CN114711056A - Degradable biological dustproof green net - Google Patents

Degradable biological dustproof green net Download PDF

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Publication number
CN114711056A
CN114711056A CN202210339199.5A CN202210339199A CN114711056A CN 114711056 A CN114711056 A CN 114711056A CN 202210339199 A CN202210339199 A CN 202210339199A CN 114711056 A CN114711056 A CN 114711056A
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CN
China
Prior art keywords
green
dustproof
super absorbent
water
degradable
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Pending
Application number
CN202210339199.5A
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Chinese (zh)
Inventor
何亚飞
沈从军
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China National Chemical Engineering Third Construction Co Ltd
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China National Chemical Engineering Third Construction Co Ltd
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Publication date
Application filed by China National Chemical Engineering Third Construction Co Ltd filed Critical China National Chemical Engineering Third Construction Co Ltd
Priority to CN202210339199.5A priority Critical patent/CN114711056A/en
Publication of CN114711056A publication Critical patent/CN114711056A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • A01G9/029Receptacles for seedlings
    • A01G9/0293Seed or shoot receptacles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/20Growth substrates; Culture media; Apparatus or methods therefor based on or containing natural organic material
    • A01G24/22Growth substrates; Culture media; Apparatus or methods therefor based on or containing natural organic material containing plant material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/30Growth substrates; Culture media; Apparatus or methods therefor based on or containing synthetic organic compounds
    • A01G24/35Growth substrates; Culture media; Apparatus or methods therefor based on or containing synthetic organic compounds containing water-absorbing polymers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/40Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure
    • A01G24/44Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure in block, mat or sheet form
    • A01G24/46Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure in block, mat or sheet form multi-layered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B15/00Preventing escape of dirt or fumes from the area where they are produced; Collecting or removing dirt or fumes from that area
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/22Materials not provided for elsewhere for dust-laying or dust-absorbing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Cultivation Of Plants (AREA)

Abstract

The invention discloses a degradable biological dustproof green net which comprises a coiled material type mode and a spray type mode, wherein the coiled material type dustproof green net comprises a net cloth structure layer, the net cloth structure layer is made of degradable materials, water-retaining agents, nutritional agents and plant seeds are uniformly distributed in the net cloth structure layer, and the water-retaining agents are super absorbent resin. The spray type dustproof green net is formed by spraying mixed spray on an exposed surface and then drying and expanding, wherein the mixed spray comprises water-retaining agents, nutritional agents, plant seeds and water, and the water-retaining agents are super absorbent resin. The invention replaces a large amount of non-degradable green nets used in modern construction, fundamentally changes the conditions of dust prevention green nets, green surfaces and great pollution on the back, and plays an important role in the development of green buildings and the restoration of ecological gardens in China on the basis of both attractiveness and economy.

