CN114717040B - Energy-saving vehicle gear oil composition - Google Patents
Energy-saving vehicle gear oil composition Download PDFInfo
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- CN114717040B CN114717040B CN202110011725.0A CN202110011725A CN114717040B CN 114717040 B CN114717040 B CN 114717040B CN 202110011725 A CN202110011725 A CN 202110011725A CN 114717040 B CN114717040 B CN 114717040B
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- gear oil
- vehicle gear
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- energy
- oil composition
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- 239000012208 gear oil Substances 0.000 title claims abstract description 66
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 13
- 239000002199 base oil Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000008139 complexing agent Substances 0.000 claims abstract description 7
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 5
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 72
- 229920002367 Polyisobutene Polymers 0.000 claims description 56
- 229960002317 succinimide Drugs 0.000 claims description 36
- -1 amide boric acid ester Chemical class 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 18
- 229910052698 phosphorus Inorganic materials 0.000 claims description 18
- 239000011574 phosphorus Substances 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 12
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 239000011733 molybdenum Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000012990 dithiocarbamate Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 150000008301 phosphite esters Chemical class 0.000 claims description 5
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- BVXOPEOQUQWRHQ-UHFFFAOYSA-N dibutyl phosphite Chemical compound CCCCOP([O-])OCCCC BVXOPEOQUQWRHQ-UHFFFAOYSA-N 0.000 claims description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 4
- 229920000193 polymethacrylate Polymers 0.000 claims description 4
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 4
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 3
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- TZGPACAKMCUCKX-UHFFFAOYSA-N 2-hydroxyacetamide Chemical compound NC(=O)CO TZGPACAKMCUCKX-UHFFFAOYSA-N 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- HDIBKVVPMJKRGL-UHFFFAOYSA-N bis(2-ethylhexyl) hydrogen phosphite Chemical compound CCCCC(CC)COP(O)OCC(CC)CCCC HDIBKVVPMJKRGL-UHFFFAOYSA-N 0.000 claims description 2
- QBCOASQOMILNBN-UHFFFAOYSA-N didodecoxy(oxo)phosphanium Chemical compound CCCCCCCCCCCCO[P+](=O)OCCCCCCCCCCCC QBCOASQOMILNBN-UHFFFAOYSA-N 0.000 claims description 2
- BAKDLAFAVHBXHW-UHFFFAOYSA-N dioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP([O-])OCCCCCCCCCCCCCCCCCC BAKDLAFAVHBXHW-UHFFFAOYSA-N 0.000 claims description 2
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 claims description 2
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 2
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920013639 polyalphaolefin Polymers 0.000 claims description 2
- 125000005040 tridecenyl group Chemical group C(=CCCCCCCCCCCC)* 0.000 claims description 2
- 125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 claims description 2
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 3
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract description 16
- 230000003647 oxidation Effects 0.000 abstract description 9
- 238000007254 oxidation reaction Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 35
- 238000012360 testing method Methods 0.000 description 27
- 230000000052 comparative effect Effects 0.000 description 9
- 230000001603 reducing effect Effects 0.000 description 6
- 238000004134 energy conservation Methods 0.000 description 5
- 238000011056 performance test Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/123—Reaction products obtained by phosphorus or phosphorus-containing compounds, e.g. P x S x with organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
- C10M2227/062—Cyclic esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/09—Complexes with metals
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
The invention relates to an energy-saving vehicle gear oil composition, which comprises the following components: (A) antiwear composite ashless dispersant: 0.5 to 5 weight portions; (B) a composite energy-saving additive: 1 to 5 parts by weight; (C) a vehicle gear oil complexing agent: 1 to 10 parts by weight; (D) a viscosity index improver: 1 to 15 parts by weight; (E) pour point depressant: 0.1 to 2 parts by weight; (F) base oil: 75-95 parts by weight. The vehicle gear oil composition provided by the invention has the advantages of low friction coefficient, excellent extreme pressure wear resistance, thermal oxidation stability and better energy-saving effect, and compared with common vehicle gear oil, the vehicle gear oil composition has the advantages of obviously prolonged service life, obviously improved transmission efficiency and realization of energy-saving and environment-friendly purposes. The invention also relates to a preparation method of the energy-saving vehicle gear oil composition.
Description
Technical Field
The invention belongs to the technical field of lubricating oil and lubricating oil additives, and particularly relates to an energy-saving vehicle gear oil composition.
