CN114773918B - Colored anti-freezing coating - Google Patents
Colored anti-freezing coating Download PDFInfo
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- CN114773918B CN114773918B CN202210370467.XA CN202210370467A CN114773918B CN 114773918 B CN114773918 B CN 114773918B CN 202210370467 A CN202210370467 A CN 202210370467A CN 114773918 B CN114773918 B CN 114773918B
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- Prior art keywords
- slow
- component
- agent
- slow release
- release shell
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- 238000000576 coating method Methods 0.000 title claims abstract description 47
- 239000011248 coating agent Substances 0.000 title claims abstract description 44
- 238000007710 freezing Methods 0.000 title claims abstract description 38
- 150000003839 salts Chemical class 0.000 claims abstract description 38
- 239000002131 composite material Substances 0.000 claims abstract description 31
- 230000008014 freezing Effects 0.000 claims abstract description 22
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims abstract description 5
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 3
- 238000003892 spreading Methods 0.000 claims description 64
- 230000007480 spreading Effects 0.000 claims description 64
- 239000000463 material Substances 0.000 claims description 33
- 238000003825 pressing Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 17
- 238000003860 storage Methods 0.000 claims description 17
- 238000005303 weighing Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910001000 nickel titanium Inorganic materials 0.000 claims description 9
- 238000012546 transfer Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 claims description 8
- 239000010426 asphalt Substances 0.000 claims description 8
- 230000007246 mechanism Effects 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 229910001285 shape-memory alloy Inorganic materials 0.000 claims description 8
- 238000002791 soaking Methods 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 239000004945 silicone rubber Substances 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 230000000881 depressing effect Effects 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 108010053481 Antifreeze Proteins Proteins 0.000 claims 1
- 230000002528 anti-freeze Effects 0.000 claims 1
- 238000009499 grossing Methods 0.000 claims 1
- HLXZNVUGXRDIFK-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni] HLXZNVUGXRDIFK-UHFFFAOYSA-N 0.000 claims 1
- 238000005728 strengthening Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 239000010410 layer Substances 0.000 description 18
- 238000007599 discharging Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 238000007789 sealing Methods 0.000 description 9
- 239000011521 glass Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 238000004821 distillation Methods 0.000 description 5
- 238000007790 scraping Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- -1 compound salt Chemical class 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 239000010420 shell particle Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
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- 238000003703 image analysis method Methods 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 239000003973 paint Substances 0.000 description 1
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- 238000005057 refrigeration Methods 0.000 description 1
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- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D121/00—Coating compositions based on unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2293—Oxides; Hydroxides of metals of nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Road Paving Structures (AREA)
- Paints Or Removers (AREA)
- Road Repair (AREA)
Abstract
The invention discloses a colorful anti-freezing coating, which comprises a freezing point depression component, a hydrophobic component, an adhesive component and a pigment component; the freezing point depression component comprises a composite salt, and the hydrophobic component comprises an organic silicon rubber emulsion, a reinforcing agent, a filler, a film forming auxiliary agent, a catalyst, a plasticizer, a flatting agent mixed solution and a defoaming agent; the coating of this application has hydrophobic performance, can effectively improve the CA angle, still contains freezing point simultaneously and reduces the component and let ice melt more easily, and the cooperation has the effect of less ice adhesion simultaneously, lets the ice sheet peel off more easily, still contains the slow-release shell in addition and can effectively improve life, extension service life.
Description
Technical Field
The invention relates to the technical field of new materials, in particular to a colorful anti-freezing coating.
Background
The ice on the road surface in winter always troubles the traffic safety, which is prominent in northern cities, and the current way of deicing the road surface is to delay the ice on the road surface by stripping the road surface by a mechanical method or reducing the ice point by a chemical method, but the conventional mechanical deicing method not only needs special equipment, but also has great damage to the road surface, has higher requirements on the road surface, and has poorer use effect on certain fluctuant and turning parts;
the chemical method is generally a practical anti-freezing agent for reducing the freezing point at present, but the chemical method also has the problems of large dosage, corrosiveness to the road surface and the like.
The integral freezing point is reduced by only depending on chemical preparations, obviously, the dosage of the anti-freezing agent can be obviously improved, and if the hydrophobic function of the surface of the pavement is increased, when an ice layer in contact with the surface of the pavement is melted by the action of the anti-freezing agent, the ice layer can be easily peeled off together with the ice layer; in addition, in order to prolong the service life of the anti-icing agent, the anti-icing effect of the road has long-term performance. The application provides a colored anti-freezing coating.
Disclosure of Invention
In view of the above problems in the prior art, the present invention provides a colored anti-icing coating to solve the above problems in the background art.
