CN114751644A - Iridescent glaze ink and preparation method thereof - Google Patents
Iridescent glaze ink and preparation method thereof Download PDFInfo
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- CN114751644A CN114751644A CN202210416009.5A CN202210416009A CN114751644A CN 114751644 A CN114751644 A CN 114751644A CN 202210416009 A CN202210416009 A CN 202210416009A CN 114751644 A CN114751644 A CN 114751644A
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- 238000002360 preparation method Methods 0.000 title claims description 16
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 239000002270 dispersing agent Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 13
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- 229910000398 iron phosphate Inorganic materials 0.000 claims abstract description 12
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims abstract description 12
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 229910052656 albite Inorganic materials 0.000 claims abstract description 8
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000002480 mineral oil Substances 0.000 claims description 7
- 235000010446 mineral oil Nutrition 0.000 claims description 7
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 238000005245 sintering Methods 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 3
- AMUTYVGRCVFCCD-UHFFFAOYSA-N 5,6-diaminopyridine-3-carboxylic acid Chemical compound NC1=CC(C(O)=O)=CN=C1N AMUTYVGRCVFCCD-UHFFFAOYSA-N 0.000 claims description 2
- AMEMLELAMQEAIA-UHFFFAOYSA-N 6-(tert-butyl)thieno[3,2-d]pyrimidin-4(3H)-one Chemical compound N1C=NC(=O)C2=C1C=C(C(C)(C)C)S2 AMEMLELAMQEAIA-UHFFFAOYSA-N 0.000 claims description 2
- 229940033357 isopropyl laurate Drugs 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical class CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims 2
- 239000002131 composite material Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 9
- 238000005507 spraying Methods 0.000 abstract description 7
- 239000000976 ink Substances 0.000 description 40
- 239000000919 ceramic Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000498 ball milling Methods 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- UNOGLHIYPXTOGD-UHFFFAOYSA-N isooctyl laurate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC(C)C UNOGLHIYPXTOGD-UHFFFAOYSA-N 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses iridescent glaze ink which comprises the following raw materials in parts by weight: inorganic glaze: 40-50 parts; organic solvent: 30-50 parts; dispersing agent: 4-8 parts; quick-drying auxiliary agent: 0.1-0.5 part; defoaming agent: 0.01-0.1 part; leveling agent: 0.1-0.2 parts; 0-5 parts of pigment; the inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: 40-80 parts of iron phosphate; 10-30 parts of potassium feldspar; 10-20 parts of albite; 1-10 parts of zinc oxide; rare earth metal oxide: 0-10 parts. The iridescent glaze ink can produce better iridescent effect after being matched with a digital glaze spraying technology for glazing.
Description
Technical Field
The invention belongs to the technical field of ceramic glaze materials, and particularly relates to iridescent glaze ink and a preparation method thereof.
Background
With the upgrading of the building ceramic technology, the technology of large-specification and ultrathin ceramic tiles of large slate boards appears, the decoration technical requirements of the ceramic tiles are higher and higher, and the digital glaze spraying technology can be popularized more and replace the traditional glazing mode based on the unique advantages of the digital glaze spraying technology. Along with the development of the digital glaze spraying technology, various related glazes are produced at the same time, and the iridescent glaze is one of the glazes, but after the conventional iridescent glaze is matched with the digital glaze spraying technology for glazing, the iridescent effect on the surface of a product is poor, and the higher and higher decoration requirements of customers cannot be met.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art. Therefore, the invention provides the iridescent glaze ink and the preparation method thereof, and the iridescent glaze ink can generate better iridescent effect after being matched with a digital glaze spraying technology for glazing.
