CN114763678A - Dyeing method of polyester fabric for high-color-fastness luggage fabric - Google Patents
Dyeing method of polyester fabric for high-color-fastness luggage fabric Download PDFInfo
- Publication number
- CN114763678A CN114763678A CN202210405215.6A CN202210405215A CN114763678A CN 114763678 A CN114763678 A CN 114763678A CN 202210405215 A CN202210405215 A CN 202210405215A CN 114763678 A CN114763678 A CN 114763678A
- Authority
- CN
- China
- Prior art keywords
- dyeing
- polyester fabric
- fabric
- fastness
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 182
- 229920000728 polyester Polymers 0.000 title claims abstract description 150
- 238000004043 dyeing Methods 0.000 title claims abstract description 108
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000000975 dye Substances 0.000 claims abstract description 57
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000002791 soaking Methods 0.000 claims abstract description 21
- 239000000986 disperse dye Substances 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 15
- 238000004321 preservation Methods 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 93
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000002245 particle Substances 0.000 claims description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 241000219782 Sesbania Species 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 31
- 238000001035 drying Methods 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 24
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 claims description 23
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 claims description 23
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 claims description 23
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 20
- 229940014800 succinic anhydride Drugs 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 16
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 11
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 11
- 229940069446 magnesium acetate Drugs 0.000 claims description 11
- 235000011285 magnesium acetate Nutrition 0.000 claims description 11
- 239000011654 magnesium acetate Substances 0.000 claims description 11
- 239000011259 mixed solution Substances 0.000 claims description 9
- 238000009210 therapy by ultrasound Methods 0.000 claims description 9
- LIWTYARTIXGSTP-UHFFFAOYSA-N prop-2-enoic acid;1,1,2-trifluoroethene Chemical compound OC(=O)C=C.FC=C(F)F LIWTYARTIXGSTP-UHFFFAOYSA-N 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 6
- 239000000835 fiber Substances 0.000 description 19
- 238000002156 mixing Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 239000005020 polyethylene terephthalate Substances 0.000 description 10
- 229920004933 Terylene® Polymers 0.000 description 9
- 239000010979 ruby Substances 0.000 description 9
- 229910001750 ruby Inorganic materials 0.000 description 9
- -1 acrylic acid trifluoroethylene ester Chemical class 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000630 rising effect Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000002411 adverse Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229920004934 Dacron® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229920000587 hyperbranched polymer Polymers 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention relates to the technical field of polyester fabric dyeing methods, and discloses a dyeing method of a polyester fabric for high-color-fastness luggage fabric, which comprises the following steps: soaking the polyester fabric into a dye solution for dyeing, heating up from room temperature at a heating rate of 0.5-1 ℃/min, then carrying out heat preservation treatment at 130-140 ℃ for 20-30 min, and finally cooling to room temperature at a cooling rate of-6 to-1 ℃/min; the dye solution comprises disperse dye, acetic acid and a leveling agent. According to the invention, the existing dyeing process is optimized, the color fastness performance of the polyester fabric is improved to reach the European standard (ISO105B02) level 5, the additional value of the case fabric is improved, and better economic benefit is obtained.
Description
Technical Field
The invention relates to the technical field of polyester fabric dyeing methods, in particular to a dyeing method of a polyester fabric for high-color-fastness luggage fabric.
Background
The terylene has excellent setting performance, and flat, fluffy or pleated forms and the like generated after the terylene yarn or the fabric is set can be enduringly unchanged after being washed for many times in use. Terylene is also known as Terylene, and Americans are also known as Dacron. When it appears on the hong Kong market in China, it is well known that people translate it into "sure" according to the word Cantonese. The terylene is the simplest of three synthetic fibers and has lower price. In addition, the novel rubber belt has the characteristics of firmness, durability, good elasticity, difficult deformation, corrosion resistance, insulation, stiffness, easy washing, quick drying and the like, and is popular among people. The high-density polyester fabric is also popular with consumers as a case fabric, but the dye is not easy to permeate into the fiber in the dyeing process of the high-density polyester fabric, the coloring rate of the fiber is poor, the durable color fastness of the fabric can only reach 3-4 grades and cannot meet the use requirement, so the price of the fabric is influenced due to poor quality, and the added value of the product is low.