The invention provides a colored anti-freezing coating, which comprises a freezing point depression component, a hydrophobic component, an adhesive component and a pigment component;
wherein,
the freezing point depressing component comprises
A complex salt;
the hydrophobic component comprises
Organosilicon rubber emulsion,
Reinforcing agent, filler for reinforcing agent to improve strength of rubber product,
A filler,
Film-forming assistant,
A catalyst,
A plasticizer,
A flatting agent mixed liquid,
Defoaming agent;
the adhesive component comprises
Emulsified asphalt,
Rubber powder,
Epoxy resin,
A silicone rubber cross-linking agent,
A silane coupling agent,
the hydrophobic component is prepared by the following process:
a1, adding a reinforcing agent, a filler and a film forming auxiliary agent into diluent water, and stirring and dispersing;
a2, adding organic silicon rubber emulsion, a catalyst, a plasticizer, a flatting agent mixed solution and a defoaming agent;
and a3, continuously stirring to obtain the hydrophobic component of the product.
Preferably, the pigment component is pigment particles which are sieved by a 300-mesh sieve, and the slow-release compound salt is one or two of sodium chloride and calcium chloride or magnesium chloride.
Preferably, the reinforcing agent is one or more of precipitated calcium carbonate, white carbon black and magnesium carbonate;
the filler is one or more of titanium dioxide, zinc oxide powder and barium sulfate;
the film-forming additive is one or more of 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, cellulose and glycol;
the catalyst is dibutyltin dilaurate;
the plasticizer is DOP, so that the solidification speed is slowed down in the coating, and cracking is prevented;
the flatting agent mixed liquid is a mixed liquid of flatting agent TH-720, ethylene glycol or glycerol and water;
the defoaming agent is methyl silicone oil.
Preferably, the silicone rubber cross-linking agent is methyl tributyl ketoxime silane, the silane coupling agent is KH-550, and the solid content of the silicone rubber emulsion is 25-30%;
preferably, the freezing point depression component further comprises a slow release shell, and the slow release shell is a hollow nickel titanium memory alloy ball with gaps.
Preferably, the composite salt is positioned inside the hollow nickel-titanium memory alloy ball, the slow release shell is subjected to deformation treatment through the matching of the material spreading part and the material pressing part, the storage part is used for filling the composite salt, a weighing mechanism is used for testing the filling degree of the composite salt in the hollow nickel-titanium memory alloy ball,
and the processing technology of the slow release shell loaded composite salt comprises the following steps:
b1, placing the slow release shell in a storage bin;
b2, starting a second motor at the bottom in the storage bin, and quantitatively transferring the slow-release shells in the storage bin to a material spreading disc;
b3, starting a second motor to transfer the slow release shell to a material spreading disc, and flattening the slow release shell through a material spreading arm;
b4, extruding the slow release shell by driving the pressing plate to move downwards so as to deform the slow release shell;
b5, starting a third motor to drive the spreading arm to rotate, and transferring the slow release shell from the spreading disc to the containing barrel;
b6, immersing the holding barrel into an immersion barrel containing the compound salt;
b7, starting a fifth motor to drive a stirring paddle to stir;
b8, the holding barrel is moved out of the soaking barrel, the air pressure of the area is reduced through an air pump, and the dispersion liquid is completely evaporated;
and B9, weighing the slow release shells in the holding barrel, repeating B6-B8 if the slow release shells do not reach the standard, and transferring the slow release shells to a transfer barrel if the slow release shells reach the standard.
Preferably, the processing technology of the slow release shell loaded with the composite salt is integrally carried out on the frame and transferred through the moving part.
The beneficial effects of the invention are: the utility model provides have in the coating and restrain freezing effect freezing point and reduce the component, the coating rolls under the effect at capillary action and vehicle, and inside salinity is separated out gradually to reduce the freezing point of road surface water, delay road surface area snow and freeze. Meanwhile, the composite salt substance can melt ice at a lower temperature so as to be convenient for removing, when the freezing point of a solution formed by the deicing salt and the ice is lower than the air temperature, ice water can flow away, and residual liquid on the road surface cannot be frozen; meanwhile, the coating also contains a hydrophobic component of the organic silicon rubber emulsion, wherein the organic silicon rubber emulsion has air-permeable water-sealing property and self-cleaning property, can automatically remove dust covered on the surface, recovers the inhibition effect of the self-melting ice modifier on the freezing point, actively maintains the deicing function, and can effectively increase the CA angle by adding the organic silicon rubber emulsion into the coating to obtain a hydrophobic effect, so that the ice layer is easier to strip; in addition, the application also comprises a processing method of the slow-release shell, and a slow-release shell structure can be provided for the composite salt, so that the long-term anti-freezing effect is achieved.