Description

Degradable biological dustproof green net
Technical Field
The invention relates to the technical field of dustproof green nets, in particular to a degradable biological dustproof green net.
Background
With the popularization of urban hardening, dirt roads and bare ground in cities become less and less. However, exposed open spaces generated by eliminating part of buildings in urban development or exposed open spaces which cannot be used recently still exist. The existence of bare space must be accompanied by raise dust, air pollution phenomenon, in order to protect the environment, reduces pm2.5, and dustproof green net has obtained wide application, and its fine solution raise dust problem has reduced the influence that the space temporarily can't use peripheral resident.
However, the existing dustproof green nets are all made of non-degradable materials, and are easy to evolve into plastic wastes. The dust-proof green screen is evolved into garbage due to two factors: 1. time factors, long-time wind and sun exposure, serious erosion and serious damage; 2. people can clean the green net and the construction waste together due to human factors, so that time and labor are saved. It can be seen that the existing dustproof green net has a great effect on preventing dust emission, but the existing dustproof green net can not only address the symptoms but also prevent the root causes, and can bring more non-degradable garbage after dust prevention, so that the dust is not compensated, and the foundation of protecting the environment is also abandoned.
The super absorbent resin contains a large number of strong hydrophilic groups such as amino, carboxyl, hydroxyl and the like and a unique three-dimensional network structure, has chelation on metal, and is a novel functional polymer material. The super absorbent resin can rapidly absorb liquid water which is hundreds of times or even thousands of times higher than the self-quality water through hydration, has good water retention capacity at normal temperature, is not easy to lose water even being heated or pressed, and has good stability in light, heat, acid and alkali. Therefore, compared with the traditional water absorption material, the super absorbent resin has the advantages of low crosslinking density, high water absorption expansion, high water retention property, strong absorption to weak alkaline substances, insolubility in water and organic solvents, repeated use and the like. As a novel multifunctional material, the super absorbent resin has wide application in the fields of agriculture, forestry, gardening, health care, building material industry and the like.
The superabsorbent resins can be classified into four major categories according to the source of the raw materials: starches, celluloses, synthetic resins, and organic-inorganic composites: (1) starch-based super absorbent resin: mainly refers to a kind of high molecular material formed by graft copolymerization of starch as skeleton and other monomers, which is the first discovered high water absorption resin kind, and is generally obtained by modifying natural starch. The starch-based super absorbent resin usually takes wheat starch, corn starch, potato starch and the like as basic raw materials, the raw materials are visible everywhere in life, and not only have wide sources and low production cost, but also are biomass and generally can be degraded by microorganisms, so the starch-based super absorbent resin is an environment-friendly material. (2) Cellulose-based super absorbent resin: like starch, cellulose is one of the most widely distributed and abundant biomass raw materials in nature. The natural cellulose molecule contains a large amount of hydrophilic groups, has a rigid flat structure, and is internally provided with a plurality of capillaries, so that the specific surface area of the material can be increased, and the characteristics make the material very suitable for being used as a water absorption material. The cellulose is a natural renewable resource, can be continuously utilized, and has the advantages of no toxicity, degradability, environmental compatibility and the like, so the fiber super absorbent resin has wide application prospect. (3) Synthetic resin-based super absorbent resin: unlike starch-based and cellulose-based super absorbent resins, synthetic resin-based super absorbent resins have a large number of hydrophilic groups and a network structure formed by crosslinking on the molecular chains, so that the material can rapidly absorb water and retain water in the network structure. Petrochemical products bring a large amount of raw materials for the production of the super absorbent resin, and the raw materials are rich and easy to obtain, and are simple and convenient to prepare, such as polyvinyl alcohol, polyacrylic acid, polyacrylamide and the like. The synthetic super absorbent resin has high water absorption rate, but is easily influenced by pH value and salinity, has small gel strength after water absorption, and has poor salt resistance and biodegradability, so that environmental pollution is easily caused after the waste, and the application range of the water absorbent material is greatly limited. The most widely used synthetic super absorbent resin is polyacrylate series, and polyvinyl alcohol series is the next. (4) Organic-inorganic composite super absorbent resin: in order to overcome the problems of complex production process, low gel strength, difficult recycling of synthetic resin super absorbent resin and the like of starch and cellulose super absorbent resin, a new functional group is introduced into natural resin and synthetic resin or the comprehensive performance of the resin is improved by means of blending and the like, so that a degradable, high-performance and multifunctional composite super absorbent resin is obtained, and the development direction of the super absorbent resin is developed. The composite materials can be classified into organic/inorganic composite super absorbent resin and organic/organic composite super absorbent resin according to their kinds.