The dyeing percentage of a fiber is also called the dye uptake percentage, and specifically refers to the ratio of the amount of dye that is loaded onto the fiber during the dyeing process to the total amount of dye that is used. The dyeing rate of the fiber is not only related to the characteristics of the fiber, but also has great relation with the dye type, the pH value of the dye solution, the dyeing temperature, the heat preservation time and the dyeing rate in the dyeing process. The higher the coloring rate of the fiber, the more appropriate the dyeing condition is, the better the control of the cost is, and the fabric can be ensured in the aspect of color fastness. The high-density polyester fabric with higher color fastness is more widely applied in the field of bags and suitcases, and the added value and the economic benefit of the product are higher.
The Chinese patent with publication number CN111455700A discloses a method for dyeing and finishing a cationic polyester fabric, which comprises the following steps of: desizing; reducing the alkali; preparing a dye, namely compounding a disperse dye and a cationic dye; dyeing by a two-step method at high temperature and high pressure in one bath; soaping; reduction cleaning; and (6) shaping. The dyeing method has the defects that the problem that the high-density polyester fabric for the case fabric is difficult to dye is not solved, although two dyes are compounded and the dyeing process is improved, the color fastness of the dyed polyester fabric is only 3-4 grades.
Disclosure of Invention
In order to solve the problem that the high-density polyester fabric for the luggage fabric is difficult to dye, the invention provides a dyeing method of the polyester fabric for the luggage fabric with high color fastness, which improves the color fastness performance to reach the European standard (ISO105B02) level 5 by optimizing the existing dyeing process, improves the added value of the fabric and obtains better economic benefit.
The specific technical scheme of the invention is as follows: the invention provides a dyeing method of polyester fabric for high-color-fastness luggage fabric, which comprises the following steps: immersing the polyester fabric into a dye solution for dyeing, heating up from room temperature at a heating rate of 0.5-1 ℃/min, then carrying out heat preservation treatment at 130-140 ℃ for 20-30 min, and finally cooling to room temperature at a cooling rate of-6-1 ℃/min; the dye solution comprises disperse dye, acetic acid and a leveling agent.
The terylene belongs to polyester fibers, and because the terylene has a compact structure, high crystallinity and polymerization degree and strong hydrophobicity, and is difficult to obtain a good dyeing effect at normal temperature and normal pressure, in order to obtain good dyeing rate of the terylene luggage fabric, the invention enables the disperse dye to be effectively adsorbed into the amorphous region of the polyester fibers at a certain temperature by optimizing the dyeing process. When the polyester fiber is at about 130 ℃, the chain segment moves violently, the intermolecular gap is opened, and the dye can be quickly adsorbed into the amorphous area of the fiber. The solubility and the high-temperature dispersion stability of the disperse dye can be optimized by slowly heating (the heating rate is 0.5-1 ℃/min); after the temperature is raised to 130-140 ℃, the temperature is kept for a certain time, and the dye is absorbed into the amorphous area of the fiber; and then cooling to room temperature to shrink the amorphous area of the fiber, so that dye molecules are fixed in the fiber, and the fiber is dyed to obtain firm and deep color. The dye molecules can be ensured to have sufficient time to permeate into the interior of the polyester fiber and be firmly fixed in an amorphous area, and the microscopic combination can ensure that the polyester fabric has better stability when being subjected to the actions of washing, solarization, friction and the like, thereby ensuring that the polyester fabric has relatively higher dyeing fastness.
In addition, a pH buffer system is added into the disperse dye to adjust the pH value of the dye solution and improve the dyeing uniformity, and in addition, a proper amount of leveling agent is added into the dye bath to improve the solubility of the disperse dye and control the dye-uptake rate at the same time, so that the phenomenon of uneven dyeing is avoided. In order to improve the color fastness performance of the existing product to reach the 5-grade European standard (ISO105B02), improve the additional value of the fabric, and influence the color fastness by the dye type, dyeing temperature, heat preservation time, dyeing speed and the like in the dyeing method, the high-density polyester fabric has the optimal color fastness under the dyeing condition of the invention.
Preferably, the polyester fabric isThe gram weight is 200-400 g/m2。
Preferably, the pH value of the dye liquor is 4-6.
Experiments show that the dye with the pH value of 4-6 has excellent dispersion stability, excellent color and absorption of the disperse dye and optimal dyeing degree and fixation rate. Moreover, the weak acid environment is maintained in the system, so that the disperse dye is prevented from being hydrolyzed or chromophoric groups are prevented from being reduced.