Drawings
FIG. 1 is a graph comparing the static contact angle of coatings of the present invention;
FIG. 2 is a comparative graph of wettability tests of coatings of the present invention;
FIG. 3 is a graph comparing ice layers before and after shearing of a coating of the present invention;
FIG. 4 is a schematic diagram of the equipment configuration for the composite salt charging process of the present invention;
FIG. 5 is a front perspective view of FIG. 4 of the present invention;
FIG. 6 is a schematic view of the state of the freeze point depressant weighing of the present invention;
FIG. 7 is a schematic view showing the state of transition of the freezing point depressing component of the present invention;
FIG. 8 is an exploded view of the moving part of the present invention;
fig. 9 is a sectional view at the sliding plate of the present invention;
FIG. 10 is a sectional view of the electronic scale according to the present invention in a weighing state;
FIG. 11 is a cross-sectional view of the enclosure, holding tank, electronic scale and closure plate of the present invention;
fig. 12 is a schematic view of the inner structure of the tub of the present invention;
FIG. 13 is an exploded view of the electronic scale portion of the present invention;
FIG. 14 is a schematic cross-sectional view of a magazine portion of the present invention;
FIG. 15 is a schematic view of a portion of the construction of the paver and the swage of the present invention;
FIG. 16 is a cross-sectional view of a paver arm of the present invention;
FIG. 17 is a schematic structural view of a paver of the present invention;
FIG. 18 is a cross-sectional view at the shoveling plate of the present invention;
fig. 19 is a schematic sectional view of the discharge hopper of the present invention.
In the figure: 1. the device comprises a transfer barrel, 2, a frame, 3, a soaking barrel, 4, a moving member, 401, a sliding plate, 402, a screw, 403, a first motor, 404, a closed barrel, 5, a spreading member, 501, a spreading disc, 502, a support, 503, a storage bin, 504, a second motor, 505, a first worm, 506, a third motor, 507, a spreading arm, 508, a discharging groove, 509, a discharging pipe, 5010, a shoveling plate, 5011, a scraping plate, 6, a pressing member, 601, a pressing plate, 602, a guide rod, 603, a toothed plate, 604, a fourth motor, 7, a storage member, 701, a containing barrel, 702, a first electric push rod, a sealing surface, 704, a discharging port, 705, a shell, 706, a spring, 707, a sliding rod, a sealing rod, 708, a fifth motor, 8, an inspection mechanism, 801, 901, 802, a closing plate, 803, a sleeve, 804, a second electric push rod, 805, an air pump, 9, a discharging hopper, a feeding port, a feeding rod, a feeding hole, 709, 902 and a discharging rod.
Detailed Description
The present invention will be further described with reference to specific examples, but it should be understood that the examples described are only a few examples of the present invention, and not all examples. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The preparation process of the colored anti-freezing ice coating comprises the following steps of mixing the components in parts by weight.
One) preparation of hydrophobic component
Firstly, taking 4 parts of reinforcing agent (carbon black), 3 parts of filler (titanium dioxide, zinc oxide powder and barium sulfate are 1;
secondly, adding 100 parts of organic silicon rubber emulsion, 1.7 parts of dibutyltin dilaurate serving as a catalyst, 4.2 parts of DOP,3 parts of a flatting agent mixed solution and 03 parts of defoaming agent methyl silicone oil into the mixed solution, and stirring at the rotating speed of 300rpm for 20min to prepare a hydrophobic component;
II) preparation of the adhesive component
1 part of silicon rubber cross-linking agent, 1.5 parts of silane coupling agent, 20 parts of emulsified asphalt, 40 parts of rubber powder and 40 parts of epoxy resin are mixed and stirred uniformly to obtain the adhesive component.
Thirdly) preparation of the freezing point depressing component
And 3 parts of sodium chloride and 6 parts of calcium chloride are mixed to obtain the freezing point depression component.
Four) preparation of the coating
And mixing and stirring 15 parts of adhesive component, 8 parts of hydrophobic component and 2 parts of freezing point depression component with 3 parts of pigment component at normal temperature until a uniform colorful anti-freezing ice coating is obtained.
The coating of the application can be applied at 0.4-0.6 kg/m by using relevant spraying equipment or manually 2 The amount of the concrete is used for construction.
To verify the effect, an anti-icing coating was applied at 0.3kg/m 2 Uniformly coating the glass slide with the coating solution, washing the surface of the glass slide with clear water, and measuring a contact angle of the glass slide by using a contact angle detector after the glass slide is dried.
