CN114772843A - Method and device for increasing pH of preserved fruit processing wastewater - Google Patents

Method and device for increasing pH of preserved fruit processing wastewater Download PDF

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Publication number
CN114772843A
CN114772843A CN202210315092.7A CN202210315092A CN114772843A CN 114772843 A CN114772843 A CN 114772843A CN 202210315092 A CN202210315092 A CN 202210315092A CN 114772843 A CN114772843 A CN 114772843A
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acid
tank
microbial degradation
wastewater
resistant
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蓝应伦
王勇
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Guangzhou Yixin Construction Group Co ltd
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Guangzhou Yixin Construction Group Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention relates to the field of preserved fruit processing wastewater treatment, in particular to a method and a device for increasing the pH of preserved fruit processing wastewater; inputting the acidic preserved fruit wastewater into an acid-resistant microbial degradation pool, and realizing pH increase and organic matter removal of the acidic preserved fruit wastewater by using acid-resistant microbial degradation; treating the effluent of the acid-resistant microbial degradation tank in a sedimentation tank, obtaining biological sludge formed by acid-resistant microbes, and conveying part of the biological sludge back to the acid-resistant microbial degradation tank; treating the effluent of the sedimentation tank by an alkaline filler filter tank; the pH value of the acidic preserved fruit wastewater is improved by the combined action of acid-resistant microbial degradation and alkaline filler filtration, a large amount of precipitates generated by adding a chemical agent and adding alkali into the preserved fruit wastewater are avoided, the operation cost is obviously reduced, and meanwhile, a part of organic matters are removed by microbial degradation, the organic load of a subsequent treatment unit is reduced, and the treatment cost is favorably reduced.

Description

Method and device for increasing pH of preserved fruit processing wastewater
Technical Field
The invention relates to the technical field of preserved fruit processing wastewater treatment, in particular to a method and a device for increasing the pH of preserved fruit processing wastewater.
Background
The waste water produced by processing the preserved fruits often has pungent smell, contains a large amount of sugar, salt, sodium cyclamate, citric acid, sodium metabisulfite and the like, has strong acidity, can cause serious pollution when being discharged into a water body, and needs to be discharged after the pH value is increased.
The preserved fruit processing wastewater is generally treated by a biological method, and in order to maintain the proper pH condition of the common biological method, a large amount of alkali liquor is used for neutralizing strong-acid preserved fruit processing wastewater, such as flake caustic soda, lime and the like.
The method adds alkaline chemical agents to increase the pH value of the preserved fruit wastewater to neutral and alkaline, a large amount of precipitates are generated, the sludge treatment load and cost are increased, and the treatment cost is increased.
Disclosure of Invention
The invention aims to provide a method and a device for increasing the pH of cold fruit processing wastewater, and aims to solve the technical problems that in the prior art, the pH of cold fruit processing wastewater is increased to be neutral and alkaline by adding an alkaline chemical agent, a large amount of precipitates are generated, the sludge treatment load and cost are increased, and the treatment cost is increased.
In order to achieve the purpose, the method for increasing the pH of the preserved fruit processing wastewater adopted by the invention comprises the following steps:
obtaining acid preserved fruit wastewater, inputting the acid preserved fruit wastewater into an acid-resistant microbial degradation pool, and realizing pH increase and organic matter removal of the acid preserved fruit wastewater by using acid-resistant microbial degradation;
treating the effluent of the acid-resistant microbial degradation tank by a sedimentation tank, acquiring biological sludge formed by acid-resistant microbes, and conveying part of the biological sludge back to the acid-resistant microbial degradation tank;
and treating the effluent of the sedimentation tank by using an alkaline filler filter tank to obtain water with the pH value being increased.
The method comprises the following steps of obtaining acid preserved fruit wastewater, inputting the acid preserved fruit wastewater into an acid-resistant microbial degradation pool, and realizing pH (potential of hydrogen) improvement and organic matter removal of the acid preserved fruit wastewater by using acid-resistant microbial degradation, wherein the method further comprises the following steps:
the acid-tolerant microorganisms are present in the form of a biofilm.