Preferably, the bath ratio of the dye liquor is 1: 5 to 10.
Preferably, the temperature reduction is as follows: the temperature is reduced to 90-100 ℃ from 130-140 ℃ at a cooling rate of-3 to-1 ℃/min, and then the temperature is reduced to room temperature at a cooling rate of-6 to-4 ℃/min.
The temperature reduction process is performed at first at a slow speed and then at a fast speed, so that the shrinkage of the amorphous area of the polyester fiber can be regulated and controlled, and dye molecules can be better fixed in the fiber.
Preferably, the dyeing method further comprises a surface pretreatment step of the polyester fabric and a dyeing post-treatment step of the polyester fabric.
Preferably, the surface pretreatment step of the polyester fabric comprises the following steps: dispersing sesbania powder and trehalose in water, adding nano titanium dioxide particles, performing ultrasonic treatment, adding succinic anhydride and citric acid, stirring and reacting at 60-90 ℃ for 2-6 hours to obtain a modified nano titanium dioxide hydrosol; and (3) soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30-40 ℃ for 20-40 min, and then taking out and drying.
The surface pretreatment of the polyester fabric before dyeing can improve the dye uptake of disperse dye, the modified nano titanium dioxide hydrosol can form a rough and uneven surface on the surface of the polyester fabric, the specific surface area of dyeing is increased, and the effect of deepening is achieved. The nano titanium dioxide also has good ultraviolet-proof functional characteristics and can improve the added value of polyester fabrics, but the compatibility between the nano titanium dioxide and the polyester fabrics is poor, and the prepared hydrosol utilizes the complexing adsorption effect and the crosslinking fixation effect of sesbania powder aqueous solution to improve the dispersibility and the compatibility. The addition of trehalose can promote disperse dyes to enter gaps among polyester molecules for dyeing, and the severe movement of molecular chains is helpful for the permeation of dye molecules because the glass transition temperature of trehalose is lower than that of polyester. In addition, the polyester fabric after surface treatment can adsorb disperse dyes more easily, and the hydrogen bond acting force between hydroxyl groups rich on the surface and polar groups (such as hydroxyl groups, amino groups and the like) in the molecules of the disperse dyes is also beneficial to improving the dye uptake.
Preferably, the particle size of the nano titanium dioxide particles is not more than 100 nm; the mass ratio of the sesbania powder to the trehalose to the water is 1-3: 0.5-1.5: 100 to 150 parts; the sesbania powder, the nano titanium dioxide particles, the succinic anhydride and the citric acid are mixed in a mass ratio of 10: 0.4-1: 1-3: 0.5 to 2.
The particle size of the nano titanium dioxide particles can influence the surface pretreatment effect of the polyester fabric, and the larger the particle size is, the more adverse the combination stability and the dye-uptake uniformity are, and the appearance quality of the polyester is influenced. In addition, the addition proportion among the raw materials influences the binding performance among substances, and also influences the effect of the disperse dye molecules entering the interior of the polyester molecules to realize effective dyeing, so that the dye-uptake and the color fastness are improved.
Preferably, the dyeing post-treatment step of the polyester fabric comprises the following steps: and (3) soaking the dyed polyester fabric into a mixed solution of trifluoroethylene acrylate, acrylamide, citric acid, magnesium acetate and water, heating to 70-80 ℃, preserving heat for 1-3 hours, and then taking out the polyester fabric and drying.
The dyeing post-treatment step can improve the color fastness of the polyester fabric, and the hyperbranched polymer is generated by in-situ crosslinking reaction on the surface of the fabric, so that the escape of dye molecules in the states of washing, solarization, friction, sweat stain and the like is reduced, and the dyeing fastness is improved. And, through selecting for use low refractive index fluorine-containing resin at polyester fiber surface film forming, reduce the refracting index, have obvious deepening effect to dyeing fabric look outward appearance, can also avoid disperse dyestuff sublime from polyester fabric in the heat setting to give polyester fabric surface hydrophobicity, further promote polyester fabric's dyeing fastness.
Preferably, the mass ratio of the trifluoroethylene acrylate to the acrylamide to the citric acid to the magnesium acetate to the water is 5-10: 1-4: 2-5: 0.1-1: 200-300.