According to the testing procedure of drop image analysis method, a photograph is taken of the surface of a glass slide which is not coated with an organic hydrophobic coating and the surface of a glass slide which is coated with an organic hydrophobic coating, and the static contact angle is compared, as shown in figure 1, the left side is a drop on a common glass slide (control group), and the right side is a drop on a glass slide (coating group) coated with the coating of the application
From the image data and measured by the contact angle measuring instrument, the contact angle of the droplet on the coated slide was 95 °, while the contact angle of the droplet on the clean slide was 32 °. The data comparison can show that the coating has good hydrophobic performance and can obviously reduce the adhesive force between the ice layer and the pavement.
And the wettability test is also carried out, the effect is shown in fig. 2, wherein the left side is a common road surface, the right side is a road surface sprayed with a coating, and the photographed picture shows that when water drops are dripped on a coating test piece sprayed with the paint, the water drops have obvious shrinkage gathering phenomenon, and on the test piece not sprayed with the coating, the water drops have no obvious shrinkage gathering phenomenon and are continuously diffused. Before the common asphalt pavement is frozen, ice water permeates into the asphalt pavement, ice whiskers are formed in pores of an asphalt pavement structure and are tightly nailed to the pavement, and an ice layer is uniformly and continuously covered on the whole pavement; and the hydrophobic road surface that the spraying has the coating of this application can have obvious shrink gathering phenomenon because the water droplet, and the ice sheet that forms is discontinuous state and distributes in local area.
Adhesion test between ice layer and anti-freezing coating pavement
The adhesion force mainly refers to the adhesion force between the ice layer and the road surface after the surface of the road panel is frozen. And (3) representing the adhesive capacity between the ice layer and the coating asphalt mixture test piece by adopting a shear test. Obviously, lower shear indicates low adhesion between the ice layer and the pavement slab, which is beneficial for the tire to crush the ice layer, making it easier to remove.
The prepared anti-freezing ice coating is coated according to the weight of 0.3kg/m 2 Uniformly spreading on a test piece prepared in advance, after drying and curing, freezing at-15 ℃, and carrying out a shearing test, wherein the conditions of an ice layer before and after shearing are shown in figure 3, and the results of measuring the adhesion between the ice layer and the road surface are shown in table 1.
TABLE 1 results of the effect of the coating on the adhesion between the ice layer and the pavement
From the above test results, the adhesion decreases 31.45% for the coated and uncoated coatings. The coating obviously reduces the adhesion force of the ice layer and the asphalt pavement, and the low adhesion force is beneficial to crushing the ice layer by the tire, so that the ice layer is easier to peel and clean.
Furthermore, in order to prolong the service life and prolong the service life of the freezing point depression component, the freezing point depression component also comprises a slow release shell, the slow release shell is a hollow nickel titanium memory alloy ball with gaps, the salt is positioned inside the hollow nickel titanium memory alloy ball, wherein the slow release shell is purchased from certain Xin nonferrous metal production enterprises in Shanghai, a hollow ball with a closed opening and a 4mm size of TiNi-03, the phase transition temperature of the hollow ball is less than 5 ℃, in spring, summer and autumn, the environment temperature enables the hollow ball to keep a memory shape, and materials such as anticoagulant salt and the like in the hollow ball are not easy to seep out, so that the service cycle is prolonged, and the wear resistance of the coating can be improved by adding the metal material;
in a low-temperature environment, the slow-release shell is continuously extruded by vehicles running on a road, so that deformation is formed and is kept for a period of time, the internal composite salt is easy to seep out and rises to the surface of the road, and the ice point is lowered to play a role in melting ice and snow.
The process of loading the composite salt to the slow-release shell is performed on the frame 2, and in order to form a good composite salt loading effect and prevent the slow-release shell from being deformed again during processing, the whole frame 2 can be operated in a closed low-temperature space (similar to a cold storage, not shown in the figure).
Specifically, an immersion barrel 3 containing a dispersion liquid (for example, DMF or THF can be used) is arranged at one end below the frame 2, fine-particle composite salt (the weight ratio of the composite salt is generally not more than 35%) can be added into the dispersion liquid, the slow-release shell is immersed in the immersion barrel 3, the dispersion liquid is promoted to carry the composite salt into the slow-release shell by a dispersion mode such as stirring, a weighing mechanism 8 for distilling the slow-release shell at a low temperature and measuring the weight of the slow-release shell after low-temperature distillation is arranged in the middle of the frame 2, the dispersion liquid in the slow-release shell is distilled out after low-temperature distillation, and only the composite salt is retained in the slow-release shell.