The method comprises the following steps of obtaining acid preserved fruit wastewater, inputting the acid preserved fruit wastewater into an acid-resistant microbial degradation pool, and realizing pH increase and organic matter removal of the acid preserved fruit wastewater by using acid-resistant microbial degradation, wherein the method further comprises the following steps:
the acid-resistant microbial degradation tank adopts a three-dimensional elastic filler as a biofilm carrier.
Wherein the sedimentation tank treats the effluent of the acid-resistant microbial degradation tank, obtains a biological sludge formed by acid-resistant microbes, and conveys a portion of the biological sludge back to the acid-resistant microbial degradation tank, the method further comprising:
and treating the effluent of the acid-resistant microbial degradation tank by the sedimentation tank, settling for 2-4 hours to obtain biological sludge formed by acid-resistant microbes, arranging a sludge return pipe at the bottom of the sedimentation tank, wherein the sludge return ratio is 50-100%, and conveying part of the biological sludge back to the acid-resistant microbial degradation tank.
Wherein, the effluent of the sedimentation tank is treated by an alkaline filler filter tank to obtain water with raised pH, and the method also comprises the following steps:
the alkaline filler in the alkaline filler filter is dolomite, the particle size of the dolomite is 1-3 cm, and the thickness of a filter bed is 1-1.5 m.
A device for increasing pH of cold fruit processing wastewater comprises an acid-resistant microbial degradation tank, a sedimentation tank, an alkaline filler filter tank and an air diffusion assembly;
the sedimentation tank is communicated with the acid-resistant microbial degradation tank, the alkaline filler filter tank is communicated with the sedimentation tank, and the air diffusion assembly is connected with the alkaline filler filter tank.
The method and the device for improving the pH value of the cold fruit processing wastewater firstly realize the pH improvement and the organic matter removal of the acidic cold fruit wastewater through the acid-resistant microbial degradation in the acid-resistant microbial degradation tank, wherein acid-resistant microbes exist in a biomembrane form, then the sedimentation tank intercepts biological sludge in the effluent of the acid-resistant microbial degradation tank, the intercepted biological sludge partially returns to the acid-resistant microbial degradation tank, the alkaline filler filter tank treats the effluent of the sedimentation tank, the alkaline filler tank is provided with alkaline filler dolomite, the pH value of the acidic cold fruit wastewater is further improved to be nearly neutral, the pH value of the acidic cold fruit wastewater is improved by the combined action of the acid-resistant microbial degradation and the alkaline filler filtration, compared with the traditional method for adding alkaline chemical agents, the method and the device avoid adding chemical agents and a large amount of sediments generated by adding alkali into the cold fruit wastewater, thereby obviously reducing the operating cost, meanwhile, a part of organic matters are removed through microbial degradation, so that the organic load of a subsequent treatment unit is reduced, and the treatment cost is favorably reduced.
Drawings
FIG. 1 is a process diagram of the method for raising pH of waste water from fruit processing according to the present invention.
FIG. 2 is a schematic structural diagram of the device for raising pH of waste water from fruit processing of the present invention.
Fig. 3 is an enlarged view of fig. 2 at a of the present invention.
201-acid-resistant microbial degradation pool, 202-sedimentation pool, 203-alkaline filler filter pool, 204-guide rail, 205-guide block, 206-exhaust pipe, 207-support seat, 208-transmission screw rod and 209-slide block.
Detailed Description
Referring to fig. 1, the present invention provides a method for increasing pH of waste water from processing preserved fruits, comprising the following steps:
s101: obtaining the acidic preserved fruit wastewater, inputting the acidic preserved fruit wastewater into an acid-resistant microbial degradation tank 201, and realizing the pH increase and organic matter removal of the acidic preserved fruit wastewater by using the acid-resistant microbial degradation.