Compared with the prior art, the invention has the following advantages:
(1) by optimizing the existing dyeing process, the color fastness performance is improved to reach the 5-grade European standard (ISO105B02), the additional value of the fabric is improved, and better economic benefit is obtained;
(2) the surface pretreatment of the polyester fabric before dyeing can improve the dye uptake of disperse dyes, and the nano titanium dioxide also has good anti-ultraviolet functional characteristics and can improve the additional value of the polyester fabric;
(3) the dyeing post-treatment step can improve the color fastness of the polyester fabric, low-refractive-index fluorine-containing resin is selected to have a darkening effect on dyed fabrics, and the polyester fabric is endowed with surface hydrophobicity.
Detailed Description
The present invention will be further described with reference to the following examples.
General examples
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps: the gram weight of the steel is 200-400 g/m2The polyester fabric is immersed in the dye liquor for dyeing, the bath ratio is 1: 5-10, adjusting the pH value to 4-6, firstly heating from room temperature at a heating rate of 0.5-1 ℃/min, then carrying out heat preservation treatment at 130-140 ℃ for 20-30 min, finally cooling to 90-100 ℃ at a cooling rate of-3-1 ℃/min, and then cooling to room temperature at a cooling rate of-6-4 ℃/min; the dye solution comprises disperse dye, acetic acid and a leveling agent.
In addition, the dyeing method can also comprise a surface pretreatment step of the polyester fabric and a dyeing post-treatment step of the polyester fabric.
The surface pretreatment step of the polyester fabric comprises the following steps: dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is (1-3): 0.5-1.5: 100 to 150 parts; then adding nano titanium dioxide particles with the particle size of not more than 100nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, reacting for 2-6 hours at 60-90 ℃ while stirring, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.4-1: 1-3: 0.5-2, obtaining the modified nano titanium dioxide hydrosol; and (3) soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30-40 ℃ for 20-40 min, and then taking out and drying.
The dyeing post-treatment step of the polyester fabric comprises the following steps: and (2) mixing the following components in a mass ratio of 5-10: 1-4: 2-5: 0.1-1: 200-300 parts of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water are mixed and fully stirred, the dyed polyester fabric is immersed into the mixed solution, the temperature is raised to 70-80 ℃, the temperature is kept for 1-3 hours, and then the polyester fabric is taken out and dried.
Example 1
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps: the gram weight is 300g/m2The polyester fabric is immersed in the dye liquor for dyeing, the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (the model of the company Ludao is ERX) according to the mass fraction, and then carrying out dyeing temperature-raising and heat-preserving treatment according to the following table 1.
TABLE 1
Example 2
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps: the gram weight is 350g/m2The polyester fabric is immersed into the dye liquor for dyeing, and the bath ratio is 1: the pH was adjusted to about 5.1, and the dye solution used comprised, in mass fraction, 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid, 0.5% of a leveling agent (Ludafu, model ERX), followed by dyeing, temperature raising and heat preservation treatment according to Table 2.
TABLE 2
| Temperature of | Rate of temperature rise | Heat preservation |
| 65℃—80℃ | 0.5℃/min | / |
| 80℃—100℃ | 0.8℃/min | / |
| 100℃—120℃ | 0.8℃/min | / |
| 120℃—130℃ | 1℃/min | 130℃*30min |
| 130℃—91℃ | -2℃/min | / |
| 91 ℃ to room temperature | -5℃/min |
Example 3
The difference from example 1 is that: the dyeing method also comprises a surface pretreatment step of the polyester fabric and a dyeing post-treatment step of the polyester fabric.
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is 2: 1: 120 of a solvent; then adding nano titanium dioxide particles with the particle size of 50nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, stirring and reacting at 80 ℃ for 3 hours, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.8: 2: 1, obtaining modified nano titanium dioxide hydrosol; the gram weight is 300g/m2And soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30 ℃ for 30min, and then taking out and drying.
And (3) soaking the polyester fabric subjected to surface pretreatment into a dye solution for dyeing, wherein the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (ERX) in percentage by mass, then carrying out dyeing, temperature rising and heat preservation treatment according to the table 1, taking out the polyester fabric and drying the polyester fabric.