In order to carry out the automatic loading process of the compound salt, the moving member 4, the spreading member 5, the pressing member 6 and the storage member 7 are required to work cooperatively;
specifically, the moving member 4 includes a sliding plate 401, the sliding plate 401 is slidably connected to the frame 2, a closed tub 404 with a downward opening is fixedly installed on the upper side of the sliding plate 401, two sides of the frame 2 are symmetrically and rotatably connected with two screws 402 through a first motor 403, two sides of the sliding plate 401 are respectively engaged and sleeved on the two screws 402, the first motor 403 is fixedly installed on the side wall of the frame 2, and an output shaft of the first motor 403 is fixedly connected with an end of the screw 402, so that when the first motor 403 is started, the first motor 403 drives the screws 402 to rotate, and since two sides of the sliding plate 401 are respectively engaged and sleeved on the two screws 402, the sliding plate 401 slides on the frame 2 after the screws 402 rotate;
the material spreading part 5 comprises a material spreading disc 501, a material discharging groove 508 with an inclined bottom wall is formed in the side wall of the material spreading disc 501 to avoid residual accumulation, a material discharging pipe 509 is arranged at the bottom end of the material discharging groove 508, the material spreading disc 501 is fixedly installed at the upper end of the closed barrel 404, a support 502 is fixedly connected to the material spreading disc 501, a bin 503 for containing a slow-release shell is fixedly installed on the support 502, a first worm 505 for quantitatively discharging the slow-release shell is rotatably connected to a material discharging opening below the bin 503 through a second motor 504, the second motor 504 is fixedly installed on the side wall of the bin 503, an output shaft of the second motor 504 is fixedly connected with the end part of the first worm 505, after the second motor 504 is started, an output shaft of the second motor 504 drives the first worm 505 to rotate, at the moment, the first worm 505 can pull out the slow-release shell inside the bin 503, and the discharge amount of the slow-release shell is limited through the number of rotation of the first worm 505, the spreading plate 501 is rotatably connected with a spreading arm 507 through a third motor 506, the third motor 506 is fixedly installed on the side wall of the spreading arm 507, an output shaft of the third motor 506 is meshed with a rotating shaft of the spreading arm 507 through a gear, so that when the third motor 506 is started, the output shaft of the third motor 506 can drive the spreading arm 507 to rotate, the rotating shaft of the spreading arm 507 is arranged at the central position of the spreading plate 501, when the spreading arm 507 rotates for a circle, the lower side of the spreading arm 507 sweeps the upper side surface of the whole spreading plate 501, the inner cavity of the spreading arm 507 is communicated with a discharge port of the storage bin 503, shoveling plates 5010 used for shoveling slow release shells on the spreading plate 501 and scraping plates 5011 used for flatly paving slow release shells inside the spreading arm 507 on the spreading plate 501 are fixedly installed on two sides of the spreading arm 507, the arrow direction is the rotating direction of the spreading arm 507, the lower side of the shoveling plate 5010 is attached to the upper side of the spreading plate 501, the lower side of the scraping plate 5011 is spaced from the spreading plate 501 by a certain distance, the distance is larger than the diameter of one slow release shell and smaller than the sum of the diameters of two slow release shells, so that the slow release shells can be flatly spread on the spreading plate 501 in a single layer, after the third motor 506 is started to drive the spreading arm 507 to rotate, the shoveling plate 5010 shovels the slow release shells in front of the spreading arm 507 away, then the slow release shells in the spreading arm 507 fall on the spreading plate 501 again, and the slow release shells are flatly spread in a single layer through the scraping plate 5011;
when the second motor 504 is started, after the second motor 504 drives the first worm 505 to rotate, the slow release shells in the storage bin 503 are discharged to the interior of the material spreading arm 507, and the second motor 504 is started, the material spreading arm 507 is positioned at one side of the material discharging groove 508, the quantity discharged into the inner cavity of the material spreading arm 507 can be the quantity only capable of spreading the upper side surface of the material spreading disc 501, then the third motor 506 is started to drive the material spreading arm 507 to rotate, in the rotating process, the slow release shells in the middle of the material spreading arm 507 are spread on the upper side surface of the material spreading disc 501 and are scraped by the scraping plate 5011, and therefore the slow release shells can be fully spread on the material spreading disc 501;