Therefore, the new material of the super absorbent resin can be applied to the production of the dustproof green screen to solve the problem that the green screen cannot be degraded, and the technical research has not been reported in the field.
Disclosure of Invention
The invention aims to provide a degradable biological dustproof green net, which solves the problem that the green net needs to be covered for dust prevention in mountains, construction sites and the like, and provides a degradable scheme, wherein the novel material and the mixed structure of super absorbent resin are used, so that the requirements of different dustproof periods are met, and the problem of ecological restoration after degradation is solved.
The invention realizes the purpose through the following technical scheme:
the utility model provides a coiled material formula biodegradable biological dustproof green net, includes the screen cloth structural layer, the screen cloth structural layer is made by degradable material, and evenly distributed has water retaining agent, nutritional agent and plant seed in the screen cloth structural layer, and wherein, the water retaining agent is super absorbent resin.
The further improvement is that the degradable material is degradable plastic or super absorbent resin.
In a further improvement, the degradable plastic is one or more of polylactic acid, polybutylene succinate/hexanoate, polyhydroxybutyrate/valerate, polyethylene succinate, polyesteramide, polycaprolactone or a blend with starch.
The further improvement is that the super absorbent resin is selected from starch super absorbent resin or cellulose super absorbent resin.
The further improvement lies in that bulky granules prepared by smashing cattail fiber and degradable coloring agent are distributed in the net cloth structural layer.
The invention also provides a spray type degradable biological dustproof green net which is formed by spraying mixed spray on an exposed surface, drying and expanding, wherein the mixed spray comprises the raw materials of a water-retaining agent, a nutrient, plant seeds and water, and the water-retaining agent is super absorbent resin.
In a further refinement, the spraying means: spraying with two parallel pipes, one spraying water and the other spraying water retaining agent, nutritious agent and plant seed mixture.
The further improvement is that the super absorbent resin is selected from starch super absorbent resin or cellulose super absorbent resin.
The further improvement is that the raw materials of the mixed spray also comprise leavening granules prepared by smashing cattail fiber and degradable coloring agent.
The invention adopts a large amount of water retention agent, especially the application of starch type super absorbent resin and cellulose type super absorbent resin, thereby meeting the strength requirement of the dustproof green net; meanwhile, the water locking capacity is strong, and the ecological environment is quickly restored by creatively changing plant seeds such as high-adaptability grass seeds and tree seeds into greenbelts and bare soil into grass bodies. And the degradable material is adopted, so that the material can be widely used for construction projects in cities and the problem of bare soil coverage in mining.
The invention has the beneficial effects that: the invention replaces a large amount of non-degradable green nets used in modern construction, radically changes the conditions of dust prevention green nets, green surfaces and great back pollution, and plays an important role in the development of green buildings and the restoration of ecological gardens in China on the aspect of both beauty and economy.
The invention provides a coiled material type and spray type green net structure, wherein a nutrient, plant seeds, a degradable net cloth structure layer and a water-retaining agent are creatively mixed by the coiled material type green net to prepare an efficient and attractive biological type degradable green net, the covering of bare soil can be rapidly completed after the laying, the problem can be fundamentally solved by one-step laying, when the plant seeds germinate, one plastic green net is really converted into a layer of ecological lawn, and the coiled material type green net structure and the spray type green net structure play an important role in recovering ecology and reducing environmental pollution. The spray type green net is innovatively paved in a spraying mode, so that the green net forming and paving process is omitted, a large amount of covering cost is saved, the efficiency is improved, gaps after covering can be reduced, the combination effect of the spray type green net and the mountain surface is improved, and the mountain shape is restored; to some mining, conflagration rescue etc, carry out quick ecological restoration to the massif that needs ecological remediation region through the trees seed and the grass and wood seed of sneaking into in the spray, really dye the ground with green, can pin moisture simultaneously, pin the moisture of fire extinction rescue in the conflagration, cover the fire extinguishing fast to the region of catching a fire, make the fire prevention isolation region, the effect is outstanding.