Background
Under the large trend of energy conservation and emission reduction, the automobile industry focuses on research on an engine assembly, but with continuous excavation of energy conservation potential of the engine, the difficulty and cost of continuous lifting are increasingly increased. Therefore, the research on the fuel-saving performance of the transmission system improves the schedule and becomes an important ring of the whole vehicle development link.
At present, gear oil adopted by a main stream vehicle transmission system in the market still emphasizes performance requirements, and great attention is not paid to energy conservation. Along with the continuous improvement of requirements on energy conservation, environmental protection, fuel economy and the like, higher requirements are put forward on the driving axle oil products. By reducing friction loss of gear shifting gears and bearing gear transmission, the transmission efficiency of a gear system can be improved. The energy saving effect of vehicle gear oils is often very relevant to the design of the formulation system, in particular the choice of additives.
Disclosure of Invention
Based on the foregoing, an object of the present invention is to provide an energy-saving vehicle gear oil composition. Compared with the common GL-5 heavy-load vehicle gear oil, the energy-saving vehicle gear oil composition provided by the invention has better extreme pressure abrasion resistance, thermal oxidation stability and energy-saving performance, and compared with a common product, the life is obviously prolonged, and the transmission efficiency is obviously improved.
To this end, the invention provides an energy efficient vehicle gear oil composition comprising the following components:
(A) Antiwear composite ashless dispersant: 0.5 to 5 weight portions;
(B) Composite energy-saving additive: 1 to 5 parts by weight;
(C) Vehicle gear oil complexing agent: 1 to 10 parts by weight;
(D) Viscosity index improver: 1 to 15 parts by weight;
(E) Pour point depressant: 0.1 to 2 parts by weight;
(F) Base oil: 75-95 parts by weight.
2. The energy efficient vehicle gear oil composition according to claim 1, comprising the following components:
(A) Antiwear composite ashless dispersant: 1 to 5 parts by weight;
(B) Composite energy-saving additive: 2-5 parts by weight;
(C) Vehicle gear oil complexing agent: 2-10 parts by weight;
(D) Viscosity index improver: 5-15 parts by weight;
(E) Pour point depressant: 0.3 to 2 parts by weight;
(F) Base oil: 80-95 parts by weight.
3. The energy-saving vehicle gear oil composition according to claim 1, wherein the component (a) is a composition of polyisobutylene succinimide and phospho-boronated polyisobutylene succinimide, and the mass ratio of polyisobutylene succinimide to phospho-boronated polyisobutylene succinimide is 3-5:1.
4. The energy efficient vehicle gear oil composition according to claim 3, wherein the selected polyisobutylene succinimide is a polymeric mono-hung polyisobutylene succinimide having the structural formula:
wherein PIB is polyisobutene, the molecular weight of the polyisobutene is 1500-3000, and n is a positive integer greater than 4.
5. An energy efficient vehicle gear oil composition according to claim 3, characterized in that the phosphated polyisobutylene succinimide is a singly or doubly phosphated polyisobutylene succinimide, preferably a singly phosphated polyisobutylene succinimide.
6. The energy efficient vehicle gear oil composition according to claim 5, wherein the mono-hung boronated polyisobutylene succinimide is prepared by the following process:
(1) Uniformly stirring base oil and low-molecular polyisobutylene maleic anhydride in a reaction kettle, slowly adding tetraethylenepentamine, then heating to 130-140 ℃ for reaction for 2-4 hours, and cooling;
(2) Sequentially adding boric acid and a phosphorus-containing compound, stirring uniformly, heating to 150-160 ℃, reacting for 4-6 hours, and filtering to obtain singly-hung phosphorus boride polyisobutene succinimide;
wherein the phosphorus-containing compound is selected from at least one of phosphoric acid, phosphorous acid, phosphorus pentoxide, phosphoric acid esters and phosphorous acid esters, preferably phosphorous acid, dibutyl phosphite or diethyl phosphite.
7. The energy-saving vehicle gear oil composition according to claim 1, wherein the component (B) is a composite of molybdenum alkyl dithiocarbamate, alkyl acid phosphite and amide borate, and the mass ratio of the molybdenum alkyl dithiocarbamate, the alkyl phosphite to the amide borate is 2-4:1-2:1; preferably, the alkyl acid phosphite is selected from at least one of di (2-ethylhexyl) phosphite, dilauryl phosphite and dioctadecyl phosphite.