the material pressing part 6 comprises two pressing plates 601 symmetrically arranged above the material spreading disc 501, the sum of the areas of the lower side surfaces of the two pressing plates 601 is equal to the area of the upper side surface of the material spreading disc 501, guide rods 602 are fixedly connected to the upper side walls of the two pressing plates 601, the guide rods 602 are slidably connected to the support 502, the pressing plates 601 are guided by the guide rods 602, the pressing plates 601 can vertically slide up and down through the guide rods 602, toothed plates 603 are fixedly connected to the upper side walls of the two pressing plates 601, a fourth motor 604 is fixedly installed on the support 502, the two toothed plates 603 are respectively meshed and connected to two sides of an output shaft of the fourth motor 604, through the starting of the fourth motor 604, the output shaft of the fourth motor 604 drives one pressing plate 601 to move downwards, the other pressing plate 601 to move upwards, so that the pressing plate 601 moving downwards presses the slow release shells on the lower side, at the same time, half of the slow release shells on the material spreading disc 501 are pressed, then the output shaft of the fourth motor 604 is driven to reversely rotate, and after the other pressing plate 601 moves downwards, the other half of the slow release shells laid on the material spreading disc 501 are pressed;
the storage component 7 comprises a containing barrel 701, the containing barrel 701 is suspended inside the closed barrel 404 through a first electric push rod 702, the first electric push rod 702 is fixedly installed on the side wall of the closed barrel 404, and the lower end of the output shaft of the first electric push rod 702 is connected to the sidewall of the tub 701, when the output shaft of the first electric push rod 702 slides up and down, the output shaft of the first electric push rod 702 drives the containing barrel 701 to slide up and down in the closed barrel 404, the upper end opening portion of the tub 701 is outwardly expanded to form a sealing surface 703 for sealing the lower end of the discharge pipe 509, a discharge hole 704 is formed at the lower end of the containing barrel 701, a housing 705 is fixedly installed inside the containing barrel 701, a sliding rod 707 is connected inside the housing 705 in a sliding manner through a spring 706, the lower end of the sliding rod 707 penetrates through the side wall of the housing 705 and is movably pressed on the side wall of the discharge hole 704, the spring 706 has downward pressure on the sliding rod 707, the lower end of the sliding rod 707 is tightly pressed against the sidewall of the discharging hole 704 by the downward elastic force of the spring 706, thereby realizing that the slow release shell is contained in the containing barrel 701 and the sliding rod 707 is upwards pressed to cause the sliding rod 707 to slide upwards against the elastic force of the spring 706, at the moment, the sliding rod 707 is separated from the side wall of the discharge hole 704 to open the discharge hole 704, at the moment, the slow release shell in the containing barrel 701 can be discharged from the discharge hole 704, the inside of the containing barrel 701 is rotatably connected with a stirring paddle 708, the stirring paddle 708 is driven to rotate by a fifth motor 709, the fifth motor 709 is fixedly arranged inside the containing barrel 701, and the output shaft of the fifth motor 709 is connected with the upper end of the stirring paddle 708, so that after the fifth motor 709 is started, the output shaft of the fifth motor 709 drives the stirring paddle 708 to rotate, so that the stirring paddle 708 stirs the slow release shell inside the holding barrel 701.
The processing process comprises the steps of pouring slow-release shell particles into a storage bin 503, starting a second motor 504 to enable the second motor 504 to drive a first worm 505 to rotate, enabling the first worm 505 to dial the slow-release shell particles in the storage bin 503 into an inner cavity of a spreading arm 507, then starting a third motor 506 to enable the spreading arm 507 to rotate, enabling the slow-release shell particles in the spreading arm 507 to be laid on the upper side surface of a spreading disc 501, starting a fourth motor 604 to enable the fourth motor 604 to drive two pressing plates 601 to alternately press the slow-release shells on the spreading disc 501, enabling the opening parts of the slow-release shells to be pressed open by the pressing plates 601 at the moment, enabling the spreading disc 501 to be arranged inside a low-temperature box, enabling the opening parts of the slow-release shells to be in a non-memory state all the time in a low-temperature state, naturally enabling each part to be additionally provided with a refrigeration structure to keep running at low temperature according to actual conditions, enabling the pressed slow-release shells to be scraped to the inside a discharge groove 5010 to the inside a discharge pipe 509 and fall into a collection barrel 701 along the discharge pipe, and enabling the slow-release shells to be collected in a collection barrel 701 and placed inside a collection barrel 701.
In order to measure and inspect the weight of the composite salt filled into the slow release shell, specifically, the weighing mechanism 8 includes an electronic scale 801 fixedly mounted on the frame 2, second electric push rods 804 are fixedly connected to the lower sides of the four corners of the electronic scale 801 and located on the side wall of the frame 2, a sealing plate 802 is placed on the weighing plate of the electronic scale 801, sleeves 803 are fixedly connected to the four corners of the lower side surface of the sealing plate 802, the lower ends of the sleeves 803 penetrate through the side wall of the weighing plate of the electronic scale 801 and are movably sleeved on the output shaft of the second electric push rods 804, and the weighing mechanism 8 further includes an air suction pump 805 fixedly mounted on the side wall of the sealing barrel 404, so that low-temperature reduced pressure distillation is performed.