In addition, the invention also adopts bulked granules prepared by crushing the cattail fiber, which can be combined with the water-retaining agent to further enhance the water locking effect and improve the strength, and simultaneously can provide a substrate for plant growth, improve the air permeability of plant seeds and root system environment and promote the growth of the plant seeds.
Drawings
FIG. 1 is a schematic structural diagram of the roll type degradable biological dustproof green net of the invention.
Detailed Description
The present application will now be described in further detail with reference to the drawings, and it should be noted that the following detailed description is given for purposes of illustration only and should not be construed as limiting the scope of the present application, as these numerous insubstantial modifications and variations can be made by those skilled in the art based on the teachings of the present application.
Example 1
The utility model provides a roll material formula biodegradable dustproof green net, includes the screen cloth structural layer, the screen cloth structural layer is made by degradable material, and evenly distributed has water retaining agent, nutritional agent and plant seed in the screen cloth structural layer, and wherein, the water retaining agent is super absorbent resin, and the nutritional agent is by being applicable to the biological nutrition of the plant seed of selecting as the main, and the plant seed can select green plants such as grass, trees. As shown in fig. 1, in the figure, a represents a mesh structure layer, B represents a plant seed, and C represents a water-retaining agent and a nutrient.
In this embodiment, the ratio of each component is not limited, and may be adjusted as needed. The degradation cycle of degradable biological green net is controlled to the thickness of accessible regulation dustproof green net, the proportion of screen cloth structural layer and water-retaining agent, screen cloth structure and the used material of water-retaining agent to reach economic efficient dustproof strategy, the pollution abatement. In the installation process, the degradable biological green net (dustproof covering) is paved, and then water is sprayed.
In this embodiment, the degradable material is degradable plastic or is made by directly pressing super absorbent resin. The degradable plastic is one or more of polylactic acid, polybutylene succinate/hexanoate, polyhydroxybutyrate/pentanoate, polyethylene succinate, polyester acid amine, polycaprolactone or a blend with starch, and other plastic additives can be added to enhance the degradation capability. The super absorbent resin is selected from starch super absorbent resin or cellulose super absorbent resin. Wherein, the starch type high water absorption resin comprises grafted starch, carboxymethylated starch, phosphated starch, starch xanthate and the like, and the cellulose type high water absorption resin comprises grafted cellulose, carboxymethylated cellulose, hydroxypropylated cellulose, xanthated cellosolve and the like.
Preferably, the mesh fabric structural layer is also distributed with bulky granules prepared by pulverizing cattail fiber and degradable coloring agents, such as some natural degradable pigments. The cattail wool fiber particles can be combined with the water-retaining agent, so that the water locking effect is further enhanced, the strength is improved, a matrix can be provided for plant growth, and the air permeability of plant seeds and a root system environment is remarkably improved, and the growth of the plant seeds is promoted. Tests show that compared with the situation that the cattail wool fiber particles are not added, the strength of the cattail wool fiber particles added is improved by about 22 percent (by a tensile strength meter), and the plant growth speed and the covering effect are obviously improved.
Example 2
The spray type degradable biological dustproof green net is formed by spraying mixed spray on exposed surfaces (bare soil, mountain bodies and the like) and then drying and expanding, wherein the raw materials of the mixed spray comprise a water-retaining agent, a nutrient, plant seeds and water, and the water-retaining agent is super absorbent resin. When in spraying, two parallel pipelines are used for spraying, wherein one pipeline sprays water, the other pipeline sprays the mixture of the water-retaining agent, the nutritional agent and the plant seeds, and the degradable biological green net can expand and cover by adjusting the aperture and the pressure of water flow.
Can be used for fire barriers of forests, grasslands, urban buildings and the like by changing the mixing ratio. Through laying a biodegradable biological green net (dustproof cover), protect water screen cloth layer at the regional production of conflagration to be used for isolated fire behavior, play the effect of fire control and put out a fire, to regional fire prevention and cure such as forest, grassland, urban building, have apparent effect.
In this example, the super absorbent resin is selected from starch super absorbent resin or cellulose super absorbent resin.
Also preferably, the raw materials of the mixed spray also comprise fluffy granules prepared by crushing cattail fiber and a degradable coloring agent.
To sum up, this biodegradable green net (dustproof cover) can use unmanned aerial vehicle to spray, the mobile vehicle sprays, the coiled material is laid to machinery, the mode such as coiled material is laid to the manual work and lay, and is very convenient.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.