The technical purpose of the invention is realized by the following technical scheme:
the iridescent glaze ink comprises the following raw materials in parts by weight: inorganic glaze: 40-50 parts; organic solvent: 30-50 parts; dispersing agent: 4-8 parts; quick-drying auxiliary agent: 0.1-0.5 part; defoaming agent: 0.01-0.1 part; leveling agent: 0.1-0.2 parts; 0-5 parts of pigment; the inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: 40-80 parts of iron phosphate; 10-30 parts of potassium feldspar; 10-20 parts of albite; 1-10 parts of zinc oxide; rare earth metal oxide: 0-10 parts.
Preferably, the rare earth metal oxide is at least one of cerium oxide and lanthanum oxide.
Preferably, the preparation method of the inorganic glaze is to mix the raw materials of the inorganic glaze, grind, calcine and crush the mixture to obtain the inorganic glaze.
Preferably, the inorganic glaze is calcined by heating to 1150-1200 ℃ at 3-10 ℃/min in an oxidizing atmosphere, and then sintering for 2-4 h.
Preferably, the particle size D90 of the inorganic glaze material is less than 8 μm.
Preferably, the organic solvent is prepared from white mineral oil and an ester solvent according to the weight ratio of (15-30): (15-20).
Preferably, the ester solvent is at least one of isooctyl palmitate and isopropyl laurate.
Preferably, the dispersant is at least one of a polyurethane type dispersant and a polymeric hydrogenated ricinoleic acid dispersant. Such as shanghai three positive CH6, huihong 1068, and Qingdao zhuo 1310.
Preferably, the quick-drying auxiliary agent is at least one of polypropylene glycol, polyoxyethylene ether and propylene glycol polyoxyethylene ether. Such as L61 and L62 of Jiangsu Haian petrochemical production.
Preferably, the defoaming agent is at least one of BYK-066N and BYK-067A.
Preferably, the leveling agent is at least one of BYK-300, BYK-301, BYK-306 and BYK-307.
Preferably, the pigment is a colored ink.
Another object of the present invention is to provide a method for preparing the above iridescent glaze ink, which comprises the following steps:
a method for preparing the iridescent glaze ink comprises the following steps: mixing and grinding the inorganic glaze, the organic solvent, the dispersing agent, the quick-drying auxiliary agent, the defoaming agent and the flatting agent, and then adding the pigment for mixing to obtain the paint.
Preferably, the method comprises the following steps: mixing inorganic glaze, organic solvent, dispersant, quick-drying assistant, defoamer and leveling agent, grinding until the particle size D90 is less than 1 mu m, and then adding pigment and mixing to obtain the paint.
The invention has the beneficial effects that:
the iridescent glaze ink can be directly matched with a digital glaze spraying technology to carry out glazing on the surface of the ceramic tile, and the glossiness of the glazed ceramic tile surface ranges from 25 degrees to 80 degrees, so that good glittering and iridescent effects can be produced, and a good decorative decoration effect is achieved on buildings.
Detailed Description
The present invention will be further described with reference to the following specific examples.
Example 1:
the red iridescent glaze ink comprises the following raw materials in parts by weight: inorganic glaze: 45 parts of (1); white mineral oil: 30 parts of (1); isooctyl laurate: 20 parts of a binder; dispersant CH 6: 4.5 parts; leveling agent BYK-306: 0.2 part; quick-drying auxiliary agent L61: 0.3 part; defoaming agent BYK-066N: 0.01 part. The inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: iron phosphate: 50 parts of a mixture; 20 parts of potassium feldspar; 20 parts of albite; 5 parts of zinc oxide; 5 parts of cerium oxide.
The preparation method of the inorganic glaze comprises the following steps:
(1) mixing the raw materials of the inorganic glaze uniformly, and ball-milling;
(2) and (2) heating the material obtained in the step (1) to 1200 ℃ at the speed of 5 ℃/min in an oxidizing atmosphere, then sintering for 3h, and then crushing until the particle size D90 is less than 8 mu m to obtain the material.
The preparation method of the red iridescent glaze ink. The method comprises the following steps:
(1) mixing inorganic glaze, organic solvent, dispersant, quick-drying assistant, defoamer and flatting agent, and grinding until the particle size D90 is less than 1 mu m.