Specifically, firstly, inputting the obtained acidic preserved fruit wastewater into the acid-resistant microbial degradation pool 201, wherein the acid-resistant microbial degradation pool 201 contains acid-resistant microorganisms, and the acid-resistant microorganisms consist of Bacillus cereus and Bacillus albus; bacillus cereus has been deposited at the Guangdong provincial collection of microorganisms at 23.8.2021, address: guangzhou city, first furious Zhonglu No. 100 large yard No. 59 building No. 5, zip code: 510070, collection accession number GDMCC NO: 61884; bacillus safensis has been deposited at the Guangdong provincial collection of microorganisms at 23.8.2021, address: building 5 of the prefecture Zhonglu No. 100 large yard No. 59 in Guangzhou city, the postcode: 510070, accession number GDMCC NO: 61886, acid-resistant microorganisms exist in the form of a biological film, the acid-resistant microorganism degradation tank 201 adopts a three-dimensional elastic filler as a biological film carrier, the acid-resistant microorganisms are attached to the filler to form a biological film, the acidic preserved fruit wastewater is treated under aerobic conditions, the pH value of the acidic preserved fruit wastewater is increased, organic matters are removed, the pH value is not required to be adjusted by adding alkali, chemical agents are prevented from being added, a large amount of precipitates generated by adding alkali into the preserved fruit wastewater are avoided, the operation cost is obviously reduced, and the treated water is discharged into the precipitation tank 202.
S102: the sedimentation tank 202 processes the effluent of the acid-resistant microbial degradation tank 201, obtains biological sludge formed by acid-resistant microbes, and conveys a portion of the biological sludge back to the acid-resistant microbial degradation tank 201.
Specifically, the sedimentation tank 202 intercepts biological sludge formed by acid-resistant microorganisms in the water discharged from the acid-resistant microbial degradation tank 201, the sedimentation time is 2-4 h, a sludge return pipe is arranged at the bottom of the sedimentation tank 202, the sludge return ratio is 50% -100%, the intercepted biological sludge is partially returned to the acid-resistant microbial degradation tank 201 and reused, the treatment cost is favorably reduced, and the treated water is discharged into the alkaline filler tank.
S103: the alkaline filler filter 203 treats the effluent of the sedimentation tank 202 to obtain water with raised pH.
Specifically, the alkaline filler filter 203 is internally provided with an alkaline filler dolomite, wherein the grain diameter of the dolomite is 1-3 cm, and the bottom of the alkaline filler filter 203 is provided with an air diffusion device for blowing off soluble CO2The regular back flushing of the alkaline filler filter 203 is completed by a gas washing device arranged at the bottom of the alkaline filler filter 203, the alkaline filler filter 203 further plays a role in lifting the pH value of the acidic preserved fruit wastewater to be near neutral, and the pH value of the acidic preserved fruit wastewater is lifted by adopting the combined action of acid-resistant microbial degradation and alkaline filler filtration.
The specific implementation mode is as follows:
1) the acid-resistant microbial degradation tank 201 directly treats strong acid preserved fruit processing wastewater, the COD concentration of the preserved fruit wastewater is 5000-15000 mg/L, the pH is 3.5-4.5, and the hydraulic retention time is 24-48 h; the sedimentation performance of acid-resistant microorganisms is poor, the acid-resistant microorganisms need to operate in a biomembrane mode, the volume filling ratio of a reaction tank adopting elastic three-dimensional fillers is 60-80%, and the membrane hanging time is about 7-14 days;
2) treating effluent of the acid-resistant microbial degradation tank 201 by using a sedimentation tank 202, wherein the sedimentation time is 2-4 h, a sludge return pipe is arranged at the bottom of the sedimentation tank 202, and the sludge return ratio is 50-100%;
3) the alkaline filler filter 203 is used for treating effluent of the sedimentation tank 202, the particle size of dolomite is 1-2 cm, the thickness of a filter bed is 1-1.5 m, the filtering speed is 1-3 m/h, the perforated pipe is used for aeration, the air-water ratio is 10-20, the perforated pipe is arranged at the bottom of the filter, the aperture is 9-12 mm, the washing period of the filter is 15d, and the washing strength of air washing is 10-15L/(m 2 s).
Specific examples are given below:
example 1: culturing acid-resistant microorganisms and starting acid-resistant microorganism degradation tank 201
The acid-resistant microorganisms are subjected to sterilization culture by adopting the following culture medium: 3g/L malt extract; 5g/L ammonium chloride; 10g/L glucose; 3g/L of oxalic acid, wherein the inoculation amount is 10 percent, and the OD600 value of the bacterial liquid after 3 days is more than or equal to 1.5;
starting the acid-resistant microbial degradation tank 201: adding elastic three-dimensional filler, wherein the volume filling ratio of the filler is 70%, the inoculation amount of the acid-resistant microbial inoculum is 20%, adding the culture medium, performing aeration culture for 7 days, completing filler film formation and reactor starting, and increasing the pH of the culture medium from initial 2.5 to above 7.5.
Example 2: PH elevation for mixed preserved fruit processing wastewater treatment
The indexes of the mixed sewage produced by processing preserved fruits are as follows: pH 4.6, COD 13500mg/L, TN 110mg/L, TP 3mg/L, TN 15mg/L, and salinity 5%, and the preserved fruit wastewater is mixed sewage of plum and cumquat preserved fruit. The acid-resistant microorganism degradation adopts a biomembrane formed by cultured acid-resistant microorganisms attached with a filler to directly treat the acid preserved fruit processing wastewater, and the acid-resistant microorganisms have good acid and salt resistance; the alkaline filler filter 203 adopts dolomite particles with the particle size of 1-3 cm, the height of a filter material is 1.5m, the filtering speed is 1m/h, and aeration is performed at the bottom; carrying out aerobic treatment on the acid-resistant microorganisms for 24 hours, wherein the pH is 7.5, and the COD is reduced to 7480 mg/L; after filtering with the alkaline filter material filter, the COD is reduced to 7160mg/L, and the pH value is 7.7. When the preserved fruit processing wastewater passes through the acid-resistant microbial degradation and is directly treated by the alkaline filler filter 203, the pH value is increased from 4.6 to 6.5. The dolomite filter is back-washed once every 15 days, the back-washing strength is 15L/(m2 s), and the washing time is 15 min.
The pH value of the preserved fruit processing wastewater is improved by adopting the combined action of acid-resistant microbial degradation and alkaline filler filtration, compared with the traditional method for adding alkaline chemical agents, the method avoids adding chemical agents and a large amount of precipitates generated by adding alkali into the preserved fruit wastewater, obviously reduces the operation cost, removes a part of organic matters through microbial degradation, reduces the organic load of a subsequent treatment unit, and is favorable for reducing the treatment cost.
Referring to fig. 2, a device for increasing pH of waste water from processing preserved fruits comprises an acid-resistant microbial degradation tank 201, a sedimentation tank 202, an alkaline filler filter tank 203, and an air diffusion component;
the sedimentation tank 202 is communicated with the acid-resistant microbial degradation tank 201, the alkaline filler filter tank 203 is communicated with the sedimentation tank 202, and the air diffusion assembly is connected with the alkaline filler filter tank 203.
Further, referring to fig. 2 and 3, the air diffusing assembly includes a support member, a guide rail 204, a guide block 205 and an exhaust pipe 206, wherein the support member is connected to the alkaline filler filter 203; the guide rail 204 is connected with the alkaline filler filter 203 and is positioned inside the alkaline filler filter 203; the guide block 205 is slidably connected with the guide rail 204 and connected with the exhaust pipe 206; the exhaust pipe 206 is connected to the support member.
Further, referring to fig. 2 and fig. 3, the supporting member includes a supporting seat 207, a transmission screw 208 and a sliding block 209, the supporting seat 207 is connected with the alkaline filler filter 203 and is located inside the alkaline filler filter 203; the transmission screw rod 208 is rotatably connected with the supporting seat 207; the sliding block 209 is rotatably connected to the driving screw 208 and is connected to the exhaust pipe 206.
In this embodiment, the acid-resistant microbial degradation tank 201 contains acid-resistant microbes, acid-resistant microbes are introduced into the acid-resistant microbial degradation tank 201, and the acid-resistant microbes degrade to achieve pH increase and removal of organic matters in the acid-resistant fruit wastewater, wherein the acid-resistant microbes exist in the form of a biofilm, the acid-resistant microbial degradation tank 201 adopts a three-dimensional elastic filler as a biofilm carrier, the treated water is introduced into the sedimentation tank 202, the sedimentation tank 202 settles for 2-4 h to obtain biological sludge formed by the acid-resistant microbes, a sludge return pipe is arranged at the bottom of the sedimentation tank 202, part of the biological sludge is conveyed back into the acid-resistant microbial degradation tank 201 for recycling, which is beneficial to saving treatment cost, the settled sewage is introduced into the alkaline filler filter tank 203, the alkaline filler filter 203 contains dolomite, and the acid-resistant fruit wastewater is further treated, raising the pH value of the water to obtain water with raised pH value; the alkaline filler filter 203 is also internally provided with the supporting seat 207, the supporting seat 207 is rotationally connected with the transmission screw rod 208, the transmission screw rod 208 is driven to rotate by a driving motor arranged above the supporting seat 207, the transmission screw rod 208 is rotationally connected with the slide block 209, the slide block 209 and the transmission screw rod 208 are arranged in a thread fit way relatively, the slide block 209 moves up and down along with the positive rotation and the reverse rotation of the transmission screw rod 208, the slide block 209 is connected with the exhaust pipe 206, the exhaust pipe 206 is connected with the guide block 205, the guide block 205 is connected with the guide rail 204 in a sliding way, the guide rail 204 is arranged in the alkaline filler filter 203 to guide the movement of the exhaust pipe 206, an air source outside the exhaust pipe 206 inflates the alkaline filler filter 203, the wastewater treatment is assisted, and the transmission of the slide block 209 by the transmission screw rod 208 is utilized, conveniently adjust the height of blast pipe 206, and then be applicable to the waste water treatment of multiple condition, conveniently shift out simultaneously blast pipe 206 washs, reduces the hand labor volume, effectively improves work efficiency.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention.

Claims (6)

1. A method for increasing pH of preserved fruit processing wastewater is characterized by comprising the following steps:
obtaining acid preserved fruit wastewater, inputting the acid preserved fruit wastewater into an acid-resistant microbial degradation pool, and realizing pH increase and organic matter removal of the acid preserved fruit wastewater by using acid-resistant microbial degradation;
treating the effluent of the acid-resistant microbial degradation tank by using a sedimentation tank to obtain biological sludge formed by acid-resistant microbes, and conveying part of the biological sludge back to the acid-resistant microbial degradation tank;
and treating the effluent of the sedimentation tank by using an alkaline filler filter tank to obtain water with the pH value being increased.
2. The method for increasing the pH of the fruit jelly processing wastewater according to claim 1, wherein the acidic fruit jelly wastewater is obtained and is input into an acid-resistant microbial degradation tank, and the pH of the acidic fruit jelly wastewater is increased and organic matters are removed by using the acid-resistant microbial degradation, and the method further comprises the following steps:
the acid-tolerant microorganism is present in the form of a biofilm.
3. The method for increasing the pH of the fruit jelly processing wastewater according to claim 2, wherein the acidic fruit jelly wastewater is obtained and is input into an acid-resistant microbial degradation tank, and the pH of the acidic fruit jelly wastewater is increased and organic matters are removed by using the acid-resistant microbial degradation, and the method further comprises the following steps:
the acid-resistant microbial degradation tank adopts a three-dimensional elastic filler as a biofilm carrier.
4. The method for raising the pH of the waste water from the fruit processing according to claim 1, wherein the sedimentation tank is used for treating the effluent of the acid-resistant microbial degradation tank, obtaining the biological sludge formed by the acid-resistant microbes, and conveying part of the biological sludge back to the acid-resistant microbial degradation tank, and the method further comprises:
and treating the effluent of the acid-resistant microbial degradation tank by the sedimentation tank, settling for 2-4 hours to obtain biological sludge formed by acid-resistant microbes, arranging a sludge return pipe at the bottom of the sedimentation tank, wherein the sludge return ratio is 50-100%, and conveying part of the biological sludge back to the acid-resistant microbial degradation tank.
5. The method for increasing the pH of the waste water from the fruit processing according to claim 1, wherein the effluent of the sedimentation tank is treated by an alkaline filler filter to obtain the pH-increased water, and the method further comprises:
the alkaline filler in the alkaline filler filter tank is dolomite, the grain size of the dolomite is 1-3 cm, and the thickness of a filter bed is 1-1.5 m.
6. A device for increasing the pH of the cold fruit processing wastewater is suitable for the method for increasing the pH of the cold fruit processing wastewater according to claim 1, and is characterized by comprising an acid-resistant microbial degradation tank, a sedimentation tank, an alkaline filler filter tank and an air diffusion assembly;
the sedimentation tank is communicated with the acid-resistant microbial degradation tank, the alkaline filler filter tank is communicated with the sedimentation tank, and the air diffusion assembly is connected with the alkaline filler filter tank.
CN202210315092.7A 2022-03-28 2022-03-28 Method and device for increasing pH of preserved fruit processing wastewater Pending CN114772843A (en)

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