The process of detection by the weighing mechanism 8 is as follows: after a certain amount of slow-release shells are placed in the holding barrel 701 (the weight is known, for example, the total number of turns of the rotation of the first worm 505), the first electric push rod 702 is started to cause the output shaft of the first electric push rod 702 to slide the holding barrel 701 downwards, so that the holding barrel 701 (provided with fine meshes) moves to the inside of the soaking barrel 3, at this time, the dispersion liquid in the soaking barrel 3 carries the previously added composite salt into the slow-release shells, and then the composite salt is loaded into the slow-release shells, in order to make the flow smoother, the fifth motor 709 is started to cause the fifth motor 709 to drive the stirring paddle 708 to rotate, so that the soaked slow-release shells are stirred, the efficiency of the composite salt entering the slow-release shells is improved, and the composite salt is uniformly dispersed in the dispersion liquid at the same time, after the containing barrel 701 is lifted upwards and reset by the first electric push rod 702, the screw 402 is rotated by starting the first motor 403, so that the sliding plate 401 drives the closed barrel 404 to slide to the weighing mechanism 8 (from the state shown in fig. 4 to the state shown in fig. 6), at this time, the second electric push rod 804 is started, so that the upper end of the output shaft of the second electric push rod 804 pushes against the sleeve 803 to slide upwards, the sleeve 803 drives the closed plate 802 to slide upwards, so that the upper side surface of the closed plate 802 is pressed against the lower side surface of the sliding plate 401, so as to seal the lower end of the closed barrel 404, in addition, after the first electric push rod 702 lifts the containing barrel 701 upwards, the sealing surface blocks the lower end of the discharge pipe 509 (as shown in fig. 11), at this time, the inside of the closed barrel 404 is in a closed state, in this state, the suction pump 805 is started, so that the air pump 805 continuously pumps the air inside the closed barrel 404, so as to perform cryogenic distillation on the slow release shell inside the holding barrel 701 (to avoid the slow release shell from being deformed), so as to distill the dispersion liquid inside the slow release shell (the stirring paddle 708 can be driven by the fifth motor 709 to rotate in the cryogenic distillation process, so as to improve the efficiency of the cryogenic distillation), so as to only leave the compound salt inside the slow release shell, after the cryogenic distillation is performed for a period of time, the second electric push rod 804 is started, so that the output shaft of the second electric push rod 804 slides downwards, so as to enable the closed plate 802 to fall on the weighing plate of the electronic scale 801 (at this time, the output shaft of the second electric push rod 804 is not in contact with the sleeve 803, so that the closed plate 802 is completely placed on the weighing plate of the electronic scale 801, so as to maintain accuracy), and then the first electric push rod 702 is started, the output shaft of the first electric push rod 702 drives the containing barrel 701 to slide downwards, the lower end of the containing barrel 701 is placed on the closing plate 802 (the output shaft of the first electric push rod 702 is connected with the containing barrel 701 in the form of a connecting shaft and a waist-shaped groove, the connecting shaft is fixed on the output shaft of the first electric push rod 702, the waist-shaped groove is formed in the side wall of the containing barrel 701), after the containing barrel 701 is placed on the closing plate 802, the connecting shaft slides to the middle position of the waist-shaped groove, the weight of the containing barrel 701 is completely supported by the closing plate 802 (as shown in figure 10), because the weight of each part is known, the weight of the slow release shell in the containing barrel 701 can be measured through the electronic scale 801, then the weight of the original slow release shell is combined to calculate the weight of the composite salt, if the weight of the composite salt does not reach the standard, the sliding plate 401 is driven to move again through the moving member 4, the holding barrel 701 is driven to move to the position right above the soaking barrel 3, and then the holding barrel 701 is soaked in the soaking barrel 3 again until the weight of the composite salt filled in the slow release shell reaches the standard.