Example 2:
the golden brown iridescent glaze ink comprises the following raw materials in parts by weight: inorganic glaze: 45 parts of (1); white mineral oil: 30 parts of (1); isooctyl laurate: 20 parts of (1); dispersant CH 6: 4.5 parts; leveling agent BYK-306: 0.2 part; quick-drying assistant L61: 0.2 part; defoaming agent BYK-066N: 0.1 part; golden brown ink: 5 parts of the raw materials. The inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: iron phosphate: 50 parts of a binder; 25 parts of potassium feldspar; 20 parts of albite; 5 parts of zinc oxide.
The preparation method of the inorganic glaze comprises the following steps:
(1) mixing the raw materials of the inorganic glaze uniformly, and ball-milling;
(2) and (2) heating the material obtained in the step (1) to 1200 ℃ at the speed of 5 ℃/min in an oxidizing atmosphere, then sintering for 3h, and then crushing until the particle size D90 is less than 8 mu m to obtain the nano-particles.
The preparation method of the golden brown iridescent glaze ink. The method comprises the following steps:
(1) mixing inorganic glaze, organic solvent, dispersant, quick-drying assistant, defoamer and flatting agent, grinding to particle size D90 less than 1 μm,
(2) and (2) adding golden brown ink into the material obtained in the step (1) and mixing to obtain the ink.
Example 3:
golden yellow iridescent glaze ink comprises the following raw materials in parts by weight: inorganic glaze: 45 parts of (1); white mineral oil: 30 parts of (1); isooctyl laurate: 20 parts of (1); dispersant CH 6: 4.5 parts; leveling agent BYK-306: 0.2 part; quick-drying assistant L61: 0.2 part; defoaming agent BYK-066N: 0.1 part; coating yellow ink: 5 parts of the raw materials. The inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: iron phosphate: 60 parts; 20 parts of potassium feldspar; 15 parts of albite; 5 parts of zinc oxide.
The preparation method of the inorganic glaze comprises the following steps:
(1) mixing the raw materials of the inorganic glaze uniformly, and then carrying out ball milling;
(2) and (2) heating the material obtained in the step (1) to 1200 ℃ at the speed of 5 ℃/min in an oxidizing atmosphere, then sintering for 3h, and then crushing until the particle size D90 is less than 8 mu m to obtain the nano-particles.
The preparation method of the golden yellow iridescent glaze ink. The method comprises the following steps:
(1) mixing inorganic glaze, organic solvent, dispersant, quick-drying assistant, defoaming agent and leveling agent, grinding until the grain diameter D90 is less than 1 μm,
(2) and (2) adding the coated yellow ink into the material obtained in the step (1) and mixing to obtain the coating yellow ink.
Example 4:
a blue iridescent glaze ink comprises the following raw materials in parts by weight: inorganic glaze: 45 parts of (1); white mineral oil: 30 parts of a binder; isooctyl laurate: 20 parts of a binder; dispersant CH 6: 4.5 parts; leveling agent BYK-306: 0.2 part; quick-drying assistant L61: 0.2 part; defoaming agent BYK-066N: 0.1 part; cobalt blue ink: 5 parts of the raw materials. The inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: iron phosphate: 60 parts; 20 parts of potassium feldspar; 15 parts of albite; 5 parts of zinc oxide.
The preparation method of the inorganic glaze comprises the following steps:
(1) mixing the raw materials of the inorganic glaze uniformly, and ball-milling;
(2) and (2) heating the material obtained in the step (1) to 1200 ℃ at the speed of 5 ℃/min in an oxidizing atmosphere, then sintering for 3h, and then crushing until the particle size D90 is less than 8 mu m to obtain the material.
A preparation method of the blue iridescent glaze ink. The method comprises the following steps:
(1) mixing inorganic glaze, organic solvent, dispersant, quick-drying assistant, defoaming agent and leveling agent, grinding until the grain diameter D90 is less than 1 μm,
(2) and (3) adding cobalt blue ink into the material obtained in the step (1) and mixing to obtain the cobalt blue ink.