8. The energy efficient vehicle gear oil composition according to claim 7 wherein the molybdenum alkyl dithiocarbamate is a complex of molybdenum dialkyl dithiocarbamate with a fatty amine having the structure:
wherein R is 1 、R 2 、R 3 、R 4 Each independently is C 4 ～C 14 Straight-chain or branched alkyl, R 1 And R is 2 Identical or different, preferably R 1 And R is 2 N-ethyl, n-butyl, n-hexyl, n-octyl, isooctyl or dodecyl, respectively, R 3 And R is 3 Identical or different, preferably R 3 And R is 3 N-octyl, isooctyl, dodecyl or tridecyl, respectively.
9. The amide borate of claim 7 wherein the amide borate is an alk (en) yl glycol amide borate having the structure:
wherein R is C 11 ～C 18 Preferably R is undecyl, tridecyl, pentadecyl, heptadecyl, undecenyl, tridecenyl, pentadecenyl or heptadecenyl.
10. The energy efficient vehicle gear oil composition according to claim 1, wherein component (C) is a gear oil complexing agent meeting the specification of GB13895-2018 GL-5 heavy duty vehicle gear oil, preferably component (D) is a dispersed polymethacrylate, preferably component (E) is a polyacrylate, a polymethacrylate or a wax-cleaved polyalphaolefin.
Therefore, the invention also provides a preparation method of the energy-saving vehicle gear oil composition, which comprises the following steps: and sequentially adding the component (A), the component (B), the component (C), the component (D), the component (E) and the component (F) into a blending kettle, heating to 60-70 ℃, and fully stirring for at least 2-3 hours until the composition is completely dissolved, thus obtaining the energy-saving vehicle gear oil.
The beneficial effects of the invention are as follows:
(1) The antiwear composite ashless dispersant is compounded by polyisobutylene succinimide and borophosphate polyisobutylene succinimide according to a certain proportion, and has good extreme pressure antiwear property while ensuring good high-temperature detergency of oil products.
(2) The composite energy-saving additive is formed by compounding molybdenum alkyl dithiocarbamate, alkyl acid phosphite ester and amide borate according to a certain proportion, wherein the amide borate has good antifriction performance under low-temperature working conditions, the molybdenum alkyl dithiocarbamate has good antifriction performance under high-temperature working conditions, the alkyl acid phosphite ester has good antifriction performance under high-speed heavy-load working conditions, and the three additives are compounded to ensure that an oil product has lasting energy-saving antifriction effect under various working conditions.
(3) The antiwear composite ashless dispersant and the composite energy-saving additive cooperate to ensure that an oil product has better extreme pressure antiwear property, thermal oxidation stability and energy-saving property, obviously prolongs the service life, obviously improves the transmission efficiency and achieves the aims of energy conservation and environmental protection.
In summary, compared with the heavy-load vehicle gear oil with the common GL-5 specification, the antiwear composite ashless dispersant provided by the invention is formed by compositing polyisobutylene succinimide and borophosphate polyisobutylene succinimide, so that the oil product has good extreme pressure antiwear property and good high-temperature detergency. The composite energy-saving additive in the composition is formed by compositing molybdenum alkyl dithiocarbamate, alkyl acid phosphite ester and amide borate, so that the friction coefficient of an oil product is reduced, the friction reducing performance of the amide borate is good under a low-temperature working condition, the friction reducing performance of the molybdenum alkyl dithiocarbamate is good under a high-temperature working condition, the friction reducing performance of the alkyl acid phosphite ester is good under a high-speed heavy-load working condition, and the three additives are compounded to ensure that the oil product has lasting energy-saving friction reducing effect under various working conditions. The antiwear composite ashless dispersant and the composite energy-saving additive cooperate to ensure that the oil product has better extreme pressure antiwear property, thermal oxidation stability and energy-saving performance, and compared with common products, the service life is obviously prolonged, and the transmission efficiency is obviously improved.
Detailed Description
The following describes embodiments of the present invention in detail: the present example is implemented on the premise of the technical scheme of the present invention, and detailed implementation modes and processes are given, but the protection scope of the present invention is not limited to the following examples, and experimental methods without specific conditions are not noted in the following examples, and generally according to conventional conditions.
The testing method comprises the following steps:
GB/T5906 copper sheet corrosion test method for Petroleum products
NB SH/T0518 method for evaluating bearing capacity of vehicle gear oil L-37
NB SH/T0519 method for evaluating scratch resistance of Gear oil for vehicle (L-42 method)
NB SH/T0517 method for evaluating rust inhibitive performance of Gear oil for vehicles L-33-1
SH/T0755 method for evaluating thermal oxidation stability of Manual Transmission oil and rear axle oil (L-60-1 method)
SRV4 high-frequency reciprocating linear vibration testing machine test
And (3) testing by adopting an SRV4 high-frequency reciprocating linear vibration testing machine under a constant condition by using an upper test piece copper disc and a lower test piece copper disc which are in surface-to-surface contact, and measuring the friction factor of an oil product. The test conditions were: load 300N, frequency 50HZ, time 2h, temperature 50 ℃, travel 1mm.
FZG gear machine temperature rise test
Adopting an FZG gear machine temperature rise test, setting the FZG test machine as the highest load and the lowest rotating speed, namely the rotating speed of the gear is 100r/min, the tooth surface load is 15826N, and the tooth surface contact stress is 1841N/mm 2 The initial oil temperature was 40℃and the time was 10 hours, and the oil temperature was measured after the test was completed.
FZG transmission efficiency test.
And carrying out transmission efficiency test on an FZG efficiency test bed by adopting a FVA345 test method, wherein the FZG test bed is used for measuring the power loss of gear oil and the efficiency evaluation of the gear oil under the working conditions of no-load, load bearing and limited friction loss, and can carry out comparison analysis of the transmission efficiency of test oil and reference oil.
(II) reference oil
The reference oil 1 (GL-5 80W-90) is heavy-duty vehicle gear oil produced by China petroleum lubrication oil company, the reference oil 2 (GL-5 80W-90) is shell heavy-duty vehicle gear oil, and the oil products are all commercial products.
(III) specific examples and comparative examples
Example 1
The energy-saving vehicle gear oil composition of the embodiment comprises the following components in parts by mass:
TABLE 1
Wherein, the structural formula of the macromolecule single-hung polyisobutylene succinimide (component A1) is as follows:
wherein PIB is polyisobutylene, the molecular weight of the polyisobutylene is 2700, and n is a positive integer greater than 4.
Wherein, the single-hung phosphorus boride polyisobutylene succinimide (component A2) is prepared by the following method:
(1) After uniformly stirring the VHVI4 base oil and the polyisobutylene maleic anhydride with the number average molecular weight of 1350 in a reaction kettle, slowly adding tetraethylenepentamine, then heating to 140 ℃, reacting for 2 hours, and cooling;
(2) Sequentially adding boric acid and a phosphorus-containing compound, stirring uniformly, heating to 150 ℃, reacting for 5 hours, and filtering to obtain singly-hung phosphorus boride polyisobutene succinimide;
wherein the phosphorus-containing compound is dibutyl phosphite.
And sequentially adding the component (A1), the component (A2), the component (B1), the component (B2), the component (B3), the component (C), the component (D), the component (E) and the component (F) into a blending kettle, heating to 60 ℃, and fully stirring for at least 2 hours until the composition is completely dissolved, thus obtaining the energy-saving vehicle gear oil.
Example 2
The energy-saving vehicle gear oil composition of the embodiment comprises the following components in parts by mass:
TABLE 2
Wherein, the structural formula of the macromolecule single-hung polyisobutylene succinimide (component A1) is as follows:
wherein PIB is polyisobutylene, the molecular weight of the polyisobutylene is 2700, and n is a positive integer greater than 4.
Wherein, the single-hung phosphorus boride polyisobutylene succinimide (component A2) is prepared by the following method:
(1) Uniformly stirring HVIP6 base oil and polyisobutene maleic anhydride with the number average molecular weight of 1100 in a reaction kettle, slowly adding tetraethylenepentamine, then heating to 140 ℃, reacting for 2 hours, and cooling;
(2) Sequentially adding boric acid and a phosphorus-containing compound, stirring uniformly, heating to 160 ℃, reacting for 4 hours, and filtering to obtain singly-hung phosphorus boride polyisobutene succinimide;
wherein the phosphorus-containing compound is diethyl phosphite.
And sequentially adding the component (A1), the component (A2), the component (B1), the component (B2), the component (B3), the component (C), the component (D), the component (E) and the component (F) into a blending kettle, heating to 65 ℃, and fully stirring for at least 2 hours until the composition is completely dissolved, thus obtaining the energy-saving vehicle gear oil.
Example 3
The energy-saving vehicle gear oil composition comprises the following raw materials in parts by weight:
TABLE 3 Table 3
Wherein, the structural formula of the macromolecule single-hung polyisobutylene succinimide (component A1) is as follows:
wherein PIB is polyisobutylene, the molecular weight of the polyisobutylene is 2700, and n is a positive integer greater than 4.