And (2) mixing the components in a mass ratio of 8: 2: 4: 0.3: mixing 250% of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water, fully stirring, immersing the dyed polyester fabric into the mixed solution, heating to 70 ℃, keeping the temperature for 3 hours, taking out the polyester fabric, and drying.
Example 4
The difference from example 1 is that: the dyeing method also comprises a surface pretreatment step of the polyester fabric and a dyeing post-treatment step of the polyester fabric.
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is 3: 1: 150; then adding nano titanium dioxide particles with the particle size of 70nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, reacting for 3 hours at 80 ℃ while stirring, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.5: 2: 2, obtaining modified nano titanium dioxide hydrosol; the gram weight is 300g/m2And soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 35 ℃ for 30min, and then taking out and drying.
And (3) soaking the polyester fabric subjected to surface pretreatment into a dye solution for dyeing, wherein the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (ERX) according to mass fraction, then carrying out dyeing, temperature rising and heat preservation treatment according to the following table 1, taking out the polyester fabric and drying the polyester fabric.
Mixing 8: 3: 5: 0.4: mixing 250 parts of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water, fully stirring, immersing the dyed polyester fabric into the mixed solution, heating to 80 ℃, keeping the temperature for 1h, taking out the polyester fabric, and drying.
Example 5
The difference from example 2 is that: the dyeing method also comprises a surface pretreatment step of the polyester fabric and a dyeing post-treatment step of the polyester fabric.
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is 2: 1: 120 of a solvent; then adding nano titanium dioxide particles with the particle size of 50nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, stirring and reacting at 80 ℃ for 3 hours, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.8: 2: 1, obtaining modified nano titanium dioxide hydrosol; the gram weight is 300g/m2And soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30 ℃ for 30min, and then taking out and drying.
And (2) soaking the polyester fabric subjected to surface pretreatment into a dye liquor for dyeing, wherein the bath ratio is 1: and 8, adjusting the pH to be about 5.1, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (the model of the company Ludao, ERX) according to the mass fraction, and then carrying out dyeing, temperature rise and heat preservation treatment according to the following table 2.
And (2) mixing the components in a mass ratio of 8: 2: 4: 0.3: mixing 250% of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water, fully stirring, immersing the dyed polyester fabric into the mixed solution, heating to 70 ℃, keeping the temperature for 3 hours, taking out the polyester fabric, and drying.
Comparative example 1
The difference from example 3 is that: the post-dyeing treatment step of the polyester fabric is not carried out.
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is 2: 1: 120 of a solvent; then adding nano titanium dioxide particles with the particle size of 50nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, stirring and reacting at 80 ℃ for 3 hours, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.8: 2: 1, obtaining modified nano titanium dioxide hydrosol; the gram weight is 300g/m2And soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30 ℃ for 30min, and then taking out and drying.
And (3) soaking the polyester fabric subjected to surface pretreatment into a dye solution for dyeing, wherein the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (ERX) in percentage by mass, then carrying out dyeing, temperature rising and heat preservation treatment according to the table 1, taking out the polyester fabric and drying the polyester fabric.
Comparative example 2
The difference from example 3 is that: trehalose is not added in the surface pretreatment step of the polyester fabric
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the water is 2: 120 of a solvent; then adding nano titanium dioxide particles with the particle size of 50nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, stirring and reacting at 80 ℃ for 3 hours, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.8: 2: 1, obtaining modified nano titanium dioxide hydrosol; the gram weight is 300g/m2And soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30 ℃ for 30min, and then taking out and drying.
And (2) soaking the polyester fabric subjected to surface pretreatment into a dye liquor for dyeing, wherein the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (ERX) according to mass fraction, then carrying out dyeing, temperature rising and heat preservation treatment according to the following table 1, taking out the polyester fabric and drying the polyester fabric.
Mixing 8: 2: 4: 0.3: mixing 250 parts of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water, fully stirring, immersing the dyed polyester fabric into the mixed solution, heating to 70 ℃, preserving heat for 3 hours, taking out the polyester fabric, and drying.
Comparative example 3
The difference from example 3 is that: the surface pretreatment step of the polyester fabric does not add nano titanium dioxide particles.
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is 2: 1: 120 of a solvent; adding succinic anhydride and citric acid, stirring and reacting at 80 ℃ for 3 hours, wherein the mass ratio of sesbania powder to succinic anhydride to citric acid is 10: 2: 1, obtaining modified hydrosol; the gram weight is 300g/m2And soaking the terylene fabric into the modified hydrosol in a dark place, keeping the temperature at 30 ℃ for 30min, and then taking out and drying.
