the sparse particle distribution areas, sound waves form positive sound pressure in the dense particle distribution areas, and alternating continuous change of the negative sound pressure and the positive sound pressure is formed, so that the medium particles can obtain certain kinetic energy and certain acceleration. The energetic effect of high-frequency ultrasound is extremely great. When the energetic media particles interact with the soil particles, they transfer energy to the soil and cause their disassociation and dispersion.
According to the invention, the cleaning powder is matched with ultrasonic action to carry out reworking cleaning on the optical lens defective product which generates dirt, the dirt on the optical lens can be cleaned, the dirt is cleaned completely through detection, the optical glass is not corroded, the atomization phenomenon does not occur, the product is qualified after being cleaned, the product can be taken as a good product for shipment, the enterprise productivity is improved, and the loss is reduced.
The following is a description of specific examples:
example 1
A cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate.
1.5Kg of cleaning powder and 98.5Kg of deionized water were mixed, and the ultrasonic waves were turned on, the temperature of the cleaning tank was 55 ℃ and the cleaning time was 150 seconds.
Example 2
The cleaning powder comprises the following components in parts by weight: 16 parts of malic acid, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 3
The cleaning powder comprises the following components in parts by weight: 16 parts of trisodium phosphate, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 4
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of hexaalkyl diphenyl ether disulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 5
A cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of ethoxylated alkyl sodium sulfate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 6
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium fluoride, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 7
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of potassium carbonate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 8
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of fatty acid alkylolamide and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 9
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkylolamide phosphate and 5 parts of sodium silicate. The cleaning method of the cleaning powder is the same.
Example 10
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium borate. The cleaning method of the cleaning powder is the same.
Example 11
The cleaning powder comprises the following components in parts by weight: 16 parts of ethanolamine, 27 parts of dodecyl benzene sulfonate, 25 parts of sodium sulfate, 13 parts of sodium hydroxide, 6 parts of alkanolamide polyoxyethylene ether and 5 parts of sodium carbonate. The cleaning method of the cleaning powder is the same.
Example 12
A cleaning powder comprises the following components in parts by weight: 15 parts of ethanolamine, 26 parts of dodecyl benzene sulfonate, 30 parts of sodium sulfate, 12 parts of sodium hydroxide, 5 parts of alkanolamide polyoxyethylene ether and 8 parts of sodium silicate.
3Kg of cleaning powder and 97Kg of deionized water were mixed, and the ultrasonic waves were started, the temperature of the cleaning tank was 65 ℃ and the cleaning time was 160 s.
Example 13
The cleaning powder comprises the following components in parts by weight: 20 parts of ethanolamine, 25 parts of dodecyl benzene sulfonate, 28 parts of sodium sulfate, 10 parts of sodium hydroxide, 4 parts of alkanolamide polyoxyethylene ether and 6 parts of sodium silicate.
2.5Kg of cleaning powder and 97.5Kg of deionized water were mixed, and the ultrasonic wave was turned on, the temperature of the cleaning tank was 60 ℃ and the cleaning time was 140 s.
Example 14
A cleaning powder comprises the following components in parts by weight: the detergent comprises, by weight, 18 parts of ethanolamine, 29 parts of dodecyl benzene sulfonate, 27 parts of sodium sulfate, 15 parts of sodium hydroxide, 3 parts of alkanolamide polyoxyethylene ether and 4 parts of sodium silicate.
5Kg of cleaning powder and 95Kg of deionized water were mixed, and the ultrasonic waves were started, the temperature of the cleaning tank was 55 ℃ and the cleaning time was 120 s.
Example 15
A cleaning powder comprises the following components in parts by weight: 19 parts of ethanolamine, 28 parts of dodecyl benzene sulfonate, 26 parts of sodium sulfate, 14 parts of sodium hydroxide, 8 parts of alkanolamide polyoxyethylene ether and 3 parts of sodium silicate.
1Kg of cleaning powder and 99Kg of deionized water were mixed, and the ultrasonic waves were started, the temperature of the cleaning tank was 63 ℃ and the cleaning time was 170 s.
Example 16
A cleaning powder comprises the following components in parts by weight: 17 parts of ethanolamine, 30 parts of dodecyl benzene sulfonate, 29 parts of sodium sulfate, 11 parts of sodium hydroxide, 7 parts of alkanolamide polyoxyethylene ether and 7 parts of sodium silicate.
Mixing 4Kg of cleaning powder and 96Kg of deionized water, starting ultrasonic waves, controlling the temperature of a cleaning tank to be 58 ℃ and the cleaning time to be 130 s.
After the soiled optical lenses are cleaned and inspected completely by using the optical lenses of the embodiments 1 to 16, the optical lenses of the embodiments 1 and 12 to 16 have better cleaning effect, and the cleaned optical lenses have no impurities such as dust and broken filaments, do not cause secondary damage to the optical glass, generate chemical corrosion, and do not generate fogging phenomenon.
It was found in the full examination of the optical lenses that the optical lenses cleaned with the cleaning powders of examples 2 to 11 had no impurities such as dust and fuzz, and no chemical corrosion caused by secondary damage to the optical glass, and no fogging phenomenon occurred, but it was found from examples 2 to 11 that the cleaning power of the cleaning powders was slightly changed when the chelating agent, the anionic surfactant, the inorganic salt, the pH adjuster, and the nonionic surfactant were replaced, and it was found that the cleaning powders of examples 1, 12 to 16 were the most preferable examples, and the cleaning power of the cleaning powders of examples 2 to 11 was slightly weaker than that of examples 1, 12 to 16, and the cleaning power of the cleaning powders of examples 1, 12 to 16 was high in cleaning speed, efficiency, and cleaning power.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (10)
1. The cleaning powder is characterized by comprising the following components in parts by weight: 15-20 parts of a chelating agent, 25-30 parts of an anionic surfactant, 25-30 parts of an inorganic salt, 10-15 parts of a pH regulator and 3-8 parts of a nonionic surfactant.
2. The cleaning powder of claim 1, further comprising 3 to 8 parts of a builder.
3. The cleaning powder of claim 2, wherein the builder is selected from one or more of silicates, borates, phosphates, carbonates, carboxylates, and polyhydroxy sulfonates.
4. The cleaning powder of claim 1, wherein the chelating agent is selected from one or more of ethanolamine, triethanolamine oleate soap, diglycolamine, isopropanolamine, malic acid, trisodium phosphate.
5. The cleaning powder of claim 1, wherein the anionic surfactant is an alkyl sulfate or a linear alkyl benzene sulfonate.
6. The cleaning powder of claim 5, wherein the alkyl sulfate is selected from one or more of sodium lauryl sulfate, sodium fatty alcohol sulfate, and sodium ethoxylated alkyl sulfate;
the linear alkyl benzene sulfonate is selected from one or more of dodecyl benzene sulfonate, dodecyl diphenyl ether disulfonate, hexadecyl diphenyl ether disulfonate, hexaalkyl diphenyl ether disulfonate, sodium octyl diphenyl ether disulfonate, dinonyl diphenyl ether disulfonate, deca alkyl benzene sulfonate, undecyl alkyl benzene sulfonate, tridecyl benzene sulfonate and tetradecyl alkyl benzene sulfonate.
7. The cleaning powder of claim 1, wherein the inorganic salt is a strong electrolyte salt containing Na, F or K.
8. The cleaning powder of claim 1, wherein the nonionic surfactant is an alkylolamide type nonionic surfactant.
9. A method of using a cleaning powder comprising the cleaning powder of any one of claims 1-9; mixing 1-5 parts of cleaning powder and 95-99 parts of deionized water in an ultrasonic cleaning tank, wherein the pH value of the mixed solution is 9-10.
10. The method of using a cleaning powder of claim 9, further comprising: and (3) placing the workpiece to be cleaned in an ultrasonic cleaning tank, wherein the ultrasonic vibration frequency is 1.5-2A, the temperature in the cleaning tank is 55-65 ℃, and the ultrasonic cleaning time is 120-170S.
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| CN105062706A (en) * | 2015-08-14 | 2015-11-18 | 上海奈拓化工科技有限公司 | High-precision ultrasonic cleaning agent for glass mould used in resin optical lens mold closing |
| CN106753873A (en) * | 2017-01-13 | 2017-05-31 | 蓝思科技（长沙）有限公司 | A kind of glass cleaner and its application method |
| CN111471536A (en) * | 2020-05-13 | 2020-07-31 | 深圳市众望丽华实业有限公司 | Water-based cleaning agent used after optical glass screen printing and application thereof |
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2021
- 2021-12-27 CN CN202111618329.0A patent/CN114774211A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105062706A (en) * | 2015-08-14 | 2015-11-18 | 上海奈拓化工科技有限公司 | High-precision ultrasonic cleaning agent for glass mould used in resin optical lens mold closing |
| CN106753873A (en) * | 2017-01-13 | 2017-05-31 | 蓝思科技（长沙）有限公司 | A kind of glass cleaner and its application method |
| CN111471536A (en) * | 2020-05-13 | 2020-07-31 | 深圳市众望丽华实业有限公司 | Water-based cleaning agent used after optical glass screen printing and application thereof |
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