Wherein, the single-hung phosphorus boride polyisobutylene succinimide (component A2) is prepared by the following method:
(1) Uniformly stirring HVIH6 base oil and polyisobutene maleic anhydride with the number average molecular weight of 900 in a reaction kettle, slowly adding tetraethylenepentamine, then heating to 135 ℃ for reaction for 2 hours, and cooling;
(2) Sequentially adding boric acid and a phosphorus-containing compound, stirring uniformly, heating to 155 ℃, reacting for 6 hours, and filtering to obtain singly-hung phosphorus boride polyisobutene succinimide;
wherein the phosphorus-containing compound is dibutyl phosphite.
And sequentially adding the component (A1), the component (A2), the component (B1), the component (B2), the component (B3), the component (C), the component (D), the component (E) and the component (F) into a blending kettle, heating to 65 ℃, and fully stirring for at least 2 hours until the composition is completely dissolved, thus obtaining the energy-saving vehicle gear oil.
Example 4
Example 1, example 2, example 3 and comparative example 1 (reference oil 1), comparative example 2 (reference oil 2) were then subjected to an oxidation resistance test. SH/T0755 (evaluation method of thermal oxidation stability of Manual gearbox oil and rear axle oil (L-60-1 method)) is adopted, the standard test time is 50 hours, the test time is enhanced to 200 hours, and the results are shown in Table 4.
TABLE 4 antioxidant Property test results (SH/T0755) for example 1, example 2, example 3 and comparative example
In Table 4, the other conditions were followed by SH/T0755 and the test time was extended to 200 hours.
As can be seen from Table 4, the energy-saving gear oil of the invention has better oxidation resistance than the reference oil, has good oxidation resistance, is beneficial to reducing the formation of sediment in a drive axle, has longer service life than the reference oil, and can prolong the oil change period.
Example 5
The energy saving performance tests of example 1, example 2, example 3 and comparative examples 1 and 2 were then performed, including SRV4 high frequency reciprocating linear vibration tester test, FZG gear machine temperature rise test, FZG transmission efficiency test.
Table 5 energy saving performance test of example 1, example 2, example 3 and comparative example
As can be seen from the SRV friction coefficient results in Table 5, the energy-saving vehicle gear oils prepared in examples 1-3 of the present invention have lower SRV friction coefficients than the reference oil of the comparative example, indicating that the oil has good energy-saving properties.
From the FZG temperature rise results in table 5, it is shown that the energy-saving vehicle gear oil prepared in examples 1 to 3 of the present invention has a lower oil temperature at the end of the test than the reference oil of the comparative example, indicating that the oil has a higher transmission efficiency, can lower the operating temperature, and reduces the friction loss of the vehicle driving deck.
The FZG transmission efficiency test in Table 5 shows that the energy-saving vehicle gear oil prepared in examples 1-3 of the invention has higher transmission efficiency and can prolong the service life of the oil product compared with the reference oil prepared in comparative examples.
Example 6
The oil performance test was performed for example 3 and the results are given in the following table:
TABLE 6 results of Performance test of example 3
The results in Table 6 show that the energy-saving vehicle gear oil provided by the invention passes through L-37, L-42 and L-33-1 racks required by GB13895-2018 GL-5 specifications and has excellent extreme pressure abrasion resistance.
Of course, the present invention is capable of other various embodiments and its several details are capable of modification and variation in light of the present invention by one skilled in the art without departing from the spirit and scope of the invention.
Claims (13)
1. An energy-saving vehicle gear oil composition is characterized by comprising the following components:
(A) Antiwear composite ashless dispersant: 0.5 to 5 weight portions;
(B) Composite energy-saving additive: 1 to 5 parts by weight;
(C) Vehicle gear oil complexing agent: 1 to 10 parts by weight;
(D) Viscosity index improver: 1 to 15 parts by weight;
(E) Pour point depressant: 0.1 to 2 parts by weight;
(F) Base oil: 75-95 parts by weight;
the component (A) is formed by compounding polyisobutylene succinimide and phosphorous boronated polyisobutylene succinimide, and the mass ratio of the polyisobutylene succinimide to the phosphorous boronated polyisobutylene succinimide is 3-5:1;
the component (B) is formed by compounding molybdenum alkyl dithiocarbamic acid, alkyl acid phosphite ester and amide boric acid ester, and the mass ratio of the molybdenum alkyl dithiocarbamic acid, the alkyl phosphite ester and the amide boric acid ester is 2-4:1-2:1;
the alkyl acid phosphite is selected from at least one of di (2-ethylhexyl) phosphite, dilauryl phosphite and dioctadecyl phosphite.
2. The energy efficient vehicle gear oil composition according to claim 1, consisting of:
(A) Antiwear composite ashless dispersant: 1 to 5 parts by weight;
(B) Composite energy-saving additive: 2-5 parts by weight;
(C) Vehicle gear oil complexing agent: 2-10 parts by weight;
(D) Viscosity index improver: 5-15 parts by weight;
(E) Pour point depressant: 0.3 to 2 parts by weight;
(F) Base oil: 80-95 parts by weight.
3. The energy efficient vehicle gear oil composition according to claim 1, wherein the selected polyisobutylene succinimide is a polymeric mono-hung polyisobutylene succinimide having the structural formula:
wherein PIB is polyisobutene, the molecular weight of the polyisobutene is 1500-3000, and n is a positive integer greater than 4.
4. The energy efficient vehicle gear oil composition according to claim 1, wherein the borophospho-polyisobutylene succinimide is a single or double pendant borophospho-polyisobutylene succinimide.
5. The energy efficient vehicle gear oil composition according to claim 4 wherein the borophospho-polyisobutylene succinimide is a mono-hung borophospho-polyisobutylene succinimide.
6. The energy efficient vehicle gear oil composition according to claim 4, wherein the mono-hung boronated polyisobutylene succinimide is prepared by the following process:
(1) Uniformly stirring base oil and low-molecular polyisobutylene maleic anhydride in a reaction kettle, slowly adding tetraethylenepentamine, then heating to 130-140 ℃ for reaction for 2-4 hours, and cooling;
(2) Sequentially adding boric acid and a phosphorus-containing compound, stirring uniformly, heating to 150-160 ℃, reacting for 4-6 hours, and filtering to obtain singly-hung phosphorus boride polyisobutene succinimide;
wherein the phosphorus-containing compound is selected from at least one of phosphoric acid, phosphorous acid, phosphorus pentoxide, phosphoric acid esters and phosphites.
7. The energy efficient vehicle gear oil composition according to claim 6, wherein the phosphorous-containing compound is phosphorous acid, dibutyl phosphite or diethyl phosphite.
8. The energy efficient vehicle gear oil composition according to claim 1, wherein the molybdenum alkyl dithiocarbamate is a complex of molybdenum dialkyl dithiocarbamate with a fatty amine, having the structure:
wherein R is 1 、R 2 、R 3 、R 4 Each independently is C 4 ～C 14 Straight-chain or branched alkyl, R 1 And R is 2 Identical or different, R 3 And R is 4 The same or different.
9. The energy efficient vehicle gear oil composition according to claim 8, wherein R 1 And R is 2 N-ethyl, n-butyl, n-hexyl, n-octyl, isooctyl or dodecyl, respectively; r is R 3 And R is 4 N-octyl, isooctyl, dodecyl or tridecyl, respectively.
10. The energy efficient vehicle gear oil composition according to claim 1, wherein the amide borate is an alk (en) yl glycol amide borate having the structure:
wherein R is C 11 ～C 18 Alkyl or alkenyl groups of (a).
11. The energy efficient vehicle gear oil composition according to claim 10, wherein R is undecyl, tridecyl, pentadecyl, heptadecyl, undecenyl, tridecenyl, pentadecenyl or heptadecenyl.
12. The energy efficient vehicle gear oil composition according to claim 1, wherein component (C) is a gear oil complexing agent meeting the specification of GB13895-2018 GL-5 heavy duty vehicle gear oil, component (D) is a dispersed polymethacrylate, and component (E) is a polyacrylate, a polymethacrylate or a wax-cleaved polyalphaolefin.
13. A method of preparing the energy efficient vehicle gear oil composition of any one of claims 1-12, comprising the steps of: and sequentially adding the component (A), the component (B), the component (C), the component (D), the component (E) and the component (F) into a blending kettle, heating to 60-70 ℃, and fully stirring for at least 2-3 hours until the composition is completely dissolved, thus obtaining the energy-saving vehicle gear oil.
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| US7229951B2 (en) * | 2001-07-18 | 2007-06-12 | Crompton Corporation | Organo-imido molybdenum complexes as friction modifier additives for lubricant compositions |
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