Example 5:
the black iridescent glaze ink comprises the following raw materials in parts by weight: inorganic glaze: 45 parts of (1); white mineral oil: 30 parts of (1); isooctyl laurate: 20 parts of a binder; dispersant CH 6: 4.5 parts; leveling agent BYK-306: 0.2 part; quick-drying auxiliary agent L61: 0.2 part; defoaming agent BYK-066N: 0.1 part; cobalt black ink: 5 parts of the raw materials. The inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze: iron phosphate: 60 parts; 20 parts of potassium feldspar; 15 parts of albite; 5 parts of zinc oxide.
The preparation method of the inorganic glaze comprises the following steps:
(1) mixing the raw materials of the inorganic glaze uniformly, and ball-milling;
(2) and (2) heating the material obtained in the step (1) to 1200 ℃ at the speed of 5 ℃/min in an oxidizing atmosphere, then sintering for 3h, and then crushing until the particle size D90 is less than 8 mu m to obtain the material.
A preparation method of the black iridescent glaze ink. The method comprises the following steps:
(1) mixing inorganic glaze, organic solvent, dispersant, quick-drying assistant, defoamer and flatting agent, grinding to particle size D90 less than 1 μm,
(2) and (3) adding cobalt black ink into the material obtained in the step (1) and mixing to obtain the cobalt black ink.
Comparative example 1:
an ink was different from example 1 in that the inorganic glaze composition of comparative example 1 was only iron phosphate, and the rest was identical to example.
Comparative example 2:
an ink was different from example 1 in that the inorganic glaze composition of comparative example 1 did not contain iron phosphate, and the rest was identical to example.
Test example:
the performance tests of the iridescent glaze inks of examples 1 to 5 were carried out, the test results are shown in table 1, and the inks of examples 1 to 5 and comparative examples 1 to 2 were digitally printed on the surface of the tile, and fired into a finished product, and the gloss and iridescent effect of the surface of the tile were observed.
Table 1: results of performance testing of iridescent glaze inks of examples 1-5
As can be seen from Table 1, the iridescent glaze ink provided by the invention can meet the requirements of digital printing, and meanwhile, through observation, after the iridescent glaze ink provided by the invention is printed on the surface of a ceramic tile, the glossiness of the surface of the ceramic tile ranges from 25 degrees to 80 degrees, and the brightness flash can fluctuate back and forth at different angles, so that better brightness flash and iridescent effects can be generated, after the ink provided by the comparative examples 1-2 is printed on the surface of the ceramic tile, the brightness flash and iridescent effects do not exist due to the fact that the content of iron phosphate is too high or the iron phosphate is not contained, the brightness flash effect is caused by the fact that iron oxide crystals are separated out from glaze ink at high temperature, a certain melting environment is needed, and the brightness flash and different colors are combined to generate the iridescent effect.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (10)
1. An iridescent glaze ink characterized by: the composite material comprises the following raw materials in parts by weight:
inorganic glaze: 40-50 parts;
organic solvent: 30-50 parts;
dispersing agent: 4-8 parts;
quick-drying auxiliary agent: 0.1-0.5 part;
defoaming agent: 0.01-0.1 part;
leveling agent: 0.1-0.2 parts;
0-5 parts of pigment;
the inorganic glaze comprises the following raw materials in parts by weight based on the total weight of the inorganic glaze:
40-80 parts of iron phosphate;
10-30 parts of potassium feldspar;
10-20 parts of albite;
1-10 parts of zinc oxide;
rare earth metal oxide: 0-10 parts.
2. An iridescent glaze ink according to claim 1, wherein: the preparation method of the inorganic glaze comprises the steps of mixing the raw materials of the inorganic glaze, grinding, calcining and crushing to obtain the inorganic glaze.
3. An iridescent glaze ink according to claim 2, wherein: the calcining method of the inorganic glaze material comprises the steps of heating to 1150-1200 ℃ at the speed of 3-10 ℃/min under the oxidizing atmosphere, and then sintering for 2-4 h.
4. An iridescent glaze ink as claimed in claim 1, wherein: the particle size D90 of the inorganic glaze is less than 8 mu m.
5. An iridescent glaze ink according to claim 1, wherein: the organic solvent is prepared from white mineral oil and an ester solvent according to the weight ratio of (15-30): (15-20).
6. An iridescent glaze ink according to claim 5, wherein: the ester solvent is at least one of isooctyl palmitate and isopropyl laurate.
7. An iridescent glaze ink according to claim 1, wherein: the dispersant is at least one of polyurethane type dispersant and polymerized hydrogenated ricinoleic acid dispersant.
8. An iridescent glaze ink according to claim 1, wherein: the method is characterized in that: the quick-drying auxiliary agent is at least one of polypropylene glycol, polyoxyethylene ether and propylene glycol polyoxyethylene ether.
9. An iridescent glaze ink according to claim 1, wherein: the leveling agent is at least one of BYK-300, BYK-301, BYK-306 and BYK-307.
10. A method of preparing an iridescent glaze ink according to any one of claims 1 to 9, wherein: the method comprises the following steps: mixing and grinding the inorganic glaze, the organic solvent, the dispersing agent, the quick-drying auxiliary agent, the defoaming agent and the flatting agent, and then adding the pigment for mixing to obtain the paint.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210416009.5A CN114751644B (en) | 2022-04-20 | 2022-04-20 | Iridescent glaze ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210416009.5A CN114751644B (en) | 2022-04-20 | 2022-04-20 | Iridescent glaze ink and preparation method thereof |
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| CN114751644A true CN114751644A (en) | 2022-07-15 |
| CN114751644B CN114751644B (en) | 2023-11-03 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116178050A (en) * | 2022-09-07 | 2023-05-30 | 佛山市东鹏陶瓷有限公司 | Preparation method of glaze with flash dry grain effect, brick and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007284279A (en) * | 2006-04-14 | 2007-11-01 | Inax Corp | Decorated ceramic article, method for manufacturing the same, and ink for inkjet |
| CN103224726A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Glaze ink with leather pattern effect for ceramic jet printing and preparation method thereof |
| CN103224724A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Metal glaze printing ink for ceramic ink-jet printing and preparation method thereof |
| CN107216716A (en) * | 2017-07-11 | 2017-09-29 | 佛山市华力达材料科技有限公司 | A kind of metallic ink and preparation method thereof |
| CN108863077A (en) * | 2018-08-10 | 2018-11-23 | 张家港市六福新材料科技有限公司 | A kind of preparation method of ceramet glaze |
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| JP2007284279A (en) * | 2006-04-14 | 2007-11-01 | Inax Corp | Decorated ceramic article, method for manufacturing the same, and ink for inkjet |
| CN103224726A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Glaze ink with leather pattern effect for ceramic jet printing and preparation method thereof |
| CN103224724A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Metal glaze printing ink for ceramic ink-jet printing and preparation method thereof |
| CN107216716A (en) * | 2017-07-11 | 2017-09-29 | 佛山市华力达材料科技有限公司 | A kind of metallic ink and preparation method thereof |
| CN108863077A (en) * | 2018-08-10 | 2018-11-23 | 张家港市六福新材料科技有限公司 | A kind of preparation method of ceramet glaze |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116178050A (en) * | 2022-09-07 | 2023-05-30 | 佛山市东鹏陶瓷有限公司 | Preparation method of glaze with flash dry grain effect, brick and application thereof |
| CN116178050B (en) * | 2022-09-07 | 2024-01-05 | 佛山市东鹏陶瓷有限公司 | Preparation method of glaze with flash dry grain effect, brick and application thereof |
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| CN114751644B (en) | 2023-11-03 |
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