And (3) soaking the polyester fabric subjected to surface pretreatment into a dye solution for dyeing, wherein the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (ERX) according to mass fraction, then carrying out dyeing, temperature rising and heat preservation treatment according to the following table 1, taking out the polyester fabric and drying the polyester fabric.
And (2) mixing the components in a mass ratio of 8: 2: 4: 0.3: mixing 250 parts of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water, fully stirring, immersing the dyed polyester fabric into the mixed solution, heating to 70 ℃, preserving heat for 3 hours, taking out the polyester fabric, and drying.
Comparative example 4
The difference from example 3 is that: in the step of surface pretreatment of the polyester fabric, the particle size of the nano titanium dioxide particles is 500 nm.
A dyeing method of polyester fabric for high-color-fastness luggage fabric comprises the following steps:
dispersing sesbania powder and trehalose in water, wherein the mass ratio of the sesbania powder to the trehalose to the water is 2: 1: 120 of a solvent; then adding nano titanium dioxide particles with the particle size of 500nm, performing ultrasonic treatment, adding succinic anhydride and citric acid, reacting for 3 hours at 80 ℃ while stirring, wherein the mass ratio of sesbania powder to nano titanium dioxide particles to succinic anhydride to citric acid is 10: 0.8: 2: 1, obtaining modified nano titanium dioxide hydrosol; the gram weight is 300g/m2And soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30 ℃ for 30min, and then taking out and drying.
And (3) soaking the polyester fabric subjected to surface pretreatment into a dye solution for dyeing, wherein the bath ratio is 1: and 6, adjusting the pH to be about 4.6, wherein the used dye solution comprises 0.12% of 2BLN disperse blue, 0.24% of S-4RL orange, 0.046% of S-5BL ruby, 0.5% of acetic acid and 0.5% of leveling agent (ERX) according to mass fraction, then carrying out dyeing, temperature rising and heat preservation treatment according to the following table 1, taking out the polyester fabric and drying the polyester fabric.
And (2) mixing the components in a mass ratio of 8: 2: 4: 0.3: mixing 250 parts of acrylic acid trifluoroethylene ester, acrylamide, citric acid, magnesium acetate and water, fully stirring, immersing the dyed polyester fabric into the mixed solution, heating to 70 ℃, preserving heat for 3 hours, taking out the polyester fabric, and drying.
Performance testing
Color fastness to rubbing: GB3920-1997
Color fastness to light: GB/T8427-1997
Color fastness to washing: GB/T3921.1-1997;
water stain resistance color fastness: GB/T5713-1997;
average ultraviolet transmittance: and testing the average transmittance of the polyester fabric at the ultraviolet wavelength of 280-400 nm.
TABLE 3 Performance testing of dyed polyester fabrics for each group
As shown in Table 1, the color fastness of the polyester fabric can reach the 5-grade European standard (ISO105B02), the added value of the polyester fabric used as the case fabric is higher, and better economic benefit can be obtained. In addition, as can be seen from examples 1 to 5, the surface pretreatment of the polyester fabric before dyeing can improve the dye uptake of the disperse dye, and the nano titanium dioxide also has good ultraviolet-proof functional characteristics and can improve the additional value of the polyester fabric; the dyeing post-treatment step can improve the color fastness of the polyester fabric, low-refractive-index fluorine-containing resin is selected to have a darkening effect on dyed fabrics, and the polyester fabric is endowed with surface hydrophobicity. In addition, combining example 3 and comparative example 1, it can also be shown that this post-dyeing treatment step can further improve the color fastness by enhancing the combination stability and hydrophobicity. Combining example 3 and comparative example 2, the added trehalose has the effect of promoting the dye molecules to enter the interior of the polyester molecules and also helps to improve the color fastness. By combining the embodiment 3 and the comparative examples 3-4, the rough and uneven surface structure formed by the nano titanium dioxide particles can improve the specific surface area and has the effects of deepening and improving the color fastness, the particle size of the nano titanium dioxide particles can influence the surface pretreatment effect of the polyester fabric, and the larger the particle size is, the more adverse the combination stability and the dye dyeing uniformity are, and the color fastness of the polyester is influenced.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention, and all simple modifications, alterations and equivalents of the above embodiments according to the technical spirit of the present invention are still within the protection scope of the technical solution of the present invention.