Specifically, after the weight of the composite salt in the slow-release shell is qualified, the holding barrel 701 is moved to the position right above the transfer barrel 1 through the moving member 4 (as shown in fig. 7), at this time, the first electric push rod 702 is caused to make the first electric push rod 702 slide downwards after the holding barrel 701 is obtained, the discharge port 704 is in contact with the discharge hopper 9, the specific discharge hopper 9 comprises the feed port 901, the whole discharge hopper 9 is in a double-V structure, the discharge rod 902 is fixedly installed in the middle position, the discharge rod 902 can jack up the slide rod 707 upwards, so that the discharge port 704 is communicated with the feed port 901, thus, the slow-release shell inside the holding barrel 701 can flow into the interior of the transfer barrel 1 through the discharge hopper 9 to be collected and transferred, and in order to quickly restore the deformation of the slow-release shell and prevent the composite salt from leaking, at this time, the transfer barrel 1 can be placed in a drying oven to be heated to restore the shape, and for the coating matching with the slow-release shell, an artificial mode is preferentially used in construction.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (7)
1. A colored anti-icing coating is characterized by comprising an ice point depression component, a hydrophobic component, an adhesive component and a pigment component;
wherein,
the freezing point depressing component comprises
A complex salt;
the hydrophobic component comprises
Organosilicon rubber emulsion,
A reinforcing agent,
A filler,
Film-forming assistant,
A catalyst,
A plasticizer,
A flatting agent mixed liquid,
Defoaming agents;
the adhesive component comprises
Emulsified asphalt,
Rubber powder,
Epoxy resin,
A silicone rubber cross-linking agent,
A silane coupling agent,
the hydrophobic component is prepared by the following process:
a1, adding a reinforcing agent, a filler and a film forming auxiliary agent into diluent water, and stirring and dispersing;
a2, adding organic silicon rubber emulsion, a catalyst, a plasticizer, a flatting agent mixed solution and a defoaming agent;
a3, continuously stirring to obtain a hydrophobic component of the product;
the freezing point depression component also comprises a slow release shell, the slow release shell is a hollow nickel-titanium memory alloy ball with a gap, the phase transition temperature of the hollow nickel-titanium memory alloy ball is less than 5 ℃, the composite salt is positioned in the hollow nickel-titanium memory alloy ball, the slow release shell is subjected to deformation treatment by matching of a material spreading piece (5) and a material pressing piece (6), and the composite salt is filled through a material storage piece (7).
2. The colored anti-freeze coating according to claim 1, wherein the pigment component is pigment particles sieved through a 300 mesh sieve, and the composite salt is one or both of sodium chloride and calcium chloride or magnesium chloride.
3. The colored anti-freezing coating according to claim 1, wherein the strengthening agent is one or more of precipitated calcium carbonate, carbon black and magnesium carbonate;
the filler is one or more of titanium dioxide, zinc oxide powder and barium sulfate;
the film forming additive is one or more of 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate and glycol;
the catalyst is dibutyltin dilaurate;
the plasticizer is DOP;
the flatting agent mixed liquid is a mixed liquid of flatting agent TH-720, ethylene glycol or glycerol and water;
the defoaming agent is methyl silicone oil.
4. The colored anti-freezing coating as claimed in claim 1, wherein the silicone rubber cross-linking agent is methyl tributyroximo silane, the silane coupling agent is KH-550, and the silicone rubber emulsion has a solid content of 25-30%.
5. A colored anti-icing coating according to claim 1, characterized in that the filling level of the composite salt inside the hollow nitinol ball is checked by means of a weighing mechanism (8).
6. The colored anti-icing coating according to claim 5, wherein the processing of the slow release shell loaded with the complex salt comprises the steps of:
b1, placing the slow-release shell in a storage bin (503);
b2, starting a second motor (504) at the bottom of the storage bin (503) to quantitatively transfer the slow release shells in the storage bin (503) to the spreading disc (501);
b3, starting a second motor (504) to transfer the slow release shell to a spreading disc (501), and smoothing the slow release shell through a spreading arm (507);
b4, the slow release shell is extruded by driving the pressing plate (601) to move downwards so as to deform the slow release shell;
b5, starting a third motor (506) to drive a spreading arm (507) to rotate, and transferring the slow-release shell from the spreading disc (501) to a holding barrel (701);
b6, immersing the holding barrel (701) into an immersion barrel (3) containing the composite salt and the dispersion liquid;
b7, starting a fifth motor (709) to drive a stirring paddle (708) to stir;
b8, removing the holding barrel (701) from the soaking barrel (3), and reducing the air pressure of the area by using an air pump (805) to completely evaporate the dispersion liquid;
and B9, weighing the slow-release shells in the holding barrel (701), repeating B6-B8 if the slow-release shells do not reach the standard, and transferring the slow-release shells into the transfer barrel (1) if the slow-release shells do not reach the standard.
7. A colored anti-icing coating according to claim 6, characterized in that said processing of slow release shell-supported complex salts is carried out entirely on the frame (2) and transferred by the moving member (4).
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| Application Number | Priority Date | Filing Date | Title |
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| CN202310043217.XA CN116200076B (en) | 2022-04-10 | 2022-04-10 | Anti-icing slow-release coating |
| CN202210370467.XA CN114773918B (en) | 2022-04-10 | 2022-04-10 | Colored anti-freezing coating |
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| CN111154363A (en) * | 2020-01-16 | 2020-05-15 | 天津滨海澳泰防水材料有限公司 | High-reflection type metal roof waterproof coating and preparation method thereof |
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| CN113150690A (en) * | 2021-03-05 | 2021-07-23 | 重庆重交再生资源开发股份有限公司 | Slow-release type anti-freezing ice fog sealing layer material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116200076A (en) | 2023-06-02 |
| CN114773918A (en) | 2022-07-22 |
| CN116200076B (en) | 2024-06-25 |
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