Claims (9)

1. The utility model provides a coiled material formula biodegradable biological dustproof green net, includes screen cloth structural layer, its characterized in that: the mesh fabric structure layer is made of degradable materials, and water-retaining agents, nutritional agents and plant seeds are uniformly distributed in the mesh fabric structure layer, wherein the water-retaining agents are super absorbent resin.
2. The roll-type degradable biological dustproof green net according to claim 1, wherein the degradable material is degradable plastic or super absorbent resin.
3. The roll-type degradable biological dustproof green net according to claim 2, wherein the degradable plastic is one or more of polylactic acid, polybutylene succinate/hexanoate, polyhydroxybutyrate/valerate, polyethylene succinate, polyesteramide, polycaprolactone, or a blend with starch.
4. The roll-type degradable biological dustproof green net according to claim 1 or 2, wherein the super absorbent resin is selected from starch super absorbent resins or cellulose super absorbent resins.
5. The roll type degradable biological dustproof green net according to claim 1, wherein the mesh fabric structural layer is also distributed with bulky granules prepared by smashing cattail fiber and a degradable coloring agent.
6. The utility model provides a spray formula biodegradable biological green net that prevents dust which characterized in that: the dustproof green net is formed by spraying mixed spray on an exposed surface and then drying and expanding, the raw materials of the mixed spray comprise a water-retaining agent, a nutrient, plant seeds and water, wherein the water-retaining agent is super absorbent resin.
7. The spray-type degradable biological dustproof green screen of claim 6, which is characterized in that: the spraying refers to: spraying with two parallel pipes, one spraying water and the other spraying water retaining agent, nutritious agent and plant seed mixture.
8. The spray-type degradable biological dustproof green screen of claim 6, which is characterized in that: the super absorbent resin is selected from starch super absorbent resin or cellulose super absorbent resin.
9. The spray-type degradable biological dustproof green screen of claim 6, which is characterized in that: the raw materials of the mixed spray also comprise leavened granules prepared by smashing cattail fiber and degradable coloring agent.
CN202210339199.5A 2022-04-01 2022-04-01 Degradable biological dustproof green net Pending CN114711056A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11280074A (en) * 1998-03-31 1999-10-12 Nisshoku Corp Biodegradable net and vegetation basic body and tree planting construction method
JPH11323940A (en) * 1998-05-16 1999-11-26 Nisshoku Corp Vegetation substrate for seeding and planting and seeding and planting vegetation method
EP1116434A1 (en) * 2000-01-11 2001-07-18 Albert W. Morgan Biodegradable mulch mat
JP2002021088A (en) * 2000-07-10 2002-01-23 Kuraray Co Ltd Construction method for greening
JP2005130732A (en) * 2003-10-29 2005-05-26 Aica Kogyo Co Ltd Greening material
KR100496118B1 (en) * 2004-02-02 2005-06-16 충청북도 Method to keep a green slope surface
CN114232126A (en) * 2021-12-07 2022-03-25 雄安创新研究院 Full-biodegradable efficient dust screen and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11280074A (en) * 1998-03-31 1999-10-12 Nisshoku Corp Biodegradable net and vegetation basic body and tree planting construction method
JPH11323940A (en) * 1998-05-16 1999-11-26 Nisshoku Corp Vegetation substrate for seeding and planting and seeding and planting vegetation method
EP1116434A1 (en) * 2000-01-11 2001-07-18 Albert W. Morgan Biodegradable mulch mat
JP2002021088A (en) * 2000-07-10 2002-01-23 Kuraray Co Ltd Construction method for greening
JP2005130732A (en) * 2003-10-29 2005-05-26 Aica Kogyo Co Ltd Greening material
KR100496118B1 (en) * 2004-02-02 2005-06-16 충청북도 Method to keep a green slope surface
CN114232126A (en) * 2021-12-07 2022-03-25 雄安创新研究院 Full-biodegradable efficient dust screen and preparation method thereof

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Application publication date: 20220708