Claims (10)
1. A dyeing method of polyester fabric for high-color-fastness luggage fabric is characterized by comprising the following steps: soaking the polyester fabric into a dye solution for dyeing, heating up from room temperature at a heating rate of 0.5-1 ℃/min, then carrying out heat preservation treatment at 130-140 ℃ for 20-30 min, and finally cooling to room temperature at a cooling rate of-6 to-1 ℃/min; the dye solution comprises disperse dye, acetic acid and a leveling agent.
2. The dyeing method of the polyester fabric for the high-color-fastness luggage fabric according to claim 1, characterized in that the gram weight of the polyester fabric is 200-400 g/m2。
3. The dyeing method of the polyester fabric for the high-color-fastness luggage fabric according to claim 1, characterized in that the pH of the dyeing solution is 4-6.
4. The method for dyeing polyester fabrics for high-color-fastness luggage fabrics according to claim 1, characterized in that the bath ratio of the dyeing solution is 1: 5 to 10.
5. The dyeing method of the polyester fabric for the high-color-fastness luggage fabric according to claim 1, characterized in that the temperature reduction is as follows: the temperature is reduced to 90-100 ℃ from 130-140 ℃ at a cooling rate of-3 to-1 ℃/min, and then the temperature is reduced to room temperature at a cooling rate of-6 to-4 ℃/min.
6. The method for dyeing the polyester fabric for the high-color-fastness luggage fabric according to any one of claims 1 to 5, characterized in that the dyeing method further comprises a step of surface pretreatment of the polyester fabric and a step of post-dyeing treatment of the polyester fabric.
7. The method for dyeing polyester fabrics used for high-color-fastness luggage fabrics according to claim 6, characterized in that the surface pretreatment step of the polyester fabrics comprises: dispersing sesbania powder and trehalose in water, adding nano titanium dioxide particles, performing ultrasonic treatment, adding succinic anhydride and citric acid, stirring while reacting for 2-6 hours at 60-90 ℃, and thus obtaining a modified nano titanium dioxide hydrosol; and (3) soaking the polyester fabric into the modified nano titanium dioxide hydrosol in a dark place, keeping the temperature at 30-40 ℃ for 20-40 min, and then taking out and drying.
8. The dyeing method of polyester fabric for high-color-fastness luggage fabric according to claim 7, characterized in that the particle size of the nano titanium dioxide particles is not more than 100 nm; the mass ratio of the sesbania powder to the trehalose to the water is 1-3: 0.5-1.5: 100 to 150 parts; the mass ratio of the sesbania powder to the nano titanium dioxide particles to the succinic anhydride to the citric acid is 10: 0.4-1: 1-3: 0.5 to 2.
9. The method for dyeing the polyester fabric for the high-color-fastness luggage fabric according to claim 6, wherein the dyeing post-treatment step of the polyester fabric comprises the following steps: and (3) soaking the dyed polyester fabric into a mixed solution of trifluoroethylene acrylate, acrylamide, citric acid, magnesium acetate and water, heating to 70-80 ℃, preserving heat for 1-3 hours, and then taking out the polyester fabric and drying.
10. The dyeing method of the polyester fabric for the high-color-fastness luggage fabric, according to claim 9, is characterized in that the mass ratio of the trifluoroethylene acrylate, the acrylamide, the citric acid, the magnesium acetate and the water is 5-10: 1-4: 2-5: 0.1-1: 200 to 300.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210405215.6A CN114763678A (en) | 2022-04-18 | 2022-04-18 | Dyeing method of polyester fabric for high-color-fastness luggage fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210405215.6A CN114763678A (en) | 2022-04-18 | 2022-04-18 | Dyeing method of polyester fabric for high-color-fastness luggage fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114763678A true CN114763678A (en) | 2022-07-19 |
Family
ID=82364984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210405215.6A Pending CN114763678A (en) | 2022-04-18 | 2022-04-18 | Dyeing method of polyester fabric for high-color-fastness luggage fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114763678A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102877326A (en) * | 2012-10-15 | 2013-01-16 | 东华大学 | Method for preparing polyester luggage material with light and perspiration fastness |
| CN104878618A (en) * | 2015-05-21 | 2015-09-02 | 互太(番禺)纺织印染有限公司 | Method for dyeing superfine terylene fabric |
| CN105200812A (en) * | 2015-10-20 | 2015-12-30 | 互太(番禺)纺织印染有限公司 | Dyeing process of using dispersal fluorescent dye to dye super-fine polyester elastic fabric |
| CN111350084A (en) * | 2020-03-11 | 2020-06-30 | 嘉兴市天伦纳米染整有限公司 | Terylene four-side elastic high-fastness dyeing processing technology |
| CN112981952A (en) * | 2021-03-02 | 2021-06-18 | 浙江航民股份有限公司 | Method for improving dyeing depth and color fastness of terylene through graft polymerization |
-
2022
- 2022-04-18 CN CN202210405215.6A patent/CN114763678A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102877326A (en) * | 2012-10-15 | 2013-01-16 | 东华大学 | Method for preparing polyester luggage material with light and perspiration fastness |
| CN104878618A (en) * | 2015-05-21 | 2015-09-02 | 互太(番禺)纺织印染有限公司 | Method for dyeing superfine terylene fabric |
| CN105200812A (en) * | 2015-10-20 | 2015-12-30 | 互太(番禺)纺织印染有限公司 | Dyeing process of using dispersal fluorescent dye to dye super-fine polyester elastic fabric |
| CN111350084A (en) * | 2020-03-11 | 2020-06-30 | 嘉兴市天伦纳米染整有限公司 | Terylene four-side elastic high-fastness dyeing processing technology |
| CN112981952A (en) * | 2021-03-02 | 2021-06-18 | 浙江航民股份有限公司 | Method for improving dyeing depth and color fastness of terylene through graft polymerization |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109797574B (en) | High-color-fastness dyeing process for western-style clothes fabric | |
| CN111455700B (en) | Cationic polyester fabric dyeing and finishing method | |
| WO2021136411A1 (en) | Acid low-temperature dip dyeing method for polyamide 56 fiber and fabric | |
| CN111909537B (en) | High-fixation disperse black dye composition, and preparation method and use method thereof | |
| CN104831560A (en) | Chinlon cationic dyeing process | |
| CN114763678A (en) | Dyeing method of polyester fabric for high-color-fastness luggage fabric | |
| CN110258141B (en) | Method for improving fixation rate of reactive dye in alcohol organic solvent-water system | |
| CN111979799A (en) | Dyeing process of polyamide fabric | |
| CN108286198B (en) | Efficient short-process dyeing and finishing process for polyamide knitted fabric by scouring and dyeing one-bath method | |
| KR101199851B1 (en) | Process Of Dyeing Having High Light Fastness For Natural Cellulose/Polyester Blended Textiles | |
| CN110886113B (en) | Disperse dye dyeing method for treating cotton fabric by using waterborne polyurethane | |
| CN109295769B (en) | Preparation method of silk with ultraviolet radiation prevention function | |
| CN111535049B (en) | Inorganic pigment dyeing method for cotton textiles | |
| CN110565369B (en) | Treatment method for improving fastness to soaping and fading of yarn dyed fabric and yarn dyed fabric | |
| US3240553A (en) | Process of conditioning yarn and fabric materials to render them receptive to dyes having affinity for cellulosic materials and such conditioned yarn and fabric materials | |
| CN112878069A (en) | Polyamide fabric dyeing process with high dye-uptake | |
| CN112981989A (en) | Printing and dyeing additive and method for dyeing real silk/viscose composite fabric | |
| CN110886112A (en) | Disperse dye dyeing method of etherified 2D resin modified cotton fabric | |
| CN111979794B (en) | Functional modification method for improving dyeing effect of natural dye alkaline bath for fabric | |
| KR101199850B1 (en) | Process Of Dyeing Having High Light Fastness For Natural Cellulose Textiles | |
| CN110016103B (en) | Modified carboxymethyl starch polymer and preparation method and application thereof | |
| CN109778527A (en) | The processing method of the natural color cotton product of high-efficient and lasting antibacterial functions | |
| CN114808435B (en) | Alkaline finishing method of low-gram-weight polyester colored gauze | |
| CN112359616B (en) | Method for improving light fastness of aramid fiber | |
| CN110041463B (en) | Modified tamarind gum polymer and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |